CN106947210A - A kind of 3D printing material - Google Patents
A kind of 3D printing material Download PDFInfo
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- CN106947210A CN106947210A CN201710262621.0A CN201710262621A CN106947210A CN 106947210 A CN106947210 A CN 106947210A CN 201710262621 A CN201710262621 A CN 201710262621A CN 106947210 A CN106947210 A CN 106947210A
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- parts
- printing material
- powder
- sitosterolum
- wollastonite
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/262—Alkali metal carbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of 3D printing material, include the raw material of following parts by weight：44 69 parts of ABS plastic master batch, 8 18 parts of PLA, 9 17 parts of Poly-s 179,4 10 parts of titania powder, 8 17 parts of polyisoprene, 15 parts of Sitosterolum, 0.1 1 parts of methyl acetate, 4 12 parts of potassium dihydrogen phosphite, 6 12 parts of wollastonite, 9 11 parts of wheat bran, 0.3 1 parts of Triallyl isocyanurate, 10 15 parts of dead leaf ashes, 16 parts of potassium feldspar.The 3D printing material has the advantages that intensity height, toughness are high；And insulating properties are good, cold resistance is good, and chemical stability is high；Simple production process, production cost is low, is conducive to the marketing of the 3D printing material.
Description
Technical field
The present invention relates to a kind of printed material, specifically a kind of 3D printing material.
Background technology
One kind of 3D printing, i.e. rapid shaping technique, it is a kind of based on mathematical model file, with powdered gold
Category or plastics etc. can jointing material, come the technology of constructed object by way of successively printing.3D printing is typically using numeral
Technologic material printer is realized.Often be used for modeling in fields such as Making mold, industrial designs, after be gradually available for one
The direct manufacture of a little products, has there is the parts printed using this technology.The technology is set in jewelry, footwear, industry
Meter, building, engineering and construction (AEC), automobile, Aero-Space, dentistry and medical industries, education, GIS-Geographic Information System, building work
Journey, gun and other field have all been applied.Country's 3D printing material production cost is higher at present, and also there is intensity, it is tough
The imperfect shortcoming of property, therefore, in the market needs the 3D printing material that a kind of production cost is low, intensity is high, toughness is high badly.
The content of the invention
It is an object of the invention to provide a kind of 3D printing material, the problem of to solve to propose in above-mentioned background technology.
To achieve the above object, the present invention provides following technical scheme：
A kind of 3D printing material, includes the raw material of following parts by weight：44-69 parts of ABS plastic master batch, 8-18 parts of PLA,
9-17 parts of Poly-s 179,4-10 parts of titania powder, 8-17 parts of polyisoprene, 1-5 parts of Sitosterolum, methyl acetate 0.1-1
Part, 4-12 parts of potassium dihydrogen phosphite, 6-12 parts of wollastonite, 9-11 parts of wheat bran, 0.3-1 parts of Triallyl isocyanurate, dead leaf
10-15 parts of ashes, 1-6 parts of potassium feldspar.
It is used as further scheme of the invention：Include the raw material of following parts by weight：58 parts of ABS plastic master batch, PLA 11
Part, 14 parts of Poly-s 179,6 parts of titania powder, 12 parts of polyisoprene, 4 parts of Sitosterolum, 0.3 part of methyl acetate, phosphorous
8 parts of acid dihydride potassium, 10 parts of wollastonite, 10 parts of wheat bran, 0.5 part of Triallyl isocyanurate, 12 parts of dead leaf ashes, potassium feldspar 2
Part.
It is used as further scheme of the invention：Include the raw material of following parts by weight：63 parts of ABS plastic master batch, PLA 9
Part, 10 parts of Poly-s 179,8 parts of titania powder, 9.5 parts of polyisoprene, 3.5 parts of Sitosterolum, 0.2 part of methyl acetate, Asia
6 parts of potassium dihydrogen phosphate, 7 parts of wollastonite, 9.5 parts of wheat bran, 0.8 part of Triallyl isocyanurate, 11 parts of dead leaf ashes, potassium feldspar
4 parts.
