CN106894025A - The pickle of zero-g aircraft detection metallic material corrosion thing and application - Google Patents
The pickle of zero-g aircraft detection metallic material corrosion thing and application Download PDFInfo
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- CN106894025A CN106894025A CN201710241886.2A CN201710241886A CN106894025A CN 106894025 A CN106894025 A CN 106894025A CN 201710241886 A CN201710241886 A CN 201710241886A CN 106894025 A CN106894025 A CN 106894025A
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- pickle
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- material corrosion
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/10—Other heavy metals
- C23G1/103—Other heavy metals copper or alloys of copper
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/04—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
- C23G1/06—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
- C23G1/063—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors heterocyclic compounds
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N5/00—Analysing materials by weighing, e.g. weighing small particles separated from a gas or liquid
- G01N5/04—Analysing materials by weighing, e.g. weighing small particles separated from a gas or liquid by removing a component, e.g. by evaporation, and weighing the remainder
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The invention belongs to the application field of metallic material corrosion field weightlessness method, and in particular to a kind of zero-g aircraft detects the pickle of metallic material corrosion thing and compares concentrated hydrochloric acid by volume mass (ml/g) using pickle：Deionized water：Hexamethylenetetramine is 5:100:9‑80；Wherein, control pickle pH is 4.15 6.15.The inventive method can obtain accurate copper corrosion product Weight loss data, reduce the loss of base metal.Meanwhile, the experiment flow of specification can ensure the comparativity between the data of different experiments.
Description
Technical field
The invention belongs to the application field of metallic material corrosion field weightlessness method, and in particular to a kind of zero-g aircraft detection
The pickle of metallic material corrosion thing and application.
Background technology
Copper and its alloy are the metal materials closely related with mankind's activity.Because of its good conductive, heat conductivility, stabilization
Chemical property and the characteristic such as good ductility, plasticity, copper and its alloy are widely applied to electrical industry, electronics
The various fields such as industry, transportation industries, energy industry and marine industry.In the consumption of China's non-ferrous metal, the consumption of copper
Amount is only second to aluminium.In the application of metal material, inevitably etching problem.It is particularly more in corrosion factor
Under environment, the etching problem of copper and its alloy is especially serious.In the measurement of corrosion rate, conventional method is that corrosion increases weightlessness
Analysis.
During the weight loss rate of present analysis copper and its alloy, the method for selection is often according to national standard (GBT16545-
The removing of corrosion product on the corrosion sample of 2015 metals and alloy) carry out.The pickle that GB is recommended is washed including sulfamic acid
Liquid, hydrochloric acid lotion and sulfuric acid lotion etc..The pickle of recommendation is primarily present the problem of the following aspects when in use：It is first
First, part washing lotion is cumbersome using process, such as the hydrochloric acid lotion recommended in GB in the logical nitrogen of solution, it is necessary to dispel oxygen
Under conditions of carry out；Secondly, the pickling liquid acidity of recommendation is larger, the inevitably Metal Substrate during cleaning
The problems such as disproportionated reaction of serious and univalent copper ion is lost at bottom, so as to influence zero-g aircraft accuracy；Finally, GB is recommended
Different cleaning fluids weightless result has differences when in use, cause the comparativity when the result of different experiments is analyzed poor.Cause
This, prepares simple, the less pickle of acidity, in being applied to zero-g aircraft under the experiment flow of specification, in copper using one kind
And its seem most important in the weight loss rate test of alloy.
The content of the invention
Pickle and application it is an object of the invention to a kind of zero-g aircraft detection metallic material corrosion thing.
To achieve the above object, the present invention use technical scheme for：
A kind of zero-g aircraft detects the pickle of metallic material corrosion thing, and pickle presses volume mass (ml/g) than dense salt
Acid：Deionized water：Hexamethylenetetramine is 5:100:9-80；Wherein, control pickle pH is in 4.15-6.15.
It is preferred that, the pickle compares concentrated hydrochloric acid by volume mass (ml/g)：Deionized water：Hexamethylenetetramine is 1:10:
2-7, wherein, pickle pH is in 4.40-5.65 for control.
The concentration of the concentrated hydrochloric acid is 12M.
A kind of application of the pickle of zero-g aircraft detection metallic material corrosion thing, the pickle is in cleaning metal material
Carry out the application in zero-g aircraft detection metallic material corrosion thing.
Further：Metal material sample is placed in after being cleaned by ultra sonic bath in the pickle take out, then according to
It is secondary by running water, pure water, absolute ethanol washing, be subsequently dried and weigh；Then the cleaning fluid of above-mentioned cleaning said sample is entered
Row cycle pickling is complete to cleaning.
