CN106960693A - A kind of touch-screen electrocondution slurry - Google Patents
A kind of touch-screen electrocondution slurry Download PDFInfo
- Publication number
- CN106960693A CN106960693A CN201610014696.2A CN201610014696A CN106960693A CN 106960693 A CN106960693 A CN 106960693A CN 201610014696 A CN201610014696 A CN 201610014696A CN 106960693 A CN106960693 A CN 106960693A
- Authority
- CN
- China
- Prior art keywords
- touch
- screen
- silver powder
- resin
- accounts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/22—Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
Abstract
The present invention discloses a kind of touch-screen slurry of suitable low temperature flash baking curing process, and it is by nano-silver powder and dendritic micron silver powder hybrid conductive silver powder, organic carrier and inorganic additive, accelerator composition.This touch-screen silver paste has excellent printing performance, meets low temperature drying curing process, with preferable line resistance after solidification, hundred lattice hardness tests, anti-hand scraping ability, the performance such as excellent contact resistance.
Description
Technical field
Produced the present invention relates to the electrocondution slurry that touch-screen is used, more particularly to low temperature flash baking curing process
The making of touch-screen silver paste.
Background technology
With the development of touch screen technology, touch-screen production production man produces the touch-screen of one of raw material to touch-screen
Electrocondution slurry requires also more and more higher, wherein house is much produced in order to save energy consumption, while improving production efficiency,
Touch-screen slurry is claimed in the requirement of 100 degree or so flash baking solidifications, and on the market now absolutely mostly
The touch-screen silver paste of number excellent performance is required for carrying out prolonged baking and curing using more than 130 degree of high temperature
Technique.
This patent, which is provided, has invented a kind of touch-screen silver paste of suitable low temperature flash baking curing process, solves above-mentioned
Nano-silver powder is added in problem, slurry can effectively reduce bulk resistor and contact resistance, while can increase touch-screen
The adhesive force of silver paste and base material, nano silver particles initially enter silver paste and base material in touch-screen silver paste drying course
Combination interface, its diffusivity is better than the Argent grain in other touch-screen silver pastes, generates part nano-particle
Caused by tunnel-effect.
Also there is very excellent performance after low temperature flash baking solidification, industry can be met in low temperature flash baking
The requirement of aspect, the blank filled up in industry.
The content of the invention
It is an object of the invention to provide a kind of touch-screen silver paste of suitable low temperature flash baking curing process, it is matched somebody with somebody
Side is by nano-silver powder and dendritic micron silver powder hybrid conductive silver powder, organic carrier, inorganic additive, accelerator
Composition.The mass percent of each component is:Hybrid conductive silver powder accounts for 30-85%, and organic carrier accounts for 25-50%,
Inorganic additive accounts for 0-4%, and accelerator accounts for 0.1-3%.
Nano-silver powder accounts for the 0.1-10.0% of hybrid conductive silver powder in the hybrid conductive silver powder, and its average grain diameter is
50-800 nanometers, dendritic micron silver powder accounts for the 90.0-99.9% of hybrid conductive silver powder, and its average grain diameter is
0.2-2.0 microns.
The resin portion of organic carrier is by by acrylic resin, polyurethane resin, polyester in the organic carrier
Resin, polyamide, phenolic resin, epoxy resin, glycidol ethers, carbamide resin, polyethylene tree
One or more of compositions in fat, vinyl chloride-vinyl acetate resin, Corvic, polyacetals resinoid.
The solvent content of the organic carrier is by PMA, butyl acetate, ethyl acetate, DBE, isophorone,
Diethylene glycol ether acetate, ethylene glycol ether acetate, butyl carbitol acetate, glycerine, ethylene glycol,
One or several kinds of compositions in ATBC.
The accelerator is had by MDI, TDI, HDI, the isocyanates of modified end-blocking, silane coupler
One kind in machine titanium coupling agent, organic zinc coupling agent, diene triamine, triolefin tetramine, IPD or
Several compositions.
The superiority that the present invention has:With excellent printing performance, low temperature drying curing process is met, Gu
There is preferable line resistance, hundred lattice hardness tests, anti-hand scraping ability is good, the better performances such as contact resistance after change.