A kind of preparation method of 3D printing material, is made up of following steps：
(1) each raw material is weighed according to above-mentioned formula, it is standby；
(2) ABS plastic master batch, PLA, polyisoprene, Poly-s 179 high-temperature fusion are well mixed；
(3) upper step mixture is cooled to 40-55 DEG C, is put into extruder, heated, then extrusion is crushed and obtain powder；
(4) clay into power, and mixed with dead leaf ashes after wheat bran is dried, obtain mixture；
(5) by powder obtained by step (3) and titania powder, potassium dihydrogen phosphite, wollastonite, potassium feldspar, three allyls
The mixing of mixture heating stirring, 110-125 DEG C of heating-up temperature, speed of agitator 125- obtained by base isocyanuric acid ester and step (4)
155 turns/min, stir 30-50min；
(6) Sitosterolum, methyl acetate are added in step gains then up, continues to stir, whipping temp rises to 130-
150 DEG C, speed of agitator 100-110 turns/min, stirs 10-15min；
(7) 30-45 DEG C is cooled to, is heated and extruded by extruder, got product.
It is used as further scheme of the invention：Upper step mixture is cooled to 45-50 DEG C by the step (3), is put into extrusion
Machine, is heated, extrusion, is then crushed and is obtained powder.
It is used as further scheme of the invention：The step (5) is by powder obtained by step (3) and titania powder, Asia
Potassium dihydrogen phosphate, wollastonite, potassium feldspar, Triallyl isocyanurate and mixture heating stirring mixing obtained by step (4),
118 DEG C of heating-up temperature, 135 turns/min of speed of agitator stirs 45min.
It is used as further scheme of the invention：The step (6) walks then up adds Sitosterolum, acetic acid in gains
Methyl esters, continues to stir, and whipping temp rises to 145 DEG C, and 103 turns/min of speed of agitator stirs 12min.
Compared with prior art, the beneficial effects of the invention are as follows：
The 3D printing material has the advantages that intensity height, toughness are high；And insulating properties are good, cold resistance is good, and chemistry is steady
Qualitative height；Simple production process, production cost is low, is conducive to the marketing of the 3D printing material.
Embodiment
The technical scheme of this patent is described in more detail with reference to embodiment.
Embodiment 1
A kind of 3D printing material, includes the raw material of following parts by weight：44 parts of ABS plastic master batch, 8 parts of PLA, polyphenylene oxide
9 parts of sulfone, 4 parts of titania powder, 8 parts of polyisoprene, 1 part of Sitosterolum, 0.1 part of methyl acetate, 4 parts of potassium dihydrogen phosphite,
6 parts of wollastonite, 9 parts of wheat bran, 0.3 part of Triallyl isocyanurate, 10 parts of dead leaf ashes, 1 part of potassium feldspar.
A kind of preparation method of 3D printing material, is made up of following steps：
(1) each raw material is weighed according to above-mentioned formula, it is standby；
(2) ABS plastic master batch, PLA, polyisoprene, Poly-s 179 high-temperature fusion are well mixed；
(3) upper step mixture is cooled to 40 DEG C, is put into extruder, heated, then extrusion is crushed and obtain powder；
(4) clay into power, and mixed with dead leaf ashes after wheat bran is dried, obtain mixture；
(5) by powder obtained by step (3) and titania powder, potassium dihydrogen phosphite, wollastonite, potassium feldspar, three allyls
Mixture heating stirring mixing obtained by base isocyanuric acid ester and step (4), 110 DEG C of heating-up temperature, 125 turns of speed of agitator/
Min, stirs 30min；
(6) Sitosterolum, methyl acetate are added in step gains then up, continue to stir, whipping temp rises to 130 DEG C,
100 turns/min of speed of agitator, stirs 10min；
(7) 30 DEG C are cooled to, is heated and extruded by extruder, got product.
