CN106946558A - A kind of forsterite periclase spinelle complex phase lightweight refracrory and preparation method thereof - Google Patents
A kind of forsterite periclase spinelle complex phase lightweight refracrory and preparation method thereof Download PDFInfo
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- CN106946558A CN106946558A CN201710258401.0A CN201710258401A CN106946558A CN 106946558 A CN106946558 A CN 106946558A CN 201710258401 A CN201710258401 A CN 201710258401A CN 106946558 A CN106946558 A CN 106946558A
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- forsterite
- complex phase
- raw material
- magnesium
- lightweight refracrory
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- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 239000000395 magnesium oxide Substances 0.000 title claims abstract description 20
- 235000012245 magnesium oxide Nutrition 0.000 title claims abstract description 20
- 229910052839 forsterite Inorganic materials 0.000 title claims abstract description 17
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title abstract description 9
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000011777 magnesium Substances 0.000 claims abstract description 40
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 40
- 239000002994 raw material Substances 0.000 claims abstract description 34
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000011148 porous material Substances 0.000 claims abstract description 15
- 239000000463 material Substances 0.000 claims abstract description 14
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 8
- 239000007767 bonding agent Substances 0.000 claims abstract description 7
- 238000003780 insertion Methods 0.000 claims abstract description 7
- 230000037431 insertion Effects 0.000 claims abstract description 7
- 238000001035 drying Methods 0.000 claims abstract description 6
- 238000003825 pressing Methods 0.000 claims abstract description 6
- 239000000758 substrate Substances 0.000 claims abstract description 6
- 239000003562 lightweight material Substances 0.000 claims abstract description 4
- 239000011029 spinel Substances 0.000 claims description 29
- 229910052596 spinel Inorganic materials 0.000 claims description 29
- 239000001095 magnesium carbonate Substances 0.000 claims description 11
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 11
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 11
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 11
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 6
- 239000011819 refractory material Substances 0.000 claims description 5
- 235000012239 silicon dioxide Nutrition 0.000 claims description 5
- 238000009792 diffusion process Methods 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 239000004375 Dextrin Substances 0.000 claims description 3
- 229920001353 Dextrin Polymers 0.000 claims description 3
- 240000007817 Olea europaea Species 0.000 claims description 3
- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 claims description 3
- 235000019425 dextrin Nutrition 0.000 claims description 3
- 239000010881 fly ash Substances 0.000 claims description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000010451 perlite Substances 0.000 claims description 3
- 235000019362 perlite Nutrition 0.000 claims description 3
- 239000003265 pulping liquor Substances 0.000 claims description 3
- 239000010453 quartz Substances 0.000 claims description 3
- 239000004576 sand Substances 0.000 claims description 3
- 238000005245 sintering Methods 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000011324 bead Substances 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- 229910010272 inorganic material Inorganic materials 0.000 claims description 2
- 239000011147 inorganic material Substances 0.000 claims description 2
- 229910052609 olivine Inorganic materials 0.000 claims description 2
- 239000010450 olivine Substances 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 239000013535 sea water Substances 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 235000012222 talc Nutrition 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- 239000012267 brine Substances 0.000 claims 1
- 229910052681 coesite Inorganic materials 0.000 claims 1
- 229910052906 cristobalite Inorganic materials 0.000 claims 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims 1
- 229910052682 stishovite Inorganic materials 0.000 claims 1
- 229910052905 tridymite Inorganic materials 0.000 claims 1
- 238000002156 mixing Methods 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000843 powder Substances 0.000 description 6
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 238000001354 calcination Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 241001131796 Botaurus stellaris Species 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- KMWBBMXGHHLDKL-UHFFFAOYSA-N [AlH3].[Si] Chemical compound [AlH3].[Si] KMWBBMXGHHLDKL-UHFFFAOYSA-N 0.000 description 1
- MKPXGEVFQSIKGE-UHFFFAOYSA-N [Mg].[Si] Chemical compound [Mg].[Si] MKPXGEVFQSIKGE-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
- C04B35/20—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in magnesium oxide, e.g. forsterite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/66—Monolithic refractories or refractory mortars, including those whether or not containing clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/36—Glass starting materials for making ceramics, e.g. silica glass
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/444—Halide containing anions, e.g. bromide, iodate, chlorite
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/74—Physical characteristics
- C04B2235/77—Density
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
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- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The present invention relates to a kind of forsterite periclase spinelle complex phase lightweight refracrory and preparation method thereof.This method comprises the following steps：10~70% magnesia raw material, 1~60% magnesium siliceous raw material, 1~30% siliceous raw material and 5~30% alumina-silica pore forming agent are well mixed, then 2~10% bonding agent of additional above-mentioned raw materials mass percent sum is kneaded, and obtains mixing pug；Pug mechanical pressing is obtained being put into after base substrate, body drying in high temperature kiln and calcined 2~8 hours under conditions of 1500~1650 DEG C, that is, obtains forsterite periclase spinelle complex phase lightweight refracrory.The present invention uses alumina-silica inorganic lightweight material for pore forming agent, is discharged in production process without gas from material internal, does not form a large amount of insertion stomatas；Obtained forsterite periclase spinelle complex phase lightweight refracrory has the characteristics of compressive resistance is high, heat-proof quality is good, high-temperature behavior is excellent.
