CN106978070A - A kind of environment-friendly type coating based on nano material - Google Patents
A kind of environment-friendly type coating based on nano material Download PDFInfo
- Publication number
- CN106978070A CN106978070A CN201710273324.6A CN201710273324A CN106978070A CN 106978070 A CN106978070 A CN 106978070A CN 201710273324 A CN201710273324 A CN 201710273324A CN 106978070 A CN106978070 A CN 106978070A
- Authority
- CN
- China
- Prior art keywords
- parts
- resin
- environment
- nano
- friendly type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
Constituted the invention discloses a kind of environment-friendly type coating based on nano material, including by the component of following parts by weight：15 30 parts of modified polysiloxane resin, 5 10 parts of nano titanium oxide, 36 parts of nano silicon, 8 10 parts of nano titanium oxide, 15 20 parts of aqueous weatherability cycloaliphatic epoxy resin, 23 parts of defoamer, 34 parts of wetting agent, 1.5 1.8 parts of levelling agent, 10 20 parts of deionized water, 15 20 parts of natural plant aqueous resin, 8 10 parts of sodium acetate, 12 18 parts of resin dispersion, 58 parts of catalyst.
Description
Technical field
The present invention relates to a kind of coating, and in particular to a kind of environment-friendly type coating based on nano material.
Background technology
With the sustained, stable growth and the continuous improvement of people's living standard of China's economy, building and decoration trade are just swift and violent
Development, the annual requirement of domestic construction coating for internal and external wall up to millions of tons more than.But, inner-outer wall building is applied both at home and abroad at present
The exemplary shortcomings of material are that resistance to soiling is poor, outdoor durable is bad so that skin, especially different kinds of roads (highway,
Railway, urban road) nearby buildings and other Architectural Equipments usually have various dusts.Dirt, greasy dirt etc., very influence beautiful
See.Traditional solvent paint (being commonly called as paint) can be to health, environmental danger, especially indoors in use, benzene class etc. has
The organic solvent of poison persistently volatilizees, and the time is long, and the health and lives for directly endangering people are safe, therefore, and exploitation has safety and environmental protection
Coating is to pay close attention to the technical problem that health one must be solved.
There is low VOC, the more environmentally friendly water paint of heavy metal free and its preparation it is an object of the invention to provide a kind of
Method.Coating provided by the present invention is applied widely, not only with excellent covering power, adhesive force and outstanding water resistance,
Chemical resistance, wear resistance, will not produce electrostatic phenomenon, and can reduce the volatile quantity and content of beary metal of organic compound,
It is a kind of coating of safety and environmental protection.
The content of the invention
The technical problems to be solved by the invention are that existing coating does not have environmentally friendly function, and adhesive force ability etc.
Poor performance, it is therefore intended that provide a kind of environment-friendly type coating based on nano material, solves existing coating not environmentally, and adhesive force
Poor the problem of.
The present invention is achieved through the following technical solutions：
A kind of environment-friendly type coating based on nano material, including be made up of the component of following parts by weight：Modified poly- silica
It is 15-30 parts of alkane resin, 5-10 parts of nano titanium oxide, 3-6 parts of nano silicon, 8-10 parts of nano titanium oxide, aqueous resistance to
15-20 parts of cycloaliphatic epoxy resin of time property, 2-3 parts of defoamer, 3-4 parts of wetting agent, 1.5-1.8 parts of levelling agent, deionized water 10-
20 parts, 15-20 parts of natural plant aqueous resin, 8-10 parts of sodium acetate, 12-18 parts of resin dispersion, 5-8 parts of catalyst.
A kind of environment-friendly type coating based on nano material, the coating is made up of the component of following parts by weight：It is modified poly-
25 parts of silicone resin, 7 parts of nano titanium oxide, 5 parts of nano silicon, 9 parts of nano titanium oxide, aqueous weatherability alicyclic ring
18 parts of race's epoxy resin, 2.5 parts of defoamer, 3.5 parts of wetting agent, 1.6 parts of levelling agent, 18 parts of deionized water, natural plant aqueous
18 parts of resin, 9 parts of sodium acetate, 15 parts of resin dispersion, 6 parts of catalyst.
A kind of environment-friendly type coating based on nano material, the resin dispersion is styrene-acrylic emulsion, silicone acrylic emulsion, acrylic acid
One or more in resin or emulsion, polyurethane resin, aqueous polyester resin, epoxy water-base resin.
A kind of environment-friendly type coating based on nano material, the catalyst is potassium peroxydisulfate.
