CN106893543A - A kind of prefabrication type flexibility grinding stone system - Google Patents

A kind of prefabrication type flexibility grinding stone system Download PDF

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Publication number
CN106893543A
CN106893543A CN201710287503.5A CN201710287503A CN106893543A CN 106893543 A CN106893543 A CN 106893543A CN 201710287503 A CN201710287503 A CN 201710287503A CN 106893543 A CN106893543 A CN 106893543A
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CN
China
Prior art keywords
parts
grinding stone
component
stone system
adhesive
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Pending
Application number
CN201710287503.5A
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Chinese (zh)
Inventor
陈遵厚
陈亮
陈军军
谢桂秀
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Fuzhou Royal Floor Co Ltd
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Fuzhou Royal Floor Co Ltd
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Priority to CN201710287503.5A priority Critical patent/CN106893543A/en
Publication of CN106893543A publication Critical patent/CN106893543A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • C09J175/08Polyurethanes from polyethers
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/12Flooring or floor layers made of masses in situ, e.g. seamless magnesite floors, terrazzo gypsum floors

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Road Paving Structures (AREA)

Abstract

The invention belongs to the realm of building construction, and in particular to a kind of prefabrication type flexibility grinding stone system.The system is, with grid cloth as substrate, by binding agent by grinding stone aggregate and the prefabricated combination of grid cloth, to constitute a kind of flexible grinding stone system.The application method of the system is that concrete ground primary surface is pre-processed first, surface of polishing, and makes its smooth, and dust out and greasy dirt;Foundation surface brushing last layer adhesive layer after treatment, is priming coat;Then, the flexible grinding stone system that will be prepared paves in base coating surface, then pours adhesive layer, Self-leveling shaping, is solidified into earth material, finally receives light and polishes.Grinding stone system of the invention obtained has high-strength wearable scratch resistance impact resistance, makes driving and safer on foot, and try to forestall traffic accidents generations, long service life, the ageing-resistant high temperature resistant of UV resistant, convenient to transport, and construction technology is simple.

