CN106948081B - The method that linen look staple fiber is prepared into flexible auxetic compound fabric based on mull technique - Google Patents

The method that linen look staple fiber is prepared into flexible auxetic compound fabric based on mull technique Download PDF

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Publication number
CN106948081B
CN106948081B CN201710127780.XA CN201710127780A CN106948081B CN 106948081 B CN106948081 B CN 106948081B CN 201710127780 A CN201710127780 A CN 201710127780A CN 106948081 B CN106948081 B CN 106948081B
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China
Prior art keywords
auxetic
staple fiber
compound fabric
linen look
prepared
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CN201710127780.XA
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CN106948081A (en
Inventor
杜赵群
许巧丽
何玲娥
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Donghua University
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Donghua University
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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/425Cellulose series
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/60Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in dry state, e.g. thermo-activatable agents in solid or molten state, and heat being applied subsequently
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/70Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
    • D04H1/76Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres otherwise than in a plane, e.g. in a tubular way

Abstract

The present invention relates to a kind of methods and purposes that linen look staple fiber is prepared into flexible auxetic compound fabric based on mull technique, the method of the present invention is to set the template for being carved with auxetic structure pattern, by linen look staple fiber along the uniform laying of auxetic structure pattern in template, and binder is sprayed in linen look staple fiber and infiltrates linen look staple fiber, increase the contact action power between adjacent fiber, cured forming again obtains flexible auxetic compound fabric.Gained flexibility auxetic compound fabric is by sewing as mesh bag, protection separation sleeve, the function textiles such as cup mat, curtain.Features of the present invention simple processing, applicable raw material are wide, including ramie, flax, yellow bluish dogbane, staple fiber of discarded circulation etc..

