CN106966446A - A kind of device and method of utilization blast furnace slag Treatment of Wastewater in Coking - Google Patents

A kind of device and method of utilization blast furnace slag Treatment of Wastewater in Coking Download PDF

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Publication number
CN106966446A
CN106966446A CN201710236014.7A CN201710236014A CN106966446A CN 106966446 A CN106966446 A CN 106966446A CN 201710236014 A CN201710236014 A CN 201710236014A CN 106966446 A CN106966446 A CN 106966446A
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China
Prior art keywords
blast furnace
furnace slag
convex disks
waste water
cooling air
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CN201710236014.7A
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CN106966446B (en
Inventor
刘洪银
郝帅
孙建卫
杨波
王孝科
路峰
袁鹏举
亓伟伟
王奉县
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Shandong Iron and Steel Group Co Ltd SISG
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Shandong Iron and Steel Group Co Ltd SISG
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B3/00General features in the manufacture of pig-iron
    • C21B3/04Recovery of by-products, e.g. slag
    • C21B3/06Treatment of liquid slag
    • C21B3/08Cooling slag
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/04Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste liquors, e.g. sulfite liquors
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/34Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • General Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Furnace Details (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of device and method of utilization blast furnace slag Treatment of Wastewater in Coking, described device includes the first convex disks, the second convex disks, the first pipeline and second pipe;The first convex disks inner hollow, upper surface is provided with several coking chemical waste water spray apertures;The second convex disks inner hollow, upper surface is provided with several cooling air spray orifices;First convex disks are above the second convex disks, and diameter of the diameter less than the second convex disks of the first convex disks;Described second pipe one end and the bottom centre of the second convex disks are fixedly linked, and first pipeline is fixedly linked through the bottom centre of second pipe and the second convex disks and the first convex disks;It is coking chemical waste water runner, the hollow internal connection coking chemical waste water spray apertures that coking chemical waste water runner passes through the first convex disks in first pipeline;Cooling air runner is formed between the outer surface of the second pipe inner surface and the first pipeline.

Description

A kind of device and method of utilization blast furnace slag Treatment of Wastewater in Coking
Technical field
The invention belongs to technical field of ferrous metallurgy, in particular it relates to which a kind of utilize blast furnace Slag treatment coking The device and method of waste water.
Background technology
Blast furnace cinder is the high temperature waste residue produced during Ferrous Metallurgy, and its temperature is at 1450 DEG C or so, and slag per ton contains Sensible heat 260 × 103~1880 × 103KJ, is roughly equivalent to the calorific value released during 60kg standard coal combustions.Current blast furnace both at home and abroad Slag treatment method be will blast furnace slag flow into pond in enter water-filling extraction processing, product as cement admixture.But traditional water Technique of quenching have that such as water resources consumption is serious, sulfurous gas discharge capacity is big, gained grain slag still needs to further dehydrate and High-temperature slag waste heat such as can not reclaim at the drawback substantially.
For the shortcoming of blast furnace cinder water quenching technique, 1970s, foreign countries just had begun working on dry type chilling granulation The method of blast furnace slag, mainly there is wind quenching method and centrifugal granulation method, and the two is all first to crush liquid blast furnace, is solidified as small After grain, then the method for taking means to reclaim its sensible heat, blast furnace slag dry type chilling granulation, the glass rate of fine granularity clinker is high, The production requirement of high-quality cement can be met.The granulation of liquid blast furnace is for the recycling of discarded object and showing for liquid blast furnace Recuperation of heat is all significant, therefore, and a kind of energy consumption of research is low, and granulation effect is good, simple in construction, and the high liquid of reliability is high Slag granulation method is very necessary.
