CN106966665A - A kind of stalk composite architectural materials and preparation method thereof - Google Patents
A kind of stalk composite architectural materials and preparation method thereof Download PDFInfo
- Publication number
- CN106966665A CN106966665A CN201710265340.0A CN201710265340A CN106966665A CN 106966665 A CN106966665 A CN 106966665A CN 201710265340 A CN201710265340 A CN 201710265340A CN 106966665 A CN106966665 A CN 106966665A
- Authority
- CN
- China
- Prior art keywords
- stalk
- preparation
- architectural materials
- composite
- seconds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 33
- 239000002131 composite material Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000010902 straw Substances 0.000 claims abstract description 34
- 239000000203 mixture Substances 0.000 claims abstract description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical class [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 28
- 240000008042 Zea mays Species 0.000 claims description 20
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 20
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 claims description 19
- 235000009973 maize Nutrition 0.000 claims description 19
- 239000000470 constituent Substances 0.000 claims description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 238000003763 carbonization Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 11
- 229910052710 silicon Inorganic materials 0.000 claims description 11
- 239000010703 silicon Substances 0.000 claims description 11
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 11
- 239000003513 alkali Substances 0.000 claims description 10
- 239000002956 ash Substances 0.000 claims description 8
- 239000010881 fly ash Substances 0.000 claims description 8
- 235000019353 potassium silicate Nutrition 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 8
- 239000002893 slag Substances 0.000 claims description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000001354 calcination Methods 0.000 claims description 7
- 238000013019 agitation Methods 0.000 claims description 6
- 238000005255 carburizing Methods 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 4
- -1 clinker Substances 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims 1
- 235000005822 corn Nutrition 0.000 claims 1
- 239000004568 cement Substances 0.000 abstract description 12
- 239000011157 advanced composite material Substances 0.000 abstract description 7
- 239000011159 matrix material Substances 0.000 abstract description 3
- 230000002742 anti-folding effect Effects 0.000 abstract description 2
- 230000006835 compression Effects 0.000 abstract description 2
- 238000007906 compression Methods 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 11
- 239000011230 binding agent Substances 0.000 description 3
- 239000004566 building material Substances 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000004381 surface treatment Methods 0.000 description 3
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 239000004035 construction material Substances 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000010257 thawing Methods 0.000 description 2
- 101100002917 Caenorhabditis elegans ash-2 gene Proteins 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- LPQOADBMXVRBNX-UHFFFAOYSA-N ac1ldcw0 Chemical compound Cl.C1CN(C)CCN1C1=C(F)C=C2C(=O)C(C(O)=O)=CN3CCSC1=C32 LPQOADBMXVRBNX-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 206010003549 asthenia Diseases 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 231100000749 chronicity Toxicity 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002389 environmental scanning electron microscopy Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000011396 hydraulic cement Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000007614 solvation Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
- C04B20/023—Chemical treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/30—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
- C04B2201/32—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The present invention discloses a kind of stalk composite architectural materials and preparation method thereof there is provided new composite architectural materials and preparation method thereof, can effectively improve stalk surface nature to solve the problem of stalk and cement matrix are glued difficult.What novel straw composite was not only selected on composition in composition simultaneously is all aboundresources and cheap environmental type resource, and can obtain a kind of strength character including resistance to compression, anti-folding, frost resistance all and heat-insulating property all unusual excellent advanced composite material (ACM)s.
Description
Technical field：
The present invention discloses a kind of stalk composite architectural materials and preparation method thereof, is related to a kind of new straw cement-based and is combined
Material and a kind of method of modifying on new maize straw surface, belong to building material technical field.
