CN106957585B - A kind of anticorrosive paint - Google Patents
A kind of anticorrosive paint Download PDFInfo
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- CN106957585B CN106957585B CN201710111145.2A CN201710111145A CN106957585B CN 106957585 B CN106957585 B CN 106957585B CN 201710111145 A CN201710111145 A CN 201710111145A CN 106957585 B CN106957585 B CN 106957585B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/04—Epoxynovolacs
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/084—Inorganic compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to technical field of coatings, and in particular to a kind of anticorrosive paint.Its construction temperature can carry out long-time coating at 0 ~ 40 DEG C, and highest construction temperature is up to 50 DEG C.A kind of anticorrosive paint of the present invention, including primary coat and face apply;The primary coat is composed of the following raw materials by weight: 45 ~ 60 parts of bisphenol A epoxide resin, 5 ~ 20 parts of reactive diluent, 20 ~ 30 parts of glass flake, 2 ~ 5 parts of thixotropic agent, 1 ~ 5 part of pigment, 0.5 ~ 1 part of auxiliary agent, 3 ~ 5 parts of filler, 5 ~ 8 parts of rust resisting pigment, 10 ~ 25 parts of curing agent A, 10 ~ 25 parts of curing agent B;The face applies and is composed of the following raw materials by weight: 50 ~ 60 parts of novolac epoxy resin, 10 ~ 15 parts of bisphenol F epoxy resin, 2 ~ 5 parts of thixotropic agent, 15 ~ 20 parts of silica flour, 13 ~ 25 parts of filler, 3 ~ 5 parts of pigment, 1 ~ 1.5 part of auxiliary agent, 10 ~ 25 parts of curing agent A, 10 ~ 25 parts of curing agent B.
Description
One, technical field:
The present invention relates to technical field of coatings, and in particular to a kind of anticorrosive paint.
Two, background technique:
Due to industrial occasions such as oil field, mining, pipeline, the container of steel structure touch sour gas, such as titanium dioxide
The corrosive gas such as carbon, sulfur dioxide after the equipment for touching steel material, to its seriously corroded, are influenced using the safe and longevity
Life.Traditional anti-corrosion material film forming is relatively thin, and anti-corrosive properties are poor, and a large amount of volatile solvent is needed in coating process, this kind of molten
Agent, which is discharged into atmosphere, can destroy atmosphere, and with the severization of environmental protection policy, environment-friendly solvent-free class heavy anticorrosive material is obtained extensively
General application.
In recent years, for conveying sewage, crude oil, produce gas steel systeming equipment it is more and more, especially production practice
It alternates, the dielectric structure in steel pipe, storage tank is complicated, and acid concentration is high, and traditional anticorrosive paint is unable to reach long-effective corrosion
Purpose.Heavy anticorrosive material in the present invention also enhances mechanical performance, such as while being significantly improved on antiseptic property
Bending strength etc., to adapt to be resisted in the process of running from external stress and deformation harm.The present invention is especially suitable as
The conveyance conduit of oil and gas industry and the interior anti-corrosion of storage and transportation steel tank are improved and are applied while improving construction efficiency
Work safety, it is ensured that service life.
Three, summary of the invention
Of the invention provides a kind of anticorrosive paint, and construction temperature can carry out long-time coating, highest at 0~40 DEG C
Construction temperature is up to 50 DEG C.
To achieve the above object, a kind of the technical solution adopted by the present invention are as follows: anticorrosive paint, it is characterised in that: including
Primary coat and face apply,
The primary coat is composed of the following raw materials by weight: 45~60 parts of bisphenol A epoxide resin, reactive diluent 5~20
Part, 20~30 parts of glass flake, 2~5 parts of thixotropic agent, 1~5 part of pigment, 0.5~1 part of auxiliary agent, 3~5 parts of filler, rust resisting pigment 5
~8 parts, 10~25 parts of curing agent A, 10~25 parts of curing agent B;
The face applies and is composed of the following raw materials by weight: 50~60 parts of novolac epoxy resin, bisphenol F epoxy resin 10~
15 parts, 2~5 parts of thixotropic agent, 15~20 parts of silica flour, 13~25 parts of filler, 3~5 parts of pigment, 1~1.5 part of auxiliary agent, curing agent A
10~25 parts, 10~25 parts of curing agent B.
The reactive diluent is non-volatile response type Environment-friendlydiluent diluent aliphatic glycidyl ether or polypropylene glycol two
Glycidol ether.
The thixotropic agent is fumed silica, polyethylene wax.
The pigment is carbon black, phthalocyanine blue or graphite.