Coking chemical waste water is a kind of typical poisonous organic wastewater with difficult degradation thereby.Coking chemical waste water essentially from coke oven gas primary-cooling and Industrial water and steam condensation waste water during coking production.Pollutant concentration is high in coking chemical waste water, many in coking chemical waste water PAH is not only difficult to degrade, and usual or strong carcinogen, and environment is caused also directly to threaten while severe contamination To human health.Shown by research, contained organic matter can be decomposed completely at 400 DEG C or so in coking chemical waste water, after processing Harmful substance contents in waste water are greatly reduced, and can meet wastewater discharge standard.
The content of the invention
To solve problem above, the present invention provides a kind of device of utilization blast furnace slag Treatment of Wastewater in Coking, utilizes blast furnace slag Contained calorific value is handled coking chemical waste water, can decompose the toxic organic compound in coking chemical waste water, blast furnace has been saved again Water resource needed for Slag treatment, while being granulated using granulation apparatus to blast furnace slag, the value of blast furnace slag after raising processing.
To reach above-mentioned purpose, present invention employs following technical scheme:
A kind of device of utilization blast furnace slag Treatment of Wastewater in Coking, described device includes the first convex disks 4, the second convex and justified Disk 6, the first pipeline 8 and second pipe 12;
The inner hollow of first convex disks 4, upper surface is provided with several coking chemical waste water spray apertures 3;Described second The inner hollow of convex disks 6, upper surface is provided with several cooling air spray orifices 5;First convex disks 4 are in the second convex disks Above 6, and diameter of the diameter less than the second convex disks 6 of the first convex disks 4;
Described one end of second pipe 12 and the bottom centre of the second convex disks 6 are fixedly linked, and first pipeline 8 is passed through The bottom centre of second pipe and the second convex disks 6 and the first convex disks is fixedly linked;It is coking chemical waste water in first pipeline 8 Runner 7, the hollow internal connection coking chemical waste water spray apertures 3 that coking chemical waste water runner 7 passes through the first convex disks;The second pipe Cooling air runner 10 is formed between the outer surface of 12 inner surfaces and the first pipeline 8, cooling air runner 10 passes through the second convex The hollow internal connection cooling air spray orifice 5 of disk;Coking chemical waste water runner 7 is connected with coking chemical waste water water source 15;Cooling air stream Road 10 is connected with cooling air source 16;
First pipeline 8 and second pipe 12 constitute hollow axle, and hollow axle is driven by motor 11.
Further, described device also includes seal closure 17, and the convex disks 6 of the first convex disks 4 and second are set In seal closure 17, just the first convex disks 4 are set at the top of seal closure 17 and also set up water at the top of slag inlet 1, seal closure Steam (vapor) outlet 2, bottom sets slag notch 9.
Preferably, the slag inlet is shaped as circle, and the diameter of slag inlet is identical with the diameter of the first convex disks.
Preferably, the coking chemical waste water runner 7 is connected by the first sealed bearings 13 with coking chemical waste water water source 15;It is described cold But air flow channel 10 is connected by the second sealed bearings 14 with cooling air source 16.
Preferably, the first pipeline is nested in inside second pipe, the central axis of the first pipeline and second pipe with it is hollow The central axis of rotating shaft is identical.
Present invention also offers based on a kind of above-mentioned method of the device of utilization blast furnace slag Treatment of Wastewater in Coking, methods described Comprise the following steps:
1) coking chemical waste water and the blast furnace slag that the first convex disks spray carry out convection current spray, blast furnace slag is cooled to 700~ 1000 DEG C, the organic compound combustion being granulated in blast furnace slag cooling procedure in the blast furnace slag being tentatively granulated, coking chemical waste water is decomposed, raw Into CO2、H2O is discharged;
2) the second convex disks with the first convex disks coaxial rotating spray cooling air, using cooling air to preliminary The blast furnace slag of granulation is further cooled down, cooling air and blast furnace slag convection heat transfer' heat-transfer by convection and convective drying, and further blast furnace slag is carried out Cooling is granulated and is dried to obtain little particle blast furnace slag.