Embodiment
The present invention is done with reference to instantiation and further illustrated:
Example 1
(1) organic carrier formula:
It is made into composition | Organic carrier 1 | Organic carrier 2 |
Acrylic resin A | 0 | 2 |
Vinyl chloride-vinyl acetate resin B | 3 | 4 |
Polyester resin C | 5 | 4 |
Epoxy resin D | 1 | 0 |
Phenolic resin E | 1 | 0 |
PMA | 73 | 50 |
Butyl acetate | 10 | 20 |
Ethyl acetate | 5 | 8 |
DBE | 0 | 2 |
Ethylene glycol | 1 | 0 |
Glycerine | 1 | 0 |
Ethylene glycol ether acetate | 0 | 10 |
(2) agent prescription is promoted:
It is made into composition | Accelerator 1 | Accelerator 2 |
The isocyanates A of modified end-blocking | 80 | 30 |
Silane coupler B | 15 | 20 |
Organic titanium coupling agent C | 5 | 10 |
IPD | 0 | 40 |
(3) entire slurry formula
(4) 100 degree of 20 minutes results that are heating and curing
Silver paste A | Silver paste B | Silver paste C | |
Fineness | Less than 8 microns | Less than 8 microns | Less than 8 microns |
Hundred lattice adhesive force | 5B | 5B | 5B |
Case hardness | 2H | 2H | 2H |
Electric conductivity | It is excellent | It is excellent | It is excellent |
Stability | Well | Well | Well |
High heat resistance height is moist | Well | Well | Well |
Continue printing capability | Well | Well | Well |
Contact resistance | It is excellent | It is excellent | It is excellent |
(5) 80 degree of 25 minutes results that are heating and curing
Silver paste A | Silver paste B | Silver paste C | |
Fineness | Less than 8 microns | Less than 8 microns | Less than 8 microns |
Hundred lattice adhesive force | 4B | 4B | 4B |
Case hardness | 2H | 2H | 2H |
Electric conductivity | It is excellent | It is excellent | It is excellent |
Stability | Well | Well | Well |
High heat resistance height is moist | Well | Well | Well |
Continue printing capability | Well | Well | Well |
Contact resistance | It is excellent | It is excellent | It is excellent |
Claims (5)
1. a kind of touch-screen electrocondution slurry, the mass percent of each component is:Hybrid conductive silver powder accounts for 51-59%, and organic carrier accounts for 35-50%, and inorganic additive accounts for 3-4%, and accelerator accounts for 0.1-3%.
2. a kind of touch-screen electrocondution slurry according to claim 1, it is characterized in that, nano-silver powder accounts for the 0.1-10.0% of hybrid conductive silver powder in the hybrid conductive silver powder, its average grain diameter is 50-800 nanometers, dendritic micron silver powder accounts for the 90.0-99.9% of hybrid conductive silver powder, and its average grain diameter is 0.2-2.0 microns.
3. a kind of touch-screen electrocondution slurry according to claim 1, it is characterised in that the resin portion of organic carrier is by by acrylic resin in the organic carrier, polyurethane resin, polyester resin, polyamide, phenolic resin, epoxy resin, glycidol ethers, carbamide resin, polyvinyl resin, one or more of compositions in vinyl chloride-vinyl acetate resin, Corvic, polyacetals resinoid.
4. a kind of touch-screen electrocondution slurry according to claim 1, it is characterised in that the solvent content of the organic carrier is by PMA, butyl acetate, ethyl acetate, DBE, isophorone, diethylene glycol ether acetate, ethylene glycol ether acetate, butyl carbitol acetate, glycerine, one or several kinds of compositions in ethylene glycol, ATBC.
5. a kind of touch-screen electrocondution slurry according to claim 1, characterized in that, the accelerator is by MDI, TDI, HDI, the isocyanates of modified end-blocking, silane coupler, organic titanium coupling agent, organic zinc coupling agent, one or several kinds of compositions in diene triamine, triolefin tetramine, IPD.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610014696.2A CN106960693A (en) | 2016-01-09 | 2016-01-09 | A kind of touch-screen electrocondution slurry |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610014696.2A CN106960693A (en) | 2016-01-09 | 2016-01-09 | A kind of touch-screen electrocondution slurry |
Publications (1)
Publication Number | Publication Date |
---|---|
CN106960693A true CN106960693A (en) | 2017-07-18 |
Family
ID=59480704
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610014696.2A Pending CN106960693A (en) | 2016-01-09 | 2016-01-09 | A kind of touch-screen electrocondution slurry |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106960693A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107705876A (en) * | 2017-09-19 | 2018-02-16 | 合肥惠科金扬科技有限公司 | A kind of TFT LCD screens conductive silver paste |
CN108047986A (en) * | 2017-12-25 | 2018-05-18 | 天津瑞爱恩科技有限公司 | Solid conductive hot-melt silver adhesive |
CN109087723A (en) * | 2018-07-01 | 2018-12-25 | 长沙新材料产业研究院有限公司 | A kind of gold electrocondution slurry and preparation method thereof |
CN111508637A (en) * | 2020-04-28 | 2020-08-07 | 无锡晶睿光电新材料有限公司 | Silver paste with high conductivity at 80 ℃ and preparation method thereof |
