CN106916951A - A kind of molybdenum-iron silicothermic process smelting process - Google Patents
A kind of molybdenum-iron silicothermic process smelting process Download PDFInfo
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- CN106916951A CN106916951A CN201510979224.6A CN201510979224A CN106916951A CN 106916951 A CN106916951 A CN 106916951A CN 201510979224 A CN201510979224 A CN 201510979224A CN 106916951 A CN106916951 A CN 106916951A
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- Prior art keywords
- molybdenum
- iron
- parts
- silicothermic
- smelting process
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B5/00—General methods of reducing to metals
- C22B5/02—Dry methods smelting of sulfides or formation of mattes
- C22B5/04—Dry methods smelting of sulfides or formation of mattes by aluminium, other metals or silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C27/00—Alloys based on rhenium or a refractory metal not mentioned in groups C22C14/00 or C22C16/00
- C22C27/04—Alloys based on tungsten or molybdenum
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
The invention discloses a kind of molybdenum-iron silicothermic process smelting process, the method is comprised the following steps:A, the molybdenum ore sand of 150-200 parts according to the mass fraction, 50-70 parts of ferrosilicon powder, 40-60 parts of brown iron oxide, 8-12 parts of lime, 4-8 parts of aluminum shot are well mixed;B, well mixed material is put into reacting furnace carries out autothermal reaction;C, will reacted product cool down after carry out molybdenum-iron and slag and separate to can obtain molybdenum-iron finished product.A kind of molybdenum-iron silicothermic process smelting process of the present invention, by with fluorite in the traditional molybdenum-iron silicothermic process smelting process of lime substitution, the generation of fluorine class pollutant effectively can be thoroughly avoided, while effectively reducing cost of material and improve product quality, the method environmental protection and economy, progressive meaning is notable.
Description
Technical field
The present invention relates to a kind of molybdenum-iron production method, more particularly to a kind of molybdenum-iron silicothermic process smelting process.
Background technology
Silicothermic process smelting process is now widely used molybdenum-iron preparation technology, due to generally needing to be used as additive using fluorite in technique, therefore easily cause fluorine contaminant generation and severe contamination destruction natural environment, hardly consistent with current environmental requirement.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of molybdenum-iron silicothermic process smelting process for being prevented effectively from fluoride pollution.
In order to solve the above-mentioned technical problem, the present invention is adopted the following technical scheme that:
A kind of molybdenum-iron silicothermic process smelting process, comprises the following steps:A, the molybdenum ore sand of 150-200 parts according to the mass fraction, 50-70 parts of ferrosilicon powder, 40-60 parts of brown iron oxide, 8-12 parts of lime, 4-8 parts of aluminum shot are well mixed;B, well mixed material is put into reacting furnace carries out autothermal reaction;C, will reacted product cool down after carry out molybdenum-iron and slag and separate to can obtain molybdenum-iron finished product.
Preferably, the granularity of the molybdenum ore sand is 1-2 millimeters.
Preferably, the content of calcium oxide is more than 90% in the lime.
Compared with prior art, a kind of molybdenum-iron silicothermic process smelting process of the present invention, replace fluorite in traditional molybdenum-iron silicothermic process smelting process by with lime, effectively can thoroughly avoid the generation of fluorine class pollutant, cost of material is effectively reduced simultaneously and improves product quality, the method environmental protection and economy, progressive meaning is notable.
Specific embodiment
All features disclosed in this specification, or disclosed all methods or during the step of, in addition to mutually exclusive feature and/or step, can combine by any way.
Any feature disclosed in this specification, unless specifically stated otherwise, can alternative features equivalent by other or with similar purpose replaced.I.e., unless specifically stated otherwise, each feature is an example in a series of equivalent or similar characteristics.
Embodiment 1:A kind of molybdenum-iron silicothermic process smelting process of the present invention, comprises the following steps:A, the molybdenum ore sand of 150 parts according to the mass fraction, 50 parts of ferrosilicon powder, 40 parts of brown iron oxide, 8 parts of lime, 4 parts of aluminum shot are well mixed;B, well mixed material is put into reacting furnace carries out autothermal reaction;C, will reacted product cool down after carry out molybdenum-iron and slag and separate to can obtain molybdenum-iron finished product.The granularity of the molybdenum ore sand is 1-2 millimeters.The content of calcium oxide is 91% in the lime.
Embodiment 2:A kind of molybdenum-iron silicothermic process smelting process of the present invention, comprises the following steps:A, the molybdenum ore sand of 200 parts according to the mass fraction, 70 parts of ferrosilicon powder, 60 parts of brown iron oxide, 12 parts of lime, 8 parts of aluminum shot are well mixed;B, well mixed material is put into reacting furnace carries out autothermal reaction;C, will reacted product cool down after carry out molybdenum-iron and slag and separate to can obtain molybdenum-iron finished product.The granularity of the molybdenum ore sand is 1-2 millimeters.The content of calcium oxide is 98% in the lime.
Embodiment 3:A kind of molybdenum-iron silicothermic process smelting process of the present invention, comprises the following steps:A, the molybdenum ore sand of 180 parts according to the mass fraction, 60 parts of ferrosilicon powder, 50 parts of brown iron oxide, 10 parts of lime, 6 parts of aluminum shot are well mixed;B, well mixed material is put into reacting furnace carries out autothermal reaction;C, will reacted product cool down after carry out molybdenum-iron and slag and separate to can obtain molybdenum-iron finished product.The granularity of the molybdenum ore sand is 1-2 millimeters.The content of calcium oxide is 95% in the lime.
Presently preferred embodiments of the present invention is the foregoing is only, is not intended to limit the invention, all any modification, equivalent and improvement made within the spirit and principles in the present invention etc. should be included within the scope of the present invention.
Claims (3)
1. a kind of molybdenum-iron silicothermic process smelting process, it is characterised in that comprise the following steps:
A, the molybdenum ore sand of 150-200 parts according to the mass fraction, 50-70 parts of ferrosilicon powder, 40-60 parts of brown iron oxide, 8-12 parts of lime, 4-8 parts of aluminum shot are well mixed;
B, well mixed material is put into reacting furnace carries out autothermal reaction;
C, will reacted product cool down after carry out molybdenum-iron and slag and separate to can obtain molybdenum-iron finished product.
2. a kind of molybdenum-iron silicothermic process smelting process according to claim 1, it is characterised in that:The granularity of the molybdenum ore sand is 1-2 millimeters.
3. a kind of molybdenum-iron silicothermic process smelting process according to claim 1, it is characterised in that:The content of calcium oxide is more than 90% in the lime.
Priority Applications (1)
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CN201510979224.6A CN106916951A (en) | 2015-12-24 | 2015-12-24 | A kind of molybdenum-iron silicothermic process smelting process |
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CN201510979224.6A CN106916951A (en) | 2015-12-24 | 2015-12-24 | A kind of molybdenum-iron silicothermic process smelting process |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109825727A (en) * | 2019-03-05 | 2019-05-31 | 郑州机械研究所有限公司 | A kind of Al-Si-Fe intermediate alloy preparation method based on thermit reaction |
-
2015
- 2015-12-24 CN CN201510979224.6A patent/CN106916951A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109825727A (en) * | 2019-03-05 | 2019-05-31 | 郑州机械研究所有限公司 | A kind of Al-Si-Fe intermediate alloy preparation method based on thermit reaction |
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Application publication date: 20170704 |
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