CN106910957A - A kind of secondary utilization lead-acid batteries screening technique - Google Patents

A kind of secondary utilization lead-acid batteries screening technique Download PDF

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Publication number
CN106910957A
CN106910957A CN201710048590.9A CN201710048590A CN106910957A CN 106910957 A CN106910957 A CN 106910957A CN 201710048590 A CN201710048590 A CN 201710048590A CN 106910957 A CN106910957 A CN 106910957A
Authority
CN
China
Prior art keywords
lead
secondary utilization
open
circuit voltage
internal resistance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710048590.9A
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Chinese (zh)
Inventor
贾蕗路
裴锋
刘欣
田旭
李财芳
毛荣军
陈丽勤
周宁
程正
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
State Grid Corp of China SGCC
Electric Power Research Institute of State Grid Jiangxi Electric Power Co Ltd
Original Assignee
State Grid Corp of China SGCC
Electric Power Research Institute of State Grid Jiangxi Electric Power Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by State Grid Corp of China SGCC, Electric Power Research Institute of State Grid Jiangxi Electric Power Co Ltd filed Critical State Grid Corp of China SGCC
Priority to CN201710048590.9A priority Critical patent/CN106910957A/en
Publication of CN106910957A publication Critical patent/CN106910957A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/54Reclaiming serviceable parts of waste accumulators
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B07SEPARATING SOLIDS FROM SOLIDS; SORTING
    • B07CPOSTAL SORTING; SORTING INDIVIDUAL ARTICLES, OR BULK MATERIAL FIT TO BE SORTED PIECE-MEAL, e.g. BY PICKING
    • B07C5/00Sorting according to a characteristic or feature of the articles or material being sorted, e.g. by control effected by devices which detect or measure such characteristic or feature; Sorting by manually actuated devices, e.g. switches
    • B07C5/34Sorting according to other particular properties
    • B07C5/344Sorting according to other particular properties according to electric or electromagnetic properties
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/84Recycling of batteries or fuel cells

Abstract

A kind of secondary utilization lead-acid batteries screening technique, comprises the following steps:(1)Charged using lead-acid batteries to secondary, make its state-of-charge SOC be 60% 80%;(2)The open-circuit voltage of each cell of detection and internal resistance;(3)Above-mentioned secondary utilization lead-acid accumulator monomer is in parallel, until its open-circuit voltage is essentially identical, with it is in parallel before cell open-circuit voltage contrast, and recording voltage lifting situation;Then secondary utilization lead-acid accumulator and standard cell are shelved 24 hours under the conditions of temperature is for 25 DEG C ± 5 DEG C, detects its open-circuit voltage and internal resistance;(4)Secondary utilization lead-acid accumulator monomer show, open-circuit voltage, internal resistance, voltage drop and health status are contrasted, is classified using lead-acid accumulator monomer to secondary, used cooperatively with the battery pack and energy storage power network or general back-up source of one-level.The inventive method is simple, improves the utilization rate of lead-acid accumulator;Secondary utilization lead-acid accumulator Large-scale Screening classified utilization can be realized.

