CN104626882A - Anti-leakage, noise-prevention and bulletproof automobile tire and manufacturing method thereof - Google Patents
Anti-leakage, noise-prevention and bulletproof automobile tire and manufacturing method thereof Download PDFInfo
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- CN104626882A CN104626882A CN201310574432.9A CN201310574432A CN104626882A CN 104626882 A CN104626882 A CN 104626882A CN 201310574432 A CN201310574432 A CN 201310574432A CN 104626882 A CN104626882 A CN 104626882A
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Abstract
The invention relates to an anti-leakage, noise-prevention and bulletproof automobile tire and a manufacturing method thereof. The surface of the inner wall of the anti-leakage, noise-prevention and bulletproof automobile tire is completely coated with a macromolecule self-seal polymerization glue anti-leakage layer the thickness of which is not less than 3.5mm, so that the anti-leakage, noise-prevention and bulletproof automobile tire is formed. The anti-leakage, noise-prevention and bulletproof automobile tire has excellent anti-leakage, noise-prevention and bulletproof effects, is mainly applied to civil vehicles, is also applied to military vehicles, and guarantees the driving safety of the vehicle; the manufacturing method is applied to manufacturing the anti-leakage, noise-prevention and bulletproof automobile tire, and is also applied to the upgrading and conversion into the manufacturing of the anti-leakage, noise-prevention and bulletproof automobile tire from the common automobile wheel tire.
Description
Technical field
The present invention relates to a kind of motor tire and preparation method thereof, specifically a kind of leakproof, noise control, bulletproof car tire and method for making.
Background technology
The motor tire of the military combat vehicle that current technology is produced, belong to tactical vehicle weakest link, the easy quilt attack of automotive wheels tire of tactical vehicle is worn and is pierced through by sharp object, be hit by a bullet, be attacked by an assassin prick after, occur to lose heart instantaneously, cause tactical vehicle to be in a kind of state of paralysis; If tactical vehicle running at high speed or above-mentioned leakage of tyre accident occurring under case of heavy load, then causes the maximum accident of car crash.
Add up according to domestic related data, the at present broken tire traffic accident caused of losing heart accounts for more than 42% of total traffic accident, and therefore the traffic accident caused of losing heart of broken tire is that numerous driver and crew pay close attention to the most or worry, is also one of traffic accident being difficult to most prevent.For this reason, found a kind of novel leakproof of development, bulletproof car tire, just have very important military significance and social effect.
Summary of the invention
For automobile in prior art easily broken tire lose heart and cause the problem of traffic accident, the invention provides a kind of leakproof, noise control, bulletproof car tire and method for making.
For solving the problems of the technologies described above, the technical solution used in the present invention is:
A kind of leakproof, noise control, bulletproof car tire, all scribble one deck silane coupling agent in motor tire inner wall surface, the surface scribbling silane coupling agent scribbles one deck Polymer self sealss polymeric gel application of anti-leakage layers, and the thickness of application of anti-leakage layers is not less than 3.5mm;
Described silane coupling agent is take chlorinated alkenes as the organic solution of solute, and chlorinated alkenes solute comprises haloflex, chlorinated isotactic polypropylene, maleic anhydride graft chlorinated polypropylene, chlorinated natural rubber etc., and wherein the content of chlorine element is between 20-40%; The solvent of chlorinated alkenes organic solution comprises aromatic hydrocarbons, esters solvent and ketones solvent and their compound; Esters solvent comprises ethyl acetate, butyl acetate, isobutyl acetate, isopropyl acetate, isoamyl acetate etc.; Ketones solvent comprises butanone, methyl isobutyl ketone, cyclohexanone; Aromatic solvent comprises toluene, dimethylbenzene; Chlorohydrocarbon comprises methenyl choloride, trichoroethylen, dichlorethane, trichloroethane etc.;
The key component of described Polymer self sealss polymeric gel according to percentage by weight is: styrene analog thermoplastic elastomer 30-38%, relative molecular weight are thermoplastic polymer resin 40-45%, the plasticising softening component 5-15% of 200-2000, anti-old antioxidant composition 1-2%, catalysed promoted component 0-2%, filling heatproof component 0-8%;
Described styrene analog thermoplastic elastomer is that SIS, SBS are mixed with one or more in SEBS; Relative molecular weight to be the thermoplastic polymer resin of 200-2000 be terpene resin, C5 petroleum resin, C5/C9 copolymerized petroleum resin, ester gum are mixed with one or more in coumarone indene resin; Described plasticising softening component is that plasticizer is mixed with one or both in soften flux, anti-old antioxidant composition is that aging inhibitor is mixed with one or both in antioxidant, catalysed promoted component is that catalyst is mixed with one or both in accelerator, and filling heatproof component is that extending agent is mixed with one or both in refractory agent;
Described plasticizer is that dioctyl phthalate, diisobutyl phthalate, diisooctyl phthalate, BBP(Butyl Benzyl Phthalate are mixed with one or more in dibutyl phthalate; Described soften flux is that naphthenic oil, 40# machine oil are mixed with one or more in aromatic naphtha; Described aging inhibitor be SP, 4010,4010NA is mixed with one or more in 4020; Described antioxidant is 300,1010,1076 mixed with one or more in 264; Described catalyst is that N methyldiethanol amine is mixed with one or both in METHYLPYRROLIDONE; Described accelerator is that PX, BZ are mixed with one or more in diethyl thiourea; Described extending agent is that silica flour, aluminium hydroxide are mixed with one or more in silica powder; Described refractory agent is that nano-calcium carbonate is mixed with one or both in nano-graphite.