Further：When carrying out pickling, first, in the environment of ultra sonic bath, the sample that band becomes rusty is put into the acid for preparing
In washing lotion, timing 1 minute；Secondly, timing is rapid after terminating takes out sample, respectively through running water, deionized water and anhydrous
Ethanol is cleaned；Finally, sample is dried, is weighed using balance.Circulation above step, cleans 10 times, is carried out according to the data for obtaining
Zero-g aircraft.If after cleaning 10 times, the still visible corrosion product of specimen surface can suitably increase scavenging period.Above-mentioned cleaning fluid
In add hexamethylenetetramine regulation pH, and then improve the stability (H ion concentrations stabilization) when pickle is cleaned；Meanwhile,
Metallic substrates can be played corrosion inhibition by the loss of substrate when the pickle for adding hexamethylenetetramine reduces cleaning.In addition, making
Acid is hydrochloric acid, and the complexing power of chlorion serves the effect for suppressing monovalence copper disproportionation so that weightless result is more accurate
Really.
Advantage for present invention：
1. Acidwash solution of the present invention is prepared simple, it is not necessary to the operation such as logical nitrogen deoxygenation gas；Reagent, the medicine for using compared with
For common, and environment will not be impacted；
2. the regulation that the present invention passes through pH so that pickle does not have larger danger in use, while reducing monovalence
The disproportionated reaction of copper ion, it is ensured that Weight loss data is more accurate；In addition, the stabilization of pH also ensure that the stabilization of pickle of the present invention
Property so that the pickle can be used repeatedly.
3. pickle of the present invention is weak for the cleaning action of metallic substrates, while reducing substrate loss, it is ensured that lose
The accuracy of tuple evidence；
4. the experiment flow of the specification recommended by the present invention uses the pickle so that have between different experimental datas
There is comparativity.
Brief description of the drawings
Fig. 1 is obtained after carrying out band rust copper sample zero-g aircraft using the pickle under flow provided in an embodiment of the present invention
Weightless figure.
Fig. 2 is after carrying out band rust copper sample zero-g aircraft using sulfamic acid washing lotion under flow provided in an embodiment of the present invention
The weightless figure for obtaining.
Fig. 3 is using carrying out the knot after XRD tests after the pickle to copper sample under flow provided in an embodiment of the present invention
Fruit is schemed.
Specific embodiment
Below in conjunction with the accompanying drawings to further description of the present invention.
The present invention is the pickle being mixed to get in proportion using concentrated hydrochloric acid, deionized water and hexamethylenetetramine, and
Experiment flow according to specification carries out the zero-g aircraft of copper and its alloy.It is weightless that the method can obtain accurate copper corrosion product
Data, reduce the loss of base metal.Meanwhile, the experiment flow of specification can ensure comparable between the data of different experiments
Property.
Embodiment 1
Zero-g aircraft detects that the pickle of metallic material corrosion thing is：10 milliliters of concentrated hydrochloric acids, 100 milliliters of water are measured, is poured into
In 250 milliliters of beakers, glass bar stirs.40 grams of hexamethylenetetramines are weighed, hydrochloric acid, the water mixed liquid for mixing is added to
In, glass bar is stirred to hexamethylenetetramine and all dissolved.The pH value of pickle, three measure are determined using the pH meter calibrated
PH average values be 5.41.
Zero-g aircraft detection is carried out using above-mentioned acquisition pickle.Prepare 200 milliliters of running water respectively, 200 milliliters
Deionized water and 50 milliliters of absolute ethyl alcohol, for cleaning the sample after pickling.It is the pure copper strips of 50 × 10 × 1mm by size
Rust sample is put into the pickle for having configured, and the beaker that will be equipped with pickle is put into ultrasonic instrument, opens ultrasound, 1 point of timing
Clock.Timing terminates, rapid to take out copper sample, clear in the running water, deionized water and absolute ethyl alcohol being already prepared to respectively
Wash.The sample that cleaning is finished is dried up rapidly using hair-dryer cold wind, sample is placed in the environment 5 minutes or so, uses analysis
Balance is weighed.The experimentation of the repetition above 10 times, it is 10 minutes to keep last scavenging period.If after cleaning 10 times, examination
The still visible corrosion product in sample surface, can suitably increase scavenging period.Then the Weight loss data of sample is represented by after cleaning every time：Δ
M=m0-mt, in formula, t represents t minutes, m after cleaningtThe quality weighed for t minutes after cleaning is represented, unit is microgram, m0Table
Show the quality of non-cleaning tape rust copper sheet, unit is microgram.
The Weight loss data under different time is calculated according to above-mentioned formula, make weightless mass-time figure (referring to Fig. 1-
2).3 to 5 data points according to the figure second half section carry out linear fit, the intercept for obtaining be weightless quality (cuprous oxide
Quality), slope is the loss speed of metallic substrates.Fig. 3 shows that the pickle recommended using the present invention will can be tried with rust copper
It is very clean that sample is cleaned.The use of the Weight loss data for recommending pickle cleaning to obtain is 3091.2 micrograms, copper-based bottom according to Fig. 1
Loss speed is 14.8 microgram per minute；According to Fig. 2, the weightless number obtained according to above-mentioned flow using GB sulfamic acid washing lotion
According to being 2142.1 micrograms, copper-based bottom loss speed is 26.9 microgram per minute.Compare and understand, the pickle recommended using the present invention
The relatively low problem of the caused Weight loss data of univalent copper ion disproportionation can be reduced, the corrosion weight loss data of sample are accurately obtained,
And ensure less metallic substrates loss.
