CN106906927A - A kind of curtain wall for building - Google Patents

A kind of curtain wall for building Download PDF

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Publication number
CN106906927A
CN106906927A CN201710218724.7A CN201710218724A CN106906927A CN 106906927 A CN106906927 A CN 106906927A CN 201710218724 A CN201710218724 A CN 201710218724A CN 106906927 A CN106906927 A CN 106906927A
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curtain wall
parts
temperature
copper alloy
stage
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CN201710218724.7A
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CN106906927B (en
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陈利
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Shenzhen Gasu Adorn Design Engineering Co., Ltd.
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陈利
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Priority to CN201811303784.XA priority patent/CN109267678B/en
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    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B2/00—Walls, e.g. partitions, for buildings; Wall construction with regard to insulation; Connections specially adapted to walls
    • E04B2/88—Curtain walls
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • C04B28/32—Magnesium oxychloride cements, e.g. Sorel cement
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C9/00—Alloys based on copper
    • C22C9/05—Alloys based on copper with manganese as the next major constituent
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/08—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of copper or alloys based thereon
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • C04B2201/32—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

Abstract

A kind of curtain wall for building, including cement base insulation inner plating and the curtain wall metal outer plate being pasted on outside cement base insulation inner plating, curtain wall metal outer plate is coated with antirust agent, copper alloy plate of the present invention has intensity high as curtain wall outer layer, hardness is high, thermal conductivity is good, service life extension when this allows for it as curtain wall alien invasion, do not allow fragile, reduce maintenance cost and maintenance load, copper alloy surface antirust agent of the present invention, copper alloy surface antirust agent is quickly forming a nanometer protective layer in copper alloy surface, and after metal surface forms nanometer protective layer, make matrix that there is excellent Corrosion Protection, and environmental pollution is small, will not skin ambustion when using, it is harmless, it is safe and reliable, it is easily operated.

Description

A kind of curtain wall for building
Technical field
The present invention relates to a kind of curtain wall for building, belongs to curtain wall field.
Background technology
Curtain wall is the exterior wall pad of building, and not load-bearing hangs up as curtain, therefore is also called suspension wall, is modern The Light Wall with decorative effect that large-scale and skyscraper is commonly used.It is made up of with sheet material is inlayed structural framing, does not undertake master Body structural loads and the architectural exterior-protecting construction for acting on.At present both at home and abroad traditional curtain wall be mainly stone curtain wall, glass curtain wall and Metal curtain wall, these three curtain walls can meet the basic decoration demand of industry and civil buildings substantially.But these three curtain walls are by certainly There is very big hidden danger and shortcoming in the limitation of body material property：Stone curtain wall weight is big, energy consumption big, it is poor to prevent fires；Glass curtain Wall energy consumption is big, light pollution serious, it is poor to prevent fires；Exclusive use metal curtain wall weatherability is poor, and heat-insulating property and intensity are relatively low.
The content of the invention
In order to solve the problems, such as curtain wall in the prior art, a kind of curtain for building of offer of the invention Wall, to solve above-mentioned technical problem.
A kind of curtain wall for building, including cement base insulation inner plating and the curtain wall gold being pasted on outside cement base insulation inner plating Category lamina rara externa, curtain wall metal outer plate is coated with antirust agent,
100 parts of mass parts cement, glass bead 80-120 parts, sand 100-130 parts, magnesia 30-40 parts, higher ridge are weighed first It is native 25-30 parts, it is magnesium chloride 15-20 parts, aerosil 5-9 parts, xanthans 3-5 parts, calcium lignosulfonate 2-7 parts, fine Plain 2-4 part of the ether of dimension, after water 40-60 part is well mixed, be molded and obtains cement base and be incubated inner plating,
Curtain wall metal outer plate is copper alloy plate, its manufacturing process：Got the raw materials ready according to proportioning, raw material is carried out into melting, melting 1090-1100 DEG C of temperature, after melting pour into a mould obtaining casting, is 750-770 DEG C by casting heating-up temperature, 20-30 points of insulation Clock, carries out first stage rolling afterwards, and first stage start rolling temperature is 750-770 DEG C, and single pass reduction ratio is in 6~8%, rolling Speed is 0.2-0.3m/s, and 710-730 DEG C of first stage finishing temperature, slab thickness reaches 10-15mm, then adds slab Heat is incubated 10-15 minutes to 870-890 DEG C, and second stage rolling is carried out afterwards, and second stage start rolling temperature is 870-890 DEG C, In 14-20%, mill speed is 0.5-0.7m/s, 820-830 DEG C of second stage finishing temperature, slab thickness to single pass reduction ratio 4-6mm is reached, then by slab at 810-830 DEG C, 10-20 minutes is incubated, phase III rolling, phase III are carried out afterwards Start rolling temperature is 810-830 DEG C, and in 10-12%, mill speed is 0.4-0.6m/s, phase III finish to gauge temperature to single pass reduction ratio 760-780 DEG C of degree, naturally cools to room temperature, and slab thickness reaches 1-2mm, and slab is reheated into 560-600 DEG C, insulation 40-50 minutes, slab is cut according to required size then, obtain curtain wall metal outer plate, curtain wall metal outer plate patch Cement base insulation inner plating outside is spread on, copper alloy is constituted including following element weight/mass percentage composition：Mn 5-6%, Mg 3-4%, Ni 2-4%, Zr 0.8-1%, Sn 0.6-0.7%, Zn 0.2-0.3%, V 0.07-0.08%, Ti 0.07-0.08%, Ce0.05- 0.06%, balance of Cu, by copper alloy surface antirust agent uniform application in curtain wall metal outer plate surface, stand 24 hours, obtain Present invention curtain wall for building.