The auxiliary agent is dispersing agent 501, defoaming agent 385N, the poly- glutamine wax of thixotropic agent, at least one in levelling agent 837
Kind.
The filler is blanc fixe, talcum powder or mica powder one of which or two or more mixtures.
The parts by weight of the mixture of the blanc fixe, talcum powder, blanc fixe and talcum powder are respectively 7~
8 parts and 5~7 parts, granularity is 800~1250 mesh.
The rust resisting pigment is the mixture of aluminum phosphate, polyaniline, aluminium triphosphate.
The curing agent A is modified fatty amine, and curing agent B is modified aromatic amine, and wherein curing agent A is used for 0~20
It is used under DEG C environment temperature, curing agent B is used under 20~40 DEG C of environment temperatures use.
The glass flake is 80 mesh, the mixture of 120 mesh and 300 mesh.
Compared with prior art, the invention has the advantages that and effect:
The reactive diluent that the present invention is added, atmosphere will not be polluted by participating in reaction, and the auxiliary agent of addition may make list
The film thickness of secondary coating reaches 500~800 μm, reduces construction times, improves speed of application.
The present invention has widened construction temperature range to greatest extent, and acid resistance, the acid gas permeation for improving coating are rotten
It loses, enhance impact resistance and adhesive force, relative to conventional anticorrosive paint, the mechanical strength of this material is bigger, and disposable coating makes
It is long with longer life expectancy;
Heavy anticorrosive material in the present invention also enhances mechanical performance while being significantly improved on antiseptic property, all
Such as bending strength, to adapt to be resisted in the process of running from external stress and deformation harm.
The present invention is especially suitable as the conveyance conduit of oil and gas industry and the interior anti-corrosion of storage and transportation steel tank,
While improving construction efficiency, working security is improved, it is ensured that service life.
Four, specific embodiment
It is limited below with reference to specific embodiment technical solution of the present invention is further:
Embodiment one: a kind of anticorrosive paint, including primary coat and face apply,
The primary coat is composed of the following raw materials by weight: 45 parts of bisphenol A epoxide resin, 5 parts of reactive diluent, and glass squama
20 parts of piece, 2 parts of thixotropic agent, 1 part of pigment, 0.5 part of auxiliary agent, 3 parts of filler, 5 parts of rust resisting pigment, 10 parts of curing agent A, curing agent B
10 parts;
The face applies and is composed of the following raw materials by weight: 50 parts of novolac epoxy resin, 10 parts of bisphenol F epoxy resin, and touching
2 parts of agent of change, 15 parts of silica flour, 13 parts of filler, 3 parts of pigment, 1 part of auxiliary agent, 10 parts of curing agent A, 10 parts of curing agent B.
The reactive diluent is non-volatile response type Environment-friendlydiluent diluent aliphatic glycidyl ether.
The thixotropic agent is fumed silica.
The pigment is carbon black.
The auxiliary agent is dispersing agent 501, defoaming agent 385N, levelling agent 837.
The filler is the mixture of blanc fixe, talcum powder.
The parts by weight of the mixture of the blanc fixe, talcum powder, blanc fixe and talcum powder are respectively 7 parts
With 5 parts, granularity is 800 mesh.
The rust resisting pigment is the mixture of aluminum phosphate, polyaniline, aluminium triphosphate.
The curing agent A is modified fatty amine, and curing agent B is modified aromatic amine, and wherein curing agent A is used for 0 DEG C of ring
It is used at a temperature of border, curing agent B is used under 20 DEG C of environment temperatures use.
The glass flake is 80 mesh, the mixture of 120 mesh and 300 mesh.
Embodiment two: a kind of anticorrosive paint, including primary coat and face apply,
The primary coat is composed of the following raw materials by weight: 60 parts of bisphenol A epoxide resin, 20 parts of reactive diluent, and glass
30 parts of scale, 5 parts of thixotropic agent, 5 parts of pigment, 1 part of auxiliary agent, 5 parts of filler, 8 parts of rust resisting pigment, 25 parts of curing agent A, curing agent B
25 parts;
The face applies and is composed of the following raw materials by weight: 60 parts of novolac epoxy resin, 15 parts of bisphenol F epoxy resin, and touching
5 parts of agent of change, 20 parts of silica flour, 25 parts of filler, 5 parts of pigment, 1.5 parts of auxiliary agent, 25 parts of curing agent A, 25 parts of curing agent B.
The reactive diluent is non-volatile response type Environment-friendlydiluent diluent polypropylene glycol diglycidyl ether.
