CN106926370A - A kind of cutting and grinding material diamond disc - Google Patents

A kind of cutting and grinding material diamond disc Download PDF

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Publication number
CN106926370A
CN106926370A CN201710045843.7A CN201710045843A CN106926370A CN 106926370 A CN106926370 A CN 106926370A CN 201710045843 A CN201710045843 A CN 201710045843A CN 106926370 A CN106926370 A CN 106926370A
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China
Prior art keywords
powder
cutter head
diamond
carcass
abrasive material
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CN201710045843.7A
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CN106926370B (en
Inventor
刘英凯
谷夕良
侯俊彦
王成军
苏士伟
李顺卿
赵振艳
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Boshen Co ltd
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Bosun Tools Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28DWORKING STONE OR STONE-LIKE MATERIALS
    • B28D1/00Working stone or stone-like materials, e.g. brick, concrete or glass, not provided for elsewhere; Machines, devices, tools therefor
    • B28D1/02Working stone or stone-like materials, e.g. brick, concrete or glass, not provided for elsewhere; Machines, devices, tools therefor by sawing
    • B28D1/12Saw-blades or saw-discs specially adapted for working stone
    • B28D1/121Circular saw blades
    • B22F1/0003
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C29/00Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/02Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
    • C22C29/06Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
    • C22C29/067Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds comprising a particular metallic binder
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C29/00Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/02Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
    • C22C29/06Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
    • C22C29/08Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on tungsten carbide
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0047Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents
    • C22C32/0052Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents only carbides

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mining & Mineral Resources (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
  • Powder Metallurgy (AREA)

Abstract

The invention discloses a kind of diamond disc, especially a kind of cutting and grinding material diamond disc, belongs to powdered metallurgical material technical field.The cutter head of the diamond disc is made after being mixed with diamond by cutter head carcass;Surface coating is added in cutter head carcass the high-abrasive material of metal cobalt powder, and the high-abrasive material is WC, W, W2One or several in C.WC, W, W are added in the present invention2The high-abrasive materials such as C are used as wear-resisting phase.The present invention is using Co powder and WC, W, W2The framework materials such as C and it is excellent with other cutter head carcass material compatibilities such as Cu, Fe the characteristics of, by the use of Co powder as middle transition binder course, carcass can be increased to W, WC, W2The hold of the high-abrasive materials such as C, high-abrasive material is difficult for drop-off in the process of use, and giving full play to wear-resisting phase can strengthen the effect of saw life.

