CN106968111A - A kind of preparation method of pressure automobile massage seat air bag - Google Patents

A kind of preparation method of pressure automobile massage seat air bag Download PDF

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Publication number
CN106968111A
CN106968111A CN201710346763.5A CN201710346763A CN106968111A CN 106968111 A CN106968111 A CN 106968111A CN 201710346763 A CN201710346763 A CN 201710346763A CN 106968111 A CN106968111 A CN 106968111A
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preparation
base fabric
air bag
seat air
massage seat
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CN106968111B (en
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余讲兵
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Shanghai Yi Shan Electrical Appliances Co Ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/10—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with styrene-butadiene copolymerisation products or other synthetic rubbers or elastomers except polyurethanes
    • D06N3/106—Elastomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/695—Polyesters containing atoms other than carbon, hydrogen and oxygen containing silicon
    • C08G63/6954—Polyesters containing atoms other than carbon, hydrogen and oxygen containing silicon derived from polxycarboxylic acids and polyhydroxy compounds
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/08—Melt spinning methods
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/08—Melt spinning methods
    • D01D5/088—Cooling filaments, threads or the like, leaving the spinnerettes
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
    • D02J1/22—Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
    • D02J1/22—Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch
    • D02J1/224—Selection or control of the temperature during stretching
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
    • D02J1/22—Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch
    • D02J1/229—Relaxing
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00—Woven fabrics designed to make specified articles
    • D03D1/02—Inflatable articles
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C15/00—Calendering, pressing, ironing, glossing or glazing textile fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/12—Decorative or sun protection articles
    • D06N2211/26—Vehicles, transportation
    • D06N2211/268—Airbags

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

A kind of preparation method of pressure automobile massage seat air bag, it is characterised in that the air bag is made in the coating by preparing base fabric long filament, base fabric and gluing liquid, and the air bag intensity prepared by this method is good, antistatic and convenient large-scale production.

Description

A kind of preparation method of pressure automobile massage seat air bag
Technical field
The present invention relates to a kind of preparation method of pressure automobile massage seat air bag.
Background technology
Various air bags are developed in recent years, and its validity has obtained the understanding of people, quickly gets reality Using.But people's still demand is not limited using the environment of air bag, its mechanical performance under the harsh and unforgiving environments such as high temperature or low temperature still Keep stable air bag.In the past, Tynex occupied the market share of the overwhelming majority always.But with gas cell fabric finishing technique Development, polyester industrial yarn due to be increasingly used for the advantages of cost is low, intensity is high, chemical resistance is good gas cell fabric plus Work.As the polyester industrial yarn of air bag, fine denier filament is selected, it is possible to decrease air bag quality more, make it easy to fold and install. Desired strength is high simultaneously, it is big to extend.But the fiber is unfavorable for the raising of drafting multiple, it is difficult to obtain the fiber of high intensity, this Invention seeks to provide a kind of preparation side for the pressure automobile massage seat air bag that intensity is good, and antistatic and convenience is mass produced Method.
The content of the invention
The purpose of patent of the present invention is that offer intensity is good, the pressure automobile massage of antistatic and convenient large-scale production The preparation method of seat air bag, the present invention is adopted the following technical scheme that：
A kind of preparation method of pressure automobile massage seat air bag, it is characterised in that comprise the following steps：
Step one, base fabric long filament is prepared using modified poly ester；
Step 2, base fabric is prepared by base fabric long filament through weaving, (base fabric be by warp thread and weft yarn cross fork-shaped into)；
Step 3, the coating of gluing liquid：Calendering is carried out to base fabric using multi-functional calender, will using scraper coating machine Adhesive is coated to base fabric, by drying, is bakeed, cooling obtains air bag.