Preferably, described curtain wall a kind of for building, first stage start rolling temperature is 765 DEG C, and single pass reduction ratio is 6 ~8%, mill speed is 0.2m/s, 710 DEG C of first stage finishing temperature,
Preferably, described curtain wall a kind of for building, second stage start rolling temperature is 880 DEG C, and single pass reduction ratio is in 14- 20%, mill speed is 0.5-0.7m/s, 820 DEG C of second stage finishing temperature.
Preferably, described curtain wall a kind of for building, phase III start rolling temperature is 810 DEG C, and single pass reduction ratio exists 10-12%, mill speed is 0.4-0.6m/s, 760 DEG C of phase III finishing temperature.
Preferably, described curtain wall a kind of for building, antirust agent preparation method：Vinyltrimethoxy silane is heated To 40-45 DEG C, the mixed solution of tetrabutyl titanate and ethanol is added, stirred with the mixing speed of 200r/min, then protected It is warm 20-25 minutes, add triethanolamine oleate to be well mixed, regulation PH is 8~9, adds phthalic acid ester and isomery alcohol poly- Oxygen vinethene is well mixed with the mixing speed of 300r/min, and 30-40 minutes is incubated at 50-55 DEG C, obtains copper alloy surface and prevents Rust agent.
Preferably, described curtain wall a kind of for building, antirust agent preparation method：Vinyltrimethoxy silane is heated To 42 DEG C, the mixed solution of tetrabutyl titanate and ethanol is added, stirred with the mixing speed of 200r/min, be then incubated 25 Minute, add triethanolamine oleate to be well mixed, regulation PH is 8~9, adds phthalic acid ester and isomeric alcohol polyethenoxy ether It is well mixed with the mixing speed of 300r/min, 35 minutes are incubated at 55 DEG C, obtain copper alloy surface antirust agent.
Preferably, described curtain wall a kind of for building, vinyltrimethoxy silane：Tetrabutyl titanate：Ethanol：Oleic acid Triethanolamine：Phthalic acid ester：Isomeric alcohol polyethenoxy ether mass ratio 2-4：1-2：5-7：0.5-0.8：0.2-0.3：0.05- 0.1。
A kind of manufacture method of curtain wall for building, curtain wall for building includes cement base insulation inner plating and is pasted on cement base Curtain wall metal outer plate outside insulation inner plating, curtain wall metal outer plate is coated with antirust agent,
100 parts of cement, glass bead 80-120 parts, sand 100-130 parts, magnesia 30-40 parts, metakaolin 25- are weighed first 30 parts, magnesium chloride 15-20 parts, aerosil 5-9 parts, xanthans 3-5 parts, calcium lignosulfonate 2-7 parts, cellulose ether 2-4 parts, after water 40-60 parts is well mixed, be molded and obtain cement base insulation inner plating,
Curtain wall metal outer plate is copper alloy plate, its manufacturing process：Got the raw materials ready according to proportioning, raw material is carried out into melting, melting 1090-1100 DEG C of temperature, after melting pour into a mould obtaining casting, is 750-770 DEG C by casting heating-up temperature, 20-30 points of insulation Clock, carries out first stage rolling afterwards, and first stage start rolling temperature is 750-770 DEG C, and single pass reduction ratio is in 6~8%, rolling Speed is 0.2-0.3m/s, and 710-730 DEG C of first stage finishing temperature, slab thickness reaches 10-15mm, then adds slab Heat is incubated 10-15 minutes to 870-890 DEG C, and second stage rolling is carried out afterwards, and second stage start rolling temperature is 870-890 DEG C, In 14-20%, mill speed is 0.5-0.7m/s, 820-830 DEG C of second stage finishing temperature, slab thickness to single pass reduction ratio 4-6mm is reached, then by slab at 810-830 DEG C, 10-20 minutes is incubated, phase III rolling, phase III are carried out afterwards Start rolling temperature is 810-830 DEG C, and in 10-12%, mill speed is 0.4-0.6m/s, phase III finish to gauge temperature to single pass reduction ratio 760-780 DEG C of degree, naturally cools to room temperature, and slab thickness reaches 1-2mm, and slab is reheated into 560-600 DEG C, insulation 40-50 minutes, slab is cut according to required size then, obtain curtain wall metal outer plate, curtain wall metal outer plate patch Cement base insulation inner plating outside is spread on, copper alloy is constituted including following element weight/mass percentage composition：Mn 5-6%, Mg 3-4%, Ni 2-4%, Zr 0.8-1%, Sn 0.6-0.7%, Zn 0.2-0.3%, V 0.07-0.08%, Ti 0.07-0.08%, Ce0.05- 0.06%, balance of Cu, by copper alloy surface antirust agent uniform application in curtain wall metal outer plate surface, stand 24 hours, obtain Present invention curtain wall for building.