Description
Technical field
The present invention relates to a kind of light thermal-shield refractory material used by fire resisting material field, more particularly to a kind of magnesium olive
Stone-square magnesium stone-spinel complex phase lightweight refracrory and preparation method thereof.
Background technology
The light thermal-shield refractory material of function admirable is used in high temperature kiln, furnace heat efficiency can be effectively improved, dropped
Low-heat is consumed.However, traditional porous refractory is due to short texture, combine weak between crystal, the apparent porosity of insertion is high
Cause that the compression strength of material is poor, temperature in use is low, effect of heat insulation is general, therefore the high performance light thermal-shield refractory of Speeding up development
Material is one of presently most important developing direction.
Current complex phase porous material is based on corundum-mullite matter and periclase-white olivine, forsterite-side's magnesium
The application of stone-spinel complex phase fire material is relatively fewer.Literature research shows that forsterite-square magnesium stone-spinel complex phase is resistance to
Fiery material is with very excellent normal temperature and high-temperature behavior.（Othman A M G, Khalil N M. Sintering of
magnesia refractories through the formation of periclase- forsterite- spinel
Phases ［ J ］ Ceramics international, 2005, (31):1117- 1121）.It is porous light further to enrich
Porous periclase-forsterite-spinelle composite ceramic material of the species of material, patent of invention " and preparation method thereof "（CN
104086206 A）Disclose with magnesite, clay powder and Al (OH)3Powder is primary raw material, utilizes in magnesite heating process points
Solve CO2The pore formation mechanism of gas, is prepared for porous periclase-forsterite-spinelle composite ceramic material.This method is in calcining
During have a large amount of gases from material internal discharge, prepared stomata is generally insertion shape stomata, to the normal temperature and high temperature of material
Mechanical property is adversely affected.
The content of the invention
The object of the invention be exactly directed to the weak point in the presence of above-mentioned prior art and provide a kind of compressive resistance it is high,
Heat-proof quality is good, temperature in use is high, the forsterite of high volume good stability-square magnesium stone-spinel complex phase light-weight refractory material
Material and preparation method thereof.
The purpose of the present invention can be realized by following technical proposals：
Forsterite-square magnesium stone-spinel complex phase lightweight refracrory of the present invention includes the raw material of following weight percentage:
10~70% magnesia raw material, 1~60% magnesium siliceous raw material, 1~30% siliceous raw material and 5~30% aluminium silicon
Matter pore forming agent, and above-mentioned raw materials percentage by weight sum 2~10% bonding agent.
Magnesia raw material of the present invention is derived from highly-purity magnesite, magnesite clinker, fused magnesite, seawater magnesia and bittern
One or more of combinations in magnesia, raw material particle size≤0.088mm.Described magnesium siliceous raw material is derived from high silicon magnesia, magnesium silicon
One or more of combinations in sand, forsterite, serpentine, talcum, raw material particle size≤0.088mm.Described titanium dioxide
Siliceous raw material is derived from SiO in one or more of combinations in vitreous silica, siliceous clinker or natural quartz, raw material2Quality hundred
Divide content >=98.0%.Described alumina-silica pore forming agent be derived from one kind in glass bead, fly ash float or closed perlite or
Several combinations.Described bonding agent is derived from one in spent pulping liquor, dextrin, magnesium chloride, polyethylene glycol or silicon dioxide gel
Plant or several combinations.
The preparation method step of the present invention is as follows：
（1）Magnesia raw material, magnesium siliceous raw material, siliceous raw material and alumina-silica pore forming agent are well mixed, added
Bonding agent is kneaded, and obtains pug；
（2）Above-mentioned pug mechanical pressing is obtained into base substrate；
（3）It will be put into high temperature kiln and calcined 2~8 hours under the conditions of 1500~1650 DEG C after body drying, that is, obtain magnesium olive
Olive stone-square magnesium stone-spinel complex phase lightweight refracrory.
