CN106893486B - A kind of Water-proof and oil-proof, antifouling treatment agent and preparation method thereof - Google Patents
A kind of Water-proof and oil-proof, antifouling treatment agent and preparation method thereof Download PDFInfo
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- CN106893486B CN106893486B CN201710198495.7A CN201710198495A CN106893486B CN 106893486 B CN106893486 B CN 106893486B CN 201710198495 A CN201710198495 A CN 201710198495A CN 106893486 B CN106893486 B CN 106893486B
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- proof
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- acid
- oil
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- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 62
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 42
- -1 polysiloxanes Polymers 0.000 claims abstract description 30
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- ABTOQLMXBSRXSM-UHFFFAOYSA-N silicon tetrafluoride Chemical compound F[Si](F)(F)F ABTOQLMXBSRXSM-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 15
- 239000003054 catalyst Substances 0.000 claims abstract description 15
- 239000002904 solvent Substances 0.000 claims abstract description 12
- 238000004090 dissolution Methods 0.000 claims abstract description 8
- 239000011259 mixed solution Substances 0.000 claims abstract description 8
- 238000010438 heat treatment Methods 0.000 claims abstract description 6
- 238000006243 chemical reaction Methods 0.000 claims abstract description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 27
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 15
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 14
- 230000000694 effects Effects 0.000 claims description 13
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 235000019441 ethanol Nutrition 0.000 claims description 9
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 8
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 7
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical compound CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 6
- HCOKJWUULRTBRS-UHFFFAOYSA-N propan-2-yloxysilane Chemical compound CC(C)O[SiH3] HCOKJWUULRTBRS-UHFFFAOYSA-N 0.000 claims description 6
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 claims description 6
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 5
- 239000007848 Bronsted acid Substances 0.000 claims description 5
- 239000007822 coupling agent Substances 0.000 claims description 5
- 238000007665 sagging Methods 0.000 claims description 5
- 239000005052 trichlorosilane Substances 0.000 claims description 5
- HJIMAFKWSKZMBK-UHFFFAOYSA-N 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F HJIMAFKWSKZMBK-UHFFFAOYSA-N 0.000 claims description 4
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 4
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 4
- 235000019253 formic acid Nutrition 0.000 claims description 4
- 125000003253 isopropoxy group Chemical group [H]C([H])([H])C([H])(O*)C([H])([H])[H] 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- JLGNHOJUQFHYEZ-UHFFFAOYSA-N trimethoxy(3,3,3-trifluoropropyl)silane Chemical compound CO[Si](OC)(OC)CCC(F)(F)F JLGNHOJUQFHYEZ-UHFFFAOYSA-N 0.000 claims description 4
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims description 4
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 3
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 claims description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 3
- 229940071870 hydroiodic acid Drugs 0.000 claims description 3
- 229910017604 nitric acid Inorganic materials 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 3
- VIFIHLXNOOCGLJ-UHFFFAOYSA-N trichloro(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)silane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CC[Si](Cl)(Cl)Cl VIFIHLXNOOCGLJ-UHFFFAOYSA-N 0.000 claims description 3
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 claims description 3
- MLXDKRSDUJLNAB-UHFFFAOYSA-N triethoxy(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)silane Chemical compound CCO[Si](OCC)(OCC)CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F MLXDKRSDUJLNAB-UHFFFAOYSA-N 0.000 claims description 3
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 claims description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 3
- 244000025254 Cannabis sativa Species 0.000 claims 1
- 229910052731 fluorine Inorganic materials 0.000 claims 1
- 239000011737 fluorine Substances 0.000 claims 1
- 150000003839 salts Chemical group 0.000 claims 1
- 239000000919 ceramic Substances 0.000 abstract description 8
- 239000011521 glass Substances 0.000 abstract description 4
- 239000004519 grease Substances 0.000 abstract description 4
- 230000002045 lasting effect Effects 0.000 abstract description 4
- 239000004567 concrete Substances 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 230000002688 persistence Effects 0.000 abstract 1
- 238000001035 drying Methods 0.000 description 10
- 238000004132 cross linking Methods 0.000 description 7