Preferably, the manufacture method of described curtain wall a kind of for building, first stage start rolling temperature is 765 DEG C, single track 6~8%, mill speed is 0.2m/s to secondary reduction ratio, 710 DEG C of first stage finishing temperature,
Preferably, the manufacture method of described curtain wall a kind of for building, second stage start rolling temperature is 880 DEG C, single pass pressure In 14-20%, mill speed is 0.5-0.7m/s, 820 DEG C of second stage finishing temperature to lower rate.
Preferably, the manufacture method of described curtain wall a kind of for building, phase III start rolling temperature is 810 DEG C, single track In 10-12%, mill speed is 0.4-0.6m/s, 760 DEG C of phase III finishing temperature to secondary reduction ratio.
Preferably, the manufacture method of described curtain wall a kind of for building, copper alloy surface antirust agent preparation method：By second Alkenyl trimethoxy silane is heated to 40-45 DEG C, the mixed solution of tetrabutyl titanate and ethanol is added, with the stirring of 200r/min Speed stirs, then insulation 20-25 minutes, adds triethanolamine oleate to be well mixed, and regulation PH is 8~9, adds adjacent benzene Dicarboxylic acid esters and isomeric alcohol polyethenoxy ether are well mixed with the mixing speed of 300r/min, and 30-40 points is incubated at 50-55 DEG C Clock, obtains copper alloy surface antirust agent.
Preferably, the manufacture method of described curtain wall a kind of for building, copper alloy surface antirust agent antirust agent preparation side Method：Vinyltrimethoxy silane is heated to 42 DEG C, the mixed solution of tetrabutyl titanate and ethanol is added, with 200r/min's Mixing speed stirs, then insulation 25 minutes, adds triethanolamine oleate to be well mixed, and regulation PH is 8~9, adds adjacent Phthalic acid ester and isomeric alcohol polyethenoxy ether are well mixed with the mixing speed of 300r/min, and 35 minutes are incubated at 55 DEG C, obtain To copper alloy surface antirust agent.
Preferably, the manufacture method of described curtain wall a kind of for building, vinyltrimethoxy silane：The positive fourth of metatitanic acid Ester：Ethanol：Triethanolamine oleate：Phthalic acid ester：Isomeric alcohol polyethenoxy ether mass ratio 2-4：1-2：5-7：0.5-0.8： 0.2-0.3：0.05-0.1.
A side surface is coated with copper alloy surface antirust agent to curtain wall metal outer plate outwardly.
Curtain wall metal outer plate, can be to curtain wall metal outer plate court before being pasted on the outside of cement base insulation inner plating Outer and inward faces are coated with copper alloy surface antirust agent, carry out curtain wall metal outer plate again afterwards and are pasted on cement base insulation Operation on the outside of inner plating.