2nd, a kind of preparation method of pressure automobile massage seat air bag as claimed in claim 1, it is characterised in that step The preparation method of base fabric long filament described in one comprises the following steps：
A, Modified polyester chips preparation
The preparation of modified poly ester：By the amino ethylene glycol fatty acid, trimethylolpropane, silicone intermediate of preparation with Mass ratio is 3-6:0.5-2:2-5 is mixed, and 5-15min is stirred at 180 DEG C and obtains mixed liquor, addition mixed liquor quality 1% Dibutyltin dilaurate catalyst, opens vavuum pump, is warming up to 230 DEG C, is incubated 60-120min, and the first modified resin is made, Vacuum is closed, about 160 DEG C are cooled to, the 20-25% triphenyl phosphites of the first modified resin quality are added, after stirring, The first modified resin quality 10-15% trimellitic anhydride is added, 200-250 DEG C is warming up to, about 2h is incubated, is passed through nitrogen, is dropped Temperature adds N, it is 7.5~8.5 that N- dimethylethanolamines, which carry out being neutralized to pH value, produces modified polyester resin to 80-150 DEG C；
The preparation of the viscous section of the height of modified poly ester：Solid phase polycondensation is viscosified after modified poly ester is granulated, and obtains modified poly- The viscous section of the height of ester, inherent viscosity is 1.0~1.2dL/g, preferably 1.15dL/g；
B, chip drying
Chip drying, main drying tower is placed in by section, and the electrical heating temperature in its drying tower is about 175 DEG C, dry in trunk The residence time is 5h in tower；
C, melt spinning：By dried polyester slice and the first compound using mass ratio as 3-6:2-4 is in mixed at high speed Mixed in machine, be delivered to spinning screw extruder, melted in spinning screw extruder, temperature setting is warming up to 15 DEG C/min 278 DEG C of holding 20-60min, 290 DEG C of holding 30-60min are warming up to 5 DEG C/min, and 310 DEG C of holding 5- are warming up to 3 DEG C/min 30min, enters filament spinning component by measuring pump afterwards and carries out melt spinning from spinneret extrusion, add by by slow cooling heater Heat, slow cooling heating-up temperature is 270-320 DEG C, then is cooled and shaped through side type blowing device, subsequently into spinning shaft, is obtained First fiber；
D, stretching and winding：
The first high temperature resistant finish is sprayed in the first fiber surface first, oil concentration used is 14%, then in 80-120 DEG C draft temperature and draft speed are that stretching drawing-off is carried out under the conditions of 500-3000m/min, draw ratio be in 3.3-3.8, then By 230-255 DEG C of high temperature relaxation heat setting, relaxation rate is 4-12%；
Secondly the long filament after to relaxation heat setting carries out the second high temperature resistant finish, and concentration is 35-40%, in 180~260 At DEG C under 1000-3000m/min winding speed to oiling after long filament carry out the compound coiling and molding of three peacekeepings two dimension, base is made Cloth long filament；
3rd, a kind of preparation method of pressure automobile massage seat air bag as claimed in claim 1, it is characterised in that step Gluing liquid is composed of the following components described in the application step of gluing liquid in three：
First component：For ethylene-alpha-olefin-nonconjugated diene copolymer rubber, its density is 850 to 900kg/m3, door Buddhist nun's viscosity (ML1+4(100 DEG C)) it is 30 to 150, iodine number is 0.1 to 40, and acetate unit content is 30 to 90 weight %；
Second component：Homopolymer and glass transition temperature by glass transition temperature less than 0 DEG C is equal at 10-50 DEG C Polymers is using mol ratio as 3-7:2-5 is constituted；
Crosslinking agent, the crosslinking agent is organic peroxide；
Sulphur system antioxidant；
First component, the second component, the mass ratio of crosslinking agent and sulphur system antioxidant are 20-40:20-35:2-6: 3-4。
4th, a kind of preparation method of pressure automobile massage seat air bag as claimed in claim 1, it is characterised in that step The application step of gluing liquid is further comprising the steps of in three：
A, using multi-functional calender at 110 DEG C to base fabric carry out calendering, pressure is 12MPa, and speed is 10m/min；
B, using scraper coating machine gluing liquid is coated to base fabric, contact pressure of the coating blade with the base fabric In the range of 0.5~4.0N/cm, the viscosity that gluing liquid is caused by temperature control is controlled in the range of 5-20Pas, and The upper and lower surface of base fabric fabric is applied to, coated weight is 15g/m2-200g/m2；
C, at 105 DEG C coating adhesive mucus dried, drying time is 40-60s；
D, as in enameling furnace at 150 DEG C bakee 60s obtain air bag.
5th, the preparation method of a kind of pressure automobile massage seat air bag as claimed in claim 1, it is characterised in that described Silicone intermediate is selected from methyl phenyl silicone resin intermediate in the preparation of modified poly ester；In melt spinning, the screw diameter For 125~150mm, draw ratio 25-30, a diameter of 190~220mm of spinneret；Stretching and winding：First oil resistant Agent is made up of mineral oil 55-80%, dodecyl sodium sulfate 2-8% and oleic acid diethyl amide 10-30%, the second resistance to height Warm finish is by mineral oil 30-55%；[(1,1,2,2- tetrafluoro ethyoxyl) methyl] oxirane 35-60%, dodecyl sodium sulfonate Sodium 2-7% is constituted.