Description

The method that linen look staple fiber is prepared into flexible auxetic compound fabric based on mull technique
Technical field
The present invention relates to it is a kind of using short linen look fiber or yarn prepare flexible auxetic compound fabric process and Purposes belongs to the preparation and use technical field of textile material and its composite material.
Background technique
Although staple fiber can prepare yarn at present, fabric is woven, its process is complicated, especially flaxen fiber.It is numb fine Tie up between short, batch that difference is big, humidity is larger to strong influence further increases its difficulty of processing.Moreover, the short fibre of linen look There is also difficulties in process for dimension, and product fault is more, and price is low, are the new technology shortcoming of product.Therefore, exploitation tool There is the linen of new construction and new function, improving value-added content of product and performance has important meaning for the development of linen look fiber Justice.Auxetic materials refer to the material with Negative poisson's ratio, i.e., material broadens when stretching perpendicular to draw direction, when compression The phenomenon that material narrows is one of 21 century intellectual material.Fabric, which is prepared into auxetic cloth using auxetic structure, has potential answer Use prospect.Report currently with auxetic structure preparation auxetic fabric is rarely seen.
The preparation of auxetic fabric can be woven using the progress of auxetic yarn, but effect is not obvious.Auxetic fabric is more at present For knitted structure, Ugbolue (Ugbolue, Warner et al.2000, Ugbolue, Kim et al.2011) is according to Hook Deng design concept devise by opening chaining and the warp knit structure that is bonded of insertion yarn.In recent years recklessly red equal scholars according to The theory of the scholars such as Grima and Evans assigns the inward turning folded rectangular connected structure of knitted fabric, and having weaved has large scale Stretching property fabric (Liu and Hu 2010, Hu, Wang et al.2011).2016, Steffens (Steffens, Rana et al.2016) etc. attempt for the first time by using high-performance fiber develop auxetic structure knitting technology, by polyamide (PA) and para-aramid (p-AR) fiber and its conjugate using knitted in flat knitting machine at purl.Ge Chaoyang (Ge, Hu et al.2013) weaving three-dimensional woven fabric, it studies its compressive deformation mechanism for generating auxetic effect and its structural parameters is discussed Influence to negative poisson's ratio.2014, Hu Hong etc. (Wang, Hu et al.2014) devised a kind of novel auxetic interval and knits Object forms a kind of warp knit isolation structure of special geometry by space fabric and parallelogram, is a kind of novel 3D auxetic fabric, using compression and thermal finalization come fixed fabric structure, and material has good Memorability.Auxetic yarn and its Fabric can be also used for preparing composite material, while auxetic textile is due to its special shearing rigidity, fracture toughness, resistance to compression trace Property and the properties such as energy absorption, there are also special synclastic curvature so that auxetic materials be referred to as 16 intellectual materials of 21 century it One, it is expected to be applied to many fields: auto industry, physical protection, aerospace, biomedicine and other national defences, thus Making the R and D of auxetic materials has realistic meaning.But it can be used in the auxetic materials or auxetic yarn of large-scale production at present Line and auxetic foam still are limited to knitted structure for the preparation of flexible auxetic textile fabric, if it is possible to solve auxetic fabric Preparation problem, will open auxetic industrial textileization application gate.
But the manufacturing process for the auxetic fabric that these above-mentioned methods are related to is using the short fiber yarn or chemical fibre of spinning forming Long filament, even with the long filament of particular/special requirement (such as diameter, elasticity, rigidity), ingredient requirement is high, to traditional flaxen fiber, tool class It is totally unfavorable like the fiber (linen look fiber) of flaxen fiber length, the product development of the staple fiber of waste gas circulation recycling, it is bottle Neck and weakness.Therefore, it is just extremely necessary that new construction, the novel technical method for the advantage for playing staple fiber are introduced.
Summary of the invention
The staple fiber product that it is an object of the invention to be difficult to develop by traditional spinning manufacturing equipment.
In order to achieve the above object, there is provided one kind to be based on mull technique for the short fibre of linen look for a technical solution of the invention Tie up the method for being prepared into flexible auxetic compound fabric, which comprises the following steps:
(a) template for being carved with auxetic structure pattern is set, by linen look staple fiber along the auxetic structure pattern in template Uniform laying arrangement;
(b) binder is sprayed on by the linen look staple fiber of auxetic structure pattern laying set by step (a), infiltrates linen look Staple fiber increases the contact action power between adjacent fiber;In order to stablize the auxetic composite structure of staple fiber base, in auxetic It is the binder of high rigidity after sprinkling solidifies on intersection point on structure plan, is the viscous of soft after sprinkling solidifies between intersection point Agent is tied, makes the auxetic composite material of staple fiber base that there is flexibility;
(c) the linen look staple fiber compound fabric solidifying and setting for obtaining step (b), the flexible auxetic for forming stable structure are multiple Close fabric.
Preferably, the auxetic structure pattern includes indent honeycomb, star network, indent diamond shape, regular dodecahedron, triangle It is grid, center rotation rectangle, center rotary triangle shape, center rotation tetrahedron, chiral honeycomb, center polygonal, hinged Hexagon, articulated quadrilateral, hinged triangle and combinations thereof.
Preferably, the preferred indent hexagon cellular structure of the auxetic structure pattern.
Preferably, the binder for after the solidification being soft is organic silicon adhesive, water-based polyurethane adhesive;It is described The binder for after solidification being high rigidity is epoxyn, polyester adhesive, acrylate adhesive.
Preferably, the hardness after binder solidifies is relative hardness, i.e. used binder at auxetic structure pattern intersection point Hardness is higher than non-point of intersection after solidification.
Preferably, the linen look staple fiber includes ramie, flax, jute, bluish dogbane, hemp, sisal hemp, piemarker, bluish dogbane, any of several broadleaf plants Fiber crops, the staple fiber for discarding circulation.
Preferably, the cured method includes that air oxidation solidification, solvent volatilization solidification, high temperature thermal finalization, room temperature are cold Sizing, ultraviolet light solidifying and setting, radiation sizing, thermal response solidification, chemical reaction solidification, melting and solidification, IR Catalysis thermal response Solidification.
