CN106953109B - Redox battery with active substance in circulating flow liquid state - Google Patents

Redox battery with active substance in circulating flow liquid state Download PDF

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Publication number
CN106953109B
CN106953109B CN201710352721.2A CN201710352721A CN106953109B CN 106953109 B CN106953109 B CN 106953109B CN 201710352721 A CN201710352721 A CN 201710352721A CN 106953109 B CN106953109 B CN 106953109B
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storage tank
electrolyte storage
face
mounting seat
galvanic pile
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CN106953109A (en
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夏百战
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University of Electronic Science and Technology of China Zhongshan Institute
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University of Electronic Science and Technology of China Zhongshan Institute
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04014Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Fuel Cell (AREA)

Abstract

The invention provides an oxidation-reduction battery with active substances in a circulating flow liquid state, which comprises a motor, a groove, cleaning cloth, a nut seat, a lead screw, a pulley, a sliding groove, a clamping plate, a mounting seat, a reset spring, a buckle and a metal elastic sheet, wherein the groove and the sliding groove are symmetrically arranged on the annular side surface of a negative electrolyte storage tank, the lead screw is arranged at the middle position in the groove, the motor is arranged on the upper end surface of the negative electrolyte storage tank, the cleaning cloth is arranged on the annular side surface in a disc body, the nut seat is arranged on the annular side surface in the disc body, and the pulley is arranged on the annular side surface in the disc body.