Description

A kind of cutting and grinding material diamond disc
Technical field
The present invention relates to a kind of diamond disc, especially a kind of cutting and grinding material diamond disc, category In powdered metallurgical material technical field.
Background technology
In existing diamond tool, W, WC, W are added sometimes2The high-abrasive materials such as C are used to carry as framework material The hardness and wearability of saw blade tip high, so as to improve the service life of saw blade.But due to W, WC, W2C has high-melting-point, height The characteristic of hardness, poor with carcass metal wellability, it is difficult to sinter, this results in carcass to holds such as W, the WC as wear-resisting phase Not enough, it is wear-resisting compatible easy to fall off in use, substantially reduce the life-span of saw blade.Simultaneously in traditional diamond disc The addition of the wear-resisting phase such as middle WC, W is difficult more than 60%, because with the increase of the additions such as W, WC, the compactness of cutter head sintering Decline, cutter head density reduction, the hard fragility of cutter head increases, and intensity declines, easily occur the tight of cutter tooth fracture in cutting process Weight consequence.Therefore, W, WC, W are added in diamond cutter2The high-abrasive materials such as C are restricted, it is impossible to largely use, cause gold The anti-wear performance of diamond saw blade is not high.
The content of the invention
The technical problem to be solved in the invention provide a kind of cutter head hardness and wearability it is good, being capable of cutting and grinding material The diamond disc of material.
In order to solve the above technical problems, the technical solution adopted in the present invention is:
A kind of cutting and grinding material diamond disc, the cutter head of diamond disc is mixed by cutter head carcass with diamond After be made;Surface coating is added in cutter head carcass the high-abrasive material of metal cobalt powder, and the high-abrasive material is WC, W, W2In C One or several.
Further, the weight that Surface coating has the high-abrasive material of metal cobalt powder account for cutter head carcass percentage by weight for 5%~ 80%, remaining is the mixture of Cu powder, Fe powder and Sn powder.
Further, it is 20% that the weight that Surface coating has the high-abrasive material of metal cobalt powder accounts for cutter head carcass percentage by weight ~70%, remaining is the mixture of Cu powder, Fe powder and Sn powder.
Further, high-abrasive material is WC and W2The mixture of C.
Further, high-abrasive material is the mixture of WC and W.
Further, high-abrasive material is W and W2The mixture of C.
Further, high-abrasive material is W, W2The mixture of C and WC.
By adopting the above-described technical solution, the present invention achieves following beneficial effect:
The present invention is using Co powder and WC, W, W2The wear-resisting phase material such as C and excellent with the cutter head carcass material compatibility such as Cu, Fe The characteristics of, by the use of Co powder as middle transition binder course, carcass can be increased to W, WC, W2The hold of the wear-resisting phase such as C, it is wear-resisting Difficult for drop-off in the process of use, giving full play to wear-resisting phase can strengthen the effect of saw life.
The present invention overcomes WC, W, W in diamond disc by adding Co powder2The addition of the wear-resisting phase such as C is difficult Problem more than 60%, Co claddings WC, W, W2The use of C powder can improve wear-resisting with carcass interface affinity, promote to burn Knot, improves the toughness and bending strength of cutter head, increases the addition of wear-resisting phase and then the service life of raising saw blade.
The present invention can add WC, W, W of any content by adding Co powder according to the demand of wearability2The wear-resisting phase such as C, Corresponding diamond saw blade can be according to demand made, diamond disc has been given full play on the premise of use is not influenceed Cutting performance.
Specific embodiment
The present invention is described in further details with reference to specific embodiment:
The invention discloses a kind of cutting and grinding material diamond disc, the diamond disc is mainly used in cutting tool There is the abrasiveness material of higher hardness and toughness.There is the wear-resisting material of metal cobalt powder in diamond circular saw blade cutter head addition Surface coating Material, the high-abrasive material is WC, W, W2One or several in C.
The preparation method of the diamond disc, comprises the following steps:
(1)WC, W, W for being coated with Co powder that cutter head carcass percetage by weight is 5%~80% will be accounted for2One or more of C powder Remaining cutter head carcass raw material is mixed to form cutter head carcass with Cu powder, Fe powder, Sn powder etc.;
(2)By step(1)In cutter head carcass weighed according to a certain ratio with diamond and mix, be put into three-dimensional material mixer, fully Mixture is uniform;Wherein cutter head carcass and the mass ratio of diamond is 1:0.02~0.05;
(3)The powder that will be mixed is put into graphite jig, the pressure sintering in hot-pressed sintering furnace, sintering temperature be 800 DEG C~ 1200 DEG C, sintering obtains diamond segment;
(4)The diamond segment that sintering is obtained is welded, smoothed, put the first edge on a knife or a pair of scissors, obtained diamond disc.
Embodiment 1
From WC as high-abrasive material in the present embodiment, WC is coated using Co powder.Specific preparation process is as follows:
(1)Remaining cutter head tire such as WC and the Cu powder for being coated with Co powder, Fe powder, Sn powder that cutter head carcass percetage by weight is 5% will be accounted for Body raw material is mixed to form cutter head carcass;
(2)By step(1)In cutter head carcass weighed according to a certain ratio with diamond and mix, be put into three-dimensional material mixer, fully Mixture is uniform;Wherein cutter head carcass and the mass ratio of diamond is 1:0.05;
