CN106937638A - A kind of Herbicidal combinations of Han clomazones and its application - Google Patents
A kind of Herbicidal combinations of Han clomazones and its application Download PDFInfo
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- CN106937638A CN106937638A CN201710281243.0A CN201710281243A CN106937638A CN 106937638 A CN106937638 A CN 106937638A CN 201710281243 A CN201710281243 A CN 201710281243A CN 106937638 A CN106937638 A CN 106937638A
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- Prior art keywords
- herbicidal combinations
- agent
- formulation
- active component
- clomazones
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
- A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
- A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of Herbicidal combinations containing clomazone and its application, the Herbicidal combinations are made up of clomazone, symetryne and S-metolachlor and other auxiliary agents and filler, and formulation is missible oil, dispersible oil-suspending agent or aqueous suspension agent.Three kinds of active component compoundings have obvious synergistic effect, reduce Pesticide use amount, reduce cost and the pollution to environment, the application of composition can delay the resistance to the action of a drug of paddy field weed, expand and prevent and kill off spectrum.
Description
Technical field
The present invention relates to Herbicidal combinations and its application of technical field of pesticide, more particularly to a kind of Han clomazones.
Background technology
Symetryne is interior suction selective herbicide, can be absorbed by root, leaf and conduct complete stool, to rice field malignant weed eye
Dish has special efficacy, has remarkable result to early stage barnyard grass, fescue, and the lasting period is long, to rice safety.
Clomazone also known as clomazone.It is a kind of selective pigment suppressive developed by FMC companies of the U.S. for 1984
Preemergence herbicide, can be absorbed by root, young shoot, each position of plant is transmitted to upwards with transpiration, in sensitive plant body
Interior suppression chlcrophyll biosynthesis, although energy rudiment is unearthed, but non-pigment, albefaction is dead in a short time.Clomazone is mainly prevented
Except broad leaved weed and grassy weed, it can be used for the weeding of soybean, cotton, cassava, corn, rape, sugarcane and Tobacco Farm etc..
S-metolachlor belongs to selective preemergence herbicide, is mainly absorbed by young shoot, young root after medicament, suppresses albumen
Matter synthetic lethal.It is usually used in corn and soybean, peanut, sugarcane, it can also be used to cotton, rape, potato and the ocean of non-sand loam soil
The crops such as green onion, capsicum, wild cabbage, preventing and treating annual gramineous weed and some broad leaved weeds, make native face processing before budding.
Herbicide single dose preventing and treating grass is used alone farmland weed and developed immunity to drugs to single, therefore by three kinds of herbicides
Science is assembled, and selects suitable formulation, so as to expand herbicide controlling spectrum, reduces times for spraying and dosage, is that current rice region is badly in need of solution
Certainly the problem of.
The content of the invention
A kind of Herbicidal combinations for Han clomazones that the present invention is provided, three kinds of active component compoundings have obvious synergy
Effect, reduces Pesticide use amount, reduces cost and the pollution to environment, and the application of composition can delay the anti-of rice weed
The property of medicine, expands and prevents and kill off spectrum.
Present invention simultaneously relates to application of the Herbicidal combinations in preventing and treating paddy field weed.
The present invention is achieved by the following technical solutions：
A kind of Herbicidal combinations of Han clomazones, it is characterised in that the active component You clomazones of the composition, west grass
Net and S-metolachlor is 2.75 according to mass ratio: 0.25-0.5：0.25-4 is constituted.
Preferably, Herbicidal combinations , clomazones, symetryne, the mass ratio of S-metolachlor are 2.75:0.25：
2。
Preferably, the formulation of above-mentioned Herbicidal combinations is missible oil, dispersible oil-suspending agent or aqueous suspension agent.
When formulation is missible oil, it is made up of following mass percent：Active component 15-40%, emulsifying agent 4-15%, cosolvent 2-
8%, balance of solvent.
When formulation is dispersible oil-suspending agent, it is made up of following mass percent：Active component 15-40%, dispersant 3-
8%, emulsifying agent 5-15%, wetting agent 2-5%, thickener 2-5%, antifreezing agent 1-3%, decentralized medium surplus.
When formulation is aqueous suspension agent, it is made up of following mass percent：Active component 15-40%, dispersion moisture agent 3%-6%,
Thickener 1.5-2%, preservative 0.2%, antifreezing agent 1-2%, defoamer 0.2%, synergist 3-5%, surplus is water.
The application of Herbicidal combinations described above in preventing and treating paddy field weed.
