CN106893282A - A kind of antibacterial textile material and preparation method thereof - Google Patents
A kind of antibacterial textile material and preparation method thereof Download PDFInfo
- Publication number
- CN106893282A CN106893282A CN201710087805.8A CN201710087805A CN106893282A CN 106893282 A CN106893282 A CN 106893282A CN 201710087805 A CN201710087805 A CN 201710087805A CN 106893282 A CN106893282 A CN 106893282A
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- textile material
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- antibacterial textile
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/02—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses a kind of antibacterial textile material and preparation method thereof, belong to functional fiber technical field.The antibacterial textile material, is made up of the raw material of following weight portion：15 35 parts of PLA, 8 18 parts of polycaprolactone, 10 20 parts of viscose rayon, 3 15 parts of carboxymethylcellulose calcium, 5 20 parts of bamboo-carbon fibre, 0.5 2 parts of negative ion powder, 35 parts of zinc oxide, 0.5 1 parts of polyacrylate, 4 15 parts of water.Antibacterial textile material of the invention has good anti-microbial property, antibacterial time permanent, is a kind of environment-friendly antibiosis textile material with biodegradability very high.
Description
Technical field
The present invention relates to functional fiber technical field, and in particular to a kind of antibacterial textile material and preparation method thereof.
Background technology
With social development and the raising of economic level, requirement of the people to the functional fabric of closeness to life is increasingly
Height, is particularly more favored with the multifunctional green healthcare face fabric such as comfortableness, health, feature of environmental protection.At present to spinning
The research report for knitting the processing of material antibacterial is a lot, is used antibacterial means used to addition antiseptic such as quaternary ammonium salt in textile more
Class, guanidine, fatty acid and metallic compound etc., wherein antiseptic have toxicity, not environmentally, some antiseptic costs in itself
High, processing technology is complicated, in addition existing anti-microbial type textile often exist antibacterial drug effect be difficult to maintain, biological difficult drop
The shortcomings of solving, pollute environment, be unfavorable for environment-friendly.
Therefore a kind of antibacterial drug effect is permanent, be readily biodegradable environment-friendly antibiosis textile material and its preparation are designed
Method has great practical value.
The content of the invention
The present invention provides a kind of antibacterial textile material, can solve above mentioned problem of the prior art.
The invention provides a kind of antibacterial textile material, it is made up of the raw material of following weight portion：PLA 15-35 parts, it is poly-
Caprolactone 8-18 parts, viscose rayon 10-20 parts, carboxymethylcellulose calcium 3-15 parts, bamboo-carbon fibre 5-20 parts, negative ion powder 0.5-2
Part, zinc oxide 3-5 parts, polyacrylate 0.5-1 parts, water 4-15 parts.
It is preferred that the antibacterial textile material is made up of the raw material of following weight portion：25 parts of PLA, polycaprolactone 15
Part, 12 parts of viscose rayon, 8 parts of carboxymethylcellulose calcium, 12 parts of bamboo-carbon fibre, 0.8 part of negative ion powder, 3.5 parts of zinc oxide, polypropylene
0.8 part of acid esters, 10 parts of water.
A kind of preparation method of antibacterial textile material, comprises the following steps：
(1) raw material of following weight portion is weighed：PLA 15-35 parts, polycaprolactone 8-18 parts, viscose rayon 10-20 parts,
Bamboo-carbon fibre 5-20 parts, polyacrylate 0.5-1 parts, water 4-15 parts, stirred at 50-80 DEG C and be added to twin-screw and squeezed
Go out in machine；
(2) in ground negative ion powder 0.5-2 parts, zinc oxide 3-5 parts of addition double screw extruder, squeezed in twin-screw
The side loading mouthful for going out machine adds 3-15 parts of carboxymethylcellulose calcium, and melting, extrusion, dry, pelletizing obtain the antibacterial weaving material
Material.
It is preferred that each zone temperatures of double screw extruder are：One 160-180 DEG C of area's temperature, two area temperature 175-210
DEG C, three 190-210 DEG C of area's temperature, four 170-180 DEG C of area's temperature.
It is preferred that each zone temperatures of double screw extruder are：One 170 DEG C of area's temperature, two 185 DEG C of area's temperature, 3rd area
200 DEG C of temperature, four 175 DEG C of area's temperature.
Compared with prior art, the beneficial effects of the invention are as follows：Antibacterial textile material of the invention has good antibacterial
Performance, antibacterial time are permanent, are a kind of environment-friendly antibiosis textile materials with biodegradability very high.
Specific embodiment
Specific embodiment of the invention is described in detail below, it is to be understood that protection scope of the present invention is not
Limited by specific embodiment.Based on the embodiment in the present invention, those of ordinary skill in the art are not making creativeness
The every other embodiment obtained on the premise of work, belongs to the scope of protection of the invention.
