CN106928966A - Expanding material composition containing polyvinyl alcohol and the application from suspended prop and proppant and preparation method - Google Patents
Expanding material composition containing polyvinyl alcohol and the application from suspended prop and proppant and preparation method Download PDFInfo
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- CN106928966A CN106928966A CN201511020962.4A CN201511020962A CN106928966A CN 106928966 A CN106928966 A CN 106928966A CN 201511020962 A CN201511020962 A CN 201511020962A CN 106928966 A CN106928966 A CN 106928966A
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- suspended prop
- material composition
- proppant
- expanding material
- aggregate
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- 239000000463 material Substances 0.000 title claims abstract description 126
- 239000000203 mixture Substances 0.000 title claims abstract description 79
- 239000004372 Polyvinyl alcohol Substances 0.000 title claims abstract description 31
- 229920002451 polyvinyl alcohol Polymers 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 239000012530 fluid Substances 0.000 claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 claims description 40
- 239000002245 particle Substances 0.000 claims description 26
- 239000011230 binding agent Substances 0.000 claims description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
- 239000003822 epoxy resin Substances 0.000 claims description 16
- 229920000647 polyepoxide Polymers 0.000 claims description 16
- -1 haydite Substances 0.000 claims description 15
- 229920006337 unsaturated polyester resin Polymers 0.000 claims description 15
- 229920005989 resin Polymers 0.000 claims description 14
- 239000011347 resin Substances 0.000 claims description 14
- 238000005253 cladding Methods 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 11
- 229920002678 cellulose Polymers 0.000 claims description 9
- 239000001913 cellulose Substances 0.000 claims description 9
- 235000010980 cellulose Nutrition 0.000 claims description 9
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 229920001568 phenolic resin Polymers 0.000 claims description 8
- 239000005011 phenolic resin Substances 0.000 claims description 8
- 210000000988 bone and bone Anatomy 0.000 claims description 7
- 239000012528 membrane Substances 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 5
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims description 5
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 4
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 4
- 239000006004 Quartz sand Substances 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 4
- 125000000623 heterocyclic group Chemical group 0.000 claims description 4
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 4
- 239000013528 metallic particle Substances 0.000 claims description 4
- 229920000609 methyl cellulose Polymers 0.000 claims description 4
- 239000001923 methylcellulose Substances 0.000 claims description 4
- 235000010981 methylcellulose Nutrition 0.000 claims description 4
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 3
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 3
- 239000001856 Ethyl cellulose Substances 0.000 claims description 3
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 3
- 229930040373 Paraformaldehyde Natural products 0.000 claims description 3
- 150000008065 acid anhydrides Chemical class 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 150000004982 aromatic amines Chemical class 0.000 claims description 3
- 229920003090 carboxymethyl hydroxyethyl cellulose Polymers 0.000 claims description 3
- 229940084030 carboxymethylcellulose calcium Drugs 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical group OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- 229920001249 ethyl cellulose Polymers 0.000 claims description 3
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 3
- 239000013505 freshwater Substances 0.000 claims description 3
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims description 3
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 3
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 3
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 3
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 3
- 150000002460 imidazoles Chemical class 0.000 claims description 3
- 230000003859 lipid peroxidation Effects 0.000 claims description 3
- 229920002866 paraformaldehyde Polymers 0.000 claims description 3
- 239000012266 salt solution Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000003079 shale oil Substances 0.000 claims description 3
- 239000010420 shell particle Substances 0.000 claims description 3
- 229920003002 synthetic resin Polymers 0.000 claims description 3
- 239000000057 synthetic resin Substances 0.000 claims description 3
- 150000003512 tertiary amines Chemical class 0.000 claims description 3
- 229960001124 trientine Drugs 0.000 claims description 3
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 claims description 2
- 229910001570 bauxite Inorganic materials 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 239000004312 hexamethylene tetramine Substances 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 150000002632 lipids Chemical class 0.000 claims description 2
- 239000002491 polymer binding agent Substances 0.000 claims description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 238000003786 synthesis reaction Methods 0.000 claims 1
- 229910001928 zirconium oxide Inorganic materials 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 22
- 239000004576 sand Substances 0.000 abstract description 10
- 239000000725 suspension Substances 0.000 abstract description 8
- 239000008239 natural water Substances 0.000 abstract description 3
- 229920000620 organic polymer Polymers 0.000 abstract description 2
- 238000003756 stirring Methods 0.000 description 17
- 238000012216 screening Methods 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 12
- 238000001816 cooling Methods 0.000 description 12
- 238000012360 testing method Methods 0.000 description 10
- 230000000694 effects Effects 0.000 description 5
- LGRFSURHDFAFJT-UHFFFAOYSA-N phthalic anhydride Chemical class C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 5
- 239000010453 quartz Substances 0.000 description 5
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 4
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 229920006305 unsaturated polyester Polymers 0.000 description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229920002521 macromolecule Polymers 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 229920001661 Chitosan Polymers 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- 229920005479 Lucite® Polymers 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 229940105329 carboxymethylcellulose Drugs 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 150000002085 enols Chemical class 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- VHSHLMUCYSAUQU-UHFFFAOYSA-N 2-hydroxypropyl methacrylate Chemical compound CC(O)COC(=O)C(C)=C VHSHLMUCYSAUQU-UHFFFAOYSA-N 0.000 description 1
