CN106965579A - A kind of glass printing technique of fade effect - Google Patents

A kind of glass printing technique of fade effect Download PDF

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Publication number
CN106965579A
CN106965579A CN201710166744.4A CN201710166744A CN106965579A CN 106965579 A CN106965579 A CN 106965579A CN 201710166744 A CN201710166744 A CN 201710166744A CN 106965579 A CN106965579 A CN 106965579A
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CN
China
Prior art keywords
pattern
fade effect
printing technique
coating
silk
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710166744.4A
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Chinese (zh)
Inventor
区锦泉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FOSHAN GAOMING GREEN DE CHEMICAL CO LTD
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FOSHAN GAOMING GREEN DE CHEMICAL CO LTD
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Priority to CN201710166744.4A priority Critical patent/CN106965579A/en
Publication of CN106965579A publication Critical patent/CN106965579A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00Inking and printing with a printer's forme
    • B41M1/12Stencil printing; Silk-screen printing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00Inking and printing with a printer's forme
    • B41M1/26Printing on other surfaces than ordinary paper
    • B41M1/34Printing on other surfaces than ordinary paper on glass or ceramic surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/0081After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using electromagnetic radiation or waves, e.g. ultraviolet radiation, electron beams
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/02Dusting, e.g. with an anti-offset powder for obtaining raised printing such as by thermogravure ; Varnishing
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0856Iron
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Electromagnetism (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention discloses a kind of glass printing technique of fade effect, comprise the following steps:S01:Using UV coating, silk-screen goes out pattern on glass material;S02:The material that silk-screen is completed is positioned on magnet plate, stands 35 minutes;S03:Pattern on ultraviolet light all solidstate material;S04:Silk-screen or brushing heat curing-type metal ink on pattern after hardening, are toasted 56 minutes under the conditions of 150 170 DEG C;S05:Metal ink layer surface silk-screen after hardening or brushing closing base oil, are toasted 7 10 minutes under the conditions of 175 200 DEG C;The UV coating used in above-mentioned technique is the UV coating containing iron powder.Process in the present invention is prepared using the technique that with the addition of the UV coating of iron powder and be adapted, comply with the demand of industrialized production, the three-dimensional gradient pattern of high-quality for meeting high-end market can be prepared again simultaneously, adhesive force of the pattern on glass material surface is good, the process costs are cheap, and existing multilayer overprinting process can be replaced completely.