The thixotropic agent is polyethylene wax.
The pigment is phthalocyanine blue.
The auxiliary agent be dispersing agent 501, defoaming agent 385N,.
The filler is talcum powder or mica powder one of which or two or more mixtures.
The parts by weight of the mixture of the mica powder, talcum powder, mica powder and talcum powder are respectively 8 parts and 7 parts, grain
Degree is 1250 mesh.
The rust resisting pigment is the mixture of aluminum phosphate, polyaniline, aluminium triphosphate.
The curing agent A is modified fatty amine, and curing agent B is modified aromatic amine, and wherein curing agent A is used for 20 DEG C of rings
It is used at a temperature of border, curing agent B is used under 40 DEG C of environment temperatures use.
The glass flake is 80 mesh, the mixture of 120 mesh and 300 mesh.
Embodiment three: a kind of anticorrosive paint, including primary coat and face apply,
The primary coat is composed of the following raw materials by weight: bisphenol A epoxide resin 50, reactive diluent 15, glass flake
25, thixotropic agent 3, pigment 4, auxiliary agent 1, filler 4, rust resisting pigment 7, curing agent A 15, curing agent B 20;
The face applies and is composed of the following raw materials by weight: novolac epoxy resin 55, bisphenol F epoxy resin 13, thixotropic agent
4, silica flour 18, filler 20, pigment 4, auxiliary agent 1, curing agent A 15, curing agent B 15.
The reactive diluent is non-volatile response type Environment-friendlydiluent diluent polypropylene glycol diglycidyl ether.
The thixotropic agent is fumed silica.
The pigment is graphite.
The auxiliary agent is defoaming agent 385N, levelling agent 837.
The filler is blanc fixe, talcum powder, mica powder, mixture.
The blanc fixe, talcum powder, mica powder mixture, the weight of blanc fixe, talcum powder, mica powder
Number is respectively 7 parts, 6 parts and 2 parts, and granularity is 1000 mesh.
The rust resisting pigment is the mixture of aluminum phosphate, polyaniline, aluminium triphosphate.
The curing agent A is modified fatty amine, and curing agent B is modified aromatic amine, and wherein curing agent A is used for 15 DEG C of rings
It is used at a temperature of border, curing agent B is used under 30 DEG C of environment temperatures use.
The glass flake is 80 mesh, the mixture of 120 mesh and 300 mesh.
The ring that bisphenol A epoxide resin used in example 1 to embodiment 3 is the production of blue star Chemical Co., Ltd. is applied in above-mentioned implementation
Oxygen resin 128, bisphenol F epoxy resin are the epoxy resin 170 of Changchun resin processing plant production, and novolac epoxy resin resin is Chang Chunshu
The novolac epoxy resin 188 of rouge factory production.Curing agent A, curing agent B are the graceful production of Hensel.
Preparation method of the invention comprises the concrete steps that: primary coat preparation method is by part bisphenol A type epoxy resin and work
Property diluent after mixing, be added auxiliary agent after, in high speed disperser keep revolving speed 1000r/min stirring, stir 0.5h after
It stands, then squeezes into liquid material in horizontal sand mill, kept for 50~60 DEG C of sand mill cavity temperature, fineness of grind is to after 50 μm
It releases stand-by.Residual resin, pigment, filler and rust resisting pigment are uniformly mixed, revolving speed is kept in high speed dispersion agent
1000r/min squeezes into liquid slurry in horizontal sand mill after stirring 0.5h, and fineness of grind is to 50 μm of releasings, by liquid slurry
As in high speed disperser, revolving speed 500r/min is kept, glass flake mixture is added and is added gradually in slurry, addition finishes
Afterwards, dispersing agent revolving speed is kept into 1000r/min, stirs 0.5h, then the liquid material got ready before is added to the slurry mixed up
In, it stirs 20 minutes, revolving speed keeps 800r/min, and then adjusting viscosity using remaining reactive diluent is 0.8Pa.s
Obtain finished product anticorrosive paint basecoat material.Face coating preparation method is to add first by novolac epoxy resin as heating in heating bath cylinder
Bisphenol F epoxy resin is poured into novolac epoxy resin liquid after heat is good, adds silica flour, filler, auxiliary agent etc. is subsequently placed in height
Under fast dispersion machine, revolving speed 800r/min is kept, after twenty minutes, revolving speed is adjusted to 1000 turns, is kept for 10 minutes, the slurry that will be mixed up
It is driven into horizontal sand mill, is dispersed to 40 microns of fineness, ground liquid material is added in finished container, then with surplus
Remaining reactive diluent adjusts viscosity and applies anticorrosive paint to 0.5Pa.s to get to finished product face.Finally solidification A and curing agent B is pressed
Ratio is added in paint mixing cylinder, after mixing up to curing agent finished product.