After testing, the flexility of the 3D printing material of embodiment 1 is：76.6Mpa, notch impact strength is：
47.9MJ/m2。
Embodiment 2
A kind of 3D printing material, includes the raw material of following parts by weight：69 parts of ABS plastic master batch, 18 parts of PLA, polyphenylene oxide
17 parts of sulfone, 10 parts of titania powder, 17 parts of polyisoprene, 5 parts of Sitosterolum, 1 part of methyl acetate, potassium dihydrogen phosphite 12
Part, 12 parts of wollastonite, 11 parts of wheat bran, 1 part of Triallyl isocyanurate, 15 parts of dead leaf ashes, 6 parts of potassium feldspar.
A kind of preparation method of 3D printing material, is made up of following steps：
(1) each raw material is weighed according to above-mentioned formula, it is standby；
(2) ABS plastic master batch, PLA, polyisoprene, Poly-s 179 high-temperature fusion are well mixed；
(3) upper step mixture is cooled to 55 DEG C, is put into extruder, heated, then extrusion is crushed and obtain powder；
(4) clay into power, and mixed with dead leaf ashes after wheat bran is dried, obtain mixture；
(5) by powder obtained by step (3) and titania powder, potassium dihydrogen phosphite, wollastonite, potassium feldspar, three allyls
Mixture heating stirring mixing obtained by base isocyanuric acid ester and step (4), 125 DEG C of heating-up temperature, 155 turns of speed of agitator/
Min, stirs 50min；
(6) Sitosterolum, methyl acetate are added in step gains then up, continue to stir, whipping temp rises to 150 DEG C,
110 turns/min of speed of agitator, stirs 15min；
(7) 45 DEG C are cooled to, is heated and extruded by extruder, got product.
After testing, the flexility of the 3D printing material of embodiment 3 is：76.3Mpa, notch impact strength is：
44.8MJ/m2。
Embodiment 3
A kind of 3D printing material, includes the raw material of following parts by weight：58 parts of ABS plastic master batch, 11 parts of PLA, polyphenylene oxide
14 parts of sulfone, 6 parts of titania powder, 12 parts of polyisoprene, 4 parts of Sitosterolum, 0.3 part of methyl acetate, potassium dihydrogen phosphite 8
Part, 10 parts of wollastonite, 10 parts of wheat bran, 0.5 part of Triallyl isocyanurate, 12 parts of dead leaf ashes, 2 parts of potassium feldspar.
A kind of preparation method of 3D printing material, is made up of following steps：
(1) each raw material is weighed according to above-mentioned formula, it is standby；
(2) ABS plastic master batch, PLA, polyisoprene, Poly-s 179 high-temperature fusion are well mixed；
(3) upper step mixture is cooled to 45-50 DEG C, is put into extruder, heated, then extrusion is crushed and obtain powder；
(4) clay into power, and mixed with dead leaf ashes after wheat bran is dried, obtain mixture；
(5) by powder obtained by step (3) and titania powder, potassium dihydrogen phosphite, wollastonite, potassium feldspar, three allyls
Mixture heating stirring mixing obtained by base isocyanuric acid ester and step (4), 118 DEG C of heating-up temperature, 135 turns of speed of agitator/
Min, stirs 45min；
(6) Sitosterolum, methyl acetate are added in step gains then up, continue to stir, whipping temp rises to 145 DEG C,
103 turns/min of speed of agitator, stirs 12min；
(7) 30-45 DEG C is cooled to, is heated and extruded by extruder, got product.
