CN106939418A - A kind of wire drawing film agent and application method - Google Patents
A kind of wire drawing film agent and application method Download PDFInfo
- Publication number
- CN106939418A CN106939418A CN201610003184.6A CN201610003184A CN106939418A CN 106939418 A CN106939418 A CN 106939418A CN 201610003184 A CN201610003184 A CN 201610003184A CN 106939418 A CN106939418 A CN 106939418A
- Authority
- CN
- China
- Prior art keywords
- agent
- nitric acid
- added
- sodium citrate
- zinc oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/12—Orthophosphates containing zinc cations
- C23C22/13—Orthophosphates containing zinc cations containing also nitrate or nitrite anions
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
Abstract
The invention discloses a kind of wire drawing film agent and application method, it is used in mixed way by A agent and B agent obtained, it is characterised in that nitric acid, 10-20% zinc oxide, 0.5-5% nickel nitrate, 0.5-5% ferric nitrate, 0.1-1% sodium citrate and the appropriate water of phosphoric acid, 10-20% including 30-40%；It processes skill：Zinc oxide is added to the water, phosphoric acid and nitric acid is added, stirs to tremble and is completely dissolved；Add nickel nitrate, ferric nitrate and sodium citrate and film agent A is both made until being completely dissolved；B agent is 0.01-0.1% natrium nitrosum；Using immersion type, take 5-10% A agent to be put into tank, add 0.01-0.1% natrium nitrosum；Wire rod is put into immersion 5 to 10 minutes by mixed liquor to 60-75 degrees Celsius in heating tank, takes out washing；Low cost, quarrel amount of sinking is few, and environmental protection increases the mold use life-span；Wire rod after processing has smooth homogeneous surface.
Description
Technical field
Wire rod appearance is covered in the present invention relates to wire drawing processing technique field, particularly one kind
The epithelium agent prescription and processing method in face.
Background technology
In the drawing production process of wire rod, film agent is wire surface is produced one layer of film
Chemicals, this film contributes to the lubrication that cold plasticity of wire rod adds, there is wire rod
The processing deformed beneficial to pull.Its effect is reduced metal and intermetallic friction；Increase mould
Service life；Allow faster drawing velocity and the bigger deformation processing of wire rod；Reduce processing
The loss of material, can make the wire rod after machining have smooth homogeneous surface, but how to reduce
Cost, reduction is the direction of this industry development to destruction of environment etc..
The content of the invention
It is good it is an object of the invention to provide a kind of coverage effect, can have during pull wire rod
Effect protection wire rod structure itself, increases mold use life-span, environmental protection, the wire rod skin of low cost
Film and its processing method.
To achieve the above object of the invention, the present invention uses following technical scheme：Wire drawing epithelium
Agent and application method, are used in mixed way obtained by A agent and B agent, it is characterised in that including 30-
40% phosphoric acid, 10-20% nitric acid, 10-20% zinc oxide, 0.5-5% nickel nitrate,
0.5-5% ferric nitrate, 0.1-1% sodium citrate and appropriate water；It processes skill：
First zinc oxide is added to the water, phosphoric acid and nitric acid is added, stirs to tremble and is completely dissolved；Add nitre
Film agent A is both made until being completely dissolved in sour nickel, ferric nitrate and sodium citrate；B agent is 0.01
- 0.1% natrium nitrosum.
Using immersion type, take 5-10% A agent to be put into tank, then add 0.01-
0.1% natrium nitrosum；Then mixed liquor is put wire rod to 60-75 degrees Celsius in heating tank
Enter immersion 5 to 10 minutes, take out washing.
Film agent and processing method are produced using above technology, low cost is environmentally friendly, can be effectively
Reduce metal and intermetallic friction；Increase the mold use life-span；Allow faster pull speed
Degree and the bigger deformation processing of wire rod；The loss of processing materials is reduced, can be made after machining
Wire rod has smooth homogeneous surface.
Embodiment
With reference to specific embodiment, the present invention will be described.
A kind of wire drawing film agent and application method, be used in mixed way by A agent and B agent it is obtained,
It is characterized in that the oxidation of the nitric acid, 10-20% of phosphoric acid, 10-20% including 30-40%
Zinc, 0.5-5% nickel nitrate, 0.5-5% ferric nitrate, 0.1-1% sodium citrate and suitable
The water of amount；It processes skill：First zinc oxide is added to the water, phosphoric acid and nitric acid is added, stirs
Tremble and be completely dissolved；Nickel nitrate, ferric nitrate and sodium citrate is added both to be made until being completely dissolved
Film agent A；B agent is 0.01-0.1% natrium nitrosum.
A kind of wire drawing film agent and application method, it is characterised in that use immersion type, take 5
- 10% A agent is put into tank, then adds 0.01-0.1% natrium nitrosum；Heating
Then wire rod is put into immersion 5 to 10 minutes, taken by mixed liquor to 60-75 degrees Celsius in groove
Go out washing.
