CN106938848B - A kind of polybasic ion anti-bacteria ceramic filtrate and preparation method thereof - Google Patents
A kind of polybasic ion anti-bacteria ceramic filtrate and preparation method thereof Download PDFInfo
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- CN106938848B CN106938848B CN201710039808.4A CN201710039808A CN106938848B CN 106938848 B CN106938848 B CN 106938848B CN 201710039808 A CN201710039808 A CN 201710039808A CN 106938848 B CN106938848 B CN 106938848B
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- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 43
- 239000000706 filtrate Substances 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 33
- 239000000919 ceramic Substances 0.000 title claims abstract description 27
- 150000002500 ions Chemical class 0.000 claims abstract description 66
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 63
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 63
- 239000002245 particle Substances 0.000 claims abstract description 40
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 38
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 36
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000010457 zeolite Substances 0.000 claims abstract description 36
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 28
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229920002472 Starch Polymers 0.000 claims abstract description 27
- 235000019698 starch Nutrition 0.000 claims abstract description 27
- 239000008107 starch Substances 0.000 claims abstract description 27
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 25
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 25
- 239000002002 slurry Substances 0.000 claims abstract description 21
- 239000006004 Quartz sand Substances 0.000 claims abstract description 17
- 239000012535 impurity Substances 0.000 claims abstract description 13
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000001099 ammonium carbonate Substances 0.000 claims abstract description 12
- 235000012501 ammonium carbonate Nutrition 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 239000000243 solution Substances 0.000 claims description 88
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 34
- 238000003756 stirring Methods 0.000 claims description 26
- 230000004913 activation Effects 0.000 claims description 25
- 239000000377 silicon dioxide Substances 0.000 claims description 23
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 22
- 229910017604 nitric acid Inorganic materials 0.000 claims description 22
- 239000000843 powder Substances 0.000 claims description 21
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 20
- 238000000498 ball milling Methods 0.000 claims description 20
- 229910052802 copper Inorganic materials 0.000 claims description 20
- 239000010949 copper Substances 0.000 claims description 20
- 239000011701 zinc Substances 0.000 claims description 20
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 19
- 229910052725 zinc Inorganic materials 0.000 claims description 19
- 229960000583 acetic acid Drugs 0.000 claims description 17
- 239000012362 glacial acetic acid Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 16
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 15
- 230000015572 biosynthetic process Effects 0.000 claims description 15
- 238000001816 cooling Methods 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 15
- 229940043237 diethanolamine Drugs 0.000 claims description 14
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 14
- 229910001369 Brass Inorganic materials 0.000 claims description 13
- 239000010951 brass Substances 0.000 claims description 13
- 239000002131 composite material Substances 0.000 claims description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 12
- 238000012216 screening Methods 0.000 claims description 12
- 239000000725 suspension Substances 0.000 claims description 12
- 238000005406 washing Methods 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 11
- 238000000227 grinding Methods 0.000 claims description 11
- 238000003786 synthesis reaction Methods 0.000 claims description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 10
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims description 10
- 239000000047 product Substances 0.000 claims description 10
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 10
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 10
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 10
- 239000004115 Sodium Silicate Substances 0.000 claims description 9
- 239000007864 aqueous solution Substances 0.000 claims description 9
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 9
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 9
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 claims description 8
- 239000003830 anthracite Substances 0.000 claims description 8
- 239000003610 charcoal Substances 0.000 claims description 8
- 239000008367 deionised water Substances 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 8
- 239000003245 coal Substances 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 230000001376 precipitating effect Effects 0.000 claims description 6
- 239000004408 titanium dioxide Substances 0.000 claims description 6
- 229920000715 Mucilage Polymers 0.000 claims description 5
- 239000000853 adhesive Substances 0.000 claims description 5
- 238000004821 distillation Methods 0.000 claims description 5
- 239000008236 heating water Substances 0.000 claims description 5
- 239000000395 magnesium oxide Substances 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 239000011259 mixed solution Substances 0.000 claims description 5
- 238000007873 sieving Methods 0.000 claims description 5
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 5
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- 238000010791 quenching Methods 0.000 claims description 4
- 230000000171 quenching effect Effects 0.000 claims description 4
- 239000002244 precipitate Substances 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 2
- 238000007613 slurry method Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 16
- 241000894006 Bacteria Species 0.000 abstract description 13
- 244000005700 microbiome Species 0.000 abstract description 3
- 230000003115 biocidal effect Effects 0.000 description 7
- 238000001179 sorption measurement Methods 0.000 description 7
- 230000001954 sterilising effect Effects 0.000 description 6
- 229940088710 antibiotic agent Drugs 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 108090000623 proteins and genes Proteins 0.000 description 5
- 102000004169 proteins and genes Human genes 0.000 description 5
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 230000000845 anti-microbial effect Effects 0.000 description 4
- 210000002421 cell wall Anatomy 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 238000004659 sterilization and disinfection Methods 0.000 description 4
- 239000002023 wood Substances 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 210000004027 cell Anatomy 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 229910052622 kaolinite Inorganic materials 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 230000001580 bacterial effect Effects 0.000 description 2
- 238000002242 deionisation method Methods 0.000 description 2
- 229940031098 ethanolamine Drugs 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 108091032973 (ribonucleotides)n+m Proteins 0.000 description 1
- 229910001015 Alpha brass Inorganic materials 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 108020004999 messenger RNA Proteins 0.000 description 1
- -1 metals ion Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 150000004714 phosphonium salts Chemical group 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 150000004804 polysaccharides Polymers 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
- C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
- A01N59/20—Copper
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
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- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
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- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/442—Carbonates
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Abstract
The present invention relates to water-purifying material field, a kind of polybasic ion anti-bacteria ceramic filtrate and preparation method thereof is disclosed.The raw material of the polybasic ion anti-bacteria ceramic filtrate comprises the following components in parts by weight: 95-105 parts of starch slurry, 70-80 parts of kaolin particle, 120-130 parts of synthetic zeolite, 95-105 parts of active carbon, 45-55 parts of quartz sand, 95-105 parts of ammonium carbonate, 70-80 parts of polybasic ion antibacterial agent and 60-190 parts of water.Filtrate of the invention can not only filter impurities in water, moreover it is possible to adsorb, kill bacterium in water, microorganism etc..It is more compact to be compared to traditional filter core, convenient carrying, replacement is convenient, therefore application field is wider.