- 239000010410 layer Substances 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 5
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 5
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 5
- 239000005642 Oleic acid Substances 0.000 description 5
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 5
- 239000003973 paint Substances 0.000 description 5
- 230000002940 repellent Effects 0.000 description 5
- 239000005871 repellent Substances 0.000 description 5
- 235000012239 silicon dioxide Nutrition 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- 238000010998 test method Methods 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- 239000006087 Silane Coupling Agent Substances 0.000 description 2
- 229910002808 Si–O–Si Inorganic materials 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 235000003599 food sweetener Nutrition 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 230000003301 hydrolyzing effect Effects 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 239000003765 sweetening agent Substances 0.000 description 2
- IBOKZQNMFSHYNQ-UHFFFAOYSA-N tribromosilane Chemical compound Br[SiH](Br)Br IBOKZQNMFSHYNQ-UHFFFAOYSA-N 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 238000009827 uniform distribution Methods 0.000 description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- ZOAMZFNAPHWBEN-UHFFFAOYSA-N 2-$l^{1}-oxidanylpropane Chemical compound CC(C)[O] ZOAMZFNAPHWBEN-UHFFFAOYSA-N 0.000 description 1
- NYTYVZFFEIBDBZ-UHFFFAOYSA-N CO[SiH](OC)OC.[Ru].[F] Chemical class CO[SiH](OC)OC.[Ru].[F] NYTYVZFFEIBDBZ-UHFFFAOYSA-N 0.000 description 1
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical compound [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- ZHPNWZCWUUJAJC-UHFFFAOYSA-N fluorosilicon Chemical compound [Si]F ZHPNWZCWUUJAJC-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- CKFGINPQOCXMAZ-UHFFFAOYSA-N methanediol Chemical compound OCO CKFGINPQOCXMAZ-UHFFFAOYSA-N 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229920005591 polysilicon Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
- C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5425—Silicon-containing compounds containing oxygen containing at least one C=C bond
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2383/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
- C08L2312/08—Crosslinking by silane
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Abstract
The invention discloses a kind of Water-proof and oil-proofs, antifouling treatment agent and preparation method thereof, the following steps are included: the silicon fluoride of 0.1%-1.0% is dissolved in the solvent of 50.5%-88.4%, the reactive polysiloxanes of 5.0%-20.0% are added, until sufficiently dissolution obtains mixed solution；The crosslinking agent I of 2.0%-10.0% is sequentially added into the mixed solution, the crosslinking agent II of 2.0%-10.0%, the water of 0.5%-5.0%, the catalyst of 0.5%-2.0% and the auxiliary agent of 1%-2%, heating reaction 0.5h-5h carries out prehydrolysis under the conditions of 50 DEG C -100 DEG C, obtain the waterproof, it is grease proofing, antifouling treatment agent, it can be in ceramics, glass, concrete, metal surface forms lasting waterproof, it is grease proofing, anti-fouling effect, it durable can store, it is active good, silicon fluoride is evenly distributed, and relative inexpensiveness, it can large-scale use, it is easy to maintain, film layer persistence is strong.
Description
Technical field
The present invention relates to field of fine chemical more particularly to a kind of Water-proof and oil-proofs, antifouling treatment agent and its preparation side
Method.
Background technique
The research for carrying out surface modification treatment to solid by chemical reagent is long-standing, can assign solid special anti-
Water, grease proofing, anti-pollution.Such as fabric is handled by the acrylic acid ester emulsion of fluorinated, it can get water repellent, the housing material for refusing oil
Material.For another example using (17 fluorine ruthenium trimethoxysilanes, 1H, 1H, 2H, 2H- perfluoro capryls such as the silane coupling agents of fluorinated
Trichlorosilane) processing glass surface, can get do not get wet, the mobile phone screen of oily dirt free, resistant.However the fluorine silicon of the prior art
The inorganic agents such as alkane, silane coupling agent have the shortcomings that higher cost, it is not degradable, be easy to cause environmental hazard, be not easy to maintain.
Therefore, the existing technology needs to be improved and developed.
Summary of the invention
The technical problem to be solved in the present invention is that in view of the above drawbacks of the prior art, provide a kind of Water-proof and oil-proof,
Antifouling treatment agent and preparation method thereof, significant effect, relative inexpensiveness, can large-scale use, and can ceramics, glass,
Concrete, metal surface form lasting Water-proof and oil-proof, anti-fouling effect.
