CN106957507A - It is a kind of for energy-saving rubber of tire and preparation method thereof - Google Patents
It is a kind of for energy-saving rubber of tire and preparation method thereof Download PDFInfo
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- CN106957507A CN106957507A CN201710199297.2A CN201710199297A CN106957507A CN 106957507 A CN106957507 A CN 106957507A CN 201710199297 A CN201710199297 A CN 201710199297A CN 106957507 A CN106957507 A CN 106957507A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2353/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2415/00—Characterised by the use of rubber derivatives
- C08J2415/02—Rubber derivatives containing halogen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
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Abstract
The present invention provides a kind of for energy-saving rubber of tire and preparation method thereof, and its composition includes rubber, macromolecule self sealss polymeric gel, chlorinated natural rubber, plasticizer, age resistor, antioxidant, vulcanizing agent, activating agent and carbon black.The present invention prepares mentioned component by a series of processing, obtained rubber tyre, with anti ageing property well, energy-conservation subtracts material, anti-wear performance is good, heat is relatively low and elastic moderate, is not likely to produce gas leakage, noise or the excessive situation of elasticity, improves the security performance in vehicle traveling process.
Description
Technical field
The invention belongs to automobile tire manufacturing technology field, and in particular to a kind of energy-saving rubber and its preparation for tire
Method.
Background technology
Tire is the annular elastic rubber product rolled in various vehicles or the ground connection mechanically assembled.It is typically mounted on
On metal wheel hub, vehicle body can be supported, foreign impacts are buffered, the contact with road surface is realized and ensures the driving performance of vehicle.Tire
Often used under complicated and exacting terms, it subjects various modifications, load, power and high temperature action in motion, therefore,
Must just there are higher load-carrying properties, hauling ability, shock-absorbing capacity.Meanwhile, also require possess high-wearing feature and flexible resistance, with
And low rolling resistance and heat generation.The world consumes rubber mass and is generally used for tire production, it is seen that tire consumes the energy of rubber
Power.
The Tire production industry of China is started late, about before and after 1987 introduce Italian Pi Lieli, Britain Deng
Lu Pu and U.S.'s Firestone technology.Digesting and assimilating and improving for the whole nation major tire manufacturing company experience decades, obtains and flies
Speed development, but the high speed durability level of tire is still less desirable.Present rubber raw materials complicated difficult is obtained, and price is higher,
The compound physical poor-performing prepared, accordingly, it would be desirable to which a kind of more preferable method for preparing rubber reaches that energy-conservation subtracts the effect of material
Really, the deficiencies in the prior art are improved.
The content of the invention
It is an object of the invention to provide a kind of for energy-saving rubber of tire and preparation method thereof, rubber produced by the present invention
Tire, with anti ageing property well, energy-conservation subtracts material, and anti-wear performance is good, heat is relatively low and elastic moderate, is not likely to produce Lou
Gas, noise or the excessive situation of elasticity, improve the security performance in vehicle traveling process.
The invention provides following technical scheme:
A kind of energy-saving rubber for tire, includes the raw material of following parts by weight:10-18 parts of rubber, macromolecule self sealss polymerization
20-27 parts of glue, 15-25 parts of chlorinated natural rubber, 10-20 parts of plasticizer, 13-19 parts of age resistor, 12-17 parts of antioxidant, sulphur
12-22 parts of 11-16 parts of agent, 8-15 parts of activating agent and carbon black.
It is preferred that, it is described to include the raw material of following parts by weight:13-16 parts of rubber, macromolecule self sealss polymeric gel 22-25
Part, 18-22 parts of chlorinated natural rubber, 12-17 parts of plasticizer, 15-19 parts of age resistor, 15-17 parts of antioxidant, vulcanizing agent 13-
14-20 parts of 15 parts, 10-14 parts of activating agent and carbon black.
It is preferred that, it is described to include the raw material of following parts by weight:15 parts of rubber, 24 parts of macromolecule self sealss polymeric gel, chlorination
21 parts of natural rubber, 16 parts of plasticizer, 17 parts of age resistor, 15 parts of antioxidant, 15 parts of vulcanizing agent, 12 parts of activating agent and carbon black 18
Part.
It is preferred that, the synthetic rubber is the one or more in butadiene-styrene rubber, cis-butadiene cement and butyl rubber, and the cost of material is low for this
It is honest and clean, wide material sources, it is easy to process.
It is preferred that, the macromolecule self sealss polymeric gel is by styrene analog thermoplastic elastomer, relative molecular mass
500-1500 thermoplastic polymer resin, catalyst and filler composition, the polymeric gel plasticity that the material is prepared is good,
It is easy to the processing in preparation process of the present invention.
