CN106967309A - A kind of production method of the water aluminum pipe with electrician's level magnesia powder of stewing - Google Patents

A kind of production method of the water aluminum pipe with electrician's level magnesia powder of stewing Download PDF

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Publication number
CN106967309A
CN106967309A CN201710102434.6A CN201710102434A CN106967309A CN 106967309 A CN106967309 A CN 106967309A CN 201710102434 A CN201710102434 A CN 201710102434A CN 106967309 A CN106967309 A CN 106967309A
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Prior art keywords
aluminum pipe
production method
electrician
magnesia powder
stewing
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CN201710102434.6A
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CN106967309B (en
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庄伟兵
宗俊
金宏伟
刘荣栋
潘文斌
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SHANGHAI INDUSTRIAL ZHENTAI CHEMICAL INDUSTRIAL Co Ltd
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SHANGHAI INDUSTRIAL ZHENTAI CHEMICAL INDUSTRIAL Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/02Compounds of alkaline earth metals or magnesium
    • C09C1/028Compounds containing only magnesium as metal
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/006Combinations of treatments provided for in groups C09C3/04 - C09C3/12
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/04Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/06Treatment with inorganic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/12Treatment with organosilicon compounds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B19/00Apparatus or processes specially adapted for manufacturing insulators or insulating bodies
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/11Powder tap density

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Resistance Heating (AREA)

Abstract

The present invention relates to electrically molten magnesia technical field, and in particular to a kind of production method of magnesia powder.A kind of production method of the water aluminum pipe with electrician's level magnesia powder of stewing, comprises the following steps:Step one:Electric smelting MAG block is crushed screened, material A is made.Step 2:By at least one organosilicon material, material B is made.Step 3:By at least one inorganic nano material, material C is made.Step 4:Material A and material B are mixed and are used as material D.Step 5:Solidify for the first time, normal temperature cure.Step 6:Second of solidification, heating cure.Step 7:Third time solidifies, and material G is made in heating cure.Step 8:Material G is sieved through 40 eye mesh screens and packed, as fused magnesium oxide product.The fused magnesium oxide powder being made of staged solidification method of the present invention, the flowing of its fused magnesite particle is greatly improved, and packed density is larger to be improved, and electric compressive resistance performance is greatly improved, and insulating properties significantly strengthen.