Description
Technical field
The present invention relates to water-purifying material fields more particularly to a kind of polybasic ion anti-bacteria ceramic filtrate and preparation method thereof.
Background technique
Now on the market for the filtering material of water purification generally very much, main filtering material is filter core.But mesh
The preceding most of or impurity to cross in drainage is main point, though impurity has filtered, these impurities in water are brought
Bacterium harm be also it is very big, can be to human body if not being filtered to the bacterium in water, going out and remove and directly drink water
Assembly healthy hidden danger.The sterilization of drinking water at present, major way are that heat sterilization either ultraviolet sterilization is carried out to water.But this
A little sterilizing means are required by external energy.And for the container that needs are carried and are drunk water, just it can not carry out
It sterilizes.
In addition, filter core is typically all to need to be fabricated to fixed shape to be filtered water, filter core is typically direct
It is installed in container and container systems selling.After when long-time, if necessary to be replaced to filter core, not only more not
Just, and higher cost is updated.It is therefore desirable to send out output it is a kind of itself just have the function of impurity screening, bacterium, and convenient for taking
Band, at low cost, the convenient filtering material of replacement.
Summary of the invention
In order to solve the above-mentioned technical problems, the present invention provides a kind of polybasic ion anti-bacteria ceramic filtrate and its preparation sides
Method.Filtrate of the invention can not only filter impurities in water, moreover it is possible to adsorb, kill bacterium in water, microorganism etc..It is compared to tradition
Filter core it is more compact, convenient carrying, replacement is convenient, therefore application field is wider.
The specific technical proposal of the invention is: a kind of polybasic ion anti-bacteria ceramic filtrate, raw material includes following parts by weight
Component: 95-105 parts of starch slurry, 70-80 parts of kaolin particle, 120-130 parts of synthetic zeolite, 95-105 parts of active carbon, quartz sand
45-55 parts, 95-105 parts of ammonium carbonate, 70-80 parts of polybasic ion antibacterial agent and 60-190 parts of water.
Anti-bacteria ceramic filtrate of the invention can not only effective impurity screening, and can also effectively adsorb, eliminating bacteria.And
And filtrate is in granular form compared with filter core, application surface is wider, unlike filter core is limited only to water purification cartridge since shape limits
It sets.
In filtrate of the present invention, synthetic zeolite has good adsorptivity, and wherein the metals such as absorbing copper, lead, cadmium, nickel, molybdenum are micro-
The ability of grain is particularly pertinent.And synthetic zeolite also has the function of preventing bumping, can effectively prevent the upward punching of liquid,
It is able to maintain liquid when heating steadily.Polybasic ion antibacterial agent coupled ion antibacterial mechanisms and micro- magnetoelectricity field technology principle resist
Bacterium property stability is good, and antibacterial activity is high, and has adsorption capacity.Active carbon has adsorption rate fast, the strong feature of adsorption capacity.
Kaolin has good plasticity, conducive to the granulating and forming of filtrate.Starch slurry is not only easy to get, at low cost, and environmentally protective,
It is harmless to water quality.And its compatibility between each component in filtrate of the present invention, adhesiveness are good.Ammonium carbonate is soluble easily in water, energy
The poisonous metals such as enough preferably auxiliary removal cadmiums, nickel.Quartz sand high mechanical strength, retaining power are strong.
Preferably, the starch slurry the preparation method is as follows: by mass ratio be 1:1-2 starch and 85-95 DEG C of heat
Water is placed in blender, and stirring obtains starch slurry until the uniform mucilage shape of formation.
Preferably, the kaolin particle the preparation method is as follows: take dioxide-containing silica be not less than 99% kaolinite
Soil is crushed, and ball milling 30-60min in ball mill is then placed into；It is taken out after ball milling, is filtered screening, choosing partial size is
The kaolin particle of 300-1000 mesh.
It is a large amount of golden because of containing in common kaolin not less than 99% that kaolinic dioxide-containing silica, which is defined in,
Belong to ion, part metals ion will affect itself whiteness of object in calcination process, have some impact on to appearance.Secondly,
It will do it chemical reaction between the part metals wherein contained under pyroreaction, can replace between each other, cause object rotten,
There may be the substances being harmful to the human body.
Preferably, the synthetic zeolite the preparation method is as follows: pouring into the silicon of 0.8-1.2mol/L into three-necked flask
Silicon is added dropwise into mixed solution after stirring 10-20min for the sodium aluminate aqueous solution of acid sodium aqueous solution and 0.8-1.2mol/L
Colloidal sol continues after stirring 50-70min, obtains the zeolite gel of homogeneous phase；Then zeolite gel is transferred to Autoclaves for synthesis
In, after reacting 20-28h at 170-190 DEG C, water quenching reaction kettle is filtered, and is continuously washed with deionized water to solution and is in
Property；20-28h is finally baked at 95-105 DEG C, is crushed after drying, and the synthetic zeolite that granularity is 120-200 mesh is obtained；Its
Middle sodium metasilicate, sodium aluminate, silica solution and washing are 5-7:1:28-32:750-800 with the molar ratio of deionized water.