Description

A kind of prefabrication type flexibility grinding stone system
Technical field
The invention belongs to the realm of building construction, and in particular to a kind of prefabrication type flexibility grinding stone system.
Background technology
Terrace is to be layed in the material on ground, it is desirable to certain strength and stiffness, and with warming, wear-resisting Performance.Concrete has become current application amount maximum, and uses building structural materials widest in area, according to statistics, China Concrete yield is up to the m of 12-13 hundred million within 20123, account for 40% of Gross World Product or so.But the easy-weathering of its generally existing The defect such as cracking, dusting, not wear-resisting is also to perplex the problem of people all the time, and receives common concern.Epoxide terrace is A kind of high intensity, floor wear-resistant, attractive in appearance, with seamless, quality is solid, resistance to chemical reagents is good, anti-corrosion, dust-proof, maintenance side Just the advantages of, maintenance cost is cheap.
But in existing epoxy floor material, its hardness, wearability, impact resistance etc. are difficult while reaching application requirement.
The content of the invention
It is an object of the invention to provide a kind of prefabrication type flexibility grinding stone system.Described prefabrication type flexibility grinding stone system is led to The selection hardness color shellfish suitable with adhesive layer is crossed as aggregate so that the grinding stone system has more flexibility characteristics, with high-strength Wear-resisting scratch resistance impact resistance, makes driving and safer on foot, and try to forestall traffic accidents generation, and long service life, UV resistant is resistance to Aging, convenient transport, construction technology is simple.
To achieve the above object, the present invention is adopted the following technical scheme that:
The system is, with grid cloth as substrate, by binding agent by grinding stone aggregate and the prefabricated combination of grid cloth, to constitute a kind of soft Property grinding stone system.
The preparation of the flexible grinding stone system:
Each raw material in binder component is weighed respectively, and then mechanical mixture is uniformly brushed in net with roller or spraying method Lattice cloth surface;Residence time is not more than 20 seconds, is then uniformly paved one layer of grinding stone aggregate in adhesive surface.
Described binding agent is by binding agent component A and binding agent B component according to mass ratio 3:1 mixing composition;Binding agent A groups Divide and be composed of the following raw materials by weight:50-60 parts, polyester resin 10-20 parts, KH-792 0.5-1 parts of E-42 epoxy resin;Stone 30-40 parts, schmigel 20-25 parts and dibutyl phthalate 5-6 parts of English powder;Binding agent B component is by following raw material Composition:Diethylenetriamine 4-8 parts, fatty amine 0.5-1 parts.
Described grinding stone aggregate is broken color shellfish;Mohs' hardness is 3-4.
The application method of described prefabrication type flexibility grinding stone system, concretely comprises the following steps:
First, concrete ground primary surface is pre-processed, surface of polishing makes its smooth, and dust out and greasy dirt;At place Foundation surface brushing last layer adhesive layer after reason, is priming coat;Then, the flexible grinding stone system that will be prepared paves in primary coat Layer surface, then adhesive layer is poured, Self-leveling shaping is solidified into earth material, finally receives light and polishes.
Described adhesive layer is by adhesive component A and adhesive B component according to mass ratio 3:1 mixing composition;Adhesive A groups Divide and be composed of the following raw materials by weight:2,6- 40-50 parts of diisocyanate base methyl caproates, ethylenediamine 2-5 parts, methyl amyl ketone 8-10 parts, dimethylethanolamine 0.8-1.2 parts, nitrocellulose 1-1.5 parts, talcum powder 10-20 parts, precipitated calcium carbonate 10-20 Part, BYK-360P 0.3-0.5 parts, BYK-310 0.1-0.4 parts, BYK-066N 0.3-0.5 parts and mill base 4-5 parts;Adhesive B Component is composed of the following raw materials by weight:Polyethylene glycol 25-30 parts, cyclohexanone 1-5 parts.
The preparation of adhesive layer, concretely comprises the following steps:
(1)Each component raw material is weighed respectively according to proportioning;
(2)By 2,6- diisocyanate bases methyl caproate, methyl amyl ketone mixing and stirring;
(3)To step(2)Mixture adds nitrocellulose, ethylenediamine, dimethylethanolamine, in dispersion at 50-60 DEG C 30min, rotating speed 800r/min;Then talcum powder, precipitated calcium carbonate are added, at a high speed dispersion 20min, rotating speed 1200r/min;