Forsterite of the present invention-square magnesium stone-spinel complex phase lightweight refracrory is using inorganic lightweight material as increasing
Hole agent, make use of the mechanism of inorganic material Reaction-diffusion terms in sintering process, and the homogenizing of composition is reached by Reaction-diffusion terms；It is made
Standby forsterite-square magnesium stone-spinel complex phase lightweight refracrory is using forsterite as principal crystalline phase, and periclase and spinelle are
Secondary crystalline phase；Material hole wall structure is fine and close, does not form a large amount of continuous insertion stomatas；Prepared forsterite-periclase-point is brilliant
The cold crushing strength of stone complex phase lightweight refracrory is 15~80MPa, and bulk density is 1.2~2.0g/cm3, loading softening
Temperature（0.2MPa）≥1500℃.
Beneficial effects of the present invention are as follows：
The present invention utilizes the inorganic lightweight material of alumina-silica for pore forming agent, and organic pore former or carbonate are avoided in preparation process
Pore former because produced in calcination process gas discharge formed by insertion stomata.Material employs high temperature in preparation process
Calcine technology, the hole wall structure formed is fine and close, and intergranular combines densification and insertion stomata is less, is conducive to obtaining preferable normal temperature
Performance and high-temperature behavior.
Brief description of the drawings
Fig. 1 is the XRD spectrum of forsterite-square magnesium stone-spinel complex phase lightweight refracrory.
Fig. 2 is the microstructure photograph of forsterite-square magnesium stone-spinel complex phase lightweight refracrory.
Embodiment：
The present invention is further described below with reference to embodiment：
Embodiment 1
By mass percentage by 60% magnesite clinker fine powder, 10% magnesium silica sand fine powder, 15% vitreous silica and 15% closed pore
Perlite be well mixed, then additional above-mentioned raw materials mass percent sum 4% dextrin as additive, be uniformly mixing to obtain mixed
Close pug；Pug mechanical pressing is obtained into base substrate；After body drying, place into high temperature furnace and calcine 5 under the conditions of 1550 DEG C
Hour, that is, obtain forsterite-square magnesium stone-spinel complex phase lightweight refracrory.
The technical indicator of forsterite-square magnesium stone-spinel complex phase lightweight refracrory prepared by the present embodiment is：Body
Product density 1.3g/cm3, compressive resistance is 18MPa, and refractoriness under load is（0.2MPa）For 1520 DEG C.
Embodiment 2
55% fused magnesite fine powder, 10% serpentine, 15% natural quartz and 20% flyash are floated by mass percentage
Pearl be well mixed, then additional above-mentioned raw materials mass percent sum 5% spent pulping liquor as additive, be uniformly mixing to obtain mixed
Close pug；Pug mechanical pressing is obtained into base substrate；After body drying, place into high temperature furnace and calcine 6 under the conditions of 1600 DEG C
Hour, that is, obtain forsterite-square magnesium stone-spinel complex phase lightweight refracrory.
The technical indicator of forsterite-square magnesium stone-spinel complex phase lightweight refracrory prepared by the present embodiment is：Body
Product density 1.25g/cm3, compressive resistance is 32MPa, and refractoriness under load is（0.2MPa）For 1580 DEG C.
Embodiment 3
It is by mass percentage that 60% highly-purity magnesite fine powder, 10% forsterite, 10% siliceous clinker and 20% vitreous is micro-
Pearl be well mixed, then additional above-mentioned raw materials mass percent sum 5% magnesium chloride as additive, be uniformly mixing to obtain mixing
Pug；Pug mechanical pressing is obtained into base substrate；After body drying, the calcining 4 under the conditions of 1580 DEG C is placed into high temperature furnace small
When, that is, obtain forsterite-square magnesium stone-spinel complex phase lightweight refracrory.
The technical indicator of forsterite-square magnesium stone-spinel complex phase lightweight refracrory prepared by the present embodiment is：Body
Product density 1.5g/cm3, compressive resistance is 38MPa, and refractoriness under load is（0.2MPa）For 1530 DEG C.
Claims (8)
1. a kind of forsterite-square magnesium stone-spinel complex phase lightweight refracrory, it is characterised in that：It includes following weight hundred
Divide the raw material of ratio:Wherein 10~70% magnesia raw material, 1~60% magnesium siliceous raw material, 1~30% siliceous original
Material and 5~30% alumina-silica pore forming agent, and above-mentioned raw materials percentage by weight sum 2~10% bonding agent.
2. forsterite according to claim 1-square magnesium stone-spinel complex phase lightweight refracrory, it is characterised in that：Institute
The magnesia raw material stated is derived from one kind or several in highly-purity magnesite, magnesite clinker, fused magnesite, seawater magnesia and brine magnesia
The combination planted, raw material particle size≤0.088mm.
3. forsterite according to claim 1-square magnesium stone-spinel complex phase lightweight refracrory, it is characterised in that：Institute
The magnesium siliceous raw material stated is derived from one or more of combinations in high silicon magnesia, magnesium silica sand, forsterite, serpentine, talcum, former
Expect particle diameter≤0.088mm.
