CN106915133A - A kind of energy saving and environment friendly corrugated sheet - Google Patents
A kind of energy saving and environment friendly corrugated sheet Download PDFInfo
- Publication number
- CN106915133A CN106915133A CN201710129290.3A CN201710129290A CN106915133A CN 106915133 A CN106915133 A CN 106915133A CN 201710129290 A CN201710129290 A CN 201710129290A CN 106915133 A CN106915133 A CN 106915133A
- Authority
- CN
- China
- Prior art keywords
- layer
- pvc
- interlayer
- antibacterial
- discoloration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010410 layer Substances 0.000 claims abstract description 118
- 239000011229 interlayer Substances 0.000 claims abstract description 59
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 48
- 238000002845 discoloration Methods 0.000 claims abstract description 46
- 239000002131 composite material Substances 0.000 claims abstract description 30
- 150000001875 compounds Chemical class 0.000 claims abstract description 12
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 63
- 239000007788 liquid Substances 0.000 claims description 28
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 24
- 239000004793 Polystyrene Substances 0.000 claims description 24
- 229920002223 polystyrene Polymers 0.000 claims description 24
- 229920001971 elastomer Polymers 0.000 claims description 22
- 239000004005 microsphere Substances 0.000 claims description 20
- 230000003115 biocidal effect Effects 0.000 claims description 19
- 210000001940 cystoblast Anatomy 0.000 claims description 19
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 18
- 238000002360 preparation method Methods 0.000 claims description 17
- 239000004411 aluminium Substances 0.000 claims description 16
- 229910052782 aluminium Inorganic materials 0.000 claims description 16
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 15
- 239000002775 capsule Substances 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 15
- 238000003475 lamination Methods 0.000 claims description 13
- 239000000758 substrate Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 9
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 9
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 9
- 238000000576 coating method Methods 0.000 claims description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 6
- 238000005119 centrifugation Methods 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 230000009514 concussion Effects 0.000 claims description 6
- 235000019441 ethanol Nutrition 0.000 claims description 6
- 230000031700 light absorption Effects 0.000 claims description 6
- 238000001556 precipitation Methods 0.000 claims description 6
- 238000001291 vacuum drying Methods 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 5
- 241000894006 Bacteria Species 0.000 claims description 4
- LIZLYZVAYZQVPG-UHFFFAOYSA-N (3-bromo-2-fluorophenyl)methanol Chemical compound OCC1=CC=CC(Br)=C1F LIZLYZVAYZQVPG-UHFFFAOYSA-N 0.000 claims description 3
- 101710134784 Agnoprotein Proteins 0.000 claims description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 238000010521 absorption reaction Methods 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 229940106691 bisphenol a Drugs 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims description 3
- 229910000397 disodium phosphate Inorganic materials 0.000 claims description 3
- 235000019800 disodium phosphate Nutrition 0.000 claims description 3
- 239000012153 distilled water Substances 0.000 claims description 3
- 238000005485 electric heating Methods 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 3
- 239000002932 luster Substances 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- LGRFSURHDFAFJT-UHFFFAOYSA-N phthalic anhydride Chemical compound C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- 239000001488 sodium phosphate Substances 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 239000003643 water by type Substances 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims 12
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims 2
- WBZKQQHYRPRKNJ-UHFFFAOYSA-L disulfite Chemical compound [O-]S(=O)S([O-])(=O)=O WBZKQQHYRPRKNJ-UHFFFAOYSA-L 0.000 claims 1
- 239000011344 liquid material Substances 0.000 claims 1
- 239000012528 membrane Substances 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 239000011259 mixed solution Substances 0.000 claims 1
- 239000003471 mutagenic agent Substances 0.000 claims 1
- 231100000707 mutagenic chemical Toxicity 0.000 claims 1
- WQSRXNAKUYIVET-UHFFFAOYSA-N sulfuric acid;zinc Chemical compound [Zn].OS(O)(=O)=O WQSRXNAKUYIVET-UHFFFAOYSA-N 0.000 claims 1
- 238000009413 insulation Methods 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 230000005855 radiation Effects 0.000 abstract description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 238000001514 detection method Methods 0.000 description 3
- 241000165940 Houjia Species 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 2
- 241001104043 Syringa Species 0.000 description 2
- 235000004338 Syringa vulgaris Nutrition 0.000 description 2
- 239000004599 antimicrobial Substances 0.000 description 2
- 230000003139 buffering effect Effects 0.000 description 2
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000013536 elastomeric material Substances 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 2
- 229960001763 zinc sulfate Drugs 0.000 description 2
- 229910000368 zinc sulfate Inorganic materials 0.000 description 2