(3)The powder that will be mixed is put into graphite jig, the pressure sintering in hot-pressed sintering furnace, and sintering temperature is 800 DEG C, sintering Obtain diamond segment;
(4)The diamond segment that sintering is obtained is welded, smoothed, put the first edge on a knife or a pair of scissors, obtained diamond disc.
Embodiment 2
From W as high-abrasive material in the present embodiment, W is coated using Co powder.Specific preparation process is as follows:
(1)Remaining cutter head tire such as W and the Cu powder for being coated with Co powder, Fe powder, Sn powder that cutter head carcass percetage by weight is 50% will be accounted for Body raw material is mixed to form cutter head carcass;
(2)By step(1)In cutter head carcass weighed according to a certain ratio with diamond and mix, be put into three-dimensional material mixer, fully Mixture is uniform;Wherein cutter head carcass and the mass ratio of diamond is 1:0.04;
(3)The powder that will be mixed is put into graphite jig, the pressure sintering in hot-pressed sintering furnace, and sintering temperature is 800 DEG C, sintering Obtain diamond segment;
(4)The diamond segment that sintering is obtained is welded, smoothed, put the first edge on a knife or a pair of scissors, obtained diamond disc.
Embodiment 3
W is selected in the present embodiment2C is used as high-abrasive material, W2C is coated using Co powder.Specific preparation process is as follows:
(1)The W for being coated with Co powder that cutter head carcass percetage by weight is 30% will be accounted for2Remaining cutter head such as C and Cu powder, Fe powder, Sn powder Carcass raw material is mixed to form cutter head carcass;
(2)By step(1)In cutter head carcass weighed according to a certain ratio with diamond and mix, be put into three-dimensional material mixer, fully Mixture is uniform;Wherein cutter head carcass and the mass ratio of diamond is 1:0.04;
(3)The powder that will be mixed is put into graphite jig, the pressure sintering in hot-pressed sintering furnace, and sintering temperature is 800 DEG C, sintering Obtain diamond segment;
(4)The diamond segment that sintering is obtained is welded, smoothed, put the first edge on a knife or a pair of scissors, obtained diamond disc.
Embodiment 4
W is selected in the present embodiment2C is used as high-abrasive material, W2C is coated using Co powder.Specific preparation process is as follows:
(1)The W for being coated with Co powder that cutter head carcass percetage by weight is 70% will be accounted for2Remaining cutter head such as C and Cu powder, Fe powder, Sn powder Carcass raw material is mixed to form cutter head carcass;
(2)By step(1)In cutter head carcass weighed according to a certain ratio with diamond and mix, be put into three-dimensional material mixer, fully Mixture is uniform;Wherein cutter head carcass and the mass ratio of diamond is 1:0.03;
(3)The powder that will be mixed is put into graphite jig, the pressure sintering in hot-pressed sintering furnace, and sintering temperature is 800 DEG C, sintering Obtain diamond segment;
(4)The diamond segment that sintering is obtained is welded, smoothed, put the first edge on a knife or a pair of scissors, obtained diamond disc.
Embodiment 5
From WC as high-abrasive material in the present embodiment, WC is coated using Co powder.Specific preparation process is as follows:
(1)Remaining cutter head such as WC and the Cu powder for being coated with Co powder, Fe powder, Sn powder that cutter head carcass percetage by weight is 80% will be accounted for Carcass raw material is mixed to form cutter head carcass;
(2)By step(1)In cutter head carcass weighed according to a certain ratio with diamond and mix, be put into three-dimensional material mixer, fully Mixture is uniform;Wherein cutter head carcass and the mass ratio of diamond is 1:0.03;
(3)The powder that will be mixed is put into graphite jig, the pressure sintering in hot-pressed sintering furnace, and sintering temperature is 800 DEG C, sintering Obtain diamond segment;
(4)The diamond segment that sintering is obtained is welded, smoothed, put the first edge on a knife or a pair of scissors, obtained diamond disc.
Embodiment 6
From W as high-abrasive material in the present embodiment, W is coated using Co powder.Specific preparation process is as follows:
(1)Remaining cutter head tire such as W and the Cu powder for being coated with Co powder, Fe powder, Sn powder that cutter head carcass percetage by weight is 80% will be accounted for Body raw material is mixed to form cutter head carcass;
(2)By step(1)In cutter head carcass weighed according to a certain ratio with diamond and mix, be put into three-dimensional material mixer, fully Mixture is uniform;Wherein cutter head carcass and the mass ratio of diamond is 1:0.04;
(3)The powder that will be mixed is put into graphite jig, the pressure sintering in hot-pressed sintering furnace, and sintering temperature is 800 DEG C, sintering Obtain diamond segment;
(4)The diamond segment that sintering is obtained is welded, smoothed, put the first edge on a knife or a pair of scissors, obtained diamond disc.
Embodiment 7
From WC and W as high-abrasive material in the present embodiment, WC and W is coated using Co powder.Specific preparation process is as follows:
(1)Remaining knife such as the W and WC that are coated with Co powder and Cu powder, Fe powder, Sn powder that cutter head carcass percetage by weight is 60% will be accounted for The first-born body raw material is mixed to form cutter head carcass;
(2)By step(1)In cutter head carcass weighed according to a certain ratio with diamond and mix, be put into three-dimensional material mixer, fully Mixture is uniform;Wherein cutter head carcass and the mass ratio of diamond is 1:0.02;
(3)The powder that will be mixed is put into graphite jig, the pressure sintering in hot-pressed sintering furnace, and sintering temperature is 800 DEG C, sintering Obtain diamond segment;
(4)The diamond segment that sintering is obtained is welded, smoothed, put the first edge on a knife or a pair of scissors, obtained diamond disc.Embodiment 8
W is selected in the present embodiment2C and W is used as high-abrasive material, W2C and W is coated using Co powder.Specific preparation process is as follows:
(1)The W and W that are coated with Co powder that cutter head carcass percetage by weight is 40% will be accounted for2C and Cu powder, Fe powder, Sn powder etc. remaining Cutter head carcass raw material is mixed to form cutter head carcass;
(2)By step(1)In cutter head carcass weighed according to a certain ratio with diamond and mix, be put into three-dimensional material mixer, fully Mixture is uniform;Wherein cutter head carcass and the mass ratio of diamond is 1:0.04;
(3)The powder that will be mixed is put into graphite jig, the pressure sintering in hot-pressed sintering furnace, and sintering temperature is 800 DEG C, sintering Obtain diamond segment;
(4)The diamond segment that sintering is obtained is welded, smoothed, put the first edge on a knife or a pair of scissors, obtained diamond disc.
Embodiment 9
W is selected in the present embodiment2C and WC is used as high-abrasive material, W2C and WC is coated using Co powder.Specific preparation process is as follows:
(1)The WC and W that are coated with Co powder that cutter head carcass percetage by weight is 20% will be accounted for2C and Cu powder, Fe powder, Sn powder etc. remaining Cutter head carcass raw material is mixed to form cutter head carcass;
(2)By step(1)In cutter head carcass weighed according to a certain ratio with diamond and mix, be put into three-dimensional material mixer, fully Mixture is uniform;Wherein cutter head carcass and the mass ratio of diamond is 1:0.05;
(3)The powder that will be mixed is put into graphite jig, the pressure sintering in hot-pressed sintering furnace, and sintering temperature is 800 DEG C, sintering Obtain diamond segment;
(4)The diamond segment that sintering is obtained is welded, smoothed, put the first edge on a knife or a pair of scissors, obtained diamond disc.
Embodiment 10
W is selected in the present embodiment2C, WC and W are used as high-abrasive material, W2C, WC and W are coated using Co powder.Specific preparation process is such as Under:
(1)W, WC and W for being coated with Co powder that cutter head carcass percetage by weight is 50% will be accounted for2Remaining knife such as C and Cu powder, Fe powder The first-born body raw material is mixed to form cutter head carcass;
(2)By step(1)In cutter head carcass weighed according to a certain ratio with diamond and mix, be put into three-dimensional material mixer, fully Mixture is uniform;Wherein cutter head carcass and the mass ratio of diamond is 1:0.04;
(3)The powder that will be mixed is put into graphite jig, the pressure sintering in hot-pressed sintering furnace, and sintering temperature is 800 DEG C, sintering Obtain diamond segment;
(4)The diamond segment that sintering is obtained is welded, smoothed, put the first edge on a knife or a pair of scissors, obtained diamond disc.
Cutter head carcass is by having coated the high-abrasive material of Co powder and the mixture of Fe powder, Cu powder and Sn powder in the various embodiments described above Composition, the mass ratio of Cu powder, Fe powder and Sn powder threes is Cu:Fe:Sn=1:(0.8~1):0.1.
Constituent element based on Fe, Cu in Diamond Tool Matrix, also including low melting material Sn and framework material, W、WC、W2C。
Co powder is mixed using coating technology with high-abrasive material in the various embodiments described above, will Co powder, high-abrasive material lead to Mechanical agitation mixing is crossed, cladding powder is made, Co powder is coated on the surface of high-abrasive material, so as to give full play to Co powder increase knife The first-born body is to W, WC, W2The effect of the wear-resisting phase hold such as C.
WC, W, W are added in the present invention2The high-abrasive materials such as C are used as wear-resisting phase.WC、W、W2The effect of C three is identical, if choosing When being two of which high-abrasive material, then two kinds of ratios of high-abrasive material can be arbitrary value.If what is selected is wherein three When planting high-abrasive material, then three kinds of ratios of high-abrasive material can be arbitrary value.
The present invention overcomes WC, W, W in diamond disc by adding Co powder2C etc. as wear-resisting phase wear-resisting material The addition of material is difficult the problem more than 60%, in the present invention WC, W, W2The addition maximum of C can reach and account for cutter head carcass matter Amount 80%, expand significantly diamond disc for varying strength abrasiveness material cutting when adaptability.
Co claddings WC, W, W in the present invention2The use of C powder can improve wear-resisting with carcass interface affinity, promote to burn Knot, improves the toughness and bending strength of cutter head, increases the addition of wear-resisting phase and then the service life of raising saw blade.WC、W、W2C Deng high-abrasive material as the wear-resisting anti-wear performance for being added in diamond segment and can improving diamond segment, extend diamond The service life of saw blade.
The present invention is using Co powder and WC, W, W2The high-abrasive materials such as C and with other cutter head carcass material compatibilities such as Cu, Fe Excellent the characteristics of, by the use of Co powder as middle transition binder course, carcass can be increased to W, WC, W2The holding of the wear-resisting phase such as C Power, wear-resisting difficult for drop-off in the process of use, giving full play to wear-resisting phase can strengthen the effect of saw life.After adding Co powder, The sintering process of diamond segment is more prone to.Meanwhile, Co powder accounts for the addition of high-abrasive material as middle transition binder course Cutter head carcass mass fraction is arbitrary value, and the weight of high-abrasive material accounts for cutter head carcass weight hundred in 1~embodiment of embodiment 10 Divide than being 5%~80%, the weight that can as needed adjust high-abrasive material accounts for cutter head carcass percentage by weight to make with not With the diamond disc of anti-wear performance, so as to cut the abrasiveness material of different hardness.
The invention provides cost performance it is high, performance is excellent, suitable for the diamond circular saw of cutting and grinding material Piece.