The performance of anticorrosive paint made from embodiment 3 detect as follows:
Experimentation:
One, anticorrosive paint sample made from embodiment 3 is tested, sample is proportionally deployed to preparation and brushes examination
Sample;
One detection project sample testing specification of table
Two, template status adjustment
Template after all brushed is placed under the conditions of constant temperature and humidity and carries out status adjustment for 24 hours, impact resistance, adhesive force,
Hardness project can be detected, after adjusting 168h, chemically-resistant stabilization, wearability, salt fog resistance, resistance to original sewage, resistance to crude oil, gas
Bubbling, high temperature and pressure test can be tested.
Three, performance test
3.1 impact resistances test uses impact tester and 4 times of magnifying glasses, by the good test plate (panel) of status adjustment as impact test
On device, the metal impact head of pull-up impactor weight weight leading portion after certain altitude, release surface of the paint film impact to be formed it is recessed
Whether slot has crackle with amplification sem observation groove, if flawless determines qualification, and calculates impact force with weight pull-out altitude,
Units of joules.
Method adhesion-force tester is pulled open in the test use of 3.2 adhesive force, and the template adjusted is bonded with survey using adhesive
Spindle special is tried, after bonding for 24 hours to status adjustment at room temperature, using method adhesion-force tester drawing spindle is pulled open, works as spindle
It pulls open in a flash, instrument can automatically record pulling-off force, and show on the electronic display screen, data, that is, adhesive force test at this time
Value, unit megapascal.
3.3 chemical-resistant stabilities, configuration volume fraction are 10%NaOH solution, 10%H2SO4Solution, 3%NaCl solution.
The good template of status adjustment is sealed to the position for applying 5 millimeters of test plate (panel) edge with rosin, regulates test plate (panel) entrance in advance after sealing
In chemical reagent, and the appearance for impregnating template is recorded once a day, checks it is whether coating is complete, if there is blistering, has and fall off,
It is kept for 90 days, process deadline is to there are the defective modes such as blister, fall off as foundation.
Then 3.4 wearability tests are placed in again by the sample for the state that regulates as weight before assay balance test experiments
On paint film abrasion instrument, sample load 1000g is set, abrasion instrument revolving speed 60r/min, CS15 grinding wheel after rotating 1000r, are tested real
Rear weight is tested, forward backward averaging of poor quality is abrasion loss, characterizes the wearability of material.
The template for the state that regulates is placed on pencil hardometer by 3.5 hardness tests, 2H pencil is used first, by pencil
At least 7mm is pushed on paint film with 45 degree of angle of angle, checks whether paint film has scratch after wiping, if can be more without scratch
Pencil with high hardness is changed, if there is the low pencil of the replaceable hardness of scratch, retest detects hardness range.
The sample regulated is being marked cross using blade, as in salt spray test chamber, opened by 3.6 salt fog resistances
Salt spray test chamber is opened, whether observation cross periphery paint film, which has, after a certain period of time falls off, to observe obscission for the first time
To test deadline.
Oilfield sewage and crude oil are contained in road container, as thermostatted water liquid furnace, and are pressed by 3.7 resistance to oilfield sewages, resistance to crude oil
Experimental temperature is adjusted according to requirement of experiment, the experiment template for the state that regulates is subjected to edge sealing using resin, is impregnated after the completion of edge sealing
In sewage and crude oil, and time and state are recorded, whether observation paint film coating is complete, if having blistering or fall off, by test
Time requirement is kept, and process deadline is to there are the defective modes such as blister, fall off as foundation.
3.8 resist bending tests test the template for the state that regulates on crooked experiment device, when test plate (panel) is with certain condition
After bending, whether observation flexure plane has crackle or breakage, to judge whether resistance to bend(ing) can qualified without damaged, flawless phenomenon,
When qualification, bending angle is set to complete the performance test results.
The experiment of 3.9 gas bells, by the sample for the state that regulates as in autoclave, being passed through pure nitrogen, and passes through tune
It is 8 ± 0.5 megapascal that pressure device, which adjusts pressure, after keeping for 24 hours, the quick pressure releasing in 1 minute, and observe whether surface of the paint film has gas
Hole is determined as criterion of acceptability with pore-free.