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 229920003225 polyurethane elastomer Polymers 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011885 synergistic combination Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/28—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer comprising a deformed thin sheet, i.e. the layer having its entire thickness deformed out of the plane, e.g. corrugated, crumpled
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F112/02—Monomers containing only one unsaturated aliphatic radical
- C08F112/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F112/06—Hydrocarbons
- C08F112/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
- C09D129/02—Homopolymers or copolymers of unsaturated alcohols
- C09D129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/10—Properties of the layers or laminate having particular acoustical properties
- B32B2307/102—Insulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/304—Insulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/71—Resistive to light or to UV
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Laminated Bodies (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of energy saving and environment friendly corrugated sheet, including PVC corrugated layers, interlayer and PVC board；The PVC corrugated layers turn into an entirety by the way that interlayer and the PVC board are compound；The PVC corrugated layers include a PVC corrugated layers and the 2nd PVC corrugated layers, and the interlayer includes the first interlayer and the second interlayer, and the PVC board includes the first PVC board and the second PVC board；The first PVC corrugated layers are compound with first PVC board by first interlayer；Cushion is filled between first PVC board and the 2nd PVC corrugated layers, the 2nd PVC corrugated layers are compound with second PVC board by second interlayer；The first PVC corrugation layer surfaces are laid with antibacterial discoloration composite film.Energy saving and environment friendly corrugated sheet of the present invention has insulation, heat-insulated, sound insulation, radiation proof, the advantage of environmental protection.
Description
Technical field
The present invention relates to building field, more particularly to a kind of energy saving and environment friendly corrugated sheet.
Background technology
Currently, metal color steel uses more building roof corrugated sheet as in the market, generally as building roof
Waterproof material is used.But because metal color steel has the characteristics of being easily corroded, especially in the situation that southern acid rain is more serious
Under, the metal color steel being corroded makes the outward appearance of building look very ugly, and then influences the attractive in appearance of City Building, its
The use in above-mentioned environment can not be adapted to.
The content of the invention
The present invention is intended to provide a kind of energy-conserving and environment-protective corrugated sheet, to solve above-mentioned technical problem.
Above-mentioned purpose of the invention is achieved by the following technical programs：.
A kind of energy saving and environment friendly corrugated sheet, including PVC corrugated layers, interlayer and PVC board；The PVC corrugated layers pass through interlayer
It is compound with the PVC board to turn into an entirety；The PVC corrugated layers include a PVC corrugated layers and the 2nd PVC corrugated layers, institute
Stating interlayer includes the first interlayer and the second interlayer, and the PVC board includes the first PVC board and the second PVC board；Described first PVC watts
Stupefied layer is compound with first PVC board by first interlayer；Filled with slow between first PVC board and the 2nd PVC corrugated layers
Layer is rushed, the 2nd PVC corrugated layers are compound with second PVC board by second interlayer；The first PVC corrugated layer tables
Face is laid with antibacterial discoloration composite film.
Used as another embodiment of the presently claimed invention, the interlayer is polystyrene material and/or polyurethane
Elastomeric material.
Used as another embodiment of the presently claimed invention, first interlayer is polystyrene material, and second interlayer is
Desmocoll material.
Used as another embodiment of the presently claimed invention, first interlayer and second interlayer are polyurethane second
It is polystyrene material that ester elastomeric material or first interlayer and second interlayer are.
Used as another embodiment of the presently claimed invention, the thickness of first interlayer is 2~5cm；Second interlayer
Thickness is 2~5cm.
As another embodiment of the presently claimed invention, described antibacterial discoloration composite film along its thickness direction from bottom to top
It is respectively：Substrate layer, aluminium lamination, thermochromic layer, antibiosis rubber cystoblast and photosensitive microballoon discoloration layer；Substrate layer supports other each layers,
The intensity of aluminium lamination enhancing light makes image more become clear, and metallic luster is presented, and thermic discoloration layer occurs antibacterial discoloration composite film
Thermochromism, antibiosis rubber cystoblast stops that bacterium enters antibacterial discoloration composite film, and photosensitive microballoon discoloration layer is combined antibacterial discoloration
There is Ultraluminescence discoloration in film layer.