Embodiment 2
Take size be 50 × 10 × 1mm parallel pure copper strips rust 5, sample, using used hydrochloric acid in embodiment 1-
Hexamethylenetetramine-water pickle is circulated cleaning again.Wherein, cleaning process is identical with the process of embodiment 1, Weight loss data
Treatment is also identical with the processing procedure of embodiment 1, and visible cleaning fluid loses caused by reducing univalent copper ion disproportionation from data
Tuple accurately obtains the corrosion weight loss data of sample according to relatively low problem, while ensureing less metallic substrates loss.
It is 5.41 that the pH value of the pickle is determined after case study on implementation 1 is completed, and is used with the pickle preceding identical.Table 1 is arranged
Gone out to reuse the pickle clean each the parallel test piece being calculated after parallel test piece weightless quality (cuprous oxide
Quality) and the pH value of the pickle for obtaining is determined after use every time.As known from Table 1, the pickle after a number of uses, its pH
Value remains constant substantially, and the Weight loss data that measurement is obtained is also close to each other.Illustrate that the pickle has after a number of uses preferable
Stability, can be used with repeated multiple times.
Table 1
| Test piece number | 1 | 2 | 3 | 4 | 5 |
| Weightless quality (microgram) | 2991 | 3008 | 3023 | 2980 | 2995 |
| PH value (after cleaning) | 5.41 | 5.41 | 5.41 | 5.42 | 5.42 |
Embodiment 3
Zero-g aircraft detects that the pickle of metallic material corrosion thing is：10 milliliters of concentrated hydrochloric acids, 100 milliliters of water are measured, is poured into
In 250 milliliters of beakers, glass bar stirs.20 grams of hexamethylenetetramines are weighed, hydrochloric acid, the water mixed liquid for mixing is added to
In, glass bar is stirred to hexamethylenetetramine and all dissolved.The pH value of pickle, three measure are determined using the pH meter calibrated
PH average values be 4.48.
Embodiment 4
Zero-g aircraft detects that the pickle of metallic material corrosion thing is：10 milliliters of concentrated hydrochloric acids, 200 milliliters of water are measured, is poured into
In 500 milliliters of beakers, glass bar stirs.160 grams of hexamethylenetetramines are weighed, hydrochloric acid, the water mixing for mixing is added to
In liquid, glass bar is stirred to hexamethylenetetramine and all dissolved.The pH value of pickle, three surveys are determined using the pH meter calibrated
Fixed pH average values are 6.10.
Claims (5)
1. a kind of zero-g aircraft detects the pickle of metallic material corrosion thing, it is characterised in that：Pickle presses volume mass (ml/
G) concentrated hydrochloric acid is compared：Deionized water：Hexamethylenetetramine is 5:100:9-80；Wherein, control pickle pH is in 4.15-6.15.
2. the zero-g aircraft as described in claim 1 detects the pickle of metallic material corrosion thing, it is characterised in that：The pickling
Liquid compares concentrated hydrochloric acid by volume mass (ml/g)：Deionized water：Hexamethylenetetramine is 1:10:2-7, wherein, control pickle pH
In 4.40-5.65.
3. the zero-g aircraft as described in claim 1 or 2 detects the pickle of metallic material corrosion thing, it is characterised in that：It is described
The concentration of concentrated hydrochloric acid is 12M.
4. the application of the pickle of the zero-g aircraft detection metallic material corrosion thing as described in claim 1, it is characterised in that：Institute
State application of the pickle in cleaning metal material carries out zero-g aircraft detection metallic material corrosion thing.
5. the application of the pickle of the zero-g aircraft detection metallic material corrosion thing as described in claim 4, it is characterised in that：Will
Metal material sample be placed in after being cleaned by ultra sonic bath in the pickle take out, then sequentially pass through running water, pure water,
Absolute ethanol washing, is subsequently dried and weighs；The cleaning fluid of above-mentioned cleaning said sample is then circulated pickling to having cleaned
Entirely.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710241886.2A CN106894025B (en) | 2017-04-14 | 2017-04-14 | Zero-g aircraft detects pickling solution and the application of metallic material corrosion object |
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| CN201710241886.2A CN106894025B (en) | 2017-04-14 | 2017-04-14 | Zero-g aircraft detects pickling solution and the application of metallic material corrosion object |
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| CN106894025B CN106894025B (en) | 2019-05-07 |
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Cited By (3)
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| CN107356519A (en) * | 2017-07-19 | 2017-11-17 | 中国科学院海洋研究所 | A kind of method for the corrosion weight loss for determining copper |
| CN109778203A (en) * | 2018-12-27 | 2019-05-21 | 中国石油天然气集团有限公司 | Solution is used in a kind of failure fracture cleaning method and cleaning |
| CN113514386A (en) * | 2021-03-16 | 2021-10-19 | 首钢集团有限公司 | Method for measuring under-film expanding corrosion width of automobile sheet coating sample |
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| CN113514386A (en) * | 2021-03-16 | 2021-10-19 | 首钢集团有限公司 | Method for measuring under-film expanding corrosion width of automobile sheet coating sample |
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| CN106894025B (en) | 2019-05-07 |
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