After existing synthetic zeolite is used to prepare filtrate of the invention, adsorptivity cannot be played completely, the present invention
For this problem, specific synthetic zeolite homemade according to the method described above synthetic zeolite obtained will be applied to according to the above method
In filtrate, water purification, adsorption effect are good.
Preferably, the active carbon the preparation method is as follows: anthracite is crushed, be filtered screening, choose partial size
For the smokeless coal particle of 80-100 purpose, then it is dried to 1.5-2.5h in 110-130 DEG C of drying machine；Again by grinding
Potassium hydroxide mixed with smokeless coal particle 2.5-3.5:1 in mass ratio, mixture is placed in horizontal activation furnace and is lived
Change, activation temperature is 650-750 DEG C, activation time 25-35min, and activation products are first used 0.4-0.6mol/L's after activation
Hydrochloric acid solution washing, then being washed to pH with distillation is 5.5-6.5, it is finally dry at 105-115 DEG C, obtain active carbon.
The homemade active carbon of the present invention is more suitable for the raw material as filtrate of the present invention compared with common active carbon,
Adsorption activity is higher, and filtering, absorption antibacterial effect are more preferable.
Preferably, quartz sand ball milling 6-8h in the ball mill in advance, sieving removes impurity after ball milling, chooses granularity
For the part of 100-400 mesh.
Preferably, the polybasic ion antibacterial agent the preparation method is as follows:
(1) first 0.5-0.6:1 in mass ratio mixes silica with water, then adds it to 0.4-0.6 times of quality
In water, suspension is stirred to get；Silver nitrate, zinc nitrate and magnesia are respectively mixed with suspension 1.5-2:1 in mass ratio, obtained
To three kinds of solution；By three kinds of solution respectively with heating water bath to 28-35 DEG C, then three kinds of solution are mixed and continued stirring until
Fully dissolved obtains solution A.
Silica is first mixed with a part of water, is then then added in water, is so capable of forming stable suspension,
If directly mixed silica with whole water, suspension just can not be formed.After silica is in conjunction with each metal ion, make
For carrier, stability is good.
(2) first copper is melted, then adding zinc makes zinc and copper melting mixing, then adds charcoal powder, wherein copper, zinc, wood
The mass ratio of powdered carbon is 1:1.4-1.6:2.8-3.2；Cooling down after mixing, grinding obtain composite brass powder.
When Zn content is less than 35% in composite brass, zinc, which can be dissolved in copper, to be formed single-phase, becomes alpha brass.This Huang
Copper plasticity is good, be suitable for cold and hot pressure processing, facilitate the performance of stabilizing material in the material, it helps antibacterial agent it is steady
It is fixed.
Pay attention to needing first to dissolve copper during the preparation process, because copper is different from the solution temperature of zinc, if first solving zinc
Words will lead to the zinc when not reaching the solution temperature of copper also and just be evaporated consumption.Charcoal is added in brass, anti-biotic material can be made
There is adsorption capacity, and charcoal is as the carrier and skeleton in anti-biotic material under original antibacterial effect, allows in anti-biotic material
Each metal ion species are adsorbed, and for application in the material, are even more formd antibacterial film on surface, are improved sterilization rate.
(3) composite brass powder is added in solution A by 1.1-1.3:2 in mass ratio, forms mixture B；It is molten to prepare nitric acid
Mixture B is added in the nitric acid solution of its 1.8-2.2 times of quality by liquid；It is warming up to 100-140 DEG C；Prepare glacial acetic acid and two
Ethanol amine total concentration is the solution of 30-40wt%, is added in nitric acid solution, generates and precipitates and wash precipitating, then heats up, washes
It washs repeatedly；0.3-0.4 times of solution quality of titanium dioxide is added into solution, is dried at 80-100 DEG C, after cooling, is obtained
Polybasic ion antibacterial agent.
Composite brass powder is mixed with solution A, polybasic ion antibacterial agent is then made, titanium dioxide is added in anti-biotic material
Titanium can not only play antibacterial action, and can increase the stabilization of powder whiteness and high temperature resistance.
Polybasic ion antibacterial agent of the invention utilizes ion antibacterial principle and micro- magnetoelectricity field technology principle, forms a kind of new
Type high-efficiency antimicrobial added material.The anti-microbial property and service life for effectively improving filtrate, avoid traditional anti-biotic material
The problems such as antibiotic property is low, service life is low and temperature dependency is too strong.Its advantage specifically:
(1) polybasic ion antibacterial agent improves antibacterial ability by the method for ion antibacterial.Polybasic ion antibacterial agent is in magnetic
On the basis of electricity, by the means of ion antibacterial, absorption exchanges various ions, stabilizes R1The length of chain is controlled can
It controls in range, antibiotic property is made to reach most active state.And there is close state for ion and cause asking for antibacterial activity difference
Topic can improve single quaternary phosphonium salt content of monomer to improve antibacterial activity in ion exchange.And ion monomer copolymerization can
Break this situation to use ion-exchange, and various harmless ions can be added mention anti-microbial property
It is high.
(2) polybasic ion antibacterial agent can effectively interfere the synthesis of cell wall.Bacteria cell wall important component is peptide glycan,
Ion antibacterial agent is to the interference effect of cell wall, and main inhibition polysaccharide chain and tetrapeptide are crosslinked with connection, so that cell wall be made to lose
Integrality, loses the protective effect to osmotic pressure, damages thallus and dead.
Polybasic ion antibacterial agent can damaging cells film.Cell membrane is the important component part of bacterial cell vital movement.Cause
This, such as damaged membrane wound, destroys, will lead to bacterial death.
