CN106905822A - A kind of powdery paints of marine climate resistant of graphene-containing and preparation method thereof - Google Patents
A kind of powdery paints of marine climate resistant of graphene-containing and preparation method thereof Download PDFInfo
- Publication number
- CN106905822A CN106905822A CN201710233090.2A CN201710233090A CN106905822A CN 106905822 A CN106905822 A CN 106905822A CN 201710233090 A CN201710233090 A CN 201710233090A CN 106905822 A CN106905822 A CN 106905822A
- Authority
- CN
- China
- Prior art keywords
- parts
- graphene
- powdery paints
- marine climate
- climate resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34924—Triazines containing cyanurate groups; Tautomers thereof
Abstract
The invention discloses a kind of powdery paints of the marine climate resistant of graphene-containing, its raw material is constituted, as mass fraction, including following component：60 80 parts of polyester resin；46 parts of triglycidyl isocyanurate；0.5 3 parts of Graphene；0.3 0.6 parts of levelling agent；3.5 5 parts of delustering agent；0.1 0.3 parts of catalyst；1.2 1.7 parts of pigment；5 10 parts of titanium dioxide；0 20 parts of filler.The present invention is obtained cheap salt spray resistance powdery paints high based on Graphene and polyester resin, its resistance to marine environment weatherability is significantly increased compared with conventional epoxies type anti-corrosive powder paint, ocean weatherability, antiseptic property, environment friendly and high performance-price ratio are taken into account, there is larger impetus to the technology upgrading of the metal anti-corrosive paint of coastal area.
Description
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of marine climate resistant of graphene-containing powdery paints and its
Preparation method.
Background technology
Seawater is a kind of natural electrolytes solution that quantity is maximum in nature, corrosivity is very strong, the weather of coastal area
Feature is high temperature, rainy and high wind convection current, causes the construction material in coastal waters and ocean, engineering equipment to be chronically at salt fog ring high
In border, air salt air corrosion is extremely serious, in the comprehensive work that strong atmospheric corrosion, electrochemical corrosion and airflow scouring corrode
With the service life of various hardwares is far below general inland environment, is often occurred within half a year using conventional powder coatings tight
Heavy corrosion, it has to using the high fluoro coatings of price, larger financial cost pressure is constituted to China's ocean engineering construction, sternly
The development of related industry is limited again.China coastline is up to 18,000 kms, and a large amount of coastal waters metal structures are exposed to ocean salt
In mist corrosive environment, every year because the economy and resources loss of salt air corrosion are huge, therefore, the cheap salt tolerant marine climate of development cost
Powdery paints, has important industry meaning to China coastal seas Land_use change, the exploitation of marine resources and various ships process industry.
Powdery paints is that one kind is mixed by resin, curing agent, pigment, filler, auxiliary agent etc., by electrostatic spraying mode
Coated article surface is coated on, then makes a kind of new solid powdery coating of its melting, levelling, solidification through overbaking.It does not make
With solvent, with environmental protection, recyclable, save energy and resource, labour intensity are relatively low, coating machinery intensity is high, corrosion resistance
Strong the features such as, it has also become acknowledged " 4E " type（Production efficiency, excellent film performance, ecological, environmental protective, economy high）Coating.
Traditional powdery paints contains epoxy resin, and weatherability is poor, and salt spray resistance is not enough, and fluorine-containing powdery paints has preferably
Ocean weatherability, but production cost is more than five times of ordinary powder coating, can not reach the weather-proof corrosion-resistant requirement of coastal waters metal.
Therefore, prior art has yet to be improved and developed.
The content of the invention
In view of above-mentioned the deficiencies in the prior art, a kind of powdery paints of the marine climate resistant of graphene-containing is provided in the present invention
And preparation method thereof, salt fog resistance is obtained by force by pure polyester combination Graphene and the powdery paints of low production cost, solve
The shortcoming of existing epoxy resin or epoxy polyester blended powder coating weatherability difference.