Embodiment 1：
A kind of antibacterial textile material, is made up of the raw material of following weight portion：18 parts of PLA, 10 parts of polycaprolactone, viscose glue
18 parts of fiber, 5 parts of carboxymethylcellulose calcium, 10 parts of bamboo-carbon fibre, 1 part of negative ion powder, 3 parts of zinc oxide, 0.5 part of polyacrylate,
6 parts of water.
A kind of preparation method of antibacterial textile material, comprises the following steps：
(1) raw material of following weight portion is weighed：18 parts of PLA, 10 parts of polycaprolactone, 18 parts of viscose rayon, bamboo-carbon fibre
10 parts, 0.5 part of polyacrylate, 6 parts of water, in being stirred at 65 DEG C and being added to double screw extruder；
(2) in 1 part ground of negative ion powder, 3 parts of addition double screw extruders of zinc oxide, in double screw extruder
Side loading mouthful adds 5 parts of carboxymethylcellulose calcium, and melting, extrusion, dry, pelletizing obtain the antibacterial textile material.
Wherein, each zone temperatures of the double screw extruder are：One 160 DEG C of area's temperature, two 180 DEG C of area's temperature, three area's temperature
195 DEG C of degree, four 170 DEG C of area's temperature.
Embodiment 2：
A kind of antibacterial textile material, is made up of the raw material of following weight portion：25 parts of PLA, 15 parts of polycaprolactone, viscose glue
12 parts of fiber, 8 parts of carboxymethylcellulose calcium, 12 parts of bamboo-carbon fibre, 0.8 part of negative ion powder, 3.5 parts of zinc oxide, polyacrylate 0.8
Part, 10 parts of water.
A kind of preparation method of antibacterial textile material, comprises the following steps：
(1) raw material of following weight portion is weighed：25 parts of PLA, 15 parts of polycaprolactone, 12 parts of viscose rayon, bamboo-carbon fibre
12 parts, 0.8 part of polyacrylate, 10 parts of water, in being stirred at 70 DEG C and being added to double screw extruder；
(2) in 0.8 part ground of negative ion powder, 3.5 parts of addition double screw extruders of zinc oxide, in twin-screw extrusion
The side loading mouthful of machine adds 8 parts of carboxymethylcellulose calcium, and melting, extrusion, dry, pelletizing obtain the antibacterial textile material.
Wherein, each zone temperatures of the double screw extruder are：One 170 DEG C of area's temperature, two 185 DEG C of area's temperature, three area's temperature
200 DEG C of degree, four 175 DEG C of area's temperature.
Embodiment 3：
A kind of antibacterial textile material, is made up of the raw material of following weight portion：30 parts of PLA, 15 parts of polycaprolactone, viscose glue
18 parts of fiber, 12 parts of carboxymethylcellulose calcium, 18 parts of bamboo-carbon fibre, 0.8 part of negative ion powder, 4 parts of zinc oxide, 1 part of polyacrylate,
12 parts of water.
A kind of preparation method of antibacterial textile material, comprises the following steps：
(1) raw material of following weight portion is weighed：30 parts of PLA, 15 parts of polycaprolactone, 18 parts of viscose rayon, bamboo-carbon fibre
18 parts, 1 part of polyacrylate, 12 parts of water, in being stirred at 75 DEG C and being added to double screw extruder；
(2) in 0.8 part ground of negative ion powder, 3.5 parts of addition double screw extruders of zinc oxide, in twin-screw extrusion
The side loading mouthful of machine adds 12 parts of carboxymethylcellulose calcium, and melting, extrusion, dry, pelletizing obtain the antibacterial textile material.
Wherein, each zone temperatures of the double screw extruder are：One 175 DEG C of area's temperature, two 205 DEG C of area's temperature, three area's temperature
200 DEG C of degree, four 180 DEG C of area's temperature.
The textile material that above-described embodiment is obtained carries out bacteriostasis property test, as shown in table 1.
The bacteriostasis property test result of each embodiment of table 1
Using soil buries method 90 days, the weight-loss ratio of embodiment 1-3 illustrated that its biological degradation rate is very high between 85-93%, has
Beneficial to environment-friendly.
To the textile material that embodiment 1-3 is obtained carry out higher than 50 times washing after product bacteriostasis rate remain at 90% with
On.
Antibacterial textile material of the invention has good anti-microbial property, antibacterial time permanent, with biological drop very high
Solution performance, is a kind of environment-friendly antibiosis textile material.
Claims (5)
1. a kind of antibacterial textile material, it is characterised in that be made up of the raw material of following weight portion：PLA 15-35 parts, gather oneself in
Ester 8-18 parts, viscose rayon 10-20 parts, carboxymethylcellulose calcium 3-15 parts, bamboo-carbon fibre 5-20 parts, negative ion powder 0.5-2 parts, oxygen
Change 3-5 parts, polyacrylate 0.5-1 parts, water 4-15 parts of zinc.