Polybasic ion antibacterial agent is able to suppress the synthesis of protein.The synthesis process of protein changes, stops, keeping bacterium dead
It dies.Protein is material base for bacterium, is organic macromolecule, is the basic organic matter for constituting cell, is that life is living
The dynamic main undertaker.There is no protein just without life, and ion-exchange breaks the ring synthesis process of protein, makes entire
Process change perhaps stops such bacterium and just stops growing or dead.
Polybasic ion antibacterial agent can interfere with the synthesis of nucleic acid.In a word be hinder hereditary information duplication, including DNA,
The synthesis of RNA and DNA profiling transcript mRNA etc..
The present invention strengthens the ionization activity and intensity of composite metal ion by magnetic field, effectively improves antibacterial sterilizing
Performance is effectively prevented the growth of bacterium.Polybasic ion antibacterial agent of the invention utilizes ion antibacterial principle and micro- magnetoelectricity field skill
Art principle, stability is good, and antibacterial activity is high, and has adsorption capacity；Anti-microbial property and the use of material can be effectively improved
Service life.
Preferably, the pH value of the nitric acid solution is 4.2-5 in step (3).
Preferably, the dosage of the solution of glacial acetic acid and diethanol amine is nitric acid solution matter when washing every time in step (3)
0.4-0.6 times of amount, and in the solution of glacial acetic acid and diethanol amine, the mass ratio of glacial acetic acid and diethanol amine is 1:1.5-2.5.
The preparation method of above-mentioned polybasic ion anti-bacteria ceramic filtrate, comprising the following steps:
Each component is weighed according to the ratio, and synthetic zeolite is added to blender together with kaolin particle, active carbon, ammonium carbonate
In be stirred, be subsequently added into starch slurry, polybasic ion antibacterial agent mixes together, then add quartz sand and be uniformly mixed, finally
Addition water is simultaneously uniformly mixed, and the pug with plasticity is made；It is the particle that granularity is 1-10mm by pug granulating and forming；It will molding
The first 10-14h dry at 65-75 DEG C of particle afterwards, then dried completely at 105-115 DEG C, then it is sintered at 300-500 DEG C
25-35min is finally sintered 55-65min at 600-900 DEG C, takes out after cooling, finished product.
Polybasic ion anti-bacteria ceramic filtrate produced by the present invention is in granular form, wide application.The present invention is according to the filtrate
The characteristics of formula, during the sintering process, specific settings are successively by the heating sintering of three steps, so that energy portion energy after filtrate sintering
A large amount of three-dimensional network hole is enough formed, to have better strainability and better water flux.
It is compared with the prior art, the beneficial effects of the present invention are: filtrate of the invention can not only filter impurities in water, moreover it is possible to
Bacterium, microorganism etc. in water are killed in absorption.It is more compact to be compared to traditional filter core, convenient carrying, replacement is convenient, therefore
Application field is wider.
Specific embodiment
The present invention will be further described with reference to the examples below.
Embodiment 1
A kind of polybasic ion anti-bacteria ceramic filtrate, raw material comprise the following components in parts by weight: 100 parts of starch slurry, kaolinite
75 parts of soil particle, 125 parts of synthetic zeolite, 100 parts of active carbon, 50 parts of quartz sand, 100 parts of ammonium carbonate, polybasic ion antibacterial agent 75
Part and 125 parts of water.
The starch slurry the preparation method is as follows: by mass ratio be 1:1.5 starch and 90 DEG C of hot water be placed in stirring
In device, stirring obtains starch slurry until the uniform mucilage shape of formation.
The kaolin particle the preparation method is as follows: take dioxide-containing silica be not less than 99% kaolin, by its powder
It is broken, it is then placed into ball milling 45min in ball mill；It is taken out after ball milling, is filtered screening, selection partial size is 300-1000 purpose
Kaolin particle.
The synthetic zeolite the preparation method is as follows: poured into three-necked flask 1mol/L sodium silicate aqueous solution and
Silica solution is added dropwise into mixed solution after stirring 15min for the sodium aluminate aqueous solution of 1mol/L, continues after stirring 60min,
Obtain the zeolite gel of homogeneous phase；Then zeolite gel is transferred in Autoclaves for synthesis, after reacting for 24 hours at 180 DEG C, uses water
Chilling reaction kettle filters, and is continuously washed to solution and is in neutrality with deionized water；It finally bakes at 100 DEG C for 24 hours, is carried out after drying
It crushes, obtains the synthetic zeolite that granularity is 120-200 mesh；Wherein sodium metasilicate, sodium aluminate, silica solution and washing deionized water
Molar ratio is 6:1:30:780.
The active carbon the preparation method is as follows: anthracite is crushed, be filtered screening, selection partial size is 80-100 mesh
Smokeless coal particle, then by it in 120 DEG C of drying machine dry 2h；Again the potassium hydroxide and anthracite by grinding
The grain mixing of 3:1 in mass ratio, mixture is placed in horizontal activation furnace and is activated, and activation temperature is 700 DEG C, activation time
For 30min, activation products are first washed with the hydrochloric acid solution of 0.5mol/L after activation, then being washed to pH with distillation is 6 or so, most
It is dry at 110 DEG C afterwards, obtain active carbon.
Quartz sand ball milling 7h in the ball mill in advance, sieving removes impurity after ball milling, and selections granularity is 100-400 mesh
Part.
The polybasic ion antibacterial agent, is made by following methods:
(1) first 0.55:1 in mass ratio mixes silica with water, then adds it in the water of 0.5 times of quality, stirs
It mixes to obtain suspension；Silver nitrate, zinc nitrate and magnesia are respectively mixed with suspension 1.8:1 in mass ratio, obtain three kinds it is molten
Liquid；It by three kinds of solution respectively with heating water bath to 30 DEG C, then three kinds of solution is mixed and continued stirring until is completely dissolved, obtain
Solution A.