After testing, the flexility of the 3D printing material of embodiment 3 is：77.9Mpa, notch impact strength is：
49.5MJ/m2。
Embodiment 4
A kind of 3D printing material, includes the raw material of following parts by weight：63 parts of ABS plastic master batch, 9 parts of PLA, polyphenylene oxide
10 parts of sulfone, 8 parts of titania powder, 9.5 parts of polyisoprene, 3.5 parts of Sitosterolum, 0.2 part of methyl acetate, dihydrogen phosphite
6 parts of potassium, 7 parts of wollastonite, 9.5 parts of wheat bran, 0.8 part of Triallyl isocyanurate, 11 parts of dead leaf ashes, 4 parts of potassium feldspar.
A kind of preparation method of 3D printing material, is made up of following steps：
(1) each raw material is weighed according to above-mentioned formula, it is standby；
(2) ABS plastic master batch, PLA, polyisoprene, Poly-s 179 high-temperature fusion are well mixed；
(3) upper step mixture is cooled to 40-55 DEG C, is put into extruder, heated, then extrusion is crushed and obtain powder；
(4) clay into power, and mixed with dead leaf ashes after wheat bran is dried, obtain mixture；
(5) by powder obtained by step (3) and titania powder, potassium dihydrogen phosphite, wollastonite, potassium feldspar, three allyls
Mixture heating stirring mixing obtained by base isocyanuric acid ester and step (4), 120 DEG C of heating-up temperature, 130 turns of speed of agitator/
Min, stirs 40min；
(6) Sitosterolum, methyl acetate are added in step gains then up, continue to stir, whipping temp rises to 145 DEG C,
105 turns/min of speed of agitator, stirs 11min；
(7) 30-45 DEG C is cooled to, is heated and extruded by extruder, got product.
After testing, the flexility of the 3D printing material of embodiment 4 is：78.5Mpa, notch impact strength is：
48.1MJ/m2。
In summary, the 3D printing material has the advantages that intensity height, toughness are high；And insulating properties are good, cold resistance is good
Good, chemical stability is high；Simple production process, production cost is low, is conducive to the marketing of the 3D printing material, further pushes away
The development of domestic 3D materials is entered.
The better embodiment to this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party
, can also be on the premise of this patent objective not be departed from formula, the knowledge that one skilled in the relevant art possesses
Make a variety of changes.
Claims (7)
1. a kind of 3D printing material, it is characterised in that include the raw material of following parts by weight：44-69 parts of ABS plastic master batch, PLA
8-18 parts, 9-17 parts of Poly-s 179,4-10 parts of titania powder, 8-17 parts of polyisoprene, 1-5 parts of Sitosterolum, tumer
0.1-1 parts of ester, 4-12 parts of potassium dihydrogen phosphite, 6-12 parts of wollastonite, 9-11 parts of wheat bran, Triallyl isocyanurate 0.3-1
Part, 10-15 parts of dead leaf ashes, 1-6 parts of potassium feldspar.
2. 3D printing material according to claim 1, it is characterised in that include the raw material of following parts by weight：ABS plastic
58 parts of master batch, 11 parts of PLA, 14 parts of Poly-s 179,6 parts of titania powder, 12 parts of polyisoprene, 4 parts of Sitosterolum, acetic acid
0.3 part of methyl esters, 8 parts of potassium dihydrogen phosphite, 10 parts of wollastonite, 10 parts of wheat bran, 0.5 part of Triallyl isocyanurate, dead leaf ash
12 parts of cinder, 2 parts of potassium feldspar.
3. 3D printing material according to claim 1, it is characterised in that include the raw material of following parts by weight：ABS plastic
63 parts of master batch, 9 parts of PLA, 10 parts of Poly-s 179,8 parts of titania powder, 9.5 parts of polyisoprene, 3.5 parts of Sitosterolum, vinegar
Sour 0.2 part of methyl esters, 6 parts of potassium dihydrogen phosphite, 7 parts of wollastonite, 9.5 parts of wheat bran, 0.8 part of Triallyl isocyanurate, dead leaf
11 parts of ashes, 4 parts of potassium feldspar.