Description

Redox battery with active substance in circulating flow liquid state
Technical Field
The invention relates to a redox battery with an active substance in a circulating flow liquid state, belonging to the field of new energy battery equipment.
Background
The vanadium battery is called as all vanadium redox flow battery, and is a redox battery with active substances in a circulating flow liquid state. The power-saving type lithium ion battery has the characteristics of high power, large capacity, high efficiency, long service life, high response speed, instant charge and discharge, high safety and environmental friendliness, and is greatly developed. The cost of the vanadium battery is similar to that of a lead-acid battery, and the vanadium battery can also be used for preparing a megawatt battery pack which can provide electric energy for a long time with high power, so that the vanadium battery has the cost performance advantage which is incomparable with that of a lithium ion battery and a nickel-hydrogen battery in the field of large-scale energy storage. The vanadium battery has simple production process, economic price and excellent electrical property, and has competitive strength in the aspect of application prospect of large-scale energy storage and power supply of electric vehicles compared with the fuel battery with complex manufacture and high price.
However, the existing vanadium battery technology has many defects, one of which is that the vanadium battery adopts a liquid storage tank with larger volume to bear electrolyte, and the liquid storage tank has huge volume, so that the problems that operators are not easy to clean, the cleaning labor intensity is high, and time and labor are wasted are caused; in the prior art, the vanadium battery galvanic pile has poor fixation firmness and is inconvenient to mount and dismount; in the vanadium battery technology in the prior art, the pile heat dissipation effect is not good, and the stability of the pile during operation is greatly influenced, so that a redox battery with an active substance in a circulating flow liquid state is urgently needed to solve the problems.
Disclosure of Invention
Aiming at the defects in the prior art, the invention aims to provide a redox battery with an active substance in a circulating flow liquid state so as to solve the problems in the background technology.
In order to realize the purpose, the invention is realized by the following technical scheme: a redox battery with active substances in a circulating flow liquid state comprises an equipment main body, a tank body cleaning mechanism, a heat dissipation mechanism and an electric push quick fixing mechanism, wherein the equipment main body comprises a positive electrolyte storage tank, a first connecting pipe, an electric push body, a second connecting pipe and a negative electrolyte storage tank, the electric push body is installed in an installation seat, the positive electrolyte storage tank and the negative electrolyte storage tank are symmetrically arranged on the left side and the right side of the electric push body, the positive electrolyte storage tank is connected with the electric push body through the first connecting pipe, the negative electrolyte storage tank is connected with the electric push body through the second connecting pipe, the tank body cleaning mechanism is provided with two groups, the two groups of tank body cleaning mechanisms are respectively installed on the positive electrolyte storage tank and the negative electrolyte storage tank, each tank body cleaning mechanism comprises a motor, a groove, a disc body, cleaning cloth, a nut seat, a screw rod, a pulley and a sliding chute, the groove and the chute are symmetrically arranged on the annular side surface of the negative electrolyte storage tank, the screw rod is arranged in the middle position in the groove, the upper end of the screw rod is connected with the motor, the motor is arranged on the upper end surface of the negative electrolyte storage tank, the cleaning cloth is arranged on the annular side surface in the disc body, the nut seat is arranged on the annular side surface in the disc body, the right end of the nut seat is connected with the screw rod, the pulley is installed on the annular side face in the disc body, the left end of the pulley is assembled in the sliding groove, the heat dissipation mechanism is arranged on the right end face of the installation seat and comprises a heat dissipation fan, a protective net and an air guide pipe, the air guide pipe is arranged in the middle of the right end face of the installation seat, the protective net is installed on the right end face of the air guide pipe, the heat dissipation fan is installed in the air guide pipe, and the fast electric pile fixing mechanism comprises a clamping plate, the mounting seat, reset spring, the cotton board of pearl, locating hole, buckle, metal shrapnel and fixed slot, reset spring installs on the terminal surface before in the mounting seat, splint are fixed on reset spring, the cotton board of pearl is fixed bottom position in the mounting seat, the fixed slot is seted up on the pile body right-hand member face, the metal shrapnel is installed in the mounting seat on the left side terminal surface, the buckle is installed on the metal shrapnel up end, the locating hole sets up upper portion position in the fixed slot.
Furthermore, the upper end faces of the positive electrolyte storage tank and the negative electrolyte storage tank are respectively provided with an electrolyte injection port.
Furthermore, the first connecting pipe and the second connecting pipe have the same specification.
Further, the splint are equipped with two sets ofly, two sets of splint symmetry is arranged in the mount pad around, and two sets of splint all are connected with the mount pad through reset spring.
Furthermore, the fixed slots are provided with two groups, and the fixed slots are symmetrically arranged on the left end face and the right end face of the electric pile body.