(2) first copper is melted, then adding zinc makes zinc and copper melting mixing, then adds charcoal powder, wherein copper, zinc, wood
The mass ratio of powdered carbon is 1:1.5:3；Cooling down after mixing, grinding obtain composite brass powder.
(3) composite brass powder is added in solution A by 1.2:2 in mass ratio, forms mixture B；The nitric acid that pH value is 4.6
Mixture B is added in the nitric acid solution of its 2 times of quality by solution；It is warming up to 120 DEG C；It prepares glacial acetic acid and diethanol amine is total
The solution (mass ratio of glacial acetic acid and diethanol amine is 1:2) that concentration is 35wt%, is added in nitric acid solution, generates precipitating simultaneously
Then washing precipitating is heated up, is washed in triplicate；The dosage of the solution of glacial acetic acid and diethanol amine is that nitric acid is molten when washing every time
0.5 times of liquid quality.The titanium dioxide of solution quality 1/3 is added into solution, 90 DEG C of drying obtain polybasic ion after cooling
Antibacterial agent.
The preparation method of the polybasic ion anti-bacteria ceramic filtrate, comprising the following steps:
Each component is weighed according to the ratio, and synthetic zeolite is added to blender together with kaolin particle, active carbon, ammonium carbonate
In be stirred, be subsequently added into starch slurry, polybasic ion antibacterial agent mixes together, then add quartz sand and be uniformly mixed, finally
Addition water is simultaneously uniformly mixed, and the pug with plasticity is made；It is the particle that granularity is 5mm or so by pug granulating and forming；It will be at
The first 12h dry at 70 DEG C of particle after type, then dried completely at 110 DEG C, it is then sintered 30min at 400 DEG C, finally exists
It is sintered 60min at 750 DEG C, is taken out after cooling, finished product.
Embodiment 2
A kind of polybasic ion anti-bacteria ceramic filtrate, raw material comprise the following components in parts by weight: 95 parts of starch slurry, kaolin
70 parts of particle, 120 parts of synthetic zeolite, 95 parts of active carbon, 45 parts of quartz sand, 95 parts of ammonium carbonate, 70 parts of polybasic ion antibacterial agent and
60 parts of water.
The starch slurry the preparation method is as follows: by mass ratio be 1:1 starch and 85 DEG C of hot water be placed in blender
In, stirring obtains starch slurry until the uniform mucilage shape of formation.
The kaolin particle the preparation method is as follows: take dioxide-containing silica be not less than 99% kaolin, by its powder
It is broken, it is then placed into ball milling 30min in ball mill；It is taken out after ball milling, is filtered screening, selection partial size is 300-1000 purpose
Kaolin particle.
The synthetic zeolite the preparation method is as follows: poured into three-necked flask 0.8mol/L sodium silicate aqueous solution and
Silica solution is added dropwise into mixed solution after stirring 10min for the sodium aluminate aqueous solution of 0.8mol/L, continues to stir 50min
Afterwards, the zeolite gel of homogeneous phase is obtained；Then zeolite gel is transferred in Autoclaves for synthesis, after reacting 28h at 170 DEG C,
Water quenching reaction kettle filters, and is continuously washed to solution and is in neutrality with deionized water；28h is finally baked at 95 DEG C, after drying
It is crushed, obtains the synthetic zeolite that granularity is 120-200 mesh；Wherein sodium metasilicate, sodium aluminate, silica solution and washing deionization
The molar ratio of water is 5:1:28:750.
The active carbon the preparation method is as follows: anthracite is crushed, be filtered screening, selection partial size is 80-100 mesh
Smokeless coal particle, then by it in 110 DEG C of drying machine dry 2.5h；Again the potassium hydroxide and anthracite by grinding
Particle 2.5:1 in mass ratio mixing, mixture is placed in horizontal activation furnace and is activated, and activation temperature is 650 DEG C, activation
Time is 35min, first washs activation products with the hydrochloric acid solution of 0.4mol/L after activation, then being washed to pH with distillation is 5.5
Left and right, it is finally dry at 105 DEG C, obtain active carbon.
Quartz sand ball milling 6-8h in the ball mill in advance, sieving removes impurity after ball milling, and selections granularity is 100-400
Purpose part.
The polybasic ion antibacterial agent, is made by following methods:
(1) first 0.5:1 in mass ratio mixes silica with water, then adds it in the water of 0.4 times of quality, stirs
Obtain suspension；Silver nitrate, zinc nitrate and magnesia are respectively mixed with suspension 1.5:1 in mass ratio, three kinds of solution are obtained；
It by three kinds of solution respectively with heating water bath to 28 DEG C, then three kinds of solution is mixed and continued stirring until is completely dissolved, obtain molten
Liquid A.
(2) first copper is melted, then adding zinc makes zinc and copper melting mixing, then adds charcoal powder, wherein copper, zinc, wood
The mass ratio of powdered carbon is 1:1.4:2.8；Cooling down after mixing, grinding obtain composite brass powder.
(3) composite brass powder is added in solution A by 1.2:2 in mass ratio, forms mixture B；Secure ph is 4.2
Mixture B is added in the nitric acid solution of its 1.8 times of quality by nitric acid solution；It is warming up to 100 DEG C；Prepare glacial acetic acid and diethyl
The solution (mass ratio of glacial acetic acid and diethanol amine is 1:1.5) that hydramine total concentration is 30wt%, is added in nitric acid solution, produces
It is raw to precipitate and wash precipitating, it then heats up, wash repetition three；The dosage of the solution of glacial acetic acid and diethanol amine is when washing every time
0.4 times of nitric acid solution quality.0.3 times of solution quality of titanium dioxide is added into solution, 80 DEG C of drying obtain after cooling
Polybasic ion antibacterial agent.