The present invention is handled blast furnace slag using two step method, and the first step is:Blast furnace slag is after slag inlet is fallen, first with Jiao Change waste water and carry out convection current spray with blast furnace slag, blast furnace slag is cooled in 700~1000 DEG C, blast furnace slag cooling procedure and is granulated, it is burnt The organic compound combustion changed in waste water is decomposed, and generates CO2、H2The materials such as O.Second step is:It is further to blast furnace slag using cooling air Cooling, cooling air and blast furnace slag convection heat transfer' heat-transfer by convection and convective drying, further can carry out cooling granulation and drying to blast furnace slag.
Specifically, the present invention carries out two step method processing using punctured disk formula centrifuge to blast furnace slag, and centrifuge top has Less first convex disks of one volume, first step processing, the first convex circle are carried out to blast furnace slag using the first convex disks Disk is coking chemical waste water spray apertures of being gathered in steel, the first convex disks, passes through the hole upward spraying coking of the first convex disks After slag inlet is fallen with coking chemical waste water convective motion, during centrifuge high-speed rotation, first occur for waste water, blast furnace slag Convex disks also high-speed rotation, the coking chemical waste water sprayed out uniformly can be sprayed onto in blast furnace slag, and blast furnace slag is acted on by spray power, and four Distribution landing is dissipated, blast furnace slag is decomposed by the organic compound combustion cooled down in preliminary granulation, coking chemical waste water, generates CO2、H2The things such as O Matter.The second convex disks that one volume is relatively large in diameter are arranged at the bottom of centrifuge, and blast furnace slag is carried out using the second convex disks Second step processing, the second convex disks are the jet hole that gathered in steel, the second convex disks, and the second convex disks are located at first Surrounding below convex disks, the first convex disks and the second convex disks are fixedly connected integrally, can be rotated together, pass through The hole of two convex disks is blown cooling air upwards, during centrifuge high-speed rotation, and the second convex disks also turn at a high speed Dynamic, blast furnace slag is after the first convex disks surrounding is fallen, and the cooling air that the holes of the second convex disks is blown out upwards is to height Clinker is cooled down and dried, and blast furnace slag is further granulated.
The rotating shaft of punctured disk formula centrifuge is designed using hollow mode, and the inside of hollow axle is used as coking chemical waste water and cold But the flow channel of air.Hollow axle is made up of the first pipeline and second pipe, and the first internal diameter of the pipeline is smaller, in second pipe Footpath is larger, and the first pipeline is nested in inside second pipe, in the central axis and hollow axle of the first pipeline and second pipe Heart axis is identical.First pipeline is as coking chemical waste water runner, between the inner surface of second pipe and the outer surface of the first pipeline Position is cooling air runner.First pipeline is connected by the first sealed bearings with outside coking chemical waste water water source, and second Pipeline is connected by the second sealed bearings with outside cooling air source of the gas.Hollow axle and motor connection.
Centrifuge is enclosed in a seal closure, and slag inlet is left on seal closure top, and the upper side of seal closure leaves water Steam and hot air outlet, the lower side of seal closure leave slag notch.
It is an advantage of the current invention that
1st, the technology provided according to the present invention, blast furnace slag is first carried out after slag inlet is fallen with coking chemical waste water with blast furnace slag Convection current is sprayed, and blast furnace slag is cooled into 700~1000 DEG C, carries out burning disposal to coking chemical waste water using the calorific value of blast furnace slag, both Blast furnace slag is cooled, preliminary granulation has been carried out to blast furnace slag, make use of the calorific value of blast furnace slag to incinerate in coking chemical waste water again Toxic organic compound, has saved the processing cost of blast furnace slag and coking chemical waste water.
2nd, the technology provided according to the present invention, the cooling air sprayed using the second convex disks is further cold to blast furnace slag But, cooling air and blast furnace slag convection heat transfer' heat-transfer by convection and convective drying, further cooling is carried out to blast furnace slag and is granulated and dries, is improved The glass rate of blast furnace slag, and clinker drying, it is not necessary to processing is dried, dry expense has been saved.