A method for making for leakproof, noise control, bulletproof car tire, comprises the following steps:
Step one: check brand-new motor tire, should meet the relevant criterion requirement of motor tire;
Step 2: utilize motor tire inner wall surface cleaning machine and motor tire purging medium, clean the motor tire inner wall surface of passed examination, in light-illuminating situation, visual inspection is without bright spot;
Step 3: utilize hot-air heater that the motor tire inner wall surface cleaned up is heated to 50-80 DEG C;
Step 4: utilize motor tire silane coupling agent flush coater all to spray to the motor tire inner wall surface after heating the silane coupling agent that a layer thickness is 0.1-0.2mm, this silane coupling agent is take chlorinated alkenes as the organic solution of solute;
Step 5: utilize motor tire hot melt glue sprayer and Polymer self sealss polymeric gel or rubber powder, all sprays to the motor tire inner wall surface after linging the Polymer self sealss polymeric gel application of anti-leakage layers that a layer thickness is not less than 3.5mm by after polymeric gel or rubber powder hot melt;
Step 6: utilize motor tire inwall cooler, carries out cooling curing to the Polymer self sealss polymeric gel application of anti-leakage layers of motor tire inner wall surface;
Step 7: utilize organic protective agent flush coater and organic protective agent, all sprays one deck methyl-silicone oil organic protective agent to the motor tire inner wall surface with Polymer self sealss polymeric gel application of anti-leakage layers, obtains leakproof, noise control, bulletproof car tire.
A method for making for leakproof, noise control, bulletproof car tire, comprises the following steps:
Step one: utilize automotive wheels handling tool, automotive wheels is unloaded from automobile;
Step 2: utilize automotive wheels kinetic balance adjusting machine, to the calibration testing of automotive wheels kinetic balance, and records its data;
Step 3: bleed off the gas medium in automotive wheels, and utilize automotive wheels resolving device that automotive wheels is resolved into automotive hub and motor tire;
Step 4: utilize motor tire inner wall surface cleaning machine and motor tire purging medium, motor tire inner wall surface is cleaned, and in light-illuminating situation, visual inspection is without bright spot;
Step 5: utilize hot-air heater that the motor tire inner wall surface cleaned up is heated to 50-80 DEG C;
Step 6: utilize motor tire silane coupling agent flush coater all to spray to the motor tire inner wall surface after heating the silane coupling agent that a layer thickness is 0.1-0.2mm, this silane coupling agent is take chlorinated alkenes as the organic solution of solute;
Step 7: utilize motor tire hot melt glue sprayer and Polymer self sealss polymeric gel or rubber powder, all sprays to the motor tire inner wall surface after linging the Polymer self sealss polymeric gel application of anti-leakage layers that a layer thickness is not less than 3.5mm by after polymeric gel or rubber powder hot melt;
Step 8: utilize motor tire inwall cooler, to the Polymer self sealss polymeric gel application of anti-leakage layers of motor tire inner wall surface, carries out cooling curing;
Step 9: utilize organic protective agent flush coater and organic protective agent, all sprays one deck methyl-silicone oil organic protective agent to the motor tire inner wall surface with Polymer self sealss polymeric gel application of anti-leakage layers, obtains leakproof, noise control, bulletproof car tire;
Step 10: utilize automotive wheels mounting equipment that automotive hub and motor tire are assembled into automotive wheels, and filling gas medium is to specifying tire pressure;
Step 11: utilize automotive wheels kinetic balance adjusting machine, to the calibration testing of automotive wheels kinetic balance, and records its data, more unchanged with the data of step 2 record;
Step 12: the automotive wheels after calibration is loaded onto automobile, namely completes the conversion of conventional tyre.Beneficial effect of the present invention:
(1) the Polymer self sealss polymeric gel spray car tire inner wall surface of the present invention's employing, after cold formed, form the highdensity flexible glue of a kind of Polymer, there is superior elasticity and ductility, in high vehicle speeds process, its coating not easily departs from motor tire inwall crown type surface, the kinetic balance of automotive wheels can not be changed, do not increase the shock momentum in vehicle travel process, the effect of noise control can be played;
(2) motor tire provided by the invention, after tire is thrust from automotive wheels tyre surface by sharp object (such as spike, blade, cullet etc.), the highdensity Polymer flexible glue layer of tire inner wall, under the effect of automotive wheels internal gas pressure, close penetrator, implement automatically to glue to wrap up in sealing to penetrator, reach the function preventing motor tire gas leak, improve vehicle driving safety;
(3) motor tire provided by the invention, when motor tire is by sharp object (such as spike, blade, cullet etc.) thrust from automotive wheels tyre surface after, at the high resiliency of Polymer self sealss polymerization glue-line, under deep drawing quality and high-tensile effect, when penetrator be pulled out or Automatic-falling time, the moment resilience of Polymer self sealss polymeric gel is shunk, automatically close motor tire under gas pressure in automotive wheels and poke place, the repaired filling of leak of motor tire, closed blocking, reach the function preventing gas leak in motor tire, improve vehicle driving safety,
(4) the Polymer self sealss polymeric gel of the present invention's employing, for making the sulfuric horizon thickening motor tire, plays certain explosion-proof to it.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the present invention is further elaborated.