- AHLWZBVXSWOPPL-RGYGYFBISA-N 20-deoxy-20-oxophorbol 12-myristate 13-acetate Chemical compound C([C@]1(O)C(=O)C(C)=C[C@H]1[C@@]1(O)[C@H](C)[C@H]2OC(=O)CCCCCCCCCCCCC)C(C=O)=C[C@H]1[C@H]1[C@]2(OC(C)=O)C1(C)C AHLWZBVXSWOPPL-RGYGYFBISA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical class C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910000616 Ferromanganese Inorganic materials 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 101000598921 Homo sapiens Orexin Proteins 0.000 description 1
- 101001123245 Homo sapiens Protoporphyrinogen oxidase Proteins 0.000 description 1
- 241001602688 Pama Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 102100029028 Protoporphyrinogen oxidase Human genes 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000006136 alcoholysis reaction Methods 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 235000001465 calcium Nutrition 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 125000001475 halogen functional group Chemical group 0.000 description 1
- 229920013818 hydroxypropyl guar gum Polymers 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 1
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000003129 oil well Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002480 polybenzimidazole Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/80—Compositions for reinforcing fractures, e.g. compositions of proppants used to keep the fractures open
- C09K8/805—Coated proppants
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
- C08L29/02—Homopolymers or copolymers of unsaturated alcohols
- C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/25—Methods for stimulating production
- E21B43/26—Methods for stimulating production by forming crevices or fractures
- E21B43/267—Methods for stimulating production by forming crevices or fractures reinforcing fractures by propping
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Mining & Mineral Resources (AREA)
- Organic Chemistry (AREA)
- Geology (AREA)
- Fluid Mechanics (AREA)
- Environmental & Geological Engineering (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of expanding material composition, said composition includes polyvinyl alcohol and semi-synthetic macromolecular material, wherein, the mass ratio of polyvinyl alcohol and semi-synthetic macromolecular material is (10-900)：1.Also disclose using expanding material composition preparation from suspended prop and its preparation method and application.Using expanding material composition of the invention prepare from suspended prop without using with the addition of organic polymer and costly fracturing fluid carries out pressure break, and directly carry out pressure break using the natural water being available anywhere, reduce pollution, reduce cost.Suspended state is can be at after prepared by expanding material composition of the invention mix from suspended prop with water, and suspension time is long, it is flow conductivity good, sand plug can be effectively reduced during filling crack, the distance of conveying is farther, and fuel-displaced/tolerance is bigger.
Description
Technical field
The present invention relates to exploitation of mineral resources field, in particular it relates to a kind of expanding material composition and certainly suspension
Proppant and its preparation method and application.
Background technology
Oil and gas occupy critical role, the oil gas money on China land in Chinese national economy development
Source by over half a century exploitation, many oil wells have started to aging or even exhaustion, for having for oil field
Effect exploitation and volume increase become more and more important.
The major measure of current well production increment is hydraulic fracturing technology, and the high pressure pump group using ground is isobaric
Equipment is split constantly to be injected beyond its absorbability, the fracturing fluid with hyperviscosity to oil reservoir by pit shaft
And cause to form pressure higher on oil reservoir, with the continuous injection of fracturing fluid, pressure is also constantly raised,
When this pressure is higher than strata pressure near the borehole wall and formation rock tensile strength, oil reservoir will be opened by pressure break
And the different crack of not of uniform size, length is formed, then will be propped up in proppant transport to crack by load fluid
Crack seam so that a fluid passage is formed between oil reservoir and pit shaft, the effect of volume increase is reached.Fracturing fluid
Flow at high speed, using turbulent suspension proppant, but after proppant reaches crack, due to rate of flow of fluid
Decline to a great extent, proppant rapid subsidence is in Slit bottom (A of patent CN 102159797).To reduce
Leak-off, and prop-carrying capacity is improved, generally addition organic high molecular compound makees thickener in fracturing fluid, and
These organic high molecular compounds can enter stratum with fracturing fluid, be partially left at the macromolecule chemical combination of underground
Thing blocks the hole on stratum, cause oil pump capacity decline, underground water pollution the problems such as.Additionally, fracturing fluid viscosity
Increase so that the pump power consumed during the row of returning is larger, and it is unfavorable for all rows of returning.
The content of the invention
It is an object of the invention to provide a kind of expanding material composition and from suspended prop and proppant
Preparation method and application, with overcome need in the prior art in fracturing fluid add thickener with complete to branch
Thickener blocks oil outlet and pollutes the defect of environment caused by supportting the conveying of agent.
To achieve these goals, first aspect present invention, there is provided a kind of expanding material composition, the group
Compound includes polyvinyl alcohol and semi-synthetic macromolecular material, wherein, polyvinyl alcohol and semi-synthetic macromolecule material
The mass ratio of material is (10-900)：1, semi-synthetic macromolecular material is modified cellulose macromolecular material.
Preferably, the weight average molecular weight of polyvinyl alcohol is 16000-200000.
Preferably, modified cellulose macromolecular material is selected from carboxymethylcellulose calcium, methylcellulose, second
Base cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose and carboxymethyl hydroxyl second
At least one in base cellulose.