The technical proposal for solving the technical problem of the invention is as follows:
A kind of Water-proof and oil-proof, antifouling treatment agent, according to quality of each component in the Water-proof and oil-proof, antifouling treatment agent
Percentage composition meter, comprising:
Silicon fluoride, content 0.1%-1.0%；
Reactive polysiloxanes, content 5.0%-20.0%；
Crosslinking agent I, content 2.0%-10.0%；
Crosslinking agent II, content 2.0%-10.0%；
Solvent, content 50.5%-88.4%；
Auxiliary agent, content 1%-2%；
Catalyst, content 0.5%-2.0%；
Water, content 0.5%-5.0%.
The Water-proof and oil-proof, antifouling treatment agent, wherein the silicon fluoride is 1H, 1H, 2H, 2H- perfluoro decyl front three
Oxysilane, 1H, 1H, 2H, 2H- perfluoro decyl triethoxysilane, 1H, 1H, 2H, three isopropoxy silane of 2H- perfluoro decyl,
1H, 1H, 2H, 2H- perfluoro decyl trichlorosilane, 1H, 1H, 2H, 2H- perfluoro decyl tribromosilane, 1H, 1H, 2H, 2H- perfluor are pungent
Base trimethoxy silane, 1H, 1H, 2H, 2H- perfluoro capryl triethoxysilane, 1H, 1H, 2H, three isopropyl oxygen of 2H- perfluoro capryl
Base silane, 1H, 1H, 2H, 2H-perfluoro capryl trichlorosilane, 1H, 1H, 2H, 2H- perfluoro capryl tribromosilane or trifluoro propyl
Trimethoxy silane.
The Water-proof and oil-proof, antifouling treatment agent, wherein the structure of the reactive polysiloxanes are as follows:
Wherein, the main chain of the reactive polysiloxanes structure is dimethyl silicone polymer, and side chain is coupling agent structure, side chain
Random distribution is in main chain, m/ (m+n+2)=3%-10%, and m+n=26-82, R are methyl, ethyl or isopropoxy.
The Water-proof and oil-proof, antifouling treatment agent, wherein the crosslinking agent I are as follows: (RO)3SiCH2-CH2Si(OR)3、
(RO)3SiCH3、(RO)3SiCH2CH2CH2Cl、(RO)3SiH、(RO)3SiCH=CH2、(RO)3Si(CH2)3S4(CH2)3Si(OR)3
Or
Any one of or two or more mixtures；
Wherein, the R is CH3Or CH3CH2。
The Water-proof and oil-proof, antifouling treatment agent, wherein the crosslinking agent II are as follows: tetraethyl orthosilicate, positive silicic acid four
Any one of methyl esters, ethyl polysilicate or two or more mixtures；The wherein SiO of ethyl polysilicate2Content be 32% or
Person 40%.
The Water-proof and oil-proof, antifouling treatment agent, wherein the solvent is methanol, ethyl alcohol, propyl alcohol, isopropanol, positive fourth
Any one of alcohol, glycerol, ethylene glycol, propylene glycol, ethylene glycol monobutyl ether, propylene glycol monobutyl ether or two or more mixing
Object.
The Water-proof and oil-proof, antifouling treatment agent, wherein the auxiliary agent is levelling agent, anticrater agent and anti-sagging agent three
The mixture of person.
The Water-proof and oil-proof, antifouling treatment agent, wherein the catalyst is bronsted acid catalyst.
The Water-proof and oil-proof, antifouling treatment agent, wherein the bronsted acid catalyst be hydrochloric acid, hydrobromic acid, hydroiodic acid,
Any one of sulfuric acid, nitric acid, phosphoric acid, sulfurous acid, formic acid, acetic acid, trichloroacetic acid, trifluoroacetic acid, n Propanoic acid, oxalic acid or two kinds
Above mixture.