A kind of leakproof, noise control, bulletproof car tire, all scribble one deck silane coupling agent in motor tire inner wall surface, the surface scribbling silane coupling agent scribbles one deck Polymer self sealss polymeric gel application of anti-leakage layers, and the thickness of application of anti-leakage layers is not less than 3.5mm;
Described silane coupling agent is take chlorinated alkenes as the organic solution of solute, and chlorinated alkenes solute comprises haloflex, chlorinated isotactic polypropylene, maleic anhydride graft chlorinated polypropylene, chlorinated natural rubber etc., and wherein the content of chlorine element is between 20-40%; The solvent of chlorinated alkenes organic solution comprises aromatic hydrocarbons, esters solvent and ketones solvent and their compound; Esters solvent comprises ethyl acetate, butyl acetate, isobutyl acetate, isopropyl acetate, isoamyl acetate etc.; Ketones solvent comprises butanone, methyl isobutyl ketone, cyclohexanone; Aromatic solvent comprises toluene, dimethylbenzene; Chlorohydrocarbon comprises methenyl choloride, trichoroethylen, dichlorethane, trichloroethane etc.;
The key component of described Polymer self sealss polymeric gel according to percentage by weight is: styrene analog thermoplastic elastomer 30-38%, relative molecular weight are thermoplastic polymer resin 40-45%, the plasticising softening component 5-15% of 200-2000, anti-old antioxidant composition 1-2%, catalysed promoted component 0-2%, filling heatproof component 0-8%;
Described styrene analog thermoplastic elastomer is that SIS, SBS are mixed with one or more in SEBS; Relative molecular weight to be the thermoplastic polymer resin of 200-2000 be terpene resin, C5 petroleum resin, C5/C9 copolymerized petroleum resin, ester gum are mixed with one or more in coumarone indene resin; Described plasticising softening component is that plasticizer is mixed with one or both in soften flux, anti-old antioxidant composition is that aging inhibitor is mixed with one or both in antioxidant, catalysed promoted component is that catalyst is mixed with one or both in accelerator, and filling heatproof component is that extending agent is mixed with one or both in refractory agent;
Described plasticizer is that dioctyl phthalate, diisobutyl phthalate, diisooctyl phthalate, BBP(Butyl Benzyl Phthalate are mixed with one or more in dibutyl phthalate; Described soften flux is that naphthenic oil, 40# machine oil are mixed with one or more in aromatic naphtha; Described aging inhibitor be SP, 4010,4010NA is mixed with one or more in 4020; Described antioxidant is 300,1010,1076 mixed with one or more in 264; Described catalyst is that N methyldiethanol amine is mixed with one or both in METHYLPYRROLIDONE; Described accelerator is that PX, BZ are mixed with one or more in diethyl thiourea; Described extending agent is that silica flour, aluminium hydroxide are mixed with one or more in silica powder; Described refractory agent is that nano-calcium carbonate is mixed with one or both in nano-graphite.
A method for making for leakproof, noise control, bulletproof car tire, comprises the following steps:
Step one: check brand-new motor tire, should meet the relevant criterion requirement of motor tire;
Step 2: utilize motor tire inner wall surface cleaning machine and motor tire purging medium, clean the motor tire inner wall surface of passed examination, in light-illuminating situation, visual inspection is without bright spot;
Step 3: utilize hot-air heater that the motor tire inner wall surface cleaned up is heated to 50-80 DEG C;
Step 4: utilize motor tire silane coupling agent flush coater all to spray to the motor tire inner wall surface after heating the silane coupling agent that a layer thickness is 0.1-0.2mm, this silane coupling agent is take chlorinated alkenes as the organic solution of solute;
Step 5: utilize motor tire hot melt glue sprayer and Polymer self sealss polymeric gel or rubber powder, all sprays to the motor tire inner wall surface after linging the Polymer self sealss polymeric gel application of anti-leakage layers that a layer thickness is not less than 3.5mm by after polymeric gel or rubber powder hot melt;
Step 6: utilize motor tire inwall cooler, carries out cooling curing to the Polymer self sealss polymeric gel application of anti-leakage layers of motor tire inner wall surface;
Step 7: utilize organic protective agent flush coater and organic protective agent, all sprays one deck methyl-silicone oil organic protective agent to the motor tire inner wall surface with Polymer self sealss polymeric gel application of anti-leakage layers, obtains leakproof, noise control, bulletproof car tire.
A method for making for leakproof, noise control, bulletproof car tire, comprises the following steps:
Step one: utilize automotive wheels handling tool, automotive wheels is unloaded from automobile;
Step 2: utilize automotive wheels kinetic balance adjusting machine, to the calibration testing of automotive wheels kinetic balance, and records its data;
Step 3: bleed off the gas medium in automotive wheels, and utilize automotive wheels resolving device that automotive wheels is resolved into automotive hub and motor tire;
Step 4: utilize motor tire inner wall surface cleaning machine and motor tire purging medium, motor tire inner wall surface carries out cleaning, in light-illuminating situation, visual inspection is without bright spot;
Step 5: utilize hot-air heater that the motor tire inner wall surface cleaned up is heated to 50-80 DEG C;
Step 6: utilize motor tire silane coupling agent flush coater all to spray to the motor tire inner wall surface after heating the silane coupling agent that a layer thickness is 0.1-0.2mm, this silane coupling agent is take chlorinated alkenes as the organic solution of solute;
Step 7: utilize motor tire hot melt glue sprayer and Polymer self sealss polymeric gel or rubber powder, all sprays to the motor tire inner wall surface after linging the Polymer self sealss polymeric gel application of anti-leakage layers that a layer thickness is not less than 3.5mm by after polymeric gel or rubber powder hot melt;
Step 8: utilize motor tire inwall cooler, to the Polymer self sealss polymeric gel application of anti-leakage layers of motor tire inner wall surface, carries out cooling curing;
Step 9: utilize organic protective agent flush coater and organic protective agent, all sprays one deck methyl-silicone oil organic protective agent to the motor tire inner wall surface with Polymer self sealss polymeric gel application of anti-leakage layers, obtains leakproof, noise control, bulletproof car tire;
Step 10: utilize automotive wheels mounting equipment that automotive hub and motor tire are assembled into automotive wheels, and filling gas medium is to specifying tire pressure;
Step 11: utilize automotive wheels kinetic balance adjusting machine, to the calibration testing of automotive wheels kinetic balance, and records its data, more unchanged with the data of step 2 record;
Step 12: the automotive wheels after calibration is loaded onto automobile, namely completes the conversion of conventional tyre.