6th, the preparation method of a kind of pressure automobile massage seat air bag as claimed in claim 2, it is characterised in that described First compound is using the general structure as described in formula (1)：
Carbochains of the R1 selected from H, C1-6 length, amino, hydroxyl, anilino-, carboxyl, carbonyl；The R2 is selected from H, C1- The carbochain of 6 length, amino, hydroxyl, carboxyl.
First compound may be selected from benzene sulfonic acid sodium salt, sodium sulfanilate, paratoluenesulfonic acid sodium salt, p-hydroxybenzenyl sulfonate Sodium, 2,4- diamino benzene sulfonic acids sodium, diphenylamines -4- sulfonate sodiums, 2- Sodium p-aminobenzene sulfonats, benzaldehyde -4- sodium sulfonates, 3- carboxyls Benzene sulfonic acid sodium salt, cumene sodium sulfonate or 4- cumene sodium sulfonates and its their arbitrary compositions.
Beneficial effect：
After adding neopentyl glycol in the preparation that research finds amino aliphatic acid so that the formation speed of amino aliphatic acid Accelerate, and product yield reaches 98%；
The long filament of the present invention is prepared from using homemade modified poly ester, and the modified poly ester has following excellent properties：
1st, heat endurance：The heat-staple protective layer of si-O-si keys is rich in the Surface Creation of copolymer, so that significantly The thermo oxidative stability of poly- cruel resin, and the increase for gathering silicone content in cruel resin copolymer with being modified are improved, The content of copolymer surface Si-O-si keys also relative increase, causes the heat endurance for being modified poly-vinegar resin also to gradually step up hot steady Qualitative to improve, peak melting temperature can reach 320-327 DEG C；
2nd, water absorbing properties：By modified the modified water absorption rate for gathering cruel resin film is substantially reduced, found by research, not It is 13-16% by the water absorbing properties of modified polyester resin, by modified, water absorption rate can be reduced to 1.32%, and this is Because organosilicon has relatively low surface free energy, the introducing of a small amount of organosilicon can make it in the modified surface enrichment for gathering cruel resin So as to improve the hydrophobic performance of copolymer.Method of testing：After modified poly- cruel resin film is weighed, it is soaked in 25e distilled water, Place and taken out after 24h, blot the moisture on surface with filter paper rapidly, measure its mass change, its water absorption rate is calculated according to following formula：
Q=(M1-M2)/M2*100%
Q is the modified water absorption rate % for gathering cruel resin film；
M1:Quality g after being absorbed water for sample,
M2：Quality g before being absorbed water for sample.
3rd, modified polyester resin by solidification, specific insulation has most reached 1.21*1015Ω·cm；Without changing The polyester resin 1.4*10 of property14Ω·cm。
4th, spinning melt temperature：Due to employing two kinds of components, therefore the rheology of spinning melt during melting extrusion Performance and spinnability depend primarily on the person's character and spinning melt temperature of various components.Effectively increase after with the addition of the first compound Entanglement point and the steric hindrance between melt macromolecular are added, the activity of macromolecular chain and segment is deteriorated, so that modified poly- The rheological property of ester spinning melt is poor compared to the rheological property of single polyester fondant.Therefore present invention employs gradual change type heating It (is specially to be melted in spinning screw, temperature setting is warming up to 15 DEG C/min that speed and gradual heating and heat preservation, which are melted, 27,8 DEG C of holding 20-60min, are warming up to 290 DEG C of holding 30-60min with 5 DEG C/min, 310 DEG C of holdings are warming up to 3 DEG C/min 5-30min) so that the rheological characteristic of melt drops to minimum, it is to avoid larger fluctuation occurs for spinning melt viscosity, and reduces lousiness And broken end, effectively improve the spinnability of spinning melt.
5th, side-blown wind velocity and temperature：Applicant has found by numerous studies, due to there are two kinds of component melts compared with list One compound is different, to obtain normal stretching thread, should select the rational technique bar such as side-blown wind velocity and temperature Part, shows cross air blasting speed control in 0.21-0.25m/s, preferably 0.23m/s, side-blown air temperature control by many experimental results System is at 25-27 DEG C, preferably 26 DEG C, can be effectively improved the defect of spinning melt rheological property and spinnability difference, improve spinning coil Fill forming quality and after-drawing performance；
6th, on drawing process：Applicant has found by numerous studies, due to there are two kinds of component melts, causes the later stage to be drawn It is different to stretch compared to single compound, therefore, and rate of deformation during stretching can not be too big, otherwise easily causes the heated work of strand Reduced with the time and produce very big stretching tensile stress, fiber is produced lousiness broken end and uniformity variation.Found by research Draw ratio selection is advisable between 3.3-3.8, and preferably 3.45, tensile stress and rate of extension can be effectively reduced, reduces and opens The fluctuation of power, improves the degree of orientation and crystallinity of fiber.
