CN106929712A - The alloy round aluminum rod and its production method of intensity in a kind of low resistance - Google Patents

The alloy round aluminum rod and its production method of intensity in a kind of low resistance Download PDF

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Publication number
CN106929712A
CN106929712A CN201710214340.8A CN201710214340A CN106929712A CN 106929712 A CN106929712 A CN 106929712A CN 201710214340 A CN201710214340 A CN 201710214340A CN 106929712 A CN106929712 A CN 106929712A
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aluminium
temperature
alloy round
aluminum rod
round aluminum
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CN106929712B (en
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李全
陈德斌
木群花
田光辉
王孟金
罗建华
李顺祥
杨亚伟
李明
陈金花
姬凤武
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Yunnan Aluminium Co Ltd
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Yunnan Aluminium Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/03Making non-ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/06Making non-ferrous alloys with the use of special agents for refining or deoxidising
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/12Alloys based on aluminium with copper as the next major constituent
    • C22C21/14Alloys based on aluminium with copper as the next major constituent with silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/12Alloys based on aluminium with copper as the next major constituent
    • C22C21/18Alloys based on aluminium with copper as the next major constituent with zinc
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/057Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with copper as the next major constituent
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/02Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys
    • H01B1/023Alloys based on aluminium

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Conductive Materials (AREA)

Abstract

The present invention relates to a kind of alloy round aluminum rod of intensity in low resistance, described alloy round aluminum rod includes Si, Fe, Cu, Zn, B, Ti and RE, and the various composition is by weight:Si:0.03‑0.10%、Fe:0.20‑0.70%、Cu:0.10‑0.28%、Zn:0.015‑0.06%、B:0.005‑0.020%、Ti:0.001‑0.02%、RE:0.05 0.2%, balance of AL and inevitable impurity, further relate to the production method of the alloy round aluminum rod.Alloy round aluminum rod tensile strength of the invention is up to more than 170MPa, resistivity is less than 29.00n Ω m, largely reduce cable installation cost, compared with steel wire aluminum stranded conductor, the cable of same cross-sectional area, current-carrying capacity is greatly improved, and the sag increase of cable is not obvious, large span erecting cable is can be widely applied to, the requirement with national energy-saving environmental protection mutually agrees with.

