CN106930745A - Exploitation of oil-gas field method - Google Patents

Exploitation of oil-gas field method Download PDF

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Publication number
CN106930745A
CN106930745A CN201511026436.9A CN201511026436A CN106930745A CN 106930745 A CN106930745 A CN 106930745A CN 201511026436 A CN201511026436 A CN 201511026436A CN 106930745 A CN106930745 A CN 106930745A
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CN
China
Prior art keywords
water
resin
exploitation
oil
gas field
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Application number
CN201511026436.9A
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Chinese (zh)
Inventor
秦升益
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Beijing Rechsand Science and Technology Group Co Ltd
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Beijing Rechsand Science and Technology Group Co Ltd
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Priority to CN201511026436.9A priority Critical patent/CN106930745A/en
Publication of CN106930745A publication Critical patent/CN106930745A/en
Withdrawn legal-status Critical Current

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Classifications

    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21BEARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/25Methods for stimulating production
    • E21B43/26Methods for stimulating production by forming crevices or fractures
    • E21B43/267Methods for stimulating production by forming crevices or fractures reinforcing fractures by propping
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins

Abstract

The present invention proposes a kind of exploitation of oil-gas field method, is that to adding 5-60 part from suspended prop in 100 parts of natural waters of parts by volume, then be transported to gained proppant slurry in subterranean strata by formation proppant slurry.Method proposed by the present invention, with natural water directly as load fluid, without thickener, hence it is evident that reduce the cost of construction liquid.Fracturing fluid need not be configured, construction equipment is reduced, simplifies construction process, shorten the engineering time, reduce the labour intensity of workman.Natural water is free of thickener, and reservoir damage is light, and production-increasing function is good.Stratum water, environmental protection are not polluted.