4. forsterite according to claim 1-square magnesium stone-spinel complex phase lightweight refracrory, it is characterised in that：Institute
The siliceous raw material stated is derived from one or more of combinations in vitreous silica, siliceous clinker or natural quartz, raw material
SiO2Weight/mass percentage composition >=98.0%.
5. forsterite according to claim 1-square magnesium stone-spinel complex phase lightweight refracrory, it is characterised in that：Institute
The alumina-silica pore forming agent stated is derived from one or more of combinations in glass bead, fly ash float or closed perlite.
6. forsterite according to claim 1-square magnesium stone-spinel complex phase lightweight refracrory, it is characterised in that：Institute
The bonding agent stated is derived from one or more of groups in spent pulping liquor, dextrin, magnesium chloride, polyethylene glycol or silicon dioxide gel
Close.
7. a kind of method for preparing forsterite described in claim 1-square magnesium stone-spinel complex phase lightweight refracrory,
It is characterized in that：Methods described step is as follows：
（1）Magnesia raw material, magnesium siliceous raw material, siliceous raw material and alumina-silica pore forming agent are well mixed, added
Bonding agent is kneaded, and obtains pug；
（2）Above-mentioned pug mechanical pressing is obtained into base substrate；
（3）It will be put into high temperature kiln and calcined 2~8 hours under the conditions of 1500~1650 DEG C after body drying, that is, obtain magnesium olive
Olive stone-square magnesium stone-spinel complex phase lightweight refracrory.
8. method according to claim 7, it is characterised in that：Described forsterite-square magnesium stone-spinel complex phase lightweight
Refractory material make use of the mechanism of inorganic material Reaction-diffusion terms in sintering process, pass through using inorganic lightweight material as pore forming agent
Reaction-diffusion terms reach the homogenizing of composition；Prepared forsterite-square magnesium stone-spinel complex phase lightweight refracrory is with olivine
For principal crystalline phase, periclase and spinelle are time crystalline phase；Material hole wall structure is fine and close, does not form a large amount of continuous insertion stomatas；Institute
The cold crushing strength of the forsterite of preparation-square magnesium stone-spinel complex phase lightweight refracrory is 15~80MPa, and volume is close
Spend for 1.2~2.0g/cm3, refractoriness under load under the conditions of 0.2 MPa >=1500 DEG C.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108129137A (en) * | 2018-01-12 | 2018-06-08 | 安徽海螺暹罗耐火材料有限公司 | Large-scale cement rotary kiln composite magnesium aluminate spinel brick and its production method |
| CN110922164A (en) * | 2019-12-11 | 2020-03-27 | 中南大学 | Preparation method of forsterite type complex phase heat insulation material |
| CN111747732A (en) * | 2020-05-13 | 2020-10-09 | 九江市璀鑫新材料有限公司 | High-tightness magnesium composite material and manufacturing method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101113097A (en) * | 2007-06-29 | 2008-01-30 | 武汉钢铁(集团)公司 | Infrared radiation porous ceramics on furnace lining firebrick and preparation method thereof |
| CN106431435A (en) * | 2016-09-22 | 2017-02-22 | 郑州大学 | Porous periclase-forsterite multiphase material and preparation method thereof |
-
2017
- 2017-04-19 CN CN201710258401.0A patent/CN106946558B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101113097A (en) * | 2007-06-29 | 2008-01-30 | 武汉钢铁(集团)公司 | Infrared radiation porous ceramics on furnace lining firebrick and preparation method thereof |
| CN106431435A (en) * | 2016-09-22 | 2017-02-22 | 郑州大学 | Porous periclase-forsterite multiphase material and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| A.G.M.OTHMAN等: "Sintering of magnesia refractories through the formation of periclase–forsterite–spinel phases", 《CERAMICS INTERNATIONAL》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108129137A (en) * | 2018-01-12 | 2018-06-08 | 安徽海螺暹罗耐火材料有限公司 | Large-scale cement rotary kiln composite magnesium aluminate spinel brick and its production method |
| CN110922164A (en) * | 2019-12-11 | 2020-03-27 | 中南大学 | Preparation method of forsterite type complex phase heat insulation material |
| CN111747732A (en) * | 2020-05-13 | 2020-10-09 | 九江市璀鑫新材料有限公司 | High-tightness magnesium composite material and manufacturing method thereof |
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| CN106946558B (en) | 2021-05-11 |
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Effective date of registration: 20230414 Address after: 452370 Group 9, Songlou Village, Laiji Town, Xinmi City, Zhengzhou City, Henan Province Patentee after: Zhengzhou jinheyuan refractory Co.,Ltd. Address before: 450001 No. 100, science Avenue, hi tech Industrial Development Zone, Henan, Zhengzhou Patentee before: Zhengzhou University |