Technical scheme is as follows：
A kind of powdery paints of the marine climate resistant of graphene-containing, wherein, its raw material composition, as mass fraction, including following component：
Polyester resin 60-80 parts；
Triglycidyl isocyanurate 4-6 parts；
Graphene 0.5-3 parts；
Levelling agent 0.3-0.6 parts；
Delustering agent 3.5-5 parts；
Catalyst 0.1-0.3 parts；
Pigment 1.2-1.7 parts；
Titanium dioxide 5-10 parts；
Filler 0-20 parts.
The powdery paints of the marine climate resistant of described graphene-containing, wherein, the polyester resin is selected from saturated polyester tree
One or more mixture in fat or unsaturated polyester resin.
The powdery paints of the marine climate resistant of described graphene-containing, wherein, the pigment includes colour carbon black, conductive charcoal
One or more mixture in black or carbon black.
The powdery paints of the marine climate resistant of described graphene-containing, wherein, the Graphene is eigenstate Graphene, oxygen
One or more mixture in the functionalization graphene of graphite alkene or remodeling.
The powdery paints of the marine climate resistant of described graphene-containing, wherein, the functionalization graphene of the remodeling includes
Contain the Graphene of hydroxyl, sulfydryl, carboxyl, carbonyl, amino group in surface.
The powdery paints of the marine climate resistant of described graphene-containing, wherein, the filler is blanc fixe, lightweight
One kind in calcium carbonate, powdered whiting, kaolin, talcum powder, bentonite, precipitated silica, silicon powder and mica powder or
Various mixtures.
A kind of preparation method of the powdery paints of the marine climate resistant of graphene-containing, wherein, comprise the following steps：
S1, the quality of each component in raw material is weighed by proportioning with electronic balance, stirred to crushing through 200-270 second mixed at high speed；
S2, high-temperature heating to melt, cooling, compressing tablet, crush, be put into flour mill high speed and clay into power；
S3, through cyclone separator sieving, classification, finished product.
The preparation method of the powdery paints of the marine climate resistant of described graphene-containing, it is characterised in that the step s2
Middle heating and temperature control is between 90 DEG C -110 DEG C.
Beneficial effect：The present invention is obtained cheap salt spray resistance powdery paints high based on Graphene and polyester resin, its
Resistance to marine environment weatherability is significantly increased compared with conventional epoxies type anti-corrosive powder paint, has taken into account ocean weatherability, anti-corrosion
There is larger promotion to make for performance, environment friendly and high performance-price ratio, the technology upgrading to the metal anti-corrosive paint of coastal area
With.
Specific embodiment
The present invention provides a kind of synthetic method of nicotinic acid zinc, to make the purpose of the present invention, technical scheme and effect more clear
Chu, clearly, the present invention is described in more detail below.It should be appreciated that specific embodiment described herein is only used to solve
The present invention is released, is not intended to limit the present invention.
A kind of powdery paints of the marine climate resistant of graphene-containing, its raw material composition, as mass fraction, including with the following group
Part：
Polyester resin 60-80 parts；
Triglycidyl isocyanurate 4-6 parts；
Graphene 0.5-3 parts；
Levelling agent 0.3-0.6 parts；
Delustering agent 3.5-5 parts；
Catalyst 0.1-0.3 parts；
Pigment 1.2-1.7 parts；
Titanium dioxide 5-10 parts；
Filler 0-20 parts.
In above-mentioned component, the triglycidyl isocyanurate of addition has high chemical stability, applies tool powder
Material has excellent heat resistance, weatherability, light resistance and corrosion resistance, improves the application performance of powdery paints.
In the present embodiment, polyester resin is mixed selected from one or more in saturated polyester resin or unsaturated polyester resin
Compound., with epoxy resin and polyester resin as main component, the weatherability of its epoxy resin is not enough, causes for traditional powder coating
The overall weatherability of film is poor, the present invention using pure polyester, i.e. polyester resin for powdery paints matrix resin, coating it is weather-proof
Property is significantly improved.
Further, pigment also includes one or more mixture in colour carbon black, conductive black or carbon black.Using
On the basis of pure polyester is for the matrix resin of powdery paints, it is preferable that present invention addition also in powdery paints has quickly to be led
The colour carbon black of electrical property, with filling paint hole and defect, colour carbon black is layering to form the physics of densification in coating
Isolation layer, and colour carbon black is very poor to the wellability of water, prevents and delay the small molecule corrosive medium in air moisture from immersing tree
Fat coating, while suppressing electrochemical corrosion effect, enables coating to have extremely strong resistance to saltfog.
In practical application, Graphene is in the functionalization graphene of eigenstate Graphene, graphene oxide or remodeling
Plant or various mixtures.
In practical application, according to different demands, the functionalization graphene of remodeling contains hydroxyl, sulfydryl, carboxylic from surface
Base, carbonyl, the Graphene of amino group.
Further, filler is blanc fixe, precipitated calcium carbonate, powdered whiting, kaolin, talcum powder, swollen
One or more mixture in profit soil, precipitated silica, silicon powder and mica powder.
A kind of preparation method of the powdery paints of the marine climate resistant of graphene-containing, wherein, comprise the following steps：
First, the quality of each component in raw material is weighed by proportioning with electronic balance, is well mixed, through 200-270 seconds mixed at high speed
Stirring is to broken；
Then, it is heated at a high temperature of 90 DEG C -110 DEG C melting, cooling, compressing tablet, crushes, is put into flour mill high speed grinds
End；
Finally, through cyclone separator sieving, classification, finished product.
Below by way of specific embodiment, the present invention will be further described.
Embodiment 1
A kind of powdery paints of the marine climate resistant of graphene-containing, its raw material composition, as mass fraction, including following component：
60 parts of polyester resin, 4 parts of triglycidyl isocyanurate, 2.5 parts of Graphene, 0.3 part of levelling agent, 4.5 parts of delustering agent is urged
0.1 part of agent, 1.2 parts of colour carbon black, 9.9 parts of titanium dioxide, 17.5 parts of filler.
Its preparation method is comprised the following steps：
First, the quality of each component in raw material is weighed by proportioning with electronic balance, is well mixed, through 200-270 seconds mixed at high speed
Stirring is to broken；
Then, it is heated at a high temperature of 90 DEG C -110 DEG C melting, cooling, compressing tablet, crushes, is put into flour mill high speed grinds
End；
Finally, through cyclone separator sieving, classification, finished product.
The present embodiment is most preferred embodiment.
Embodiment 2
The present embodiment is essentially identical with the preparation method of embodiment 1, and the technique effect for reaching is also essentially identical, unlike, this
A kind of powdery paints of the marine climate resistant of graphene-containing that embodiment is provided, its raw material composition, as mass fraction, including with
Lower component：80 parts of polyester resin, 6 parts of triglycidyl isocyanurate, 0.5 part of Graphene, 0.3 part of levelling agent, delustering agent
3.5 parts, 0.1 part of catalyst, 1.2 parts of colour carbon black, 5 parts of titanium dioxide, 3.4 parts of filler.
Embodiment 3
The present embodiment is essentially identical with the preparation method of embodiment 1, and the technique effect for reaching is also essentially identical, unlike, this
A kind of powdery paints of the marine climate resistant of graphene-containing that embodiment is provided, its raw material composition, as mass fraction, including with
Lower component：66 parts of polyester resin, 5.1 parts of triglycidyl isocyanurate, 3 parts of Graphene, 0.3 part of levelling agent, delustering agent 5
Part, 0.1 part of catalyst, 1.2 parts of colour carbon black, 10 parts of titanium dioxide, 9.3 parts of filler.
Embodiment 4
The present embodiment is essentially identical with the preparation method of embodiment 1, and the technique effect for reaching is also essentially identical, unlike, this
A kind of powdery paints of the marine climate resistant of graphene-containing that embodiment is provided, its raw material composition, as mass fraction, including with
Lower component：70 parts of polyester resin, 5 parts of triglycidyl isocyanurate, 1.6 parts of Graphene, 0.2 part of levelling agent, delustering agent
4.5 parts, 0.1 part of catalyst, 1.2 parts of colour carbon black, 7.4 parts of titanium dioxide, 10 parts of filler.
Embodiment 5
The present embodiment is essentially identical with the preparation method of embodiment 1, and the technique effect for reaching is also essentially identical, unlike, this
A kind of powdery paints of the marine climate resistant of graphene-containing that embodiment is provided, its raw material composition, as mass fraction, including with
Lower component：75 parts of polyester resin, 5.7 parts of triglycidyl isocyanurate, 1.8 parts of Graphene, 0.3 part of levelling agent, delustering agent
3.5 parts, 0.1 part of catalyst, 1.2 parts of colour carbon black, 5 parts of titanium dioxide, 7.4 parts of filler.
Embodiment 6
The present embodiment is essentially identical with the preparation method of embodiment 1, and the technique effect for reaching is also essentially identical, unlike, this
A kind of powdery paints of the marine climate resistant of graphene-containing that embodiment is provided, its raw material composition, as mass fraction, including with
Lower component：70 parts of polyester resin, 5 parts of triglycidyl isocyanurate, 0.5 part of Graphene, 0.2 part of levelling agent, delustering agent
4.5 parts, 0.1 part of catalyst, 1.2 parts of colour carbon black, 8 parts of titanium dioxide, 10.5 parts of filler.
Embodiment 7
The present embodiment is essentially identical with the preparation method of embodiment 1, and the technique effect for reaching is also essentially identical, unlike, this
A kind of powdery paints of the marine climate resistant of graphene-containing that embodiment is provided, its raw material composition, as mass fraction, including with
Lower component：70 parts of polyester resin, 5 parts of triglycidyl isocyanurate, 3 parts of Graphene, 0.3 part of levelling agent, delustering agent 3.5
Part, 0.1 part of catalyst, 1.2 parts of colour carbon black, 7.5 parts of titanium dioxide, 9.4 parts of filler.
Comparative example
A kind of powdery paints of the marine climate resistant of graphene-containing, its raw material composition, as mass fraction, including following component：
70 parts of polyester resin, 5 parts of triglycidyl isocyanurate, 0.2 part of levelling agent, 4.5 parts of delustering agent, 0.1 part of catalyst is general
Logical 1.2 parts of pigment, 9 parts of titanium dioxide, filler 10%.
Its preparation method is comprised the following steps：
First, the quality of each component in raw material is weighed by proportioning with electronic balance, is well mixed, through 200-270 seconds mixed at high speed
Stirring is to broken；
Then, it is heated at a high temperature of 90 DEG C -110 DEG C melting, cooling, compressing tablet, crushes, is put into flour mill high speed grinds
End；
Finally, through cyclone separator sieving, classification, finished product.
Embodiment 1-8 salt spray resistance test results, it is as shown in the table.
Upper table is the salt spray resistance test knot of the powdery paints of the marine climate resistant of graphene-containing prepared by embodiment 1-8
Really, embodiment 8 is the polyester powder coating salt spray resistance test result for being not added with Graphene and colour carbon black, the data from table
Contrast is visible, the unidirectional extent of corrosion of embodiment 8 considerably beyond embodiment 1-7 unidirectional extent of corrosion, thus, the present invention contains stone
The powdery paints of the marine climate resistant of black alkene is designed by the rational formula of addition Graphene and colour carbon black, and salt spray resistance is big
Amplitude is improved, and fully meets the weather-proof protection requirement of coastal waters metal structure.
It should be appreciated that application of the invention is not limited to above-mentioned citing, and for those of ordinary skills, can
To be improved according to the above description or converted, all these modifications and variations should all belong to the guarantor of appended claims of the present invention
Shield scope.
Claims (8)
1. a kind of powdery paints of the marine climate resistant of graphene-containing, it is characterised in that its raw material is constituted, as mass fraction,
Including following component：
Polyester resin 60-80 parts；
Triglycidyl isocyanurate 4-6 parts；
Graphene 0.5-3 parts；
Levelling agent 0.3-0.6 parts；
Delustering agent 3.5-5 parts；
Catalyst 0.1-0.3 parts；
Pigment 1.2-1.7 parts；
Titanium dioxide 5-10 parts；
Filler 0-20 parts.
2. the powdery paints of the marine climate resistant of graphene-containing according to claim 1, it is characterised in that the polyester tree
Fat is selected from one or more mixture in saturated polyester resin or unsaturated polyester resin.
3. the powdery paints of the marine climate resistant of graphene-containing according to claim 1, it is characterised in that the pigment bag
Include one or more mixture in colour carbon black, conductive black or carbon black.
4. the powdery paints of the marine climate resistant of graphene-containing according to claim 1, it is characterised in that the Graphene
It is one or more mixture in the functionalization graphene of eigenstate Graphene, graphene oxide or remodeling.
5. the powdery paints of the marine climate resistant of graphene-containing according to claim 4, it is characterised in that the remodeling
Functionalization graphene contains the Graphene of hydroxyl, sulfydryl, carboxyl, carbonyl, amino group including surface.
6. the powdery paints of the marine climate resistant of graphene-containing according to claim 1, it is characterised in that the filler
For blanc fixe, precipitated calcium carbonate, powdered whiting, kaolin, talcum powder, bentonite, precipitated silica, silicon powder and
One or more mixture in mica powder.
7. the preparation side of the powdery paints of the marine climate resistant of a kind of graphene-containing as described in claim 1-5 any one
Method, it is characterised in that comprise the following steps：
S1, the quality of each component in raw material is weighed by proportioning with electronic balance, stirred to crushing through 200-270 second mixed at high speed；
S2, high-temperature heating to melt, cooling, compressing tablet, crush, be put into flour mill high speed and clay into power；
S3, through cyclone separator sieving, classification, finished product.
8. the preparation method of the powdery paints of the marine climate resistant of graphene-containing according to claim 7, it is characterised in that
Heating and temperature control is between 90 DEG C -110 DEG C in the step s2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710233090.2A CN106905822A (en) | 2017-04-11 | 2017-04-11 | A kind of powdery paints of marine climate resistant of graphene-containing and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710233090.2A CN106905822A (en) | 2017-04-11 | 2017-04-11 | A kind of powdery paints of marine climate resistant of graphene-containing and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106905822A true CN106905822A (en) | 2017-06-30 |
Family
ID=59195027
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710233090.2A Pending CN106905822A (en) | 2017-04-11 | 2017-04-11 | A kind of powdery paints of marine climate resistant of graphene-containing and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106905822A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108707398A (en) * | 2018-06-20 | 2018-10-26 | 安徽辰融金属表面处理科技有限公司 | A kind of electrostatic spraying powder and preparation method thereof for metal component protection |
| CN111303734A (en) * | 2020-02-17 | 2020-06-19 | 安徽华辉塑业科技股份有限公司 | Ultraviolet-absorbing powder coating for thunder and lightning and preparation method thereof |
| CN111826035A (en) * | 2019-04-18 | 2020-10-27 | 深圳市励高表面处理材料有限公司 | Conductive coating and preparation method and application thereof |
| CN116102908A (en) * | 2023-04-13 | 2023-05-12 | 广东睿智环保科技股份有限公司 | Weather-resistant powder coating, coating and preparation method |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106280920A (en) * | 2016-08-24 | 2017-01-04 | 六安科瑞达新型材料有限公司 | Outdoor weathe resistance powdery paints |
-
2017