3rd, harmful substance contents are low in the water vapour produced after handling, heat and moisture content recoverable in water vapour, Heat and water resource are saved.
Brief description of the drawings
Fig. 1 is the vertical cross section of apparatus of the present invention;
Fig. 2 is the top view of apparatus of the present invention;
Reference:1 is slag inlet;2 be steam outlet;3 be coking chemical waste water spray apertures;4 be the first convex disks;5 For cooling air spray orifice;6 be the second convex disks;7 be coking chemical waste water runner;8 be the first pipeline;9 be slag notch;10 be cooling Air flow channel;11 be motor;12 be second pipe;13 be the first sealed bearings;14 be the second sealed bearings;15 be coking chemical waste water Water source;16 be cooling air source of the gas;17 be seal closure.
Embodiment
With the drawings and specific embodiments, the present invention is further detailed explanation below.
Using equipment as shown in Figure 1 and Figure 2 to carrying out two step method processing to blast furnace slag, the first step is:Blast furnace slag is from circle Slag inlet 1 fall after, first carries out convection current spray with coking chemical waste water and blast furnace slag, blast furnace slag is cooled to 700~1000 DEG C, height It is granulated during cooling of furnace slag, the organic compound combustion in coking chemical waste water is decomposed, generates CO2、H2The materials such as O.Second step is:Using Cooling air, can be further to blast furnace to the further cooling of blast furnace slag, cooling air and blast furnace slag convection heat transfer' heat-transfer by convection and convective drying Slag carries out cooling granulation and drying.
Two step method processing, centrifuge top are carried out to blast furnace slag using punctured disk formula centrifuge as shown in Figure 1 and Figure 2 There are less first convex disks 4 of a volume, first step processing is carried out to blast furnace slag using the first convex disks 4, first is convex The diameter of shape disk is identical with the diameter of slag inlet, and the material of the first convex disks 4 is to be gathered in steel, the first convex disks 4 Coking chemical waste water spray apertures 3, by the upward spraying coking chemical waste water of coking chemical waste water spray apertures 3 of the first convex disks, blast furnace slag is from circle After the slag inlet 1 of shape is fallen, occur convective motion, during centrifuge high-speed rotation, the first convex disks with coking chemical waste water Also high-speed rotation, the coking chemical waste water sprayed out uniformly can be sprayed onto in blast furnace slag, and blast furnace slag is acted on by spray power, and four dissipate distribution drop Fall, blast furnace slag is tentatively granulated by cooling, and the organic compound combustion in coking chemical waste water is decomposed, and generates CO2、H2The materials such as O, first is convex The coking chemical waste water amount that the upward spraying of shape disk 4 goes out flows downwardly into the 10%~30% of blast furnace slag quality for circular slag inlet 1.From The second larger convex disks 6 of one volume are arranged at the bottom of scheming, and blast furnace slag is carried out at second step using the second convex disks 6 Reason, the material of the second convex disks 6 is gathered in steel, the second convex disks 6 cooling air spray orifice 5, the second convex disks 6 The surrounding below the first convex disks 4, the first convex disks 4 are fixedly connected integrally with the second convex disks 6, can be turned together It is dynamic, cooling air is blown by the cooling air spray orifice 5 of the second convex disks 6 upwards, cooling air straying quatity is 10~100L Air/Kg slags, during centrifuge high-speed rotation, the second convex disks 6 also high-speed rotation, blast furnace slag is from the first convex disks After 4 surrounding is fallen, the cooling air that the cooling air spray orifice 5 of the second convex disks 6 is blown out upwards is cold to blast furnace slag progress But and dry, blast furnace slag is further granulated.