Copper alloy of the present invention is by adding the high temperature, normal temperature plasticity and intergranular knot that Mn, Mg, Ni, Zr of specified quantitative improve With joint efforts, it is possible to refined crystal grain, the elements such as Ti, V, Ce are added and forms intermetallic compound with copper, changed microstructure, improve Machining property, so that alloy has good mechanical performance.The present invention uses three stage rolling techniques+Technology for Heating Processing So that there is copper alloy plate hardness to reach 90~110HB, tensile strength reaches 280~310MPa, and elongation percentage reaches 18~25%, Control crystal grain is reached by open rolling finishing temperature in three stage rolling techniques of control and single pass reduction ratio and mill speed to grow up, Degraded in mechanical properties is prevented, copper alloy plate of the present invention has intensity high as curtain wall outer layer, and hardness is high, and thermal conductivity is good, and this is just So that service life extension when it is as curtain wall alien invasion, it is not easy to damage, reduce maintenance cost and maintenance load, this hair Bright copper alloy surface antirust agent, copper alloy surface antirust agent in copper alloy surface quickly forming a nanometer protective layer, and metal watch After face forms nanometer protective layer, make matrix that there is excellent Corrosion Protection, and environmental pollution is small, will not be burnt when using Skin, it is harmless, it is safe and reliable, it is easy to operate.Cement base insulation inner plating of the present invention has intensity heat insulating ability higher, protects Demonstrate,prove the bulk life time and heat-insulating property of curtain wall.
Specific embodiment
Embodiment 1
A kind of curtain wall for building, including cement base is incubated inner plating and is pasted on outside the curtain wall metal that cement base is incubated outside inner plating Laminate, curtain wall metal outer plate is coated with antirust agent,
100 parts of cement, 90 parts of glass bead, 120 parts of sand, 32 parts of magnesia, 30 parts of metakaolin, magnesium chloride 15 are weighed first Part, 6 parts of aerosil, 3 parts of xanthans, 5 parts of calcium lignosulfonate, 4 parts of cellulose ether, after 45 parts of water is well mixed, Be molded and obtain cement base insulation inner plating,
Curtain wall metal outer plate is copper alloy plate, its manufacturing process：Got the raw materials ready according to proportioning, raw material is carried out into melting, melting 1100 DEG C of temperature, after melting pour into a mould obtaining casting, by casting heating-up temperature be 750 DEG C, be incubated 20-30 minutes, it is laggard The row first stage rolls, and first stage start rolling temperature is 750 DEG C, and 6~8%, mill speed is 0.2- to single pass reduction ratio 0.3m/s, 710 DEG C of first stage finishing temperature, slab thickness reaches 10-15mm, then by heating of plate blank to 890 DEG C, insulation 10-15 minutes, carry out second stage rolling afterwards, second stage start rolling temperature is 890 DEG C, single pass reduction ratio in 14-20%, Mill speed is 0.5-0.7m/s, 830 DEG C of second stage finishing temperature, and slab thickness reaches 4-6mm, then by slab 820 DEG C, 10-20 minutes is incubated, phase III rolling is carried out afterwards, phase III start rolling temperature is 820 DEG C, and single pass reduction ratio exists 10-12%, mill speed is 0.4-0.6m/s, and 760 DEG C of phase III finishing temperature naturally cools to room temperature, and slab thickness reaches To 1-2mm, slab is reheated to 580 DEG C, is incubated 40-50 minutes, then the size according to needed for is cut to slab, Curtain wall metal outer plate is obtained, curtain wall metal outer plate is pasted on cement base insulation inner plating outside, and copper alloy includes following unit Plain weight/mass percentage composition composition：Mn 5%, Mg 3.5%, Ni 2%, Zr 0.85%, Sn 0.7%, Zn 0.2%, V 0.075%, Ti 0.07%, Ce0.05%, balance of Cu, by copper alloy surface antirust agent uniform application in curtain wall metal outer plate surface, stand 24 Hour, curtain wall for building of the invention is obtained,
Antirust agent preparation method：Vinyltrimethoxy silane is heated to 40-45 DEG C, adds tetrabutyl titanate mixed with ethanol Solution is closed, is stirred with the mixing speed of 200r/min, then insulation 20-25 minutes, add triethanolamine oleate mixing equal Even, regulation PH is 8~9, adds phthalic acid ester and isomeric alcohol polyethenoxy ether equal with the mixing speed mixing of 300r/min It is even, 30-40 minutes is incubated at 50-55 DEG C, obtain copper alloy surface antirust agent, vinyltrimethoxy silane：Tetrabutyl titanate： Ethanol：Triethanolamine oleate：Phthalic acid ester：Isomeric alcohol polyethenoxy ether mass ratio 4：1：5：0.6：0.25：0.08.
