CN106916514A - A kind of aqueous wear-resistant coating and preparation method thereof - Google Patents
A kind of aqueous wear-resistant coating and preparation method thereof Download PDFInfo
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- CN106916514A CN106916514A CN201710257350.XA CN201710257350A CN106916514A CN 106916514 A CN106916514 A CN 106916514A CN 201710257350 A CN201710257350 A CN 201710257350A CN 106916514 A CN106916514 A CN 106916514A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Road Paving Structures (AREA)
Abstract
The invention discloses a kind of aqueous wear-resistant coating, it is characterised in that:It is mixed with and is formed by A material and B material;Wherein described A material include macromolecular aqueous epoxy resins, Propylene Glycol, kaolin, titanium dioxide and deionized water, and the B material include waterborne curing agent and barium sulfate.Using aqueous wear-resistant coating of the invention, it is possible to increase wearability and adhesiveness.
Description
Technical field
The present invention relates to a kind of aqueous road coating, more particularly to a kind of pavement engineering and the wear-resisting painting used by traffic safety
Layer.
Background technology
Colored road surface technology from birth, just constantly after reform, now, colored road surface be subdivided into slow-vehicle system with it is fast
The class of row system two.Wherein, slow-vehicle system makes function with its good visual experience and landscape, in pavement, parking lot, scape
The field such as square is seen to succeed utilization.But as urban population density increases, the factor, colored slow-vehicle system road such as municipal pollution
Face is polluted and wear problem is on the rise.Polluted by different medium for a long time when ground surface material, worn and torn, surface is come off, ftractureed,
Finally influence whole pavement quality and service life.The method of current road maintenance has micro-surface area, thin cover and mist sealing, wherein
Effect it is best be mist sealing.
A kind of mist sealing and preparation method thereof is disclosed in Chinese patent CN104446163B, the mist sealing in the patent
Constituted using modified emulsifying asphalt, nano material, waterproofing agent and wear-proof sliding-proof sand.But carried out using the mist sealing in the patent
During the maintenance on road surface, emulsified asphalt and water-base epoxy poor compatibility.Cause the mist sealing poor durability.Its wearing valve for >=
0.053g, and code requirement value is≤0.025g.
The content of the invention
It is an object of the invention to provide the good road aqueous wear-resistant coating of a kind of wearability, adhesiveness, and use should
Aqueous wear-resistant Coating Durability is good, and use time is long.
To achieve these goals, the present invention is realized in:A kind of aqueous wear-resistant coating, it is characterised in that:Expected by A
It is mixed with B material and is formed;Wherein described A material include macromolecular aqueous epoxy resins, Propylene Glycol, kaolin, titanium dioxide
And deionized water, B material includes waterborne curing agent and barium sulfate.The aqueous wear-resistant coating prepared using aforesaid way, can
For urban pavement maintenance, good endurance, and wearability is good, adhesiveness is good, nontoxic pollution-free.
In order to further improve durability, each material in the A material is configured by following parts by weight:Macromolecular water
60-80 parts, Propylene Glycol 10-20 parts, kaolin 5-15 parts, titanium dioxide 10-20 parts and deionized water 20-30 of epoxy resin of property
Part.
The drawing value and adhesiveness of aqueous wear-resistant coating are further improved, dispersant, wetting are also included in the A material
Agent, defoamer, silica flour and bentonite.
In order to further improve durability, each material is configured by following parts by weight in the A material:Macromolecular is aqueous
Epoxy resin 65-80 parts, Propylene Glycol 15-20 parts, kaolin 5-12 parts, titanium dioxide 10-28 parts, deionized water 25-30 parts,
Dispersant 0.02-0.35 parts, wetting agent 0.04-0.10 parts, defoamer 0.045-0.25 parts, silica flour 20-40 parts and bentonite
10-30 parts.
In order to further improve the drawing value of aqueous wear-resistant coating, the dispersant is polyethylene glycol, dibutyl dichloride
One or more in tin, HMPA.
In order to further improve the adhesiveness of aqueous wear-resistant coating, the wetting agent is dimethyl sulfoxide (DMSO), polyoxyethylene alkane
One or more in base phenolic ether, polyoxyethylene aliphatic alcohol ether.