- 2017-04-11 CN CN201710233090.2A patent/CN106905822A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106280920A (en) * | 2016-08-24 | 2017-01-04 | 六安科瑞达新型材料有限公司 | Outdoor weathe resistance powdery paints |
Non-Patent Citations (2)
| Title |
|---|
| 傅绍燕: "《涂装工艺及车间设计手册》", 31 January 2013, 机械工业出版社 * |
| 宣兆龙: "《装备环境工程第2版》", 31 May 2015, 北京航空航天大学出版社 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108707398A (en) * | 2018-06-20 | 2018-10-26 | 安徽辰融金属表面处理科技有限公司 | A kind of electrostatic spraying powder and preparation method thereof for metal component protection |
| CN111826035A (en) * | 2019-04-18 | 2020-10-27 | 深圳市励高表面处理材料有限公司 | Conductive coating and preparation method and application thereof |
| CN111826035B (en) * | 2019-04-18 | 2022-04-01 | 深圳市励高表面处理材料有限公司 | Conductive coating and preparation method and application thereof |
| CN111303734A (en) * | 2020-02-17 | 2020-06-19 | 安徽华辉塑业科技股份有限公司 | Ultraviolet-absorbing powder coating for thunder and lightning and preparation method thereof |
| CN116102908A (en) * | 2023-04-13 | 2023-05-12 | 广东睿智环保科技股份有限公司 | Weather-resistant powder coating, coating and preparation method |
| CN116102908B (en) * | 2023-04-13 | 2023-08-15 | 广东睿智环保科技股份有限公司 | Weather-resistant powder coating, coating and preparation method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106905822A (en) | A kind of powdery paints of marine climate resistant of graphene-containing and preparation method thereof | |
| CN105713481B (en) | A kind of graphene modified epoxy zinc rich primer and preparation method thereof | |
| CN107916047A (en) | Graphene anticorrosive paint and preparation method | |
| CN106189719A (en) | A kind of Graphene anticorrosive paint and preparation method thereof | |
| CN108997889A (en) | A kind of ocean naval vessel graphene heavy antisepsis priming paint and preparation method thereof | |
| CN103289531A (en) | Underwater coating anti-pollution and anti-corrosion epoxy coating and preparation method thereof | |
| CN103602220B (en) | A kind of Siloxane hybrid anticorrosive paint | |
| CN108864905A (en) | A kind of lozenge bedded zirconium phosphate and the marine anticorrosion powdery paints of carbon nanotube and the preparation method and application thereof | |
| CN107964097A (en) | The ternary nano composite material preparation method and application of redox graphene, ferroso-ferric oxide and polyaniline | |
| CN105295585A (en) | Novel paint for anti-fouling and anti-corrosion treatment on marine metal component and preparation method of novel paint | |
| CN105860815A (en) | Waterborne anti-static anti-corrosive thermal insulation coating and preparation method | |
| CN103952060A (en) | Epoxy anticorrosive paint modified by polymer containing chlorine and preparation method of epoxy anticorrosive paint | |
| CN110128943A (en) | A kind of graphene high-efficiency energy anticorrosive paint and preparation method thereof and product | |
| CN105907240B (en) | A kind of water corrosion-resistant epoxy paint and preparation method thereof containing anti-flash rusting agent | |
| CN110499088A (en) | Modified anti-corrosive powder paint of a kind of graphene and preparation method thereof | |
| CN104341924A (en) | Water-based antirust and rust removing asphalt ship bottom coating and preparation method for same | |
| CN110330865A (en) | Modified anti-corrosion primer of a kind of graphene and preparation method thereof | |
| CN102212303A (en) | Preparation of room-temperature underwater solvent-free epoxy heavy sizing composite heavy-duty anticorrosive paint | |
| CN104449223A (en) | Aluminum-zinc-silicon epoxy composite powder anticorrosive coating and preparation method thereof | |
| CN105694667B (en) | Thick coated type epoxy insulation antiseptic paint | |
| CN102723620B (en) | Composite anticorrosion grounding device and preparation method thereof | |
| CN1250071A (en) | White waterproof heat insulating elastic paint | |
| CN106752156B (en) | A kind of new aqueous inorganic zinc-enriched coating | |
| CN109836871A (en) | A kind of preparation method of graphene composite material and a kind of polymer coating | |
| CN109370365A (en) | A kind of ship anticorrosion and antifouling dual-function paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170630 |