CN106977777B - Radial air tire carcass layer kiss-coating - Google Patents

Radial air tire carcass layer kiss-coating Download PDF

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Publication number
CN106977777B
CN106977777B CN201710263810.XA CN201710263810A CN106977777B CN 106977777 B CN106977777 B CN 106977777B CN 201710263810 A CN201710263810 A CN 201710263810A CN 106977777 B CN106977777 B CN 106977777B
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CN
China
Prior art keywords
coating
kiss
air
adhesion promoter
tire
Prior art date
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Application number
CN201710263810.XA
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Chinese (zh)
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CN106977777A (en
Inventor
吴春齐
俞华英
刘蓉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chemchina Shuguang Rubber Industry Research and Design Institute Co Ltd
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Chemchina Shuguang Rubber Industry Research and Design Institute Co Ltd
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Publication date
Application filed by Chemchina Shuguang Rubber Industry Research and Design Institute Co Ltd filed Critical Chemchina Shuguang Rubber Industry Research and Design Institute Co Ltd
Priority to CN201710263810.XA priority Critical patent/CN106977777B/en
Publication of CN106977777A publication Critical patent/CN106977777A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0041Compositions of the carcass layers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

Rubber system of the present invention is used in combination using natural rubber and butadiene rubber.Reinforcement system is using STERLIN V (SV) carbon blacks and uses part white carbon, the compounding agents such as addition silane coupling agent KH 560, adhesive SL 3090, adhesion promoter AIR 201, adhesion promoter AIR 1 in formula.The body piles kiss-coating hardness of the present invention, stress at definite elongation are relatively low, and sizing material is softer, and body piles kiss-coating is not just allowed to be also easy to produce breach when repeated deformation;It is suitable for the high performance requirement of the following new architecture tire high speed, high load, renovation number;Sizing material and nylon cord adhesive strength are high before aging, after aging, and fatigue performance is good, heat is low, rebound value is high, hysteresis loss is small, and carcass delamination layer, bulge, sidewall can be prevented quick-fried, improves the service life and security performance of radial air tire.

Description

Radial air tire carcass layer kiss-coating
Technical field
The present invention relates to technical field of polymer materials, specifically radial air tire carcass layer kiss-coating.
Background technology
Radial air tire carcass layer is the skeleton of tire, other than the air pressure for bearing tire, still suffers from tire Load and the external impact force of buffering, meridian tyre body layer cord radially arrange, sidewall radial deformation compares oblique Tire is big by 10%~30%, and in addition radial air tyre rebuilding number requires high, and existing radial air tire is due to speed Top load is big, and sidewall position distortions are big and many-sided reason such as kiss-coating raw material used and material combination causes tire high speed to be rolled It is quick-fried etc. that it is susceptible to carcass delamination layer, bulge, sidewall when dynamic, influences service life and safety.
Invention content
That the object of the present invention is to provide a kind of bond properties is good, fatigue performance is good, heat is low, hysteresis loss is small, rebound It is worth the radial air tire carcass layer kiss-coating of the features such as high.
Realizing the technical solution of the object of the invention is:
A kind of radial air tire carcass layer kiss-coating is to pass through two sections of mixer by following raw materials by weight ratio Be kneaded, produce rubber compound, rolled with tri-roll press machine and rubberized cord, body piles bandage is made in slice applying machine bench, at It is molded on type machine, green tyre is made, and become tire finished product by vulcanizer vulcanizes tire base;
1#Smoke sheet rubber 75~90
Cis-butadiene cement 9000 10~25
STERLIN V (SV) carbon black 25~28
White carbon 5~8
Silane coupling agent KH-560 1~3
Adhesion promoter AIR-201 1~3
Adhesion promoter AIR-1 1~5
Adhesive SL-3090 1~3
Adhesive A 1~2
Zinc oxide 3~6
Stearic acid 1~3
P phenylenediamine type antioxidant 4020 1~3
Antioxidant BLE 1~3
Aromatic naphtha 3~5
Insoluble sulfuy 1~3
Sulfenamide type accelerators 0.5~2
Anti-scorching agent CTP 0.1~0.3
Anti-recovery agent WK-901 0.2~0.5
Rubber system of the present invention is used in combination using natural rubber and butadiene rubber, and natural rubber has tensile strength high, elastic Greatly, heat is low, elongation is high, the good feature of processing performance, and the fatigue performance that butadiene rubber is conducive to improve sizing material is added, subtracts The hysteresis loss of small sizing material.Reinforcement system is using STERLIN V (SV) carbon blacks and with part white carbon, STERLIN V (SV) charcoal Black is a kind of semi-reinforcing hydrocarbon black, has the characteristics that easily dispersion, impurity content are few, are added the body piles of STERLIN V (SV) carbon black Kiss-coating fatigue performance is good, heat is low, hysteresis loss is small;White carbon, which is added, can reduce the heat of sizing material, improve sizing material and brocade The adhesive strength of synthetic fibre cord.Silane coupling agent KH-560 is added in formula, the bonding with nylon cord after sizing material aging can be improved Intensity;Adhesive SL-3090 is added in formula, adhesion promoter AIR-201, AIR-1 improve the bond properties of sizing material and cord. Preventing aging system is used in combination using p phenylenediamine type antioxidant 4020 and ketoamine class anti-aging agent RD, BLE, and antioxidant 4020 is old to hot oxygen etc. Changing, there is excellent protective action, anti-aging agent RD to have the function of that the oxidation of rejection condition harshness and heat ageing, antioxidant BLE remove Play the role of outside age inhibiting, while being conducive to the bonding of glue and line.Anti-recovery agent WK-901 is added, improves the anti-of sizing material Recovery performance prevents body piles kiss-coating from reverting when being repeatedly remoulded vulcanization.
The present invention is a kind of radial air tire carcass layer kiss-coating, and specific performance is shown in Table 2. after tested
2 properties of rubber of table
Advantages of the present invention:
1. the body piles kiss-coating hardness of the present invention, stress at definite elongation are relatively low, sizing material is softer, and body piles kiss-coating is repeatedly Just do not allow to be also easy to produce breach when deformation;
2. being suitable for the high performance requirement of the following new architecture tire high speed, high load, renovation number;Before aging, after aging Sizing material is high with nylon cord adhesive strength, and fatigue performance is good, heat is low, rebound value is high, hysteresis loss is small, can prevent tire Carcass delamination layer, bulge, sidewall are quick-fried, improve the service life and security performance of radial air tire.
Description of the drawings
Fig. 1 is that the comprehensive of tire cuts structural schematic diagram;
In figure:1 tread rubber, 2 belts, 3 shoulder wedges, 4 body piles kiss-coatings, 5 sidewalls, 6 tyre beads.
Specific implementation mode
With reference to embodiment, the present invention will be further described, but is not limitation of the invention.
Each component raw material dosage is parts by weight in embodiment
Raw material title Embodiment 1 Embodiment 2
1#Smoke sheet rubber 75 80
Cis-butadiene cement 9000 25 20
STERLIN V (SV) carbon black 27 30
White carbon 8 5
Silane coupling agent KH-560 2 2
Adhesion promoter AIR-201 1 2
Adhesion promoter AIR-1 3 2
Adhesive SL-3090 2 2
Adhesive A 1.5 1.5
Zinc oxide 5 5
Stearic acid 2 2
P phenylenediamine type antioxidant 4020 2 2
Antioxidant BLE 2 2
Aromatic naphtha 3 3
Insoluble sulfuy 2 2
Sulfenamide type accelerators 1.5 1.5
Anti-scorching agent CTP 0.2 0.2
Anti-recovery agent WK-901 0.4 0.3