Used as another embodiment of the presently claimed invention, the preparation process of antibacterial discoloration composite film is as follows：On substrate layer
Aluminium coated, coats thermochromic material layer on aluminium lamination, thermochromic material layer upper coated antibacterial capsule layer is applied on antibiosis rubber cystoblast
The photosensitive microballoon layer of cloth, the another side of substrate layer applies transfer glue-line, and glue-line causes that the antibacterial discoloration composite film pastes energy-saving ring
Protect on corrugated sheet.
Used as another embodiment of the presently claimed invention, the preparation method of described antibacterial discoloration composite film is as follows：
Step one, the preparation of thermochromic material：It is 350 according to mass ratio:2.3:4:40:80 weigh butanone, purple respectively
Outer fluorescent material, bisphenol-A, crystal violet lactone, granules of polystyrene, in sequentially adding flask at 25 ± 5 DEG C in the order described above, shape
Into uniform liquid, stir 3 hours, the content of ultraviolet fluorescence powder is the 0.15% of whole temperature changing resin, the uniform liquid that will be formed
Material；
Step 2, the preparation of antibacterial capsule material：In separatory funnel add 500ml deionized waters, weigh 3g urea and
3.0g polyvinylpyrrolidones (PVP) are added in above-mentioned separatory funnel, add 1.5g NaCl, after concussion 10min, use length
Neck dropper is slowly added dropwise AgNO to it3Solution, after concussion 10min, is added dropwise a certain amount of titania solution liquid, adds appropriate
Solution of zinc sulfate, be cooled to room temperature after 80 DEG C of water-bath 3h, add 5ml disodium phosphate solns, shake 30min；Add 10ml
Absolute ethyl alcohol shakes 30min；With traditional vacuum, precipitation is successively with distilled water, acid solution, absolute ethanol washing；Precipitation is put into electric heating
Air dry oven is dried；By dry powder it is ground be made after loose powder to be put into Muffle furnace be calcined, it is natural after terminating
It is down to room temperature；Ground after calcination can be prepared by nano-antibacterial capsule material；
Step 3, the preparation of photosensitive micro-sphere material：A certain amount of styrene monomer is dissolved into absolute ethyl alcohol and water mixes molten
In liquid, 60 DEG C are heated to, constant temperature keeps 30min, are again heated to 90 DEG C, constant temperature keeps 30min, PVP is fully dissolved, Ran Houjia
Enter sodium peroxydisulfate solution, react 5h, reaction is centrifuged after terminating, and polystyrene microsphere is obtained after drying；Wherein, it is anhydrous
The volume ratio of second alcohol and water is 60:40；Weigh a certain amount of polystyrene microsphere and be added to certain density phthalic anhydride
In solution, nitrogen protection adds alchlor, 55 DEG C of reaction 12h to obtain surface-modified polystyrene microspheres while stirring, will
Surface-modified polystyrene microspheres carry out absorption 12h in being put into spiro-pyrans ethanol solution, are then centrifuged for separating, through drying prepared light
Quick microballoon, obtained photosensitive microballoon is added in certain density polyvinyl alcohol (PVA) solution and soaks 24h, centrifugation
After be placed in absolute ethyl alcohol disperse, centrifugation, dry, dried PVA polyethylene microballoon is put into tin ash solution
Immersion 48h, then 80 DEG C are drying to obtain；
Step 4, antibacterial discoloration is combined film preparation：
First, according to step 2:1:2 mass ratio claim to take respectively it is appropriate via the thermochromic material prepared by step one,
The photosensitive micro-sphere material prepared by antibacterial capsule material and step 3 prepared by step 2；
Second, thermochromic material is dissolved in butanone solution, formed uniform liquid A, stirring 90 minutes it is standby；
3rd, antibacterial capsule material is dissolved in butanone solution, formed uniform liquid B, stirring 120 minutes it is standby；
4th, photosensitive micro-sphere material is dissolved in toluene solution, formed uniform liquid C, stirring 180 minutes it is standby；
5th, liquid A coating and naturally film forming are dried 8 on aluminium lamination, in negative pressure 0.1~0.5MPa vacuum drying chambers small
When, obtain the thermochromic layer of appearance uniform；
6th, liquid B is coated with and natural film forming is on thermochromic layer, in negative pressure 0.2~0.3MPa vacuum drying chambers
Dry 10 hours, irradiated 2 hours as under 60Co rays after taking-up, obtain the thermochromic layer-antibiosis rubber cystoblast of appearance uniform；
7th, by liquid C coatings, simultaneously natural film forming on antibiosis rubber cystoblast, is vacuum dried 24 hours, obtains appearance uniform
Thermochromic layer-antibiosis rubber cystoblast-photosensitive microballoon layer, i.e. antibacterial discoloration composite film.