Described styrene analog thermoplastic elastomer SIS is styrene-isoprene-styrene triblock copolymer; SBS is the periodic copolymer of styrene and butadidenne; SEBS is saturation type SBS, or title Hydrogenated SBS, be make double bond saturated and obtained by extraordinary type SBS hydrogenation, SBS is appropriate directed hydrogenation in the presence of a catalyst, then make polybutadiene segments be hydrogenated to polyethylene (E) and polybutene (B) chain drum, therefore be called SEBS;
Described antioxidant SP is also known as styrenated phenol; Antioxidant 4010 is also known as N-phenyl-N'-cyclohexyl p-phenylenediamine (PPD); Antioxidant 4010NA also known as N-isopropyl-N, diphenyl-para-phenylene diamine; Antioxidant 4020 is also known as N-(1,3-dimethylbutyl)-N'-diphenyl-para-phenylene diamine;
Described antioxidant 300 is β-positive octadecanol ester of (3,5-di-tert-butyl-hydroxy phenyl) propionic acid; Antioxidant 1010 is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester; Antioxidant 1076 is β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid octadecyl ester; Antioxidant 264 is BHT;
Accelerator PX is N-ethyl, N-phenyl zinc dithiocarbamate; Accelerant B Z is zinc dibutyl dithiocaarbamate.
Embodiment 1
A kind of leakproof, noise control, bulletproof car tire, all scribble one deck silane coupling agent haloflex ethyl acetate solution in motor tire inner wall surface, the surface scribbling silane coupling agent scribbles one deck Polymer self sealss polymeric gel application of anti-leakage layers, and the thickness of application of anti-leakage layers is 3.5mm;
The key component of described Polymer self sealss polymeric gel according to percentage by weight is: styrene analog thermoplastic elastomer SIS:33%, styrene analog thermoplastic elastomer SEBS:5%, thermoplastic polymer resin's terpene resin: 40%, plasticizer phthalic acid dioctyl ester: 5%, soften flux 40# machine oil: 5%, antioxidant SP: 1%, antioxidant 300:1%, catalyst n-methyldiethanolamine 1%, accelerator PX:1%, extending agent silica flour: 4%, refractory agent nano-calcium carbonate: 4%.
A method for making for leakproof, noise control, bulletproof car tire, comprises the following steps:
Step one: check brand-new motor tire, should meet the relevant criterion requirement of motor tire;
Step 2: utilize motor tire inner wall surface cleaning machine and motor tire purging medium, clean the motor tire inner wall surface of passed examination, in light-illuminating situation, visual inspection is without bright spot;
Step 3: utilize hot-air heater that the motor tire inner wall surface cleaned up is heated to 50 DEG C;
Step 4: utilize motor tire silane coupling agent flush coater all to spray to the motor tire inner wall surface after heating the silane coupling agent haloflex ethyl acetate solution that a layer thickness is 0.1mm;
Step 5: utilize motor tire hot melt glue sprayer and Polymer self sealss polymeric gel or rubber powder, all spray to the motor tire inner wall surface after linging the Polymer self sealss polymeric gel application of anti-leakage layers that a layer thickness is 3.5mm by after polymeric gel or rubber powder hot melt;
Step 6: utilize motor tire inwall cooler, carries out cooling curing to the Polymer self sealss polymeric gel application of anti-leakage layers of motor tire inner wall surface;
Step 7: utilize organic protective agent flush coater and organic protective agent, all sprays one deck methyl-silicone oil organic protective agent to the motor tire inner wall surface with Polymer self sealss polymeric gel application of anti-leakage layers, obtains leakproof, noise control, bulletproof car tire.
Embodiment 2
A kind of leakproof, noise control, bulletproof car tire, all scribble one deck silane coupling agent chlorinated isotactic polypropylene butanone solution in motor tire inner wall surface, the surface scribbling silane coupling agent scribbles one deck Polymer self sealss polymeric gel application of anti-leakage layers, and the thickness of application of anti-leakage layers is 4mm;
The key component of described Polymer self sealss polymeric gel according to percentage by weight is: styrene analog thermoplastic elastomer SBS:25%, styrene analog thermoplastic elastomer SEBS:5%, thermoplastic polymer resin C5 petroleum resin: 45%, plasticizer phthalic acid diisobutyl ester: 7.5%, soften flux naphthenic oil: 7.5%, antioxidant 4010: 1%, antioxidant 1010: 1%, extending agent aluminium hydroxide: 4%, refractory agent nano-graphite: 4%.
