CN110295497A - A kind of aging-resistant flame-proof type canvas maceration extract - Google Patents
A kind of aging-resistant flame-proof type canvas maceration extract Download PDFInfo
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- CN110295497A CN110295497A CN201910456243.9A CN201910456243A CN110295497A CN 110295497 A CN110295497 A CN 110295497A CN 201910456243 A CN201910456243 A CN 201910456243A CN 110295497 A CN110295497 A CN 110295497A
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- Prior art keywords
- liquid
- parts
- maceration extract
- canvas
- aging
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- 239000000284 extract Substances 0.000 title claims abstract description 37
- 238000002803 maceration Methods 0.000 title claims abstract description 37
- 230000032683 aging Effects 0.000 title claims abstract description 22
- 239000007788 liquid Substances 0.000 claims abstract description 81
- 239000003063 flame retardant Substances 0.000 claims abstract description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000008367 deionised water Substances 0.000 claims abstract description 25
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 25
- 239000002994 raw material Substances 0.000 claims abstract description 22
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000006210 lotion Substances 0.000 claims abstract description 17
- 239000000945 filler Substances 0.000 claims abstract description 16
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 15
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 14
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 14
- 238000001035 drying Methods 0.000 claims abstract description 14
- 239000004593 Epoxy Substances 0.000 claims abstract description 13
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000839 emulsion Substances 0.000 claims abstract description 13
- 239000004816 latex Substances 0.000 claims abstract description 13
- 229920000126 latex Polymers 0.000 claims abstract description 13
- 229910052901 montmorillonite Inorganic materials 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 11
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 12
- 239000011574 phosphorus Substances 0.000 claims description 12
- 229910052698 phosphorus Inorganic materials 0.000 claims description 12
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims description 10
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
- 229920000388 Polyphosphate Polymers 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- 239000001205 polyphosphate Substances 0.000 claims description 6
- 235000011176 polyphosphates Nutrition 0.000 claims description 6
- 229920000877 Melamine resin Polymers 0.000 claims description 4
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 5
- 238000009472 formulation Methods 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 abstract description 3
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 description 8
- 238000002485 combustion reaction Methods 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 229910010271 silicon carbide Inorganic materials 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000004079 fireproofing Methods 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- -1 acrylic ester Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
- D06M13/358—Triazines
- D06M13/364—Cyanuric acid; Isocyanuric acid; Derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
- D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/55—Epoxy resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention discloses a kind of aging-resistant flame-proof type canvas maceration extract, including A liquid and B liquid, the wherein raw material in A liquid are as follows: water-based acrylic resin lotion, ptfe emulsion, dilute hydrochloric acid, montmorillonite, fire retardant and deionized water；Raw material in B liquid are as follows: silane coupling agent, age resister nano-titanium dioxide, epoxy curing agent, filler, butadiene-vinylpyridine copylymer latex, aqueous slkali and deionized water；When work, first openpore canvas is immersed in A liquid, after drying, then is immersed in B liquid, then drying and processing.The present invention is poor for canvas maceration extract flame retardant effect in the prior art, the technical problems such as roller surface formation convex block influence production are easily adhered to improve, by the way that age resister and suitable flame-retardant formulations are added into maceration extract, the surface that maceration extract is coated in canvas has preferable fire retardant performance, maceration extract is not easy to be adhered to the surface of roll during canvas is processed simultaneously, reduce the artificial worry except material, improves production efficiency.
Description
Technical field
The present invention relates to cloth maceration extract field more particularly to a kind of aging-resistant flame-proof type canvas maceration extracts.
Background technique
Existing Zhi Bu manufacturer is in order to improve the service performance of canvas, it will usually come to canvas in such a way that more baths are impregnated
It is surface modified, usually the surface of canvas can be first chemically treated, then the leaching by it by having fire proofing again
It is surface-treated in stain liquid, is then dried again, batched.And phosphorus flame retardant has nothing as a kind of halogen-free flame retardants
The advantages that poison, good flame retardation effect, it is used in the fields such as house cloth, fireproof facing material already.There is canvas more preferably to hinder
Fuel efficiency fruit, and the bond properties between rubber is more preferable, it has also become textile technology field urgent need to solve the problem at present.And
Existing canvas is on surface after chemical treatment, and in the sun, the chemical substance on surface is easy aging, becomes for exposure for a long time
Firmly, thus more easily by rain erosion.And existing maceration extract tends to be adhered to during conveying cloth drying
The surface of roll will be piled into soil block on the surface of roll after a period of time, influence the machine-shaping of cloth.