7th, creative first compound that adds carries out melt spinning, is found by test：Preparation-obtained fiber Long filament damping 24h in normal conditions, using YG061 type electronics single fiber strength testers, test speed is 20mm/min, and gauge is 20mm, is tested 50 times, pre-tension is 0.1cN.Length 40mm, line density/dtex=1.38.Add the modification of the first compound Polyester filaments fracture strength can reach 6.7
(cN·dtcx-1), elongation at break (%) is 23.8, and ratio resistance is 6.7*105(Ω·cm)；Unmodified polyester Resin fracture intensity can reach 4.9 (cNdtcx-1), elongation at break (%) is 20.8, and ratio resistance is 1.8*106(Ω· cm)；It can be seen that polyester fiber Jing Guo Gai Xing and adding the first compound and melt and obtain fiber filament fracture strength and obtain To effective lifting, fiber flexibility is also improved, and ratio resistance is reduced, and can effectively reduce electrostatic generation.
8th, as the method for covering on the two sides of base fabric fabric with gluing liquid, the coating that gluing liquid can be coated with liquid Mode.According to bed scraper for coating mode, tree is promoted by carrying on the back the pressure of two sides application appropriateness from the table of synthetic fabrics Fat is impregnated with to intertexture portion, it is easy to improve the area ratio of the resin in intertexture portion interface.It is preferred that by scraper and bottom to base Cloth contact is set to 0.5~4.0N/cm.Contact mentioned here is the width with the scraper contacted with synthetic fabrics Degree is except the value for the power for pushing scraper to synthetic fabrics.In the case where contact is less than 0.5N/cm, the coating of resin Amount is possible to become excessive, storage, flexibility is suffered damage, weight increase.If contact is more than 4.0N/cm, It is possible to that on the surface of synthetic fabrics uniform resin covering film can not be formed.It is preferred that contact be 1.0~3.0N/ Cm, most preferred contact is 2.5N/cm.
The first and second components are employed in gluing liquid：
First component is that the first component is divided into ethylene-alpha-olefin-nonconjugated diene copolymer rubber, and its density is 850 to 900kg/m3, Mooney viscosity (ML1+4(100 DEG C)) be 30 to 150, iodine number be 0.1 to 40, acetate unit content be 30 to 90 weight %；Second component is that homopolymer of the glass transition temperature less than 0 DEG C and glass transition temperature are equal at 10-50 DEG C Polymers；Find to further increase coated airbag being packaged into its mould using the collocation mode and proportioning of the present invention by studying Ability in part.Obtained hybrid resin shows at least 1,100p.si tensile strength and at least about 210% fracture is stretched Long rate.
Performance on prepared base fabric：
The total fiber number of base fabric is preferably 155~470dtex, more preferably 235~470dtex.If total fiber number is less than 155dtex, it is likely that be difficult to the intensity for maintaining cloth and silk.If total fiber number increases more than 470dtex, the thickness of base fabric, gas The storage of capsule is possible to be deteriorated.
The total fiber number (dtex) 320 of the most preferred base fabric, monofilament number (root) 72, fabric density (root/2.54cm) 46：
1st, according to the standards of ASTM D 726, the resilience for determining coated base fabric by Georgia Lee trial machine is less than or equal to 60g；
2nd, the Air permenbility for determining coated base fabric under 20KPa pressure according to high pressure ventilation characteristic measuring machine is less than or equal to 0.1Lcm-2min-1；
3rd, according to JIS L1096 (8.15.2A-2 methods), with the tearing strength (N) during draw speed stretching in 200mm/ minutes =320-347；
4th, stiffness：Stiffness (mm)=78-87 is obtained by JIS L1096 (8.19.1A methods).
The performance test of air bag：
1st, tested according to the testing standard of JIS K6404 fabric tensile strengths and elongation.Specific method is to draw Stretch on test instrument and 3 × 20 (cm) sample is clipped on the special carrier of Tensile Tester, the chuck spacing of Tensile Tester is 15cm, is tested with 200mm/min speed.Tensile strength：670-860N/cm, preferably 790N/cm.