Second aspect present invention, there is provided one kind should include proppant from suspended prop from suspended prop
Body and cladding or part are coated on the intumescent material of proppant body surface, and the intumescent material is by this
The expanding material composition of invention first aspect is bonded through binding agent and curing agent and coated or part cladding
Formed on the proppant body；Wherein, expanding material composition is with the mass ratio of proppant body
1：(100-1600)；The weight ratio of proppant body, binding agent and curing agent is 1：(0.001-0.2)：
(0.001-0.2)。
Preferably, proppant body is aggregate and/or pre-coated membrane bone material.
Preferably, aggregate is selected from quartz sand, haydite, metallic particles, globular glass particle, sintered aluminium
At least one in the shell particle of Tu Kuang, sintered alumina, sintered zirconia, synthetic resin and crushing；
The particle diameter of the aggregate is 6-200 mesh.
Preferably, pre-coated membrane bone material is to include that aggregate and cladding or part are coated on the pre- overlay film of aggregate surface
Resin bed.
Preferably, pre- film covered resin layer is resin material obtained by the coated treatment of aggregate surface, wherein,
Resin material is selected from least one in phenolic resin, furane resins and epoxy resin.
Preferably, binding agent is high selected from phenolic resin, epoxy resin, unsaturated polyester resin and heterocycle
At least one in molecular binder.
Preferably, curing agent be selected from aliphatic amine and its addition product, tertiary amine and its salt, aromatic amine and
Its modified body, imidazoles, acid anhydrides, acyl peroxide, lipid peroxidation, paraformaldehyde, phenolic aldehyde amine, divinyl
At least one in triamine, triethylene tetramine and hexamethylenetetramine.
Third aspect present invention, there is provided the preparation method from suspended prop of second aspect present invention, should
Method includes：(1) by proppant body and binding agent and curing agent, dispersion mixing is uniform at the first temperature,
Wherein, the weight ratio of proppant body, binding agent and curing agent is 1：(0.001-0.2)：(0.001-0.2)；
(2) make the proppant body and expanding material composition at the second temperature dispersion mixing it is uniform so that
Expanding material composition is coated or part is coated on proppant body, obtains granular from suspension support
Agent, wherein, expanding material composition is 1 with the mass ratio of the proppant body：(100-1600).
Preferably, the first temperature is 150-240 DEG C；Second temperature is 80-180 DEG C.
Fourth aspect present invention, there is provided second aspect present invention from suspended prop in fluid ore deposit exploitation side
The application in face.
Preferably, fluid ore deposit is including in natural gas, oil, shale gas, shale oil, fresh water and salt solution
It is at least one.
By above-mentioned technical proposal, expanding material composition low cost of the invention, environmental pollution is small.
By expanding material composition of the invention be coated on aggregate it is obtained from suspended prop without using adding
Plus organic polymer and costly fracturing fluid carries out pressure break, directly use natural water, and and water
Suspended state is can be at after mixing, suspension time is long, flow conductivity good, the energy during crack is filled
Enough effectively to reduce sand plug, the distance of conveying is farther, and fuel-displaced/tolerance is bigger.Further, since of the invention swollen
The swollen material compositions characteristics of itself, can reduce the frictional resistance of fracturing fluid, easily conveying, the easily row of returning, and the row of returning
Energy consumption reduction, does not have macromolecular material to remain, and is conducive to environmental protection, can better meet oil recovery
Need.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Specific embodiment
Specific embodiment of the invention is described in detail below.It should be appreciated that this place is retouched
The specific embodiment stated is merely to illustrate and explain the present invention, and is not intended to limit the invention.
First aspect present invention：A kind of expanding material composition is provided, the composition includes polyvinyl alcohol
With semi-synthetic macromolecular material.
According to the first aspect of the invention, the mass ratio of polyvinyl alcohol and semi-synthetic macromolecular material is larger
In the range of can realize the purpose of the present invention, for example, the matter of polyvinyl alcohol and semi-synthetic macromolecular material
Amount ratio can be (10-900)：1.
According to the first aspect of the invention, polyvinyl alcohol is that structural formula is [CH2CH(OH)]nMacromolecule
Polymer, wherein, n can be 102-106Between arbitrary integer.The presence of great amount of hydroxy group group makes poly- second
Enol has very strong water solubility, however, due to being existed compared with strong hydrogen bonding with intermolecular in macromolecular, and
Hinder it water-soluble.On the other hand, the acetate of partial alcoholysis polyvinyl alcohol remaining has hydrophobicity,
Its larger steric hindrance can weaken intermolecular and intramolecular hydrogen bond, so as to improve the water-soluble of polyvinyl alcohol
Property.Therefore, the present invention needs to choose the polyvinyl alcohol with suitable water soluble, under preferable case, is applicable
In formed expanding material composition polyvinyl alcohol weight average molecular weight in 16000-200000.Weight-average molecular
Amount polyvinyl alcohol within the above range can meet the purpose of the present invention, for example, commercial polyethylene alcohol
The trade mark can be but be not limited to：The external type trade mark be 1xx and 2xx, the domestic type trade mark be 17-xx,
20-xx, 22-xx and 24-xx, wherein xx are the numeral for representing solubility.