Furthermore, the metal elastic sheet and the buckles are arranged in two groups, the metal elastic sheet is symmetrically arranged on the left end face and the right end face in the mounting seat, the buckles are respectively arranged on the upper end faces of the two groups of metal elastic sheets, and the push handles are arranged on the buckles.
The invention has the beneficial effects that: according to the redox battery with the active substance in the circulating flow liquid state, the motor, the groove, the disc body, the cleaning cloth, the nut seat, the screw rod, the pulley and the sliding groove are added, so that the rapid cleaning of the electrolyte storage tank is realized, the cleaning efficiency of the electrolyte storage tank is improved, the labor intensity of operating personnel is greatly reduced, and the problems that the operating personnel are difficult to clean, the cleaning labor intensity is high, and time and labor are wasted due to the fact that the original vanadium battery adopts the liquid storage tank with a large volume to bear the electrolyte are solved.
Because the radiating fan, the protective net and the air guide pipe are added, the radiating efficiency of the invention is improved, the continuous cooling of the galvanic pile is realized, the stability of the galvanic pile in operation is ensured, the service life of the galvanic pile is prolonged, and the problems that the radiating effect of the galvanic pile is poor and the stability of the galvanic pile in operation is greatly influenced in the original vanadium battery technology are solved.
Because the clamp plate, the mounting seat, the reset spring, the pearl wool plate, the positioning hole, the buckle, the metal elastic sheet and the fixing groove are added, the design realizes the quick mounting and dismounting of the galvanic pile, the fixing stability is good, the damping effect is good, the maintenance by operating personnel is convenient, and the problems that the fixing firmness of the original vanadium cell galvanic pile is poor, the mounting and dismounting are inconvenient, and the maintenance wastes time and labor are solved.
The liquid injection port is added, so that the design is convenient for operating personnel to inject the electrolyte, and the push handle is added, so that the operating personnel can move the buckle conveniently.
Drawings
Other features, objects and advantages of the invention will become more apparent upon reading of the detailed description of non-limiting embodiments with reference to the following drawings:
FIG. 1 is a schematic diagram of a redox cell of the present invention in which the active material is in a circulating liquid state;
FIG. 2 is a schematic diagram of a tank cleaning mechanism in a redox cell of the present invention in which the active material is in a circulating liquid state;
fig. 3 is a schematic structural diagram of a heat dissipation mechanism in a redox cell in which an active material is in a circulating liquid state according to the present invention;
FIG. 4 is a schematic cross-sectional view of B-B in a redox cell of the present invention with the active material in a circulating liquid state;
FIG. 5 isbase:Sub>A schematic cross-sectional view A-A ofbase:Sub>A redox cell of the present invention with an active material inbase:Sub>A circulating liquid state;
in the figure: 1-tank cleaning mechanism, 2-heat dissipation mechanism, 3-fast electric pile fixing mechanism, 4-positive electrode electrolyte storage tank, 5-connecting pipe I, 6-electric pile body, 7-connecting pipe II, 8-negative electrode electrolyte storage tank, 11-motor, 12-groove, 13-disc body, 14-cleaning cloth, 15-nut seat, 16-screw rod, 17-pulley, 18-chute, 21-heat dissipation fan, 22-protective net, 23-air guide pipe, 31-clamping plate, 32-mounting seat, 33-reset spring, 34-pearl cotton plate, 35-positioning hole, 36-buckle, 37-metal shrapnel and 38-fixing groove.
Detailed Description
In order to make the technical means, the creation characteristics, the achievement purposes and the effects of the invention easy to understand, the invention is further explained by combining the specific embodiments.
Referring to fig. 1-5, the present invention provides a technical solution: the utility model provides an active material is liquid redox battery of circulation flow, including the equipment principal, jar body cleaning mechanism 1, heat dissipation mechanism 2 and quick fixed establishment 3 of pile, the equipment principal includes anodal electrolyte storage tank 4, connecting pipe one 5, pile body 6, two 7 of connecting pipe and negative pole electrolyte storage tank 8, pile body 6 is installed in mount pad 32, anodal electrolyte storage tank 4 sets up in the 6 left and right sides of pile body with 8 symmetries of negative pole electrolyte storage tank, anodal electrolyte storage tank 4 is connected with pile body 6 through connecting pipe one 5, negative pole electrolyte storage tank 8 is connected with pile body 6 through two 7 of connecting pipe.
The two groups of tank cleaning mechanisms 1 are arranged, the two groups of tank cleaning mechanisms 1 are respectively installed on an anode electrolyte storage tank 4 and a cathode electrolyte storage tank 8, each tank cleaning mechanism 1 comprises a motor 11, a groove 12, a disc body 13, cleaning cloth 14, a nut seat 15, a lead screw 16, a pulley 17 and a sliding groove 18, the grooves 12 and the sliding grooves 18 are symmetrically formed in the annular side face of the cathode electrolyte storage tank 8, the lead screw 16 is installed in the middle of the groove 12, the upper end of the lead screw 16 is connected with the motor 11, the motor 11 is installed on the upper end face of the cathode electrolyte storage tank 8, the cleaning cloth 14 is installed on the annular side face of the disc body 13, the nut seat 15 is installed on the annular side face of the disc body 13, the right end of the nut seat 15 is connected with the lead screw 16, the pulley 17 is installed on the annular side face of the disc body 13, and the left end of the pulley 17 is assembled in the sliding groove 18.
