CN106904803A - Transfer electron formula electro-osmosis advanced oxidation sludge dewatering system and its dewatering - Google Patents

Transfer electron formula electro-osmosis advanced oxidation sludge dewatering system and its dewatering Download PDF

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Publication number
CN106904803A
CN106904803A CN201710184067.9A CN201710184067A CN106904803A CN 106904803 A CN106904803 A CN 106904803A CN 201710184067 A CN201710184067 A CN 201710184067A CN 106904803 A CN106904803 A CN 106904803A
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electro
osmosis
sludge
medicament
injection tube
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CN106904803B (en
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李亚林
刘蕾
楚云鹏
李晓冉
魏添
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Henan Institute of Engineering
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Henan Institute of Engineering
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/006Electrochemical treatment, e.g. electro-oxidation or electro-osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/06Treatment of sludge; Devices therefor by oxidation
    • C02F11/08Wet air oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatment Of Sludge (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

Transfer electron formula electro-osmosis advanced oxidation sludge dewatering system and its dewatering, including power supply, both positive and negative polarity converter and underframe, underframe top is provided with mounting bracket, electric osmose liquid collecting bin below mounting bracket is installed on underframe, the electro-osmosis reactor that profile is cuboid is installed on mounting bracket, administration injection device is connected with by rope yarn on mounting bracket, it is left and right horizontal direction with the length direction of electro-osmosis reactor, the width and length of electric osmose liquid collecting bin are all higher than the width and length of electro-osmosis reactor, the left side and right side of electro-osmosis reactor are open, sludge mouthful is offered at the top of electro-osmosis reactor, rear side is hinged with cover plate by hinge at sludge mouthful, cover plate front side is connected by hasp with the roof of electro-osmosis reactor;In sum, the present invention combines advanced oxidation and sludge is dehydrated by electro-osmosis, without add substantial amounts of advanced oxidation agent, will not caused by the excessive corrosion of generation battery lead plate heavy metal pollution, technological process it is simple.

Description

Transfer electron formula electro-osmosis advanced oxidation sludge dewatering system and its dewatering
Technical field
The invention belongs to sludge dewatering technical field, and in particular to a kind of transfer electron formula electro-osmosis advanced oxidation sludge takes off Water system and its dewatering.
Background technology
Sludge is that produce after Sewage Plant active sludge treatment waste water a kind of is highly soluble in the solid matter of water, wherein containing Substantial amounts of organic matter, poisonous and harmful substance and some inorganic matter fragments.
Sludge has the features such as yield is big, moisture content is high, intractability is big, does not dispose or ineptly treatment sludge has Secondary pollution may be caused and the health of soil, water source, resident and livestock is endangered.It has been investigated that, the safe disposal of sludge is very It is effectively to remove the moisture in sludge to the secondary premise for utilizing, so as to reduce the difficulty of disposal link.
The processing mode that sewage treatment plant is commonly used is to utilize plate and frame filter press, centrifugal dehydrator or belt filter press, Shallow-layer treatment is carried out to sludge by the physics mode such as extruding or centrifugation.Sludge after above-mentioned PROCESS FOR TREATMENT cannot meet me substantially The increasingly strict specific resistance to filtration standard of state.
In view of the foregoing, deep dehydration technology is increasingly becoming the new way of sludge dewatering.Advanced oxidation system Yin Qigao The characteristics of water separation capability and shirtsleeve operation mode of effect once turn into research, but due to many actual limitations cannot extensive use, Such as advanced oxidation system is only for the liquid sludge of moisture content 95%-99%, the dirt after largely adding handled by inorganic medicament Mud cannot be utilized directly, and the filtrate of removing could be flowed back after must also carrying out complicated treatment.
Chinese patent literature《A kind of method for improving dehydrating municipal sludge performance》(Publication number CN105502882A)Announce A kind of technique of advanced oxidation deep dehydration, adds specifically by the municipal sludge that moisture content is 98%-99% or so Ferrous salt and persulfate are stirred reaction, add quick lime and are nursed one's health with portland cement, are obtained after suction filtration dehydration The mud cake of moisture content 50%-55%, the technique with the addition of substantial amounts of inorganic conditioner, and the filtrate after treatment is in strong basicity;In reality In the application of border, integrated artistic need to be transformed using the sewage treatment plant of mechanical dehydration, be otherwise difficult to.
Electro-osmosis technology has begun to small range and is applied to the dry of sludge as a kind of cleaning, efficient deep dehydration technology Change processing links.But traditional electro-osmosis technology there is also the shortcoming for limiting its application, for example:Carried out using only electro-osmosis technology During dehydration, the sludge after treatment is near anode-side moisture content 15%-20% lower than cathode side or so;Electro-osmosis anodic The speed of metal electrode corrosion is exceedingly fast, and the heavy metal ion produced after corrosion is into can cause heavy metal-polluted in sludge and filtrate Dye.
Electro-osmosis combined dehydration technology has turned into the research main flow of environmental industry.Chinese patent literature《One kind is for municipal administration The dewatering system of deeply dehydrating sludge》(Publication number CN204111556U)Disclose the depth that composite conditioner is added in a kind of electro-osmosis Degree dewatering type.Specifically, sludge dewatering to 70%-85% is then first carried out into electro-osmosis after the stirring of addition composite conditioner Dehydration, 50%-55% is reduced to by moisture content, and the technological process is complicated, and needs the substantial amounts of inorganic medicament of addition, electro-osmosis Mud cake lack of homogeneity afterwards, it is impossible to directly carry out follow-up sludge treatment.
The content of the invention
The present invention in order to solve weak point of the prior art, there is provided one kind need not add substantial amounts of advanced oxidation agent, Will not because produce battery lead plate excessive corrosion caused by heavy metal pollution, the simple senior oxygen of transfer electron formula electro-osmosis of technological process Change sludge dewatering system and its dewatering.
In order to solve the above technical problems, the present invention is adopted the following technical scheme that:Transfer electron formula electro-osmosis advanced oxidation is dirty Mud dewatering system, including power supply, both positive and negative polarity converter and underframe, underframe top are provided with mounting bracket, are provided with underframe positioned at peace The electric osmose liquid collecting bin of lower section is shelved, the electro-osmosis reactor that profile is cuboid is installed on mounting bracket, passed through on mounting bracket Rope yarn is connected with administration injection device, is left and right horizontal direction with the length direction of electro-osmosis reactor, electric osmose liquid collecting bin Width and length are all higher than the width and length of electro-osmosis reactor, and the left side and right side of electro-osmosis reactor are open, electric osmose Offer sludge mouthful at the top of saturating reactor, sludge mouthful place rear side is hinged with cover plate by hinge, cover plate front side by hasp and The roof connection of electro-osmosis reactor;The inwall of electro-osmosis reactor is provided with filter cloth, the front side wall of electro-osmosis reactor, rear wall Some permeable holes are offered with bottom, correspondence offers medicine feeding hole, medicine feeding hole on the front side wall and filter cloth of electro-osmosis reactor At least provided with two, plug is provided with medicine feeding hole;The left side and right side of electro-osmosis reactor are respectively equipped with one group of electrode group, two groups Center line of the electrode group on electro-osmosis reactor is symmetrical set, and the electrode group positioned at left side includes hydraulic cylinder and iron electrode Plate, the cylinder body of hydraulic cylinder is fixed on the left side of mounting bracket and its axis is set along left and right horizontal direction, and ferroelectricity pole plate is slidably connected In electro-osmosis reactor, the lateral wall of ferroelectricity pole plate coordinates with the inner wall sealing of electro-osmosis reactor, the piston rod of hydraulic cylinder It is connected to the left surface of ferroelectricity pole plate;Power supply, both positive and negative polarity converter and two pieces of ferroelectricity pole plates are connected by wire;
Administration injection device includes push rod and injection tube, one end closure of injection tube and other end opening, the closure end of injection tube Circular hole is offered, push rod slides and is plugged in circular hole and extend into injection tube, and the one end for the push rod extending into injection tube is consolidated Surely there is piston, the other end of push rod is provided with the handle outside injection tube, and piston outer rim is slided and sealed with injection tube inwall Coordinate, the side of piston is fixed with rotating shaft, and rotating shaft is coaxially set with injection tube;The opening end of injection tube is provided with stirring spraying machine Structure.
Internal thread is offered on the inside of the open end of injection tube, stirring injection equipment includes the injector head of cone cylinder structure, Some spray-holes are uniformly offered on injection rostral wall, coaxial line is fixed with columnar erecting bed on injector head, outside erecting bed Side offers external screw thread, and erecting bed is threaded in the open end of injection tube, fixed mount is fixed with erecting bed, on fixed mount Fixing axle is fixed with, fixing axle is coaxially set with injection tube, flabellum, the precession direction court of flabellum are rotatably connected in fixing axle To injector head.
The open end face of injection tube is provided with rubber gasket with the joint of injector head.
The periphery of cover plate is provided with sealing strip with the joint of electro-osmosis reactor.
The dewatering of transfer electron formula electro-osmosis advanced oxidation sludge dewatering system, comprises the following steps:
(1), prepare medicament;According to selected advanced oxidation agent and the medicament of the proportions respective concentration of sludge, selected senior oxygen Agent is hydrogen peroxide, sodium peroxide, calper calcium peroxide, sodium peroxydisulfate, potassium peroxydisulfate or ammonium persulfate;
(2), load sludge;Hasp is opened, cover plate is opened, by sludge mouthful to sludge is loaded in electro-osmosis reactor, lid is closed Plate, locks hasp;
(3), by administration injection device to injecting medicament in electro-osmosis reactor;
(4)Electroosmotic dewatering;Turn on the power, two pieces of ferroelectricity pole plates obtain electric, at the same time start two hydraulic cylinders, two hydraulic cylinders Two pieces of ferroelectricity pole plates are promoted to move towards, two pieces of ferroelectricity pole plates start to carry out the sludge in electro-osmosis reactor electro-osmosis and squeeze Pressure, wherein in the presence of both positive and negative polarity converter, through certain frequency time change electrode, final sludge is in medicine for two pieces of ferroelectricity pole plates Deviate from water in the presence of agent, electro-osmosis and extruding force and produce gas, the gaseous volatilization of generation is dissipated, the water of abjection is through filter Cloth flows out from permeable hole, finally flow in electric osmose liquid collecting bin;
(5)Collect mud cake;After electroosmotic dewatering, sludge forms mud cake, closes power supply and two hydraulic cylinders, opens hasp and beats Uncap plate, pressed from both sides out the mud cake in electro-osmosis reactor using clamping device.
Step(3)In by administration injection device in electro-osmosis reactor inject medicament specific method be:Will injection In the medicament that head insertion has been prepared, handle is then pulled upwards, handle pulls piston to move up by push rod, so as in work Medicament after being filled medicament in injection tube, extracts the plug at medicine feeding hole, then from spray-hole suction injection tube in the presence of plug By in the sludge of injection tube insertion electro-osmosis reactor, driving handle while in injection tube insertion sludge makes piston to inject Medicament in cylinder sprays from the spray-hole of injector head, and because medicament flows along the axial direction of injection tube, flabellum is by medicament Rotated under the impact of flowing, so as to be stirred to the medicament by flabellum, because medicament has revolving force, medicament by flabellum Enter into injector head further to mix, injector head is cone cylinder structure in addition, and spray-hole is arranged on the side wall of injector head, so medicine Agent can scatter when being sprayed from injector head to surrounding, finally equably be injected in sludge, during push rod injection is promoted, injection Cylinder is moved back and forth along the longitudinal direction in electro-osmosis reactor, reaches the effect of more uniform injection, is noted in a medicine feeding hole After shooting away medicament, reselection another medicine feeding hole repetition above injection process;After injection medicament, injection tube is extracted and by plug Again get back at medicine feeding hole.
Above-mentioned technical proposal is used, the invention has the advantages that:
(1)Technique of the invention is dehydrated using electro-osmosis technical tie-up advanced oxidation, can be to the liquid of moisture content 75%-99% Or semisolid sludge is processed, significantly reduce the sludge after the moisture content of sludge, and treatment and can be directly used for subsequently Sludge treatment;
(2)The present invention can presently, there are the wide sludge of form and carry out dewater treatment for two kinds(What i.e. moisture content was higher is in The relatively low primary dewatering sludge in solid-state of dilute sludge and moisture content of liquid);
(3)Present invention process only needs a small amount of advanced oxidation agent of addition, i.e. reflowable after handled electric osmose liquid simple process;
(4)Device of the invention using both positive and negative polarity converter go to change two pieces of ferroelectricity pole plates electric situation, not only improve mud The uniformity of cake, also slow down the extent of corrosion of positive plate to a certain extent;
(5)The battery lead plate that device of the invention is used is ferroelectricity pole plate, the Fe that ferroelectricity pole plate is produced after corrosion2+Can pair plus The advanced oxidation agent for entering activated, and lifts the deep dehydration effect of sludge, it is to avoid conventional to be produced using other metal electrodes Secondary pollution phenomenon;
(6)Device of the invention has installed hydraulic means additional at the left and right two ends of electro-osmosis reactor, effectively improves dehydration speed Rate, dehydrating effect has also obtained significant raising;
(7)Device of the invention offers permeable hole in the outer wall of electro-osmosis reactor, the structure be capable of will produce gas with And penetrating fluid is quickly discharged, so as to rate of water loss is greatly improved, dewatering time is shortened;
(8)Present invention employs electro-osmosis compound advanced oxidation technology treatment sludge, and the use of the complex technique can be effective Ground lifting water separation capability, moreover it is possible to which the consumption of a certain degree of reduction medicament, so as to avoid the generation of secondary pollution, this is due to height The property of level oxidant change sludge in sludge handling process, the structure of destruction sludge constraint moisture, and electro-osmosis process It is responsible for the moisture in removing sludge, therefore a large amount of inorganic flocculating agents need not be added;
(9)Present invention process obtains electric situation during electro-osmosis by both positive and negative polarity converter two pieces of ferroelectricity pole plates of change( After dehydration a period of time, the positive pole of ferroelectricity pole plate becomes negative pole, and another piece of negative pole of ferroelectricity pole plate becomes positive pole)Imitated for Treatment of Sludge Fruit is greatly improved, and first, the anodic attack of electro-osmosis technology is difficult to avoid that very much, and the anticorrosive material for working out now Material also mostly cannot volume production, therefore can effectively slow down anodic attack speed using both positive and negative polarity variable power supply, secondly, electro-osmosis In processing procedure, the moisture in sludge is largely moved from anode to negative electrode, at the end of processing procedure, cathode side sludge often by In treatment not exclusively remain substantial amounts of moisture, using both positive and negative polarity variable power supply make the sludge of cathode side residual moisture carry out again by Treatment, so as to lift treatment effect;
(10)System of the invention provides a kind of injection chemicals dosing plant, and the injection chemicals dosing plant is connected to mounting bracket by rope yarn On, prevent its commonly using when lose;The sludge in electro-osmosis reactor is added additionally by the injection chemicals dosing plant Medicine so that sludge can fully receive medicament, wherein because medicament flows along the axial direction of injection tube, flabellum is by medicine Rotated under the impact of agent flowing, so as to be stirred to the medicament by flabellum, because medicament has revolving force, medicine by flabellum Agent enters into injector head and further mixes, and the principle of its stirring is:The air that drives according to fan produces axial flow of air Principle, in turn, when fluid moves axially through flabellum, can drive flabellum to rotate;Other injector head is cone cylinder structure, spray-hole It is arranged on the side wall of injector head, so medicament can scatter when being sprayed from injector head to surrounding, is finally equably injected in sludge Interior, during push rod injection is promoted, injection tube is moved back and forth in the fore-and-aft direction of electro-osmosis reactor, reaches more uniform note The effect penetrated;Injector head is threaded in the end of injection tube by erecting bed, and be so easy for installation and maintenance flabellum.
Brief description of the drawings
Fig. 1 is the structural representation of the oxidising dehydration reactor of electric osmose;
Fig. 2 is the top view of Fig. 1;
Fig. 3 is the structural representation of administration injection device;
Fig. 4 is the enlarged drawing at I in Fig. 3;
Fig. 5 is the structural representation that flabellum is arranged on erecting bed.
Specific embodiment
As Figure 1-5, transfer electron formula electro-osmosis advanced oxidation sludge dewatering system of the invention, including power supply, just Negative pole converter and underframe 6(Power supply and both positive and negative polarity converter are existing conventional techniques, not shown in figure), the top of underframe 6 is provided with Mounting bracket 7, is provided with the electric osmose liquid collecting bin 8 positioned at the lower section of mounting bracket 7 on underframe 6, it is rectangular that profile is provided with mounting bracket 7 The electro-osmosis reactor 9 of body, administration injection device 24 is connected with mounting bracket 7 by rope yarn, with the length of electro-osmosis reactor 9 Direction is left and right horizontal direction, and the width and length of electric osmose liquid collecting bin 8 are all higher than the width and length of electro-osmosis reactor 9, The left side and right side of electro-osmosis reactor 9 are open, and the top of electro-osmosis reactor 9 offers sludge mouthful, rear side at sludge mouthful Cover plate 11 is hinged with by hinge 10, the front side of cover plate 11 is connected by hasp 12 with the roof of electro-osmosis reactor 9;Electro-osmosis The inwall of reactor 9 is provided with filter cloth, and the front side wall of electro-osmosis reactor 9, rear wall and bottom offer some permeable holes 13, Correspondence offers medicine feeding hole on the front side wall and filter cloth of electro-osmosis reactor 9, and medicine feeding hole is provided with least provided with two at medicine feeding hole Plug 14;The left side and right side of electro-osmosis reactor 9 are respectively equipped with one group of electrode group, and two arrays of electrodes group is on electro-osmosis reactor 9 center line is symmetrical set, and the electrode group positioned at left side includes hydraulic cylinder 15 and ferroelectricity pole plate 16, and the cylinder body of hydraulic cylinder 15 is consolidated The left side and its axis for being scheduled on mounting bracket 7 are set along left and right horizontal direction, and ferroelectricity pole plate 16 is slidably connected at electro-osmosis reactor 9 Interior, the lateral wall of ferroelectricity pole plate 16 coordinates with the inner wall sealing of electro-osmosis reactor 9, and the bar of piston 4 of hydraulic cylinder 15 is connected to iron The left surface of battery lead plate 16;Power supply, both positive and negative polarity converter and two pieces of ferroelectricity pole plates 16 are connected by wire.
Administration injection device 24 includes push rod 1 and injection tube 2, one end closure of injection tube 2 and other end opening, injection tube 2 closure end offers circular hole 3, and push rod 1 slides and is plugged in circular hole 3 and extend into injection tube 2, extend into injection tube 2 One end of push rod 1 be fixed with piston 4, the other end of push rod 1 is provided with the handle 5 outside injection tube 2, the outer rim of piston 4 with The inwall of injection tube 2 is slided and seals cooperation;The opening end of injection tube 2 is provided with stirring injection equipment;
Internal thread is offered on the inside of the open end of injection tube 2, stirring injection equipment includes the injector head 17 of cone cylinder structure, spray Penetrate and some spray-holes 18 are uniformly offered on the wall of first 17 side, coaxial line is fixed with columnar erecting bed 19 on injector head 17, pacify The outside of dress platform 19 offers external screw thread, and erecting bed 19 is threaded in the open end of injection tube 2, erecting bed 19 and is fixed with Determine frame 23, fixing axle 20 is fixed with fixed mount 23, fixing axle 20 is coaxially set with injection tube 2, the company of rotation in fixing axle 20 It is connected to flabellum 21, the precession direction of flabellum 21 is towards injector head 17.
The open end face of injection tube 2 is provided with rubber gasket 22 with the joint of injector head 17.
The periphery of cover plate 11 is provided with sealing strip with the joint of electro-osmosis reactor 9.
The dewatering of transfer electron formula electro-osmosis advanced oxidation sludge dewatering system, comprises the following steps:
(1), prepare medicament;According to selected advanced oxidation agent and the medicament of the proportions respective concentration of sludge, selected senior oxygen Agent is hydrogen peroxide, sodium peroxide, calper calcium peroxide, sodium peroxydisulfate, potassium peroxydisulfate or ammonium persulfate;(Such as:Control sludge with The mass ratio of hydrogen peroxide is 1:0.03, or sodium peroxydisulfate and the mass ratio of sludge are 0.02:1)
(2), load sludge;Hasp 12 is opened, cover plate 11 is opened, by sludge mouthful to sludge is loaded in electro-osmosis reactor 9, closed Cover plate 11 is closed, hasp 12 is locked;
(3), by administration injection device 24 to injecting medicament in electro-osmosis reactor 9;Injector head 17 is inserted what is prepared In medicament, handle 5 is then pulled upwards, handle 5 pulls piston 4 to move up by push rod 1, so as in the presence of piston 4 Medicament after being filled medicament in injection tube 2, extracts the plug 14 at medicine feeding hole from the suction injection tube 2 of spray-hole 18, then will note In the sludge of the insertion electro-osmosis of shooting cylinder 2 reactor 9, driving handle 5 while in the insertion sludge of injection tube 2 makes piston 4 to inject Medicament in cylinder 2 sprays from the spray-hole 18 of injector head 17, and because medicament flows along the axial direction of injection tube 2, flabellum 21 exists Rotated under the impact flowed by medicament, so as to be stirred to the medicament by flabellum 21, because medicament has by flabellum 21 There is revolving force, medicament enters into injector head 17 and further mixes, and injector head 17 is cone cylinder structure in addition, and spray-hole 18 is arranged on spray Penetrate on first 17 side wall, so medicament can scatter when being sprayed from injector head 18 to surrounding, be finally equably injected in sludge, Promote during the injection of push rod 1, injection tube 2 is moved back and forth along the longitudinal direction in electro-osmosis reactor 9, reaches more uniform note The effect penetrated, after having injected medicament in a medicine feeding hole, reselection another medicine feeding hole repetition above injection process;Injection After medicament, extract injection tube 2 and get back at medicine feeding hole plug 14 again;
(4)Electroosmotic dewatering;Turn on the power, two pieces of ferroelectricity pole plates 16 obtain electric, at the same time start two hydraulic cylinders 15, two liquid Cylinder pressure 15 promotes two pieces of ferroelectricity pole plates 16 to move towards, and two pieces of ferroelectricity pole plates 16 start to enter the sludge in electro-osmosis reactor 9 Row electro-osmosis is simultaneously extruded, wherein in the presence of both positive and negative polarity converter, two pieces of ferroelectricity pole plates 16 are through certain frequency time change electricity Pole, final sludge deviates from water in the presence of medicament, electro-osmosis and extruding force and produces gas, and the gaseous volatilization of generation dissipates Fall, the water of abjection flows out through filter cloth from permeable hole 13, finally flow in electric osmose liquid collecting bin 8;
(5)Collect mud cake;After electroosmotic dewatering, sludge forms mud cake, closes power supply and two hydraulic cylinders 15, opens hasp 12 And cover plate 11 is opened, the mud cake in electro-osmosis reactor 9 is pressed from both sides out using clamping device.
The present embodiment not makees any formal limitation to shape of the invention, material, structure etc., every according to this hair Any simple modification, equivalent variations and modification that bright technical spirit is made to above example, belong to the technology of the present invention side The protection domain of case.

Claims (6)

1. transfer electron formula electro-osmosis advanced oxidation sludge dewatering system, it is characterised in that:Including power supply, both positive and negative polarity converter and Underframe, underframe top is provided with mounting bracket, and the electric osmose liquid collecting bin below mounting bracket is provided with underframe, is installed on mounting bracket The electro-osmosis reactor for having profile to be cuboid, administration injection device is connected with mounting bracket by rope yarn, is reacted with electro-osmosis The length direction of device is left and right horizontal direction, the width and length of electric osmose liquid collecting bin be all higher than electro-osmosis reactor width and Length, the left side and right side of electro-osmosis reactor is open, and sludge mouthful is offered at the top of electro-osmosis reactor, at sludge mouthful after Side is hinged with cover plate by hinge, and cover plate front side is connected by hasp with the roof of electro-osmosis reactor;Electro-osmosis reactor Inwall is provided with filter cloth, and the front side wall of electro-osmosis reactor, rear wall and bottom offer some permeable holes, electro-osmosis reactor Front side wall and filter cloth on correspondence offer medicine feeding hole, medicine feeding hole is provided with plug at least provided with two at medicine feeding hole;Electric osmose transflection The left side and right side of device is answered to be respectively equipped with one group of electrode group, center line of the two arrays of electrodes group on electro-osmosis reactor is symmetrical to be set Put, the electrode group positioned at left side includes hydraulic cylinder and ferroelectricity pole plate, and the cylinder body of hydraulic cylinder is fixed on left side and its axle of mounting bracket Line is set along left and right horizontal direction, and ferroelectricity pole plate is slidably connected in electro-osmosis reactor, the lateral wall and electric osmose of ferroelectricity pole plate The inner wall sealing of saturating reactor coordinates, and the piston rod of hydraulic cylinder is connected to the left surface of ferroelectricity pole plate;Power supply, both positive and negative polarity converter Connected by wire with two pieces of ferroelectricity pole plates;
Administration injection device includes push rod and injection tube, one end closure of injection tube and other end opening, the closure end of injection tube Circular hole is offered, push rod slides and is plugged in circular hole and extend into injection tube, and the one end for the push rod extending into injection tube is consolidated Surely there is piston, the other end of push rod is provided with the handle outside injection tube, and piston outer rim is slided and sealed with injection tube inwall Coordinate, the side of piston is fixed with rotating shaft, and rotating shaft is coaxially set with injection tube;The opening end of injection tube is provided with stirring spraying machine Structure.
2. transfer electron formula electro-osmosis advanced oxidation sludge dewatering system according to claim 1, it is characterised in that:Injection Internal thread is offered on the inside of the open end of cylinder, stirring injection equipment includes the injector head of cone cylinder structure, on injection rostral wall Some spray-holes are uniformly offered, coaxial line is fixed with columnar erecting bed on injector head, erecting bed outside offers outer spiral shell Line, erecting bed is threaded in the open end of injection tube, and fixed mount is fixed with erecting bed, and fixation is fixed with fixed mount Axle, fixing axle is coaxially set with injection tube, is rotatably connected to flabellum in fixing axle, and the precession direction of flabellum is towards injector head.
3. transfer electron formula electro-osmosis advanced oxidation sludge dewatering system according to claim 2, it is characterised in that:Injection The open end face of cylinder is provided with rubber gasket with the joint of injector head.
4. transfer electron formula electro-osmosis advanced oxidation sludge dewatering system according to claim 3, it is characterised in that:Cover plate The joint of periphery and electro-osmosis reactor be provided with sealing strip.
5. the dewatering of transfer electron formula electro-osmosis advanced oxidation sludge dewatering system according to claim 4, it is special Levy and be:Comprise the following steps:
(1), prepare medicament;According to selected advanced oxidation agent and the medicament of the proportions respective concentration of sludge, selected senior oxygen Agent is hydrogen peroxide, sodium peroxide, calper calcium peroxide, sodium peroxydisulfate, potassium peroxydisulfate or ammonium persulfate;
(2), load sludge;Hasp is opened, cover plate is opened, by sludge mouthful to sludge is loaded in electro-osmosis reactor, lid is closed Plate, locks hasp;
(3), by administration injection device to injecting medicament in electro-osmosis reactor;
(4)Electroosmotic dewatering;Turn on the power, two pieces of ferroelectricity pole plates obtain electric, at the same time start two hydraulic cylinders, two hydraulic cylinders Two pieces of ferroelectricity pole plates are promoted to move towards, two pieces of ferroelectricity pole plates start to carry out the sludge in electro-osmosis reactor electro-osmosis and squeeze Pressure, wherein in the presence of both positive and negative polarity converter, through certain frequency time change electrode, final sludge is in medicine for two pieces of ferroelectricity pole plates Deviate from water in the presence of agent, electro-osmosis and extruding force and produce gas, the gaseous volatilization of generation is dissipated, the water of abjection is through filter Cloth flows out from permeable hole, finally flow in electric osmose liquid collecting bin;
(5)Collect mud cake;After electroosmotic dewatering, sludge forms mud cake, closes power supply and two hydraulic cylinders, opens hasp and beats Uncap plate, pressed from both sides out the mud cake in electro-osmosis reactor using clamping device.