A kind of Water-proof and oil-proof as described above, the preparation method of antifouling treatment agent, comprising the following steps:
A, the silicon fluoride of 0.1%-1.0% is dissolved in the solvent of 50.5%-88.4%, adds 5.0%-20.0%'s
Reactive polysiloxanes, until sufficiently dissolution obtains mixed solution；
B, crosslinking agent I, 2.0%- of 2.0%-10.0% are sequentially added into the mixed solution that step A is obtained
The auxiliary agent of 10.0% water of crosslinking agent II, 0.5%-5.0%, the catalyst of 0.5%-2.0% and 1%-2%, 50 DEG C-
Heating reaction 0.5h-5h carries out prehydrolysis under the conditions of 100 DEG C, obtains the Water-proof and oil-proof, antifouling treatment agent.
Compared with prior art, the invention has the following advantages that
Firstly, silicon fluoride is at high cost, very big with conventional organic solvent polarity difference, in compounding, selection sweetening agent is tired
Difficulty generally requires to use fluoride solvent, cost is caused to further increase, and there is not degradable to ask for organofluorine compound
Topic has potential environmental hazard, and using special cheap reactive polysiloxanes, (polysiloxanes has molecule to the present invention
Measure it is moderate and the characteristics of containing coupling agent structure) replace most silicon fluoride, have while cost is greatly reduced same
Water repellent, refuse oil, anti-fouling effect.
Secondly, silicon fluoride, it is easy to appear preservations to be not good at the problem of leading to gel for silane coupler solution system, even if protecting
It deposits well, as the micro-moisture in system causes the continuous hydrolytic crosslinking of Si-O-R group to form Si-O-Si key, most end form
At gel, it is made to lose use value, causes very huge economic loss.The present invention is made by specifically heating prehydrolysis condition
Preliminary crosslinking occurs in system, the higher Si-O-R group of activity and gel can be consumed, and because of preliminary
Hydrolysis, uniform distribution is formed between each component, especially silicon fluoride can be uniformly distributed in system, and it is lasting to have
Water repellent, refuse oil, anti-fouling effect, and conventional system silicon fluoride causes initial effect highly desirable easily in surface aggregation, but surface layer is damaged
Rear effect is consumed to be greatly reduced.
Again, it is used cooperatively by reactive polysiloxanes and crosslinking agent I, crosslinking agent II, increases the toughness, hard of film layer
Degree, adhesive force, and endurance quality is obviously improved.
Specific embodiment
To make the objectives, technical solutions, and advantages of the present invention clearer and more explicit, with reference to embodiments to the present invention into
One step is described in detail.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to limit this
Invention.
The present invention provides a kind of Water-proof and oil-proofs, antifouling treatment agent, according to each component in the Water-proof and oil-proof, antifouling place
Manage the mass percentage meter in agent, comprising:
Silicon fluoride, content 0.1%-1.0%；
Reactive polysiloxanes, content 5.0%-20.0%；
Crosslinking agent I, content 2.0%-10.0%；
Crosslinking agent II, content 2.0%-10.0%；
Solvent, content 50.5%-88.4%；
Auxiliary agent, content 1%-2%；
Catalyst, content 0.5%-2.0%；
Water, content 0.5%-5.0%.
Specifically, the silicon fluoride can be 1H, 1H, 2H, 2H- perfluoro decyl trimethoxy silane, 1H, 1H, 2H,
2H- perfluoro decyl triethoxysilane, 1H, 1H, 2H, three isopropoxy silane of 2H- perfluoro decyl, 1H, 1H, 2H, the 2H- perfluor last of the ten Heavenly stems
Base trichlorosilane, 1H, 1H, 2H, 2H- perfluoro decyl tribromosilane, 1H, 1H, 2H, 2H- perfluoro capryl trimethoxy silane, 1H,
1H, 2H, 2H- perfluoro capryl triethoxysilane, 1H, 1H, 2H, three isopropoxy silane of 2H- perfluoro capryl, 1H, 1H, 2H, 2H-
Perfluoro capryl trichlorosilane, 1H, 1H, 2H, 2H- perfluoro capryl tribromosilane or trifluoro propyl trimethoxy silane.Preferably,
The silicon fluoride is 1H, 1H, 2H, 2H- perfluoro decyl trimethoxy silane or 1H, 1H, 2H, 2H- perfluoro capryl trimethoxy
Silane.