The preferred plan of A agent：Phosphorus acid content is 35%, and nitric acid content is 15%；Zinc oxide
Content is 15%, and nitric acid iron content is 2%, and nitric acid nickel content is 3%, and sodium citrate contains
Measure as 0.5%, and appropriate water.
Embodiment one, phosphorus acid content is 30%, and nitric acid content is 20%；Zinc oxide content is
20%, nitric acid iron content is 5%, and nitric acid nickel content is 5%, and the content of sodium citrate is 1%,
And appropriate water.
Embodiment two, phosphorus acid content is 40%, and nitric acid content is 10%；Zinc oxide content is
10%, nitric acid iron content is 1%, and nitric acid nickel content is 1%, and the content of sodium citrate is 1%,
And appropriate water.
Embodiment three, phosphorus acid content is 38%, and nitric acid content is 12%；Zinc oxide content is
10%, nitric acid iron content is 1%, and nitric acid nickel content is 1%, and the content of sodium citrate is 1%,
And appropriate water.
Example IV, phosphorus acid content is 36%, and nitric acid content is 14%；Zinc oxide content is
15%, nitric acid iron content is 3%, and nitric acid nickel content is 2%, and the content of sodium citrate is 1%,
And appropriate water.
The film agent and processing method produced using above technology, low cost, environmental protection can effectively be subtracted
Few metal and intermetallic friction；Increase the mold use life-span；Allow faster drawing velocity
And the bigger deformation processing of wire rod；The loss of processing materials is reduced, the line after machining can be made
Material has smooth homogeneous surface.
Claims (2)
1. a kind of wire drawing film agent and application method, system is used in mixed way by A agent and B agent
, it is characterised in that the nitric acid of phosphoric acid, 10-20% including 30-40%, 10-20%
Zinc oxide, 0.5-5% nickel nitrate, 0.5-5% ferric nitrate, 0.1-1% sodium citrate
And appropriate water；It processes skill：First zinc oxide is added to the water, phosphoric acid and nitric acid is added,
Stir to tremble and be completely dissolved；Nickel nitrate, ferric nitrate and sodium citrate is added both to make until being completely dissolved
Obtain film agent A；B agent is 0.01-0.1% natrium nitrosum.
2. a kind of wire drawing film agent according to claim 1 and application method, it is special
It is to use immersion type to levy, and takes 5-10% A agent to be put into tank, then adds 0.01
- 0.1% natrium nitrosum；Mixed liquor is to 60-75 degrees Celsius in heating tank, then by wire rod
Immersion 5 to 10 minutes is put into, washing is taken out.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610003184.6A CN106939418A (en) | 2016-01-04 | 2016-01-04 | A kind of wire drawing film agent and application method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610003184.6A CN106939418A (en) | 2016-01-04 | 2016-01-04 | A kind of wire drawing film agent and application method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106939418A true CN106939418A (en) | 2017-07-11 |
Family
ID=59469153
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610003184.6A Pending CN106939418A (en) | 2016-01-04 | 2016-01-04 | A kind of wire drawing film agent and application method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106939418A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110129782A (en) * | 2019-05-20 | 2019-08-16 | 浙江伟星实业发展股份有限公司 | A kind of film agent, preparation method and pull head treatment process |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB760327A (en) * | 1953-05-22 | 1956-10-31 | Pyrene Co Ltd | Improvements in the formation of phosphate coatings on wire or strip |
| CN101634023A (en) * | 2008-07-24 | 2010-01-27 | 张燕 | Novel normal-temperature zinc series phosphating agent |
| CN102808172A (en) * | 2012-08-24 | 2012-12-05 | 安徽启明表面技术有限公司 | Universal environment-friendly non-phosphorus phosphating solution |
-
2016
- 2016-01-04 CN CN201610003184.6A patent/CN106939418A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB760327A (en) * | 1953-05-22 | 1956-10-31 | Pyrene Co Ltd | Improvements in the formation of phosphate coatings on wire or strip |
| CN101634023A (en) * | 2008-07-24 | 2010-01-27 | 张燕 | Novel normal-temperature zinc series phosphating agent |
| CN102808172A (en) * | 2012-08-24 | 2012-12-05 | 安徽启明表面技术有限公司 | Universal environment-friendly non-phosphorus phosphating solution |
Non-Patent Citations (1)
| Title |
|---|
| 石镇楢: "《包装材料生产方法选编》", 31 December 1986, 北京包装技术协会 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110129782A (en) * | 2019-05-20 | 2019-08-16 | 浙江伟星实业发展股份有限公司 | A kind of film agent, preparation method and pull head treatment process |
| CN110129782B (en) * | 2019-05-20 | 2021-10-22 | 浙江伟星实业发展股份有限公司 | Skin membrane agent, preparation method thereof and puller treatment process |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170711 |