Specifically, natural plant aqueous resin extracts manufacture from pure plant, product is in a liquid state natural drying, has
One or both of the nontoxic aromatic odor of natural vegetation Normal juice, preferably rosin, raw lacquer, maple fat, fir resin, trachelospermum jasminoide resin
Mixture above, further preferred rosin or raw lacquer or its mixture.
Sodium acetate can adjust the acid-base value of emulsion as buffer, it is ensured that the smoothness of elicitation procedure.
The resin dispersion be styrene-acrylic emulsion, silicone acrylic emulsion, acrylic resin, polyurethane resin, aqueous polyester resin,
One or more in epoxy water-base resin.What resin dispersion was selected is free from free monomer, without triphen, VOC content
≤ 65g/L material.
Above-mentioned resin dispersion is under the emulsification of dodecyl sodium sulfate, and in catalyst potassium peroxydisulfate and buffer
Under the collective effect of sodium acetate, polymerization forms copolymer.Solid thing composition in water paint is exactly above-mentioned copolymer.
The present invention compared with prior art, has the following advantages and advantages：
1st, a kind of environment-friendly type coating based on nano material of the present invention, the coating prepared by the present invention is nontoxic, to ring
Border pollution is small, and adhesive force is better than existing environmental protection coating material；
2nd, a kind of environment-friendly type coating based on nano material of the present invention, adhesive force of the invention is preferable, and its water resistance,
The performance such as chemical resistance, wear-resistant is also preferable；
Embodiment
For the object, technical solutions and advantages of the present invention are more clearly understood, with reference to embodiment, to present invention work
Further to describe in detail, exemplary embodiment and its explanation of the invention is only used for explaining the present invention, is not intended as to this
The restriction of invention.
Embodiment 1
A kind of environment-friendly type coating based on nano material of the present invention, the coating is made up of the component of following parts by weight：
It is 25 parts of modified polysiloxane resin, 7 parts of nano titanium oxide, 5 parts of nano silicon, 9 parts of nano titanium oxide, aqueous weather-proof
Property 18 parts of cycloaliphatic epoxy resin, 2.5 parts of defoamer, 3.5 parts of wetting agent, 1.6 parts of levelling agent, 18 parts of deionized water, natural plant
18 parts of thing water-base resin, 9 parts of sodium acetate, 15 parts of resin dispersion, 6 parts of catalyst.The resin dispersion is styrene-acrylic emulsion, silicon
One or more in acrylic emulsion, acrylic resin or emulsion, polyurethane resin, aqueous polyester resin, epoxy water-base resin.Institute
Catalyst is stated for potassium peroxydisulfate.
Nano titanium oxide, wetting agent are proportionally added into deionized water and be mixed evenly, is entered with 600-800rpm
Row is uniformly dispersed at a high speed, obtains water-borne dispersions；
In the natural plant aqueous resin that water-borne dispersions are added to stirring, after stirring, by modified polyorganosiloxane tree
Fat, nano silicon, aqueous weatherability cycloaliphatic epoxy resin in proportion together add grinding pot in stir, then by than
Example adds defoamer, stirs 50 minutes, to fineness≤4 μm, is then proportionally added into levelling agent, deionized water, sodium acetate, scattered
Body resin, catalyst are filtered after stirring, and moisturizing simultaneously adjusts viscosity for 90KU, and environment-friendly type coating is made.
Obtained coating material is nontoxic in the present embodiment, and environmental pollution is small and its adhesive force is better than existing
The 9% of the adhesive force of coating, meanwhile, also with the performance such as preferable water resistance, chemical resistance, wear-resistant.
Embodiment 2
The coating is made up of the component of following parts by weight：10 parts of modified polysiloxane resin, nano titanium oxide 3
Part, 1 part of nano silicon, 5 parts of nano titanium oxide, 11 parts of aqueous weatherability cycloaliphatic epoxy resin, 1 part of defoamer, profit
1 part of humectant, 1 part of levelling agent, 5 parts of deionized water, 8 parts of natural plant aqueous resin, 6 parts of sodium acetate, 8 parts of resin dispersion, urge
1 part of agent.The resin dispersion is styrene-acrylic emulsion, silicone acrylic emulsion, acrylic resin or emulsion, polyurethane resin, polyester water
One or more in property resin, epoxy water-base resin.The catalyst is potassium peroxydisulfate.