The rotating shaft of punctured disk formula centrifuge is designed using hollow mode, and the inside of hollow axle is used as coking chemical waste water and cold But the flow channel of air.There are the first pipeline 8 and second pipe 12 inside hollow axle, the internal diameter of the first pipeline 8 is smaller, second The internal diameter of pipeline 12 is larger, and the first pipeline 8 is nested in the center of the inside of second pipe 12, the first pipeline 8 and second pipe 12 Axis is identical with the central axis of hollow axle.First pipeline 8 as coking chemical waste water runner 7, the inner surface of second pipe 12 and Position between the outer surface of first pipeline 8 is cooling air runner 10.First pipeline 8 passes through the first sealed bearings 13 and outside Coking chemical waste water water source 15 be connected, second pipe 12 is connected by the second sealed bearings 14 with outside cooling air source of the gas 16 It is logical.Hollow axle is connected with motor 11, and the velocity of rotation of hollow axle is 100~300 revs/min.
Centrifuge is enclosed in a seal closure 17, and slag inlet 1 is left on seal closure top, and the upper side of seal closure leaves Steam outlet 2, water vapour flows out automatically from steam outlet 2, water vapour waste heat and the recovery of water resource into next step System, the lower side of seal closure leaves slag notch 9, and the little particle blast furnace slag after cooling flows out automatically from slag notch 9.
Embodiment 1:
Simultaneously adapting device schematic diagram 1, a kind of 2 pairs of devices of utilization blast furnace slag Treatment of Wastewater in Coking are done further for citing below Explanation.
Using equipment as shown in Figure 1 and Figure 2 to carrying out two step method processing to blast furnace slag, the first step is:Blast furnace slag is from circle Slag inlet 1 fall after, first carries out convection current spray with coking chemical waste water and blast furnace slag, blast furnace slag is cooled to 700~1000 DEG C, height It is granulated during cooling of furnace slag, the organic compound combustion in coking chemical waste water is decomposed, generates CO2、H2The materials such as O.Second step is:Using Cooling air, can be further to blast furnace to the further cooling of blast furnace slag, cooling air and blast furnace slag convection heat transfer' heat-transfer by convection and convective drying Slag carries out cooling granulation and drying.
Two step method processing, centrifuge top are carried out to blast furnace slag using punctured disk formula centrifuge as shown in Figure 1 and Figure 2 There are less first convex disks 4 of a volume, first step processing is carried out to blast furnace slag using the first convex disks 4, first is convex The diameter of shape disk is identical with the diameter of slag inlet, and the material of the first convex disks 4 is to be gathered in steel, the first convex disks 4 Coking chemical waste water spray apertures 3, by the upward spraying coking chemical waste water of coking chemical waste water spray apertures 3 of the first convex disks, blast furnace slag is from circle After the slag inlet 1 of shape is fallen, occur convective motion, during centrifuge high-speed rotation, the first convex disks with coking chemical waste water Also high-speed rotation, the coking chemical waste water sprayed out uniformly can be sprayed onto in blast furnace slag, and blast furnace slag is acted on by spray power, and four dissipate distribution drop Fall, blast furnace slag is tentatively granulated by cooling, and the organic compound combustion in coking chemical waste water is decomposed, and generates CO2、H2The materials such as O, first is convex The coking chemical waste water amount that the upward spraying of shape disk 4 goes out flows downwardly into the 10% of blast furnace slag quality for circular slag inlet 1.Centrifuge The second larger convex disks 6 of one volume are arranged at bottom, and second step processing is carried out to blast furnace slag using the second convex disks 6, the The material of two convex disks 6 is steel, and gather in the second convex disks 6 cooling air spray orifice 5, and the second convex disks 6 are located at the Surrounding below one convex disks 4, the first convex disks 4 are fixedly connected integrally with the second convex disks 6, can be rotated together, Cooling air is blown by the cooling air spray orifice 5 of the second convex disks 6 upwards, cooling air straying quatity is 100L air/Kg Slag, during centrifuge high-speed rotation, the second convex disks 6 also high-speed rotation, surrounding of the blast furnace slag from the first convex disks 4 After falling, the cooling air that the cooling air spray orifice 5 of the second convex disks 6 is blown out upwards is cooled down and done to blast furnace slag Dry, blast furnace slag is further granulated.