Wherein, the defoamer is in OPEO, polyether siloxane copolymers, polyoxypropylene glyceryl
One or more.
Preferably, each material is configured by following parts by weight in the B material:Waterborne curing agent 10-20 parts and sulfuric acid
Barium 5-20 parts.
In order to further improve yield, the waterborne curing agent is water soluble polyamide.The curing agent has pliability, resistance to
Aqueous and anti-corrosion property, and curing agent low toxicity, the environmental protection.
In order to further improve durability, the aqueous wear-resistant coating is matched somebody with somebody by following material by following parts by weight
Put:65-75 parts of macromolecular aqueous epoxy resins, Propylene Glycol 15-18 parts, kaolin 5-10 parts, titanium dioxide 10-15 parts, go
Ionized water 25-28 parts, 0.02-0.25 parts of polyethylene glycol (400), dimethyl sulfoxide (DMSO) 0.04-0.08 parts, OPEO
0.045-0.15 parts, silica flour 20-35 parts, bentonite 10-25 parts, waterborne curing agent 10-20 parts and barium sulfate 5-20 parts.
A kind of preparation method of aqueous wear-resistant coating, is carried out as follows:
Step one, by aqueous epoxy resins, anion aqueous styrene-acrylic emulsion, Propylene Glycol, kaolin, titanium dioxide, point
Powder, wetting agent, defoamer, deionized water mix according to the above ratio, are stirred according to 500r/min rotating speeds, until mixture
It is middle without obvious particle after, add aforementioned proportion bentonite, silica flour, into cutter, cut according to 7000r/min rotating speeds
Cut, shear 30~45min, it is standby;
Step 2, by waterborne curing agent, barium sulfate pour into it is above-mentioned prepare solution, be well mixed, abundant mix 10 minutes,
Until solution is uniform;
Step 3, spraying, solidification.
Beneficial effect:
Aqueous wear-resistant coating of the present invention is one kind of sprayable involved Colorful Asphalt Pavement in colored slow-vehicle system
Wear-resistant resistant to pollution surface layer protection materials, have anti-wear performance excellent, glutinous according to the aqueous wear-resistant coating obtained by the present invention
Attached performance is strong, low cost the characteristics of, its drawing value >=5.0MPa, adhesion >=2.5Mpa, high income is up to more than 99%, the present invention
Preparation process is simple, yield is big, low cost, is adapted to industrialized production.
30~50 μm of wear-resistant protective layer is formed in road crust using aqueous wear-resistant coating of the invention, is solved colored slow
The problem that row system durability is not enough, easily pollutes, be easily worn, while its production is convenient, construction is simple, nontoxic pollution-free, tool
There are preferable mechanical strength and a cohesive force, good stability, corrosion resistance, weatherability are good and wearability is good.When coating consumption >=
1.4Kg/m3, wearability≤0.0213g.
Specific embodiment:
Specific embodiment of the invention is described in further detail below, but the invention is not limited in these realities
Mode is applied, any improvement or replacement on the present embodiment essence spirit still falls within the claims in the present invention required for protection
Scope.
Embodiment 1:A kind of aqueous wear-resistant coating, is mixed with and is formed by A material and B material;Wherein described A material include macromolecular
Aqueous epoxy resins, Propylene Glycol, kaolin, titanium dioxide and deionized water, the B material include waterborne curing agent and sulfuric acid
Barium.The aqueous wear-resistant coating prepared using aforesaid way, can be used in urban pavement maintenance, good endurance, and wearability is good, viscous
Attached property is good, nontoxic pollution-free.
Wherein, each material in the A material is configured by following parts by weight:60 parts of macromolecular aqueous epoxy resins,
20 parts of 10 parts of Propylene Glycol, 5 parts of kaolin, 10 parts of titanium dioxide and deionized water.
Each material is configured by following parts by weight in the B material:5 parts of 10 parts of waterborne curing agent and barium sulfate.