Embodiment 2
A kind of curtain wall for building, including cement base is incubated inner plating and is pasted on outside the curtain wall metal that cement base is incubated outside inner plating Laminate, curtain wall metal outer plate is coated with antirust agent,
100 parts of cement, 80 parts of glass bead, 110 parts of sand, 35 parts of magnesia, 30 parts of metakaolin, magnesium chloride 20 are weighed first Part, 6 parts of aerosil, 3 parts of xanthans, 3 parts of calcium lignosulfonate, 4 parts of cellulose ether, after 50 parts of water is well mixed, Be molded and obtain cement base insulation inner plating,
Curtain wall metal outer plate is copper alloy plate, its manufacturing process：Got the raw materials ready according to proportioning, raw material is carried out into melting, melting 1095 DEG C of temperature, after melting pour into a mould obtaining casting, by casting heating-up temperature be 770 DEG C, be incubated 20-30 minutes, it is laggard The row first stage rolls, and first stage start rolling temperature is 770 DEG C, and 6~8%, mill speed is 0.2- to single pass reduction ratio 0.3m/s, 720 DEG C of first stage finishing temperature, slab thickness reaches 10-15mm, then by heating of plate blank to 885 DEG C, insulation 10-15 minutes, carry out second stage rolling afterwards, second stage start rolling temperature is 885 DEG C, single pass reduction ratio in 14-20%, Mill speed is 0.5-0.7m/s, 830 DEG C of second stage finishing temperature, and slab thickness reaches 4-6mm, then by slab 830 DEG C, 10-20 minutes is incubated, phase III rolling is carried out afterwards, phase III start rolling temperature is 830 DEG C, and single pass reduction ratio exists 10-12%, mill speed is 0.4-0.6m/s, and 770 DEG C of phase III finishing temperature naturally cools to room temperature, and slab thickness reaches To 1-2mm, slab is reheated to 590 DEG C, is incubated 40-50 minutes, then the size according to needed for is cut to slab, Curtain wall metal outer plate is obtained, curtain wall metal outer plate is pasted on cement base insulation inner plating outside, and copper alloy includes following unit Plain weight/mass percentage composition composition：Mn 5.5%, Mg 3%, Ni 4%, Zr 0.8%, Sn 0.6%, Zn 0.3%, V 0.07%, Ti 0.08%, Ce0.055%, balance of Cu, by copper alloy surface antirust agent uniform application in curtain wall metal outer plate surface, stand 24 Hour, curtain wall for building of the invention is obtained,
Copper alloy surface antirust agent preparation method：Vinyltrimethoxy silane is heated to 40-45 DEG C, tetrabutyl titanate is added With the mixed solution of ethanol, stirred with the mixing speed of 200r/min, then insulation 20-25 minutes, add oily triethylenetetraminehexaacetic acid Hydramine is well mixed, and regulation PH is 8~9, adds phthalic acid ester and isomeric alcohol polyethenoxy ether with the stirring of 300r/min Speed is well mixed, and 30-40 minutes is incubated at 50-55 DEG C, obtains copper alloy surface antirust agent, vinyltrimethoxy silane： Tetrabutyl titanate：Ethanol：Triethanolamine oleate：Phthalic acid ester：Isomeric alcohol polyethenoxy ether mass ratio 3：1.5：5： 0.8： 0.3：0.06.
Embodiment 3
A kind of curtain wall for building, including cement base is incubated inner plating and is pasted on outside the curtain wall metal that cement base is incubated outside inner plating Laminate, curtain wall metal outer plate is coated with antirust agent,
100 parts of cement, 110 parts of glass bead, 110 parts of sand, 36 parts of magnesia, 28 parts of metakaolin, magnesium chloride 20 are weighed first Part, 9 parts of aerosil, 3 parts of xanthans, 5 parts of calcium lignosulfonate, 2 parts of cellulose ether, after 60 parts of water is well mixed, Be molded and obtain cement base insulation inner plating,
Curtain wall metal outer plate is copper alloy plate, its manufacturing process：Got the raw materials ready according to proportioning, raw material is carried out into melting, melting 1100 DEG C of temperature, after melting pour into a mould obtaining casting, by casting heating-up temperature be 770 DEG C, be incubated 20-30 minutes, it is laggard The row first stage rolls, and first stage start rolling temperature is 770 DEG C, and 6~8%, mill speed is 0.2- to single pass reduction ratio 0.3m/s, 715 DEG C of first stage finishing temperature, slab thickness reaches 10-15mm, then by heating of plate blank to 880 DEG C, insulation 10-15 minutes, carry out second stage rolling afterwards, second stage start rolling temperature is 880 DEG C, single pass reduction ratio in 14-20%, Mill speed is 0.5-0.7m/s, 825 DEG C of second stage finishing temperature, and slab thickness reaches 4-6mm, then by slab 830 DEG C, 10-20 minutes is incubated, phase III