Background technology：
Maize straw main component is cellulose etc., and cellulose point after aqueous slkali is met when straw skin is incorporated into cement-based material
Solve as monose, and carbohydrate contains many-OH functional groups, with free Ga in alkaline medium2+The unstable complex compound of generation, with
This simultaneously, hydroxyl easily with hydrone by hydrogen bond association, make cement particle surface formation one layer of solvation moisture film, hinder aquation
Process, so that the especially early strength loss of binder materials intensity can be caused serious.In addition, obtained by ESEM
Straw skin apparent form is as shown in Figure 1, it can be seen that the outer surface structure of maize straw bast fiber is fine and close and very smooth,
" diaphragm " with one layer of bright wax, it may thus be appreciated that maize straw bast in binder materials recombination process with that can produce
The insecure phenomenon of certain interfacial adhesion, can equally make binder materials intensity produce decline.Therefore, these factors are to a certain degree
On limit application of the stalk in construction material.So being pre-processed to the progress of stalk surface just particularly important.Conventional stalk
Surface treatment mode has mechanical damage, chemical treatment, physical treatment etc..Mechanical treatment technique is simple, can allow the thick of stalk surface
Rugosity increased, but the destructive power of machinery is stronger, can make the original silicon dioxide skeleton of stalk by broken meeting so as to intensity
Significantly decline；Chemical treatment can make the organic material decompositions such as cellulose inside stalk such as sodium hydroxide solution infusion method
For glucide dissolution, but 30% or so alkali lye can be remained inside stalk, alkali concn is too high for some engineerings to cause
Anti- alkali phenomenon.
Conventional silicate series cement can make its serious slow setting, intensity decline to a great extent with stalk compound tense, work as stalk
When volume is 10%, its intensity can drop to below 1MPa, and even stalk is handled by methods such as sodium hydroxide solution immersions,
Intensity increase rate also very little, final actual strength is very low can not to be applied to prepare in building material.
The content of the invention：
The invention provides a kind of stalk composite architectural materials, solve that straw cement-based composite material strength is low, anti-freezing property
Difference, the technical barrier such as stalk volume is small.
Invention further provides a kind of preparation method of stalk composite architectural materials, a kind of intensity, heat insulating ability are obtained
And frost resistance all unusual excellent advanced composite material (ACM)s.
A kind of stalk composite architectural materials of the present invention, it is characterised in that be by the raw material system of following ratio of weight and number
Into：
Slag 40-70, flyash 10-30, alkaline constituents 10-20, surface carbonation maize straw 2-20, silicon ash 2-15, calcining
Diatomite 2-10, clinker 1-5；Water 25-50.
Described alkaline constituents is made up of 50-70 parts by weight waterglass and 30-50 parts by weight sodium hydroxides.
Calcined diatomite used is made by 5-40min grindings, 200-1000 DEG C of calcining.
Described surface carbonation maize straw is the bast part being carbonized by surface shallow-layer, and length is 1-15mm.
A kind of preparation method of stalk composite architectural materials of the present invention, is comprised the following steps that：
1）The filament for taking maize straw skin to be crushed to 1-20mm is fully dried, and carries out carbonization treatment after drying under vacuum state：Deng
Nitrogen protection carbonization 10-30min, 200-350 DEG C of carburizing temperature are pressed, stalk is taken out and seals stand-by up for safekeeping after room temperature is down to；
2）By than weighing alkaline constituents material waterglass and sodium hydroxide, it is mixed evenly stand-by；
3）By than weighing slag, flyash, silicon ash, calcined diatomite, clinker, water and step 1）Surface carbonation stalk,
Stirred after mixing；
4）By step 1）, step 3）In raw material mixing after carry out mechanical agitation, low-speed running simultaneously adds step 2 slowly）Alkali
Component solution mix, stirring at low speed stops 10 ~ 15 seconds after 90 ~ 120 seconds, continues high-speed stirred and is produced after 90 ~ 120 seconds.
The present invention contains stalk surface treatment method --- surface carbonation method, in a certain temperature conditions vacuum carburization
Regular hour effectively can volatilize away the organic matter on stalk surface, the straw skin surface of otherwise smooth is showed bumps
Uneven lamination stratiform, as shown in Fig. 2 scanning electron microscope (SEM) photographs, so as to increase the cohesive force between stalk and cement matrix.Together
When stalk fixed carbon after surface carbonation and silica content increase, carbohydrate etc. can extract material reduce, so
The material of heat evolution velocity is delayed to reduce, so that smaller to the intensity effect of cement matrix.