A method for making for leakproof, noise control, bulletproof car tire, comprises the following steps:
Step one: utilize automotive wheels handling tool, automotive wheels is unloaded from automobile;
Step 2: utilize automotive wheels kinetic balance adjusting machine, to the calibration testing of automotive wheels kinetic balance, and records its data;
Step 3: bleed off the gas medium in automotive wheels, and utilize automotive wheels resolving device that automotive wheels is resolved into automotive hub and motor tire;
Step 4: utilize motor tire inner wall surface cleaning machine and motor tire purging medium, motor tire inner wall surface is cleaned, and in light-illuminating situation, visual inspection is without bright spot;
Step 5: utilize hot-air heater that the motor tire inner wall surface cleaned up is heated to 60 DEG C;
Step 6: utilize motor tire silane coupling agent flush coater all to spray to the motor tire inner wall surface after heating the silane coupling agent chlorinated isotactic polypropylene butanone solution that a layer thickness is 0.2mm;
Step 7: utilize motor tire hot melt glue sprayer and Polymer self sealss polymeric gel or rubber powder, all spray to the motor tire inner wall surface after linging the Polymer self sealss polymeric gel application of anti-leakage layers that a layer thickness is 4mm by after polymeric gel or rubber powder hot melt;
Step 8: utilize motor tire inwall cooler, to the Polymer self sealss polymeric gel application of anti-leakage layers of motor tire inner wall surface, carries out cooling curing;
Step 9: utilize organic protective agent flush coater and organic protective agent, all sprays one deck methyl-silicone oil organic protective agent to the motor tire inner wall surface with Polymer self sealss polymeric gel application of anti-leakage layers, obtains leakproof, noise control, bulletproof car tire;
Step 10: utilize automotive wheels mounting equipment that automotive hub and motor tire are assembled into automotive wheels, and filling gas medium is to specifying tire pressure;
Step 11: utilize automotive wheels kinetic balance adjusting machine, to the calibration testing of automotive wheels kinetic balance, and records its data, more unchanged with the data of step 2 record;
Step 12: the automotive wheels after calibration is loaded onto automobile, namely completes the conversion of conventional tyre.
Embodiment 3
A kind of leakproof, noise control, bulletproof car tire, one deck silane coupling agent maleic anhydride graft chlorinated polypropylene dichloroethane solution is all scribbled in motor tire inner wall surface, the surface scribbling silane coupling agent scribbles one deck Polymer self sealss polymeric gel application of anti-leakage layers, and the thickness of application of anti-leakage layers is 4.5mm;
The key component of described Polymer self sealss polymeric gel according to percentage by weight is: styrene analog thermoplastic elastomer SIS:33%, styrene analog thermoplastic elastomer SBS:2.5%, styrene analog thermoplastic elastomer SEBS:2.5%, thermoplastic polymer resin C5/C9 copolymerized petroleum resin: 42%, plasticizer phthalic acid di-isooctyl: 5%, soften flux aromatic naphtha: 5%, antioxidant SP: 1%, catalyst n-N-methyl-2-2-pyrrolidone N-: 1%, extending agent silica powder: 4%, refractory agent nano-calcium carbonate: 4%.
A method for making for leakproof, noise control, bulletproof car tire, comprises the following steps:
Step one: check brand-new motor tire, should meet the relevant criterion requirement of motor tire;
Step 2: utilize motor tire inner wall surface cleaning machine and motor tire purging medium, clean the motor tire inner wall surface of passed examination, in light-illuminating situation, visual inspection is without bright spot;
Step 3: utilize hot-air heater that the motor tire inner wall surface cleaned up is heated to 70 DEG C;
Step 4: utilize motor tire silane coupling agent flush coater all to spray to the motor tire inner wall surface after heating the silane coupling agent maleic anhydride graft chlorinated polypropylene dichloroethane solution that a layer thickness is 0.1mm;
Step 5: utilize motor tire hot melt glue sprayer and Polymer self sealss polymeric gel or rubber powder, all spray to the motor tire inner wall surface after linging the Polymer self sealss polymeric gel application of anti-leakage layers that a layer thickness is 4.5mm by after polymeric gel or rubber powder hot melt;
Step 6: utilize motor tire inwall cooler, carries out cooling curing to the Polymer self sealss polymeric gel application of anti-leakage layers of motor tire inner wall surface;
Step 7: utilize organic protective agent flush coater and organic protective agent, all sprays one deck methyl-silicone oil organic protective agent to the motor tire inner wall surface with Polymer self sealss polymeric gel application of anti-leakage layers, obtains leakproof, noise control, bulletproof car tire.
Embodiment 4
A kind of leakproof, noise control, bulletproof car tire, one deck silane coupling agent chlorinated natural rubber isopropyl acetate solution is all scribbled in motor tire inner wall surface, the surface scribbling silane coupling agent scribbles one deck Polymer self sealss polymeric gel application of anti-leakage layers, and the thickness of application of anti-leakage layers is 3.5mm;
The key component of described Polymer self sealss polymeric gel according to percentage by weight is: styrene analog thermoplastic elastomer SIS:25%, styrene analog thermoplastic elastomer SBS:5%, thermoplastic polymer resin's ester gum: 45%, plasticizer phthalic acid butyl benzyl: 6.5%, soften flux aromatic naphtha: 6.5%, antioxidant 4020: 1%, antioxidant 264:1%, catalyst n-N-methyl-2-2-pyrrolidone N-: 1%, accelerant B Z:1%, extending agent aluminium hydroxide: 4%, refractory agent nano-graphite: 4%.
