CN106905634A - A kind of perfume antibacterial polyvinyl chloride bottle and preparation method thereof - Google Patents
A kind of perfume antibacterial polyvinyl chloride bottle and preparation method thereof Download PDFInfo
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- CN106905634A CN106905634A CN201510977287.8A CN201510977287A CN106905634A CN 106905634 A CN106905634 A CN 106905634A CN 201510977287 A CN201510977287 A CN 201510977287A CN 106905634 A CN106905634 A CN 106905634A
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- polyvinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/10—Applications used for bottles
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
Abstract
The present invention relates to plastic containers preparation field, a kind of perfume antibacterial polyvinyl chloride bottle and preparation method thereof is disclosed, be obtained by following raw material：Polyvinyl chloride 60-80 parts, carboxymethylcellulose calcium 4-6 parts, aniline 4-6 parts, sorbierite 8-10 parts, antiseptic 8-10 parts, plasticizer 4-6 parts, toughener 4-6 parts, antioxidant 4-6 parts, lubricant 4-6 parts, Photoresist 4-6 parts.Preparation method：1）, weigh each raw material and add it to mix in reactor, heating melting；2）, by the raw material after melting pass through extruding machine extrusion moulding；3）, the raw material of extrusion moulding is molded embryo by injection machine；4）, by embryo successively by bottle blowing, prolong modeling, cooling, it is interior it is cold, abandon and pressurize, be made bottled；5）, finished product after de- bottle.On the basis of intensity is good, with antibacterial functions, and antibacterial timeliness is long for perfume of the invention antibacterial polyvinyl chloride bottle.
Description
Technical field
The present invention relates to plastic containers preparation field, more particularly to a kind of perfume antibacterial polyvinyl chloride bottle and preparation method thereof.
Background technology
Because plastic bottle is lightweight, it is easily worked, and manufacturing cost is relatively low, therefore plastic bottle has been widely used as the product container in the fields such as food and drink, commodity.However, in daily life, the invasive organism such as bacterium is ubiquitous, many products are easily contaminated during storage, if people's human body in practical product is contacted with plastic bottle, just easy bacterial infection, so as to threaten health.
The Chinese patent of Application No. CN201510550180.5 discloses a kind of environmentally-friendly plastic bottle and preparation method thereof, wherein, in parts by mass, environmentally-friendly plastic bottle is made up of following component raw material：High density polyethylene (HDPE) 20-30 parts, asbestos fibre 10-20 parts, nylon 5-10 parts, PLA 10-20 parts, polylactic resin 10-20 parts, polycaprolactone 5-10 parts, makrolon 5-10 parts, polystyrene 5-10 parts, methyl-silicone oil 3-5 parts, bulking agent 1-5 parts and coupling agent 3-5 parts.Environmentally-friendly plastic bottle degradation speed is fast, and its intensity, fine heat-resisting performance, is Green Product.
The Chinese patent of Application No. CN201310169406.8 discloses a kind of double-layer polyethylene liquid, medicinal bottle and preparation method thereof, belongs to plastic drug package processing technique field.The liquid, medicinal bottle is made up of internal layer and outer layer, and internal layer is made up of high density polyethylene (HDPE), and outer layer is made up of the component of following weight percentage：68%~88% high density polyethylene (HDPE), 0.2%~3% antioxidant 264,0.05%~2% antioxidant CA and 10%~30% aluminium hydroxide.It is an advantage of the invention that with good anti-flammability, barrier properties for gases and impact strength, so as to meet the demand of liquid preparation storage, transport, while also can guarantee that the quality of liquid preparation.
Although above-mentioned plastic bottle has preferable intensity, anti-flammability, without antibacterial functions.
The content of the invention
In order to solve the above-mentioned technical problem, the invention provides a kind of perfume antibacterial polyvinyl chloride bottle and preparation method thereof.Perfume of the invention with antibacterial polyvinyl chloride bottle on the basis of intensity is good, with antibacterial functions.
Concrete technical scheme of the invention is：A kind of perfume antibacterial polyvinyl chloride bottle, is obtained by the raw material of following weight portion：Polyvinyl chloride 60-80 parts, carboxymethylcellulose calcium 4-6 parts, aniline 4-6 parts, sorbierite 8-10 parts, antiseptic 8-10 parts, plasticizer 4-6 parts, toughener 4-6 parts, antioxidant 4-6 parts, lubricant 4-6 parts, Photoresist 4-6 parts.
PVC bottle of the invention has antibacterial functions, and antibacterial actual effect is long, and intensity is high, and good toughness is ageing-resistant, moreover it is possible to plays light blocking effect, is particularly suitable for the container of cosmetics.
Preferably, the antiseptic is one or more mixture in silver nitrate, silver iodide, zinc oxide, nano silicon, nano titanium oxide.It is above-mentioned antiseptic inherently safe, nontoxic, and compatibility comparatively with polyvinyl chloride is good, the good dispersion in PVC base system, antibacterial actual effect is long.
Preferably, the plasticizer is ATBC.Plasticizer can increase the plasticity of polyvinyl chloride, be easy to machine-shaping.
Preferably, the toughener is copolymer of methyl methacrylatestyrene.Toughener can improve the toughness of plastic bottle body.
Preferably, the antioxidant is phenolic antioxidant.
Preferably, the lubricant is paraffin or Tissuemat E.Lubricant can be conducive to ductility of the polyvinyl chloride in shaping, be easy to processing.
Preferably, the Photoresist is cellulose or lignin.
A kind of perfume preparation method of antibacterial polyvinyl chloride bottle, step is as follows：
1）, respectively weigh each raw material and add the raw material into and mixed in reactor, heat melting；
2）, by the raw material after melting pass through extruding machine extrusion moulding；
3）, the raw material of extrusion moulding is molded embryo by injection machine；
4）, by the embryo successively by bottle blowing, prolong modeling, cooling, it is interior it is cold, abandon and pressurize, be made bottled；
5）, finished product after de- bottle.
It is compared with the prior art, the beneficial effects of the invention are as follows：On the basis of intensity is good, with antibacterial functions, and antibacterial timeliness is long for perfume of the invention antibacterial polyvinyl chloride bottle.
Specific embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1
A kind of perfume antibacterial polyvinyl chloride bottle, is obtained by the raw material of following weight portion：70 parts of polyvinyl chloride, 5 parts of carboxymethylcellulose calcium, 5 parts of aniline, 9 parts of sorbierite, 4 parts of silver nitrate, 5 parts of nano titanium oxide, 5 parts of ATBC, 5 parts of copolymer of methyl methacrylatestyrene, 5 parts of phenolic antioxidant, 5 parts of paraffin, 5 parts of cellulose.
A kind of perfume preparation method of antibacterial polyvinyl chloride bottle, step is as follows：
1）, respectively weigh each raw material and add the raw material into and mixed in reactor, heat melting；
2）, by the raw material after melting pass through extruding machine extrusion moulding；
3）, the raw material of extrusion moulding is molded embryo by injection machine；
4）, by the embryo successively by bottle blowing, prolong modeling, cooling, it is interior it is cold, abandon and pressurize, be made bottled；
5）, finished product after de- bottle.
Embodiment 2
A kind of perfume antibacterial polyvinyl chloride bottle, is obtained by the raw material of following weight portion：60 parts of polyvinyl chloride, 4 parts of carboxymethylcellulose calcium, 4 parts of aniline, 8 parts of sorbierite, 8 parts of silver iodide, 4 parts of ATBC, 4 parts of copolymer of methyl methacrylatestyrene, 4 parts of phenolic antioxidant, 4 parts of Tissuemat E, 4 parts of lignin.
A kind of perfume preparation method of antibacterial polyvinyl chloride bottle, step is as follows：
1）, respectively weigh each raw material and add the raw material into and mixed in reactor, heat melting；
2）, by the raw material after melting pass through extruding machine extrusion moulding；
3）, the raw material of extrusion moulding is molded embryo by injection machine；
4）, by the embryo successively by bottle blowing, prolong modeling, cooling, it is interior it is cold, abandon and pressurize, be made bottled；
5）, finished product after de- bottle.
Embodiment 3
A kind of perfume antibacterial polyvinyl chloride bottle, is obtained by the raw material of following weight portion：80 parts of polyvinyl chloride, 6 parts of carboxymethylcellulose calcium, 6 parts of aniline, 10 parts of sorbierite, 5 parts of zinc oxide, 5 parts of nano silicon, 6 parts of ATBC, 6 parts of copolymer of methyl methacrylatestyrene, 6 parts of phenolic antioxidant, 6 parts of Tissuemat E, 6 parts of cellulose.
A kind of perfume preparation method of antibacterial polyvinyl chloride bottle, step is as follows：
1）, respectively weigh each raw material and add the raw material into and mixed in reactor, heat melting；
2）, by the raw material after melting pass through extruding machine extrusion moulding；
3）, the raw material of extrusion moulding is molded embryo by injection machine；
4）, by the embryo successively by bottle blowing, prolong modeling, cooling, it is interior it is cold, abandon and pressurize, be made bottled；
5）, finished product after de- bottle.
Embodiment 4
A kind of perfume antibacterial polyvinyl chloride bottle, is obtained by the raw material of following weight portion：65 parts of polyvinyl chloride, 4 parts of carboxymethylcellulose calcium, 5 parts of aniline, 10 parts of sorbierite, 3 parts of nano silicon, 5 parts of nano titanium oxide, 5 parts of ATBC, 4 parts of copolymer of methyl methacrylatestyrene, 6 parts of phenolic antioxidant, 4 parts of paraffin, 6 parts of lignin.
A kind of perfume preparation method of antibacterial polyvinyl chloride bottle, step is as follows：
1）, respectively weigh each raw material and add the raw material into and mixed in reactor, heat melting；
2）, by the raw material after melting pass through extruding machine extrusion moulding；
3）, the raw material of extrusion moulding is molded embryo by injection machine；
4）, by the embryo successively by bottle blowing, prolong modeling, cooling, it is interior it is cold, abandon and pressurize, be made bottled；
5）, finished product after de- bottle.
Embodiment 5
A kind of perfume antibacterial polyvinyl chloride bottle, is obtained by the raw material of following weight portion：75 parts of polyvinyl chloride, 6 parts of carboxymethylcellulose calcium, 4 parts of aniline, 8 parts of sorbierite, 2 parts of silver nitrate, 6 parts of nano silicon, 5 parts of ATBC, 6 parts of copolymer of methyl methacrylatestyrene, 4 parts of phenolic antioxidant, 6 parts of Tissuemat E, 5 parts of lignin.
A kind of perfume preparation method of antibacterial polyvinyl chloride bottle, step is as follows：
1）, respectively weigh each raw material and add the raw material into and mixed in reactor, heat melting；
2）, by the raw material after melting pass through extruding machine extrusion moulding；
3）, the raw material of extrusion moulding is molded embryo by injection machine；
4）, by the embryo successively by bottle blowing, prolong modeling, cooling, it is interior it is cold, abandon and pressurize, be made bottled；
5）, finished product after de- bottle.
Raw materials used in the present invention, equipment, unless otherwise noted, is the conventional raw material, equipment of this area；Method therefor in the present invention, unless otherwise noted, is the conventional method of this area.
The above, is only presently preferred embodiments of the present invention, and not the present invention is imposed any restrictions, every any simple modification, change and equivalent transformation substantially made to above example according to the technology of the present invention, still falls within the protection domain of technical solution of the present invention.
Claims (8)
1. a kind of perfume with antibacterial polyvinyl chloride bottle, it is characterised in that：It is obtained by the raw material of following weight portion：Polyvinyl chloride 60-80 parts, carboxymethylcellulose calcium 4-6 parts, aniline 4-6 parts, sorbierite 8-10 parts, antiseptic 8-10 parts, plasticizer 4-6 parts, toughener 4-6 parts, antioxidant 4-6 parts, lubricant 4-6 parts, Photoresist 4-6 parts.
2. a kind of perfume as claimed in claim 1 antibacterial polyvinyl chloride bottle, it is characterised in that the antiseptic is one or more mixture in silver nitrate, silver iodide, zinc oxide, nano silicon, nano titanium oxide.
3. a kind of perfume as claimed in claim 1 antibacterial polyvinyl chloride bottle, it is characterised in that the plasticizer is ATBC.
4. a kind of perfume as claimed in claim 1 antibacterial polyvinyl chloride bottle, it is characterised in that the toughener is copolymer of methyl methacrylatestyrene.
5. a kind of perfume as claimed in claim 1 antibacterial polyvinyl chloride bottle, it is characterised in that the antioxidant is phenolic antioxidant.
6. a kind of perfume as claimed in claim 1 antibacterial polyvinyl chloride bottle, it is characterised in that the lubricant is paraffin or Tissuemat E.
7. a kind of perfume as claimed in claim 1 antibacterial polyvinyl chloride bottle, it is characterised in that the Photoresist is cellulose or lignin.
8. a kind of perfume as described in one of claim 1-7 with antibacterial polyvinyl chloride bottle preparation method, it is characterised in that step is as follows：
1）, respectively weigh each raw material and add the raw material into and mixed in reactor, heat melting；
2）, by the raw material after melting pass through extruding machine extrusion moulding；
3）, the raw material of extrusion moulding is molded embryo by injection machine；
4）, by the embryo successively by bottle blowing, prolong modeling, cooling, it is interior it is cold, abandon and pressurize, be made bottled；
5）, finished product after de- bottle.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510977287.8A CN106905634A (en) | 2015-12-23 | 2015-12-23 | A kind of perfume antibacterial polyvinyl chloride bottle and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510977287.8A CN106905634A (en) | 2015-12-23 | 2015-12-23 | A kind of perfume antibacterial polyvinyl chloride bottle and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106905634A true CN106905634A (en) | 2017-06-30 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510977287.8A Pending CN106905634A (en) | 2015-12-23 | 2015-12-23 | A kind of perfume antibacterial polyvinyl chloride bottle and preparation method thereof |
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| Country | Link |
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| CN (1) | CN106905634A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110527215A (en) * | 2019-09-02 | 2019-12-03 | 华南理工大学 | A kind of PVC plastic and preparation method thereof with from anti-microbial property |
| CN110964252A (en) * | 2019-12-18 | 2020-04-07 | 苏州洁之宝塑料制品有限公司 | Medicine storage bottle and preparation method thereof |
-
2015
- 2015-12-23 CN CN201510977287.8A patent/CN106905634A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110527215A (en) * | 2019-09-02 | 2019-12-03 | 华南理工大学 | A kind of PVC plastic and preparation method thereof with from anti-microbial property |
| CN110964252A (en) * | 2019-12-18 | 2020-04-07 | 苏州洁之宝塑料制品有限公司 | Medicine storage bottle and preparation method thereof |
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170630 |