The preparation method of the polybasic ion anti-bacteria ceramic filtrate, comprising the following steps:
Each component is weighed according to the ratio, and synthetic zeolite is added to blender together with kaolin particle, active carbon, ammonium carbonate
In be stirred, be subsequently added into starch slurry, polybasic ion antibacterial agent mixes together, then add quartz sand and be uniformly mixed, finally
Addition water is simultaneously uniformly mixed, and the pug with plasticity is made；It is the particle that granularity is 1mm or so by pug granulating and forming；It will be at
The first 14h dry at 65 DEG C of particle after type, then dried completely at 105 DEG C, it is then sintered 35min at 300 DEG C, finally exists
It is sintered 65min at 600 DEG C, is taken out after cooling, finished product.
Embodiment 3
A kind of polybasic ion anti-bacteria ceramic filtrate, raw material comprise the following components in parts by weight: 105 parts of starch slurry, kaolinite
80 parts of soil particle, 130 parts of synthetic zeolite, 105 parts of active carbon, 55 parts of quartz sand, 105 parts of ammonium carbonate, polybasic ion antibacterial agent 80
Part and 190 parts of water.
The starch slurry the preparation method is as follows: by mass ratio be 1:2 starch and 95 DEG C of hot water be placed in blender
In, stirring obtains starch slurry until the uniform mucilage shape of formation.
The kaolin particle the preparation method is as follows: take dioxide-containing silica be not less than 99% kaolin, by its powder
It is broken, it is then placed into ball milling 60min in ball mill；It is taken out after ball milling, is filtered screening, selection partial size is 300-1000 purpose
Kaolin particle.
The synthetic zeolite the preparation method is as follows: poured into three-necked flask 1.2mol/L sodium silicate aqueous solution and
Silica solution is added dropwise into mixed solution after stirring 20min for the sodium aluminate aqueous solution of 1.2mol/L, continues to stir 70min
Afterwards, the zeolite gel of homogeneous phase is obtained；Then zeolite gel is transferred in Autoclaves for synthesis, after reacting 20h at 190 DEG C,
Water quenching reaction kettle filters, and is continuously washed to solution and is in neutrality with deionized water；20h is finally baked at 105 DEG C, after drying
It is crushed, obtains the synthetic zeolite that granularity is 120-200 mesh；Wherein sodium metasilicate, sodium aluminate, silica solution and washing deionization
The molar ratio of water is 7:1:32:800.
The active carbon the preparation method is as follows: anthracite is crushed, be filtered screening, selection partial size is 80-100 mesh
Smokeless coal particle, then by it in 130 DEG C of drying machine dry 1.5h；Again the potassium hydroxide and anthracite by grinding
Particle 3.5:1 in mass ratio mixing, mixture is placed in horizontal activation furnace and is activated, and activation temperature is 750 DEG C, activation
Time is 25min, first washs activation products with the hydrochloric acid solution of 0.6mol/L after activation, then being washed to pH with distillation is 6.5
Left and right, it is finally dry at 115 DEG C, obtain active carbon.
Quartz sand ball milling 6-8h in the ball mill in advance, sieving removes impurity after ball milling, and selections granularity is 100-400
Purpose part.
The polybasic ion antibacterial agent, is made by following methods:
(1) first 0.6:1 in mass ratio mixes silica with water, then adds it in the water of 0.6 times of quality, stirs
Obtain suspension；Silver nitrate, zinc nitrate and magnesia are respectively mixed with suspension 2:1 in mass ratio, three kinds of solution are obtained；It will
Then three kinds of solution are mixed and are continued stirring until and be completely dissolved respectively with heating water bath to 35 DEG C by three kinds of solution, obtain solution
A。
(2) first copper is melted, then adding zinc makes zinc and copper melting mixing, then adds charcoal powder, wherein copper, zinc, wood
The mass ratio of powdered carbon is 1:1.6:3.2；Cooling down after mixing, grinding obtain composite brass powder.
(3) composite brass powder is added in solution A by 1.1-1.3:2 in mass ratio, forms mixture B；Secure ph is 5
Nitric acid solution, mixture B is added in the nitric acid solution of its 2.2 times of quality；It is warming up to 140 DEG C；Prepare glacial acetic acid and two
The solution (mass ratio of glacial acetic acid and diethanol amine is 1:2.5) that ethanol amine total concentration is 40wt%, is added in nitric acid solution,
It generates and precipitates and wash precipitating, then heat up, wash in triplicate；The use of the solution of glacial acetic acid and diethanol amine when washing every time
Amount is 0.6 times of nitric acid solution quality.0.4 times of solution quality of titanium dioxide is added into solution, 100 DEG C dry, after cooling,
Obtain polybasic ion antibacterial agent.
The preparation method of the polybasic ion anti-bacteria ceramic filtrate, comprising the following steps:
Each component is weighed according to the ratio, and synthetic zeolite is added to blender together with kaolin particle, active carbon, ammonium carbonate
In be stirred, be subsequently added into starch slurry, polybasic ion antibacterial agent mixes together, then add quartz sand and be uniformly mixed, finally
Addition water is simultaneously uniformly mixed, and the pug with plasticity is made；It is the particle that granularity is 10mm or so by pug granulating and forming；It will be at
The first 10h dry at 75 DEG C of particle after type, then dried completely at 115 DEG C, it is then sintered 25min at 500 DEG C, finally exists
It is sintered 55min at 900 DEG C, is taken out after cooling, finished product.
Indices are as follows in polybasic ion anti-bacteria ceramic filtrate of the present invention treated water:
The antibacterial effect figure of polybasic ion anti-bacteria ceramic filtrate of the present invention is as follows: (common tap water)
Raw materials used in the present invention, equipment is unless otherwise noted the common raw material, equipment of this field；In the present invention
Method therefor is unless otherwise noted the conventional method of this field.