Each active component is due to composition, structure, the difference of physicochemical property after different herbicidal activity component mixing so that each
Synergy between active component is usually expressed as synergistic effect, summation action or antagonism.So-called synergistic effect is exactly
Effect is cooperated between different material, its effect produced is more than the sum total of each composition effect；And summation action is exactly it
The effect of generation is equal to the sum total of each composition effect；When antagonism refers to that two kinds of materials act on living organism, generate
A kind of material disturbs the effect of another material, or the effect of interfering with an opponent each other, makes what general effect declined
Phenomenon.
The present invention dexterously make use of clomazone, symetryne, the not same-action machine of three kinds of herbicides of S-metolachlor
Reason, three is compounded, synergistic effect has been reached.
Beneficial effects of the present invention：
1. the Herbicidal combinations that the present invention is provided, rationally, herbicidal effect is good, and drug cost is low for component, and its activity and weeding effect
Fruit is not the simple superposition of each component activity, but has significant synergistic effect, can expand control of weeds spectrum, to crop safety
It is good, meet the security requirement of pesticidal preparations, while reducing times for spraying, reduce drug cost.
2. the Herbicidal combinations that the present invention is provided, three kinds of active component mechanism of action are not quite identical, it can overcome long-term
The single shortcoming using easily generation resistance, delaying drug resistance extends the service life of medicament, and the comprehensive regulation to Weed Resistance has
Significance.
3. the present composition can be made into missible oil, dispersible oil-suspending agent or aqueous suspension agent, the selection of auxiliary material and formulation is carried
High drug effect.
Embodiment
As described below is only the present invention preferably embodiment, is used only for the description present invention, it is impossible to be interpreted as to the present invention
Scope limitation.It should be pointed out that any modification made within the spirit and principles of the invention, equivalent and
Improve etc., it should be included within the scope of the present invention.
Embodiment 1
A kind of Herbicidal combinations of Han clomazones：Formulation is missible oil, by weight composition：Clomazone 27.5%, symetryne
2.5%th, S-metolachlor 5%, ethylene polyethenoxy ether 10%, ethylene glycol 2%, propane diols 3%, dimethylbenzene surplus.
Embodiment 2
A kind of Herbicidal combinations of Han clomazones：Formulation is dispersible oil-suspending agent, by weight composition：Clomazone
27.5%th, symetryne 5%, S-metolachlor 7.5%, Negel 5%, Tween-60 #10%, sodium naphthalene sulfonate 3%, bentonite
2%, ethylene glycol 2%, decentralized medium is methylated vegetable oil surplus.
When formulation is dispersible oil-suspending agent, by dispersant in above-mentioned formula, emulsifying agent, wetting agent, thickener, antifreeze
Agent, decentralized medium, it is well mixed by high speed shear, active component is added, high speed shear is disperseed, and is made after being sanded with sand mill
The dispersible oil-suspending agent of clomazone.
Embodiment 3
A kind of Herbicidal combinations of Han clomazones：Formulation is aqueous suspension agent, by weight composition：Clomazone 27.5%, west grass
Net 2.5%, S-metolachlor 10%, ammonium xylene sulfonate 4%, xanthans 1.8%, Sodium Benzoate 0.2%, urea 1.6%, dimethyl
Silicone oil 0.1%, n-octyl alcohol 0.1%, surplus is water.
Comparative example 1
A kind of Herbicidal combinations of Han clomazones：Formulation is missible oil, by weight composition：Clomazone 27.5%, prometryn
2.5%th, S-metolachlor 5%, ethylene polyethenoxy ether 10%, ethylene glycol 2%, propane diols 3%, dimethylbenzene surplus.
Comparative example 2
A kind of Herbicidal combinations of Han clomazones：Formulation is aqueous suspension agent, by weight composition：Clomazone 35%, prometryn
8%th, S-metolachlor 10%, ammonium xylene sulfonate 4%, xanthans 1.8%, Sodium Benzoate 0.2%, urea 1.6%, dimethicone
0.1%, n-octyl alcohol 0.1%, surplus is water.
Comparative example 3
A kind of Herbicidal combinations of Han clomazones：Formulation is granule, by weight composition：Clomazone 27.5%, symetryne
2.5%th, S-metolachlor 5%, is aided with the other compositions of granule.
Field control effectiveness test embodiment：Prevent and kill off rice terrace annual grassy weeds field control effectiveness test.