A kind of preparation method of energy-saving rubber for tire, comprises the following steps:
Step 1: rubber, macromolecule self sealss polymeric gel, chlorinated natural rubber and carbon black are well mixed, at 500-800 DEG C
Rubber is melted in heating, is stirred 20-30min, obtains mixed rubber;
Step 2: plasticizer, age resistor, antioxidant, vulcanizing agent and activating agent are put into the mixed rubber of step one, enter
Row heats and stirs 40-60min, and heating-up temperature is 200-400 DEG C, and mixing speed is less than 20r/min;
Step 3: step 2 product is heated into 10-15min at 100-150 DEG C, the bubble in step 2 product is excluded;
Step 4: step 3 product is poured into mould, cooling shaping.
It is preferred that, one layer of primary coat glue is sprayed after the step 4 cooling shaping again, is conducive to increasing the anti-wear performance of rubber
And antioxygenic property.
It is preferred that, the primary coat glue is the organic solution using chlorinated alkenes as solute, and the lower cost for material is conducive to drop
Low preparation cost, energy-conservation subtracts material.
The beneficial effects of the invention are as follows:
The macromolecule self sealss polymeric gel that the present invention is used has fine plasticity, and its compounded rubber composition prepared has
Higher wear-resisting, resistance to elevated temperatures, and this material manufacture is with low cost, and material cost performance is high.
The primary coat glue that the present invention is added is conducive to strengthening each performance of rubber for tire, makes its more durable, durable, equivalent to
The layer protecting film of product, extends the life-span of product, and it is prepared simply, with low cost.
Rubber tyre produced by the present invention, with anti ageing property well, energy-conservation subtracts material, anti-wear performance is good, heat compared with
It is low and elastic moderate, gas leakage, noise or the excessive situation of elasticity are not likely to produce, the security in vehicle traveling process is improved
Energy.
Embodiment
Embodiment 1
A kind of energy-saving rubber for tire, includes the raw material of following parts by weight:18 parts of rubber, macromolecule self sealss polymeric gel 27
Part, 25 parts of chlorinated natural rubber, 20 parts of plasticizer, 19 parts of age resistor, 17 parts of antioxidant, 16 parts of vulcanizing agent, 15 parts of activating agent
With 22 parts of carbon black.
Synthetic rubber is made up of butadiene-styrene rubber, cis-butadiene cement and butyl rubber, the lower cost for material, wide material sources, it is easy to plus
Work.
Macromolecule self sealss polymeric gel is by styrene analog thermoplastic elastomer, the thermoplastic that relative molecular mass is 500-1500
Property fluoropolymer resin, catalyst and filler composition, the polymeric gel plasticity that the material is prepared is good, it is easy to prepared by the present invention
During processing.
A kind of preparation method of energy-saving rubber for tire, comprises the following steps:
Step 1: rubber, macromolecule self sealss polymeric gel, chlorinated natural rubber and carbon black are well mixed, heated at 800 DEG C
Rubber is melted, 30min is stirred, mixed rubber is obtained;
Step 2: plasticizer, age resistor, antioxidant, vulcanizing agent and activating agent are put into the mixed rubber of step one, enter
Row heats and stirs 60min, and heating-up temperature is 400 DEG C, and mixing speed is less than 20r/min;
Step 3: step 2 product is heated into 15min at 150 DEG C, the bubble in step 2 product is excluded;
Step 4: step 3 product is poured into mould, cooling shaping.
One layer of primary coat glue is sprayed after step 4 cooling shaping again, is conducive to increasing the anti-wear performance and inoxidizability of rubber
Energy.
Primary coat glue is the organic solution using chlorinated alkenes as solute, and the lower cost for material advantageously reduces preparation cost,
Energy-conservation subtracts material.
Embodiment 2
A kind of energy-saving rubber for tire, includes the raw material of following parts by weight:10 parts of rubber, macromolecule self sealss polymeric gel 20
Part, 15 parts of chlorinated natural rubber, 10 parts of plasticizer, 13 parts of age resistor, 12 parts of antioxidant, 11 parts of vulcanizing agent, 8 parts of activating agent and
12 parts of carbon black.
Synthetic rubber is made up of cis-butadiene cement and butyl rubber, the lower cost for material, wide material sources, it is easy to process.
Macromolecule self sealss polymeric gel is by styrene analog thermoplastic elastomer, the thermoplastic poly that relative molecular mass is 500
Polymer resin, catalyst and filler composition, the polymeric gel plasticity that the material is prepared are good, it is easy to preparation process of the present invention
In processing.