Description

A kind of production method of the water aluminum pipe with electrician's level magnesia powder of stewing
Technical field
The present invention relates to electrically molten magnesia technical field, and in particular to a kind of production method of magnesia powder.
Background technology
Fused magnesium oxide powder has excellent electric insulation and heat-conductive characteristic, is mainly used in making electrical heating elements.Electricity Molten magnesium oxide sand is wide by pulverizing processing and grain size proportion and the fused magnesium oxide powder that produces after some row materializing strategies It is used as the insulation filling material of electric heating element generally.
Influence the factor of fused magnesium oxide mealiness energy a lot, the wherein mobile performance of magnesia powder, tap density, insulation The characteristics such as performance, compressive resistance are all the important indicators for determining that product quality is good and bad.
Be used as pot water aluminum pipe with electrician level magnesia powder (hereinafter referred to as " aluminum pipe powder ") primary raw material --- fused magnesite and Organosilicon material.The major defect that generally existing mobility and insulating properties are contradicted in the market, such as has preferably flowing The aluminum pipe powder insulating properties of property are poor, the easy moisture absorption of magnesium oxide product;Then mobility is poor for aluminum pipe powder with preferable insulating properties, The small compressive resistance of product packed density is low easily breakdown under high pressure conditions, influences magnesia electric property, shortens electric heating element Working life, hidden trouble is buried to product quality.
The content of the invention
It is an object of the present invention to provide more than a kind of production method of the water aluminum pipe with electrician's level magnesia powder of stewing, solution Technical problem.
Technical problem solved by the invention can be realized using following technical scheme:
A kind of production method of the water aluminum pipe with electrician's level magnesia powder of stewing, comprises the following steps:
Step one:Electric smelting MAG block is crushed screened, the fused magnesite of the size distribution of 40~325 mesh is made, thing is used as Expect A;
Step 2:By at least one organosilicon material, uniform liquid shape additive is made, material B is used as;
Step 3:By at least one inorganic nano material, uniform powdery oil absorbent is made, material C is used as;
Step 4:According to ratio requirement, by 100:0.2 (wt%) ratio of (wt%)~1.5 is by material A and material B mixed Mixed 30 minutes~120 minutes in clutch, make its full and uniform, be used as material D;
Step 5:Solidify for the first time, normal temperature cure --- by the compound of step 4, according to ratio requirement, by 100:0.5 (wt%)~2.0 (wt%) ratio mixes material D and material C 10 minutes~60 minutes in a mixer, makes its full and uniform, It is used as material E;
Step 6:Second of solidification, heating cure --- in the kiln that the material E of step 5 is placed in 80 DEG C~150 DEG C Solidified, 0.5 hour~3 hours heating cure residence time, cooled down after material is come out of the stove after solidification by natural cooling device To 50 DEG C of <, material F is used as;
Step 7:Third time solidifies, heating cure --- in the kiln that the material F of step 6 is placed in 200 DEG C~250 DEG C Solidified, 0.5 hour~3 hours heating cure residence time, cooled down after material is come out of the stove after solidification by natural cooling device To room temperature (50 DEG C of <), material G is used as;
Step 8:Step 7 resulting material G is sieved through 40 eye mesh screens and packed, is electrician's level oxygen prepared by the present invention Change magnesium products --- aluminum pipe powder.
The present invention is handled by above-mentioned staged solidification method, it is possible to achieve aluminum pipe powder is in lower temperature, no more than 250 DEG C works Organosilicon material solidifies under the conditions of skill, and conventional solidified technique, and generally using one-step solidification, and temperature is often higher than 250 DEG C, one As temperature at 250 DEG C~350 DEG C.The present invention is handled by above-mentioned staged solidification method, is enclosed with fused magnesite particle surface Machine silicon materials, so that superior isolation performance is realized, the hydrophobicity performance under such as normal temperature;Handled by staged solidification method so that electricity The flowing of fused magnesia particle is greatly improved, and reaches that (aluminum pipe internal oxidition magnesium is well filled out for good tap density and filling effect Fill density) purpose.Handled by staged solidification method so that the packed density of electrothermal tube internal oxidition magnesium powder is greatly changed It is kind, reach the purpose of good compressive resistance.The aluminum pipe powder that the present invention is made is stewed to end product electric kettle or coffee machine etc. The performance of water class small household appliances has significant enhancement effect.
In step one, the material A can be the fused magnesite of a grade as material A, magnesia can also be included Content accounts for the different grades of material As of 96%-98% of fused magnesite gross weight, and ratio can be matched arbitrarily according to requirements.
In step 2, the organosilicon material can be that organic silicone oil or organic siliconresin are therein one or more Combination, is considered in terms of technical matters and economy, and the design of the formula of organosilicon material to curing process is very important Foundation.
In step 3, the inorganic nano material, can be the inorganic nanos such as nano aluminium oxide or nano zine oxide wherein One or more combinations.
Heating cure mode in step 6 and step 7 can be that electrical heating, diesel oil or gas gun are directly heated, from From the aspect of economy, preferred gas heating can be achieved relatively low cost and be easy to high-volume operation.
Kiln in step 6 and step 7 is preferred to use rotary kiln.By the way of rotary kiln, sufficiently long In time, the uniformity and heat utilization rate of furnace temperature can be improved, makes the reduction of material stable homogeneous and production cost.
The rotary kiln can be the energy as heating with natural gas, diesel oil or electricity.
Beneficial effect:Due to using above technical scheme, the fused magnesium oxide product that the present invention is obtained, with traditional electricity Work level magnesia is compared, with following remarkable result:
1st, its insulating properties significantly strengthens, and amplification is up to 10 times or more than 100 times;
2nd, electric compressive resistance performance is greatly improved, and amplification is up to more than 200V/0.5mA;
3rd, mobility is obviously improved, and flow velocity can accelerate more than 2S-4S;
4th, packed density is larger improves, so as to reach the product quality of improvement end product-electrical heating elements (aluminum pipe).
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, enter below One step illustrates the present invention.
A kind of production method of the water aluminum pipe with electrician's level magnesia powder of stewing, comprises the following steps:
Step one:Electric smelting MAG block is crushed screened, the fused magnesite of the size distribution of 40~325 mesh is made, thing is used as Expect A.Material A can be the fused magnesite of a grade as material A, fused magnesite gross weight can also be accounted for including content of magnesia The different grades of material As of 96%-98% of amount, ratio can be matched arbitrarily according to requirements.
Step 2:By at least one organosilicon material, uniform liquid shape additive is made, material B is used as.Organosilicon material Material, can be organic silicone oil or organic siliconresin one or more combination therein, be examined in terms of technical matters and economy Amount, the design of the formula of organosilicon material to curing process is very important foundation.
Step 3:By at least one inorganic nano material, uniform powdery oil absorbent is made, material C is used as.Inorganic nano material Material, can be the one or more combinations therein of the inorganic nanos such as nano aluminium oxide or nano zine oxide.
Step 4:According to ratio requirement, by 100:0.2 (wt%) ratio of (wt%)~1.5 is by material A and material B mixed Mixed 30 minutes~120 minutes in clutch, make its full and uniform, be used as material D.
Step 5:Solidify for the first time, normal temperature cure --- by the compound of step 4, according to ratio requirement, by 100:0.5 (wt%)~2.0 (wt%) ratio mixes material D and material C 10 minutes~60 minutes in a mixer, makes its full and uniform, It is used as material E.
Step 6:Second of solidification, heating cure --- in the kiln that the material E of step 5 is placed in 80 DEG C~150 DEG C Solidified, 0.5 hour~3 hours heating cure residence time, cooled down after material is come out of the stove after solidification by natural cooling device To 50 DEG C of <, material F is used as.
Step 7:Third time solidifies, heating cure --- in the kiln that the material F of step 6 is placed in 200 DEG C~250 DEG C Solidified, 0.5 hour~3 hours heating cure residence time, cooled down after material is come out of the stove after solidification by natural cooling device To room temperature (50 DEG C of <), material G is used as.Kiln in step 6 and step 7 is preferred to use rotary kiln.Using rotary kiln Mode, within the sufficiently long time, the uniformity and heat utilization rate of furnace temperature can be improved, make material stable homogeneous and production The reduction of cost.Rotary kiln can be the energy as heating with natural gas, diesel oil or electricity.
Step 8:Step 7 resulting material G is sieved through 40 eye mesh screens and packed, is electrician's level oxygen prepared by the present invention Change magnesium products --- aluminum pipe powder.
Using aluminum pipe powder (1#) produced by the invention, (only preparation method is different, former with common aluminum pipe powder (2#) performance comparision Material all same):
1st, mobile performance compares:
1# 2#
Flow velocity (S/100g, 4# Ford cup) 34-38 38-42
Flow rate (S/100g, 3# Ford cup) 155-175 180-200
2nd, tap density and aluminum pipe powder packed density compare:
3rd, compressive resistance performance comparision:
4th, insulating properties compare:
Testing standard according to:Ministry of Machine-Building Industry's professional standard《Fused magnesium oxide》JB/T 8508-1996, Shanghai City enterprise Industry standard《Fused magnesium oxide》Q/IAQA 4-2014.
To sum up state, the fused magnesium oxide powder being made of staged solidification method of the present invention, i.e. aluminum pipe powder, its fused magnesite The flowing of particle is greatly improved, and packed density is larger to be improved, and electric compressive resistance performance is greatly improved, and insulating properties are significantly Enhancing, so as to reach the product quality of improvement end product-electrical heating elements (aluminum pipe).
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (8)