Used as another embodiment of the presently claimed invention, the thickness of the thermochromic layer is 10~100nm；The antibiosis rubber
The thickness of cystoblast is 50~60nm；The thickness of the photosensitive microballoon layer is 10~100nm.
Used as another embodiment of the presently claimed invention, the antibacterial discoloration composite film also includes one layer of light-absorption layer, described
Light-absorption layer is painted on the photosensitive microballoon layer top.
Relative to prior art, beneficial effects of the present invention：
1st, energy saving and environment friendly corrugated sheet of the present invention have insulation, it is heat-insulated, sound insulation, radiation proof, environmental protection it is excellent
Point.
2nd, energy saving and environment friendly corrugated sheet of the present invention is provided with two interlayers, and each interlayer can be used alone polyphenyl second
Alkene material or Desmocoll material, or above two material combination so that the PVC corrugated boards have
Have resistance to compression, do not absorb water, lightweight and corrosion resistant characteristic, relative to traditional metal color steel, its service life extends 35%
~45%, and because its thermal conductivity factor is relatively low, situation cold in winter and hot in summer will not occur, it is a kind of type for building of environmental protection
Material, with extensive popularization and application ability and potential commercial value.
3rd, energy-conserving and environment-protective corrugated sheet of the present invention is laid with thermic/photochromic film layer in PVC corrugation layer surfaces, should
Thermic/photochromic film layer can follow temperature and the strong and weak of illumination that discoloration occurs so that use the building of the PVC corrugated sheets
With intelligent color-changing effect, the aesthetic of building substance environment is improved, enhance urban.
4th, energy-conserving and environment-protective corrugated sheet of the present invention is laid with antibiotic layer in PVC corrugation plate surfaces, and the antibiotic layer is included
There are complex antimicrobials, be combined together for titanium dioxide, zinc ion and silver ion by this complex antimicrobials, make use of titanium dioxide
Photocatalysis Decomposition, the characteristics of silver ion is more sensitive to light and heat so that there is the energy-conserving and environment-protective corrugated sheet light thermic of making peace to make
Used time, all possess antibacterial action, light make peace thermic when the effect of antibacterial synergistic combinations, enhance the antibiotic property of the environmentally friendly corrugated sheet
Energy.
Brief description of the drawings
Accompanying drawing herein is merged in specification and constitutes the part of this specification, shows and meets implementation of the invention
Example, and be used to explain principle of the invention together with specification.
Fig. 1 is structural representation of the invention.
Fig. 2 is the structural representation of the described photic/thermochromic film in Fig. 1.
Wherein：1- antibacterial discoloration composite films, the PVC corrugated layers of 2- the, the interlayers of 3- first, the PVC boards of 4- first, 5- bufferings
Layer, the PVC corrugated layers of 6- the 2nd, the interlayers of 7- second, the PVC boards of 8- second, 10- substrate layers, 11- aluminium laminations, 12- thermochromic layers, 13-
Antibiosis rubber cystoblast, the photosensitive microballoon layers of 14-.
Specific embodiment
The invention will be further described with the following Examples.
As shown in figure 1, a kind of energy saving and environment friendly corrugated sheet, including PVC corrugated layers, interlayer and PVC board；The PVC corrugations
Layer turns into an entirety by the way that interlayer and the PVC board are compound；The PVC corrugated layers include a PVC corrugated layers 2 and second
PVC corrugated layers 6, the interlayer includes the first interlayer 3 and the second interlayer 7, and the PVC board includes the first PVC board 4 and the 2nd PVC
Plate 8；The first PVC corrugated layers 2 are by first interlayer 3 and first PVC board compound 4；First PVC board 4 and second
Cushion 5 is filled between PVC corrugated layers 6, the one side of cushion 5 plays a part of buffering, strengthens corrugation of the present invention
The intensity and anti-impact force of plate, on the other hand enhance the heat-proof quality of corrugated sheet.The 2nd PVC corrugated layers 6 are by described
Second interlayer 7 and second PVC board compound 8；The surface of first PVC corrugated layers 2 is laid with antibacterial discoloration as shown in Figure 2
Composite film 1.