In order that straw cement-based composite has higher intensity and frost resistance, to be prepared using the composite
The construction materials such as the right straw building block of excellent performance, stalk wallboard, and in the present invention using a kind of intensity it is high, condense fast through silicon
Ash, calcined diatomite are modified alkali-activated slag-fine coal celadon novel gelled material and compound, the of the invention NEW TYPE OF COMPOSITE of stalk
The early stage of material and increasing substantially for later strength can dramatically increase the anti-freezing property of composite.
While intensity and frost resistance of the present invention obtain improving, because the volume of stalk is big, its guarantor is greatly improved
Warm nature energy, so the novel straw composite of the present invention is a kind of ideal material with many-sided premium properties,
The positive effect of the present invention is：There is provided new composite architectural materials and preparation method thereof, contain a kind of new
Stalk surface treatment method-surface carbonation method, can effectively improve stalk surface nature so as to solving stalk and cement base
The problem of material is glued difficult.What novel straw composite was not only selected on composition in composition simultaneously is all aboundresources and honest and clean
The environmental type resource of valency, and resistance to compression, anti-folding, frost resistance can be obtained all and heat-insulating property is all very excellent new
Composite.
Brief description of the drawings：
Fig. 1 is former straw skin surface scan electron microscope；
Fig. 2 is the surface carbonation stalk surface scan electron microscope used in the present invention.
Embodiment：
Further illustrated the description present invention by following examples, the present invention is not limited in any way, without departing substantially from this hair
On the premise of bright technical solution, any change that those of ordinary skill in the art made for the present invention easily realize or
Change is fallen within scope of the presently claimed invention.
Embodiment 1：
1）The filament for taking maize straw skin to be crushed to 1-20mm is fully dried, and carries out carbonization treatment after drying under vacuum state：Deng
Nitrogen protection carbonization 10min, 200 DEG C of carburizing temperature are pressed, stalk is taken out and seals stand-by up for safekeeping after room temperature is down to；
2）Alkaline constituents material waterglass 50kg and sodium hydroxide 30kg are taken, is mixed evenly stand-by；
3）Weigh slag 40kg, the kg of flyash 10, the kg of alkaline constituents 10, the kg of surface carbonation stalk 4, the kg of silicon ash 2, calcining diatom
2 kg of soil, clinker 1 kg, the kg of water 25 and step 1）Surface carbonation maize straw 2kg, stirred after mixing；
4）By step 1）, step 3）In raw material mixing after carry out mechanical agitation, low-speed running simultaneously adds step 2 slowly）Alkali
Component 10kg solution mixs, 60 ± 2r/min stirring at low speed stops 10 seconds after 90 seconds, continues 80 ± 4r/min high-speed stirreds
Produced after 90 seconds.
Embodiment 2：
1）The filament for taking maize straw skin to be crushed to 1-20mm is fully dried, and carries out carbonization treatment after drying under vacuum state：Deng
Nitrogen protection carbonization 20min, 250 DEG C of carburizing temperature are pressed, stalk is taken out and seals stand-by up for safekeeping after room temperature is down to；
2）Alkaline constituents material waterglass 60kg and sodium hydroxide 40kg are weighed, is mixed evenly stand-by；
3）Weigh slag 55kg, the kg of flyash 20, the kg of alkaline constituents 15, surface carbonation stalk 10kg, the kg of silicon ash 8, calcining diatom
Soil 4 kg, clinker 3kg, water 40kg and step 1）Surface carbonation maize straw 10kg, stirred after mixing；
4）By step 1）, step 3）In raw material mixing after carry out mechanical agitation, low-speed running simultaneously adds step 2 slowly）Alkali
Component solution mix, 60 ± 2r/min stirring at low speed stops 10 seconds after 90 seconds, continues 80 ± 4r/min high-speed stirreds 90 seconds
Produced after clock.