Reagent agent and dispenser dosage：Herbicide prepared by granule, comparative example 1-3 from embodiment 1-3 preparations, and
46% clomazone missible oil, 40% symetryne wettable powder, 72% S-metolachlor missible oil, every mu of consumption 50-60 is used alone
Gram.
Test site：Xiangfan City of Hubei Province.
Mainly grass is mutually in field：Lady's-grass, green bristlegrass, eleusine indica, moleplant seed, barnyard grass.In paddy rice 2-5 leaf phases, weeds 3-4 leaves
Phase, by Herbicidal combinations according to above-mentioned every mu of preparation consumption, every mu is watered 30 liters and carries out the uniform cauline leaf spraying in full field.
Result of the test：Table 1 prevents and kill off rice terrace annual grassy weeds field control effectiveness test result (after medicine 21 days)
From experimental result as can be seen that the Herbicidal combinations of the present invention reach 94% to the average preventive effect of rice terrace annual grassy weeds
More than, hence it is evident that it is better than the single dose of control, synergistic effect significantly, and expands herbicidal spectrum, and quick-acting and lasting period are substantially better than
Single dose, preventive effect is acted on also superior to comparative example 1 and comparative example 2 and comparative example 3.During experiment, the rice terrace of embodiment effect is had no
There is symptom of chemical damage, Herbicidal combinations of the invention are to rice safety, no underproduction influence.
Claims (7)
1. a kind of Herbicidal combinations of Han clomazones, it is characterised in that the active component You clomazones of the composition, west
Careless net and S-metolachlor is 2.75 according to mass ratio: 0.25-0.5：0.25-1 is constituted.
2. Herbicidal combinations according to claim 1, it is characterised in that clomazone, symetryne, S-metolachlor
Mass ratio is 2.75:0.25：0.5.
3. Herbicidal combinations according to claim 1 or 2, it is characterised in that formulation be missible oil, dispersible oil-suspending agent or
Aqueous suspension agent.
4. Herbicidal combinations according to claim 3, it is characterised in that when formulation is missible oil, by following mass percent
Composition：Active component 15-40%, emulsifying agent 4-15%, cosolvent 2-8%, balance of solvent.
5. Herbicidal combinations according to claim 3, it is characterised in that when formulation is dispersible oil-suspending agent, by following
Mass percent is constituted：Active component 15-40%, dispersant 3-8%, emulsifying agent 5-15%, wetting agent 2-5%, thickener 2-5%, prevent
Freeze agent 1-3%, decentralized medium surplus.
6. Herbicidal combinations according to claim 3, it is characterised in that when formulation is aqueous suspension agent, by following quality hundred
Divide than composition：Active component 15-40%, dispersion moisture agent 3%-6%, thickener 1.5-2%, preservative 0.2%, antifreezing agent 1-2%, disappear
Infusion 0.2%, synergist 3-5%, surplus is water.
7. application of the Herbicidal combinations in preventing and treating paddy field weed any one of claim 1-6.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710281243.0A CN106937638A (en) | 2017-04-26 | 2017-04-26 | A kind of Herbicidal combinations of Han clomazones and its application |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710281243.0A CN106937638A (en) | 2017-04-26 | 2017-04-26 | A kind of Herbicidal combinations of Han clomazones and its application |
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| CN201710281243.0A Pending CN106937638A (en) | 2017-04-26 | 2017-04-26 | A kind of Herbicidal combinations of Han clomazones and its application |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108391661A (en) * | 2018-04-01 | 2018-08-14 | 南京拓际生物科技有限公司 | A kind of broad-spectrum pesticide aqueous suspension agent special assistant and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104041501A (en) * | 2014-04-30 | 2014-09-17 | 浙江天丰生物科学有限公司 | Weeding composition |
| CN104255748A (en) * | 2014-09-02 | 2015-01-07 | 青岛永通电梯工程有限公司 | Soybean field post-emergence herbicide mixture |
-
2017
- 2017-04-26 CN CN201710281243.0A patent/CN106937638A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104041501A (en) * | 2014-04-30 | 2014-09-17 | 浙江天丰生物科学有限公司 | Weeding composition |
| CN104255748A (en) * | 2014-09-02 | 2015-01-07 | 青岛永通电梯工程有限公司 | Soybean field post-emergence herbicide mixture |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108391661A (en) * | 2018-04-01 | 2018-08-14 | 南京拓际生物科技有限公司 | A kind of broad-spectrum pesticide aqueous suspension agent special assistant and preparation method thereof |
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Application publication date: 20170711 |