Against the above technical problems, the invention discloses a kind of aging-resistant flame-proof type canvas maceration extract, by maceration extract
Middle addition age resister and suitable flame-retardant formulations, the surface that maceration extract is coated in canvas have preferable fire protection flame retarding
Can, while maceration extract is not easy to be adhered to the surface of roll during canvas is processed, and reduces the artificial worry except material, improves
Production efficiency.
Summary of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of aging-resistant flame-proof type canvas maceration extract,
It is poor to solve canvas maceration extract flame retardant effect in the prior art, roller surface is easily adhered in process forms convex block shadow
Ring the technical problems such as production；The present invention can have preferable fire retardant performance, while the process that maceration extract is processed in canvas
In be not easy to be adhered to the surface of roll, reduce the artificial worry except material, improve production efficiency.
In order to solve the above technical problems, the invention discloses a kind of aging-resistant flame-proof type canvas maceration extracts, including A liquid and B
Liquid, the wherein raw material in A liquid are as follows: water-based acrylic resin lotion, ptfe emulsion, dilute hydrochloric acid, montmorillonite, fire retardant and
Deionized water；Water-soluble acrylic ester coating in A liquid is made of the copolymer resins of active cross-linking functional group, is made
The paint film of three-dimensional-structure is cross-linked to form between active function groups in film forming.And its price is low, pollution-free；Polytetrafluoroethylene (PTFE) simultaneously
Lotion has excellent chemical stability, corrosion resistance, leakproofness, high lubrication and non-stickiness and good anti-aging endurance etc..
Water-based acrylic resin lotion and fire proofing can also be uniformly dispersed in the surface of canvas by ptfe emulsion.It covers
De- soil plays the role of carrier, and fire proofing can be adsorbed on to its surface, dispersion more evenly.Raw material in B liquid are as follows:
Silane coupling agent, age resister nano-titanium dioxide, epoxy curing agent, filler, butadiene-vinylpyridine copylymer latex, aqueous slkali and deionization
Water；When work, first openpore canvas is immersed in A liquid, after drying, then is immersed in B liquid, then drying and processing.
Further, fire retardant is phosphorus flame retardant in A liquid, and phosphorus flame retardant high-temp combustion will not release in the process again
More harmful halogen gas, it is more environmentally-friendly, and its flame retardant property is more excellent.
Further, phosphorus flame retardant is cyclic phosphate, melamine polyphosphate or polyphosphate.
Further, in A liquid each raw material components by weight percent are as follows: 30~50 parts of water-based acrylic resin lotion, polytetrafluoroethyl-ne
15~20 parts of alkene lotion, 5~8 parts of montmorillonite, 2~3 parts of fire retardant, 50~80 parts of deionized water, the pH value of A liquid is 3~5.
Further, in B liquid filler be pigment and silicon carbide powder, silicon carbide high temperature resistant with higher, high-heat performance,
Its surface that lotion in B liquid can be also uniformly dispersed in canvas simultaneously.
Further, in B liquid each raw material components by weight percent are as follows: 15~18 parts of silane coupling agent, age resister nano-silica
3~5 parts of titanium of change, 13~15 parts of epoxy curing agent, 2~3 parts of filler, 35~50 parts of butadiene-vinylpyridine copylymer latex, deionized water 50~80
Part, the pH value of B liquid is 8~10.
Further, in order to preferably be convenient for forming ammonium root complex ion with other macromolecules, in increase is intermolecular, aqueous slkali
The ammonia spirit for being 28% for mass concentration.
It is fire-retardant for canvas maceration extract in the prior art the invention discloses a kind of aging-resistant flame-proof type canvas maceration extract
Effect is poor, easily adhered in process roller surface formed convex block influence production etc. technical problems improve, pass through to
Age resister and suitable flame-retardant formulations are added in maceration extract, the surface that maceration extract is coated in canvas has preferable fire prevention resistance
Performance is fired, while maceration extract is not easy to be adhered to the surface of roll during canvas is processed, reduces the artificial worry except material,
Improve production efficiency.
Specific embodiment
It elaborates below to the embodiment of the present invention, the present embodiment carries out under the premise of the technical scheme of the present invention
Implement, the detailed implementation method and specific operation process are given, but protection scope of the present invention is not limited to following implementation
Example.
Embodiment 1
Embodiment 1 discloses a kind of aging-resistant flame-proof type canvas maceration extract, including A liquid and B liquid, wherein the raw material in A liquid
Are as follows: water-based acrylic resin lotion, ptfe emulsion, dilute hydrochloric acid, montmorillonite, fire retardant and deionized water；Each original in A liquid
The components by weight percent of material are as follows: 30 parts of water-based acrylic resin lotion, 15 parts of ptfe emulsion, 5 parts of montmorillonite, 2 parts of fire retardant,
50 parts of deionized water, the pH value of A liquid is 3.