Nano titanium oxide, wetting agent are proportionally added into deionized water and be mixed evenly, is entered with 600-800rpm
Row is uniformly dispersed at a high speed, obtains water-borne dispersions；
In the natural plant aqueous resin that water-borne dispersions are added to stirring, after stirring, by modified polyorganosiloxane tree
Fat, nano silicon, aqueous weatherability cycloaliphatic epoxy resin in proportion together add grinding pot in stir, then by than
Example adds defoamer, stirs 50 minutes, to fineness≤4 μm, is then proportionally added into levelling agent, deionized water, sodium acetate, scattered
Body resin, catalyst are filtered after stirring, and moisturizing simultaneously adjusts viscosity for 90KU, and environment-friendly type coating is made.
The VOC that obtained coating contains in embodiment 2 is higher than coating obtained in embodiment 1, therefore its environment-friendly type
Embodiment 1 is worse than, meanwhile, its poor adhesive force is also, its water resistance, chemical resistance, wear-resistant in the adhesive force of existing coating
Coating prepared in embodiment 1 is also worse than etc. performance.
Embodiment 3
The coating is made up of the component of following parts by weight：40 parts of modified polysiloxane resin, nano titanium oxide 15
Part, 8 parts of nano silicon, 15 parts of nano titanium oxide, 25 parts of aqueous weatherability cycloaliphatic epoxy resin, 5 parts of defoamer, profit
6 parts of humectant, 5 parts of levelling agent, 36 parts of deionized water, 35 parts of natural plant aqueous resin, 20 parts of sodium acetate, resin dispersion 20
Part, 12 parts of catalyst.The resin dispersion be styrene-acrylic emulsion, silicone acrylic emulsion, acrylic resin or emulsion, polyurethane resin,
One or more in aqueous polyester resin, epoxy water-base resin.The catalyst is potassium peroxydisulfate.
Nano titanium oxide, wetting agent are proportionally added into deionized water and be mixed evenly, is entered with 600-800rpm
Row is uniformly dispersed at a high speed, obtains water-borne dispersions；
In the natural plant aqueous resin that water-borne dispersions are added to stirring, after stirring, by modified polyorganosiloxane tree
Fat, nano silicon, aqueous weatherability cycloaliphatic epoxy resin in proportion together add grinding pot in stir, then by than
Example adds defoamer, stirs 50 minutes, to fineness≤4 μm, is then proportionally added into levelling agent, deionized water, sodium acetate, scattered
Body resin, catalyst are filtered after stirring, and moisturizing simultaneously adjusts viscosity for 90KU, and environment-friendly type coating is made.
The VOC that obtained coating contains in embodiment 3 is higher than coating obtained in embodiment 1, while in embodiment 3
The VOC of prepared coating is less than the coating in embodiment 2, therefore its environment-friendly type is worse than embodiment 1, meanwhile, in embodiment 3
Adhesive force is better than the 2% of existing coating；Also, the performance such as its water resistance, chemical resistance, wear-resistant is also worse than in embodiment 1
Prepared coating.
In summary, embodiments of the invention 1 are in the formula range of the present invention, embodiment 2 and embodiment 3 and embodiment
1 has same composition, but the component formula of embodiment 2 and embodiment 3 is outside the formula range of the present invention, obtained coating
Environment-friendly type embodiment 1 in preferably, and embodiment 1 also has preferable water resistance, chemical resistance, the performance such as wear-resistant, because
This component formula of the invention complements each other, and the adhesive force of coating obtained in the formula range of the present invention and its
His performance is preferably and the most environmentally friendly.
Above-described embodiment, has been carried out further to the purpose of the present invention, technical scheme and beneficial effect
Describe in detail, should be understood that the embodiment that the foregoing is only the present invention, be not intended to limit the present invention
Protection domain, within the spirit and principles of the invention, any modification, equivalent substitution and improvements done etc. all should be included
Within protection scope of the present invention.
Claims (4)
1. a kind of environment-friendly type coating based on nano material, it is characterised in that be made up of the component of following parts by weight：It is modified poly-
15-30 parts of silicone resin, 5-10 parts of nano titanium oxide, 3-6 parts of nano silicon, 8-10 parts of nano titanium oxide, water
15-20 parts of weatherability cycloaliphatic epoxy resin of property, 2-3 parts of defoamer, 3-4 parts of wetting agent, 1.5-1.8 parts of levelling agent, deionization
10-20 parts of water, 15-20 parts of natural plant aqueous resin, 8-10 parts of sodium acetate, 12-18 parts of resin dispersion, 5-8 parts of catalyst.