The rotating shaft of punctured disk formula centrifuge is designed using hollow mode, and the inside of hollow axle is used as coking chemical waste water and cold But the flow channel of air.There are the first pipeline 8 and second pipe 12 inside hollow axle, the internal diameter of the first pipeline 8 is smaller, second The internal diameter of pipeline 12 is larger, and the first pipeline 8 is nested in the center of the inside of second pipe 12, the first pipeline 8 and second pipe 12 Axis is identical with the central axis of hollow axle.First pipeline 8 as coking chemical waste water runner 7, the inner surface of second pipe 12 and Position between the outer surface of first pipeline 8 is cooling air runner 10.First pipeline 8 passes through the first sealed bearings 13 and outside Coking chemical waste water water source 15 be connected, second pipe 12 is connected by the second sealed bearings 14 with outside cooling air source of the gas 16 It is logical.Hollow axle is connected with motor 11, and the velocity of rotation of hollow axle is 300 revs/min.
Centrifuge is enclosed in a seal closure 17, and slag inlet 1 is left on seal closure top, and the upper side of seal closure leaves Steam outlet 2, water vapour flows out automatically from steam outlet 2, water vapour waste heat and the recovery of water resource into next step System, after testing, the harmful substance contents in water vapour are less, and wherein COD contents are less than 20PPM, meet national corresponding row Standard is put, the lower side of seal closure leaves slag notch 9, the little particle blast furnace slag after cooling flows out automatically from slag notch 9, through inspection Survey, the diameter of little particle blast furnace slag is less than 10mm, and glass rate is more than 97%, and water content is less than 1%, belongs to cement high-quality Raw material.
Embodiment 2
Simultaneously adapting device schematic diagram 1, a kind of 2 pairs of methods of utilization blast furnace slag Treatment of Wastewater in Coking are done further for citing below Explanation.
Using equipment as shown in Figure 1 and Figure 2 to carrying out two step method processing to blast furnace slag, the first step is:Blast furnace slag is from circle Slag inlet 1 fall after, first carries out convection current spray with coking chemical waste water and blast furnace slag, blast furnace slag is cooled to 700~1000 DEG C, height It is granulated during cooling of furnace slag, the organic compound combustion in coking chemical waste water is decomposed, generates CO2、H2The materials such as O.Second step is:Using Cooling air, can be further to blast furnace to the further cooling of blast furnace slag, cooling air and blast furnace slag convection heat transfer' heat-transfer by convection and convective drying Slag carries out cooling granulation and drying.
Two step method processing, centrifuge top are carried out to blast furnace slag using punctured disk formula centrifuge as shown in Figure 1 and Figure 2 There are less first convex disks 4 of a volume, first step processing is carried out to blast furnace slag using the first convex disks 4, first is convex The diameter of shape disk is identical with the diameter of slag inlet, and the material of the first convex disks 4 is to be gathered in steel, the first convex disks 4 Coking chemical waste water spray apertures 3, by the upward spraying coking chemical waste water of coking chemical waste water spray apertures 3 of the first convex disks, blast furnace slag is from circle After the slag inlet 1 of shape is fallen, occur convective motion, during centrifuge high-speed rotation, the first convex disks with coking chemical waste water Also high-speed rotation, the coking chemical waste water sprayed out uniformly can be sprayed onto in blast furnace slag, and blast furnace slag is acted on by spray power, and four dissipate distribution drop Fall, blast furnace slag is tentatively granulated by cooling, and the organic compound combustion in coking chemical waste water is decomposed, and generates CO2、H2The materials such as O, first is convex The coking chemical waste water amount that the upward spraying of shape disk 4 goes out flows downwardly into the 30% of blast furnace slag quality for circular slag inlet 1.Centrifuge The second larger convex disks 6 of one volume are arranged at bottom, and second step processing is carried out to blast furnace slag using the second convex disks 6, the The material of two convex disks 6 is steel, and gather in the second convex disks 6 cooling air spray orifice 5, and the second convex disks 6 are located at the Surrounding below one convex disks 4, the first convex disks 4 are fixedly connected integrally with the second convex disks 6, can be rotated together, Cooling air is blown by the cooling air spray orifice 5 of the second convex disks 6 upwards, cooling air straying quatity is 10L air/Kg Slag, during centrifuge high-speed rotation, the second convex disks 6 also high-speed rotation, surrounding of the blast furnace slag from the first convex disks 4 After falling, the cooling air that the cooling air spray orifice 5 of the second convex disks 6 is blown out upwards is cooled down and done to blast furnace slag Dry, blast furnace slag is further granulated.