(4)To step(3)System adds BYK-360P, BYK-310, BYK-066N and mill base, stirs and evenly mixs 20min.
Remarkable advantage of the invention is:
(1)The prefabrication type flexibility grinding stone system that the present invention is prepared, with grid cloth as substrate, obtained is a kind of flexible grinding stone Coiled material, convenient transport, construction is simple.
(2)Because cellulose nitrate have a fabulous solvent release, it is too fast to be used alone rate of drying, but gloss it is not high, Poor adhesive force, poor in flexibility, non-volatile content content are very low, but it has good compatibility to various kinds of resin, in the present invention with 2,6- diisocyanate base methyl caproates and nitrocellulose blending, i.e., be plasticized and be modified to nitrocellulose, is improved and is applied The combination property of material such as weatherability, adhesive force, pliability, corrosion resistance, also ensure the good compatibility of cellulose nitrate, and play Its advantage for being added into shortening drying time after system.
(3)Inorganic filler is all added with binding agent and adhesive layer in the present invention, by the distinctive pin of inorganic filler Shape and fibre structure extend the diffusion path of corrosive medium, and being suitably oriented in film can reduce the crack-sensitivity of coating Property, improve the overall performance and weatherability and heat resistance of film.
(4)The present invention with broken color shellfish as filler aggregate, and be directed to color shellfish Mohs' hardness and the adhesive layer researched and developed, itself and it is color Shellfish is in same hardness platform, will not protrude aggregate, the characteristics of this also highlights " flexibility " grinding stone system of the invention.Enter one Step ground, is bonded on grid cloth, then the base for being brushed with adhesive layer is cast in homemade adhesive formulation by homemade binding agent On plinth layer, wherein it is also polyurethane cover that the adhesive for pouring is constituted, hardness is higher, so the composite construction of its multilayer ensures The flexible grinding stone system has high-strength wearable scratch resistance impact resistance, makes driving and safer on foot, and try to forestall traffic accidents hair It is raw, long service life, resistance to ultraviolet ageing-resistant high temperature resistant.
Specific embodiment
For further disclosure is of the invention rather than limitation, below in conjunction with example, the present invention is described in further detail.
The preparation of adhesive layer, concretely comprises the following steps in embodiment:
(1)Each component raw material is weighed respectively according to proportioning;
(2)By 2,6- diisocyanate bases methyl caproate, methyl amyl ketone mixing and stirring;
(3)To step(2)Mixture adds nitrocellulose, ethylenediamine, dimethylethanolamine, in dispersion at 50-60 DEG C 30min, rotating speed 800r/min;Then talcum powder, precipitated calcium carbonate are added, at a high speed dispersion 20min, rotating speed 1200r/min;
(4)To step(3)System adds BYK-360P, BYK-310, BYK-066N and mill base, stirs and evenly mixs 20min.
Embodiment 1
The preparation of prefabrication type flexibility grinding stone system:
Each raw material in binder component is weighed respectively, and then mechanical mixture is uniformly brushed in net with roller or spraying method Lattice cloth surface;18 seconds residence times, then uniformly paved one layer of grinding stone aggregate in adhesive surface.Described binding agent is by bonding Agent component A and binding agent B component are according to mass ratio 3:1 mixing composition;Binding agent component A is composed of the following raw materials by weight:E- 42 50 parts of epoxy resin, 10 parts of polyester resin, 0.5 part of KH-792;30 parts of silica flour, 20 parts of schmigel and phthalic acid two 5 parts of butyl ester;Binding agent B component is composed of the following raw materials by weight:4 parts of diethylenetriamine, 0.5 part of fatty amine.
The application method of prefabrication type flexibility grinding stone system, concretely comprises the following steps:
First, concrete ground primary surface is pre-processed, surface of polishing makes its smooth, and dust out and greasy dirt;At place Foundation surface brushing last layer adhesive layer after reason, is priming coat;Then, the flexible grinding stone system that will be prepared paves in primary coat Layer surface, then adhesive layer is poured, Self-leveling shaping is solidified into earth material, finally receives light and polishes.