The heat dissipation mechanism 2 is arranged on the right end face of the mounting seat 32, the heat dissipation mechanism 2 comprises a heat dissipation fan 21, a protective net 22 and an air guide pipe 23, the air guide pipe 23 is arranged in the middle of the right end face of the mounting seat 32, the protective net 22 is arranged on the right end face of the air guide pipe 23, and the heat dissipation fan 21 is arranged in the air guide pipe 23.
Pile quick fixed establishment 3 includes splint 31, mount pad 32, reset spring 33, the cotton board 34 of pearl, locating hole 35, buckle 36, metal shrapnel 37 and fixed slot 38, reset spring 33 installs on the preceding terminal surface in mount pad 32, splint 31 is fixed on reset spring 33, the cotton board 34 of pearl fixes the bottom position in mount pad 32, fixed slot 38 is seted up on pile 6 right-hand member face of body, metal shrapnel 37 is installed on the left side terminal surface in mount pad 32, buckle 36 is installed on metal shrapnel 37 up end, locating hole 35 sets up upper portion position in fixed slot 38, this design has realized the quick installation and the dismantlement of pile, and fixed stability is good, the shock attenuation is effectual, the operating personnel of being convenient for overhaul.
All install on anodal electrolyte storage tank 4 and the 8 up end of negative pole electrolyte storage tank and annotate the liquid mouth, connecting pipe one 5 is the same with two 7 specifications of connecting pipe, splint 31 is equipped with two sets ofly, the symmetry is arranged in mount pad 32 around two sets of splint 31, and two sets of splint 31 all are connected with mount pad 32 through reset spring 33, fixed slot 38 is equipped with two sets ofly, fixed slot 38 symmetry is seted up and is gone at the pile body 6 left end face and right-hand member face, metal shrapnel 37 all is equipped with two sets ofly with buckle 36, metal shrapnel 37 symmetry is installed in mount pad 32 on left end face and the right-hand member face, buckle 36 is installed respectively on two sets of metal shrapnel 37 up ends, and install on the buckle 36 and push away the handle.
The specific implementation mode is as follows: when the cleaning device is used, firstly, an operator checks the cleaning device to check whether the cleaning device has defects or not, if the defects exist, the operator cannot use the cleaning device, at the moment, the operator needs to inform the maintenance personnel to maintain, if the problems do not exist, the maintenance device can be used, when the operator needs to clean the anode electrolyte storage tank 4 and the cathode electrolyte storage tank, the operator operates the motor 11, the motor 11 drives the screw rod 16 to rotate in the groove 12, the nut seat 15 moves up and down on the screw rod 16, the nut seat 15 drives the disc body 13 to move up and down on the outer surface of the anode electrolyte storage tank 4 or the outer surface of the cathode electrolyte storage tank 8, the disc body 13 moves up and down to drive the pulley 17 to move in the sliding groove 18, the disc body 13 drives the cleaning cloth 14 to move up and down, and the cleaning cloth 14 moves up and down to automatically clean the outer surfaces of the anode electrolyte storage tank 4 or the cathode electrolyte storage tank 8, so that the cleaning efficiency is improved, the mechanization of cleaning operation is realized, and the labor intensity of the operator is greatly reduced.
The operation personnel place the pile body 6 in mount pad 32, the operation personnel inserts buckle 36 in fixed slot 38, then promote pile body 6 downwards, pile body 6 extrudees splint 31 and buckle 36, splint 31 oppresses reset spring 33 and takes place elastic deformation, buckle 36 oppresses metal shrapnel 37 and takes place elastic deformation, after terminal surface and the inseparable laminating of pearl wool board 34 under pile body 6, metal shrapnel 37 fixes buckle 36 in locating hole 35 under the effect of resilience force, reset spring 33 is under the effect of resilience force, closely laminate splint 31 and pile body 6, pile body 6 is fixed in mount pad 32, thereby the quick installation of pile body 6 has been realized, the stationary stability is good, when the operation personnel need dismantle pile body 6, the operation personnel shift out buckle 36 in locating hole 35 through pushing away the handle, and upwards lift up and draw pile body 6, take pile body 6 out of mount pad 32, thereby the quick dismantlement of pile body 6 has been realized, be convenient for the operation personnel to overhaul.
When the electric pile body 6 needs to be cooled, the worker operates the heat radiation fan 21, the heat radiation fan 21 conveys hot air in the mounting seat 32 to the outside of the mounting seat 32 through the air guide pipe 23, foreign matters are prevented from entering the air guide pipe 23 due to the addition of the protective net 22, and the operation stability of the heat radiation fan 21 is ensured, so that the cooling function of the electric pile body 6 is realized, and the operation stability of the electric pile body 6 is ensured.
While there have been shown and described what are at present considered the fundamental principles and essential features of the invention and its advantages, it will be apparent to those skilled in the art that the invention is not limited to the details of the foregoing exemplary embodiments, but is capable of other specific forms without departing from the spirit or essential characteristics thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Any reference sign in a claim should not be construed as limiting the claim concerned.
Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art.