2. a kind of environment-friendly type coating based on nano material according to claim 1, it is characterised in that the coating by with
The component composition of lower parts by weight：25 parts of modified polysiloxane resin, 7 parts of nano titanium oxide, 5 parts of nano silicon, receive
9 parts of titanium dioxide of rice, 18 parts of aqueous weatherability cycloaliphatic epoxy resin, 2.5 parts of defoamer, 3.5 parts of wetting agent, levelling agent 1.6
Part, 18 parts of deionized water, 18 parts of natural plant aqueous resin, 9 parts of sodium acetate, 15 parts of resin dispersion, 6 parts of catalyst.
3. a kind of environment-friendly type coating based on nano material according to claim 1, it is characterised in that the dispersion tree
Fat is in styrene-acrylic emulsion, silicone acrylic emulsion, acrylic resin or emulsion, polyurethane resin, aqueous polyester resin, epoxy water-base resin
One or more.
4. a kind of environment-friendly type coating based on nano material according to claim 1, it is characterised in that the catalyst is
Potassium peroxydisulfate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710273324.6A CN106978070A (en) | 2017-04-21 | 2017-04-21 | A kind of environment-friendly type coating based on nano material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710273324.6A CN106978070A (en) | 2017-04-21 | 2017-04-21 | A kind of environment-friendly type coating based on nano material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106978070A true CN106978070A (en) | 2017-07-25 |
Family
ID=59344754
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710273324.6A Withdrawn CN106978070A (en) | 2017-04-21 | 2017-04-21 | A kind of environment-friendly type coating based on nano material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106978070A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107964352A (en) * | 2017-10-27 | 2018-04-27 | 成都瞬科仪器仪表有限公司 | A kind of environment-friendly type coating |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105385342A (en) * | 2015-11-24 | 2016-03-09 | 安徽省金盾涂料有限责任公司 | Aqueous weather-resisting polysiloxane coating |
-
2017
- 2017-04-21 CN CN201710273324.6A patent/CN106978070A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105385342A (en) * | 2015-11-24 | 2016-03-09 | 安徽省金盾涂料有限责任公司 | Aqueous weather-resisting polysiloxane coating |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107964352A (en) * | 2017-10-27 | 2018-04-27 | 成都瞬科仪器仪表有限公司 | A kind of environment-friendly type coating |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105017906B (en) | A kind of colorful sealing wax of water-water and preparation method thereof | |
| CN104140732B (en) | A kind of water paint of high salt fog high durable and preparation method thereof | |
| CN105219195B (en) | A kind of compound sliver paint of aqueous colorful and preparation method thereof | |
| CN106867406A (en) | The preparation method of the new environment-friendly type coating based on nano material | |
| CN103013258A (en) | Uvioresistant super-self-cleaning granite building coating and preparation method thereof | |
| CN106752430A (en) | A kind of diatom ooze Environmentally-frieinner-wall inner-wall emulsion paint and preparation method thereof | |
| CN105440925A (en) | Waterborne woodware surface color modifier | |
| CN102898906A (en) | Environment-friendly water-based metal decorative effect coating and preparation method thereof | |
| CN105462470A (en) | High-fullness and high-performance one-component waterborne polyurethane top-coat varnish | |
| CN102643586A (en) | High-solid-content quick-drying water-based white primer and preparation method thereof | |
| CN104497726A (en) | Sprayable diatom-based styrene-acrylic interior wall coating having humidity-regulating function and preparation method of sprayable diatom-based styrene-acrylic interior wall coating | |
| CN103409023A (en) | Aqueous high weather-proof matt exterior wall emulsion paint and preparation method thereof | |
| CN103666174A (en) | Heat reflecting paint, and preparation method and application thereof | |
| CN104497732A (en) | Heat discoloration emulsion paint and preparation method thereof | |
| CN108977015A (en) | A kind of water alcohol acid finishing coat and its preparation method and application | |
| CN112778860A (en) | Reflective heat-insulation sand-containing multicolor paint | |
| CN104610863A (en) | Single-component and double-component compound water-based wood top-coat paint and preparation method thereof | |
| CN106752488A (en) | Road sign reflectorised paint and preparation method thereof | |
| CN104293075A (en) | Modified polyaniline type anticorrosive coating and preparation method thereof | |
| CN106978070A (en) | A kind of environment-friendly type coating based on nano material | |
| CN102220061B (en) | Core-shell polyurethane and acrylic acid copolymer aqueous wood lacquer and preparation method thereof | |
| CN107652790A (en) | The preparation method of environment-friendly type coating | |
| CN107141922A (en) | A kind of universal aqueous metal bucket baking vanish | |
| CN104419276A (en) | Graffiti-resistant interior wall paint formula and preparation method thereof | |
| CN107964352A (en) | A kind of environment-friendly type coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170725 |