The structure of the reactive polysiloxanes are as follows:
Wherein, the main chain of the reactive polysiloxanes structure is dimethyl silicone polymer, and side chain is coupling agent structure, side chain
Random distribution is in main chain, m/ (m+n+2)=3%-10%, m+n=26-82, and the R of the reactive polysiloxanes is methyl, second
Base or isopropoxy.Preferably, the R is isopropoxy.
The crosslinking agent I are as follows: (RO)3SiCH2-CH2Si(OR)3、(RO)3SiCH3、(RO)3SiCH2CH2CH2Cl、(RO)3SiH、(RO)3SiCH=CH2、(RO)3Si(CH2)3S4(CH2)3Si(OR)3OrAny one of or two or more mixtures；Wherein, the crosslinking
The R of agent I is CH3Or CH3CH2。
The crosslinking agent II are as follows: any one of tetraethyl orthosilicate, positive quanmethyl silicate, ethyl polysilicate or two kinds with
On mixture；The wherein SiO of ethyl polysilicate2Content is 32% or 40%.
Preferably, the solvent is methanol, ethyl alcohol, propyl alcohol, isopropanol, n-butanol, glycerol, ethylene glycol, propylene glycol, second two
Any one of alcohol monobutyl ether, propylene glycol monobutyl ether or two or more mixtures.
The auxiliary agent is levelling agent (BYK-358N), anticrater agent (BYK-333) and anti-sagging agent (BYK-410) three's
Mixture, wherein the mass percent of the levelling agent, anticrater agent and anti-sagging agent according to each component in the auxiliary agent
Meter, mLevelling agent:mAnticrater agent:mAnti-sagging agent=1:1:1.
Preferably, the catalyst is bronsted acid catalyst.The bronsted acid catalyst be hydrochloric acid, hydrobromic acid, hydroiodic acid,
Any one of sulfuric acid, nitric acid, phosphoric acid, sulfurous acid, formic acid, acetic acid, trichloroacetic acid, trifluoroacetic acid, n Propanoic acid, oxalic acid or two kinds
Above mixture.
The present invention also provides a kind of Water-proof and oil-proofs, the preparation method of antifouling treatment agent, comprising the following steps:
(1), the silicon fluoride of 0.1%-1.0% is dissolved in the solvent of 50.5%-88.4%, adds 5.0%-20.0%
Reactive polysiloxanes, until sufficiently dissolution obtain mixed solution；
(2), crosslinking agent I, 2.0%- of 2.0%-10.0% are sequentially added in the mixed solution obtained to step (1)
The auxiliary agent of 10.0% water of crosslinking agent II, 0.5%-5.0%, the catalyst of 0.5%-2.0% and 1%-2%, 50 DEG C-
Heating reaction 0.5h-5h carries out prehydrolysis under the conditions of 100 DEG C, obtains the Water-proof and oil-proof, antifouling treatment agent.
When doing ceramics, the Water-proof and oil-proof of glass surface, antifouling process, need the Water-proof and oil-proof, antifouling process
It is reused after agent dilution 10-40 times of weight of dilution agent.Wherein, the diluent is methanol, in ethyl alcohol, isopropanol, butanol
Any one or two or more mixtures.
Compared with prior art, the invention has the following advantages that
Firstly, silicon fluoride is at high cost, very big with conventional organic solvent polarity difference, in compounding, selection sweetening agent is tired
Difficulty generally requires to use fluoride solvent, cost is caused to further increase, and there is not degradable to ask for organofluorine compound
Topic has potential environmental hazard, and using special cheap reactive polysiloxanes, (polysiloxanes has molecule to the present invention
Measure it is moderate and the characteristics of containing coupling agent structure) replace most silicon fluoride, have while cost is greatly reduced same
Water repellent, refuse oil, anti-fouling effect.
Secondly, silicon fluoride, it is easy to appear preservations to be not good at the problem of leading to gel for silane coupler solution system, even if protecting
It deposits well, as the micro-moisture in system causes the continuous hydrolytic crosslinking of Si-O-R group to form Si-O-Si key, most end form
At gel, it is made to lose use value, causes very huge economic loss.The present invention is made by specifically heating prehydrolysis condition
Preliminary crosslinking occurs in system, the higher Si-O-R group of activity and gel can be consumed, and because of preliminary
Hydrolysis, uniform distribution is formed between each component, especially silicon fluoride can be uniformly distributed in system, and it is lasting to have
Water repellent, refuse oil, anti-fouling effect, and conventional system silicon fluoride causes initial effect highly desirable easily in surface aggregation, but surface layer is damaged
Rear effect is consumed to be greatly reduced.