3.10 high temperature and pressure experiments are 5% sodium chloride solutions being soaked in the template for the state that regulates in high temperature and high pressure kettle
In, it is arranged 55 DEG C of temperature, nitrogen and carbon dioxide mix ratio are 94:6, and mixture pressure is 3 megapascal, after keeping for 24 hours,
Template is taken out, whether observation specimen surface there are the defective modes such as blistering, and complete with paint film, good is qualification determination foundation.
Four, examining report
One surface material performance test of table report
Two primer performance test of table report
Three face of table, bottom composite property test report
By the data in table it is found that the anticorrosive paint in the present invention improves the acid resistance, alkali resistance and attachment of paint film
Power, so that the overall performance of anticorrosive paint is improved.
Claims (1)
1. a kind of anticorrosive paint, it is characterised in that: it is applied including primary coat and face,
The primary coat is composed of the following raw materials by weight: 45 ~ 60 parts of bisphenol A epoxide resin, 5 ~ 20 parts of reactive diluent, and glass
20 ~ 30 parts of scale, 2 ~ 5 parts of thixotropic agent, 1 ~ 5 part of pigment, 0.5 ~ 1 part of auxiliary agent, 3 ~ 5 parts of filler, 5 ~ 8 parts of rust resisting pigment, curing agent A
10 ~ 25 parts, 10 ~ 25 parts of curing agent B;
The face applies and is composed of the following raw materials by weight: 50 ~ 60 parts of novolac epoxy resin, 10 ~ 15 parts of bisphenol F epoxy resin,
2 ~ 5 parts of thixotropic agent, 15 ~ 20 parts of silica flour, 13 ~ 25 parts of filler, 3 ~ 5 parts of pigment, 1 ~ 1.5 part of auxiliary agent, 10 ~ 25 parts of curing agent A,
10 ~ 25 parts of curing agent B;
The reactive diluent is that non-volatile response type Environment-friendlydiluent diluent aliphatic glycidyl ether or polypropylene glycol two shrink
Glycerin ether;
The thixotropic agent is fumed silica, polyethylene wax;
The pigment is carbon black, phthalocyanine blue or graphite;
The auxiliary agent is at least one of dispersing agent 501, defoaming agent 385N, the poly- glutamine wax of thixotropic agent, levelling agent 837;
The filler is at least one of blanc fixe, talcum powder or mica powder;When filler is blanc fixe, talcum
When the mixture of powder, the parts by weight of blanc fixe and talcum powder are respectively 7 ~ 8 parts and 5 ~ 7 parts, and granularity is 800 ~ 1250
Mesh;
The rust resisting pigment is the mixture of aluminum phosphate, polyaniline, aluminium triphosphate;
The curing agent A is modified fatty amine, and curing agent B is modified aromatic amine;
The glass flake is the mixture of 80 mesh, 120 mesh, 300 mesh;
Anticorrosive paint primary coat is the preparation method comprises the following steps: part bisphenol A epoxide resin and amount of activated diluent are uniformly mixed;It is added
Auxiliary agent keeps revolving speed 1000r/min stirring in high speed disperser, stands after stirring 0.5h;Then liquid material is squeezed into horizontal
In sand mill, kept for 50 ~ 60 DEG C of sand mill cavity temperature, fineness of grind is stand-by to releasing after 50 μm;
Remaining bisphenol A epoxide resin is uniformly mixed with pigment, filler and rust resisting pigment, revolving speed is kept in high speed disperser
1000r/min stirs 0.5h;Liquid slurry is squeezed into horizontal sand mill, fineness of grind to 50 μm of releasings;Liquid slurry is set
In in high speed disperser, revolving speed 500r/min is kept, glass flake is added gradually in slurry;After addition, it will disperse
Agent revolving speed keeps 1000r/min, stirs 0.5h;The liquid material got ready before is added in the slurry mixed up, is stirred 20 minutes,
Revolving speed keeps 800r/min;Adjusting viscosity using remaining reactive diluent is 0.8Pa.s, and finished product anticorrosive paint can be obtained
Basecoat material.
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EP2850139B1 (en) * | 2012-05-16 | 2019-05-15 | Université de Haute Alsace | Radiation radically and cationically curable composition, and method for preparing a hybrid sol-gel layer on a surface of a substrate using said composition |
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CN105086774B (en) * | 2015-08-20 | 2019-02-19 | 成都拜迪新材料有限公司 | The preparation method of low VOC composite coating applied to heavy antisepsis field |
CN105111887B (en) * | 2015-09-14 | 2018-05-15 | 廊坊市京龙防腐工程有限公司 | A kind of solventless epoxy coating and its preparation, application method |
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