Description

A kind of glass printing technique of fade effect
Technical field
The present invention relates to the glass article that a kind of surface has gradual change decorative effect, and in particular to one kind is prepared with gradual change The technique of decorative effect glass article.
Background technology
The technique with three-dimensional fade effect is made in glass using common UV ink on glass material to be processed Product is referred to as " fantasy coloured effect " when selling, and possesses very high market economy value.In the prior art often through screen printing The method of brush obtains such glassware.It is vertical to prepare that the technique of multilayer planar silk-screen printing is used in the prior art The pattern of body fade effect, mesh is reached by the design screen mesh before the pattern is prepared and by the way of multi-sheet printed , i.e., after one layer of ink of silk-screen, its solidification is treated and then again in one layer of ink of its surface silk-screen, then solidified, after being repeated several times Ideal stereoeffect pattern can be obtained.Although preferable pattern can be obtained by the way of multi-sheet printed, into This is in the increase of geometry multiple, because not only to utilize heat UV curing ink at double, in addition it is also necessary to spend substantial amounts of cost to be used for Integrated artistic flow is designed, and proposes the new technical barrier such as multilayer overprinting process, especially needs to solve multilayer UV chromatographys The problem of layer ply adhesion.
For above-mentioned the problems of the prior art, many researchers also proposed other solutions, such as be turned using three-dimensional Die, printing coating finish after by other mechanical means depictions etc. technique, be difficult to solve to turn using the technique of transfer The problem of being patterned the poor adhesive force between glass material, and the technique for carving coating then waste time and energy it is costly, it is difficult at present With volume production.
The content of the invention
One kind is provided for the problems of above-mentioned prior art and existing process, in the present invention using UV coating to exist The process of glass material surface printing stereo fade effect pattern, using the UV coating that with the addition of iron powder and is adapted Prepared by technique, comply with the demand of industrialized production, while can prepare the high-quality solid for meeting high-end market again Gradient pattern, adhesive force of the pattern on glass material surface is good, and the process costs are cheap, and existing multilayer can be replaced completely Overprinting process.
Effect in the present invention is realized by following scheme:
The glass printing technique of the fade effect provided in the present invention, comprises the following steps:
S01:Using UV coating, silk-screen goes out pattern on glass material;
S02:The material that silk-screen is completed is positioned on magnet plate, stands 3-5 minutes;
S03:Pattern on ultraviolet light all solidstate material;
S04:Silk-screen or brushing heat curing-type metal ink on pattern after hardening, toast 5-6 points under the conditions of 150-170 DEG C Clock;
S05:Metal ink layer surface silk-screen after hardening or brushing closing base oil, toast 7- under the conditions of 175-200 DEG C 10 minutes;
The UV coating used in above-mentioned technique is the UV coating containing iron powder.
The composition and weight/mass percentage composition that coating is adapted with above-mentioned preparation method are as follows:
Pure third UV resins 30-50%
Polyurethane acrylate resin 5-10%
Iron powder 30-40%
Adhesive agent 1-2%
Monomer resin 10-20%
Light curing agent 3-5%
Other auxiliary agents 1-2%
Its preparation method is:Pure third pure third UV resins, polyurethane acrylate resin and monomer resin are mixed, stirred, Then iron powder is added, is disperseed under 800-1500r/min speed 20-30 minutes, adhesive agent is then added and other auxiliary agents continues It is scattered 3-5 minutes, it is eventually adding light curing agent and disperses to come into operation for 3-5 minutes.
In the preparation method of the present invention, the magnetic property of iron powder make use of.The work of iron powder in UV coating in magnet plate magnetic force Special three-dimensional pattern effect can be formed with lower, the three-dimensional multi-color effect that multilayer UV ink chromatographys are unable to reach is reached.With What iron powder was adapted, additionally provide corresponding UV formulation for coating material in the present invention.Because iron powder unit mass is relatively heavy, to ensure It can be moved freely in coating wet film to form required pattern, therefore the UV formulation for coating material used in the present invention is low viscous Resin and low viscosity monomer formula are spent, the technique of screen painting had not only been adapted to but also ensure that iron powder during in wet film state Mobility wherein.
Further preferably, most preferably 3-5 μm of iron particle size scope in UV coating, the need for stereoeffect can either being met, Follow-up coating ink layer and confining bed will not be brought inconvenience again.
It is preferred to use TPO, ITS and 184 3 kinds of curing agent with mass ratio 1:1:3 composition combination and solidification agent, for for The solidification of above-mentioned low plastic state UV coating, speeds its curing rate, promotes solidification effect.
Preferred monomers resin is HDDA or TMPTA, and the average weight-molecular mass of polyurethane acrylate resin is 1000-3000, can be further ensured that arrangement mobility, curing performance and the attachment on glass material surface of UV coating Power.
Other described auxiliary agents are the one or more in adhesion promoter, levelling agent, retarding agent, delustering agent, are used for Aid in UV coating film forming and lifting appearance of coat visual effect.