Description

A kind of secondary utilization lead-acid batteries screening technique
Technical field
The present invention relates to a kind of secondary utilization lead-acid batteries screening technique, category battery technology field.
Background technology
Secondary utilization lead-acid accumulator refers to not completely lose value and complete appearance but performance have been unsatisfactory for original and have made With requiring, while holding structure is intact, the lead-acid accumulator recycled after collecting, detecting or repair.Secondary utilization lead Acid accumulator has particularity, has both been different from new battery, and the battery for scrapping recovery is different from again, in battery life cycle management Interlude.
Major part moves back the lead-acid accumulator of fortune, and residual capacity is up to 80%, by these battery applications in energy-accumulating power station or general Back-up source has economic worth and social value very high, but the health status of these batteries is uneven, it is necessary to carry out Strict screening, secondary utilization could ensure its performance.
The content of the invention
It is an object of the present invention in order to solve above-mentioned problem, disclose a kind of secondary utilization lead-acid batteries Screening technique.
Realize the technical scheme is that, a kind of secondary utilization lead-acid batteries screening technique, step is as follows:
(1)Charged using lead-acid batteries to secondary, make its state-of-charge SOC be 60%-80%;Then battery is taken apart Group, is checked secondary, and record using lead-acid batteries and cell outward appearance.
(2)The open-circuit voltage of each cell of detection and internal resistance are simultaneously recorded, and with the open circuit electricity of standard cell Pressure, internal resistance contrast;By voltage, the internal resistance tested according to standard cell charging and discharging curve, secondary utilization lead acid storage battery is assessed Pond group cell capacity.
(3)Above-mentioned secondary utilization lead-acid accumulator monomer is in parallel, until its open-circuit voltage is essentially identical, with it is in parallel before it is single The open-circuit voltage contrast of body battery, and recording voltage lifting situation.Then by secondary utilization lead-acid accumulator and standard monomer electricity Pond is shelved 24 hours under the conditions of being 25 DEG C ± 5 DEG C in temperature, detects its open-circuit voltage and internal resistance, and record.Standard cell Discharge cycles test is done, using standard cell state-of-charge, capacitance-voltage curves, internal resistance as reference, according to secondary utilization Lead-acid accumulator monomer open-circuit voltage and internal resistance size, assess secondary utilization lead-acid accumulator monomer health status.
(4)According to above record case, secondary utilization lead-acid accumulator monomer show, open-circuit voltage, internal resistance, voltage are contrasted Drop and health state evaluation, be classified using lead-acid accumulator monomer to secondary, with one-level battery in groups with energy storage power network Or general back-up source is used cooperatively.If having battery can not carry out discharge and recharge, it can be carried out to scrap treatment.
Described standard cell refer to it is identical with the cell of secondary utilization lead-acid batteries, including it is inherent just The raw material ratio of negative material, electrolyte, barrier film etc., composition and manufacture craft, do cycle performance survey on charging/discharging apparatus Examination, makes that its capacity drops to the percentage of rated capacity and the capacity of secondary utilization lead-acid batteries drops to rated capacity Percentage is identical.And make its state-of-charge identical with secondary utilization lead-acid batteries.
The beneficial effects of the invention are as follows the present invention provides a kind of secondary utilization lead-acid batteries screening technique, using electricity Pond attribute in itself(Voltage, internal resistance, voltage drop)Contrasted with standard cell, be classified, can in groups, with storage with the battery of one-level Energy power network or general back-up source are used cooperatively.The rate that maximally utilizes of lead-acid accumulator is realized, and method, step are simple;Drop Low energy-storage battery use cost;Secondary utilization lead-acid accumulator Large-scale Screening classification is capable of achieving, energy saving promotes the well-being of mankind.
Specific embodiment
Embodiment 1:
A kind of secondary utilization lead-acid batteries screening technique of the present embodiment, comprises the following steps:
1st, charged using lead-acid batteries to secondary, make its state-of-charge SOC be 80%.Then battery pack is taken apart, to two It is secondary to be checked using lead-acid batteries and cell outward appearance, and record.
2nd, detect the open-circuit voltage of each cell and internal resistance and record, and with the open circuit electricity of standard cell Pressure, internal resistance contrast.By voltage, the internal resistance tested according to standard cell charging and discharging curve, secondary utilization lead acid storage battery is assessed Pond group cell capacity.
3rd, it is above-mentioned secondary utilization lead-acid accumulator monomer is in parallel, until its open-circuit voltage is essentially identical, with it is in parallel before it is single The open-circuit voltage contrast of body battery, and recording voltage lifting situation.Then by secondary utilization lead-acid accumulator and standard monomer electricity Pond is shelved 24 hours under the conditions of being 25 DEG C in temperature, detects its open-circuit voltage and internal resistance, and record.Standard cell does and discharges Loop test, using standard cell state-of-charge, capacitance-voltage curves, internal resistance as reference, stores according to secondary utilization plumbic acid Battery cell open-circuit voltage and internal resistance size, assess secondary utilization lead-acid accumulator monomer health status.
4th, according to above record case, secondary utilization lead-acid accumulator monomer show, open-circuit voltage, internal resistance, voltage are contrasted Drop and health state evaluation, be classified using lead-acid accumulator monomer to secondary, with one-level battery in groups with energy storage power network Or general back-up source is used cooperatively.If having battery can not carry out discharge and recharge, it can be carried out to scrap treatment.
Embodiment 2
A kind of secondary utilization lead-acid batteries screening technique of the present embodiment, comprises the following steps:
1st, charged using lead-acid batteries to secondary, make its state-of-charge SOC be 65%.Then battery pack is taken apart, to two It is secondary to be checked using lead-acid batteries and cell outward appearance, and record.
2nd, detect the open-circuit voltage of each cell and internal resistance and record, and with the open circuit electricity of standard cell Pressure, internal resistance contrast.By voltage, the internal resistance tested according to standard cell charging and discharging curve, secondary utilization lead acid storage battery is assessed Pond group cell capacity.
3rd, it is above-mentioned secondary utilization lead-acid accumulator monomer is in parallel, until its open-circuit voltage is essentially identical, with it is in parallel before it is single The open-circuit voltage contrast of body battery, and recording voltage lifting situation.Then by secondary utilization lead-acid accumulator and standard monomer electricity Pond is shelved 24 hours under the conditions of being 20 DEG C in temperature, detects its open-circuit voltage and internal resistance, and record.Standard cell does and discharges Loop test, using standard cell state-of-charge, capacitance-voltage curves, internal resistance as reference, stores according to secondary utilization plumbic acid Battery cell open-circuit voltage and internal resistance size, assess secondary utilization lead-acid accumulator monomer health status.
4th, according to above record case, secondary utilization lead-acid accumulator monomer show, open-circuit voltage, internal resistance, voltage are contrasted Drop and health state evaluation, be classified using lead-acid accumulator monomer to secondary, with one-level battery in groups with energy storage power network Or general back-up source is used cooperatively.If having battery can not carry out discharge and recharge, it can be carried out to scrap treatment.