The rotating shaft of punctured disk formula centrifuge is designed using hollow mode, and the inside of hollow axle is used as coking chemical waste water and cold But the flow channel of air.There are the first pipeline 8 and second pipe 12 inside hollow axle, the internal diameter of the first pipeline 8 is smaller, second The internal diameter of pipeline 12 is larger, and the first pipeline 8 is nested in the center of the inside of second pipe 12, the first pipeline 8 and second pipe 12 Axis is identical with the central axis of hollow axle.First pipeline 8 as coking chemical waste water runner 7, the inner surface of second pipe 12 and Position between the outer surface of first pipeline 8 is cooling air runner 10.First pipeline 8 passes through the first sealed bearings 13 and outside Coking chemical waste water water source 15 be connected, second pipe 12 is connected by the second sealed bearings 14 with outside cooling air source of the gas 16 It is logical.Hollow axle is connected with motor 11, and the velocity of rotation of hollow axle is 100 revs/min.
Centrifuge is enclosed in a seal closure 17, and slag inlet 1 is left on seal closure top, and the upper side of seal closure leaves Steam outlet 2, water vapour flows out automatically from steam outlet 2, water vapour waste heat and the recovery of water resource into next step System, after testing, the harmful substance contents in water vapour are less, and wherein COD contents are less than 40PPM, meet national corresponding row Standard is put, the lower side of seal closure leaves slag notch 9, the little particle blast furnace slag after cooling flows out automatically from slag notch 9, through inspection Survey, the diameter of little particle blast furnace slag is less than 20mm, and glass rate is more than 96%, and water content is less than 1%, belongs to cement high-quality Raw material.
It should be noted last that, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although ginseng The present invention is described in detail according to embodiment, it will be apparent to an ordinarily skilled person in the art that to the technical side of the present invention Case is modified or equivalent substitution, and without departure from the spirit and scope of technical solution of the present invention, it all should cover in the present invention Right among.

Claims (6)

1. a kind of device of utilization blast furnace slag Treatment of Wastewater in Coking, it is characterised in that described device includes the first convex disks (4), the second convex disks (6), the first pipeline (8) and second pipe (12);
First convex disks (4) inner hollow, upper surface is provided with several coking chemical waste water spray apertures (3);Described second Convex disks (6) inner hollow, upper surface is provided with several cooling air spray orifices (5);First convex disks (4) are convex second Above shape disk (6), and diameter of the diameter less than the second convex disks (6) of the first convex disks (4);
Described second pipe (12) one end and the bottom centre of the second convex disks (6) are fixedly linked, and first pipeline (8) is worn The bottom centre for crossing second pipe and the second convex disks (6) and the first convex disks is fixedly linked;It is Jiao in first pipeline (8) Change waste water runner (7), the hollow internal connection coking chemical waste water spray apertures (3) that coking chemical waste water runner (7) passes through the first convex disks; Cooling air runner (10), cooling air are formed between the outer surface of second pipe (12) inner surface and the first pipeline (8) The hollow internal connection cooling air spray orifice (5) that runner (10) passes through the second convex disks;Coking chemical waste water runner (7) gives up with coking Water water source (15) is connected;Cooling air runner (10) is connected with cooling air source (16);
First pipeline (8) and second pipe (12) composition hollow axle, hollow axle are driven by motor (11).