Further, space pattern, the preparation of assistant coating space pattern can be also provided with magnet plate.
Further, the heat curing-type metal ink is thermal-curable acrylic resin ink, and ink film thickness is 15-30 μ m.The closing base oil is transparent or light gray.
The present invention has the advantages that:
1st, provided in the present invention a kind of completely different in the printing of glass material surface with printing technology of the prior art The process of three-dimensional fade effect pattern, not only adhesive force is strong for the three-dimensional fade effect pattern that the process is prepared, And stereoeffect is substantially, apparent visual effect is good.
2nd, the process in glass material surface printing stereo fade effect pattern in the present invention, preparation technology letter It is single, meet the demand of industrialized production, it is with low cost, it may replace the UV printing ink printing arts of existing multilayer half tone chromatography.
Embodiment
The formula and composition of the UV coating used in the present embodiment be:
Raw material used in UV dope preparing process is all marketable material, and wherein iron powder particle mean size is 3 μm, is if desired obtained Third dimension very strong pattern, optional average grain diameter bigger iron powder relatively, while in the technique of pattern is prepared, accordingly Increase the brushing thickness of heat curing-type metal ink, to be completely covered by UV dope layers.The light curing agent used in UV coating is TPO, ITS and 184 3 kinds of curing agent are with mass ratio 1:1:The combination and solidification agent of 3 compositions.The polyurethane acrylate resin of selection Average weight-molecular mass be 2300.The auxiliary agent of selection is with mass ratio 1:The adhesion promoter and levelling agent of 1 composition Mixed aid.
The preparation method of UV coating is:Pure third pure third UV resins, polyurethane acrylate resin and monomer resin are mixed, Stir, then add iron powder, disperse under 1200r/min speed 25 minutes, then add adhesive agent and other auxiliary agents after It is continuous scattered 4 minutes, it is eventually adding light curing agent and disperses to come into operation for 3 minutes.
Take size be 10cm × 10cm × 1cm common glass sheet as application glass material, on its surface The pattern of printing stereo fade effect, step is as follows:
S01:Using UV coating, silk-screen goes out pattern on glass material, and silk-screen plate hole is 200 mesh;
S02:The material that silk-screen is completed is positioned on magnet plate, stands 3-5 minutes.Designed figure can be coordinated on the magnet plate After the completion of the composition of space pattern, standing needed for case is formed, also suitably pattern effect can be made more three-dimensional by moving magnet plate, the step Suddenly a variety of stereoeffects can be obtained by designing, are not added with repeating herein;
S03:Utilize the pattern on the ultraviolet light all solidstate material of UV mercury lamps;
S04:Silk-screen or brushing thermal-curable acrylic resin ink on pattern after hardening, it is 20 μ that ink layer, which applies thickness, M, is toasted 5 minutes under the conditions of 165 DEG C;
S05:Metal ink layer surface silk-screen light gray closing base oil after hardening, toasts 8 minutes under the conditions of 180 DEG C, makes Space pattern surface forms very elegant bright outer layer.
By the glass material produced carries out adhesive force test, impact property test, normal temperature bubble is tested, water boils adhesive force Test, the UV coating material that selection example numbering is 8 carries out test comparison, and comparative example is to use common UV of the prior art Ink is on identical glass material surface with the identical patterns of 200 mesh steel mesh silk-screen chromatographys.
Adhesion test method is:The pattern of transfer or printing to material surface carries out hundred lattice experiments, then uses 3M adhesive tapes are even drawn 3 times in same position.Impact property test method be:The pattern of transfer or printing to material surface enters Row 500g weight 1m height freely falling body is tested.Normal temperature bubble is tested:The pattern of the transfer on material surface or printing is normal Temperature is soaked into running water 24 hours, then carries out hundred lattice experiments, is then even drawn 3 times in same position using 3M adhesive tapes.Water is boiled Adhesion test method is:Material is positioned in boiling water to boil hundred lattice experiments are carried out after 1 hour, then using 3M adhesive tapes identical Even draw 3 times position.
Test result is as follows:
What the method for the present invention was prepared it can be seen from test result has the UV patterns adhesive force of three-dimensional fade effect than existing Have the space pattern adhesive force of Silkscreen print in technology more preferably, its shock resistance, anti-poor environment performance with the prior art Space pattern it is the same, fully meet the demand to existing product.The stereogram on glass material prepared in the present embodiment Case, third dimension is true, and surface is beautiful seamless, and appearance air is high-grade, forms very dazzling fade effect, and comparative example In space pattern be difficult to present identical appearance.
It is last it should be noted that above example is only entered to the technical scheme that illustrates the embodiment of the present invention rather than to it Row limitation, although the embodiment of the present invention is described in detail with reference to preferred embodiment, one of ordinary skill in the art It should be understood that the technical scheme of the embodiment of the present invention can still be modified or equivalent substitution, and these are changed or waited It can not also make the scope of amended technical scheme disengaging technical scheme of the embodiment of the present invention with replacing.