The above is only presently preferred embodiments of the present invention, is not intended to limit the invention in any way, it is all according to the present invention
Technical spirit any simple modification, change and equivalent transformation to the above embodiments, still fall within the technology of the present invention side
The protection scope of case.
Claims (9)
1. a kind of polybasic ion anti-bacteria ceramic filtrate, it is characterised in that raw material comprises the following components in parts by weight: starch slurry 95-
105 parts, 70-80 parts of kaolin particle, 120-130 parts of synthetic zeolite, 95-105 parts of active carbon, 45-55 parts of quartz sand, ammonium carbonate
95-105 parts, 70-80 parts of polybasic ion antibacterial agent and 60-190 parts of water；
The polybasic ion antibacterial agent the preparation method is as follows:
(1) first 0.5-0.6:1 in mass ratio mixes silica with water, then adds it in the water of 0.4-0.6 times of quality,
Stir to get suspension；Silver nitrate, zinc nitrate and magnesia are respectively mixed with suspension 1.5-2:1 in mass ratio, obtain three
Kind solution；By three kinds of solution respectively with heating water bath to 28-35 DEG C, then three kinds of solution are mixed and are continued stirring until completely molten
Solution, obtains solution A；
(2) first copper is melted, then adding zinc makes zinc and copper melting mixing, then adds charcoal powder, wherein copper, zinc, charcoal powder
Mass ratio be 1:1.4-1.6:2.8-3.2；Cooling down after mixing, grinding obtain composite brass powder；
(3) composite brass powder is added in solution A by 1.1-1.3:2 in mass ratio, forms mixture B；Nitric acid solution is prepared, it will
Mixture B is added in the nitric acid solution of its 1.8-2.2 times of quality；It is warming up to 100-140 DEG C；Prepare glacial acetic acid and diethanol amine
Total concentration is the solution of 30-40wt%, is added in nitric acid solution, generates and precipitates and wash precipitating, is then heated up, washing repeats
Repeatedly；Add 0.3-0.4 times of solution quality of titanium dioxide into solution, dried at 80-100 DEG C, after cooling down, obtain it is polynary from
Sub- antibacterial agent.
2. a kind of polybasic ion anti-bacteria ceramic filtrate as described in claim 1, which is characterized in that the preparation side of the starch slurry
Method is as follows: mass ratio being placed in blender for the starch of 1:1-2 and 85-95 DEG C of hot water, stirring is until form uniform
Mucilage shape, obtains starch slurry.
3. a kind of polybasic ion anti-bacteria ceramic filtrate as described in claim 1, which is characterized in that the system of the kaolin particle
Preparation Method is as follows: taking dioxide-containing silica to be not less than 99% kaolin, is crushed, be then placed into ball milling 30- in ball mill
60min；It is taken out after ball milling, is filtered screening, choose the kaolin particle that partial size is 300-1000 mesh.
4. a kind of polybasic ion anti-bacteria ceramic filtrate as described in claim 1, which is characterized in that the preparation of the synthetic zeolite
Method is as follows: the sodium aluminate of sodium silicate aqueous solution and 0.8-1.2mol/L that 0.8-1.2mol/L is poured into three-necked flask is water-soluble
Silica solution is added dropwise into mixed solution after stirring 10-20min for liquid, continues after stirring 50-70min, obtains homogeneous phase
Zeolite gel；Then zeolite gel is transferred in Autoclaves for synthesis, after reacting 20-28h at 170-190 DEG C, water quenching
Reaction kettle filters, and is continuously washed to solution and is in neutrality with deionized water；20-28h is finally baked at 95-105 DEG C, is dried laggard
Row crushes, and obtains the synthetic zeolite that granularity is 120-200 mesh；Wherein sodium metasilicate, sodium aluminate, silica solution and washing deionized water
Molar ratio be 5-7:1:28-32:750-800.
5. a kind of polybasic ion anti-bacteria ceramic filtrate as described in claim 1, which is characterized in that the preparation side of the active carbon
Method is as follows: anthracite is crushed, is filtered screening, selection partial size is the smokeless coal particle of 80-100 purpose, then by its
Dry 1.5-2.5h in 110-130 DEG C of drying machine；Again in mass ratio the potassium hydroxide and smokeless coal particle for passing through grinding
2.5-3.5:1 mixing, mixture is placed in horizontal activation furnace and is activated, and activation temperature is 650-750 DEG C, activation time
For 25-35min, activation products are first washed with the hydrochloric acid solution of 0.4-0.6mol/L after activation, then is washed to pH with distillation and is
5.5-6.5, it is finally dry at 105-115 DEG C, obtain active carbon.
6. a kind of polybasic ion anti-bacteria ceramic filtrate as described in claim 1, which is characterized in that the quartz sand is in advance in ball
Ball milling 6-8h in grinding machine, sieving removes impurity after ball milling, chooses the part that granularity is 100-400 mesh.
7. a kind of polybasic ion anti-bacteria ceramic filtrate as described in claim 1, which is characterized in that in step (3), the nitric acid
The pH value of solution is 4.2-5.
8. a kind of polybasic ion anti-bacteria ceramic filtrate as claimed in claim 7, which is characterized in that in step (3), wash every time
When glacial acetic acid and the dosage of solution of diethanol amine be 0.4-0.6 times of nitric acid solution quality, and glacial acetic acid and diethanol amine
In solution, the mass ratio of glacial acetic acid and diethanol amine is 1:1.5-2.5.