Embodiment 3：
1）The filament for taking maize straw skin to be crushed to 1-20mm is fully dried, and carries out carbonization treatment after drying under vacuum state：Deng
Nitrogen protection carbonization 25min, 300 DEG C of carburizing temperature are pressed, stalk is taken out and seals stand-by up for safekeeping after room temperature is down to；
2）Alkaline constituents material waterglass 65kg and sodium hydroxide 45kg are weighed, is mixed evenly stand-by；
3）Weigh slag 60kg, the kg of flyash 25, the kg of alkaline constituents 20, surface carbonation stalk 15kg, the kg of silicon ash 10, calcining silicon
The kg of diatomaceous earth 8, clinker 4 kg, water 45kg and step 1）Surface carbonation maize straw 20kg, stirred after mixing；
4）By step 1）, step 3）In raw material mixing after carry out mechanical agitation, low-speed running simultaneously adds step 2 slowly）Alkali
Component 20kg solution mixs, 60 ± 2r/min stirring at low speed stops 10 seconds after 90 seconds, continues 80 ± 4r/min high-speed stirreds
Produced after 90 seconds.
Embodiment 4：
1）The filament for taking maize straw skin to be crushed to 1-20mm is fully dried, and carries out carbonization treatment after drying under vacuum state：Deng
Nitrogen protection carbonization 20min, 350 DEG C of carburizing temperature are pressed, stalk is taken out and seals stand-by up for safekeeping after room temperature is down to；
2）Alkaline constituents material waterglass 70kg and sodium hydroxide 50kg are weighed, is mixed evenly stand-by；
3）Weigh slag 70kg, the kg of flyash 30, the kg of alkaline constituents 20, surface carbonation maize straw 20kg, the kg of silicon ash 15, forge
Burn the kg of diatomite 10, clinker 5 kg, water 50kg and step 1）Surface carbonation stalk 20kg, stirred after mixing；
4）By step 1）, step 3）In raw material mixing after carry out mechanical agitation, low-speed running simultaneously adds step 2 slowly）Alkali
Component 20kg solution mixs, 60 ± 2r/min stirring at low speed stops 10 seconds after 90 seconds, continues 80 ± 4r/min high-speed stirreds
Produced after 90 seconds.
Test example
Strength character, heat-insulating property and frost resistance experiment are carried out to the product prepared by embodiment 1-4.Strength detecting method according to
《Test method for strength of hydraulic cement mortar（ISO methods）》GB/T 17617-1999 are carried out；Frost resistance is according to GB/T50082-2009《It is general
Logical concrete chronicity and endurance quality test method standard》Carry out the measure of freeze thawing resistance cycle-index；Heat-insulating property according to
GB50411-2007《Code for Acceptance of Construction Quality of Building Energy-saving Engineering》Carry out the measure of thermal conductivity factor.
The stalk advanced composite material (ACM) performance of each embodiment of table 1
The experimental data of table 1 shows, is being continuously increased from embodiment 1 to the surface carbonation maize straw volume in embodiment 4, real
Apply stalk volume up to 10% in example 4, the intensity of advanced composite material (ACM) of the invention is still up to 27.6MPa, compared to ordinary silicon
Composite material strength after stalk is mixed in acid salt cement will be higher by nearly 10 times or so.For rupture strength, although on a declining curve,
But bend-press ratio data but constantly rise, this has absolutely proved that the toughness of the novel straw composite of the present invention is changed
It is kind.At the same time, in the case of with high intensity heat-insulating property but also more protrude, superficial charring stalk volume be 10% when
Thermal conductivity factor is only 0.1109W/mK.Frost resistance is gradually reduced with the increase of stalk surface carbonation stalk volume, still
When stalk volume is 4%, freeze thawing resistance circulation is up to 60 times, compared to the common straw cement-based composite wood under the conditions of same volume
The frost resistance of material can be improved 15 times or so.So the present invention obtains a kind of excellent novel straw complex building material of properties
Material.