rolling is carried out afterwards, phase III start rolling temperature is 830 DEG C, and single pass reduction ratio exists 10-12%, mill speed is 0.4-0.6m/s, and 770 DEG C of phase III finishing temperature naturally cools to room temperature, and slab thickness reaches To 1-2mm, slab is reheated to 560 DEG C, is incubated 40-50 minutes, then the size according to needed for is cut to slab, Curtain wall metal outer plate is obtained, curtain wall metal outer plate is pasted on cement base insulation inner plating outside, and copper alloy includes following unit Plain weight/mass percentage composition composition：Mn 6%, Mg 3%, Ni 2%, Zr 0.8%, Sn 0.65%, Zn 0.2%, V 0.08%, Ti 0.07%, Ce0.05%, balance of Cu, by copper alloy surface antirust agent uniform application in curtain wall metal outer plate surface, stand 24 Hour, curtain wall for building of the invention is obtained,
Copper alloy surface antirust agent preparation method：Vinyltrimethoxy silane is heated to 40-45 DEG C, tetrabutyl titanate is added With the mixed solution of ethanol, stirred with the mixing speed of 200r/min, then insulation 20-25 minutes, add oily triethylenetetraminehexaacetic acid Hydramine is well mixed, and regulation PH is 8~9, adds phthalic acid ester and isomeric alcohol polyethenoxy ether with the stirring of 300r/min Speed is well mixed, and 30-40 minutes is incubated at 50-55 DEG C, obtains copper alloy surface antirust agent, vinyltrimethoxy silane： Tetrabutyl titanate：Ethanol：Triethanolamine oleate：Phthalic acid ester：Isomeric alcohol polyethenoxy ether mass ratio 4：1： 7：0.6： 0.2： 0.1.
Embodiment 4
A kind of curtain wall for building, including cement base is incubated inner plating and is pasted on outside the curtain wall metal that cement base is incubated outside inner plating Laminate, curtain wall metal outer plate is coated with antirust agent,
100 parts of cement, 80 parts of glass bead, 100 parts of sand, 30 parts of magnesia, 25 parts of metakaolin, magnesium chloride 20 are weighed first Part, 5 parts of aerosil, 4 parts of xanthans, 6 parts of calcium lignosulfonate, 2 parts of cellulose ether, after 55 parts of water is well mixed, Be molded and obtain cement base insulation inner plating,
Curtain wall metal outer plate is copper alloy plate, its manufacturing process：Got the raw materials ready according to proportioning, raw material is carried out into melting, melting 1095 DEG C of temperature, after melting pour into a mould obtaining casting, by casting heating-up temperature be 760 DEG C, be incubated 20-30 minutes, it is laggard The row first stage rolls, and first stage start rolling temperature is 760 DEG C, and 6~8%, mill speed is 0.2- to single pass reduction ratio 0.3m/s, 710 DEG C of first stage finishing temperature, slab thickness reaches 10-15mm, then by heating of plate blank to 870 DEG C, insulation 10-15 minutes, carry out second stage rolling afterwards, second stage start rolling temperature is 870 DEG C, single pass reduction ratio in 14-20%, Mill speed is 0.5-0.7m/s, 820 DEG C of second stage finishing temperature, and slab thickness reaches 4-6mm, then by slab 810 DEG C, 10-20 minutes is incubated, phase III rolling is carried out afterwards, phase III start rolling temperature is 810 DEG C, and single pass reduction ratio exists 10-12%, mill speed is 0.4-0.6m/s, and 760 DEG C of phase III finishing temperature naturally cools to room temperature, and slab thickness reaches To 1-2mm, slab is reheated to 570 DEG C, is incubated 40-50 minutes, then the size according to needed for is cut to slab, Curtain wall metal outer plate is obtained, curtain wall metal outer plate is pasted on cement base insulation inner plating outside, and copper alloy includes following unit Plain weight/mass percentage composition composition：Mn 5.5%, Mg 3.5%, Ni 2%, Zr 0.8%, Sn 0.7%, Zn 0.25%, V 0.08%, Ti 0.07%, Ce0.05%, balance of Cu, by copper alloy surface antirust agent uniform application in curtain wall metal outer plate surface, stand 24 hours, curtain wall for building of the invention is obtained,
Copper alloy surface antirust agent preparation method：Vinyltrimethoxy silane is heated to 40-45 DEG C, tetrabutyl titanate is added With the mixed solution of ethanol, stirred with the mixing speed of 200r/min, then insulation 20-25 minutes, add oily triethylenetetraminehexaacetic acid Hydramine is well mixed, and regulation PH is 8~9, adds phthalic acid ester and isomeric alcohol polyethenoxy ether with the stirring of 300r/min Speed is well mixed, and 30-40 minutes is incubated at 50-55 DEG C, obtains copper alloy surface antirust agent, vinyltrimethoxy silane： Tetrabutyl titanate：Ethanol：Triethanolamine oleate：Phthalic acid ester：Isomeric alcohol polyethenoxy ether mass ratio 3：1.5：6：0.6： 0.2：0.08.