2nd, determined according to ASTM D6478 testing standards, fabric after folding, be put into standard holder and obtain it Compression curve, it is 20N, 40N, 60N, 80N, 100N, 120N, 140N, 160N, base during 180N that loading on compression curve is read respectively The thickness of cloth.The value of storage property is calculated according to following formula：Storage property
(cm3Summation × 100 × 150/1000 of)=each loading correspondence thickness.Obtain 1270-1850 (cm3), preferably 1740 (cm3)。
3rd, elongation at break：According to JIS L1096 (8.12.1A methods), determine with fabric width 3cm, stretching grabbing interval Elongation at break when 15cm, draw speed stretching in 200mm/ minutes.Obtain 29-33 (%), preferably 32 (%)
4th, tearing strength：According to JIS L1096 (8.15.2A-2 methods), when obtaining with draw speed stretching in 200mm/ minutes Tearing strength.Obtain 290-340 (N), preferably 310 (N).
Considered according to properties, the tensile strength of the air bag：790N/cm, elongation at break：32 (%), tear Intensity 310 (N), storage property (cm3(the cm of)=17403) when, it is optimal.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.
A kind of preparation method of pressure automobile massage seat air bag, it is characterised in that comprise the following steps：
Step one, base fabric long filament is prepared using modified poly ester；
Step 2, base fabric is prepared by base fabric long filament through weaving, and the base fabric is into always by warp thread and weft yarn cross fork-shaped Fiber number is preferably 155~470dtex, more preferably 235~470dtex, most preferably 320dtex；
Step 3, the coating of gluing liquid：Calendering is carried out to base fabric using multi-functional calender, will using scraper coating machine Adhesive is coated to base fabric, by drying, is bakeed, cooling obtains air bag.
The preparation method of base fabric long filament described in step one comprises the following steps：
A, Modified polyester chips preparation
(1) preparation of amino aliphatic acid
By alpha-chloro-fatty acid, binary of fatty acids, neopentyl glycol, ammoniacal liquor 1-2 in molar ratio:0.5-1：0.2-0.5：2-3 It is added in reactor, reaction 30-120min is stirred at room temperature, then reaction product is heated to 50-65 DEG C of distillation, heats the phase Between constantly exclude gas, until reaction solution bubble-free is produced, that is, stop distillation, and be passed through at 45 DEG C nitrogen, be incubated 60- 90min, is cooled to normal temperature afterwards, carries out suction filtration, obtained sediment is washed with deionized water 3-5 times, product is dried in vacuo Obtain product amino aliphatic acid；
(2) preparation of amino ethylene glycol fatty acid
It is 1-2 in molar ratio by ethylene glycol, obtained amino aliphatic acid, terephthalic acid (TPA):1-3:1-2 is stirred 15-30min, sulfuric acid is added by the 1~3% of amino fatty acid wt, and addition titanium ethylene glycolate is catalyst, carries out esterification, Esterification reaction temperature is increased to be forced into 270kPa at 160~200 DEG C, reacts 60-120min, moisture is excluded, by reaction product Amino ethylene glycol fatty acid is obtained through separating-purifying；
(3) preparation of modified poly ester
By the amino ethylene glycol fatty acid, trimethylolpropane, silicone intermediate of preparation using mass ratio as 3-6: 0.5-2:2-5 is mixed, and 5-15min is stirred at 180 DEG C and obtains mixed liquor, the fourth of tin dilaurate two of addition mixed liquor quality 1% Base tin catalyst, opens vavuum pump, is warming up to 230 DEG C, is incubated 60-120min, and the first modified resin is made, and closes vacuum, drop 160 DEG C of Wen Zhiyue, adds the 20-25% triphenyl phosphites of the first modified resin quality, after stirring, and adds first and is modified Resin quality 10-15% trimellitic anhydride, is warming up to 200-250 DEG C, is incubated about 2h, is passed through nitrogen, is cooled to 80-150 DEG C, N is added, it is 7.5~8.5 that N- dimethylethanolamines, which carry out being neutralized to pH value, produces modified polyester resin；
(4) preparation of the viscous section of the height of modified poly ester
Solid phase polycondensation is viscosified after modified poly ester is granulated, and obtains the viscous section of height of modified poly ester, inherent viscosity is 1.0 ~1.2dL/g, preferably 1.15dL/g；
B, chip drying
Chip drying, main drying tower is placed in by section, and the electrical heating temperature in its drying tower is about 175 DEG C, dry in trunk The residence time is 5h in tower；