2. a kind of device of utilization blast furnace slag Treatment of Wastewater in Coking according to claim 1, it is characterised in that described device Also include seal closure (17), first convex disks (4) and the second convex disks (6) are arranged in seal closure (17), close Just the first convex disks (4) are set at the top of sealing cover (17) and also set up steam outlet (2) at the top of slag inlet (1), seal closure, Bottom sets slag notch (9).
3. a kind of device of utilization blast furnace slag Treatment of Wastewater in Coking according to claim 2, it is characterised in that the slag input Mouthful be shaped as circle, the diameter of slag inlet is identical with the diameter of the first convex disks.
4. a kind of device of utilization blast furnace slag Treatment of Wastewater in Coking according to claim 1, it is characterised in that the coking Waste water runner (7) is connected by the first sealed bearings (13) with coking chemical waste water water source (15);The cooling air runner (10) is led to The second sealed bearings (14) are crossed to connect with cooling air source (16).
5. a kind of device of utilization blast furnace slag Treatment of Wastewater in Coking according to claim 1, it is characterised in that the first pipeline It is nested in inside second pipe, the central axis of the first pipeline and second pipe is identical with the central axis of hollow axle.
6. based on a kind of any one of claim 1-5 methods of the device of utilization blast furnace slag Treatment of Wastewater in Coking, the side Method comprises the following steps:
1) coking chemical waste water that the first convex disks spray carries out convection current spray with blast furnace slag, and blast furnace slag is cooled into 700~1000 DEG C, the organic compound combustion being granulated in blast furnace slag cooling procedure in the blast furnace slag being tentatively granulated, coking chemical waste water is decomposed, generation CO2、H2O is discharged;
2) the second convex disks with the first convex disks coaxial rotating spray cooling air, using cooling air to preliminary granulation Blast furnace slag further cool down, cooling air and blast furnace slag convection heat transfer' heat-transfer by convection and convective drying are further cooled down to blast furnace slag It is granulated and is dried to obtain little particle blast furnace slag.
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CN108275736A (en) * 2018-02-08 2018-07-13 山东钢铁股份有限公司 The method for handling coking wastewater using high-temperature slag granulation system
CN108411053A (en) * 2018-02-26 2018-08-17 西安交通大学 A kind of molten slag granulation apparatus and driving device with elevating function

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GB8328393D0 (en) * 1983-10-24 1983-11-23 British Steel Corp Granulation of slag
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CN103757157A (en) * 2013-12-31 2014-04-30 河南圣石节能环保工程有限公司 Novel slag dry quenching granulating device
CN106381354A (en) * 2016-12-05 2017-02-08 中冶赛迪工程技术股份有限公司 Treatment system and method utilizing biochemically treated tail water of coking wastewater for slag flushing water replenishing
CN206799182U (en) * 2017-04-12 2017-12-26 山东钢铁股份有限公司 A kind of device using blast furnace slag Treatment of Wastewater in Coking

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GB8328393D0 (en) * 1983-10-24 1983-11-23 British Steel Corp Granulation of slag
CN101993964A (en) * 2010-11-30 2011-03-30 武汉都市环保工程技术股份有限公司 Metallurgical molten slag dry granulating and heat recovering system
CN103757157A (en) * 2013-12-31 2014-04-30 河南圣石节能环保工程有限公司 Novel slag dry quenching granulating device
CN106381354A (en) * 2016-12-05 2017-02-08 中冶赛迪工程技术股份有限公司 Treatment system and method utilizing biochemically treated tail water of coking wastewater for slag flushing water replenishing
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108275736A (en) * 2018-02-08 2018-07-13 山东钢铁股份有限公司 The method for handling coking wastewater using high-temperature slag granulation system
CN108411053A (en) * 2018-02-26 2018-08-17 西安交通大学 A kind of molten slag granulation apparatus and driving device with elevating function
CN108411053B (en) * 2018-02-26 2020-03-17 西安交通大学 Liquid slag granulation equipment with lifting function and driving device

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