9. a kind of preparation method of polybasic ion anti-bacteria ceramic filtrate as described in one of claim 1-8, it is characterised in that packet
Include following steps:
Weigh each component according to the ratio, synthetic zeolite is added to together with kaolin particle, active carbon, ammonium carbonate in blender into
Row stirring, is subsequently added into starch slurry, polybasic ion antibacterial agent mixes together, then adds quartz sand and is uniformly mixed, finally adds
Water is simultaneously uniformly mixed, and the pug with plasticity is made；It is the particle that granularity is 1-10mm by pug granulating and forming；It will be after molding
The first 10-14h dry at 65-75 DEG C of particle, then dried completely at 105-115 DEG C, then 25- is sintered at 300-500 DEG C
35min is finally sintered 55-65min at 600-900 DEG C, takes out after cooling, finished product.
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| CN107722643A (en) * | 2017-10-25 | 2018-02-23 | 宁波科邦华诚技术转移服务有限公司 | A kind of preparation method of ionic medical nanometer antibacterial material |
| CN113087097A (en) * | 2019-12-23 | 2021-07-09 | 江苏嘉恒环境科技有限公司 | High-efficiency composite filter material for water body disinfection and preparation process thereof |
| CN111632334A (en) * | 2020-06-17 | 2020-09-08 | 成都市图腾环保科技有限公司 | Disinfectant, and preparation method and application thereof |
| CN117700207B (en) * | 2023-12-22 | 2024-06-28 | 广东枫树陶瓷原料有限公司 | Environment-friendly antibacterial ceramic wine bottle blank based on reutilization of waste ceramic powder and preparation process thereof |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1090708A (en) * | 1992-09-16 | 1994-08-17 | 德山曹达株式会社 | Antibacterial agent and utilization thereof |
| CN1686933A (en) * | 2004-06-04 | 2005-10-26 | 程正勇 | Antibacterial composite material and preparation method |
| CN1789158A (en) * | 2004-12-15 | 2006-06-21 | 林明助 | Antibacterial granule and production method thereof |
| CN101274176A (en) * | 2007-12-19 | 2008-10-01 | 华南理工大学 | Method for preparing tourmaline functional ceramic filter element |
| WO2010069152A1 (en) * | 2008-12-18 | 2010-06-24 | 香港科技大学 | A multi-effect antimicrobial surface coating forming material and its preparation |
| WO2013073555A1 (en) * | 2011-11-17 | 2013-05-23 | 堺化学工業株式会社 | Surface-treated zinc oxide powder, anti-bacterial agent, and anti-bacterial composition |
| CN104043288A (en) * | 2014-05-20 | 2014-09-17 | 浙江朝晖过滤技术股份有限公司 | Nnano-silver diatomite antibacterial filter core and preparation method thereof |
| CN104206420A (en) * | 2014-08-07 | 2014-12-17 | 蔡惠萍 | Preparation method and application of silver-free powdery solid solution anti-bacterial agent |
| CN105921130A (en) * | 2016-05-25 | 2016-09-07 | 厦门建霖工业有限公司 | Slow-release antibacterial adsorption material for drinking water treatment and preparation method of material |
| CN105948162A (en) * | 2016-06-23 | 2016-09-21 | 苏州腾纳环保科技有限公司 | Antimicrobial corrosion-resistant water-purification composite filter material |
| CN106145298A (en) * | 2016-07-20 | 2016-11-23 | 苏州腾纳环保科技有限公司 | A kind of antibacterial type water purification filtrate |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1820606A (en) * | 2006-03-24 | 2006-08-23 | 东华理工学院 | Process for preparing magnesium clay antibiotic material |
-
2017
- 2017-01-18 CN CN201710039808.4A patent/CN106938848B/en active Active
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1090708A (en) * | 1992-09-16 | 1994-08-17 | 德山曹达株式会社 | Antibacterial agent and utilization thereof |
| CN1686933A (en) * | 2004-06-04 | 2005-10-26 | 程正勇 | Antibacterial composite material and preparation method |
| CN1789158A (en) * | 2004-12-15 | 2006-06-21 | 林明助 | Antibacterial granule and production method thereof |
| CN101274176A (en) * | 2007-12-19 | 2008-10-01 | 华南理工大学 | Method for preparing tourmaline functional ceramic filter element |
| WO2010069152A1 (en) * | 2008-12-18 | 2010-06-24 | 香港科技大学 | A multi-effect antimicrobial surface coating forming material and its preparation |
| WO2013073555A1 (en) * | 2011-11-17 | 2013-05-23 | 堺化学工業株式会社 | Surface-treated zinc oxide powder, anti-bacterial agent, and anti-bacterial composition |
| CN104043288A (en) * | 2014-05-20 | 2014-09-17 | 浙江朝晖过滤技术股份有限公司 | Nnano-silver diatomite antibacterial filter core and preparation method thereof |
| CN104206420A (en) * | 2014-08-07 | 2014-12-17 | 蔡惠萍 | Preparation method and application of silver-free powdery solid solution anti-bacterial agent |
| CN105921130A (en) * | 2016-05-25 | 2016-09-07 | 厦门建霖工业有限公司 | Slow-release antibacterial adsorption material for drinking water treatment and preparation method of material |
| CN105948162A (en) * | 2016-06-23 | 2016-09-21 | 苏州腾纳环保科技有限公司 | Antimicrobial corrosion-resistant water-purification composite filter material |
| CN106145298A (en) * | 2016-07-20 | 2016-11-23 | 苏州腾纳环保科技有限公司 | A kind of antibacterial type water purification filtrate |
Non-Patent Citations (3)
| Title |
|---|
| Sol-gel制备二氧化钛复合抗菌材料的研究;江伟 等;《材料导报》;20061130;第20卷;全文 |
| 复合离子不同载入顺序抗菌沸石的制备及其抗菌性能研究;林海 等;《功能材料》;20140219(第5期);全文 |
| 载银锌纳米二氧化硅抗菌剂的制备及应用;侯文生 等;《合成纤维工业》;20040630;第27卷(第3期);全文 |
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