According to the first aspect of the invention, the implication of semi-synthetic macromolecular material is those skilled in the art institute
Know, be chemically modified by natural materials and obtain, it is preferable that semi-synthetic macromolecular material can be to change
Property cellulosic polymer material.Wherein, modified cellulose macromolecular material can be selected from carboxymethyl cellulose
Element, methylcellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl
At least one in cellulose and carboxymethyl hydroxyethyl cellulose.The semi-synthetic high score of commercially available mentioned kind
Sub- material product can be used as semi-synthetic macromolecular material of the invention, for example, above-mentioned kind
The semi-synthetic macromolecular material of class can grind life purchased from Aladdin reagent (Shanghai) Co., Ltd., Shanghai one
Thing Science and Technology Ltd., Zhongxiang Hubei gold auspicious sign Chemical Co., Ltd., Guangzhou Hu Ao Chemical Co., Ltd.s,
Shanghai Hu Zhen Industrial Co., Ltd.s and Shanghai Yan Sheng Industrial Co., Ltd.s etc..Using above-mentioned semi-synthetic macromolecule
The water-soluble expansion suspension material that material is formed with polyvinyl alcohol can be soluble in water rapidly and then be expanded, can
Suspended state is in for a long time, while there is low cost, polluting small.
Second aspect present invention, there is provided one kind should include proppant from suspended prop from suspended prop
Body and cladding or part are coated on the intumescent material of proppant body surface.By first aspect present invention
Expanding material composition stick in proppant body surface after, it is resulting from suspended prop in normal temperature
Can dissolve and expand in water after mixing with water down so that the sinking speed from suspended prop is slack-off,
With suspending power.
According to the second aspect of the invention, in order to reach the purpose of the present invention, expanding material composition is at least
Part is coated on proppant body surface, it is preferable that the quality of expanding material composition and proppant body
Than that can be 1：(100-1600), what is obtained under said ratio is easier in water from suspended prop
Long-time suspend.
According to the second aspect of the invention, proppant body is mechanical enough with crack closure stress is born
The natural hard particle of intensity or the artificial hard particles fired, can be aggregate and/or pre-coated membrane bone material.
Aggregate can be the existing various aggregates that can be used in preparing fracturing propping agents, for example, aggregate can be
Selected from quartz sand, haydite, metallic particles, globular glass particle, sintered bauxite, sintered alumina,
At least one in the shell particle of sintered zirconia, synthetic resin and crushing；The aggregate of metal material is excellent
The material that hardness is high is selected, for example, the material of metallic particles can be stainless steel, aluminium alloy, carbon steel, iron nickel
At least one in alloy or ferromanganese.The average grain diameter of aggregate can be in interior change in a big way, can
To be selected according to actual needs, for example, the particle diameter of skeletal grain can be 6-200 mesh.Using above-mentioned kind
The aggregate of class is made proppant body and is had from suspended prop with obtained in expanding material composition of the invention
Standby resistant to breakage ability higher.
According to the second aspect of the invention, one layer of pre- film covered resin layer can also be coated in above-mentioned aggregate surface
Pre-coated membrane bone material is formed so as to further improve the resistant to breakage ability of aggregate, improves circularity and sphericity, improved
Flow conductivity.Therefore, the proppant body is additionally may included in above-mentioned aggregate surface and coats pre- overlay film tree
The pre-coated membrane bone material that lipid layer is formed, for example, can be precoated sand and film-coated ceramisite；It is coated on aggregate surface
Resin material can be selected from least one in phenolic resin, furane resins and epoxy resin.
According to the second aspect of the invention, intumescent material is coated on the process of proppant body surface
In, binding agent and curing agent can also be added, so that intumescent material is more easy to stick in proppant body
On.The species of binding agent and curing agent can be well known to those skilled in the art for fracturing propping agents
Preparation field conventional binding agent and curing agent, for example, binding agent can be selected from phenolic resin, epoxy
At least one in resin, unsaturated polyester resin and heterocyclic polymer binding agent.It is further preferred that
Phenolic resin can be thermoplastic phenolic resin or thermosetting phenolic resin；Epoxy resin can use epoxy
Equivalent is the epoxy resin of 0.09-0.14mol/100g；Preferably bisphenol A type epoxy resin, more preferably
Be selected from epoxy resin E-55 (616), E-51 (618), E-44 (6101), E-42 (634), E-35 (637),
At least one in E-20 (601), E-12 (604), E-06 (607) and E-03 (609)；Unsaturated polyester (UP) tree
Fat can be unsaturated for m-phthalate unsaturated polyester resin, metaphenylene unsaturated polyester resin, xylol type
Polyester resin, Bisphenol a unsaturated polyester resin, halo unsaturated polyester resin and vinyl ester resin
In at least one；It is preferred that m-phthalate unsaturated polyester resin, model can be 191 or 196；Isophthalic
Type unsaturated polyester resin model can be 199；Xylol type unsaturated polyester resin model can be
2608th, at least one in 902A3, Xm-1 and Xm-2；Bisphenol a unsaturated polyester resin type
Number can be 197,3301 and 323 at least one；Heterocyclic polymer bonding agent can be selected from polyamides
At least one in imines, polybenzimidazoles, polyphenylene sulfide and polydiphenyl ether.Curing agent can be selected from
Aliphatic amine and its addition product, tertiary amine and its salt, aromatic amine and its modified body, imidazoles, acid anhydrides, mistake
Oxidation acyl, lipid peroxidation, paraformaldehyde, phenolic aldehyde amine, diethylenetriamine, triethylene tetramine and six first
At least one in urotropine.Using the binding agent and curing agent of mentioned kind may be such that intumescent material with
Proppant body adhesion effect more preferably, and will not make proppant particles reunite and influence fracturing propping agents
Particle size and dispersiveness.