Again, it is used cooperatively by reactive polysiloxanes and crosslinking agent I, crosslinking agent II, increases the toughness, hard of film layer
Degree, adhesive force, and endurance quality is obviously improved.
Water-proof and oil-proof of the invention, several embodiments of the preparation method of antifouling treatment agent is given below.
Embodiment 1
By 0.1 part of 1H, 1H, 2H, 2H- perfluoro decyl trimethoxy silane is dissolved in 76.9 parts of ethyl alcohol, adds 10 parts of work
Property polysiloxanes (in the structure of the reactive polysiloxanes, m/m+n+2=0.03, m+n=26, R=CH3), after completely dissolution
Sequentially adding 5 parts of crosslinking agent I, (crosslinking agent I is (RO)3SiCH2-CH2Si(OR)3), (crosslinking II is positive silicic acid four by 5 parts of crosslinking II
Ethyl ester), 1 part of water, 0.5 part of concentrated hydrochloric acid and 1.5 parts of auxiliary agents, reacted under the conditions of 50 DEG C and obtain the Water-proof and oil-proof, anti-after 5h
Dirty inorganic agent.
In use, the inorganic agent prepared in 1 part of the present embodiment is diluted to 20 parts with ethyl alcohol, it is sprayed at smooth ceramic tile table
Face, spontaneously dries 48h or 120 DEG C of drying 3min, and effect is equivalent, it should be noted that the method for drying 3min using 120 DEG C
When need to be processed dose of levelling after dry again.The present embodiment spraying after formed 76 ° of 125 ° of film layer water contact angle, oleic acid contact angle,
1 grade of fouling resistance rating (GB/T9780-2013 Test method for dirt resistance of film of architectural coatings and paint).
Embodiment 2
By 1 part of 1H, 1H, 2H, three isopropoxy silane of 2H- perfluoro capryl is dissolved in 50.5 parts of isopropanols, and 20 parts of work are added
Property polysiloxanes (in the structure of the reactive polysiloxanes, m/m+n+2=0.07, m+n=50, R=CH3CH2), sufficiently dissolve
After sequentially add 10 parts of crosslinking agent I (crosslinking agent I be (RO)3SiCH3), (crosslinking agent II is positive silicic acid tetramethyl by 10 parts of crosslinking agent II
Ester), 5 parts of water, 2 parts of concentrated sulfuric acids and 1.5 parts of auxiliary agents, reacted under the conditions of 100 DEG C and obtain the Water-proof and oil-proof, anti-after 0.5h
Dirty inorganic agent.
In use, the inorganic agent prepared in 1 part of the present embodiment is interpreted into 40 parts with isopropanol floride, it is sprayed at smooth ceramic tile table
Face, spontaneously dries 48h or 120 DEG C of drying 3min, and effect is equivalent, it should be noted that the method for drying 3min using 120 DEG C
When need to be processed dose of levelling after dry again.The present embodiment spraying after formed 78 ° of 127 ° of film layer water contact angle, oleic acid contact angle,
0 grade of fouling resistance rating (GB/T9780-2013 Test method for dirt resistance of film of architectural coatings and paint).
Embodiment 3
By 0.5 part of 1H, 1H, 2H, 2H- perfluoro decyl trichlorosilane is dissolved in 87.5 parts of methanol, and 5 parts of activity poly silicon oxygen are added
Alkane (in the structure of the reactive polysiloxanes, m/m+n+2=0.1, m+n=82, R=CH3CH3CH), successively add after completely dissolution
Entering 2 parts of crosslinking agent I, (crosslinking agent I is (RO)3SiH), (crosslinking agent II is ethyl polysilicate to 2 parts of crosslinking agent II, and SiO2 content is
40%), 1 part of water, 0.5 part of formic acid and 1.5 parts of auxiliary agents obtain the Water-proof and oil-proof, antifouling after reacting 2h under the conditions of 80 DEG C
Inorganic agent.