There is provided a kind of flexible auxetic being prepared using the above method is compound for another technical solution of the invention The purposes of fabric, which is characterized in that flexible auxetic compound fabric is used as function textile by cutting and sewing.
Preferably, the function textile is mesh bag, protection separation sleeve, cup mat or curtain.
Using the applicant nearly ten years in the redundancy technique of auxetic textile research field, the short fibre of auxetic structure is designed Product is tieed up, the advantages of product new construction can be assigned, and can effectively protrude staple fiber, linen look staple fiber is prepared into have and is drawn The auxetic fabric of swollen structure and effect.And applicable raw materials of the invention are in extensive range, can reduce production cost, and preparation method letter Single, added value of product is high.
The principle of the present invention is by linen look staple fiber along the uniform laying of auxetic structure pattern in template, viscous by spraying It ties agent and infiltrates linen look staple fiber, increase the contact action power between adjacent fiber, improve the stability of structure;Especially in auxetic knot There is good intensity and anti-torsion, resistant to bending ability, the structure for improving auxetic compound fabric is steady on the intersection point of structure pattern It is qualitative;And the bar between the intersection point of auxetic structure pattern has reasonable rigidity, can be subjected to displacement and rotate around intersection point, assigns auxetic The flexibility of compound fabric;Finally by compound fabric solidified forming, flexible auxetic compound fabric is obtained.Gained flexibility auxetic is compound Fabric is by sewing as mesh bag, protection separation sleeve, the function textiles such as cup mat, curtain.Gained flexibility auxetic compound fabric It can also be combined into the sandwich structure of sandwich with frivolous, elastomeric film and there are water-proof breathable properties, being used as has rainproof function Shopping bag.
Although the present invention is directed to linen look staple fiber, it is also applied for the fiber or yarn of auxetic or non-auxetic, wherein wrapping Include pure spinning or blended auxetic or non-auxetic yarn, arrange fiber or yarn according to auxetic patterning, and by adhesive or Heat effect etc. increases the interaction between adjacent fiber or yarn, forms flexible auxetic composite material.Equally, the auxetic knot Structure pattern can be indent hexagon cellular structure, and auxetic effect is adjusted by indent hexagon cellular structure size.The hair The small-scale workshop of manual laying had both can be used in bright method, it is possible to use the large-scale production of mechanization, i.e., using on roller It is carved with auxetic structure pattern, by fiber in roller laying at auxetic structure pattern, then by roller continuous rotation, passes through transmission Band transmission auxetic compound fabric is continuously finished.The generation that the structure of fiber or yarn is arranged so as to auxetic effect in the present invention is done Structure prepares, and the modes such as bonding, solidification are in order to which structure is fixed, and roller, conveyer belt or syringe are for continuous production It is necessary.
The features of the present invention and beneficial effect are:
1) staple fiber is arranged using the template with auxetic structure pattern, facilitates staple fiber and forms auxetic knot in template Structure, to have auxetic effect.
2) for the raw material that the method uses for linen look staple fiber, raw material sources are extensive and at low cost, are linen look staple fiber Industrial applications provide New methods in working.
3) the method step is simple, the small-scale workshop of manual laying both can be used, it is possible to use the big rule of mechanization Mould production.
4) product has auxetic effect, can be by cutting and sewing as mesh bag, protection separation sleeve, cup mat, curtain etc. Function textile.
Detailed description of the invention
Fig. 1 is indent hexagon cellular structural model figure;
Fig. 2 is double-head arrow structural model figure;
Fig. 3 is sinusoidal structured illustraton of model;
Fig. 4 is Star Network structure chart.
Specific embodiment
Present invention will be further explained below with reference to specific examples.It should be understood that these embodiments are merely to illustrate the present invention Rather than it limits the scope of the invention.In addition, it should also be understood that, after reading the content taught by the present invention, those skilled in the art Member can make various changes or modifications the present invention, and such equivalent forms equally fall within the application the appended claims and limited Range.
A kind of method that linen look staple fiber is prepared by flexible auxetic compound fabric based on mull technique provided by the invention, packet Include following steps:
(a) template for being carved with auxetic structure pattern is set, by linen look staple fiber along the auxetic structure pattern in template Uniform laying arrangement.
Auxetic structure pattern includes indent honeycomb, star network, indent diamond shape, regular dodecahedron, triangle grid, center rotation It is torque shape, center rotary triangle shape, center rotation tetrahedron, chiral honeycomb, center polygonal, hinged hexagon, hinged Quadrangle, hinged triangle and combinations thereof, preferably indent hexagon cellular structure.
(b) binder is sprayed on by the linen look staple fiber of auxetic structure pattern laying set by step (a), infiltrates linen look Staple fiber increases the contact action power between adjacent fiber;In order to stablize the auxetic composite structure of staple fiber base, in auxetic It is the binder of high rigidity after sprinkling solidifies on intersection point on structure plan, is the viscous of soft after sprinkling solidifies between intersection point Agent is tied, makes the auxetic composite material of staple fiber base that there is flexibility.
The binder for after solidification being soft is organic silicon adhesive, water-based polyurethane adhesive;It is high after the solidification The binder of hardness is epoxyn, polyester adhesive, acrylate adhesive.Hardness after binder solidifies is phase To hardness, i.e., hardness is higher than non-point of intersection after used binder solidification at auxetic structure pattern intersection point.
Cured method includes that air oxidation solidification, solvent volatilization solidification, high temperature thermal finalization, room temperature is cold formed, ultraviolet light Solidifying and setting, radiation sizing, thermal response solidification, chemical reaction solidification, melting and solidification, the solidification of IR Catalysis thermal response.
Linen look staple fiber includes ramie, flax, jute, bluish dogbane, hemp, sisal hemp, piemarker, bluish dogbane, abaca, discarded circulation Staple fiber
(c) the linen look staple fiber compound fabric solidifying and setting for obtaining step (b), the flexible auxetic for forming stable structure are multiple Close fabric.
The flexible auxetic compound fabric being prepared by the above method is by cutting and sewing as mesh bag, protection isolation Set, the function textiles such as cup mat or curtain.