Description

Exploitation of oil-gas field method
Technical field
The invention belongs to exploitation of mineral resources field, and in particular to a kind of by support reinforcing crack The oil field of hydraulic fracturing, gas field, shale gas exploitation method.
Background technology
Riverfrac treatment (Water Fracturing) is that a small amount of drag reducer, stabilization are added in clear water The fracturing work that the additives such as agent, surfactant are carried out as fracturing fluid, is called and does drag reduction water Pressure break.Experiment shows, with the addition of the riverfrac treatment effect of proppant significantly better than being not added with proppant When effect, proppant can allow crack fracturing fluid return after still keep it turned on.Clear water Pressure break low cost, formation damage is small, is that current shale gas develop topmost fracturing technique.
But, fluid loss additive, thickener are contained in the clear water in existing riverfrac treatment technology, it is main If macromolecular compound, the such as high molecular weight polysaccharide or melon of mannose and galactolipin composition Gum derivative or cellulose derivative, or biopolymer, such as xanthans, diphenylmethyl Alkane and scleroglucan etc., to provide the effect of antifriction.These macromolecular compounds are in company with clear Water enters stratum, and underground water is entered by ground layer gap during exploitation, after exploitation, causes environment Pollution, caused multi-party concern (《Oilfields engineering》09 phase in 2010).On the other hand, When fracturing fluid recovery (backflow), very big pump power is consumed, be unfavorable for all rows of returning.If high Molecular material and proppant are combined, and there is a problem of that intensity is bad, difficult recovery again, if combination Proppant it is damaged, macromolecular material is entered geological formations, cause underground water pollution.
The content of the invention
In place of in view of the shortcomings of the prior art, it is an object of the invention to provide a kind of clear water pressure Split the exploitation of oil-gas field method of support.
To achieve the above object, concrete technical scheme is:
A kind of exploitation of oil-gas field method of riverfrac treatment support, it is natural to 100 parts of parts by volume Added in water 5-60 parts (volume integral) from suspended prop, form proppant slurry, then Gained proppant slurry is transported in subterranean strata;The subterranean strata can be viscous crude oil One kind in rock stratum, natural gas rock stratum, Salt layer, the sedimentary type formations of Tibetan.
The natural water is selected from the one kind in river, breeding water, lake water, seawater and underground water Or it is various;
It is described from suspended prop be spherical particle that macromolecular material is coated with aggregate;Institute It is water-soluble high-molecular material and the mixture of resin to state macromolecular material, and the resin is natural Resin or synthetic resin;
During the subterranean strata is rock stratum, rammell, Salt layer, the sedimentary type formations of heavy crude reservoir One kind.
The natural water is selected from the one kind in river, breeding water, lake water, seawater and underground water Or it is various;
It is described from suspended prop be spherical particle that macromolecular material is coated with aggregate;Institute It is water-soluble high-molecular material and the mixture of resin to state macromolecular material, and the resin is natural Resin or synthetic resin;
During the subterranean strata is rock stratum, rammell, Salt layer, the sedimentary type formations of heavy crude reservoir One kind.
Wherein, described is that adhesive solution is scattered in aggregate from suspended prop, is added Water-soluble high-molecular material is obtained, and the binder solution accounts for aggregate weight 10-30%, water-soluble Macromolecular material accounts for aggregate weight 0.1~5%.
Wherein, the aggregate is quartz sand, haydite, precoated sand, metallic particles, globular glass One kind in particle, the shell particle crushed;The size of the aggregate be 6-200 mesh (i.e. Between 2.8mm-0.075mm).
Preferably, the natural resin is rosin, shellac or kopol;The synthetic resin It is phenolic resin or epoxy resin.
Further, the phenolic resin is thermoplastic phenolic resin and/or thermosetting phenolic tree Fat;The epoxy resin be preferably epoxy resin E-55, E-51, E44, E-42, E-35, One or more in E-20 (601), E-14, E-12, E-06, E-03;
Wherein, the solvent of the adhesive solution is organic solvent, and the organic solvent preferably is selected from Acetone, ethyl acetate, methyl acetate chloroform, in dimethylformamide, tetrahydrofuran, ethanol One or more;
Preferably, described water-soluble high-molecular material be selected from tragacanth gum, locust bean gum, guanidine glue, Sesbania gum, rubber made from soybean cake, xanthans, gellan gum, shitosan, polyamino resin, amino resins, Polyurethane resin, polyacrylamide, polyacrylic acid, polyethylene glycol, polyethylene glycol oxide, poly- horse Come acid anhydrides, polyquaternium, carboxymethylcellulose calcium, hydroxymethyl cellulose, methylcellulose, second Base cellulose, quaternary ammonium salt-modified shitosan, hydroxyethyl cellulose, carboxyethyl starch, acetic acid form sediment One or more in powder, methylol guanidine glue, hydroxypropyl guar, carboxy-methyl hydroxy propyl guanidine glue.
It is proposed by the present invention to be manufactured using any method from suspended prop.Preferably, institute State from the preparation method of suspended prop and be:
1) particle with 16-200 mesh is described to binder solution is added in aggregate as aggregate Binder solution accounts for aggregate weight 10-30%, adds the water solubility for accounting for aggregate weight 0.1-2.0% Macromolecular material.
2) stir, dry screening.
Step 2) it is preferably the heat drying at 60-100 DEG C, drying time 2-10h.
The beneficial effects of the present invention are:
Use proposed by the present invention from the riverfrac treatment system oil production method of suspended prop, without Using with the addition of organic polymer and costly fracturing fluid carries out pressure break, and directly use with Locating available natural water carries out pressure break;Natural water directly as load fluid, without thickener, Significantly reduce the cost of construction liquid.Fracturing fluid need not be configured, construction equipment, letter is reduced Change construction process, shorten the engineering time, reduce the labour intensity of workman.
Returning discharge opeing can be with secondary re-injection, not polluted underground water.Eliminate extensive repeatedly configuration pressure Split liquid performance change possibility, pressing crack construction stabilization.The frictional resistance of fracturing fluid is small, increases fracturing pump Effect, sand than high, beneficial to being sufficient filling with for geology crack.
Method proposed by the present invention is wide using scope, can apply to conventional oil well, gas well, water The fracturing work of the fluid minerals such as well, it is also possible to be applied to the fracturing work of shale gas, coal bed gas. The row of returning is quick, it is possible to use rubber breaker, and the macromolecule of proppant surface is decomposed into small molecule, Realize the quick row of returning.Applied widely, either natural fresh water or seawater, can be used for taking Sand liquid, carries out fracturing work.
Brief description of the drawings
Fig. 1 is the flow chart of exploitation.
Specific embodiment
Following examples are used to illustrate the present invention, but are not limited to the scope of the present invention.
Embodiment 1
1) with quartz sand (river sand) 1000g as raw material, after cleaning drying, in sand completely Not aqueous, it is aggregate (the pre- place of quartz sand in following examples to screen the quartz sand of 20-40 mesh Reason process is identical);
2) epoxy resin E-55, by 1:1 ratio mixes with ethyl acetate.Stir, make The adhesive solution of 50mL is obtained, then to addition aggregate, 10g guanidine glue in adhesive solution.
3) step 2) gained mixture spontaneously dry after, screening.
The proppant for obtaining is the particle (more slightly larger than aggregate size) of particle diameter 20-40 mesh, aggregate table Bread covers or part is coated with guanidine glue macromolecular material.
Embodiment 2
1) 40-70 mesh 1kg quartz sands (aeolian sand) is taken as aggregate, it is standby;
2) epoxy resin E-51, by 1:1 ratio mixes with Ethyl formate.Stir, make The adhesive solution of 50mL is obtained, then to addition aggregate, 10g carboxymethyl guanidines in adhesive solution Glue.
3) step 2) gained mixture spontaneously dry after, screening.
Embodiment 3
1) 30-50 mesh 1kg quartz sands (sea sand) and sintered alumina are taken as aggregate, two kinds Material mesh number is identical, isometric mixing, standby;
2) resol 8g, adds ethanol 20g.Stir, then to bonding agent Aggregate, 10g polyacrylamides are added in solution.
3) step 2) gained mixture spontaneously dry after, screening.
Comparative example 1
Proppant:Quartz sand, granularity 20-40 mesh.
Sedimentation experiment in natural water (not adding chemicals).
Embodiment 1-3, the sinking speed of the proppant of comparative example 1 in the natural water of table 1
Embodiment 4
1) 30-50 mesh 1kg precoated sands are taken (according to patent CN1640981A, the side of embodiment 2 It is prepared by method) as aggregate, it is standby;
2) epoxy resin E-51, by 1:1 ratio mixes with Ethyl formate.Stir, make The adhesive solution of 40mL is obtained, then to addition aggregate, 10g xanthans in adhesive solution.
3) step 2) gained mixture spontaneously dry after, screening.
Embodiment 5
1) 40-70 mesh 1kg haydites are taken as aggregate, it is standby;
2) epoxy resin E-55, by 1:1 ratio mixes with ethyl acetate.Stir, make The adhesive solution of 40mL is obtained, it is then fine to addition aggregate, 10g carboxymethyls in adhesive solution Dimension element.
3) step 2) gained mixture spontaneously dry after, screening.
Comparative example 2
Proppant:With haydite as proppant.
Embodiment 4,5, the sinking speed of the proppant of comparative example 2 in the natural water of table 2
Embodiment 6
1) the 30-50 mesh stainless steel particles of 1kg are taken as aggregate, it is standby;
2) epoxy resin E-51, by 1:1 ratio mixes with Ethyl formate.Stir, make The adhesive solution of 40mL is obtained, then to addition aggregate, 20g shitosan seasons in adhesive solution Ammonium salt.
3) step 2) gained mixture spontaneously dry after, screening.
Embodiment 7
1) the 30-50 mesh stainless steel particles of 1kg are taken as aggregate, it is standby;
2) epoxy resin E-51, by 1:1 ratio mixes with Ethyl formate.Stir, make The adhesive solution of 40mL is obtained, then to addition aggregate, 10g shitosan seasons in adhesive solution Ammonium salt.
3) step 2) gained mixture spontaneously dry after, screening.
Embodiment 8
1) walnut shell of 40-70 mesh 1kg crushing is taken as aggregate, it is standby;
2) epoxy resin E-51, by 1:1 ratio mixes with Ethyl formate.Stir, make The adhesive solution of 50mL is obtained, then to addition aggregate, 10g both sexes poly- third in adhesive solution Acrylamide.
3) step 2) gained mixture spontaneously dry after, screening.
Comparative example 3
Proppant:Patent CN1640981A, the precoated sand of the method preparation of embodiment 2.