Claims (2)

1. a kind of secondary utilization lead-acid batteries screening technique, it is characterised in that be the step of methods described:
(1)Charged using lead-acid batteries to secondary, make its state-of-charge SOC be 60%-80%;Then battery is taken apart Group, is checked secondary, and record using lead-acid batteries and cell outward appearance;
(2)The open-circuit voltage of each cell of detection and internal resistance, and record;It is open-circuit voltage with standard cell, interior Resistance contrast;By voltage, the internal resistance tested according to standard cell charging and discharging curve, secondary utilization lead-acid batteries list is assessed Body battery capacity;
(3)Above-mentioned secondary utilization lead-acid accumulator monomer is in parallel, until its open-circuit voltage is essentially identical, with it is in parallel before monomer electricity The open-circuit voltage contrast in pond, and recording voltage lifting situation;Then secondary utilization lead-acid accumulator and standard cell are existed Temperature detects its open-circuit voltage and internal resistance, and record to be shelved 24 hours under the conditions of 25 DEG C ± 5 DEG C;Standard cell is put Electric loop test, using standard cell state-of-charge, capacitance-voltage curves, internal resistance as reference, according to secondary utilization plumbic acid Single battery open-circuit voltage and internal resistance size, assess secondary utilization lead-acid accumulator monomer health status;
(4)According to above record case, contrast secondary utilization lead-acid accumulator monomer show, open-circuit voltage, internal resistance, voltage drop and Health state evaluation, is classified to secondary using lead-acid accumulator monomer, with one-level battery in groups with energy storage power network or one As back-up source use cooperatively.
2. a kind of secondary utilization lead-acid batteries screening technique according to claim 1, it is characterised in that the standard Cell refer to positive and negative pole material identical with the cell of secondary utilization lead-acid batteries including inherent, electrolyte, every The raw material ratio of film etc., composition and manufacture craft, do cycle performance test on charging/discharging apparatus, its capacity is dropped to volume The percentage of constant volume is identical with the percentage that the capacity of secondary utilization lead-acid batteries drops to rated capacity;And make its lotus Electricity condition is identical with secondary utilization lead-acid batteries.
CN201710048590.9A 2017-01-23 2017-01-23 A kind of secondary utilization lead-acid batteries screening technique Pending CN106910957A (en)

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CN106910957A true CN106910957A (en) 2017-06-30

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108550893A (en) * 2018-05-09 2018-09-18 江苏海四达电源股份有限公司 Method for group matching for ferric phosphate lithium cell
CN109078871A (en) * 2018-07-12 2018-12-25 深圳大学 A kind of elimination method of the retired battery parallel module utilized towards echelon
CN109759354A (en) * 2018-12-25 2019-05-17 天能电池集团有限公司 One kind retracting battery and shunts screening technique
CN113488703A (en) * 2021-07-01 2021-10-08 国网河北省电力有限公司电力科学研究院 Method for activating and recycling retired lead-acid storage battery

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103337671A (en) * 2013-06-27 2013-10-02 国家电网公司 Cascade utilization screening method of waste power batteries
CN103346358A (en) * 2013-06-25 2013-10-09 奇瑞汽车股份有限公司 Grouping method of lead-acid battery
CN103594742A (en) * 2013-11-22 2014-02-19 天能电池集团有限公司 Sorting and grouping method for power lead-acid storage battery set
CN105428734A (en) * 2015-12-21 2016-03-23 中盐安徽红四方锂电有限公司 Matching method for electric vehicle power batteries

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103346358A (en) * 2013-06-25 2013-10-09 奇瑞汽车股份有限公司 Grouping method of lead-acid battery
CN103337671A (en) * 2013-06-27 2013-10-02 国家电网公司 Cascade utilization screening method of waste power batteries
CN103594742A (en) * 2013-11-22 2014-02-19 天能电池集团有限公司 Sorting and grouping method for power lead-acid storage battery set
CN105428734A (en) * 2015-12-21 2016-03-23 中盐安徽红四方锂电有限公司 Matching method for electric vehicle power batteries

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108550893A (en) * 2018-05-09 2018-09-18 江苏海四达电源股份有限公司 Method for group matching for ferric phosphate lithium cell
CN108550893B (en) * 2018-05-09 2020-06-16 南通隆力电子科技有限公司 Matching method for lithium iron phosphate battery
CN109078871A (en) * 2018-07-12 2018-12-25 深圳大学 A kind of elimination method of the retired battery parallel module utilized towards echelon
CN109759354A (en) * 2018-12-25 2019-05-17 天能电池集团有限公司 One kind retracting battery and shunts screening technique
CN113488703A (en) * 2021-07-01 2021-10-08 国网河北省电力有限公司电力科学研究院 Method for activating and recycling retired lead-acid storage battery
CN113488703B (en) * 2021-07-01 2022-10-21 国网河北省电力有限公司电力科学研究院 Method for activating and recycling retired lead-acid storage battery

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