CN106947395B - Preparation method of light-colored polymerized rosin - Google Patents
Preparation method of light-colored polymerized rosin Download PDFInfo
- Publication number
- CN106947395B CN106947395B CN201710115643.4A CN201710115643A CN106947395B CN 106947395 B CN106947395 B CN 106947395B CN 201710115643 A CN201710115643 A CN 201710115643A CN 106947395 B CN106947395 B CN 106947395B
- Authority
- CN
- China
- Prior art keywords
- polymerized rosin
- light
- colored
- catalyst
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 title claims abstract description 63
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 title claims abstract description 63
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 title claims abstract description 63
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 238000006243 chemical reaction Methods 0.000 claims abstract description 24
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 23
- 239000008158 vegetable oil Substances 0.000 claims abstract description 23
- 239000003054 catalyst Substances 0.000 claims abstract description 19
- 241000779819 Syncarpia glomulifera Species 0.000 claims abstract description 17
- 239000001739 pinus spp. Substances 0.000 claims abstract description 17
- 229940036248 turpentine Drugs 0.000 claims abstract description 17
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002904 solvent Substances 0.000 claims abstract description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000001257 hydrogen Substances 0.000 claims abstract description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 8
- UKVIEHSSVKSQBA-UHFFFAOYSA-N methane;palladium Chemical group C.[Pd] UKVIEHSSVKSQBA-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 5
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims abstract description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 6
- 244000043261 Hevea brasiliensis Species 0.000 claims description 4
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 4
- 229920003052 natural elastomer Polymers 0.000 claims description 4
- 229920001194 natural rubber Polymers 0.000 claims description 4
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 4
- 235000019483 Peanut oil Nutrition 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000004359 castor oil Substances 0.000 claims description 3
- 235000019438 castor oil Nutrition 0.000 claims description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 3
- 235000021388 linseed oil Nutrition 0.000 claims description 3
- 239000000944 linseed oil Substances 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000000312 peanut oil Substances 0.000 claims description 3
- 239000003549 soybean oil Substances 0.000 claims description 3
- 235000012424 soybean oil Nutrition 0.000 claims description 3
- 229910045601 alloy Inorganic materials 0.000 claims description 2
- 239000000956 alloy Substances 0.000 claims description 2
- 239000001293 FEMA 3089 Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000003963 antioxidant agent Substances 0.000 description 5
- 230000003078 antioxidant effect Effects 0.000 description 4
- 238000004040 coloring Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229910001252 Pd alloy Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000013064 chemical raw material Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 238000013401 experimental design Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F1/00—Obtaining purification, or chemical modification of natural resins, e.g. oleo-resins
- C09F1/04—Chemical modification, e.g. esterification
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Developing Agents For Electrophotography (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710115643.4A CN106947395B (en) | 2017-03-01 | 2017-03-01 | Preparation method of light-colored polymerized rosin |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710115643.4A CN106947395B (en) | 2017-03-01 | 2017-03-01 | Preparation method of light-colored polymerized rosin |
Publications (2)
Publication Number | Publication Date |
---|---|
CN106947395A CN106947395A (en) | 2017-07-14 |
CN106947395B true CN106947395B (en) | 2020-04-10 |
Family
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Family Applications (1)
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CN201710115643.4A Active CN106947395B (en) | 2017-03-01 | 2017-03-01 | Preparation method of light-colored polymerized rosin |
Country Status (1)
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CN (1) | CN106947395B (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107603486B (en) * | 2017-09-20 | 2020-02-21 | 广西鼎弘树脂有限公司 | Light-colored high-stability polymerized rosin resin and preparation method thereof |
CN107699137A (en) * | 2017-11-01 | 2018-02-16 | 南宁市青秀区嘉利林化有限公司 | A kind of method that high-quality newtrex pentaerythritol ester is prepared using crude product as raw material |
CN107573853A (en) * | 2017-11-01 | 2018-01-12 | 南宁市青秀区嘉利林化有限公司 | A kind of method that light newtrex is produced using newtrex crude product as raw material |
CN107573852A (en) * | 2017-11-01 | 2018-01-12 | 南宁市青秀区嘉利林化有限公司 | A kind of newtrex light new technology |
CN107652896A (en) * | 2017-11-01 | 2018-02-02 | 南宁市青秀区嘉利林化有限公司 | A kind of method that light hydrogenated rosin is prepared using rosin as raw material |
CN107699136A (en) * | 2017-11-01 | 2018-02-16 | 南宁市青秀区嘉利林化有限公司 | A kind of new technology that light product is prepared using polymerized rosin glycerol ester crude product |
CN108587471B (en) * | 2018-01-09 | 2019-11-01 | 广西鼎弘树脂有限公司 | A kind of an ultra shallow color high stability disproportionated rosin and preparation method thereof |
CN108559403B (en) * | 2018-01-09 | 2019-11-05 | 广西鼎弘树脂有限公司 | A kind of an ultra shallow color high stability acrylic acid rosin and preparation method thereof |
CN111393996B (en) * | 2020-04-21 | 2022-02-15 | 广东科茂林产化工股份有限公司 | Polymerized rosin mixed ester and preparation method and application thereof |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104119801B (en) * | 2014-07-30 | 2016-01-20 | 广西众昌树脂有限公司 | The preparation method of polymerized rosin glycerol ester |
CN106010267A (en) * | 2016-05-26 | 2016-10-12 | 广西众昌树脂有限公司 | Method for producing hydrogenated rosin |
CN106010268A (en) * | 2016-05-26 | 2016-10-12 | 广西众昌树脂有限公司 | Method for producing hydrogenated rosin glyceride |
-
2017
- 2017-03-01 CN CN201710115643.4A patent/CN106947395B/en active Active
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CN106947395A (en) | 2017-07-14 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A preparation method for light colored polymerized rosin Effective date of registration: 20230925 Granted publication date: 20200410 Pledgee: Bank of China Limited Chongzuo Branch Pledgor: GUANGXI DINGHONG RESIN CO.,LTD. Registration number: Y2023980058786 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20200410 Pledgee: Bank of China Limited Chongzuo Branch Pledgor: GUANGXI DINGHONG RESIN CO.,LTD. Registration number: Y2023980058786 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right |