The preparation method of the aqueous wear-resistant coating is:
Step one, by aqueous epoxy resins, anion aqueous styrene-acrylic emulsion, Propylene Glycol, kaolin, titanium dioxide, go
Ionized water mixes according to the above ratio, is stirred according to 500r/min rotating speeds, until in mixture without obvious particle after, into cutting
Machine is cut, is sheared according to 7000r/min rotating speeds, shear 30min, it is standby;
Step 2, by waterborne curing agent, barium sulfate pour into according to the above ratio it is above-mentioned prepare solution, be well mixed, fully
Mix 10 minutes, until solution is uniform;
Step 3, spraying, solidification.Wherein, the coating consumption in the present embodiment is 1.4Kg/m3。
The aqueous wear-resistant coating for finishing will be as stated above made, corresponding experimental verification is carried out, its experimental result see the table below:
The aqueous wear-resistant coating made by the present embodiment method has that anti-wear performance is excellent, Adhesion property strong, low cost
Feature, and preparation process is simple of the present invention, yield are big, low cost, are adapted to industrialized production.
30~50 μm of wear-resistant protective layer is formed in road crust using the aqueous wear-resistant coating of the present embodiment, is solved colored
The problem that slow-vehicle system durability is not enough, easily pollutes, be easily worn, while its production is convenient, construction is simple, nontoxic pollution-free,
With preferable mechanical strength and cohesive force, good stability, corrosion resistance, weatherability are good and wearability is good.
Embodiment 2:A kind of aqueous wear-resistant coating, is mixed with and is formed by A material and B material;Wherein described A material include macromolecular
Aqueous epoxy resins, Propylene Glycol, kaolin, titanium dioxide, deionized water, dispersant, wetting agent, defoamer, silica flour and
Bentonite.The B material include waterborne curing agent and barium sulfate.
Wherein, the dispersant be polyethylene glycol, the wetting agent be dimethyl sulfoxide (DMSO), the defoamer be octylphenol polyethylene
Oxygen vinethene.The waterborne curing agent is water soluble polyamide.
The aqueous wear-resistant coating is configured by following parts by weight:70 parts of macromolecular aqueous epoxy resins, methyl second
16.5 parts of glycol, 8 parts of kaolin, 12 parts of titanium dioxide, 27 parts of deionized water, (400) 0.023 parts of polyethylene glycol, dimethyl sulfoxide (DMSO)
0.06 part, 0.03 part of OPEO, 30 parts of silica flour, 118 parts of bentonite, 18 parts of waterborne curing agent and barium sulfate 10
Part.
A kind of preparation method of aqueous wear-resistant coating, is carried out as follows:
Step one, by aqueous epoxy resins, anion aqueous styrene-acrylic emulsion, Propylene Glycol, kaolin, titanium dioxide, point
Powder, wetting agent, defoamer, deionized water mix according to the above ratio, are stirred according to 500r/min rotating speeds, until mixture
It is middle without obvious particle after, add aforementioned proportion bentonite, silica flour, into cutter, cut according to 7000r/min rotating speeds
Cut, shear 30~45min, it is standby;
Step 2, by waterborne curing agent, barium sulfate pour into it is above-mentioned prepare solution, be well mixed, abundant mix 10 minutes,
Until solution is uniform;
Step 3, spraying, solidification.Wherein, the coating consumption in the present embodiment is 1.4Kg/m3。
The aqueous wear-resistant coating for finishing will be as stated above made, corresponding experimental verification is carried out, its experimental result see the table below:
The aqueous wear-resistant coating made by the present embodiment method has that anti-wear performance is excellent, Adhesion property strong, low cost
Feature, and preparation process is simple of the present invention, yield are big, low cost, are adapted to industrialized production.
30~50 μm of wear-resistant protective layer is formed in road crust using the aqueous wear-resistant coating of the present embodiment, is solved colored
The problem that slow-vehicle system durability is not enough, easily pollutes, be easily worn, while its production is convenient, construction is simple, nontoxic pollution-free,
With preferable mechanical strength and cohesive force, good stability, corrosion resistance, weatherability are good and wearability is good.
Embodiment 3:A kind of aqueous wear-resistant coating, is mixed with and is formed by A material and B material;Wherein described A material include macromolecular
Aqueous epoxy resins, Propylene Glycol, kaolin, titanium dioxide, deionized water, dispersant, wetting agent, defoamer, silica flour and
Bentonite.The B material include waterborne curing agent and barium sulfate.