Described adhesive layer is by adhesive component A and adhesive B component according to mass ratio 3:1 mixing composition;Adhesive A groups Divide and be composed of the following raw materials by weight:2,6- 40 parts of diisocyanate base methyl caproates, 2 parts of ethylenediamine, 8 parts of methyl amyl ketone, 0.8 part of dimethylethanolamine, 1 part of nitrocellulose, 10 parts of talcum powder, 10 parts of precipitated calcium carbonate, 0.3 part of BYK-360P, BYK- 4 parts of 310 0.1 parts, 0.3 part of BYK-066N and mill base;Adhesive B component is composed of the following raw materials by weight:Polyethylene glycol 25 Part, 1 part of cyclohexanone.
Embodiment 2
The preparation of prefabrication type flexibility grinding stone system:
Each raw material in binder component is weighed respectively, and then mechanical mixture is uniformly brushed in net with roller or spraying method Lattice cloth surface;19 seconds residence times, then uniformly paved one layer of grinding stone aggregate in adhesive surface.
Described binding agent is by binding agent component A and binding agent B component according to mass ratio 3:1 mixing composition;Binding agent A groups Divide and be composed of the following raw materials by weight:55 parts of E-42 epoxy resin, 15 parts of polyester resin, 0.6 part of KH-792;36 parts of silica flour, 5 parts of 22 parts of schmigel and dibutyl phthalate;Binding agent B component is composed of the following raw materials by weight:Diethylenetriamine 6 Part, 0.8 part of fatty amine.
The application method of described prefabrication type flexibility grinding stone system, concretely comprises the following steps:
First, concrete ground primary surface is pre-processed, surface of polishing makes its smooth, and dust out and greasy dirt;At place Foundation surface brushing last layer adhesive layer after reason, is priming coat;Then, the flexible grinding stone system that will be prepared paves in primary coat Layer surface, then adhesive layer is poured, Self-leveling shaping is solidified into earth material, finally receives light and polishes.
Described adhesive layer is by adhesive component A and adhesive B component according to mass ratio 3:1 mixing composition;Adhesive A groups Divide and be composed of the following raw materials by weight:2,6- 45 parts of diisocyanate base methyl caproates, 4 parts of ethylenediamine, 9 parts of methyl amyl ketone, 1.0 parts of dimethylethanolamine, 1.2 parts of nitrocellulose, 15 parts of talcum powder, 15 parts of precipitated calcium carbonate, 0.4 part of BYK-360P, 4 parts of 0.3 part of BYK-310,0.4 part of BYK-066N and mill base;Adhesive B component is composed of the following raw materials by weight:Poly- second two 26 parts of alcohol, 4 parts of cyclohexanone.
Embodiment 3
The preparation of the flexible grinding stone system:
Each raw material in binder component is weighed respectively, and then mechanical mixture is uniformly brushed in net with roller or spraying method Lattice cloth surface;18 seconds residence times, then uniformly paved one layer of grinding stone aggregate in adhesive surface.
Described binding agent is by binding agent component A and binding agent B component according to mass ratio 3:1 mixing composition;Binding agent A groups Divide and be composed of the following raw materials by weight:60 parts of E-42 epoxy resin, 20 parts of polyester resin, 1 part of KH-792;40 parts of silica flour, just 6 parts of 25 parts of beautiful powder and dibutyl phthalate;Binding agent B component is composed of the following raw materials by weight:8 parts of diethylenetriamine, 1 part of fatty amine.
The application method of described prefabrication type flexibility grinding stone system, concretely comprises the following steps:
First, concrete ground primary surface is pre-processed, surface of polishing makes its smooth, and dust out and greasy dirt;At place Foundation surface brushing last layer adhesive layer after reason, is priming coat;Then, the flexible grinding stone system that will be prepared paves in primary coat Layer surface, then adhesive layer is poured, Self-leveling shaping is solidified into earth material, finally receives light and polishes.
Described adhesive layer is by adhesive component A and adhesive B component according to mass ratio 3:1 mixing composition;Adhesive A groups Divide and be composed of the following raw materials by weight:2,6- 50 parts of diisocyanate base methyl caproates, 5 parts of ethylenediamine, 10 parts of methyl amyl ketone, 1.2 parts of dimethylethanolamine, 1.5 parts of nitrocellulose, 20 parts of talcum powder, 20 parts of precipitated calcium carbonate, 0.5 part of BYK-360P, 4 parts of 0.3 part of BYK-310,0.5 part of BYK-066N and mill base;Adhesive B component is composed of the following raw materials by weight:Poly- second two 30 parts of alcohol, 4 parts of cyclohexanone.
The foregoing is only presently preferred embodiments of the present invention, all impartial changes done according to scope of the present invention patent with Modification, should all belong to covering scope of the invention.