Embodiment 6-8, the sinking speed of the proppant of comparative example 3 in the natural water of table 3
Test example 1
Active water:The PAMA (molecular weight 3,000,000) of 0.25g, the OP-10 of 1g, The water of the potassium chloride, 0.1g formaldehyde and 488.65g of 10g.
The preparation process of active water is:The polyacrylamide of above-mentioned specified quantitative is dissolved in 488.65g Water in, be well mixed, obtain viscous water;The OP-10 of above-mentioned specified quantitative is dissolved in acquisition In viscous water, it is well mixed;10g potassium chloride is added, is stirred;Add 0.1g first Aldehyde, stirs.
Clear water:Natural water (surface water), without addition chemicals.
Test method:To embodiment 1-8, comparative example 1-3 proppant respectively in active water Solid-carrying performance and frictional resistance parameter testing are carried out, viscosity determining procedure is referring to standard (SYT5107-2005);Sinking speed is determined and uses 0.5m lucite tubes, loads 45cm Active water high and sand shake up the sinking speed of test proppant than the proppant for 30%;Rub Resistance uses DV-III viscosimeters, 30% sand of configuration than pressure break system, fixed rotating speed and rotor, Their moment of torsion is determined to characterize.Test result such as table 4 below:
In table 4, proppant is 30 with the mass ratio of active water:100.Sequence number 1,2 ... is represented Embodiment 1, embodiment 2 ..., sequence number " to 1 " represent comparative example 1.Similarly hereinafter.
The sinking speed of proppant in the active water of table 4
Test method:To embodiment 1-8, the proppant of comparative example 1-3 enters in clear water respectively Liquid viscosity, solid-carrying performance and frictional resistance parameter testing are gone, viscosity determining procedure is referring to standard (SYT5107-2005);Sinking speed is determined and uses 0.5m lucite tubes, loads 45cm Active water high and sand shake up the sinking speed of test proppant than the proppant for 30%;Rub Resistance uses DV-III viscosimeters, 30% sand of configuration than pressure break system, fixed rotating speed and rotor, Their moment of torsion is determined to characterize.Test result such as table 5 below, 6:
The frictional resistance of proppant in the natural water of table 5
The test result of table 5 shows, proposed by the present invention to have in natural water from suspended prop There are excellent prop-carrying capacity and drop frictional resistance ability.
Table 6 adds the viscosity of clear water after proppant
Proppant prepared by the embodiment of the present application 1-10, according to the sand ratio (weight of proppant and water Part ratio) 10:100、20:100、30:100 are added in clear water, after stirring, equal energy Suspend more than two hours.
The proppant of comparative example, according to sand ratio (weight ratio of proppant and water) 10:100、 20:100、30:100 are added in clear water, after stirring, about 10 seconds sedimentation 0.5m of quartz sand, Haydite about 15 seconds, precoated sand about 30 seconds.
Experimental example 2
Using clear water system, fracturing fluid is natural water (surface water), without addition chemicals.
With reference to People's Republic of China's oil and gas industry standard, fracturing propping agents filling bed is short Phase flow conductivity evaluation method, i.e. the permeability of the different proppant packed layers of APIRP61 tests, Mechanical property.The results are shown in Table 7, table 8.
Each test group permeability result (unit of table 7:μm2.cm)
Mechanical performance detection, the group life of each experimental group are carried out according to standard SY/T5108-2006 Ibid, testing result is shown in Table 8 to name:
The mechanical strength test of table 8
Test example 3:
Liaohe Oil Field, certain horizontal well, well depth 1900m.Degassing viscosity of thickened oil 5620mPas (50 DEG C), initial reservoir pressure 10MPa.38 DEG C of the temperature of the original reservoir.
A kind of pressing crack construction method that sand is taken based on natural water, for oil well, as shown in figure 1, Comprise the following steps:
Natural water used by the present embodiment is the clear water of crawl discharge, estimates no solid particle. Proppant used by the present embodiment is made from suspended prop for embodiment 3.
, used as prepad fluid, frozen glue used is 0.4% hydroxypropyl guar gum for step one, configuration frozen glue The aqueous solution is crosslinked through borax and obtains.
Step 2, connection pressing crack construction pipeline, using prepad fluid frozen glue pressure testing, and press off target Reservoir.
Step 3, in the state of continuously stirring, with 2.38m3The flow of/min pumps into clear water Fracturing blender truck, while with 1.02m3The speed of/min is mixed fracturing blender truck is conveyed into from suspended prop Close uniform.
Step 4, well mixed suspension, via pressure break pump truck with mulling identical speed Pump into target reservoir crack.
Work progress pressure is steady, whole process 1.5 hours, after construction finishes closing well 3 hours The row of returning.Return discharge opeing limpid, 10 hours rows of returning are thoroughly.Initial stage daily output liquid 2.6m3/ d, oil-producing 1.7 m3/ d, compared with Lin Jing routine guar gum frozen glue pressure breaks, output increased 12%.
Embodiment above is only that the preferred embodiment of the present invention is described, not right The scope of the present invention is defined, on the premise of design spirit of the present invention is not departed from, this area The all variations and modifications that ordinary skill technical staff makes to technical scheme, all should Fall into the protection domain of claims of the present invention determination.