Further, the interlayer is polystyrene material and/or Desmocoll material.
Further, first interlayer 3 is polystyrene material, and second interlayer 7 is polyurethane rubber
Glue material.
Further, first interlayer 3 and second interlayer 7 are Desmocoll material or described
It is polystyrene material that first interlayer 3 and second interlayer 7 are.
Further, the thickness of first interlayer 3 is 2~5cm；The thickness of second interlayer 7 is 2~5cm.
Further, as shown in Fig. 2 described antibacterial discoloration composite film 1 is respectively from bottom to top along its thickness direction：
Substrate layer 10, aluminium lamination 11, thermochromic layer 12, antibiosis rubber cystoblast 13 and photosensitive microballoon discoloration layer 14；Substrate layer 10 supports other
Each layer, the intensity of the enhancing light of aluminium lamination 11 makes image more become clear, and metallic luster is presented, and thermic discoloration layer 12 is combined antibacterial discoloration
There is thermochromism in film layer 1, antibiosis rubber cystoblast 13 stops that bacterium enters antibacterial discoloration composite film 1, photosensitive microballoon discoloration layer 14
Make antibacterial discoloration composite film 1 that Ultraluminescence to occur to change colour.
Further, the preparation process of antibacterial discoloration composite film 1 is as follows：Aluminium coated 11 on substrate layer, on aluminium lamination 11
Coating thermochromic material layer, coated antibacterial capsule layer 13, is coated with photosensitive on antibiosis rubber cystoblast 13 on thermochromic material layer 12
Microballoon layer 14, the another side of substrate layer 10 applies transfer glue-line, and glue-line causes that the antibacterial discoloration composite film 1 pastes energy-conserving and environment-protective
On corrugated sheet.
Further, the preparation method of described antibacterial discoloration composite film 1 is as follows：
Step one, the preparation of thermochromic material：It is 350 according to mass ratio:2.3:4:40:80 weigh butanone, purple respectively
Outer fluorescent material, bisphenol-A, crystal violet lactone, granules of polystyrene, in sequentially adding flask at 25 ± 5 DEG C in the order described above, shape
Into uniform liquid, stir 3 hours, the content of ultraviolet fluorescence powder is the 0.15% of whole temperature changing resin, the uniform liquid that will be formed
Material；
Step 2, the preparation of antibacterial capsule material：In separatory funnel add 500ml deionized waters, weigh 3g urea and
3.0g polyvinylpyrrolidones (PVP) are added in above-mentioned separatory funnel, add 1.5g NaCl, after concussion 10min, use length
Neck dropper is slowly added dropwise AgNO to it3Solution, after concussion 10min, is added dropwise a certain amount of titania solution liquid, adds appropriate
Solution of zinc sulfate, be cooled to room temperature after 80 DEG C of water-bath 3h, add 5ml disodium phosphate solns, shake 30min；Add 10ml
Absolute ethyl alcohol shakes 30min；With traditional vacuum, precipitation is successively with distilled water, acid solution, absolute ethanol washing；Precipitation is put into electric heating
Air dry oven is dried；By dry powder it is ground be made after loose powder to be put into Muffle furnace be calcined, it is natural after terminating
It is down to room temperature；Ground after calcination can be prepared by nano-antibacterial capsule material；
Step 3, the preparation of photosensitive micro-sphere material：A certain amount of styrene monomer is dissolved into absolute ethyl alcohol and water mixes molten
In liquid, 60 DEG C are heated to, constant temperature keeps 30min, are again heated to 90 DEG C, constant temperature keeps 30min, PVP is fully dissolved, Ran Houjia
Enter sodium peroxydisulfate solution, react 5h, reaction is centrifuged after terminating, and polystyrene microsphere is obtained after drying；Wherein, it is anhydrous
The volume ratio of second alcohol and water is 60:40；Weigh a certain amount of polystyrene microsphere and be added to certain density phthalic anhydride
In solution, nitrogen protection adds alchlor, 55 DEG C of reaction 12h to obtain surface-modified polystyrene microspheres while stirring, will
Surface-modified polystyrene microspheres carry out absorption 12h in being put into spiro-pyrans ethanol solution, are then centrifuged for separating, through drying prepared light
Quick microballoon, obtained photosensitive microballoon is added in certain density polyvinyl alcohol (PVA) solution and soaks 24h, centrifugation