Claims (5)
1. a kind of stalk composite architectural materials, it is characterised in that be made up of the raw material of following ratio of weight and number：
Slag 40-70, flyash 10-30, alkaline constituents 10-20, surface carbonation maize straw 2-20, silicon ash 2-15, calcining
Diatomite 2-10, clinker 1-5；Water 25-50.
2. a kind of stalk composite architectural materials according to claim 1, it is characterised in that：
Described alkaline constituents is made up of 50-70 parts by weight waterglass and 30-50 parts by weight sodium hydroxides.
3. a kind of stalk composite architectural materials according to claim 1 and preparation method thereof is characterized in that：
Calcined diatomite used is made by 5-40min grindings, 200-1000 DEG C of calcining.
4. a kind of novel straw composite according to claim 1 and preparation method thereof, it is characterised in that：
Described surface carbonation maize straw is the bast part being carbonized by surface shallow-layer, and length is 1-15mm.
5. a kind of preparation method of stalk composite architectural materials as described in claim 1 ~ 4, is comprised the following steps that：
1）The filament for taking maize straw skin to be crushed to 1-20mm is fully dried, and carries out carbonization treatment after drying under vacuum state：Deng
Nitrogen protection carbonization 10-30min, 200-350 DEG C of carburizing temperature are pressed, stalk is taken out and seals stand-by up for safekeeping after room temperature is down to；
2）By than weighing alkaline constituents material waterglass and sodium hydroxide, it is mixed evenly stand-by；
3）By than weighing slag, flyash, silicon ash, calcined diatomite, clinker, water and step 1）Surface carbonation corn stalk
Stirred after stalk, mixing；
4）By step 1）, step 3）In raw material mixing after carry out mechanical agitation, low-speed running simultaneously adds step 2 slowly）Alkali
Component solution mix, stirring at low speed stops 10 ~ 15 seconds after 90 ~ 120 seconds, continues high-speed stirred and is produced after 90 ~ 120 seconds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710265340.0A CN106966665B (en) | 2017-04-21 | 2017-04-21 | A kind of stalk composite architectural materials and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710265340.0A CN106966665B (en) | 2017-04-21 | 2017-04-21 | A kind of stalk composite architectural materials and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106966665A true CN106966665A (en) | 2017-07-21 |
| CN106966665B CN106966665B (en) | 2019-06-25 |
Family
ID=59332981
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710265340.0A Expired - Fee Related CN106966665B (en) | 2017-04-21 | 2017-04-21 | A kind of stalk composite architectural materials and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106966665B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108658537A (en) * | 2018-05-24 | 2018-10-16 | 江蔓青 | A kind of maize straw and polymer-modified cement composite architectural materials |
| CN108892494A (en) * | 2018-08-06 | 2018-11-27 | 德威特涂料有限公司 | A kind of preparation method of nano-titanium dioxide-slag-composite diatomite construction material |
| CN109516708A (en) * | 2019-01-04 | 2019-03-26 | 吉林建筑大学 | A kind of diatomite modified stalk fibre building board and preparation method thereof |
| CN110713370A (en) * | 2019-11-18 | 2020-01-21 | 常熟理工学院 | Preparation method of composite environment-friendly building material |
| CN112852447A (en) * | 2021-01-07 | 2021-05-28 | 吉林建筑大学 | Fireproof flame-retardant straw composite material and preparation method and application thereof |
| CN113800877A (en) * | 2021-09-28 | 2021-12-17 | 上海缘滔新材料有限公司 | Preparation method of concrete road brick |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105948607A (en) * | 2016-04-28 | 2016-09-21 | 合肥云峰信息科技有限公司 | Carbonized plant fiber reinforced coal gangue brick and production method thereof |
-
2017