Raw material in B liquid are as follows: silane coupling agent, age resister nano-titanium dioxide, epoxy curing agent, filler, fourth
Pyrrole latex, aqueous slkali and deionized water；The components by weight percent of each raw material in B liquid are as follows: 15 parts of silane coupling agent, age resister nanometer two
3 parts of titanium oxide, 13 parts of epoxy curing agent, 2 parts of filler, 35 parts of butadiene-vinylpyridine copylymer latex, 50 parts of deionized water, the pH value of B liquid is 8.B
Filler is the pigment of 1 parts by weight and the silicon carbide powder of 1 parts by weight in liquid.In order to preferably be convenient for forming ammonium with other macromolecules
Root complex ion, in increase is intermolecular, aqueous slkali is the ammonia spirit that mass concentration is 28%.When work, first openpore canvas is soaked
Stain is in A liquid, after drying, then is immersed in B liquid, then drying and processing.Fire retardant is phosphorus flame retardant cyclic phosphate in A liquid.Phosphorus
Flame retardant will not release more harmful halogen gas in the process by high-temp combustion again, more environmentally-friendly, and its flame retardant property
It is more excellent.
Embodiment 2
Embodiment 2 discloses a kind of aging-resistant flame-proof type canvas maceration extract, including A liquid and B liquid, wherein the raw material in A liquid
Are as follows: water-based acrylic resin lotion, ptfe emulsion, dilute hydrochloric acid, montmorillonite, fire retardant and deionized water；Each original in A liquid
The components by weight percent of material are as follows: 50 parts of water-based acrylic resin lotion, 15 parts of ptfe emulsion, 8 parts of montmorillonite, 3 parts of fire retardant,
50 parts of deionized water, the pH value of A liquid is 5.
Raw material in B liquid are as follows: silane coupling agent, age resister nano-titanium dioxide, epoxy curing agent, filler, fourth
Pyrrole latex, aqueous slkali and deionized water；The components by weight percent of each raw material in B liquid are as follows: 18 parts of silane coupling agent, age resister nanometer two
5 parts of titanium oxide, 15 parts of epoxy curing agent, 3 parts of filler, 50 parts of butadiene-vinylpyridine copylymer latex, 50 parts of deionized water, the pH value of B liquid is 10.
Filler is the pigment and 1.5 parts of silicon carbide powders of 0.5 parts by weight in B liquid.When work, first openpore canvas is immersed in A liquid, is dried
It after dry, then is immersed in B liquid, then drying and processing, fire retardant is phosphorus flame retardant melamine polyphosphate in A liquid.
Embodiment 3
Embodiment 3 discloses a kind of aging-resistant flame-proof type canvas maceration extract, including A liquid and B liquid, wherein the raw material in A liquid
Are as follows: water-based acrylic resin lotion, ptfe emulsion, dilute hydrochloric acid, montmorillonite, fire retardant and deionized water；Each original in A liquid
The components by weight percent of material are as follows: 40 parts of water-based acrylic resin lotion, 20 parts of ptfe emulsion, 5 parts of montmorillonite, 3 parts of fire retardant,
70 parts of deionized water, the pH value of A liquid is 5.
Raw material in B liquid are as follows: silane coupling agent, age resister nano-titanium dioxide, epoxy curing agent, filler, fourth
Pyrrole latex, aqueous slkali and deionized water；The components by weight percent of each raw material in B liquid are as follows: 18 parts of silane coupling agent, age resister nanometer two
5 parts of titanium oxide, 15 parts of epoxy curing agent, 3 parts of filler, 50 parts of butadiene-vinylpyridine copylymer latex, 80 parts of deionized water, the pH value of B liquid is 10.
Filler is 0.3 part of pigment and 1.7 parts of silicon carbide powders in B liquid.When work, first openpore canvas is immersed in A liquid, after drying,
It is immersed in B liquid again, then drying and processing.Fire retardant is phosphorus flame retardant melamine polyphosphate in the present embodiment A liquid.
Embodiment 4
Embodiment 4 discloses a kind of aging-resistant flame-proof type canvas maceration extract, including A liquid and B liquid, wherein the raw material in A liquid
Are as follows: water-based acrylic resin lotion, ptfe emulsion, dilute hydrochloric acid, montmorillonite, fire retardant and deionized water；Each original in A liquid
The components by weight percent of material are as follows: 30 parts of water-based acrylic resin lotion, 20 parts of ptfe emulsion, 6 parts of montmorillonite, 3 parts of fire retardant,
80 parts of deionized water, the pH value of A liquid is 3.
