CN106892626A - A kind of thermal insulation coatings of utilization hollow glass micropearl and preparation method thereof - Google Patents

A kind of thermal insulation coatings of utilization hollow glass micropearl and preparation method thereof Download PDF

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Publication number
CN106892626A
CN106892626A CN201710261969.8A CN201710261969A CN106892626A CN 106892626 A CN106892626 A CN 106892626A CN 201710261969 A CN201710261969 A CN 201710261969A CN 106892626 A CN106892626 A CN 106892626A
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hollow glass
glass micropearl
thermal insulation
insulation coatings
powder
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荣延洲
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Individual
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • C04B2201/32Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

Abstract

The invention belongs to insulation material technical field, a kind of thermal insulation coatings of utilization hollow glass micropearl and preparation method thereof are disclosed, the component of the thermal insulation coatings of the utilization hollow glass micropearl is made up of hollow glass micropearl and compo material;Preparation method includes:Example weighs each component of compo material in mass ratio, and mixed on low speed is stirred during each component is put into drum-type blender;Coating material each component to be mixed uniformly after mixing, the hollow glass micropearl that example in mass ratio is weighed is added after importing another stainless steel, and mixed on low speed stirs, and is utilized the thermal insulation coatings of hollow glass micropearl.Glass microballoon addition of the present invention can substantially reduce the thermal conductivity factor of coating in coating, play heavily-shielded effect.