Wherein, the dispersant be polyethylene glycol, the wetting agent be dimethyl sulfoxide (DMSO), the defoamer be octylphenol polyethylene
Oxygen vinethene.The waterborne curing agent is water soluble polyamide
The aqueous wear-resistant coating is configured by following parts by weight:75 parts of macromolecular aqueous epoxy resins, methyl second
18 parts of glycol, 10 parts of kaolin, 15 parts of titanium dioxide, 28 parts of deionized water, (400) 0.25 parts of polyethylene glycol, dimethyl sulfoxide (DMSO)
0.08 part, 0.045 part of OPEO, 35 parts of silica flour, 25 parts of bentonite, 20 parts of waterborne curing agent and barium sulfate 20
Part.
A kind of preparation method of aqueous wear-resistant coating, is carried out as follows:
Step one, by aqueous epoxy resins, anion aqueous styrene-acrylic emulsion, Propylene Glycol, kaolin, titanium dioxide, point
Powder, wetting agent, defoamer, deionized water mix according to the above ratio, are stirred according to 500r/min rotating speeds, until mixture
It is middle without obvious particle after, add aforementioned proportion bentonite, silica flour, into cutter, cut according to 7000r/min rotating speeds
Cut, shear 30~45min, it is standby;
Step 2, by waterborne curing agent, barium sulfate pour into it is above-mentioned prepare solution, be well mixed, abundant mix 10 minutes,
Until solution is uniform;
Step 3, spraying, solidification.Wherein, the coating consumption in the present embodiment is 1.4Kg/m3。
The aqueous wear-resistant coating for finishing will be as stated above made, corresponding experimental verification is carried out, its experimental result see the table below:
The aqueous wear-resistant coating made by the present embodiment method has that anti-wear performance is excellent, Adhesion property strong, low cost
Feature, and preparation process is simple of the present invention, yield are big, low cost, are adapted to industrialized production.
30~50 μm of wear-resistant protective layer is formed in road crust using the aqueous wear-resistant coating of the present embodiment, is solved colored
The problem that slow-vehicle system durability is not enough, easily pollutes, be easily worn, while its production is convenient, construction is simple, nontoxic pollution-free,
With preferable mechanical strength and cohesive force, good stability, corrosion resistance, weatherability are good and wearability is good.
Claims (11)
1. a kind of aqueous wear-resistant coating, it is characterised in that:It is mixed with and is formed by A material and B material;Wherein described A material include big point
Sub- aqueous epoxy resins, Propylene Glycol, kaolin, titanium dioxide and deionized water, the B material include waterborne curing agent and sulfuric acid
Barium.
2. aqueous wear-resistant coating as claimed in claim 1, it is characterised in that:Each material in the A material presses following weight portion
Number is configured:60-80 parts of macromolecular aqueous epoxy resins, Propylene Glycol 10-20 parts, kaolin 5-15 parts, titanium dioxide 10-
20 parts and deionized water 20-30 parts.
3. aqueous wear-resistant coating as claimed in claim 1 or 2, it is characterised in that:Also include dispersant, wetting in the A material
Agent, defoamer, silica flour and bentonite.
4. aqueous wear-resistant coating as claimed in claim 3, it is characterised in that:Each material presses following parts by weight in the A material
Configured:65-80 parts of macromolecular aqueous epoxy resins, Propylene Glycol 15-20 parts, kaolin 5-12 parts, titanium dioxide 10-28
Part, deionized water 25-30 parts, dispersant 0.02-0.35 parts, wetting agent 0.04-0.10 parts, defoamer 0.045-0.25 parts, stone
20-40 parts and bentonite 10-30 parts of English powder.
5. the aqueous wear-resistant coating as described in claim 3 or 4, it is characterised in that:The dispersant is polyethylene glycol, dibutyl
One or more in stannous chloride, HMPA.
6. the aqueous wear-resistant coating as described in claim 3,4 or 5, it is characterised in that:The wetting agent is dimethyl sulfoxide (DMSO), gathers
One or more in oxygen vinyl alkyl phenolic ether, polyoxyethylene aliphatic alcohol ether.