After be placed in absolute ethyl alcohol disperse, centrifugation, dry, dried PVA polyethylene microballoon is put into tin ash solution
Immersion 48h, then 80 DEG C are drying to obtain；
Step 4, antibacterial discoloration is combined film preparation：
First, according to step 2:1:2 mass ratio claim to take respectively it is appropriate via the thermochromic material prepared by step one,
The photosensitive micro-sphere material prepared by antibacterial capsule material and step 3 prepared by step 2；
Second, thermochromic material is dissolved in butanone solution, formed uniform liquid A, stirring 90 minutes it is standby；
3rd, antibacterial capsule material is dissolved in butanone solution, formed uniform liquid B, stirring 120 minutes it is standby；
4th, photosensitive micro-sphere material is dissolved in toluene solution, formed uniform liquid C, stirring 180 minutes it is standby；
5th, liquid A coating and naturally film forming are dried 8 on aluminium lamination, in negative pressure 0.1~0.5MPa vacuum drying chambers small
When, obtain the thermochromic layer of appearance uniform；
6th, liquid B is coated with and natural film forming is on thermochromic layer, in negative pressure 0.2~0.3MPa vacuum drying chambers
Dry 10 hours, irradiated 2 hours as under 60Co rays after taking-up, obtain the thermochromic layer-antibiosis rubber cystoblast of appearance uniform；
7th, by liquid C coatings, simultaneously natural film forming on antibiosis rubber cystoblast, is vacuum dried 24 hours, obtains appearance uniform
Thermochromic layer-antibiosis rubber cystoblast-photosensitive microballoon layer, i.e. antibacterial discoloration composite film.
Further, the thickness of the thermochromic layer is 10~100nm；The thickness of the antibiosis rubber cystoblast be 50~
60nm；The thickness of the photosensitive microballoon layer is 10~100nm.
Used as another embodiment of the presently claimed invention, the antibacterial discoloration composite film also includes one layer of light-absorption layer, described
Light-absorption layer is painted on the top of the photosensitive microballoon layer 14.
Photic phenomenon to energy-conserving and environment-protective corrugated sheet of the present invention is detected：
1. the detection of Ultraluminescence is carried out, is detected using the uviol lamp on cash inspecting machine.
2. sunlight, Indoor Natural light are used.
The photic experimental result of table 2
| Type of wavelength | Color |
| Dark condition | Pink |
| Sunlight irradiates | Purple |
| Indoor conditions | Lilac |
| Uviol lamp | It is red |
Energy-conserving and environment-protective corrugated sheet of the present invention shows pink under the conditions of darkness, photosensitive micro- under sunlight irradiation
Layers of balls color is changed, and shows purple, and lilac is showed in room conditions.Under ultra violet lamp, color is red.
Further, the Reversible temperature denaturation to energy-conserving and environment-protective corrugated sheet of the present invention is detected：
Directly the hot water of uniform temperature is splashed on energy-conserving and environment-protective corrugated sheet of the present invention, section of the present invention
Can the color of environmentally friendly corrugated sheet change at once, be changed into very shallow blue or almost colourless from navy blue, then soon
Return to initial navy blue.This detection method is very convenient, just can be not only fast but also directly perceived as long as being splashed with hot water at one's side
Detect, significantly facilitate the detection of the energy-conserving and environment-protective corrugated sheet of the present invention, widened its range of application.
The thermic experimental result of table 2
In 65 DEG C~68 DEG C of temperature, color change is most obvious, is changed into very shallow blue or almost colourless from blueness, becomes
Chromatic sensitivity is very high, runs into the hot water that temperature reaches more than minimum temperature and changes colour at once, and recovery time section, about 4s is then restored to just
Beginning color.
Finally it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than the present invention is protected
The limitation of scope is protected, although being explained to the present invention with reference to preferred embodiment, one of ordinary skill in the art should
Work as understanding, technical scheme can be modified or equivalent, without deviating from the reality of technical solution of the present invention
Matter and scope.