A method for making for leakproof, noise control, bulletproof car tire, comprises the following steps:
Step one: utilize automotive wheels handling tool, automotive wheels is unloaded from automobile;
Step 2: utilize automotive wheels kinetic balance adjusting machine, to the calibration testing of automotive wheels kinetic balance, and records its data;
Step 3: bleed off the gas medium in automotive wheels, and utilize automotive wheels resolving device that automotive wheels is resolved into automotive hub and motor tire;
Step 4: utilize motor tire inner wall surface cleaning machine and motor tire purging medium, motor tire inner wall surface is cleaned, and in light-illuminating situation, visual inspection is without bright spot;
Step 5: utilize hot-air heater that the motor tire inner wall surface cleaned up is heated to 80 DEG C;
Step 6: utilize motor tire silane coupling agent flush coater all to spray to the motor tire inner wall surface after heating the silane coupling agent chlorinated natural rubber isopropyl acetate solution that a layer thickness is 0.2mm;
Step 7: utilize motor tire hot melt glue sprayer and Polymer self sealss polymeric gel or rubber powder, all spray to the motor tire inner wall surface after linging the Polymer self sealss polymeric gel application of anti-leakage layers that a layer thickness is 3.5mm by after polymeric gel or rubber powder hot melt;
Step 8: utilize motor tire inwall cooler, to the Polymer self sealss polymeric gel application of anti-leakage layers of motor tire inner wall surface, carries out cooling curing;
Step 9: utilize organic protective agent flush coater and organic protective agent, all sprays one deck methyl-silicone oil organic protective agent to the motor tire inner wall surface with Polymer self sealss polymeric gel application of anti-leakage layers, obtains leakproof, noise control, bulletproof car tire;
Step 10: utilize automotive wheels mounting equipment that automotive hub and motor tire are assembled into automotive wheels, and filling gas medium is to specifying tire pressure;
Step 11: utilize automotive wheels kinetic balance adjusting machine, to the calibration testing of automotive wheels kinetic balance, and records its data, more unchanged with the data of step 2 record;
Step 12: the automotive wheels after calibration is loaded onto automobile, namely completes the conversion of conventional tyre.
Embodiment 5
A kind of leakproof, noise control, bulletproof car tire, all scribble one deck silane coupling agent haloflex cyclohexanone solution in motor tire inner wall surface, the surface scribbling silane coupling agent scribbles one deck Polymer self sealss polymeric gel application of anti-leakage layers, and the thickness of application of anti-leakage layers is 4mm;
The key component of described Polymer self sealss polymeric gel according to percentage by weight is: styrene analog thermoplastic elastomer SIS:34%, thermoplastic polymer resin's coumarone indene resin: 45%, soften flux 40# machine oil: 6.5%, plasticizer phthalic acid dibutyl ester: 6.5%, antioxidant 4010NA: 1%, antioxidant 1076:1%, catalyst n-methyldiethanolamine: 2%, extending agent silica flour: 4%.
A method for making for leakproof, noise control, bulletproof car tire, comprises the following steps:
Step one: check brand-new motor tire, should meet the relevant criterion requirement of motor tire;
Step 2: utilize motor tire inner wall surface cleaning machine and motor tire purging medium, clean the motor tire inner wall surface of passed examination, in light-illuminating situation, visual inspection is without bright spot;
Step 3: utilize hot-air heater that the motor tire inner wall surface cleaned up is heated to 60 DEG C;
Step 4: utilize motor tire silane coupling agent flush coater all to spray to the motor tire inner wall surface after heating the silane coupling agent haloflex cyclohexanone solution that a layer thickness is 0.1mm;
Step 5: utilize motor tire hot melt glue sprayer and Polymer self sealss polymeric gel or rubber powder, all spray to the motor tire inner wall surface after linging the Polymer self sealss polymeric gel application of anti-leakage layers that a layer thickness is 4mm by after polymeric gel or rubber powder hot melt;
Step 6: utilize motor tire inwall cooler, carries out cooling curing to the Polymer self sealss polymeric gel application of anti-leakage layers of motor tire inner wall surface;
Step 7: utilize organic protective agent flush coater and organic protective agent, all sprays one deck methyl-silicone oil organic protective agent to the motor tire inner wall surface with Polymer self sealss polymeric gel application of anti-leakage layers, obtains leakproof, noise control, bulletproof car tire.
Embodiment 6
A kind of leakproof, noise control, bulletproof car tire, all scribble one deck silane coupling agent chlorinated isotactic polypropylene toluene solution in motor tire inner wall surface, the surface scribbling silane coupling agent scribbles one deck Polymer self sealss polymeric gel application of anti-leakage layers, and the thickness of application of anti-leakage layers is 4.5mm;
The key component of described Polymer self sealss polymeric gel according to percentage by weight is: styrene analog thermoplastic elastomer SBS:38%, thermoplastic polymer resin's terpene resin 22.5%, thermoplastic polymer resin C5 petroleum resin: 22.5%, soften flux naphthenic oil: 6.5%, plasticizer phthalic acid dibutyl ester: 6.5%, antioxidant 1076:2%, catalyst n-methyldiethanolamine: 1%, accelerator diethyl thiourea: 1%.
A method for making for leakproof, noise control, bulletproof car tire, comprises the following steps:
Step one: utilize automotive wheels handling tool, automotive wheels is unloaded from automobile;
Step 2: utilize automotive wheels kinetic balance adjusting machine, to the calibration testing of automotive wheels kinetic balance, and records its data;
Step 3: bleed off the gas medium in automotive wheels, and utilize automotive wheels resolving device that automotive wheels is resolved into automotive hub and motor tire;
Step 4: utilize motor tire inner wall surface cleaning machine and motor tire purging medium, motor tire inner wall surface is cleaned, and in light-illuminating situation, visual inspection is without bright spot;
Step 5: utilize hot-air heater that the motor tire inner wall surface cleaned up is heated to 70 DEG C;
Step 6: utilize motor tire silane coupling agent flush coater all to spray to the motor tire inner wall surface after heating the silane coupling agent chlorinated isotactic polypropylene toluene solution that a layer thickness is 0.2mm;
Step 7: utilize motor tire hot melt glue sprayer and Polymer self sealss polymeric gel or rubber powder, all spray to the motor tire inner wall surface after linging the Polymer self sealss polymeric gel application of anti-leakage layers that a layer thickness is 4.5mm by after polymeric gel or rubber powder hot melt;
Step 8: utilize motor tire inwall cooler, to the Polymer self sealss polymeric gel application of anti-leakage layers of motor tire inner wall surface, carries out cooling curing;
Step 9: utilize organic protective agent flush coater and organic protective agent, all sprays one deck methyl-silicone oil organic protective agent to the motor tire inner wall surface with Polymer self sealss polymeric gel application of anti-leakage layers, obtains leakproof, noise control, bulletproof car tire;
Step 10: utilize automotive wheels mounting equipment that automotive hub and motor tire are assembled into automotive wheels, and filling gas medium is to specifying tire pressure;
Step 11: utilize automotive wheels kinetic balance adjusting machine, to the calibration testing of automotive wheels kinetic balance, and records its data, more unchanged with the data of step 2 record;
Step 12: the automotive wheels after calibration is loaded onto automobile, namely completes the conversion of conventional tyre.