Claims (4)

1. The utility model provides an active substance is liquid redox battery of circulation flow, includes equipment main part, jar clean mechanism (1), heat dissipation mechanism (2) and quick fixed establishment of galvanic pile (3), its characterized in that: the equipment main body comprises an anode electrolyte storage tank (4), a first connecting pipe (5), a galvanic pile body (6), a second connecting pipe (7) and a cathode electrolyte storage tank (8), wherein the galvanic pile body (6) is installed in a mounting seat (32), the anode electrolyte storage tank (4) and the cathode electrolyte storage tank (8) are symmetrically arranged on the left side and the right side of the galvanic pile body (6), the anode electrolyte storage tank (4) is connected with the galvanic pile body (6) through the first connecting pipe (5), the first connecting pipe (5) is identical to the second connecting pipe (7) in specification, and the cathode electrolyte storage tank (8) is connected with the galvanic pile body (6) through the second connecting pipe (7);
the cleaning mechanism comprises a tank body cleaning mechanism (1) and a tank cover, wherein the tank body cleaning mechanism (1) comprises two groups, the two groups of tank body cleaning mechanisms (1) are respectively installed on a positive electrolyte storage tank (4) and a negative electrolyte storage tank (8), each tank body cleaning mechanism (1) comprises a motor (11), a groove (12), a disc body (13), cleaning cloth (14), a nut seat (15), a lead screw (16), a pulley (17) and a sliding groove (18), the grooves (12) and the sliding grooves (18) are symmetrically formed in the annular side surface of the negative electrolyte storage tank (8), the lead screw (16) is installed in the middle of the groove (12), the upper end of the lead screw (16) is connected with the motor (11), the motor (11) is installed on the upper end surface of the negative electrolyte storage tank (8), the cleaning cloth (14) is installed on the annular side surface of the disc body (13), the nut seat (15) is installed on the annular side surface of the disc body (13), the right end of the nut seat (15) is connected with the lead screw (16), the pulley (17) is installed on the annular side surface of the disc body (13), and the left end of the pulley (17) is assembled in the sliding groove (18);
the heat dissipation mechanism (2) is arranged on the right end face of the mounting seat (32), the heat dissipation mechanism (2) comprises a heat dissipation fan (21), a protective net (22) and an air guide pipe (23), the air guide pipe (23) is arranged in the middle of the right end face of the mounting seat (32), the protective net (22) is arranged on the right end face of the air guide pipe (23), and the heat dissipation fan (21) is arranged in the air guide pipe (23);
the fast fixing mechanism (3) of the galvanic pile comprises a clamping plate (31), a mounting seat (32), a reset spring (33), a pearl cotton plate (34), a positioning hole (35), a buckle (36), a metal elastic sheet (37) and a fixing groove (38), wherein the reset spring (33) is installed on the front end face in the mounting seat (32), the clamping plate (31) is fixed on the reset spring (33), the pearl cotton plate (34) is fixed at the bottom position in the mounting seat (32), the fixing groove (38) is formed in the right end face of the galvanic pile body (6), the metal elastic sheet (37) is installed on the left end face in the mounting seat (32), the buckle (36) is installed on the upper end face of the metal elastic sheet (37), the positioning hole (35) is formed in the upper portion position in the fixing groove (38), the fixing groove (38) is provided with two sets, and the fixing groove (38) is symmetrically formed in the left end face and the right end face of the galvanic pile body (6).
2. A redox cell according to claim 1 wherein the active material is in a liquid state of circulation, characterized in that: and the upper end faces of the positive electrolyte storage tank (4) and the negative electrolyte storage tank (8) are respectively provided with an injection port.
3. A redox cell according to claim 1 wherein the active material is in a liquid state of circulation, characterized in that: splint (31) are equipped with two sets ofly, two sets of splint (31) front and back symmetry arranges in mount pad (32), and two sets of splint (31) are all connected with mount pad (32) through reset spring (33).
4. A redox cell according to claim 1 wherein the active material is in a circulating liquid state, and wherein: the metal elastic sheet (37) and the buckle (36) are both provided with two groups, the metal elastic sheet (37) is symmetrically arranged on the left end face and the right end face in the mounting seat (32), the buckle (36) is respectively arranged on the upper end faces of the two groups of metal elastic sheets (37), and the buckle (36) is provided with a push handle.
CN201710352721.2A 2017-05-18 2017-05-18 Redox battery with active substance in circulating flow liquid state Active CN106953109B (en)