7. the aqueous wear-resistant coating as described in claim 3,4,5 or 6, it is characterised in that:The defoamer is octyl phenol polyoxy
One or more in vinethene, polyether siloxane copolymers, polyoxypropylene glyceryl.
8. the aqueous wear-resistant coating as described in above-mentioned any one claim, it is characterised in that:Each material is by following in the B material
Parts by weight are configured:Waterborne curing agent 10-20 parts and barium sulfate 5-20 parts.
9. aqueous wear-resistant coating as claimed in claim 8, it is characterised in that:The waterborne curing agent be water soluble polyamide,
One or more in triethylene tetramine, polyethylene polyamine.
10. aqueous wear-resistant coating as claimed in claim 8 or 9, it is characterised in that:There is following material by following parts by weight
Configured:65-75 parts of macromolecular aqueous epoxy resins, Propylene Glycol 15-18 parts, kaolin 5-10 parts, titanium dioxide 10-15
Part, deionized water 25-28 parts, polyethylene glycol(400)0.02-0.25 parts, dimethyl sulfoxide (DMSO) 0.04-0.08 parts, octyl phenol polyoxy
Vinethene 0.045-0.15 parts, silica flour 20-35 parts, bentonite 10-25 parts, waterborne curing agent 10-20 parts and barium sulfate 5-20
Part.
A kind of 11. preparation methods of aqueous wear-resistant coating, it is characterised in that:Carry out as follows:
Step one, by aqueous epoxy resins, anion aqueous styrene-acrylic emulsion, Propylene Glycol, kaolin, titanium dioxide, dispersant,
Wetting agent, defoamer, deionized water mix according to the above ratio, are stirred according to 500r/min rotating speeds, until nothing in mixture
After obvious particle, bentonite, the silica flour of aforementioned proportion are added, into cutter, are sheared according to 7000r/min rotating speeds,
30 ~ 45min is sheared, it is standby;
Step 2, by waterborne curing agent, barium sulfate pour into it is above-mentioned prepare solution, be well mixed, abundant mix 10 minutes, until
Solution is uniform;
Step 3, spraying, solidification.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108744420A (en) * | 2018-08-24 | 2018-11-06 | 常州市第二人民医院 | A kind of diabetic's limb exercising device |
CN116004079A (en) * | 2022-12-15 | 2023-04-25 | 洛阳科博思新材料科技有限公司 | Wear-resistant high-impedance paint for steel rail coating, steel rail and spraying method |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104789059A (en) * | 2015-05-12 | 2015-07-22 | 重庆市智翔铺道技术工程有限公司 | Paint for colored roads |
CN106221509A (en) * | 2016-08-10 | 2016-12-14 | 中科院广州化学有限公司南雄材料生产基地 | A kind of cement concrete basal plane protective treatment aqueous epoxy coating and preparation method |
CN106318108A (en) * | 2015-07-08 | 2017-01-11 | 魏忠 | Novel traffic sign paint |
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2017
- 2017-04-19 CN CN201710257350.XA patent/CN106916514A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104789059A (en) * | 2015-05-12 | 2015-07-22 | 重庆市智翔铺道技术工程有限公司 | Paint for colored roads |
CN106318108A (en) * | 2015-07-08 | 2017-01-11 | 魏忠 | Novel traffic sign paint |
CN106221509A (en) * | 2016-08-10 | 2016-12-14 | 中科院广州化学有限公司南雄材料生产基地 | A kind of cement concrete basal plane protective treatment aqueous epoxy coating and preparation method |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108744420A (en) * | 2018-08-24 | 2018-11-06 | 常州市第二人民医院 | A kind of diabetic's limb exercising device |
CN108744420B (en) * | 2018-08-24 | 2024-04-05 | 丰都县中医院 | Limb exercise device for diabetics |
CN116004079A (en) * | 2022-12-15 | 2023-04-25 | 洛阳科博思新材料科技有限公司 | Wear-resistant high-impedance paint for steel rail coating, steel rail and spraying method |
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Application publication date: 20170704 |