Embodiment 7
A kind of leakproof, noise control, bulletproof car tire, all scribble one deck silane coupling agent chlorinated natural rubber chloroform soln in motor tire inner wall surface, the surface scribbling silane coupling agent scribbles one deck Polymer self sealss polymeric gel application of anti-leakage layers, and the thickness of application of anti-leakage layers is 4mm;
The key component of described Polymer self sealss polymeric gel according to percentage by weight is: styrene analog thermoplastic elastomer SEBS:38%, thermoplastic polymer resin C5/C9 copolymerized petroleum resin: 22.5%, thermoplastic polymer resin's ester gum: 22.5%, soften flux naphthenic oil: 5%, antioxidant 4010NA: 2%, accelerator diethyl thiourea: 2%, extending agent silica powder: 4%, refractory agent nano-graphite: 4%.
A method for making for leakproof, noise control, bulletproof car tire, comprises the following steps:
Step one: check brand-new motor tire, should meet the relevant criterion requirement of motor tire;
Step 2: utilize motor tire inner wall surface cleaning machine and motor tire purging medium, clean the motor tire inner wall surface of passed examination, in light-illuminating situation, visual inspection is without bright spot;
Step 3: utilize hot-air heater that the motor tire inner wall surface cleaned up is heated to 80 DEG C;
Step 4: utilize motor tire silane coupling agent flush coater all to spray to the motor tire inner wall surface after heating the silane coupling agent chlorinated natural rubber chloroform soln that a layer thickness is 0.2mm;
Step 5: utilize motor tire hot melt glue sprayer and Polymer self sealss polymeric gel or rubber powder, all spray to the motor tire inner wall surface after linging the Polymer self sealss polymeric gel application of anti-leakage layers that a layer thickness is 4mm by after polymeric gel or rubber powder hot melt;
Step 6: utilize motor tire inwall cooler, carries out cooling curing to the Polymer self sealss polymeric gel application of anti-leakage layers of motor tire inner wall surface;
Step 7: utilize organic protective agent flush coater and organic protective agent, all sprays one deck methyl-silicone oil organic protective agent to the motor tire inner wall surface with Polymer self sealss polymeric gel application of anti-leakage layers, obtains leakproof, noise control, bulletproof car tire.
Claims (3)
1. leakproof, noise control, a bulletproof car tire, is characterized in that: all scribble one deck silane coupling agent in motor tire inner wall surface, and the surface scribbling silane coupling agent scribbles one deck Polymer self sealss polymeric gel application of anti-leakage layers, and the thickness of application of anti-leakage layers is not less than 3.5mm;
Described silane coupling agent is take chlorinated alkenes as the organic solution of solute, and chlorinated alkenes solute comprises haloflex, chlorinated isotactic polypropylene, maleic anhydride graft chlorinated polypropylene, chlorinated natural rubber etc., and wherein the content of chlorine element is between 20-40%; The solvent of chlorinated alkenes organic solution comprises aromatic hydrocarbons, esters solvent and ketones solvent and their compound; Esters solvent comprises ethyl acetate, butyl acetate, isobutyl acetate, isopropyl acetate, isoamyl acetate etc.; Ketones solvent comprises butanone, methyl isobutyl ketone, cyclohexanone; Aromatic solvent comprises toluene, dimethylbenzene; Chlorohydrocarbon comprises methenyl choloride, trichoroethylen, dichlorethane, trichloroethane etc.;
The key component of described Polymer self sealss polymeric gel according to percentage by weight is: styrene analog thermoplastic elastomer 30-38%, relative molecular weight are thermoplastic polymer resin 40-45%, the plasticising softening component 5-15% of 200-2000, anti-old antioxidant composition 1-2%, catalysed promoted component 0-2%, filling heatproof component 0-8%;
Described styrene analog thermoplastic elastomer is that SIS, SBS are mixed with one or more in SEBS; Relative molecular weight to be the thermoplastic polymer resin of 200-2000 be terpene resin, C5 petroleum resin, C5/C9 copolymerized petroleum resin, ester gum are mixed with one or more in coumarone indene resin; Described plasticising softening component is that plasticizer is mixed with one or both in soften flux, anti-old antioxidant composition is that aging inhibitor is mixed with one or both in antioxidant, catalysed promoted component is that catalyst is mixed with one or both in accelerator, and filling heatproof component is that extending agent is mixed with one or both in refractory agent;
Described plasticizer is that dioctyl phthalate, diisobutyl phthalate, diisooctyl phthalate, BBP(Butyl Benzyl Phthalate are mixed with one or more in dibutyl phthalate; Described soften flux is that naphthenic oil, 40# machine oil are mixed with one or more in aromatic naphtha; Described aging inhibitor be SP, 4010,4010NA is mixed with one or more in 4020; Described antioxidant is 300,1010,1076 mixed with one or more in 264; Described catalyst is that N methyldiethanol amine is mixed with one or both in METHYLPYRROLIDONE; Described accelerator is that PX, BZ are mixed with one or more in diethyl thiourea; Described extending agent is that silica flour, aluminium hydroxide are mixed with one or more in silica powder; Described refractory agent is that nano-calcium carbonate is mixed with one or both in nano-graphite.