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ES2841509B2 (en) * 2019-12-16 2022-05-30 Santana Ramirez Alberto Andres Process for cleaning cathodic surfaces in voltaic cells

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Publication number Priority date Publication date Assignee Title
CN1768442A (en) * 2003-03-14 2006-05-03 新南创新私人有限公司 Novel vanadium halide redox flow battery
CA2727399A1 (en) * 2008-06-12 2009-12-17 Massachusetts Institute Of Technology High energy density redox flow device
JP2013026142A (en) * 2011-07-25 2013-02-04 National Institute Of Advanced Industrial & Technology Lithium semi-redox flow battery renewable both by electrical charge and by chemical oxidation using oxidant
CN106099152A (en) * 2016-08-31 2016-11-09 安徽远东船舶有限公司 A kind of vanadium cell peculiar to vessel of high sealing anti-leak
CN106252683A (en) * 2016-08-31 2016-12-21 安徽远东船舶有限公司 A kind of all-vanadium flow battery galvanic pile module peculiar to vessel
CN106347149A (en) * 2016-08-31 2017-01-25 安徽远东船舶有限公司 Mobile all-vanadium redox flow chargeable vehicle
CN206059527U (en) * 2016-10-10 2017-03-29 广州市泓能五金有限公司 A kind of electrolyte of vanadium redox battery fluid reservoir

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1768442A (en) * 2003-03-14 2006-05-03 新南创新私人有限公司 Novel vanadium halide redox flow battery
CA2727399A1 (en) * 2008-06-12 2009-12-17 Massachusetts Institute Of Technology High energy density redox flow device
JP2013026142A (en) * 2011-07-25 2013-02-04 National Institute Of Advanced Industrial & Technology Lithium semi-redox flow battery renewable both by electrical charge and by chemical oxidation using oxidant
CN106099152A (en) * 2016-08-31 2016-11-09 安徽远东船舶有限公司 A kind of vanadium cell peculiar to vessel of high sealing anti-leak
CN106252683A (en) * 2016-08-31 2016-12-21 安徽远东船舶有限公司 A kind of all-vanadium flow battery galvanic pile module peculiar to vessel
CN106347149A (en) * 2016-08-31 2017-01-25 安徽远东船舶有限公司 Mobile all-vanadium redox flow chargeable vehicle
CN206059527U (en) * 2016-10-10 2017-03-29 广州市泓能五金有限公司 A kind of electrolyte of vanadium redox battery fluid reservoir

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