Claims (1)

1. a kind of radial air tire carcass layer kiss-coating, characterized in that be passed through by following raw materials by weight ratio it is close Mill two-stage mixing forms:
1#Smoke sheet rubber 75~90
Cis-butadiene cement 9,000 10~25
STERLING V (SV) carbon black 25~28
White carbon 5~8
Silane coupling agent KH-560 1~3
Adhesion promoter AIR-201 1~3
Adhesion promoter AIR-1 1~5
Adhesive SL-3090 1~3
Adhesive A 1~2
Zinc oxide 3~6
Stearic acid 1~3
P phenylenediamine type antioxidant 4,020 1~3
Antioxidant BLE 1~3
Aromatic naphtha 3~5
Insoluble sulfuy 1~3
Sulfenamide type accelerators 0.5~2
Anti-scorching agent CTP 0.1~0.3
Anti-recovery agent WK-901 0.2~0.5.
CN201710263810.XA 2017-04-21 2017-04-21 Radial air tire carcass layer kiss-coating Active CN106977777B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710263810.XA CN106977777B (en) 2017-04-21 2017-04-21 Radial air tire carcass layer kiss-coating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710263810.XA CN106977777B (en) 2017-04-21 2017-04-21 Radial air tire carcass layer kiss-coating

Publications (2)

Publication Number Publication Date
CN106977777A CN106977777A (en) 2017-07-25
CN106977777B true CN106977777B (en) 2018-10-09

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Country Status (1)

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Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109929155B (en) * 2017-12-15 2021-08-03 中国石油化工股份有限公司 Rubber composition for shoe sole, vulcanized rubber, and preparation method and application thereof
CN112552558A (en) * 2020-12-04 2021-03-26 中国化工集团曙光橡胶工业研究设计院有限公司 Cord fabric skim of bias aircraft tire and preparation method thereof
CN112592519A (en) * 2020-12-15 2021-04-02 中国化工集团曙光橡胶工业研究设计院有限公司 Aviation radial tire tread rubber and preparation method thereof
CN113512238A (en) * 2021-08-09 2021-10-19 中国化工集团曙光橡胶工业研究设计院有限公司 Aircraft tire bead reinforcing rubber and preparation method and application thereof
CN115785537A (en) * 2022-12-16 2023-03-14 中国化工集团曙光橡胶工业研究设计院有限公司 Repair adhesive for hot repair of aircraft tire appearance defects and preparation method and application thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60139727A (en) * 1983-12-27 1985-07-24 Ohtsu Tire & Rubber Co Ltd Tire tread rubber composition
CN1069234A (en) * 1992-06-30 1993-02-24 沈阳第三橡胶厂 Crooked pattern tyre for high speed truck
CN102746536B (en) * 2012-06-29 2013-12-11 中橡集团曙光橡胶工业研究设计院 Formula of low-heat generation aircraft tire tread rubber
CN103881152A (en) * 2012-12-21 2014-06-25 风神轮胎股份有限公司 All steel truck radial tire tread rubber
CN104987549A (en) * 2015-07-31 2015-10-21 中国化工集团曙光橡胶工业研究设计院有限公司 Aviation tire reinforcing layer adhesive of high adhesive strength

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