According to the second aspect of the invention, binding agent can be according to intumescent material with the inventory of curing agent
Selected in the cladding degree of proppant body surface, under preferable case, proppant body, binding agent
Can be 1 with the weight ratio of curing agent：(0.001-0.2)：(0.001-0.2).
Third aspect present invention, there is provided the preparation method from suspended prop of second aspect present invention, should
Method includes：(1) by proppant body and binding agent and curing agent, dispersion mixing is uniform at the first temperature,
Wherein, the weight ratio of proppant body, binding agent and curing agent is 1：(0.001-0.2)：(0.001-0.2)；
(2) make the proppant body and expanding material composition at the second temperature dispersion mixing it is uniform so that
Expanding material composition is coated or part is coated on proppant body, obtains granular from suspension support
Agent, wherein, expanding material composition is 1 with the mass ratio of the proppant body：(100-1600).
Preparation method from suspended prop of the invention can be in proppant body surface cladding expansion material
Feed composition, obtain from suspended prop can using water as fracturing fluid, meanwhile, from suspended prop
The expanding material composition on surface is rapid swelling in water, forms the hydrated sheath of expansion, reduces proppant
The relative density of grain, makes it be suspended on the water surface, consequently facilitating the conveying of fracturing fluid.
In the preparation method from suspended prop of the invention, in order to improve proppant body cladding
The covered effect of expanding material composition, can pre-process to proppant body, and processing method is this
Known to art personnel, for example, it is preferred to the steps such as scouring, drying, screening can be first passed through,
To remove the moisture in aggregate, it is easy to aggregate preferably to be combined with expanding material composition.
In the preparation method from suspended prop of the invention, the first Contact Temperature and second is contacted
Temperature do not require particularly, as long as meet above-mentioned binding agent and curing agent can be with the first Contact Temperature
Melt to be coated on proppant body surface；Above-mentioned expanding material composition can be with the second Contact Temperature
It is further bonded.Under preferable case, the first temperature can be 150-240 DEG C；Second temperature can be with
It is 80-180 DEG C.At the temperature disclosed above, can obtain expanding material composition cladding or part cladding from
Suspended proppant particles.The obtained step that cooling and screening are can further include from suspended prop
Suddenly.
Fourth aspect present invention, there is provided second aspect present invention from suspended prop in fluid ore deposit exploitation side
The application in face.Wherein, fluid ore deposit includes natural gas, oil, shale gas, shale oil, fresh water and salt solution
In at least one.
The present invention is further illustrated below by embodiment, but therefore the present invention is not subject to any limit
System.
Embodiment 1
The present embodiment is used to illustrate expanding material composition of the invention and by expanding material composition system
It is standby from suspended prop and preparation method thereof.
Take polyvinyl alcohol (purchased from Shenzhen uncle along Chemical Co., Ltd.) and 0.06g that the 10g trades mark are 17-99
Carboxymethylcellulose calcium (being purchased from Aladdin reagent (Shanghai) Co., Ltd.) is mixed as expanding material
Composition.
1kg quartz sands that average particle diameter is 20-40 mesh are taken as aggregate, 200 DEG C are heated to, 15g is added
Epoxy resin E-35 (637) and 5g curing agent phthalic anhydrides, stirring add after being cooled to 140 DEG C
Enter expanding material composition obtained above, stir.Cooling, screening, obtain the present embodiment from
Suspended prop.
Embodiment 2
The present embodiment is used to illustrate expanding material composition of the invention and by expanding material composition system
It is standby from suspended prop and preparation method thereof.
Take polyvinyl alcohol (purchased from Shenzhen uncle along Chemical Co., Ltd.) and 0.02g that the 15g trades mark are 17-88
Hydroxyethyl cellulose (being purchased from Guangzhou Hu Ao Chemical Co., Ltd.s) is mixed to be combined as expanding material
Thing.
2kg haydites that average particle diameter is 50-100 mesh are taken as aggregate, 180 DEG C are heated to, 45g is added
Bisphenol a unsaturated polyester resin 197 and 6g curing agent benzoyl peroxides, after being cooled to 120 DEG C
Expanding material composition obtained above is added, is stirred.Cooling, screening, obtain the present embodiment
From suspended prop.
Embodiment 3
The present embodiment is used to illustrate expanding material composition of the invention and by expanding material composition system
It is standby from suspended prop and preparation method thereof.
Take polyvinyl alcohol (purchased from Shenzhen uncle along Chemical Co., Ltd.) and 0.7g that the 7g trades mark are 17-78
Hydroxypropyl methyl cellulose (being purchased from Guangzhou Hu Ao Chemical Co., Ltd.s) is mixed as expanding material
Composition.
2kg glass microspheres that average particle diameter is 70-140 mesh are taken as aggregate, 240 DEG C are heated to, added
400g neighbour's benzene-type unsaturated polyester (UP) 191 and 400g curing agent diethylenetriamines, add after being cooled to 100 DEG C
Enter expanding material composition obtained above, stir.Cooling, screening, obtain the present embodiment from
Suspended prop.
Embodiment 4
The present embodiment is used to illustrate expanding material composition of the invention and by expanding material composition system
It is standby from suspended prop and preparation method thereof.
Take polyvinyl alcohol (purchased from Shenzhen uncle along Chemical Co., Ltd.) and 0.01g that the 5g trades mark are 17-92
Methylcellulose (grinding bio tech ltd purchased from Shanghai one) is mixed to be combined as expanding material
Thing.