Claims (10)

1. the glass printing technique of a kind of fade effect, it is characterised in that comprise the following steps:
S01:Using UV coating, silk-screen goes out pattern on glass material;
S02:The material that silk-screen is completed is positioned on magnet plate, stands 3-5 minutes;
S03:Pattern on ultraviolet light all solidstate material;
S04:Silk-screen or brushing heat curing-type metal ink on pattern after hardening, toast 5-6 points under the conditions of 150-170 DEG C Clock;
S05:Metal ink layer surface silk-screen after hardening or brushing closing base oil, toast 7- under the conditions of 175-200 DEG C 10 minutes;
The UV coating used in above-mentioned technique is the UV coating containing iron powder.
2. the glass printing technique of fade effect as claimed in claim 1, it is characterised in that:Used UV coating composition and matter Measure percentage composition as follows:
Pure third UV resins 30-50%
Polyurethane acrylate resin 5-10%
Iron powder 30-40%
Adhesive agent 1-2%
Monomer resin 10-20%
Light curing agent 3-5%
Other auxiliary agents 1-2%
Its preparation method is:Pure third pure third UV resins, polyurethane acrylate resin and monomer resin are mixed, stirred, Then iron powder is added, is disperseed under 800-1500r/min speed 20-30 minutes, adhesive agent is then added and other auxiliary agents continues It is scattered 3-5 minutes, it is eventually adding light curing agent and disperses to come into operation for 3-5 minutes.
3. the glass printing technique of fade effect as claimed in claim 2, it is characterised in that:Iron particle size is in the UV coating 3-5μm。
4. the glass printing technique of fade effect as claimed in claim 2, it is characterised in that:The light curing agent is TPO, ITS With 184 3 kinds of curing agent with mass ratio 1:1:3 compositions.
5. the glass printing technique of fade effect as claimed in claim 2, it is characterised in that:The monomer resin be HDDA or TMPTA。
6. the glass printing technique of fade effect as claimed in claim 2, it is characterised in that:The polyurethane acrylate resin Average weight-molecular mass be 1000-3000.
7. the glass printing technique of fade effect as claimed in claim 2, it is characterised in that:Other described auxiliary agents are made every effort to promote for attachment The one or more entered in agent, levelling agent, retarding agent, delustering agent.
8. the glass printing technique of fade effect as claimed in claim 1, it is characterised in that:The magnet plate is provided with stereogram Case.
9. the glass printing technique of fade effect as claimed in claim 1, it is characterised in that:The heat curing-type metal ink is heat Curable type acrylic resin ink, ink film thickness is 15-30 μm.
10. the glass printing technique of fade effect as claimed in claim 1, it is characterised in that:The closing base oil to be transparent or Person is light grey.
CN201710166744.4A 2017-03-20 2017-03-20 A kind of glass printing technique of fade effect Pending CN106965579A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108819525A (en) * 2018-05-31 2018-11-16 深圳市柏星龙创意包装股份有限公司 A kind of 3D illusion-colour silk screen printing process
CN109703224A (en) * 2019-03-05 2019-05-03 苏州恒辰印刷科技有限公司 The packing box printing technology of UV solid frosted
CN110879434A (en) * 2019-11-07 2020-03-13 精电(河源)显示技术有限公司 Preparation method of color gradient film and display device with color gradient film
CN112167801A (en) * 2019-07-05 2021-01-05 深圳市卡乐尔化妆用品有限公司 Three-dimensional color printing cosmetic brush and preparation method thereof
CN114126872A (en) * 2019-04-18 2022-03-01 埃克森蒂斯知识股份有限公司 Apparatus and method for producing a three-dimensional screen-printed workpiece
CN114144307A (en) * 2019-04-18 2022-03-04 埃克森蒂斯知识股份有限公司 Method for producing a three-dimensional screen-printed workpiece
US11787733B2 (en) 2019-03-06 2023-10-17 Owens-Brockway Glass Container Inc. Three-dimensional printing of a porous matrix on a container

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CN106280689A (en) * 2016-08-26 2017-01-04 佛山市高明绿色德化工有限公司 A kind of LED UV ink and preparation method thereof, using method

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108819525A (en) * 2018-05-31 2018-11-16 深圳市柏星龙创意包装股份有限公司 A kind of 3D illusion-colour silk screen printing process
CN109703224A (en) * 2019-03-05 2019-05-03 苏州恒辰印刷科技有限公司 The packing box printing technology of UV solid frosted
US11787733B2 (en) 2019-03-06 2023-10-17 Owens-Brockway Glass Container Inc. Three-dimensional printing of a porous matrix on a container
CN114126872A (en) * 2019-04-18 2022-03-01 埃克森蒂斯知识股份有限公司 Apparatus and method for producing a three-dimensional screen-printed workpiece
CN114144307A (en) * 2019-04-18 2022-03-04 埃克森蒂斯知识股份有限公司 Method for producing a three-dimensional screen-printed workpiece
CN114144307B (en) * 2019-04-18 2024-07-02 埃克森蒂斯知识股份有限公司 Method for producing three-dimensional screen-printed workpieces
CN114126872B (en) * 2019-04-18 2024-07-09 埃克森蒂斯知识股份有限公司 Apparatus and method for producing three-dimensional screen printed workpieces
CN112167801A (en) * 2019-07-05 2021-01-05 深圳市卡乐尔化妆用品有限公司 Three-dimensional color printing cosmetic brush and preparation method thereof
CN110879434A (en) * 2019-11-07 2020-03-13 精电(河源)显示技术有限公司 Preparation method of color gradient film and display device with color gradient film

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Application publication date: 20170721