2. antibacterial textile material as claimed in claim 1, it is characterised in that be made up of the raw material of following weight portion：PLA
25 parts, 15 parts of polycaprolactone, 12 parts of viscose rayon, 8 parts of carboxymethylcellulose calcium, 12 parts of bamboo-carbon fibre, 0.8 part of negative ion powder, oxygen
Change 3.5 parts of zinc, 0.8 part of polyacrylate, 10 parts of water.
3. the preparation method of antibacterial textile material as claimed in claim 1, it is characterised in that comprise the following steps：
(1) raw material of following weight portion is weighed：PLA 15-35 parts, polycaprolactone 8-18 parts, viscose rayon 10-20 parts, bamboo charcoal
Fiber 5-20 parts, polyacrylate 0.5-1 parts, water 4-15 parts, stir at 50-80 DEG C and be added to double screw extruder
In；
(2) in ground negative ion powder 0.5-2 parts, zinc oxide 3-5 parts of addition double screw extruder, in double screw extruder
Side loading mouthful add 3-15 part of carboxymethylcellulose calcium, melting, extrusion, dry, pelletizing obtain the antibacterial textile material.
4. the preparation method of antibacterial textile material as claimed in claim 3, it is characterised in that each area of double screw extruder
Duan Wendu is：One 160-180 DEG C of area's temperature, two 175-210 DEG C of area's temperature, three 190-210 DEG C of area's temperature, four area temperature 170-
180℃。
5. the preparation method of antibacterial textile material as claimed in claim 4, it is characterised in that each area of double screw extruder
Duan Wendu is：One 170 DEG C of area's temperature, two 185 DEG C of area's temperature, three 200 DEG C of area's temperature, four 175 DEG C of area's temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710087805.8A CN106893282B (en) | 2017-02-18 | 2017-02-18 | A kind of antibacterial textile material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710087805.8A CN106893282B (en) | 2017-02-18 | 2017-02-18 | A kind of antibacterial textile material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106893282A true CN106893282A (en) | 2017-06-27 |
| CN106893282B CN106893282B (en) | 2018-12-11 |
Family
ID=59184716
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710087805.8A Expired - Fee Related CN106893282B (en) | 2017-02-18 | 2017-02-18 | A kind of antibacterial textile material and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN106893282B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109423701A (en) * | 2017-08-23 | 2019-03-05 | 安徽瑞华棉业发展股份有限公司 | A kind of antibacterial textile material and preparation method thereof |
| CN109706539A (en) * | 2018-12-25 | 2019-05-03 | 上海德福伦化纤有限公司 | A kind of anion acid fiber by polylactic and preparation method thereof |
| CN111592767A (en) * | 2020-06-16 | 2020-08-28 | 浦江环彩纺织有限公司 | Novel health-care material and preparation method thereof |
| CN114456557A (en) * | 2022-01-21 | 2022-05-10 | 金旸（厦门）新材料科技有限公司 | Plant fiber-imitated degradable polyester composite material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102453317A (en) * | 2010-10-22 | 2012-05-16 | 中国石油化工股份有限公司 | Antibacterial polylactic acid composition and preparation method thereof |
| CN103172991A (en) * | 2013-03-13 | 2013-06-26 | 同济大学 | Novel long-lasting antibacterial polylactic acid plastic and preparation method thereof |
| CN105482396A (en) * | 2016-01-18 | 2016-04-13 | 苏州法斯特信息科技有限公司 | Novel antibacterial degradable textile material and preparation method thereof |
-
2017
- 2017-02-18 CN CN201710087805.8A patent/CN106893282B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102453317A (en) * | 2010-10-22 | 2012-05-16 | 中国石油化工股份有限公司 | Antibacterial polylactic acid composition and preparation method thereof |
| CN103172991A (en) * | 2013-03-13 | 2013-06-26 | 同济大学 | Novel long-lasting antibacterial polylactic acid plastic and preparation method thereof |
| CN105482396A (en) * | 2016-01-18 | 2016-04-13 | 苏州法斯特信息科技有限公司 | Novel antibacterial degradable textile material and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109423701A (en) * | 2017-08-23 | 2019-03-05 | 安徽瑞华棉业发展股份有限公司 | A kind of antibacterial textile material and preparation method thereof |
| CN109706539A (en) * | 2018-12-25 | 2019-05-03 | 上海德福伦化纤有限公司 | A kind of anion acid fiber by polylactic and preparation method thereof |
| CN111592767A (en) * | 2020-06-16 | 2020-08-28 | 浦江环彩纺织有限公司 | Novel health-care material and preparation method thereof |
| CN114456557A (en) * | 2022-01-21 | 2022-05-10 | 金旸（厦门）新材料科技有限公司 | Plant fiber-imitated degradable polyester composite material and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN106893282B (en) | 2018-12-11 |
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Granted publication date: 20181211 Termination date: 20200218 |