Claims (7)

1. a kind of prefabrication type flexibility grinding stone system, it is characterised in that:The system is, with grid cloth as substrate, to be incited somebody to action by binding agent Grinding stone aggregate and the prefabricated combination of grid cloth, constitute a kind of flexible grinding stone system.
2. prefabrication type according to claim 1 flexibility grinding stone system, it is characterised in that:Described binding agent is by binding agent A Component and binding agent B component are according to mass ratio 3:1 mixing composition;Binding agent component A is composed of the following raw materials by weight:E-42 rings 50-60 parts, polyester resin 10-20 parts, KH-792 0.5-1 parts of oxygen tree fat;Silica flour 30-40 parts, schmigel 20-25 parts and neighbour Dibatyl phithalate 5-6 parts;Binding agent B component is composed of the following raw materials by weight:Diethylenetriamine 4-8 parts, fatty amine 0.5-1 parts.
3. prefabrication type according to claim 1 flexibility grinding stone system, it is characterised in that:Described grinding stone aggregate is broken coloured silk Shellfish;Mohs' hardness is 3-4.
4. the preparation method of a kind of prefabrication type flexibility grinding stone system as described in claim 1-3, it is characterised in that:
Each raw material in binder component is weighed respectively, and then mechanical mixture is uniformly brushed in net with roller or spraying method Lattice cloth surface, the residence time is not more than 20 seconds, is then uniformly paved one layer of grinding stone aggregate in adhesive surface.
5. a kind of application method of prefabrication type as claimed in claim 1 flexibility grinding stone system, it is characterised in that:Specific steps For:
First, concrete ground primary surface is pre-processed, surface of polishing makes its smooth, and dust out and greasy dirt;At place Foundation surface brushing last layer adhesive layer after reason, is priming coat;Then, the flexible grinding stone system that will be prepared paves in primary coat Layer surface, then adhesive layer is poured, Self-leveling shaping is solidified into earth material, finally receives light and polishes.
6. the application method of prefabrication type according to claim 5 flexibility grinding stone system, it is characterised in that:Described is gluing Layer is by adhesive component A and adhesive B component according to mass ratio 3:1 mixing composition;Adhesive component A is by following raw material Composition:2,6- 40-50 parts of diisocyanate base methyl caproates, ethylenediamine 2-5 parts, methyl amyl ketone 8-10 parts, dimethyl ethanol Amine 0.8-1.2 parts, nitrocellulose 1-1.5 parts, talcum powder 10-20 parts, precipitated calcium carbonate 10-20 parts, BYK-360P 0.3- 0.5 part, BYK-310 0.1-0.4 parts, BYK-066N 0.3-0.5 parts and mill base 4-5 parts;Adhesive B component is by following weight portion Raw material is constituted:Polyethylene glycol 25-30 parts, cyclohexanone 1-5 parts.
7. the application method of prefabrication type according to claim 6 flexibility grinding stone system, it is characterised in that:The adhesive layer Prepare, concretely comprise the following steps:
(1)Each component raw material is weighed respectively according to proportioning;
(2)By 2,6- diisocyanate bases methyl caproate, methyl amyl ketone mixing and stirring;
(3)To step(2)Mixture adds nitrocellulose, ethylenediamine, dimethylethanolamine, in dispersion at 50-60 DEG C 30min, rotating speed 800r/min;Then talcum powder, precipitated calcium carbonate are added, at a high speed dispersion 20min, rotating speed 1200r/min;
(4)To step(3)System adds BYK-360P, BYK-310, BYK-066N and mill base, stirs and evenly mixs 20min.
CN201710287503.5A 2017-04-27 2017-04-27 A kind of prefabrication type flexibility grinding stone system Pending CN106893543A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111622459A (en) * 2020-05-25 2020-09-04 杨华 High-durability polished concrete floor and construction process thereof
EP4219580A1 (en) * 2022-01-27 2023-08-02 Henkel AG & Co. KGaA Solvent-based polyurethane adhesive composition for bonding flexible packaging material

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201184036Y (en) * 2007-08-17 2009-01-21 郑桂清 Epoxy resin floor terrace coating
CN102010572A (en) * 2010-11-16 2011-04-13 宏昌电子材料股份有限公司 Environment-friendly epoxy resin composition as well as preparation method and application thereof
CN105781070A (en) * 2016-03-31 2016-07-20 福州皇家地坪有限公司 Pandora stone floor

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201184036Y (en) * 2007-08-17 2009-01-21 郑桂清 Epoxy resin floor terrace coating
CN102010572A (en) * 2010-11-16 2011-04-13 宏昌电子材料股份有限公司 Environment-friendly epoxy resin composition as well as preparation method and application thereof
CN105781070A (en) * 2016-03-31 2016-07-20 福州皇家地坪有限公司 Pandora stone floor

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111622459A (en) * 2020-05-25 2020-09-04 杨华 High-durability polished concrete floor and construction process thereof
EP4219580A1 (en) * 2022-01-27 2023-08-02 Henkel AG & Co. KGaA Solvent-based polyurethane adhesive composition for bonding flexible packaging material
WO2023143876A1 (en) * 2022-01-27 2023-08-03 Henkel Ag & Co. Kgaa Solvent-based polyurethane adhesive composition for bonding flexible packaging material

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Application publication date: 20170627