C, melt spinning：By dried polyester slice and the first compound using mass ratio as 3-6:2-4 is in mixed at high speed Mixed in machine, be delivered to spinning screw extruder, melted in spinning screw extruder, temperature setting is warming up to 15 DEG C/min 278 DEG C of holding 20-60min, 290 DEG C of holding 30-60min are warming up to 5 DEG C/min, and 310 DEG C of holding 5- are warming up to 3 DEG C/min 30min, enters filament spinning component by measuring pump afterwards and carries out melt spinning from spinneret extrusion, add by by slow cooling heater Heat, slow cooling heating-up temperature is 270-320 DEG C, then is cooled and shaped through side type blowing device, subsequently into spinning shaft, is obtained First fiber；Cross air blasting speed control is in 0.21-0.25m/s, preferably 0.23m/s, and cross air blasting temperature control is excellent at 25-27 DEG C Select 26 DEG C；
D, stretching and winding：
The first high temperature resistant finish is sprayed in the first fiber surface first, oil concentration used is 14%, then in 80-120 DEG C draft temperature and draft speed are that stretching drawing-off is carried out under the conditions of 500-3000m/min, draw ratio be in 3.3-3.8, then By 230-255 DEG C of high temperature relaxation heat setting, relaxation rate is 4-12%；
Secondly the long filament after to relaxation heat setting carries out the second high temperature resistant finish, and concentration is 35-40%, in 180~260 At DEG C under 1000-3000m/min winding speed to oiling after long filament carry out the compound coiling and molding of three peacekeepings two dimension, base is made Cloth long filament；
Gluing liquid is composed of the following components described in the application step of gluing liquid in step 3：
First component, is divided into ethylene-alpha-olefin-nonconjugated diene copolymer rubber, and its density is 850 to 900kg/m3, Mooney viscosity (ML1+4(100 DEG C)) it is 30 to 150, iodine number is 0.1 to 40, and acetate unit content is 30 to 90 weight %；
First component be selected from ethylene-propylene -5- ethylidene -2- ENBs copolymer rubber, ethylene-propylene -1- butylene - 5- ethylidene -2- ENBs copolymer rubber or ethene -1- hexenes -5- ethylidene -2- ENBs copolymer rubber and its Composition；
Second component, the homopolymer and glass transition temperature by glass transition temperature less than 0 DEG C is equal at 10-50 DEG C Polymers is using mol ratio as 3-7:2-5 is constituted；
Homopolymer of the glass transition temperature less than 0 DEG C is selected from polyethyl acrylate, positive third fat of polyacrylic acid, polyacrylic acid The just own ester of isopropyl ester, polyacrylic acid N-butyl, polyisobutyl acrylate, polyacrylic acid n-pentyl ester, polyacrylic acid, polyacrylic acid- 2- ethylhexyls；
Glass transition temperature is selected from positive third fat of polymethylacrylic acid, the positive fourth of polymethylacrylic acid between 10-50 DEG C Ester, polymethylacrylic acid n-pentyl ester, polymethylacrylic acid hydroxypropyl fat, polyvinyl acetate；
Crosslinking agent, the crosslinking agent be organic peroxide, selected from from ketal peroxide, alkyl super-acid ester, peroxocarbonate, Dicumyl peroxide, 2,2,4- tri-methyl-amyl -2- hydroperoxides, diisopropyl phenyl methyl hydroperoxide, p- chlorine Benzoyl peroxide and combinations thereof；
Sulphur system antioxidant, selected from dilauryl -3,3 '-thiodipropionate, myristyl -3,3 '-thio dipropyl Acid esters, distearyl acyl group -3,3 '-thiodipropionate, lauryl stearyl -3,3 '-thiodipropionate, thio-2 acid Dilauryl, two (octadecyl) thioethers, (β-lauryl-thiopropionate of pentaerythrite-four；
First component, the second component, the mass ratio of crosslinking agent and sulphur system antioxidant are 20-40:20-35:2-6: 3-4
The application step of gluing liquid is further comprising the steps of in step 3：
A, using multi-functional calender at 110 DEG C to base fabric carry out calendering, pressure is 12MPa, and speed is 10m/min；
B, using scraper coating machine gluing liquid is coated to base fabric, contact pressure of the coating blade with the base fabric Power is in the range of 0.5~4.0N/cm, contact preferably is 1.0~3.0N/cm, and most preferred contact is 2.5N/ Cm, the viscosity that gluing liquid is caused by temperature control is controlled in the range of 5-20Pas (5,000-20,000cP), and is coated with To the upper and lower surface of base fabric fabric, coated weight is 15g/m2-200g/m2, preferably 25-35g/m2；
C, at 105 DEG C coating adhesive mucus dried, drying time is 40-60s；
D, as in enameling furnace at 150 DEG C bakee 60s obtain air bag.