In use, the inorganic agent methanol dilution prepared in 1 part of the present embodiment is sprayed at smooth ceramic tile table at 10 parts
Face, spontaneously dries 48h or 120 DEG C of drying 3min, and effect is equivalent, it should be noted that the method for drying 3min using 120 DEG C
When need to be processed dose of levelling after dry again.The present embodiment spraying after formed 80 ° of 130 ° of film layer water contact angle, oleic acid contact angle,
0 grade of fouling resistance rating (GB/T9780-2013 Test method for dirt resistance of film of architectural coatings and paint).
Embodiment 4
By 0.1 part of 1H, 1H, 2H, 2H-perfluoro capryl trichlorosilane is dissolved in 88.4 parts of isopropanol and ethylene glycol monobutyl ether
In the mixed solvent (wherein, mIsopropanol/mEthylene glycol monobutyl ether=1) 5 parts of reactive polysiloxanes (structures of the reactive polysiloxanes, are added
In, m/m+n+2=0.1, m+n=82, R=CH3CH3CH), sequentially adding 2 parts of crosslinking agent I after completely dissolution, (crosslinking agent I is
(RO)3SiCH=CH2), 2 parts of crosslinking agent II (crosslinking agent II is tetraethyl orthosilicate), 0.5 part of water, 0.5 part of acetic acid and 1.5 parts help
Agent obtains the Water-proof and oil-proof, antifouling treatment agent after reacting 2h under the conditions of 80 DEG C.
In use, the inorganic agent methanol dilution prepared in 1 part of the present embodiment is sprayed at smooth ceramic tile table at 10 parts
Face, spontaneously dries 48h or 120 DEG C of drying 3min, and effect is equivalent, it should be noted that the method for drying 3min using 120 DEG C
When need to be processed dose of levelling after dry again.The present embodiment spraying after formed 70 ° of 110 ° of film layer water contact angle, oleic acid contact angle,
2 grades of fouling resistance rating (GB/T9780-2013 Test method for dirt resistance of film of architectural coatings and paint).
Embodiment 5
The mixing that 1 part of trifluoro propyl trimethoxy silane is dissolved in 60 parts of methanol, isopropanol and ethylene glycol monobutyl ether is molten
In agent (wherein, m methanol/m isopropanol/m ethylene glycol monobutyl ether=1:1:1), 15 parts of reactive polysiloxanes (activity polies are added
In the structure of siloxanes, m/m+n+2=0.1, m+n=82, R=CH3CH3CH), 6 parts of crosslinking agent I are sequentially added after completely dissolution
(crosslinking agent I is (RO)3Si(CH2)3S4(CH2)3Si(OR)3), (crosslinking agent II is ethyl polysilicate, SiO2 by 12 parts of crosslinking agent II
Content be 32%), 3 parts of water, 1.5 parts of trifluoroacetic acids and 1.5 parts of auxiliary agents, reacted under the conditions of 60 DEG C obtain after 3h it is described anti-
Water, grease proofing, antifouling treatment agent.
In use, the inorganic agent prepared in 1 part of the present embodiment is diluted to 30 parts with butanol, it is sprayed at smooth ceramic tile table
Face, spontaneously dries 48h or 120 DEG C of drying 3min, and effect is equivalent, it should be noted that the method for drying 3min using 120 DEG C
When need to be processed dose of levelling after dry again.The present embodiment spraying after formed 77 ° of 123 ° of film layer water contact angle, oleic acid contact angle,
0 grade of fouling resistance rating (GB/T9780-2013 Test method for dirt resistance of film of architectural coatings and paint).
It should be understood that the application of the present invention is not limited to the above for those of ordinary skills can
With improvement or transformation based on the above description, all these modifications and variations all should belong to the guarantor of appended claims of the present invention
Protect range.