Claims (10)
1. a kind of energy saving and environment friendly corrugated sheet, it is characterised in that including PVC corrugated layers, interlayer and PVC board；The PVC corrugated layers
Turn into an entirety by the way that interlayer and the PVC board are compound；The PVC corrugated layers include a PVC corrugated layers and the 2nd PVC watts
Stupefied layer, the interlayer includes the first interlayer and the second interlayer, and the PVC board includes the first PVC board and the second PVC board；Described
One PVC corrugated layers are compound with first PVC board by first interlayer；First PVC board and the 2nd PVC corrugations
Cushion is filled between layer, the 2nd PVC corrugated layers are compound with second PVC board by second interlayer；It is described
First PVC corrugation layer surfaces are laid with antibacterial discoloration composite film.
2. a kind of energy saving and environment friendly corrugated sheet according to claim 1, it is characterised in that the interlayer is polystyrene material
Material and/or Desmocoll material.
3. a kind of energy-conserving and environment-protective corrugated sheet according to claim 1, it is characterised in that first interlayer is polystyrene
Material, second interlayer is Desmocoll material.
4. a kind of year energy-conserving and environment-protective corrugated sheet according to claim 3, it is characterised in that first interlayer and described
Two interlayers are Desmocoll material or first interlayer and second interlayer to be polystyrene material
Material.
5. a kind of energy-conserving and environment-protective corrugated sheet according to claim 4, it is characterised in that the thickness of first interlayer is 2
~5cm；The thickness of second interlayer is 2~5cm.
6. a kind of energy-conserving and environment-protective corrugated sheet according to claim 1, it is characterised in that described antibacterial discoloration composite film
It is respectively from bottom to top along its thickness direction：Substrate layer, aluminium lamination, thermochromic layer, antibiosis rubber cystoblast and photosensitive microballoon discoloration layer；
Substrate layer supports other each layers, and the intensity that aluminium lamination strengthens light makes image more become clear, and metallic luster is presented, and thermic discoloration layer makes to resist
There is thermochromism in bacterium discoloration composite film, antibiosis rubber cystoblast stops that bacterium enters antibacterial discoloration composite film, photosensitive microballoon color
Change layer makes antibacterial discoloration composite film that Ultraluminescence discoloration to occur.
7. a kind of energy saving and environment friendly corrugated sheet according to claim 1, it is characterised in that the system of antibacterial discoloration composite film
Standby process is as follows：The aluminium coated on substrate layer, coats thermochromic material layer, the upper coated antibacterial of thermochromic material layer on aluminium lamination
Capsule layer, is coated with photosensitive microballoon layer on antibiosis rubber cystoblast, the another side of substrate layer applies transfer glue-line, and glue-line causes the antibacterial discoloration
Composite film is pasted on energy-conserving and environment-protective corrugated sheet.
8. a kind of energy saving and environment friendly corrugated sheet according to claim 7, it is characterised in that described antibacterial discoloration composite membrane
The preparation method of layer is as follows：
Step one, the preparation of thermochromic material：It is 350 according to mass ratio:2.3:4:40:80 weigh butanone, ultraviolet glimmering respectively
Light powder, bisphenol-A, crystal violet lactone, granules of polystyrene, sequentially add in flask in the order described above at 25 ± 5 DEG C, form equal
Even liquid, stirs 3 hours, and the content of ultraviolet fluorescence powder is the 0.15% of whole temperature changing resin, the uniform liquid material that will be formed；
Step 2, the preparation of antibacterial capsule material：500ml deionized waters are added in separatory funnel, 3g urea is weighed and 3.0g is poly-
Vinylpyrrolidone (PVP) is added in above-mentioned separatory funnel, adds 1.5g NaCl, after concussion 10min, uses long-neck dropper
AgNO is slowly added dropwise to it3Solution, after concussion 10min, is added dropwise a certain amount of titania solution liquid, adds appropriate sulfuric acid
Zinc solution, is cooled to room temperature after 80 DEG C of water-bath 3h, add 5ml disodium phosphate solns, shakes 30min；Add the anhydrous second of 10ml