A kind of preparation method of energy-saving rubber for tire, comprises the following steps:
Step 1: rubber, macromolecule self sealss polymeric gel, chlorinated natural rubber and carbon black are well mixed, heated at 500 DEG C
Rubber is melted, 20min is stirred, mixed rubber is obtained;
Step 2: plasticizer, age resistor, antioxidant, vulcanizing agent and activating agent are put into the mixed rubber of step one, enter
Row heats and stirs 40min, and heating-up temperature is 200 DEG C, and mixing speed is less than 20r/min;
Step 3: step 2 product is heated into 10min at 100 DEG C, the bubble in step 2 product is excluded;
Step 4: step 3 product is poured into mould, cooling shaping.
One layer of primary coat glue is sprayed after step 4 cooling shaping again, is conducive to increasing the anti-wear performance and inoxidizability of rubber
Energy.
Primary coat glue is the organic solution using chlorinated alkenes as solute, and the lower cost for material advantageously reduces preparation cost,
Energy-conservation subtracts material.
Embodiment 3
A kind of energy-saving rubber for tire, includes the raw material of following parts by weight:15 parts of rubber, macromolecule self sealss polymeric gel 24
Part, 21 parts of chlorinated natural rubber, 16 parts of plasticizer, 17 parts of age resistor, 15 parts of antioxidant, 15 parts of vulcanizing agent, 12 parts of activating agent
With 18 parts of carbon black.
Synthetic rubber is made up of butadiene-styrene rubber and butyl rubber, the lower cost for material, wide material sources, it is easy to process.
Macromolecule self sealss polymeric gel is by styrene analog thermoplastic elastomer, the thermoplastic poly that relative molecular mass is 500
Polymer resin, catalyst and filler composition, the polymeric gel plasticity that the material is prepared are good, it is easy to preparation process of the present invention
In processing.
A kind of preparation method of energy-saving rubber for tire, comprises the following steps:
Step 1: rubber, macromolecule self sealss polymeric gel, chlorinated natural rubber and carbon black are well mixed, heated at 800 DEG C
Rubber is melted, 20min is stirred, mixed rubber is obtained;
Step 2: plasticizer, age resistor, antioxidant, vulcanizing agent and activating agent are put into the mixed rubber of step one, enter
Row heats and stirs 60min, and heating-up temperature is 200 DEG C, and mixing speed is less than 20r/min;
Step 3: step 2 product is heated into 15min at 100 DEG C, the bubble in step 2 product is excluded;
Step 4: step 3 product is poured into mould, cooling shaping.
One layer of primary coat glue is sprayed after step 4 cooling shaping again, is conducive to increasing the anti-wear performance and inoxidizability of rubber
Energy.
Primary coat glue is the organic solution using chlorinated alkenes as solute, and the lower cost for material advantageously reduces preparation cost,
Energy-conservation subtracts material.
Embodiment 4
A kind of energy-saving rubber for tire, includes the raw material of following parts by weight:13 parts of rubber, macromolecule self sealss polymeric gel 25
Part, 18 parts of chlorinated natural rubber, 17 parts of plasticizer, 15 parts of age resistor, 17 parts of antioxidant, 13 parts of vulcanizing agent, 14 parts of activating agent
With 14 parts of carbon black.
Synthetic rubber is made up of cis-butadiene cement and butyl rubber, the lower cost for material, wide material sources, it is easy to process.
Macromolecule self sealss polymeric gel is by styrene analog thermoplastic elastomer, the thermoplastic poly that relative molecular mass is 1500
Polymer resin, catalyst and filler composition, the polymeric gel plasticity that the material is prepared are good, it is easy to preparation process of the present invention
In processing.
A kind of preparation method of energy-saving rubber for tire, comprises the following steps:
Step 1: rubber, macromolecule self sealss polymeric gel, chlorinated natural rubber and carbon black are well mixed, heated at 800 DEG C
Rubber is melted, 30min is stirred, mixed rubber is obtained;
Step 2: plasticizer, age resistor, antioxidant, vulcanizing agent and activating agent are put into the mixed rubber of step one, enter
Row heats and stirs 60min, and heating-up temperature is 400 DEG C, and mixing speed is less than 20r/min;
Step 3: step 2 product is heated into 15min at 150 DEG C, the bubble in step 2 product is excluded;
Step 4: step 3 product is poured into mould, cooling shaping.
One layer of primary coat glue is sprayed after step 4 cooling shaping again, is conducive to increasing the anti-wear performance and inoxidizability of rubber
Energy.
Primary coat glue is the organic solution using chlorinated alkenes as solute, and the lower cost for material advantageously reduces preparation cost,
Energy-conservation subtracts material.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, although with reference to foregoing reality
Apply example the present invention is described in detail, for a person skilled in the art, it still can be to foregoing each implementation
Technical scheme described in example is modified, or carries out equivalent to which part technical characteristic.All essences in the present invention
God is with principle, and any modifications, equivalent substitutions and improvements made etc. should be included within the scope of the present invention.