Raw material in B liquid are as follows: silane coupling agent, age resister nano-titanium dioxide, epoxy curing agent, filler, fourth
Pyrrole latex, aqueous slkali and deionized water；The components by weight percent of each raw material in B liquid are as follows: 18 parts of silane coupling agent, age resister nanometer two
5 parts of titanium oxide, 15 parts of epoxy curing agent, 3 parts of filler, 45 parts of butadiene-vinylpyridine copylymer latex, 70 parts of deionized water, the pH value of B liquid is 8.B
Filler is 0.5 part of pigment and 1.5 parts of silicon carbide powders in liquid.When work, first openpore canvas is immersed in A liquid, after drying, then
It is immersed in B liquid, then drying and processing, fire retardant is phosphorus flame retardant cyclic phosphate in A liquid in the present embodiment.
Maceration extract in above embodiments is respectively coated on to the polyester fiber canvas surface of same batch production, and is carried out
Fire-retardant, strength test.
Experiment detection:
After Finished polyester openpore canvas is immersed in above-mentioned maceration extract respectively, finished product is sent by petroleum and chemical industry new material
It is tested with quality of item Supervision Test Center, report number: HQT2-2019-04019, test basis and decision principle: Q/
HY02-2013 " the industrial impregnation synthetic fibers canvas of flame retardant type "；Inspection project: breaking strength, elongation at break, damage length
Degree, flaming combustion time, glowing time and ageing-resistant performance etc..
Test result is as follows:
By experiment detection it can be seen that each canvas has reached standard requirements, the damage of canvas in terms of flame retardant property
Also all in 10mm hereinafter, in the case where flaming combustion, burning time is also no more than 15s to length for control, has significantly not
Slight susceptibility to combustion, it is seen that the flame retardant effect of maceration extract is obviously.
When senile experiment, ageing oven model are as follows: Ci65/DMC type, light source 6.5KW, water-cooled xenon long-arc lamp, examination
It tests using continuous illumination, temperature is controlled in 45 ± 5 DEG C of ultraviolet irradiation intensity 56W/m2, after illumination in 1000 hours to canvas into
Row strength test statistics tests the canvas in above embodiments respectively, and surface occurs without obvious metachromatism, breaking strength
It is kept at radial 580N/mm or more, broadwise is kept at 110N/mm or more, hence it is evident that be more than the resistance to old of general polyester canvas
Change performance.
Claims (7)
1. a kind of aging-resistant flame-proof type canvas maceration extract, which is characterized in that including A liquid and B liquid, wherein the raw material in the A liquid
Are as follows: water-based acrylic resin lotion, ptfe emulsion, dilute hydrochloric acid, montmorillonite, fire retardant and deionized water；
Raw material in the B liquid are as follows: silane coupling agent, age resister nano-titanium dioxide, epoxy curing agent, filler, fourth
Pyrrole latex, aqueous slkali and deionized water；
When work, first openpore canvas is immersed in A liquid, after drying, then is immersed in B liquid, then drying and processing.
2. aging-resistant flame-proof type canvas maceration extract as described in claim 1, which is characterized in that fire retardant described in A liquid is phosphorus
Flame retardant.
3. aging-resistant flame-proof type canvas maceration extract as claimed in claim 2, which is characterized in that the phosphorus flame retardant is ring phosphorus
Acid esters, melamine polyphosphate or polyphosphate.
4. aging-resistant flame-proof type canvas maceration extract as described in claim 1, which is characterized in that the weight group of each raw material in A liquid
It is divided into: 30~50 parts of water-based acrylic resin lotion, 15~20 parts of ptfe emulsion, 5~8 parts of montmorillonite, fire retardant 2~
3 parts, 50~80 parts of deionized water, the pH value of A liquid is 3~5.
5. aging-resistant flame-proof type canvas maceration extract as described in claim 1, which is characterized in that filler described in B liquid is pigment
And silicon carbide powder.
6. aging-resistant flame-proof type canvas maceration extract as described in claim 1, which is characterized in that the weight group of each raw material in B liquid
It is divided into: 15~18 parts of silane coupling agent, 3~5 parts of age resister nano-titanium dioxide, 13~15 parts of epoxy curing agent, fills out
2~3 parts of material, 35~50 parts of butadiene-vinylpyridine copylymer latex, 50~80 parts of deionized water, the pH value of B liquid is 8~10.
7. aging-resistant flame-proof type canvas maceration extract as claimed in claim 6, which is characterized in that the aqueous slkali is mass concentration
For 28% ammonia spirit.
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