Claims (7)

1. a kind of cutting and grinding material diamond disc, it is characterised in that:The cutter head of diamond disc is by cutter head tire Body is made after mixing with diamond;Surface coating is added in cutter head carcass the high-abrasive material of metal cobalt powder, the high-abrasive material It is WC, W, W2One or several in C.
2. a kind of cutting and grinding material diamond disc according to claim 1, it is characterised in that:Surface coating It is 5%~80% that the weight for having the high-abrasive material of metal cobalt powder accounts for cutter head carcass percentage by weight, and remaining is Cu powder, Fe powder and Sn powder Mixture.
3. a kind of cutting and grinding material diamond disc according to claim 1, it is characterised in that:Surface coating It is 20%~70% that the weight for having the high-abrasive material of metal cobalt powder accounts for cutter head carcass percentage by weight, and remaining is Cu powder, Fe powder and Sn The mixture of powder.
4. a kind of cutting and grinding material diamond disc according to any one of Claims 2 or 3, its feature exists In:High-abrasive material is WC and W2The mixture of C.
5. a kind of cutting and grinding material diamond disc according to any one of Claims 2 or 3, its feature exists In:High-abrasive material is the mixture of WC and W.
6. a kind of cutting and grinding material diamond disc according to any one of Claims 2 or 3, its feature exists In:High-abrasive material is W and W2The mixture of C.
7. a kind of cutting and grinding material diamond disc according to any one of Claims 2 or 3, its feature exists In:High-abrasive material is W, W2The mixture of C and WC.
CN201710045843.7A 2017-01-22 2017-01-22 A kind of cutting and grinding material diamond disc Active CN106926370B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113368782A (en) * 2021-06-18 2021-09-10 邵阳市东昇超硬材料有限公司 Processing method for synthesizing diamond by adopting high-temperature high-pressure method

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Publication number Priority date Publication date Assignee Title
CN1657257A (en) * 2004-02-17 2005-08-24 河南黄河旋风股份有限公司 Diamond saw bit and its manufacturing method
CN101314849A (en) * 2007-05-29 2008-12-03 湖北昌利超硬材料有限公司 Rare earth iron-rich diamond saw blade bonding agent
CN104072138A (en) * 2014-06-18 2014-10-01 河海大学 Tungsten carbide-cubic boron nitride composite material and preparation method thereof
CN105463291A (en) * 2015-12-09 2016-04-06 博深工具股份有限公司 Fully-prealloyed powder and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1657257A (en) * 2004-02-17 2005-08-24 河南黄河旋风股份有限公司 Diamond saw bit and its manufacturing method
CN101314849A (en) * 2007-05-29 2008-12-03 湖北昌利超硬材料有限公司 Rare earth iron-rich diamond saw blade bonding agent
CN104072138A (en) * 2014-06-18 2014-10-01 河海大学 Tungsten carbide-cubic boron nitride composite material and preparation method thereof
CN105463291A (en) * 2015-12-09 2016-04-06 博深工具股份有限公司 Fully-prealloyed powder and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113368782A (en) * 2021-06-18 2021-09-10 邵阳市东昇超硬材料有限公司 Processing method for synthesizing diamond by adopting high-temperature high-pressure method

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