Alcohol shakes 30min；With traditional vacuum, precipitation is successively with distilled water, acid solution, absolute ethanol washing；Precipitation is put into electric heating air blast and does
Dry case is dried；By dry powder it is ground be made after loose powder to be put into Muffle furnace be calcined, be down to room naturally after terminating
Temperature；Ground after calcination can be prepared by nano-antibacterial capsule material；
Step 3, the preparation of photosensitive micro-sphere material：A certain amount of styrene monomer is dissolved into absolute ethyl alcohol and water mixed solution,
60 DEG C are heated to, constant temperature keeps 30min, are again heated to 90 DEG C, constant temperature keeps 30min, PVP is fully dissolved, and is subsequently adding
Metabisulfite solution, reacts 5h, and reaction is centrifuged after terminating, and polystyrene microsphere is obtained after drying；Wherein, absolute ethyl alcohol
It is 60 with the volume ratio of water:40；Weigh a certain amount of polystyrene microsphere and be added to certain density phthalic acid anhydride solution
In, nitrogen protection adds alchlor, 55 DEG C of reaction 12h surface-modified polystyrene microspheres to be obtained, by surface while stirring
Modified polystyrene spheres carry out absorption 12h in being put into spiro-pyrans ethanol solution, are then centrifuged for separating, prepared photosensitive micro- through drying
Ball, obtained photosensitive microballoon is added in certain density polyvinyl alcohol (PVA) solution and soaks 24h, and centrifugation is rearmounted
Disperse in absolute ethyl alcohol, centrifugation, dry, dried PVA@polyethylene microballoons are put into tin ash solution and are soaked
48h, then 80 DEG C are drying to obtain；
Step 4, antibacterial discoloration is combined film preparation：
First, according to step 2:1:2 mass ratio claims to take respectively in right amount via the thermochromic material prepared by step one, step
The photosensitive micro-sphere material prepared by antibacterial capsule material and step 3 prepared by two；
Second, thermochromic material is dissolved in butanone solution, formed uniform liquid A, stirring 90 minutes it is standby；
3rd, antibacterial capsule material is dissolved in butanone solution, formed uniform liquid B, stirring 120 minutes it is standby；
4th, photosensitive micro-sphere material is dissolved in toluene solution, formed uniform liquid C, stirring 180 minutes it is standby；
5th, by liquid A coating, simultaneously natural film forming on aluminium lamination, is dried 8 hours in negative pressure 0.1~0.5MPa vacuum drying chambers,
Obtain the thermochromic layer of appearance uniform；
6th, by liquid B coating, simultaneously natural film forming on thermochromic layer, is dried in negative pressure 0.2~0.3MPa vacuum drying chambers
10 hours, irradiated 2 hours as under 60Co rays after taking-up, obtain the thermochromic layer-antibiosis rubber cystoblast of appearance uniform；
7th, by liquid C coatings, simultaneously natural film forming on antibiosis rubber cystoblast, is vacuum dried 24 hours, obtains the heat of appearance uniform
Mutagens chromatograph-antibiosis rubber cystoblast-photosensitive microballoon layer, i.e. antibacterial discoloration composite film.
9. a kind of energy saving and environment friendly corrugated sheet according to claim 8, it is characterised in that the thickness of the thermochromic layer
It is 10~100nm；The thickness of the antibiosis rubber cystoblast is 50~60nm；The thickness of the photosensitive microballoon layer is 10~100nm.
10. a kind of energy-conserving and environment-protective corrugated sheet according to claim 6, it is characterised in that the antibacterial discoloration composite film
Also include one layer of light-absorption layer, the light-absorption layer is painted on the photosensitive microballoon layer top.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5842315A (en) * | 1997-03-24 | 1998-12-01 | Tung Yik Trading Co., Ltd. | Corrugated board structure |
| CN202039509U (en) * | 2011-04-27 | 2011-11-16 | 海盐宝仕龙塑业有限公司 | PVC (polyvinyl chloride) corrugated board |
| CN104527145A (en) * | 2015-01-13 | 2015-04-22 | 正业包装（中山）有限公司 | High-strength and high-pressure-resistance composite paperboard |
-
2017
- 2017-03-06 CN CN201710129290.3A patent/CN106915133B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5842315A (en) * | 1997-03-24 | 1998-12-01 | Tung Yik Trading Co., Ltd. | Corrugated board structure |
| CN202039509U (en) * | 2011-04-27 | 2011-11-16 | 海盐宝仕龙塑业有限公司 | PVC (polyvinyl chloride) corrugated board |
| CN104527145A (en) * | 2015-01-13 | 2015-04-22 | 正业包装（中山）有限公司 | High-strength and high-pressure-resistance composite paperboard |
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