1. a kind of production method of the water aluminum pipe with electrician's level magnesia powder of stewing, it is characterised in that comprise the following steps:
Step one:Electric smelting MAG block is crushed screened, the fused magnesite of the size distribution of 40~325 mesh is made, material A is used as;
Step 2:By at least one organosilicon material, uniform liquid shape additive is made, material B is used as;
Step 3:By at least one inorganic nano material, uniform powdery oil absorbent is made, material C is used as;
Step 4:According to ratio requirement, by 100:0.2 (wt%) ratio of (wt%)~1.5 is by material A and material B in blender Middle mixing 30 minutes~120 minutes, makes its full and uniform, is used as material D;
Step 5:Solidify for the first time, normal temperature cure --- by the compound of step 4, according to ratio requirement, by 100:0.5 (wt%)~2.0 (wt%) ratio mixes material D and material C 10 minutes~60 minutes in a mixer, makes its full and uniform, It is used as material E;
Step 6:Second of solidification, heating cure --- the material E of step 5 is placed in 80 DEG C~150 DEG C of kiln and carried out Solidification, 0.5 hour~3 hours heating cure residence time, < is cooled to after material is come out of the stove after solidification by natural cooling device 50 DEG C, it is used as material F;
Step 7:Third time solidifies, heating cure --- and the material F of step 6 is placed in 200 DEG C~250 DEG C of kiln and carried out Solidification, 0.5 hour~3 hours heating cure residence time, room is cooled to after material is come out of the stove after solidification by natural cooling device Temperature, is used as material G;
Step 8:Step 7 resulting material G is sieved through 40 eye mesh screens and packed, is the fused magnesium oxide prepared by the present invention Product --- aluminum pipe powder.
2. a kind of production method of the water aluminum pipe with electrician's level magnesia powder of stewing according to claim 1, it is characterised in that step In rapid one, the material A is the fused magnesite of same grade as material A.
3. a kind of production method of the water aluminum pipe with electrician's level magnesia powder of stewing according to claim 1, it is characterised in that step In rapid one, the material A includes the different grades of material As of 96%-98% that content of magnesia accounts for fused magnesite gross weight.
4. a kind of production method of the water aluminum pipe with electrician's level magnesia powder of stewing according to claim 1, it is characterised in that step In rapid two, the organosilicon material is organic silicone oil or organic siliconresin one or more combination therein.
5. a kind of production method of the water aluminum pipe with electrician's level magnesia powder of stewing according to claim 1, it is characterised in that step In rapid three, the inorganic nano material is nano aluminium oxide or nano zine oxide one or more combinations therein.
6. a kind of production method of the water aluminum pipe with electrician's level magnesia powder of stewing according to claim 1, it is characterised in that step Rapid six and step 7 in heating cure mode be that electrical heating, diesel oil or gas gun are directly heated.
7. a kind of production method of the water aluminum pipe with electrician's level magnesia powder of stewing according to claim 1, it is characterised in that step Rapid six and step 7 in kiln use rotary kiln.
8. a kind of production method of the water aluminum pipe with electrician's level magnesia powder of stewing according to claim 7, it is characterised in that institute It is the energy with natural gas, diesel oil or electricity as heating to state rotary kiln.
CN201710102434.6A 2017-02-24 2017-02-24 It is a kind of to stew the water aluminum pipe production method of electrician's grade magnesia powder Active CN106967309B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109835927A (en) * 2017-11-28 2019-06-04 中国科学院大连化学物理研究所 A kind of high temperature resistant, Gao Shushui fused magnesium oxide powder and preparation method thereof
CN110012565A (en) * 2018-01-05 2019-07-12 上海实业振泰化工有限公司 A kind of production method of copper pipe powder