CN111511099A (en) * | 2020-03-25 | 2020-08-07 | 上海玖银电子科技有限公司 | Quick-drying silver paste for large keyboard conductive film circuit and preparation method thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009252507A (en) * | 2008-04-04 | 2009-10-29 | Dowa Electronics Materials Co Ltd | Conductive paste containing micro silver particles, and hardened film |
CN101882481A (en) * | 2010-06-28 | 2010-11-10 | 彩虹集团公司 | Halogen-free type low-temperature solidified silver paste and method for preparing same |
CN103000252A (en) * | 2012-11-10 | 2013-03-27 | 江苏瑞德新能源科技有限公司 | Solar cell silver-backed slurry ultralow in silver content |
CN103000255A (en) * | 2012-11-10 | 2013-03-27 | 江苏瑞德新能源科技有限公司 | Solar cell front sliver paste adaptable to low-temperature sintering |
CN103903675A (en) * | 2012-12-28 | 2014-07-02 | 北京中科纳通科技有限公司 | High-stability conductive slurry and preparation method thereof |
-
2016
- 2016-01-09 CN CN201610014696.2A patent/CN106960693A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009252507A (en) * | 2008-04-04 | 2009-10-29 | Dowa Electronics Materials Co Ltd | Conductive paste containing micro silver particles, and hardened film |
CN101882481A (en) * | 2010-06-28 | 2010-11-10 | 彩虹集团公司 | Halogen-free type low-temperature solidified silver paste and method for preparing same |
CN103000252A (en) * | 2012-11-10 | 2013-03-27 | 江苏瑞德新能源科技有限公司 | Solar cell silver-backed slurry ultralow in silver content |
CN103000255A (en) * | 2012-11-10 | 2013-03-27 | 江苏瑞德新能源科技有限公司 | Solar cell front sliver paste adaptable to low-temperature sintering |
CN103903675A (en) * | 2012-12-28 | 2014-07-02 | 北京中科纳通科技有限公司 | High-stability conductive slurry and preparation method thereof |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107705876A (en) * | 2017-09-19 | 2018-02-16 | 合肥惠科金扬科技有限公司 | A kind of TFT LCD screens conductive silver paste |
CN108047986A (en) * | 2017-12-25 | 2018-05-18 | 天津瑞爱恩科技有限公司 | Solid conductive hot-melt silver adhesive |
CN109087723A (en) * | 2018-07-01 | 2018-12-25 | 长沙新材料产业研究院有限公司 | A kind of gold electrocondution slurry and preparation method thereof |
CN111511099A (en) * | 2020-03-25 | 2020-08-07 | 上海玖银电子科技有限公司 | Quick-drying silver paste for large keyboard conductive film circuit and preparation method thereof |
CN111511099B (en) * | 2020-03-25 | 2021-06-08 | 上海玖银电子科技有限公司 | Quick-drying silver paste for large keyboard conductive film circuit and preparation method thereof |
CN111508637A (en) * | 2020-04-28 | 2020-08-07 | 无锡晶睿光电新材料有限公司 | Silver paste with high conductivity at 80 ℃ and preparation method thereof |
CN111508637B (en) * | 2020-04-28 | 2021-08-31 | 无锡晶睿光电新材料有限公司 | Silver paste with high conductivity at 80 ℃ and preparation method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN106960693A (en) | A kind of touch-screen electrocondution slurry | |
JP2013521595A5 (en) | ||
CN106098145B (en) | A kind of low-temperature cured conductive paste based on flexible parent metal and preparation method thereof | |
CN110157196B (en) | Graphene material directional arrangement and silica gel pad composite forming method and product | |
TW201603656A (en) | Graphene printed pattern circuit structure | |
KR101579522B1 (en) | Resin composition having electro-magnetic wave absorption function with high thermal radiation, and molded article manufacture by using the same | |
CN106675434B (en) | One kind can rapid curing conductive silver glue | |
CN102191001B (en) | Epoxy conductive adhesive composition | |
CN103059767A (en) | Conductive silver paste with high-temperature resistance and low sheet resistance and preparation method of conductive silver paste | |
CN107163398A (en) | A kind of polypropylene color masterbatch of graphene-containing and preparation method thereof | |
CN106024101B (en) | A kind of composite conductive ceramic slurry and preparation method thereof | |
CN107189103B (en) | A kind of conductive filler, preparation method and the usage | |
CN104817995A (en) | Novel polyurethane conductive adhesive and preparation method thereof | |
JP2016103473A (en) | Multilayer carbon brush and manufacturing method of the same | |
CN104858437A (en) | Nano silver paste for printing conducting circuit and preparation method of nano silver paste | |
CN104143372B (en) | A kind of modified mullite conductive silver paste and preparation method thereof | |
KR101993883B1 (en) | Method for Manufacturing Non Metallic Silicon Complex Using Nano Hole of CNT and the Silicon Complex | |
CN206242599U (en) | A kind of Anti-static release liner | |
CN101974291A (en) | Conductive rubber emulsion paint | |
JP2003331648A (en) | Conductive paste and manufacturing method for electric circuit | |
CN103194108A (en) | Wear-resistant conductive coating paint and preparation method thereof | |
CN104078095A (en) | Conductive oxygen-free ceramic powder/nano-graphite composite conductive silver paste and preparing method thereof | |
CN106634775A (en) | High-temperature-resistant conductive silver colloid | |
CN103219065A (en) | Carbon nanotube-nanometer copper powder-based environment-friendly conductive paste | |
CN103881610A (en) | Conductive adhesive and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170718 |
|
RJ01 | Rejection of invention patent application after publication |