Claims (8)
1. a kind of energy-saving rubber for tire, it is characterised in that include the raw material of following parts by weight:10-18 parts of rubber, high score
It is sub- 20-27 parts of self sealss polymeric gel, 15-25 parts of chlorinated natural rubber, 10-20 parts of plasticizer, 13-19 parts of age resistor, anti-oxidant
12-22 parts of 12-17 parts of agent, 11-16 parts of vulcanizing agent, 8-15 parts of activating agent and carbon black.
2. a kind of energy-saving rubber for tire according to claim 1, it is characterised in that include the original of following parts by weight
Material:It is 13-16 parts of rubber, 22-25 parts of macromolecule self sealss polymeric gel, 18-22 parts of chlorinated natural rubber, 12-17 parts of plasticizer, anti-
14-20 parts of old agent 15-19 parts, 15-17 parts of antioxidant, 13-15 parts of vulcanizing agent, 10-14 parts of activating agent and carbon black.
3. a kind of energy-saving rubber for tire according to claim 1, it is characterised in that include the original of following parts by weight
Material:It is 15 parts of rubber, 24 parts of macromolecule self sealss polymeric gel, 21 parts of chlorinated natural rubber, 16 parts of plasticizer, 17 parts of age resistor, anti-
18 parts of 15 parts of oxidant, 15 parts of vulcanizing agent, 12 parts of activating agent and carbon black.
4. a kind of energy-saving rubber for tire according to claim 1, it is characterised in that the synthetic rubber is butylbenzene
One or more in glue, cis-butadiene cement and butyl rubber.
5. a kind of energy-saving rubber for tire according to claim 1, it is characterised in that the macromolecule self sealss gather
Rubber alloy is 500-1500 thermoplastic polymer resin by styrene analog thermoplastic elastomer, relative molecular mass, catalyst and
Filler is constituted.
6. a kind of preparation method of energy-saving rubber for tire described in claim any one of 1-5, it is characterised in that including
Following steps:
Step 1: rubber, macromolecule self sealss polymeric gel, chlorinated natural rubber and carbon black are well mixed, at 500-800 DEG C
Rubber is melted in heating, is stirred 20-30min, obtains mixed rubber;
Step 2: plasticizer, age resistor, antioxidant, vulcanizing agent and activating agent are put into the mixed rubber of step one, enter
Row heats and stirs 40-60min, and heating-up temperature is 200-400 DEG C, and mixing speed is less than 20r/min;
Step 3: step 2 product is heated into 10-15min at 100-150 DEG C, the bubble in step 2 product is excluded;
Step 4: step 3 product is poured into mould, cooling shaping.
7. a kind of preparation method of energy-saving rubber for tire according to claim 6, it is characterised in that the step
One layer of primary coat glue is sprayed after four cooling shapings again.
8. a kind of preparation method of energy-saving rubber for tire according to claim 7, it is characterised in that the primary coat
Glue is the organic solution using chlorinated alkenes as solute.
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CN201710199297.2A CN106957507A (en) | 2017-03-29 | 2017-03-29 | It is a kind of for energy-saving rubber of tire and preparation method thereof |
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CN201710199297.2A CN106957507A (en) | 2017-03-29 | 2017-03-29 | It is a kind of for energy-saving rubber of tire and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108623870A (en) * | 2018-05-07 | 2018-10-09 | 佛山市万善环保科技有限公司 | A kind of tire special graphite alkene modified rubber composite modification material and preparation method thereof |
CN109233030A (en) * | 2018-09-04 | 2019-01-18 | 潍坊市跃龙橡胶有限公司 | A kind of high-temperature resistant rubber tire and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103450516A (en) * | 2013-08-02 | 2013-12-18 | 山东永泰化工集团有限公司 | Rubber tire tread and milling process thereof |
CN104626882A (en) * | 2013-11-15 | 2015-05-20 | 洛阳骏腾能源科技有限公司 | Anti-leakage, noise-prevention and bulletproof automobile tire and manufacturing method thereof |
-
2017
- 2017-03-29 CN CN201710199297.2A patent/CN106957507A/en not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103450516A (en) * | 2013-08-02 | 2013-12-18 | 山东永泰化工集团有限公司 | Rubber tire tread and milling process thereof |
CN104626882A (en) * | 2013-11-15 | 2015-05-20 | 洛阳骏腾能源科技有限公司 | Anti-leakage, noise-prevention and bulletproof automobile tire and manufacturing method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108623870A (en) * | 2018-05-07 | 2018-10-09 | 佛山市万善环保科技有限公司 | A kind of tire special graphite alkene modified rubber composite modification material and preparation method thereof |
CN109233030A (en) * | 2018-09-04 | 2019-01-18 | 潍坊市跃龙橡胶有限公司 | A kind of high-temperature resistant rubber tire and preparation method thereof |
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