Table 1：Copper alloy plate coating antirust agent is characterized
Copper alloy plate coats antirust agent test event As a result
Density g/cm3 1.030-1.060
Damp heat test：Humidity 90%, 35 DEG C, 30 days of temperature Without rust spot
Salt spray test：40 DEG C of 5% salt fog continuously sprays 48 hours Without rust spot
Table 2：Copper alloy plate is characterized
Copper alloy plate is tested Elongation percentage δ (%) Hardness（HV） Plastic strain ratio r Yield strength σ s (MPa) Tensile strength sigma b (MPa)
Embodiment 1 37.1 120 1.31 348 445
Embodiment 2 38,5 128 1.34 353 458
Embodiment 3 37.6 135 1.30 355 440
Embodiment 4 36.2 133 1.37 342 451
Table 3：Cement base insulation inner plating is characterized
Cement base is incubated inner plating test event As a result
Compression strength/MPa 0.43-0.48
Tensile strength/MPa 0.15-1.9
Thermal conductivity factor W/mK 0.045-0.058
Dry apparent density/km/m3 135-148
The present invention is not limited to above-mentioned implementation method, it is all using and similar structure of the invention and its method realize the object of the invention All modes, within protection scope of the present invention.

Claims (8)

1. the curtain wall metal that a kind of curtain wall for building, including cement base is incubated inner plating and is pasted on outside cement base insulation inner plating Lamina rara externa, curtain wall metal outer plate is coated with antirust agent,
100 parts of cement, glass bead 80-120 parts, sand 100-130 parts, magnesia 30-40 parts, metakaolin 25- are weighed first 30 parts, magnesium chloride 15-20 parts, aerosil 5-9 parts, xanthans 3-5 parts, calcium lignosulfonate 2-7 parts, cellulose ether 2-4 parts, after water 40-60 parts is well mixed, be molded and obtain cement base insulation inner plating,
Curtain wall metal outer plate is copper alloy plate, its manufacturing process：Got the raw materials ready according to proportioning, raw material is carried out into melting, melting 1090-1100 DEG C of temperature, after melting pour into a mould obtaining casting, is 750-770 DEG C by casting heating-up temperature, 20-30 points of insulation Clock, carries out first stage rolling afterwards, and first stage start rolling temperature is 750-770 DEG C, and single pass reduction ratio is in 6~8%, rolling Speed is 0.2-0.3m/s, and 710-730 DEG C of first stage finishing temperature, slab thickness reaches 10-15mm, then adds slab Heat is incubated 10-15 minutes to 870-890 DEG C, and second stage rolling is carried out afterwards, and second stage start rolling temperature is 870-890 DEG C, In 14-20%, mill speed is 0.5-0.7m/s, 820-830 DEG C of second stage finishing temperature, slab thickness to single pass reduction ratio 4-6mm is reached, then by slab at 810-830 DEG C, 10-20 minutes is incubated, phase III rolling, phase III are carried out afterwards Start rolling temperature is 810-830 DEG C, and in 10-12%, mill speed is 0.4-0.6m/s, phase III finish to gauge temperature to single pass reduction ratio 760-780 DEG C of degree, naturally cools to room temperature, and slab thickness reaches 1-2mm, and slab is reheated into 560-600 DEG C, insulation 40-50 minutes, slab is cut according to required size then, obtain curtain wall metal outer plate, curtain wall metal outer plate patch Cement base insulation inner plating outside is spread on, copper alloy is constituted including following element weight/mass percentage composition：Mn 5-6%, Mg 3-4%, Ni 2-4%, Zr 0.8-1%, Sn 0.6-0.7%, Zn 0.2-0.3%, V 0.07-0.08%, Ti 0.07-0.08%, Ce0.05- 0.06%, balance of Cu, by copper alloy surface antirust agent uniform application in curtain wall metal outer plate surface, stand 24 hours, obtain Present invention curtain wall for building.
2. a kind of curtain wall for building as claimed in claim 1, first stage start rolling temperature is 765 DEG C, and single pass reduction ratio is 6 ~8%, mill speed is 0.2m/s, 710 DEG C of first stage finishing temperature.