Claims (7)
1. a kind of Water-proof and oil-proof, antifouling treatment agent, which is characterized in that according to each component in the Water-proof and oil-proof, antifouling process
Mass percentage meter in agent, comprising:
Silicon fluoride, content 0.1%-1.0%；
Reactive polysiloxanes, content 5.0%-20.0%；
Crosslinking agent I, content 2.0%-10.0%；
Crosslinking agent II, content 2.0%-10.0%；
Solvent, content 50.5%-88.4%；
Auxiliary agent, content 1%-2%；
Catalyst, content 0.5%-2.0%；
Water, content 0.5%-5.0%；
The structure of the reactive polysiloxanes are as follows:
Wherein, the main chain of the reactive polysiloxanes structure is dimethyl silicone polymer, and side chain is coupling agent structure, and side chain is random
Be distributed in main chain, m/ (m+n+2)=3%-10%, m+n=26-82, R be methyl, ethyl or isopropoxy,
The crosslinking agent I are as follows: (RO)3SiCH2-CH2Si(OR)3、(RO)3SiCH3、(RO)3SiCH2CH2CH2Cl、(RO)3SiH、
(RO)3SiCH=CH2、(RO)3Si(CH2)3S4(CH2)3Si(OR)3OrAny one of or two or more mixtures, wherein the R is
CH3Or CH3CH2,
The crosslinking agent II are as follows: any one of tetraethyl orthosilicate, positive quanmethyl silicate, ethyl polysilicate are two or more
Mixture；The wherein SiO of ethyl polysilicate2Content is 32% or 40%.
2. Water-proof and oil-proof as described in claim 1, antifouling treatment agent, which is characterized in that the silicon fluoride be 1H, 1H, 2H,
2H- perfluoro decyl trimethoxy silane, 1H, 1H, 2H, 2H- perfluoro decyl triethoxysilane, 1H, 1H, 2H, 2H- perfluoro decyl
Three isopropoxy silane, 1H, 1H, 2H, 2H- perfluoro decyl trichlorosilane, 1H, 1H, 2H, 2H- perfluoro decyl tribromosilane, 1H,
1H, 2H, 2H- perfluoro capryl trimethoxy silane, 1H, 1H, 2H, 2H- perfluoro capryl triethoxysilane, 1H, 1H, 2H, 2H- are complete
Three isopropoxy silane of fluorine octyl, 1H, 1H, 2H, 2H-perfluoro capryl trichlorosilane, 1H, 1H, 2H, 2H- perfluoro capryl tribromo silicon
Alkane or trifluoro propyl trimethoxy silane.
3. Water-proof and oil-proof as described in claim 1, antifouling treatment agent, which is characterized in that the solvent is methanol, ethyl alcohol, third
Any one of alcohol, isopropanol, n-butanol, glycerol, ethylene glycol, propylene glycol, ethylene glycol monobutyl ether, propylene glycol monobutyl ether or two
Kind or more mixture.
4. Water-proof and oil-proof as described in claim 1, antifouling treatment agent, which is characterized in that the auxiliary agent is levelling agent, shrinkproof
The mixture of hole agent and anti-sagging agent three.
5. Water-proof and oil-proof as described in claim 1, antifouling treatment agent, which is characterized in that the catalyst is Protic Acid Catalyzed
Agent.
6. Water-proof and oil-proof as claimed in claim 5, antifouling treatment agent, which is characterized in that the bronsted acid catalyst is salt
Acid, hydrobromic acid, hydroiodic acid, sulfuric acid, nitric acid, phosphoric acid, sulfurous acid, formic acid, acetic acid, trichloroacetic acid, trifluoroacetic acid, n Propanoic acid, grass
Any one of acid or two or more mixtures.
7. a kind of such as Water-proof and oil-proof as claimed in any one of claims 1 to 6, the preparation method of antifouling treatment agent, feature exist
In, comprising the following steps:
A, the silicon fluoride of 0.1%-1.0% is dissolved in the solvent of 50.5%-88.4%, adds the activity of 5.0%-20.0%
Polysiloxanes, until sufficiently dissolution obtains mixed solution；
B, sequentially add crosslinking agent I, 2.0%-10.0%'s of 2.0%-10.0% into the mixed solution that step A is obtained
The auxiliary agent of the water of crosslinking agent II, 0.5%-5.0%, the catalyst of 0.5%-2.0% and 1%-2%, in 50 DEG C of -100 DEG C of items
Heating reaction 0.5h-5h carries out prehydrolysis under part, obtains the Water-proof and oil-proof, antifouling treatment agent.
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