2. the method for making of leakproof as claimed in claim 1, noise control, bulletproof car tire, is characterized in that, comprise the following steps:
Step one: check brand-new motor tire, should meet the relevant criterion requirement of motor tire;
Step 2: utilize motor tire inner wall surface cleaning machine and motor tire purging medium, clean the motor tire inner wall surface of passed examination, in light-illuminating situation, visual inspection is without bright spot;
Step 3: utilize hot-air heater that the motor tire inner wall surface cleaned up is heated to 50-80 DEG C;
Step 4: utilize motor tire silane coupling agent flush coater all to spray to the motor tire inner wall surface after heating the silane coupling agent that a layer thickness is 0.1-0.2mm, this silane coupling agent is take chlorinated alkenes as the organic solution of solute;
Step 5: utilize motor tire hot melt glue sprayer and Polymer self sealss polymeric gel or rubber powder, all sprays to the motor tire inner wall surface after linging the Polymer self sealss polymeric gel application of anti-leakage layers that a layer thickness is not less than 3.5mm by after polymeric gel or rubber powder hot melt;
Step 6: utilize motor tire inwall cooler, carries out cooling curing to the Polymer self sealss polymeric gel application of anti-leakage layers of motor tire inner wall surface;
Step 7: utilize organic protective agent flush coater and organic protective agent, all sprays one deck methyl-silicone oil organic protective agent to the motor tire inner wall surface with Polymer self sealss polymeric gel application of anti-leakage layers, obtains leakproof, noise control, bulletproof car tire.
3. the method for making of leakproof as claimed in claim 1, noise control, bulletproof car tire, is characterized in that, comprise the following steps:
Step one: utilize automotive wheels handling tool, automotive wheels is unloaded from automobile;
Step 2: utilize automotive wheels kinetic balance adjusting machine, to the calibration testing of automotive wheels kinetic balance, and records its data;
Step 3: bleed off the gas medium in automotive wheels, and utilize automotive wheels resolving device that automotive wheels is resolved into automotive hub and motor tire;
Step 4: utilize motor tire inner wall surface cleaning machine and motor tire purging medium, motor tire inner wall surface carries out cleaning, in light-illuminating situation, visual inspection is without bright spot;
Step 5: utilize hot-air heater that the motor tire inner wall surface cleaned up is heated to 50-80 DEG C;
Step 6: utilize motor tire silane coupling agent flush coater all to spray to the motor tire inner wall surface after heating the silane coupling agent that a layer thickness is 0.1-0.2mm, this silane coupling agent is take chlorinated alkenes as the organic solution of solute;
Step 7: utilize motor tire hot melt glue sprayer and Polymer self sealss polymeric gel or rubber powder, all sprays to the motor tire inner wall surface after linging the Polymer self sealss polymeric gel application of anti-leakage layers that a layer thickness is not less than 3.5mm by after polymeric gel or rubber powder hot melt;
Step 8: utilize motor tire inwall cooler, to the Polymer self sealss polymeric gel application of anti-leakage layers of motor tire inner wall surface, carries out cooling curing;
Step 9: utilize organic protective agent flush coater and organic protective agent, all sprays one deck methyl-silicone oil organic protective agent to the motor tire inner wall surface with Polymer self sealss polymeric gel application of anti-leakage layers, obtains leakproof, noise control, bulletproof car tire;
Step 10: utilize automotive wheels mounting equipment that automotive hub and motor tire are assembled into automotive wheels, and filling gas medium is to specifying tire pressure;
Step 11: utilize automotive wheels kinetic balance adjusting machine, to the calibration testing of automotive wheels kinetic balance, and records its data, more unchanged with the data of step 2 record;
Step 12: the automotive wheels after calibration is loaded onto automobile, namely completes the conversion of conventional tyre.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310574432.9A CN104626882A (en) | 2013-11-15 | 2013-11-15 | Anti-leakage, noise-prevention and bulletproof automobile tire and manufacturing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310574432.9A CN104626882A (en) | 2013-11-15 | 2013-11-15 | Anti-leakage, noise-prevention and bulletproof automobile tire and manufacturing method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105327823A (en) * | 2015-12-01 | 2016-02-17 | 卢文哲 | Automatic assembly line for spraying adhesives in tires and production method |
| CN105925116A (en) * | 2016-05-23 | 2016-09-07 | 冯智勇 | Novel composite tire-sealing material containing C5 petroleum resin |
| CN106957507A (en) * | 2017-03-29 | 2017-07-18 | 合肥天沃能源科技有限公司 | It is a kind of for energy-saving rubber of tire and preparation method thereof |
| CN112898672A (en) * | 2021-01-26 | 2021-06-04 | 赛轮集团股份有限公司 | Rubber composition with self-sealing function, preparation method and tire |
-
2013
- 2013-11-15 CN CN201310574432.9A patent/CN104626882A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105327823A (en) * | 2015-12-01 | 2016-02-17 | 卢文哲 | Automatic assembly line for spraying adhesives in tires and production method |
| CN105925116A (en) * | 2016-05-23 | 2016-09-07 | 冯智勇 | Novel composite tire-sealing material containing C5 petroleum resin |
| CN106957507A (en) * | 2017-03-29 | 2017-07-18 | 合肥天沃能源科技有限公司 | It is a kind of for energy-saving rubber of tire and preparation method thereof |
| CN112898672A (en) * | 2021-01-26 | 2021-06-04 | 赛轮集团股份有限公司 | Rubber composition with self-sealing function, preparation method and tire |
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Application publication date: 20150520 |