Claims (9)

1. a kind of method that linen look staple fiber is prepared into flexible auxetic compound fabric based on mull technique, which is characterized in that including Following steps:
(a) template for being carved with auxetic structure pattern is set, linen look staple fiber is uniform along the auxetic structure pattern in template Laying arrangement;
(b) binder is sprayed on by the linen look staple fiber of auxetic structure pattern laying set by step (a), infiltrates the short fibre of linen look Dimension increases the contact action power between adjacent fiber;In order to stablize the auxetic composite structure of staple fiber base, in auxetic structure It is the binder of high rigidity after sprinkling solidifies on intersection point on pattern, is the bonding of soft after sprinkling solidifies between intersection point Agent makes the auxetic composite material of staple fiber base have flexibility;
(c) the linen look staple fiber compound fabric solidifying and setting for obtaining step (b), the flexible auxetic for forming stable structure compound are knitted Object.
2. a kind of side that linen look staple fiber is prepared into flexible auxetic compound fabric based on mull technique as described in claim 1 Method, which is characterized in that the auxetic structure pattern includes indent honeycomb, star network, indent diamond shape, regular dodecahedron, triangle Grid, center rotation rectangle, center rotary triangle shape, chiral honeycomb, center polygonal, hinged hexagon, hinged four side Shape, hinged triangle and combinations thereof.
3. a kind of side that linen look staple fiber is prepared into flexible auxetic compound fabric based on mull technique as claimed in claim 2 Method, which is characterized in that the preferred indent hexagon cellular structure of auxetic structure pattern.
4. a kind of side that linen look staple fiber is prepared into flexible auxetic compound fabric based on mull technique as described in claim 1 Method, which is characterized in that the binder for after the solidification being soft is organic silicon adhesive, water-based polyurethane adhesive;It is described The binder for after solidification being high rigidity is epoxyn, polyester adhesive, acrylate adhesive.
5. a kind of side that linen look staple fiber is prepared into flexible auxetic compound fabric based on mull technique as described in claim 1 Method, which is characterized in that the hardness after binder solidifies is relative hardness, i.e., institute is solid using binder at auxetic structure pattern intersection point Hardness is higher than non-point of intersection after change.
6. a kind of side that linen look staple fiber is prepared into flexible auxetic compound fabric based on mull technique as described in claim 1 Method, which is characterized in that the linen look staple fiber includes ramie, flax, jute, bluish dogbane, hemp, sisal hemp, piemarker, bluish dogbane, any of several broadleaf plants Fiber crops, the staple fiber for discarding circulation.
7. a kind of side that linen look staple fiber is prepared into flexible auxetic compound fabric based on mull technique as described in claim 1 Method, which is characterized in that the cured method includes that solvent volatilization solidification, high temperature thermal finalization, room temperature is cold formed, ultraviolet light solidifies Sizing, radiation sizing, thermal response solidification, chemical reaction solidification, melting and solidification.
8. a kind of purposes for the flexible auxetic compound fabric being prepared using claim 1 the method, which is characterized in that soft Property auxetic compound fabric by cut and sewing be used as function textile.
9. a kind of purposes of flexible auxetic compound fabric as claimed in claim 8, which is characterized in that the function textile is Mesh bag, protection separation sleeve, cup mat or curtain.
CN201710127780.XA 2017-03-06 2017-03-06 The method that linen look staple fiber is prepared into flexible auxetic compound fabric based on mull technique Expired - Fee Related CN106948081B (en)

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CN107988674B (en) * 2017-11-30 2020-08-11 东华大学 Method and device for processing friction-spun negative Poisson ratio yarn with front-mounted auxetic structure
CN107904785B (en) * 2017-12-27 2020-08-11 东华大学 Preparation device and method and application of soft and elastic stretch-expansion grid non-woven fabric
CN108660525B (en) * 2018-05-03 2021-05-25 东华大学 Processing method, device and application of conductive auxetic mesh based on auxetic wire
CN108749062B (en) * 2018-05-03 2020-07-31 东华大学 Processing method, device and application of auxetic fiber prepared based on template
KR102288913B1 (en) * 2018-08-16 2021-08-10 전남대학교산학협력단 Synclatic curvature deformable sandwich panel and fabrication method thereof

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