Take average particle diameter be 50-100 mesh 1kg precoated sands (according to patent CN1274626A embodiments 1
Method manufacture) as aggregate, be heated to 200 DEG C, add 80g epoxy resin E12 (604) and 40g
Curing agent HPMA, adds expanding material composition obtained above after being cooled to 140 DEG C, stirring
Uniformly.Cooling, screening, obtain of the invention from suspended prop.
Embodiment 5
The present embodiment is used to illustrate expanding material composition of the invention and by expanding material composition system
It is standby from suspended prop and preparation method thereof.
Take polyvinyl alcohol (purchased from Shenzhen uncle along Chemical Co., Ltd.) and 0.03g that the 23g trades mark are 24-88
Carboxymethyl hydroxyethyl cellulose (purchased from Zhongxiang Hubei gold auspicious sign Chemical Co., Ltd.) is mixed as swollen
Swollen material compositions.
Take 10kg precoated sands (the scientific and technological group production of benevolence wound, model that average particle diameter is 30-50 mesh
ZFS-KGD) as aggregate, 250 DEG C are heated to, add 35g metaphenylene unsaturated polyester resins 199
With 800g curing agent chitosan quaternary ammonium salts, expanding material obtained above is added to combine after being cooled to 100 DEG C
Thing, stirs.Cooling, screening, obtain of the invention from suspended prop.
Embodiment 6
The present embodiment is used to illustrate expanding material composition of the invention and by expanding material composition system
It is standby from suspended prop and preparation method thereof.
Take polyvinyl alcohol (purchased from Shenzhen uncle along Chemical Co., Ltd.) and 0.01g that the 9g trades mark are 22-99
Ethyl cellulose (being purchased from Shanghai Hu Zhen Industrial Co., Ltd.s) is mixed as expanding material composition.
Take 9kg precoated sands (the scientific and technological group production of benevolence wound, model that average particle diameter is 20-40 mesh
ZFS-KGM) as aggregate, 250 DEG C are heated to, add 900g Bisphenol a unsaturated polyester resins
3301 and 900g curing agent chitosan quaternary ammonium salts, add expansion material obtained above after being cooled to 100 DEG C
Feed composition, stirs.Cooling, screening, obtain of the invention from suspended prop.
Embodiment 7
The present embodiment is used to illustrate expanding material composition of the invention and by expanding material composition system
It is standby from suspended prop and preparation method thereof.
Take polyvinyl alcohol (purchased from Shenzhen uncle along Chemical Co., Ltd.) and 0.2g that the 7g trades mark are 20-99
Hydroxypropyl cellulose (being purchased from Shanghai Yan Sheng Industrial Co., Ltd.s) is mixed as expanding material composition.
1kg sintered aluminas that average particle diameter is 50-100 mesh are taken as aggregate, 200 DEG C are heated to, plus
Enter 55g epoxy resin E-55 (616) and 10g curing agent triethylene tetramines, add after being cooled to 140 DEG C
Enter expanding material composition obtained above, stir.Cooling, screening, obtain of the invention certainly outstanding
Floating proppant.
Embodiment 8
The present embodiment is used to illustrate expanding material composition of the invention and by expanding material composition system
It is standby from suspended prop and preparation method thereof.
Take polyvinyl alcohol (purchased from Shenzhen uncle along Chemical Co., Ltd.) and 0.5g that the 10g trades mark are 20-88
Hydroxypropyl cellulose (being purchased from Shanghai Yan Sheng Industrial Co., Ltd.s) is mixed as expanding material composition.
Stainless steel particles of 16kg that average particle diameter is 30-50 mesh are taken as aggregate, 280 DEG C are heated to, plus
Enter 16g xylol types unsaturated polyester resin 2608 and 20g curing agent hexamethylenetetramines, be cooled to
Expanding material composition obtained above is added after 100 DEG C, is stirred.Cooling, screening, obtain this
Invention from suspended prop.
Comparative example 1
It is the quartz sand of 20-40 mesh as proppant to use particle mean size.
Comparative example 2
1kg quartz sands that average particle diameter is 20-40 mesh are taken as aggregate, 200 DEG C are heated to, 15g is added
Epoxy resin E-35 (637) and 5g curing agent phthalic anhydrides, stirring, stir.Cooling,
Screening, obtains the proppant of this comparative example.
Comparative example 3
1kg quartz sands that average particle diameter is 20-40 mesh are taken as aggregate, 200 DEG C are heated to, 15g is added
Epoxy resin E-35 (637) and 5g curing agent phthalic anhydrides, stirring add after being cooled to 140 DEG C
Enter 0.06g carboxymethylcellulose calciums (purchased from Aladdin reagent (Shanghai) Co., Ltd.), stir.It is cold
But, sieve, obtain this comparative example from suspended prop.
Comparative example 4
1kg quartz sands that average particle diameter is 20-40 mesh are taken as aggregate, 200 DEG C are heated to, 15g is added
Epoxy resin E-35 (637) and 5g curing agent phthalic anhydrides, stirring add after being cooled to 140 DEG C
Enter the polyvinyl alcohol that the 10g trades mark are 17-99, stir.Cooling, screening, obtain this comparative example
From suspended prop.