Claims (7)

1. a kind of exploitation of oil-gas field method, it is characterised in that be to 100 parts of natural waters of parts by volume 5-60 parts of middle addition forms proppant slurry, then by gained proppant from suspended prop Suspension is transported in subterranean strata;
The natural water is selected from the one kind in river, breeding water, lake water, seawater and underground water Or it is various;
It is described from suspended prop be spherical particle that macromolecular material is coated with aggregate;Institute It is water-soluble high-molecular material and the mixture of resin to state macromolecular material, and the resin is natural Resin or synthetic resin;
During the subterranean strata is rock stratum, rammell, Salt layer, the sedimentary type formations of heavy crude reservoir One kind.
2. exploitation of oil-gas field method according to claim 1, it is characterised in that it is described from Suspended prop is that adhesive solution is scattered in aggregate, adds water-soluble high-molecular material It is obtained, the binder solution accounts for aggregate weight 10-30%, and water-soluble high-molecular material accounts for aggregate Weight 0.1~5%.
3. exploitation of oil-gas field method according to claim 1, it is characterised in that the bone Expect for quartz sand, haydite, precoated sand, metallic particles, sintered bauxite, sintered alumina, Sintered zirconia, synthetic resin, globular glass particle, crush shell particle in one kind or It is various;The size of the aggregate is 6-200 mesh.
4. exploitation of oil-gas field method according to claim 1, it is characterised in that described Natural resin is rosin, shellac or kopol;The synthetic resin is phenolic resin or epoxy Resin.
5. exploitation of oil-gas field method according to claim 4, it is characterised in that described Phenolic resin is thermoplastic phenolic resin and/or thermosetting phenolic resin;The epoxy resin choosing From epoxy resin E-55, E-51, E44, E-42, E-35, E-20 (601), E-14, E-12, One or more in E-06, E-03.
6. exploitation of oil-gas field method according to claim 2, it is characterised in that described The solvent of adhesive solution be organic solvent, the organic solvent be selected from acetone, ethyl acetate, Methyl acetate chloroform, one or more in dimethylformamide, tetrahydrofuran, ethanol.
7. exploitation of oil-gas field method according to claim 1, it is characterised in that described Water-soluble high-molecular material be selected from tragacanth gum, locust bean gum, guanidine glue, sesbania gum, rubber made from soybean cake, Xanthans, gellan gum, shitosan, polyamino resin, amino resins, polyurethane resin, poly- third Acrylamide, polyacrylic acid, polyethylene glycol, polyethylene glycol oxide, HPMA, polyquaternium, Carboxymethylcellulose calcium, hydroxymethyl cellulose, methylcellulose, ethyl cellulose, quaternary ammonium salt change Property shitosan, hydroxyethyl cellulose, carboxyethyl starch, acetic starch, methylol guanidine glue, hydroxyl One or more in propyl guanidine glue, carboxy-methyl hydroxy propyl guanidine glue.
CN201511026436.9A 2015-12-31 2015-12-31 Exploitation of oil-gas field method Withdrawn CN106930745A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109233787A (en) * 2018-10-30 2019-01-18 河北鑫合生物化工有限公司 A kind of shale gas slippery water fracturing fluid and preparation method thereof based on microbial polysaccharide
CN109281645A (en) * 2018-09-30 2019-01-29 重庆长江造型材料(集团)股份有限公司 Using the construction method from suspension riverfrac treatment proppant

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104948158A (en) * 2014-03-28 2015-09-30 北京仁创科技集团有限公司 Hydraulic fracturing oil and gas field exploitation method

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104948158A (en) * 2014-03-28 2015-09-30 北京仁创科技集团有限公司 Hydraulic fracturing oil and gas field exploitation method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109281645A (en) * 2018-09-30 2019-01-29 重庆长江造型材料(集团)股份有限公司 Using the construction method from suspension riverfrac treatment proppant
CN109233787A (en) * 2018-10-30 2019-01-18 河北鑫合生物化工有限公司 A kind of shale gas slippery water fracturing fluid and preparation method thereof based on microbial polysaccharide

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