Description

The alloy round aluminum rod and its production method of intensity in a kind of low resistance
Technical field
The present invention relates to a kind of a kind of alloy round aluminum rod of intensity in alloy round aluminum rod, especially low resistance, it is further related to Production method, belongs to aluminum alloy wire technical field of cable.
Background technology
The novel energy-conserving wire that current China promotes mainly includes high conductivity energy-conservation hard aluminum wire, and aluminium alloy core, aluminium is twisted Line, middle this three class of intensity all aluminium alloy twisted wire.High conductivity energy-conservation hard aluminum wire and aluminum stranded wire of aluminum alloy core are identical with aluminium section Common steel-cored aluminium strand compare, the raising of aluminum steel conductance can make wire entirety DC resistance reduction, and electric energy loss subtracts It is few, but its tensile strength is relatively low, and cable sag is larger.Strength aluminium alloy material in middle intensity all aluminium alloy twisted wire whole use, Compared with common steel-cored aluminium strand of total cross section is waited, because aluminum alloy materials substitute steel core, equivalent to conductive section is increased, drop Low overall DC resistance, improves conductive capability, lightweight because its intensity is high, and has the advantages that preferable electric conductivity, It is widely used in west economy more developed country.
With the fast development of China's power industry, many with reference to western with a varied topography, large crossing projects, ordinary steel is compared in exploitation The substituting product that core aluminum stranded wire intensity is high, current-carrying capacity is big, there is extensive promotional value.
The content of the invention
In order to realize above-mentioned target, the element such as present invention analysis silicon, iron, copper, boron, rare earth is to aluminium conductor electric conductivity, anti- The influence of tensile strength, rational proportion is carried out to each element, preferably improves the cast sturcture of aluminium alloy, makes the conduction of aluminium bar Property, tensile strength reach best of breed state, it is further provided in a kind of low resistance strength alloys circle aluminium bar, concrete scheme is such as Under:
A kind of alloy round aluminum rod of intensity in low resistance, described alloy round aluminum rod includes Si, Fe, Cu, Zn, B, Ti and RE, The various composition is by weight:Si:0.03-0.10%、Fe:0.20-0.70%、Cu:0.10-0.28%、Zn:0.015- 0.06%、B:0.005-0.020%、Ti:0.001-0.02%、RE:0.05-0.2%, balance of AL and inevitable impurity.
Ferro element adds the intensity that can improve alloy, while the influence to resistivity is smaller;Copper is added and can formed CuAl2, plays solution strengthening effect and improves the intensity of alloy, but can rise high resistivity simultaneously;The addition of boron element can remove aluminium liquid In vanadium, reduce influence of the v element to resistivity;This aluminium alloy rod is that continuous casting and rolling is formed, if casting blank crystal grains are excessive, rolling During the distortion of lattice that occurs it is serious, improve the resistivity of product, and the addition of titanium elements can obvious crystal grain thinning, so as to drop Low-resistivity;The addition of rare earth element contributes to the reduction of hydrogen in aluminium liquid, product resistivity is reduced, by the conjunction of alloying element Reason allotment and the control of impurity element, while being improved this aluminium alloy rod tensile strength, resistivity only has on slightly Rise.
The alloy round aluminum rod production method of intensity in a kind of low resistance of the present invention, including smelting technology, teemer Skill and rolling mill practice, wherein smelting technology step are as follows:
(1), add in smelting furnace more than 99.50% aluminium liquid, temperature of aluminum liquid controlled at 780-800 DEG C;
(2), first with 75% copper agent add aluminum melt formed CuAl2 hardening constituents, secondly add 75% chalybeate, be subsequently adding aluminium boron Harmful element vanadium in alloy removal aluminium liquid, is eventually adding rare earth alloy, recycles 30-40 minutes electromagnetic agitation time;It is determined that Each element content meets the requirements in chemical composition;
(3), after the aluminium solution for preparing, powder refining agent is blown into refining treatment in melt with nitrogen, refining agent consumption is 0.6-0.8kg/t, is passed through nitrogen pressure for 0.1-0.2MPa, time 20-30 minutes, 730-760 DEG C of refining temperature, so as to obtain Obtain clarity aluminium solution higher;Refining agent is by KCl, NaCl, ice crystal, the ground flux that constitutes;
(4) the aluminium solution that, composition is qualified, temperature is qualified is stood, time of repose 25-35 minutes.
Further, the cast temperature of the casting process is 700-710 DEG C, casting machine cooling water pressure 0.2-0.25MPa, 25-35 DEG C of temperature, casting rate 4-5 ton hours, aluminium titanium boron wire is added with 1.0 ms/min of speed online(AlTi5B)Refinement Crystal grain, obtains equiax crystal strand.
Further, the emulsion pressure 0.15-0.25MPa of rolling mill practice, 50-60 DEG C of temperature;Quenching coolant-temperature gage 20-25 DEG C, pressure 0.4-0.6MPa, by above rolling mill practice by 4 two-roller mills, 10 y-type rolling mills are rolled into diameter 9.5mm, and Recrystallized structure and the uniform aluminium alloy rod of CuAl2 hardening constituents.
Advantages of the present invention is as follows:
The present invention solves traditional high conductivity energy-conservation hard aluminum wire and aluminum stranded wire of aluminum alloy core deficiency in actual applications, Cable tensile strength is increased substantially, its tensile strength has been reached 6101,6201 alloy designations standards, and resistance is gone up by a small margin Rise, only 6101, the 82% of 6201 alloy designations.It has current-carrying capacity big, and pulling force is big, pulling force substance than it is big the advantages of, can increase Span, reduces shaft tower number, or reduces shaft tower highly, reduces construction costs, moreover it is possible to preferably improve cast sturcture, make tension Intensity is less than 29.00n Ω m, largely reduces cable installation cost up to more than 170MPa, resistivity.
Using this aluminium alloy cable, compared with steel wire aluminum stranded conductor, the cable of same cross-sectional area, current-carrying capacity is greatly improved, The sag increase of cable is not obvious, can be widely applied to large span erecting cable, and the requirement with national energy-saving environmental protection mutually agrees with.
Specific embodiment
The technical scheme in the present embodiment is clearly and completely described below, it is clear that described embodiment is only It is to a part of example of the invention, rather than whole examples.Based on the embodiment in the present invention, those of ordinary skill in the art The every other embodiment obtained under the premise of creative work is not paid, belongs to the scope of protection of the invention.
Embodiment 1
Strength alloys circle aluminium bar includes Si, Fe, Cu, Zn, B, Ti and RE in the low resistance of the present embodiment, described various Composition is by weight ratio(%)It is as follows:Si:0.04、Fe:0.41、Cu:0.21、Zn:0.05、B:0.015、Ti:0.011 and RE: 0.06, balance of AL and inevitable impurity.
The alloy round aluminum rod production method of intensity in the low resistance of the present embodiment, including smelting technology, casting process and roll Technique processed, wherein smelting technology step is as follows:
(1), add in smelting furnace more than 99.55% aluminium liquid, temperature of aluminum liquid controlled at 786 DEG C;
(2), first with 75% copper agent add aluminum melt formed CuAl2 hardening constituents, secondly add 75% chalybeate, be subsequently adding aluminium boron Harmful element vanadium in alloy removal aluminium liquid, is eventually adding rare earth alloy, recycles 33 minutes electromagnetic agitation time;It is determined that chemical Each element content meets the requirements in composition;
(3), after the aluminium solution for preparing, powder refining agent is blown into refining treatment in melt with nitrogen, refining agent consumption is 0.62g/t, is passed through nitrogen pressure for 0.15MPa, 24 minutes time, 742 DEG C of refining temperature, so as to obtain clarity aluminium higher Solution;Refining agent is the ground flux being made up of KCl, NaCl, ice crystal;
(4), the aluminium solution that composition is qualified, temperature is qualified stood, time of repose 32 minutes.
The cast temperature of the casting process is 700-707 DEG C, casting machine cooling water pressure 0.2-0.25MPa, temperature 25-27 DEG C, the ton hour of casting rate 4.4 adds aluminium titanium boron wire online with 1.0 ms/min of speed(AlTi5B)Crystal grain thinning, obtains Equiax crystal strand.
The emulsion pressure 0.19MPa of rolling mill practice, 50-58 DEG C of temperature;Quenching 24 DEG C of coolant-temperature gage, pressure 0.48MPa, by with By 4 two-roller mills, 10 y-type rolling mills are rolled into diameter 9.5mm, and recrystallized structure and CuAl2 reinforcings to upper rolling mill practice The uniform aluminium alloy rod of phase.
Embodiment 2
Strength alloys circle aluminium bar includes Si, Fe, Cu, Zn, B, Ti and RE in the low resistance of the present embodiment, described various Composition is by weight ratio(%)It is as follows:Si:0.05、Fe:0.28、Cu:0.27、Zn:0.04、B:0.022、Ti:0.007 and RE: 0.08, balance of AL and inevitable impurity.
The alloy round aluminum rod production method of intensity in the low resistance of the present embodiment, including smelting technology, casting process and roll Technique processed, wherein smelting technology step is as follows:
(1), add in smelting furnace more than 99.57% aluminium liquid, temperature of aluminum liquid controlled at 791 DEG C;
(2), first with 75% copper agent add aluminum melt formed CuAl2 hardening constituents, secondly add 75% chalybeate, be subsequently adding aluminium boron Harmful element vanadium in alloy removal aluminium liquid, is eventually adding rare earth alloy, recycles 36 minutes electromagnetic agitation time;It is determined that chemical Each element content meets the requirements in composition;
(3), after the aluminium solution for preparing, powder refining agent is blown into refining treatment in melt with nitrogen, refining agent consumption is 0.64g/t, is passed through nitrogen pressure for 0.15MPa, 27 minutes time, 749 DEG C of refining temperature, so as to obtain clarity aluminium higher Solution;Refining agent is the ground flux being made up of KCl, NaCl, ice crystal;
(4), the aluminium solution that composition is qualified, temperature is qualified stood, time of repose 35 minutes.
The cast temperature of the casting process is 700-707 DEG C, casting machine cooling water pressure 0.2-0.25MPa, temperature 26-27 DEG C, the ton hour of casting rate 4.7 adds aluminium titanium boron wire online with 1.0 ms/min of speed(AlTi5B)Crystal grain thinning, obtains Equiax crystal strand.
The emulsion pressure 0.19MPa of rolling mill practice, 53-57 DEG C of temperature;Quenching 23 DEG C of coolant-temperature gage, pressure 0.46MPa, by with By 4 two-roller mills, 10 y-type rolling mills are rolled into diameter 9.5mm, and recrystallized structure and CuAl2 reinforcings to upper rolling mill practice The uniform aluminium alloy rod of phase.
The physical property of strength alloys bar is as follows in the low resistance of production:
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all it is of the invention spirit and Within principle, any modification, equivalent substitution and improvements made etc. should be included within the scope of the present invention.