- 2017-04-21 CN CN201710265340.0A patent/CN106966665B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105948607A (en) * | 2016-04-28 | 2016-09-21 | 合肥云峰信息科技有限公司 | Carbonized plant fiber reinforced coal gangue brick and production method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 肖力光等: "利用秸秆制造新型复合节能墙体材料的可行性研究", 《吉林建筑工程学院学报》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108658537A (en) * | 2018-05-24 | 2018-10-16 | 江蔓青 | A kind of maize straw and polymer-modified cement composite architectural materials |
| CN108892494A (en) * | 2018-08-06 | 2018-11-27 | 德威特涂料有限公司 | A kind of preparation method of nano-titanium dioxide-slag-composite diatomite construction material |
| CN109516708A (en) * | 2019-01-04 | 2019-03-26 | 吉林建筑大学 | A kind of diatomite modified stalk fibre building board and preparation method thereof |
| CN110713370A (en) * | 2019-11-18 | 2020-01-21 | 常熟理工学院 | Preparation method of composite environment-friendly building material |
| CN112852447A (en) * | 2021-01-07 | 2021-05-28 | 吉林建筑大学 | Fireproof flame-retardant straw composite material and preparation method and application thereof |
| CN112852447B (en) * | 2021-01-07 | 2021-11-26 | 吉林建筑大学 | Fireproof flame-retardant straw composite material and preparation method and application thereof |
| CN113800877A (en) * | 2021-09-28 | 2021-12-17 | 上海缘滔新材料有限公司 | Preparation method of concrete road brick |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106966665B (en) | 2019-06-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106966665A (en) | A kind of stalk composite architectural materials and preparation method thereof | |
| CN104844090B (en) | A kind of raw-soil suitable for raw-soil building block is plastered binding material and preparation method thereof | |
| CN103539391A (en) | Waterproof heat insulation mortar | |
| CN104844078A (en) | Polymer repairing mortar and preparation method thereof | |
| CN107417129A (en) | Low-thermal conductivity rock wool thermal insulation material and preparation method thereof | |
| CN104961391A (en) | Crack-resistant heat insulation mortar for exterior wall, and preparation method thereof | |
| CN104944884A (en) | Anti-cracking thermal insulation mortar and preparation method thereof | |
| CN105541313A (en) | Nano heat-insulating material and preparation method of nano heat-insulating board | |
| CN104230252B (en) | A kind of self-heat conserving for Light trabs connection is high-strength is dry mixed adhesive mortar and preparation method thereof | |
| CN103466985A (en) | Graphene cement reinforcer | |
| CN108314360A (en) | Environment-friendly flame-retardant low-heat-conductivity heat-insulation board and preparation method thereof | |
| CN102898113A (en) | Hydrophobic expanded perlite heat insulating product and preparation method thereof | |
| CN108658564A (en) | A kind of external wall compound insulating material and its preparation process | |
| CN107417183A (en) | A kind of Novel wall body heat insulation material and preparation method | |
| CN107188469A (en) | A kind of fire-resistant waterproof insulation material and preparation method thereof | |
| CN106746826A (en) | A kind of new alkali-activated slag fly ash gel material retarder and preparation method | |
| CN107235671A (en) | A kind of fire preventing and heat insulating building material and preparation method thereof | |
| CN101781919A (en) | Low heat conduction light heat insulating silica brick | |
| CN106365562A (en) | Efficient energy-saving environment-friendly inorganic building heat preservation material and preparation method thereof | |
| CN107337429B (en) | Preparation method of ceramic curtain wall and foamed ceramic composite material | |
| CN103304201B (en) | Thermal insulation mortar for building | |
| CN106630862A (en) | 3D substrate dry-mixed mortar raw material ratio and production technology | |
| CN107162625A (en) | A kind of fireproof insulation brick and preparation method thereof | |
| CN105399381A (en) | Building external wall thermal insulation material and preparation method thereof | |
| CN106699046A (en) | Washing resistant heat insulation and flame retardant material for exterior walls |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20190625 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |