CN106894224A - A kind of halogen-free flameproof self-repairing super hydrophobic coating glue used for textiles and fire-retardant self-repairing super hydrophobic fabric - Google Patents
A kind of halogen-free flameproof self-repairing super hydrophobic coating glue used for textiles and fire-retardant self-repairing super hydrophobic fabric Download PDFInfo
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- CN106894224A CN106894224A CN201710144280.7A CN201710144280A CN106894224A CN 106894224 A CN106894224 A CN 106894224A CN 201710144280 A CN201710144280 A CN 201710144280A CN 106894224 A CN106894224 A CN 106894224A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/72—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with metaphosphoric acids or their salts; with polyphosphoric acids or their salts; with perphosphoric acids or their salts
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic System; Zincates; Cadmates
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/47—Oxides or hydroxides of elements of Groups 5 or 15 of the Periodic System; Vanadates; Niobates; Tantalates; Arsenates; Antimonates; Bismuthates
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/328—Amines the amino group being bound to an acyclic or cycloaliphatic carbon atom
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
Abstract
A kind of halogen-free flameproof self-repairing super hydrophobic coating glue used for textiles and fire-retardant self-repairing super hydrophobic fabric, belong to textile finish technical field.The coating adhesive is stirred well to uniformly after being mixed by 100mL solvents, 0~10.0g halogen-free flame retardants, 0.01~10.0g retardant synergists, 0.01~10.0g thickeners, 0.01~10.0g Halogens water-repelling agent, is obtained after being configured to mixed dispersion liquid.The present invention can easily assign fabrics flame resistance and self-repairing super hydrophobic function.Ultra-hydrophobicity assigns the good water proofing property of fabric and automatic cleaning action, can simultaneously be effectively improves the stability of fabrics flame resistance function.Additionally, super-hydrophobicity can be recovered after impaired by selfreparing.Fire-retardant self-repairing super hydrophobic coating glue preparation process prepared by the present invention is simple, meets environmental protection, and the technological requirement of low cost simultaneously can be widely applied to bedding, and home decoration etc. meets the requirement of development new material, with wide market application foreground.
Description
Technical field
The invention belongs to textile finish technical field, and in particular to a kind of halogen-free flameproof selfreparing used for textiles is super thin
Water coating adhesive and fire-retardant self-repairing super hydrophobic fabric.
Background technology
Fabric is seen everywhere in the life of people.But due to its inflammable characteristic, in the last few years because fabric burning is made
Into personal injury and property loss it is also more and more many.Therefore, to carry out flame retardant treatment to fabric imperative.Compared to China,
The American-European relatively early research begun to flame-retardant textile.The development ＆ production of China's flame-retardant textile starts from the sixties in 20th century.Up to
Although today, the research and development and production of China's flame-retardant textile achieve considerable progress, but still cannot meet growing need
Ask.Nowadays, it is a kind of the most commonly used method for preparing flame-retardant textile flame retardant treatment to be carried out to fabric using flame-retardant coatings glue.But
Be, existing flame-retardant coatings glue exist some shortcomings, one of them be exactly coating adhesive stability it is not good enough.Due to flame-retardant coatings glue
Readily soluble or labile feature, after carrying out washing cleaning to flame-retardant textile, the reduction that the anti-flammability of fabric can be drastically is even lost.
Therefore, it is still a challenge as how inexpensive mode prepares the flame-retardant coatings glue with good stability.
In recent years, with the development of bionics and nano science, research of the people to super hydrophobic material is more thorough.It is similar
In lotus leaf, feather of palmipeds etc., artificial super hydrophobic material has extremely strong hydrophobic ability.Water droplet is contacted on super hydrophobic material
Angle is more than 150 °, and roll angle is less than 10 °.Therefore, super hydrophobic material has wide practical use in anticorrosion, automatically cleaning field.
Super hydrophobic functional is incorporated into flame-retardant coatings glue, the novel flame-retardant with superpower waterproof ability and self-cleaning performance can be obtained
Fabric.Due to the self-cleaning property that super hydrophobic functional brings, fire-retardant superhydrophobic fabric does not need prolonged washing by soaking, it is only necessary to
Being rinsed with a small amount of water can remove the dust and spot of fabric face, greatly reducing time and face that coating adhesive is contacted with water
Product, therefore the service life of flame-retardant textile can be effectively improved.Additionally, the research and development of self-repairing super hydrophobic material are received in the recent period
Extensive concern.Being irradiated with, chemical attack or after scratching, self-repairing super hydrophobic material can be spontaneous to being damaged
Function is repaired, so as to effectively improve the service life of material.Therefore, the preparation tool of fire-retardant self-repairing super hydrophobic coating glue
There is important scientific research and economic implications.But the research of this respect is few.By literature search, only one periodical text
Offer the method for preparing fire-retardant self-repairing super hydrophobic fabric that reports (referring to ACS Nano 2015,9,4070-4076).But the party
Method has certain defect：(1) the method is excessively complicated.In order to realize the preparation of fire-retardant superhydrophobic fabric, it is necessary to enter to fabric
The treatment of row multi-time modification, takes a substantial amount of time and the energy, and is difficult mutually compatible with existing production equipment.(2) the method makes
Material has fluorine-containing material, and expensive and to environment and user health has potentially hazardous.
The content of the invention
The invention aims to the defect for overcoming prior art to exist, a kind of Halogen used for textiles of low cost is prepared
Fire-retardant self-repairing super hydrophobic coating glue and the fire-retardant self-repairing super hydrophobic fabric by being obtained after coating adhesive coating.The coating adhesive can
Fabric face is coated to by the method once soaked, there is provided good fire resistance and self-repairing super hydrophobic performance.
A kind of halogen-free flameproof self-repairing super hydrophobic coating glue used for textiles of low cost of the present invention, its component is：
Comprising 0~10.0g halogen-free flame retardants in per 100mL solvents, 0.01~10.0g retardant synergists, 0.01~10.0g thickeners,
0.01~10.0g Halogen water-repelling agents.
It is stirred well to uniformly after above-mentioned component mixing, is configured to mixed dispersion liquid, that is, is obtained halogen-free flameproof selfreparing and surpass
Hydrophobic coating glue.
Preferably, described halogen-free flame retardants can select APP (APP), melamine resin emulsion,
One or more combination in triphenyl phosphate.
Preferably, described Halogen water-repelling agent can select paraffin, beeswax, palm wax, octadecylamine, octadecanoid acid
In one or more combination.
Preferably, during described retardant synergist can select antimony oxide, nano zine oxide, nano silicon
One or more combination.
Preferably, described thickener can select polyacrylate dispersion, dimethyl silicone polymer (PDMS), poly- ammonia
One or more combination in ester emulsion.
Preferably, described solvent can select to combine for one or more in tetrahydrofuran, acetone.
A kind of fire-retardant self-repairing super hydrophobic fabric, is that fabric (pure cotton, terylene etc.) is immersed in into foregoing textile
With after 5~30 minutes, taking-up is obtained after drying, and the fire-retardant selfreparing is super thin in halogen-free flameproof self-repairing super hydrophobic coating sol solution
Water fabric has good flame-retardance energy and self-repairing super hydrophobic performance.
The fabric prepared using the present invention has good flame retardant effect, and burning things which may cause a fire disaster withdraws rear fabric self-extinguish, is fabric
Large-scale use provide safe and reliable guarantee.Ultra-hydrophobicity assigns fabric good water proofing property, and water droplet is on its surface
Contact angle be more than 150 °, roll angle be less than 10 °, fire retardant can be effectively protected.Super-hydrophobicity is by ultraviolet, chemistry
After corrosion, 0.5~8 hour is kept at 30~90 DEG C, water-repelling agent can be diffused into impaired region, make the hydrophobicity of fabric extensive
The multiple state to before being damaged.Such reparation destruction can be repeated 10 times the above, so that it is super thin effectively to extend fire-retardant selfreparing
The service life of water fabric.Additionally, this invention is not limited to provide fire-retardant self-repairing super hydrophobic function for flammable fabric, it is also possible to logical
Formula composition is overregulated, removes halogen-free flame retardants, be coated on the fabric for had anti-flaming function as it provides lasting oneself
Repair super hydrophobic functional.Fire-retardant self-repairing super hydrophobic coating glue preparation process prepared by the present invention is simple, the resistance for being used
Combustion agent, water-repelling agent are free of halogen, and environment-protecting asepsis can be widely applied to bedding, home decoration etc., meet development new material
Requirement, with wide market application foreground.
Brief description of the drawings
Fig. 1：A) freshly prepd fire-retardant self-repairing super hydrophobic fabric face contact angle photo；B) fire-retardant self-repairing super hydrophobic is knitted
Contact angle photo of the thing by surface after oxygen plasma etch；C) table after selfreparing is carried out by the fabric after oxygen plasma etch
The contact angle photo in face；Correspondence embodiment 1.
Fig. 2：Fire-retardant self-repairing super hydrophobic fabric combustion testing photo.A) fabric contacts photo with burning things which may cause a fire disaster；B) burning things which may cause a fire disaster is withdrawn
The photo after fabric self-gravitation, corresponds to embodiment 1 afterwards.
Fig. 3：A) freshly prepd fire-retardant self-repairing super hydrophobic fabric face contact angle photo；B) fire-retardant self-repairing super hydrophobic is knitted
Contact angle photo of the thing by surface after oxygen plasma etch；C) table after selfreparing is carried out by the fabric after oxygen plasma etch
The contact angle photo in face；Correspondence embodiment 3.
Fig. 4：Fire-retardant self-repairing super hydrophobic fabric combustion testing photo.A) fabric contacts photo with burning things which may cause a fire disaster；B) burning things which may cause a fire disaster is withdrawn
The photo after fabric self-gravitation, corresponds to embodiment 3 afterwards.
Specific embodiment
Embodiment 1
Pure cotton fabric halogen-free flameproof self-repairing super hydrophobic coating glue is formulated as follows：
Solvent：100mL tetrahydrofurans；Halogen-free flame retardants：2.0g polyphosphoric acid amines (APP)；Retardant synergist：1.0g zinc oxide
Nano-particle；Thickener：1.0g polyacrylate dispersions；Halogen water-repelling agent：0.2g paraffin.
It is formulated more than, successively to addition 100mL tetrahydrofurans in the beaker of 250mL, 2.0g polyphosphoric acid amines (APP),
1.0g zinc oxide nano-particles, 1.0g polyacrylate dispersions, 0.2g paraffin is stirred well to uniformly, is configured to mixing dispersion
Liquid, that is, obtain halogen-free flameproof self-repairing super hydrophobic coating glue of the present invention.Pure cotton fabric is soaked in above-mentioned mixing dispersion
Liquid 5min, takes out, and suspension nature dries, you can obtain fire-retardant self-repairing super hydrophobic fabric.
By the fire-retardant self-repairing super hydrophobic fabric prepared by above method, contact angle reaches 158 °, rolling to water droplet thereon
Dynamic angle is less than 5 °, with good superhydrophobic property (Fig. 1 a).After the oxygen plasma etch 5 minutes by 200 watts, fabric
Super-hydrophobicity destroyed, contact angle is changed into 0 ° (Fig. 1 b).Impaired fabric is heated to 80 DEG C of holding 30min, you can make
Contact angle returns to 158 ° (Fig. 1 c), realizes the selfreparing of super-hydrophobicity.This impaired/repair process can be repeated 10 times with
On.The fabric has good flame retardant effect simultaneously.After burning things which may cause a fire disaster is removed (Fig. 2 a), fabric extinguishes immediately, and the length that overdoes is less than
4cm (Fig. 2 b).As a comparison, unmodified fabric is burnt away after burning things which may cause a fire disaster is removed until all burning out.
Embodiment 2
Pure cotton fabric halogen-free flameproof self-repairing super hydrophobic coating glue is formulated as follows：
Solvent：100mL acetone；Halogen-free flame retardants：10.0g triphenyl phosphates；Retardant synergist：10.0g zinc-oxide nanos
Particle；Thickener：10.0g dimethyl silicone polymers (PDMS)；Halogen water-repelling agent：10.0g palm waxs.
It is formulated more than, successively to addition 100mL acetone, 10.0g triphenyl phosphates, 10.0g oxygen in the beaker of 250mL
Change zinc nano-particle, 10.0g dimethyl silicone polymers (PDMS), 10.0g palm waxs are stirred well to uniformly, are configured to mixing
Dispersion liquid, that is, obtain halogen-free flameproof self-repairing super hydrophobic coating glue of the present invention.Pure cotton fabric is soaked in above-mentioned mixing
Dispersion liquid 5min, takes out, and suspension nature dries, you can obtain fire-retardant self-repairing super hydrophobic fabric.
By the fire-retardant self-repairing super hydrophobic fabric prepared by above method, contact angle reaches 159 °, rolling to water droplet thereon
Dynamic angle is less than 3 °, with good superhydrophobic property.The fabric has good flame retardant effect simultaneously.After burning things which may cause a fire disaster is removed, knit
Thing extinguishes immediately, and the length that overdoes is less than 4cm.After the oxygen plasma etch 5 minutes by 200 watts, the super-hydrophobicity of fabric
Destroyed, contact angle is changed into 0 °.Impaired fabric is heated into 30 DEG C to be kept for 8 hours, you can make contact angle return to 159 °,
Realize the selfreparing of super-hydrophobicity.Compared with Example 1, halogen-free flameproof self-repairing super hydrophobic coating glue prepared in this example
With bigger concentration, thus the fire-retardant self-repairing super hydrophobic fabric prepared using this coating adhesive than embodiment 1 in it is fire-retardant from
Repairing superhydrophobic fabric has stronger prosthetic.The fire-retardant self-repairing super hydrophobic fabric can be damaged/be repaired by 20 times
Cheng Yiran keeps good super-hydrophobicity.
Embodiment 3
Flame retardant polyester fabric halogen-free flameproof self-repairing super hydrophobic coating glue is formulated as follows：
Solvent：100mL acetone solvents；Retardant synergist：1.5g Nano particles of silicon dioxide；Thickener：The poly- diformazans of 1.0g
Radical siloxane (PDMS)；Halogen water-repelling agent：0.25g beeswaxs.
It is formulated more than, successively to addition 100mL acetone in the beaker of 250mL, 1.5g Nano particles of silicon dioxide,
1.0g dimethyl silicone polymers (PDMS), 0.25g beeswaxs are stirred well to uniformly, are configured to mixed dispersion liquid.By flame-resistant terylene
Fabric is soaked in above-mentioned mixed dispersion liquid 10min, takes out, and suspension nature dries, and obtains fire-retardant self-repairing super hydrophobic fabric.
By fire-retardant superhydrophobic fabric prepared by above method, water droplet reaches 160 ° in its surface contact angle, and roll angle is small
In 3 °, with good superhydrophobic property (Fig. 3 a).After the oxygen plasma etch 5 minutes by 200 watts, super-hydrophobicity is received
To destruction, contact angle is changed into 0 ° (Fig. 3 b).Impaired fabric is heated to 80 DEG C of holding 30min, you can return to contact angle
160 ° (Fig. 3 c), realizes the selfreparing of super-hydrophobicity.The fabric has good flame retardant effect simultaneously.(figure after burning things which may cause a fire disaster is removed
4a), fabric extinguishes (Fig. 4 b) immediately.
Embodiment 4
Flame retardant polyester fabric halogen-free flameproof self-repairing super hydrophobic coating glue is formulated as follows：
Solvent：100mL tetrahydrofurans；Retardant synergist：0.01g antimony oxides；Thickener：0.01g poly dimethyl silicon
Oxygen alkane (PDMS)；Halogen water-repelling agent：0.01g octadecylamines.
It is formulated more than, successively to addition 100mL tetrahydrofurans in the beaker of 250mL, 0.01g antimony oxides,
0.01g dimethyl silicone polymers (PDMS), 0.01g octadecylamines are stirred well to uniformly, are configured to mixed dispersion liquid.Will
Flame retardant polyester fabric is soaked in above-mentioned mixed dispersion liquid 30min, takes out, and suspension nature dries, and obtains fire-retardant self-repairing super hydrophobic and knits
Thing.
By fire-retardant superhydrophobic fabric prepared by above method, water droplet reaches 160 ° in its surface contact angle, and roll angle is small
In 3 °, with good superhydrophobic property.The fabric has good flame retardant effect simultaneously.After burning things which may cause a fire disaster is removed, fabric is immediately
Extinguish.After the oxygen plasma etch 5 minutes by 200 watts, super-hydrophobicity is destroyed, and contact angle is changed into 0 °.Will be impaired
Fabric be heated to 90 DEG C holding 30min, you can contact angle is returned to 160 ° (Fig. 3 c), realize the selfreparing of super-hydrophobicity.
Compared with Example 3, halogen-free flameproof self-repairing super hydrophobic coating gum concentration prepared in this example is low, uses this coating adhesive system
Standby fire-retardant self-repairing super hydrophobic fabric than embodiment 3 in fire-retardant self-repairing super hydrophobic fabric restoration it is slightly worse.This is fire-retardant certainly
Repairing superhydrophobic fabric can still keep good super-hydrophobicity by 5 impaired/repair processes.It is prepared in this example
Halogen-free flameproof self-repairing super hydrophobic coating glue is applied to preparation fire-retardant self-repairing super hydrophobic fabric less demanding to prosthetic.
Claims (4)
1. a kind of halogen-free flameproof self-repairing super hydrophobic coating glue used for textiles, it is characterised in that：By 100mL solvents, 0~10.0g
Halogen-free flame retardants, 0.01~10.0g retardant synergists, 0.01~10.0g thickeners, the mixing of 0.01~10.0g Halogens water-repelling agent
After be stirred well to uniform, obtained after being configured to mixed dispersion liquid；Wherein, halogen-free flame retardants is APP, melamine first
One or more in urea formaldehyde emulsion, triphenyl phosphate；Halogen water-repelling agent be paraffin, beeswax, palm wax, octadecylamine,
One or more in octadecanoid acid；Retardant synergist is the one kind in antimony oxide, nano zine oxide, nano silicon
Or it is various；Thickener is one or more in polyacrylate dispersion, dimethyl silicone polymer, polyaminoester emulsion.
2. a kind of halogen-free flameproof self-repairing super hydrophobic coating glue used for textiles as claimed in claim 1, it is characterised in that：Solvent
It is one or more in tetrahydrofuran, acetone.
3. a kind of fire-retardant self-repairing super hydrophobic fabric, it is characterised in that：It is that fabric is immersed in the spinning described in claim 1 or 2
Fabric is with after 5~30 minutes, taking-up is obtained after drying in halogen-free flameproof self-repairing super hydrophobic coating sol solution.
4. a kind of fire-retardant self-repairing super hydrophobic fabric as claimed in claim 3, it is characterised in that：Fabric is pure cotton or terylene.
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| CN113026357A (en) * | 2021-03-23 | 2021-06-25 | 苏州莱昊新材料科技有限公司 | Preparation method of washable and self-repairing super-hydrophobic polyester fabric |
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