Claims (4)

1. in a kind of low resistance intensity alloy round aluminum rod, it is characterised in that:Described alloy round aluminum rod include Si, Fe, Cu, Zn, B, Ti and RE, the various composition is by weight:
Si:0.03-0.10%、
Fe:0.20-0.70%、
Cu:0.10-0.28%、
Zn:0.015-0.06%、
B:0.005-0.020%、
Ti:0.001-0.02%、
RE:0.05-0.2%, balance of AL and inevitable impurity.
2. in a kind of low resistance intensity alloy round aluminum rod production method, it is characterised in that:Including melting, casting and rolling, its The step of middle melting, is as follows:
(1), add in smelting furnace more than 99.50% aluminium liquid, temperature of aluminum liquid controlled at 780-800 DEG C;
(2), first with 75% copper agent add aluminum melt formed CuAl2 hardening constituents, secondly add 75% chalybeate, be subsequently adding aluminium boron Alloy, is eventually adding rare earth alloy, recycles 30-40 minutes electromagnetic agitation time;It is chemically defined middle each element content symbol Close and require;
(3), after the aluminium solution for preparing, powder refining agent is blown into refining treatment in melt with nitrogen, refining agent consumption is 0.6-0.8 ㎏/t, are passed through nitrogen pressure for 0.1-0.2MPa, time 20-30 minutes, 730-760 DEG C of refining temperature;Refining agent It is by KCl, NaCl, ice crystal, the ground flux that constitutes;
(4), the aluminium solution that composition is qualified, temperature is qualified stood, time of repose 25-35 minutes.
3. in a kind of low resistance according to claim 2 intensity alloy round aluminum rod production method, it is characterised in that:It is described The cast temperature of casting is 700-710 DEG C, casting machine cooling water pressure 0.2-0.25MPa, 25-35 DEG C of temperature, casting rate 4-5 Ton hour, aluminium titanium boron wire crystal grain thinning is added with 1.0 ms/min of speed online, obtains equiax crystal strand.
4. in a kind of low resistance according to claim 2 intensity alloy round aluminum rod production method, it is characterised in that:Rolling Emulsion pressure 0.15-0.25MPa, 50-60 DEG C of temperature;20-25 DEG C of coolant-temperature gage of quenching, pressure 0.4-0.6Mpa rolls more than Technique processed is rolled into recrystallized structure and the uniform aluminium alloy rod of CuAl2 hardening constituents by 4 two-roller mills, 10 y-type rolling mills.
CN201710214340.8A 2017-04-01 2017-04-01 The alloy round aluminum rod and its production method of intensity in a kind of low resistance Active CN106929712B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109402457A (en) * 2018-12-11 2019-03-01 新疆众和股份有限公司 A kind of aluminium alloy rod and preparation method thereof for copper clad aluminum material
CN110629076A (en) * 2019-09-12 2019-12-31 中国科学院金属研究所 High-conductivity aluminum alloy rod material and preparation method thereof
CN110706841A (en) * 2019-10-31 2020-01-17 武汉电缆有限公司 High-strength high-conductivity aluminum alloy wire for electrician and manufacturing method thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101956103B (en) * 2010-10-20 2012-10-03 云南铝业股份有限公司 High strength alloy round aluminium rod and production method thereof
CN102994816B (en) * 2012-12-04 2014-01-08 安徽太平洋电缆股份有限公司 High-strength aluminium alloy wire material and preparation method for same
CN105296810B (en) * 2015-10-15 2017-06-27 远东电缆有限公司 A kind of high-strength aluminum alloy bar continuous casting and tandem rolling production technology
CN106435286A (en) * 2016-10-17 2017-02-22 山东创辉新材料科技有限公司 Manufacturing method for extrusion electrician round aluminum rod

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109402457A (en) * 2018-12-11 2019-03-01 新疆众和股份有限公司 A kind of aluminium alloy rod and preparation method thereof for copper clad aluminum material
CN110629076A (en) * 2019-09-12 2019-12-31 中国科学院金属研究所 High-conductivity aluminum alloy rod material and preparation method thereof
CN110629076B (en) * 2019-09-12 2021-05-18 中国科学院金属研究所 High-conductivity aluminum alloy rod material and preparation method thereof
CN110706841A (en) * 2019-10-31 2020-01-17 武汉电缆有限公司 High-strength high-conductivity aluminum alloy wire for electrician and manufacturing method thereof

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