Comparative example 5
1kg quartz sands that average particle diameter is 20-40 mesh are taken as aggregate, 200 DEG C are heated to, 15g is added
Epoxy resin E-35 (637) and 5g curing agent phthalic anhydrides, stirring add after being cooled to 140 DEG C
Enter 10g PPOXs (purchased from Shanghai Zhen Zhun bio tech ltd) and 0.06g carboxymethyl celluloses
Element (is purchased from Aladdin reagent (Shanghai) Co., Ltd.), stirs.Cooling, screening, obtain this
Comparative example from suspended prop.
Testing example 1
The preparation of active water：By the PAMA of 0.25g, (weight average molecular weight is 3 × 106)
It is dissolved in the water of 488.65g, is well mixed, obtains viscous water；The OP-10 of 1g is dissolved in acquisition
In viscous water, it is well mixed；10g potassium chloride is added, is stirred；Add 0.1g formaldehyde, stirring
Uniformly.
Test method：By embodiment 1-8, comparative example 1-5 from suspended prop respectively in active water
Liquid viscosity, solid-carrying performance and frictional resistance parameter testing are carried out, viscosity determining procedure is referring to standard
(SYT5107-2005)；Sinking speed is determined and uses 0.5m lucite tubes, loads 45cm work high
Property water and sand than the proppant for 30%, shake up the sinking speed of test proppant；Frictional resistance uses DV-III
Viscosimeter, configuration 30% sand than pressure break system, rotating speed is 100rpm, and the moment of torsion for determining them carrys out table
Levy the frictional resistance of proppant.Test result is as shown in table 1 below：
Table 1
From table 1 data can be seen that prepared by expanding material composition of the invention from suspended prop
Possess excellent prop-carrying capacity and drop frictional resistance ability in active water.From embodiment 1-8 and comparative example 1-5
Data Comparison can be seen that prepared by expanding material composition of the invention from suspended prop with do not make
The proppant aggregate of any cladding and only coat binding agent and compared with the proppant aggregate of curing agent, its
Sinking speed and frictional resistance are lower, and the viscosity of the active water for obtaining is also smaller, illustrate expanding material of the invention
Prepared by composition possesses more excellent prop-carrying capacity and drop frictional resistance ability from suspended prop；It is of the invention
Be applied in combination for polyvinyl alcohol and semi-synthetic macromolecular material by expanding material composition, than poly- second is used alone
Enol is used alone semi-synthetic macromolecular material all with more preferable effect；And it is water-soluble high using other
The resulting effect that molecule substitutes polyvinyl alcohol is poor.From the data of embodiment 4-6 it can also be seen that
When doing aggregate using precoated sand, the taking from suspended prop prepared by expanding material composition of the invention
Sand ability and drop frictional resistance ability are more prominent.
Testing example 2
The proppant of embodiment 1-8, comparative example 1-5 is carried out into liquid viscosity in clear water respectively, sand is taken
Performance and frictional resistance parameter testing, viscosity determining procedure is referring to standard (SYT5107-2005)；Sedimentation speed
Degree is determined and uses 0.5m lucite tubes, loads 45cm active waters high and sand than the support for 30%
Agent, shakes up the sinking speed of test proppant；Frictional resistance use DV-III viscosimeters, configuration 30% sand than
Pressure break system, fixed rotating speed and rotor, determine their moment of torsion to characterize.Test result is as shown in table 2：
Table 2
Data can be seen that existing from suspended prop for water-soluble composition preparation of the invention from table 2
Possess excellent prop-carrying capacity and drop frictional resistance ability in riverfrac treatment system.
Testing example 3：
Liaohe Oil Field, certain horizontal well, well depth 1900m.Degassing viscosity of thickened oil 5620mPas (50 DEG C),
Initial reservoir pressure 10MPa.38 DEG C of the temperature of the original reservoir.
Natural water used is the clear water of crawl discharge, estimates no solid particle.Proppant used is real
Apply example 5 from suspended prop.
, used as prepad fluid, frozen glue used is the aqueous solution of 0.4% hydroxypropyl guar gum for step one, configuration frozen glue
It is crosslinked through borax and is obtained.
Step 2, connection pressing crack construction pipeline, using prepad fluid frozen glue pressure testing, and press off target reservoir.
Step 3, in the state of continuously stirring, with 2.38m3Clear water is pumped into fracturing blender truck by the flow of/min,
Simultaneously with 1.02m3The speed of/min is well mixed fracturing blender truck is conveyed into from suspended prop.
Step 4, well mixed suspension, mesh is pumped into via pressure break pump truck with mulling identical speed
Mark Reservoir Fracture.
Work progress pressure is steady, whole process 1.5 hours, and construction finishes the closing well row of returning after 3 hours.
Return discharge opeing limpid, 10 hours rows of returning are thoroughly.Initial stage daily output liquid 2.2m3/ d, oil-producing 1.4m3/ d, and faces
Well routine guar gum frozen glue pressure break is compared, output increased 10%.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited to above-mentioned reality
The detail in mode is applied, in range of the technology design of the invention, can be to technical side of the invention
Case carries out various simple variants, and these simple variants belong to protection scope of the present invention.
It is further to note that each particular technique described in above-mentioned specific embodiment is special
Levy, in the case of reconcilable, can be combined by any suitable means.In order to avoid need not
The repetition wanted, the present invention is no longer separately illustrated to various possible combinations.
Additionally, can also be combined between a variety of implementation methods of the invention, as long as its
Without prejudice to thought of the invention, it should equally be considered as content disclosed in this invention.