3. a kind of curtain wall for building as claimed in claim 1, second stage start rolling temperature is 880 DEG C, and single pass reduction ratio exists 14-20%, mill speed is 0.5-0.7m/s, 820 DEG C of second stage finishing temperature.
4. a kind of curtain wall for building as claimed in claim 1, phase III start rolling temperature is 810 DEG C, and single pass reduction ratio exists 10-12%, mill speed is 0.4-0.6m/s, 760 DEG C of phase III finishing temperature.
5. a kind of curtain wall for building as claimed in claim 1, antirust agent preparation method：Vinyltrimethoxy silane is heated To 40-45 DEG C, the mixed solution of tetrabutyl titanate and ethanol is added, stirred with the mixing speed of 200r/min, then protected It is warm 20-25 minutes, add triethanolamine oleate to be well mixed, regulation PH is 8~9, adds phthalic acid ester and isomery alcohol poly- Oxygen vinethene is well mixed with the mixing speed of 300r/min, and 30-40 minutes is incubated at 50-55 DEG C, obtains copper alloy surface and prevents Rust agent.
6. a kind of curtain wall for building as claimed in claim 1, antirust agent preparation method：Vinyltrimethoxy silane is heated To 42 DEG C, the mixed solution of tetrabutyl titanate and ethanol is added, stirred with the mixing speed of 200r/min, be then incubated 25 Minute, add triethanolamine oleate to be well mixed, regulation PH is 8~9, adds phthalic acid ester and isomeric alcohol polyethenoxy ether It is well mixed with the mixing speed of 300r/min, 35 minutes are incubated at 55 DEG C, obtain copper alloy surface antirust agent.
7. a kind of curtain wall for building as claimed in claim 1, vinyltrimethoxy silane：Tetrabutyl titanate：Ethanol：Oleic acid Triethanolamine：Phthalic acid ester：Isomeric alcohol polyethenoxy ether mass ratio 2-4：1-2：5-7：0.5-0.8：0.2-0.3：0.05- 0.1。
8. a kind of manufacture method of curtain wall for building, curtain wall for building includes cement base insulation inner plating and is pasted on cement base guarantor Curtain wall metal outer plate outside warm inner plating, curtain wall metal outer plate is coated with antirust agent,
100 parts of cement, glass bead 80-120 parts, sand 100-130 parts, magnesia 30-40 parts, metakaolin 25- are weighed first 30 parts, magnesium chloride 15-20 parts, aerosil 5-9 parts, xanthans 3-5 parts, calcium lignosulfonate 2-7 parts, cellulose ether 2-4 parts, after water 40-60 parts is well mixed, be molded and obtain cement base insulation inner plating,
Curtain wall metal outer plate is copper alloy plate, its manufacturing process：Got the raw materials ready according to proportioning, raw material is carried out into melting, melting 1090-1100 DEG C of temperature, after melting pour into a mould obtaining casting, is 750-770 DEG C by casting heating-up temperature, 20-30 points of insulation Clock, carries out first stage rolling afterwards, and first stage start rolling temperature is 750-770 DEG C, and single pass reduction ratio is in 6~8%, rolling Speed is 0.2-0.3m/s, and 710-730 DEG C of first stage finishing temperature, slab thickness reaches 10-15mm, then adds slab Heat is incubated 10-15 minutes to 870-890 DEG C, and second stage rolling is carried out afterwards, and second stage start rolling temperature is 870-890 DEG C, In 14-20%, mill speed is 0.5-0.7m/s, 820-830 DEG C of second stage finishing temperature, slab thickness to single pass reduction ratio 4-6mm is reached, then by slab at 810-830 DEG C, 10-20 minutes is incubated, phase III rolling, phase III are carried out afterwards Start rolling temperature is 810-830 DEG C, and in 10-12%, mill speed is 0.4-0.6m/s, phase III finish to gauge temperature to single pass reduction ratio 760-780 DEG C of degree, naturally cools to room temperature, and slab thickness reaches 1-2mm, and slab is reheated into 560-600 DEG C, insulation 40-50 minutes, slab is cut according to required size then, obtain curtain wall metal outer plate, curtain wall metal outer plate patch Cement base insulation inner plating outside is spread on, copper alloy is constituted including following element weight/mass percentage composition：Mn 5-6%, Mg 3-4%, Ni 2-4%, Zr 0.8-1%, Sn 0.6-0.7%, Zn 0.2-0.3%, V 0.07-0.08%, Ti 0.07-0.08%, Ce0.05- 0.06%, balance of Cu, by copper alloy surface antirust agent uniform application in curtain wall metal outer plate surface, stand 24 hours, obtain Present invention curtain wall for building.
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