6. the dewatering of transfer electron formula electro-osmosis advanced oxidation sludge dewatering system according to claim 5, it is special Levy and be:Step(3)In by administration injection device in electro-osmosis reactor inject medicament specific method be:By injector head In the medicament that insertion has been prepared, handle is then pulled upwards, handle pulls piston to move up by push rod, so as in piston In the presence of medicament from spray-hole suction injection tube in, after being filled medicament in injection tube, extract medicine feeding hole at plug, then will In the sludge of injection tube insertion electro-osmosis reactor, driving handle while in injection tube insertion sludge makes piston by injection tube Interior medicament sprays from the spray-hole of injector head, and because medicament flows along the axial direction of injection tube, flabellum is by medicament stream Rotated under dynamic impact, so as to be stirred to the medicament by flabellum, because medicament has revolving force by flabellum, medicament enters Enter to injector head and further mix, injector head is cone cylinder structure in addition, and spray-hole is arranged on the side wall of injector head, so medicament Can be scattered to surrounding when being sprayed from injector head, be finally equably injected in sludge, during push rod injection is promoted, injection tube Moved back and forth along the longitudinal direction in electro-osmosis reactor, reach the effect of more uniform injection, injected in a medicine feeding hole After complete medicament, reselection another medicine feeding hole repetition above injection process;After injection medicament, injection tube is extracted and by plug weight Newly get back at medicine feeding hole.
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CN109534628A (en) * 2018-11-30 2019-03-29 华南农业大学 The electric repair method in situ of black smelly pollutant in a kind of removal polluted bed mud
CN109608022A (en) * 2018-11-09 2019-04-12 启迪桑德环境资源股份有限公司 A kind of electro-osmosis filter plate
CN109867427A (en) * 2019-04-12 2019-06-11 河南工程学院 Dual oxide cooperates with electro-osmosis sludge lateral depth dewatering system and method
CN110240388A (en) * 2019-06-06 2019-09-17 河南工程学院 Exchange electrode electro-osmosis sludge dewatering system and method based on voltage hierarchical detection
CN110240387A (en) * 2019-06-06 2019-09-17 河南工程学院 Oxidative degradation organic matter rotary electric permeates sludge dewatering system and method
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CN108529835A (en) * 2018-04-19 2018-09-14 东北大学 A kind of device and method of employing periodic reverse electrocoagulation reinforcement sludge dehydration
CN108640450A (en) * 2018-05-29 2018-10-12 河海大学 A kind of original position silt sludge synchronization dehydration decontamination soilization disposition soil engineering bag combination unit
CN109608022A (en) * 2018-11-09 2019-04-12 启迪桑德环境资源股份有限公司 A kind of electro-osmosis filter plate
CN109534628A (en) * 2018-11-30 2019-03-29 华南农业大学 The electric repair method in situ of black smelly pollutant in a kind of removal polluted bed mud
CN109534628B (en) * 2018-11-30 2021-11-16 华南农业大学 In-situ electric repairing method for removing black and odorous pollutants in polluted bottom mud
CN109867427A (en) * 2019-04-12 2019-06-11 河南工程学院 Dual oxide cooperates with electro-osmosis sludge lateral depth dewatering system and method
CN110240388A (en) * 2019-06-06 2019-09-17 河南工程学院 Exchange electrode electro-osmosis sludge dewatering system and method based on voltage hierarchical detection
CN110240387A (en) * 2019-06-06 2019-09-17 河南工程学院 Oxidative degradation organic matter rotary electric permeates sludge dewatering system and method
CN110240388B (en) * 2019-06-06 2023-09-12 河南工程学院 Exchange electrode electroosmosis sludge dewatering system and method based on voltage grading detection
CN110240387B (en) * 2019-06-06 2023-12-22 河南工程学院 Rotary electroosmosis sludge dewatering system and method for oxidative degradation of organic matters
CN111499130A (en) * 2020-05-13 2020-08-07 中山市环保产业有限公司 Electrochemical sludge pretreatment device and sludge treatment method thereof

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