Ammonia concn described in the preparation of the amino aliphatic acid is 15~25wt% ammoniacal liquor；Amino fatty acid ethylene glycol Sulfuric acid is the sulfuric acid that concentration is 40~50wt%, the mass ratio 0.2-0.6 of titanium ethylene glycolate and amino aliphatic acid in the preparation of ester：3- 8；Silicone intermediate is selected from methyl phenyl silicone resin intermediate in the preparation of modified poly ester；In melt spinning, the screw rod is straight Footpath is 125~150mm, draw ratio 25-30, a diameter of 190~220mm of spinneret；Stretching and winding：First high temperature resistant Finish is made up of mineral oil 55-80%, dodecyl sodium sulfate 2-8% and oleic acid diethyl amide 10-30%, and described second is resistance to High temperature finish is by mineral oil 30-55%；[(1,1,2,2- tetrafluoro ethyoxyl) methyl] oxirane 35-60%, dodecyl sulphur Sour sodium 2-7% compositions.
First compound is using the general structure as described in formula (1)：
Carbochains of the R1 selected from H, C1-6 length, amino, hydroxyl, anilino-, carboxyl, carbonyl；The R2 is selected from H, C1- The carbochain of 6 length, amino, hydroxyl, carboxyl；
First compound may be selected from benzene sulfonic acid sodium salt, sodium sulfanilate, paratoluenesulfonic acid sodium salt, p-hydroxybenzenyl sulfonate Sodium, 2,4- diamino benzene sulfonic acids sodium, diphenylamines -4- sulfonate sodiums, 2- Sodium p-aminobenzene sulfonats, benzaldehyde -4- sodium sulfonates, 3- carboxyls Benzene sulfonic acid sodium salt, cumene sodium sulfonate or 4- cumene sodium sulfonates and its their arbitrary compositions.
It should be understood that these embodiments are only illustrative of the invention and is not intended to limit the scope of the invention.In addition, it is to be understood that After the content of the invention lectured has been read, those skilled in the art can make various changes or modifications to the present invention, these The equivalent form of value equally falls within the application appended claims limited range.

Claims (8)

1. a kind of preparation method of pressure automobile massage seat air bag, it is characterised in that comprise the following steps：
Step one, base fabric long filament is prepared using modified poly ester；
Step 2, base fabric is prepared by base fabric long filament through weaving；
Step 3, the coating of gluing liquid：Calendering is carried out to base fabric using multi-functional calender, using scraper coating machine by gluing Agent is coated to base fabric, by drying, is bakeed, cooling obtains air bag.
2. the preparation method of a kind of pressure automobile massage seat air bag as claimed in claim 1, it is characterised in that in step one The preparation method of the base fabric long filament comprises the following steps：
A, Modified polyester chips preparation
The preparation of modified poly ester：By amino ethylene glycol fatty acid, trimethylolpropane, silicone intermediate using mass ratio as 3- 6:0.5-2:2-5 is mixed, and 5-15min is stirred at 180 DEG C and obtains mixed liquor, the tin dilaurate two of addition mixed liquor quality 1% Butyl tin catalyst, opens vavuum pump, is warming up to 230 DEG C, is incubated 60-120min, and the first modified resin is made, and closes vacuum, About 160 DEG C are cooled to, the first modified resin quality 20-25% triphenyl phosphite is added, after stirring, first is added and changes Property resin quality 10-15% trimellitic anhydride, be warming up to 200-250 DEG C, be incubated about 2h, be passed through nitrogen, be cooled to 80-150 DEG C, N is added, it is 7.5~8.5 that N- dimethylethanolamines, which carry out being neutralized to pH value, produces modified polyester resin；
The preparation of Modified polyester chips：Solid phase polycondensation is viscosified after modified poly ester is granulated, and obtains Modified polyester chips, characteristic Viscosity is 1.0~1.2dL/g；
B, chip drying
Chip drying, main drying tower is placed in by section, and the electrical heating temperature in its drying tower is about 130-175 DEG C, dry in trunk The residence time is 1-5h in tower；
C, melt spinning：By dried polyester slice and the first compound using mass ratio as 3-6:2-4 is in high-speed mixer Mixing, is delivered to spinning screw extruder, is melted in spinning screw extruder, and temperature setting is warming up to 278 with 15 DEG C/min DEG C keep 20-60min, with 5 DEG C/min be warming up to 290 DEG C holding 30-60min, with 3 DEG C/min be warming up to 310 DEG C holding 5- 30min, enters filament spinning component by measuring pump afterwards and carries out melt spinning from spinneret extrusion, add by by slow cooling heater Heat, slow cooling heating-up temperature is 270-320 DEG C, then is cooled and shaped through side type blowing device, subsequently into spinning shaft, is obtained First fiber；
D, stretching and winding：
The first obtained fiber progress stretching and winding is obtained into base fabric long filament.