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011048885A1 (en) * 2009-10-22 2011-04-28 電気化学工業株式会社 Insulating sheet, circuit board, and process for production of insulating sheet
CN102254651A (en) * 2011-04-20 2011-11-23 荆巍 Preparation method of heat-conducting insulating material for resistance wire heating disc
CN103971786A (en) * 2013-12-27 2014-08-06 上海实业振泰化工有限公司 Electric-grade organic coating high-temperature-resistant insulating magnesia powder for electric ovens and production method of electric-grade organic coating high-temperature-resistant insulating magnesia powder
CN105566950A (en) * 2015-12-07 2016-05-11 上海实业振泰化工有限公司 Preparation method of highly-voltage-withstanding high-temperature-resistant fused magnesium oxide

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011048885A1 (en) * 2009-10-22 2011-04-28 電気化学工業株式会社 Insulating sheet, circuit board, and process for production of insulating sheet
CN102254651A (en) * 2011-04-20 2011-11-23 荆巍 Preparation method of heat-conducting insulating material for resistance wire heating disc
CN103971786A (en) * 2013-12-27 2014-08-06 上海实业振泰化工有限公司 Electric-grade organic coating high-temperature-resistant insulating magnesia powder for electric ovens and production method of electric-grade organic coating high-temperature-resistant insulating magnesia powder
CN105566950A (en) * 2015-12-07 2016-05-11 上海实业振泰化工有限公司 Preparation method of highly-voltage-withstanding high-temperature-resistant fused magnesium oxide

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109835927A (en) * 2017-11-28 2019-06-04 中国科学院大连化学物理研究所 A kind of high temperature resistant, Gao Shushui fused magnesium oxide powder and preparation method thereof
CN110012565A (en) * 2018-01-05 2019-07-12 上海实业振泰化工有限公司 A kind of production method of copper pipe powder

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Denomination of invention: A production method of electrical grade magnesium oxide powder for aluminum tube in water pot

Effective date of registration: 20231019

Granted publication date: 20190122

Pledgee: The Bank of Shanghai branch Caohejing Limited by Share Ltd.

Pledgor: SHANGHAI SIIC ZHENTAI CHEMICAL CO.,LTD.

Registration number: Y2023980061678