4. the preparation method of a kind of 3D printing material as described in claim 1-3 is any, it is characterised in that by following steps system
Into：
(1) each raw material is weighed according to above-mentioned formula, it is standby；
(2) ABS plastic master batch, PLA, polyisoprene, Poly-s 179 high-temperature fusion are well mixed；
(3) upper step mixture is cooled to 40-55 DEG C, is put into extruder, heated, then extrusion is crushed and obtain powder；
(4) clay into power, and mixed with dead leaf ashes after wheat bran is dried, obtain mixture；
(5) it is powder obtained by step (3) and titania powder, potassium dihydrogen phosphite, wollastonite, potassium feldspar, triallyl is different
The mixing of mixture heating stirring, 110-125 DEG C of heating-up temperature, speed of agitator 125-155 obtained by cyanurate and step (4)
Turn/min, stir 30-50min；
(6) Sitosterolum, methyl acetate are added in step gains then up, continue to stir, whipping temp rises to 130-150 DEG C,
Speed of agitator 100-110 turns/min, stirs 10-15min；
(7) 30-45 DEG C is cooled to, is heated and extruded by extruder, got product.
5. the preparation method of 3D printing material according to claim 4, it is characterised in that the step (3) mixes upper step
Compound is cooled to 45-50 DEG C, is put into extruder, heats, extrusion, then crushes and obtains powder.
6. the preparation method of 3D printing material according to claim 4, it is characterised in that the step (5) is by step (3)
Gained powder and titania powder, potassium dihydrogen phosphite, wollastonite, potassium feldspar, Triallyl isocyanurate and step
(4) mixing of gained mixture heating stirring, 118 DEG C of heating-up temperature, 135 turns/min of speed of agitator, stir 45min.
7. the preparation method of 3D printing material according to claim 4, it is characterised in that the step (6) is then up
Walk and Sitosterolum, methyl acetate added in gains, continue to stir, whipping temp rises to 145 DEG C, 103 turns/min of speed of agitator,
Stir 12min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710262621.0A CN106947210A (en) | 2017-04-20 | 2017-04-20 | A kind of 3D printing material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710262621.0A CN106947210A (en) | 2017-04-20 | 2017-04-20 | A kind of 3D printing material |
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| Publication Number | Publication Date |
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| CN106947210A true CN106947210A (en) | 2017-07-14 |
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ID=59477205
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710262621.0A Pending CN106947210A (en) | 2017-04-20 | 2017-04-20 | A kind of 3D printing material |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107739511A (en) * | 2017-09-26 | 2018-02-27 | 芜湖天梦信息科技有限公司 | A kind of 3D printing material using PSU as matrix |
| CN114147954A (en) * | 2021-12-01 | 2022-03-08 | 深圳市中蓝绿源科技有限公司 | Method for directly printing methanol fuel cell shell by adopting 3D printing technology |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104893334A (en) * | 2015-06-08 | 2015-09-09 | 东北林业大学 | Green environment-friendly 3D printing wire and preparation method thereof |
| CN104945837A (en) * | 2015-07-15 | 2015-09-30 | 上海锦湖日丽塑料有限公司 | ABS/PLA alloy resin combination for 3D printing and preparation method thereof |
-
2017
- 2017-04-20 CN CN201710262621.0A patent/CN106947210A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104893334A (en) * | 2015-06-08 | 2015-09-09 | 东北林业大学 | Green environment-friendly 3D printing wire and preparation method thereof |
| CN104945837A (en) * | 2015-07-15 | 2015-09-30 | 上海锦湖日丽塑料有限公司 | ABS/PLA alloy resin combination for 3D printing and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107739511A (en) * | 2017-09-26 | 2018-02-27 | 芜湖天梦信息科技有限公司 | A kind of 3D printing material using PSU as matrix |
| CN114147954A (en) * | 2021-12-01 | 2022-03-08 | 深圳市中蓝绿源科技有限公司 | Method for directly printing methanol fuel cell shell by adopting 3D printing technology |
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