3. the preparation method of a kind of pressure automobile massage seat air bag as claimed in claim 1, it is characterised in that in step 3 Gluing liquid is composed of the following components described in the application step of gluing liquid：
First component：For ethylene-alpha-olefin-nonconjugated diene copolymer rubber；
Second component：The homopolymer of homopolymer and glass transition temperature at 10-50 DEG C by glass transition temperature less than 0 DEG C Using mol ratio as 3-7:2-5 is constituted；
Crosslinking agent, the crosslinking agent is organic peroxide；
Sulphur system antioxidant；
First component, the second component, the mass ratio of crosslinking agent and sulphur system antioxidant are 20-40:20-35:2-6:3-4.
4. the preparation method of a kind of pressure automobile massage seat air bag as claimed in claim 1, it is characterised in that in step 3 The application step of gluing liquid is further comprising the steps of：
A, using multi-functional calender at 110 DEG C to base fabric carry out calendering, pressure is 12MPa, and speed is 10m/min；
B, using scraper coating machine gluing liquid is coated to base fabric, contact pressure of the coating blade with the base fabric is In the range of 0.5~4.0N/cm, the viscosity that gluing liquid is caused by temperature control is controlled in the range of 5-20Pas, and is applied Cloth is to the upper and lower surface of base fabric fabric, and coated weight is 15g/m2-200g/m2；
C, at 105 DEG C coating adhesive mucus dried, drying time is 40-60s；
D, drying after as in enameling furnace at 150 DEG C bakee 60s obtain air bag.
5. a kind of preparation method of pressure automobile massage seat air bag as claimed in claim 2, it is characterised in that the modification Silicone intermediate is selected from methyl phenyl silicone resin intermediate in the preparation of polyester；In melt spinning, the screw diameter is 125 ~150mm, draw ratio 25-30, a diameter of 190~220mm of spinneret.
6. a kind of preparation method of pressure automobile massage seat air bag as claimed in claim 2, it is characterised in that stretching and winding Specifically include following steps：
The first high temperature resistant finish is sprayed in the first fiber surface first, oil concentration used is 14%, then in 80-120 DEG C of drawing It is that stretching drawing-off is carried out under the conditions of 500-3000m/min to stretch temperature and draft speed, and draw ratio is, in 3.3-3.8, then to pass through 230-255 DEG C of high temperature relaxation heat setting, relaxation rate is 4-12%；
Secondly the long filament after to relaxation heat setting carries out the second high temperature resistant finish, and concentration is 35-40%, at 180~260 DEG C Under 1000-3000m/min winding speed to oiling after long filament carry out the compound coiling and molding of three peacekeepings two dimension, base fabric is made long Silk.
7. the preparation method of a kind of pressure automobile massage seat air bag as claimed in claim 6, it is characterised in that described first High temperature resistant finish is made up of mineral oil 55-80%, dodecyl sodium sulfate 2-8% and oleic acid diethyl amide 10-30%, described Second high temperature resistant finish is by mineral oil 30-55%；[(1,1,2,2- tetrafluoro ethyoxyl) methyl] oxirane 35-60%, 12 Sodium alkyl sulfonate 2-7% is constituted.
8. the preparation method of a kind of pressure automobile massage seat air bag as claimed in claim 2, it is characterised in that described first Compound is using the general structure as described in formula (1)：
Carbochains of the R1 selected from H, C1-6 length, amino, hydroxyl, anilino-, carboxyl, carbonyl；The R2 is selected from H, C1-6 length The carbochain of degree, amino, hydroxyl, carboxyl.
CN201710346763.5A 2017-05-17 2017-05-17 Preparation method of air bag of air pressure type automobile massage seat Expired - Fee Related CN106968111B (en)

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CN103397395A (en) * 2013-08-07 2013-11-20 亚东工业（苏州）有限公司 Preparation method of high-resilience polyester industrial filament yarns for supplementary restraint system
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CN1159402A (en) * 1995-09-18 1997-09-17 东丽株式会社 Base cloth for air bag, preparation process and the air bag therefrom
CN1831040A (en) * 2005-03-07 2006-09-13 住友化学株式会社 Process for producing thermoplastic elastomer composition, and safety air-bag cover
CN101336321A (en) * 2005-12-06 2008-12-31 Nexis纤维股份公司 Coated woven fabric or knit fabric for a safety air bag
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CN112359608A (en) * 2020-11-10 2021-02-12 浙江莎特勒新材料股份有限公司 Production process of coated airbag base cloth

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