Claims (13)
1. a kind of expanding material composition, it is characterised in that the composition includes polyvinyl alcohol and half
Synthesis macromolecular material, the mass ratio of the polyvinyl alcohol and the semi-synthetic macromolecular material is
(10-900)：1, the semi-synthetic macromolecular material is modified cellulose macromolecular material.
2. composition according to claim 1, it is characterised in that the weight of the polyvinyl alcohol is equal
Molecular weight is 16000-200000.
3. composition according to claim 1, it is characterised in that the modified cellulose high score
Sub- material is selected from carboxymethylcellulose calcium, methylcellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxyl
At least one in propyl cellulose, hydroxypropyl methyl cellulose and carboxymethyl hydroxyethyl cellulose.
4. one kind is from suspended prop, it is characterised in that described to include proppant sheet from suspended prop
Body and cladding or part are coated on the intumescent material of proppant body surface, and the intumescent material is by right
It is required that the expanding material composition in 1-3 described in any one bonded through binding agent and curing agent and coat or
Part is coated on the proppant body and is formed；The expanding material composition and the proppant body
Mass ratio be 1：(100-1600)；The weight ratio of the proppant body, binding agent and curing agent is
1：(0.001-0.2)：(0.001-0.2).
5. it is according to claim 4 from suspended prop, it is characterised in that the proppant sheet
Body is aggregate and/or pre-coated membrane bone material.
6. it is according to claim 5 from suspended prop, it is characterised in that the aggregate is choosing
From quartz sand, haydite, metallic particles, globular glass particle, sintered bauxite, sintered alumina, burning
At least one in the shell particle of knot zirconium oxide, synthetic resin and crushing；The particle diameter of the aggregate is
6-200 mesh.
7. it is according to claim 5 from suspended prop, it is characterised in that the pre-coated membrane bone
Material is to include that aggregate and cladding or part are coated on the pre- film covered resin layer of aggregate surface.
8. it is according to claim 7 from suspended prop, it is characterised in that the pre- overlay film tree
Lipid layer be resin material obtained by the coated treatment of aggregate surface, the resin material is selected from phenolic aldehyde tree
At least one in fat, furane resins and epoxy resin.
9. it is according to claim 4 from suspended prop, it is characterised in that the binding agent is
Selected from least in phenolic resin, epoxy resin, unsaturated polyester resin and heterocyclic polymer binding agent
Kind；The curing agent is selected from aliphatic amine and its addition product, tertiary amine and its salt, aromatic amine and its changes
Gonosome, imidazoles, acid anhydrides, acyl peroxide, lipid peroxidation, paraformaldehyde, phenolic aldehyde amine, diethylenetriamine,
At least one in triethylene tetramine and hexamethylenetetramine.
10. the preparation method from suspended prop in claim 4-9 described in any one, its feature
It is that the method is comprised the following steps：
(1) by proppant body and binding agent and curing agent, dispersion mixing is uniform at the first temperature, its
In, the weight ratio of the proppant body, binding agent and curing agent is 1：(0.001-0.2)：(0.001-0.2)；
(2) dispersion mixing is uniform at the second temperature to make the proppant body and expanding material composition
So that the expanding material composition cladding or part are coated on the proppant body, graininess is obtained
From suspended prop, wherein, the expanding material composition is with the mass ratio of the proppant body
1：(100-1600).
11. preparation methods according to claim 10, it is characterised in that first temperature is
150-240℃；The second temperature is 80-180 DEG C.
In 12. claim 4-9 described in any one from suspended prop in terms of fluid ore deposit exploitation
Using.
13. applications according to claim 12, it is characterised in that the fluid ore deposit includes natural
At least one in gas, oil, shale gas, shale oil, fresh water and salt solution.
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Cited By (2)
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|---|---|---|---|---|
| CN108841372A (en) * | 2018-07-04 | 2018-11-20 | 中国石油集团渤海钻探工程有限公司 | Water-absorbing resins overlay film is from suspended prop and preparation method thereof |
| EP3904401A4 (en) * | 2018-12-27 | 2022-02-16 | Mitsubishi Chemical Corporation | Diverting agent and method for closing crack in well using same |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104364343A (en) * | 2012-04-19 | 2015-02-18 | 自悬浮支撑有限公司 | Self-suspending proppants for hydraulic fracturing |
| CN104948160A (en) * | 2014-03-28 | 2015-09-30 | 北京仁创科技集团有限公司 | Self-suspension proppant and preparation method thereof and construction method |
-
2015
- 2015-12-30 CN CN201511020962.4A patent/CN106928966A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104364343A (en) * | 2012-04-19 | 2015-02-18 | 自悬浮支撑有限公司 | Self-suspending proppants for hydraulic fracturing |
| CN104379697A (en) * | 2012-04-19 | 2015-02-25 | 自悬浮支撑有限公司 | Self-suspending proppants for hydraulic fracturing |
| CN104948160A (en) * | 2014-03-28 | 2015-09-30 | 北京仁创科技集团有限公司 | Self-suspension proppant and preparation method thereof and construction method |
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| CN108841372A (en) * | 2018-07-04 | 2018-11-20 | 中国石油集团渤海钻探工程有限公司 | Water-absorbing resins overlay film is from suspended prop and preparation method thereof |
| EP3904401A4 (en) * | 2018-12-27 | 2022-02-16 | Mitsubishi Chemical Corporation | Diverting agent and method for closing crack in well using same |
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