Description

A kind of thermal insulation coatings of utilization hollow glass micropearl and preparation method thereof
Technical field
The invention belongs to field of heat insulating materials, more particularly to a kind of utilization hollow glass micropearl thermal insulation coatings and its preparation Method.
Background technology
Existing insulation material is usually based on solid material.Solid insulation material has construction hardly possible, and high cost is protected Adiabator takes larger volume, and cannot accomplish insulation comprehensively.Therefore solid insulation material is not suitable for doing heat insulating inner wall.Only There is thermal insulating soft material, such as thermal insulation mortar and thermal insulation paint is just adapted to do heat insulating inner wall treatment.At present effect is yet there are no in China Good software heat insulating inner wall material.Existing some thermal insulation coatings can not realize insulation truly, and this point can Find out with from insulation material thermal conductivity factor proficiency testing result, and easily crackle, internal shrinkage etc. occur after solidification, and The poor-performings such as acid-fast alkali-proof, adhesive force, so as to influence its heat insulation effect, therefore excellent combination property thermal insulation coatings urgently Solve.
Thermal insulation coatings are a kind of new insulation materials, and the one of heat-insulation and heat-preservation is realized by low thermal conductivity and thermal resistance high Plant coating.
Glass microballoon is a kind of a kind of special new material of widely used, performance developed in recent years.The product Processed through high-tech by borosilicate raw material, granularity is 10-250 microns, wall thickness 1-2 microns.The product have light weight, The advantages of low heat conduction, intensity higher, good chemical stability, its surface has oleophyllie hydrophobic performance by specially treated, It is very easy to be scattered in organic material system.
In sum, the problem of prior art presence is:Architectural commonly used thermal insulation coatings have various, but due to matching somebody with somebody Side is unreasonable, easily lamination occurs with surface layer mortar under strong sunlight for a long time, produces section bar seam crossing cold Bridge heat waste, causes heat insulation effect poor, and service life is short, poor ductility, easy-to-break layer, and is also easy to produce toxic gas at high temperature, its Unitary function, without waterproof, anti-corrosion, fireproof effect;Thermal insulation coatings of the prior art are not bound with glass microballoon and carry out Insulation material is produced.
The content of the invention
For prior art exist problem, the invention provides a kind of utilization hollow glass micropearl thermal insulation coatings and its Preparation method.Hollow glass micropearl of the invention has heat-insulated, sound insulation, insulation, water absorption rate low.The inside of hollow glass micropearl is Thin gas, thus it there is sound insulation, every thermal property, be the splendid filler as various insulations, acoustical insulation products.It is hollow The insulative properties of glass microballoon can also be used to protect product to undergo the heat punching for alternately changing and causing between anxious heat and chilling condition Hit.The applicant lives in Germany, manages hollow glass micropearl inside and outside wall thermal insulation coating in Germany and obtains applications well.
The present invention is achieved in that a kind of thermal insulation coatings of utilization hollow glass micropearl, and the utilization hollow glass is micro- The component of the thermal insulation coatings of pearl is made up of hollow glass micropearl and compo material;The hollow glass micropearl and compo The mass ratio of material is respectively 30%~80%, 20%~70%;The component example in mass ratio of the compo material by Ultra tiny powder of lacquer putty for use on pulverized limestone and titanium white powder mixture 0~20%, white cement 0~15%, rubber powder 0~10%, floating bead powder 0~ 5%;Natural resin 0~20%, styrene-acrylic emulsion 0~20%, formaldehyde absorbent 2~6%, coalescents 2~5%, defoamer 2~ 5%, phytochrome 1%~3%, nano-antibacterial powder 0.5%~1% is constituted.
Another object of the present invention is to provide a kind of preparation method of the thermal insulation coatings of utilization hollow glass micropearl, including with Lower step:
Example weighs each component of compo material in mass ratio, by mixed on low speed in each component input drum-type blender Stirring;
Coating material each component to be mixed is uniformly after mixing, imports after another stainless steel and adds example in mass ratio and claim The hollow glass micropearl for taking, mixed on low speed stirs, and is utilized the thermal insulation coatings of hollow glass micropearl.
Further, mixed on low speed mixing speed is 150 revs/min~300 revs/min;Mixing time 60min~90min.
Further, the thermal insulation coatings addition of the utilization hollow glass micropearl that will be obtained is applied using the insulation of hollow glass micropearl The deionized water of the 30%~50% of material quality, obtains the thermal insulation coatings of the utilization hollow glass micropearl for smearing metope.
Further, when adding deionized water, using heating stirring, whipping temp is 50 DEG C -80 DEG C.
Further, mixing time is 30min~60min.
Another object of the present invention is to provide a kind of interior for being prepared using the thermal insulation coatings of hollow glass micropearl as described above Thermal insulation coatings, component is made up of hollow glass micropearl and compo material;The hollow glass micropearl and compo material Mass ratio be respectively 50%~80%, 20%~50%;The component example in mass ratio of the compo material is by ultra micro Fine and smooth sub- powder lime powder and titanium white powder mixture 0~20%, white cement 0~15%, rubber powder 0~10%, floating bead powder 0~5%;My god Right resin 0~20%, styrene-acrylic emulsion 0~20%, formaldehyde absorbent 2%~6%, coalescents 2%~5%, defoamer 2%~ 5%, phytochrome 1%~3%, nano-antibacterial powder 0.5%~1% is constituted.
Another object of the present invention is to provide a kind of outdoor for being prepared using the thermal insulation coatings of hollow glass micropearl as described above Thermal insulation coatings, component is made up of hollow glass micropearl and compo material;The hollow glass micropearl and compo material Mass ratio be respectively 30%~50%, 50%~70%;The component example in mass ratio of the compo material is by ultra micro Fine and smooth sub- powder lime powder and titanium white powder mixture 0~20%, white cement 0~15%, rubber powder 0~10%, floating bead powder 0~5%;My god Right resin 0~20%, styrene-acrylic emulsion 0~20%, formaldehyde absorbent 2~6%, coalescents 2~5%, defoamer 2~5% is planted Element 1%~3%, nano-antibacterial powder 0.5%~1% is looked for constitute.
Advantages of the present invention and good effect are:
Hollow glass micropearl addition of the invention can substantially reduce the thermal conductivity factor of coating in coating, play heat-insulated Effect.
In patent of the present invention using hollow glass micropearl acting as in coating:Cenosphere proterties:Cenosphere is Hollow heavy wall microballon.Microballon 99.5% is aluminum silicate ceramic.It is a kind of high intensity, high rigidity, inert thick-wall hollow microballon.
Hollow glass micropearl energy reduces cost, increases solids content and promotes properties of product, specifically includes:Resin demand The potentiality of few/dosage are big:Because in any shape, spherical with minimum surface area/volume ratio, cenosphere is to resin Demand is also minimum.The accumulation situation of particle is also modified.The particle diameter distribution wide of cenosphere enables that small microballon is filled out It is charged in the space between big microballoon, forms a closely knit entirety.As a result, overall addition is high, it is highly filled, Relatively low organic volatile and the consumption of reduction other compositions;
Low viscosity/improvement mobility:Particle from irregular shape is different, and cenosphere is easy to roll among each other It is dynamic;This causes there is relatively low viscosity, preferable mobility using the system of cenosphere;And, the sprayable property of system Improved;
Hardness/wearability:Common coating or inserts are more or less in surface and leave some soft and hard particles, particle It is damaged or influence attractive in appearance after wearing away.However, cenosphere is that a kind of intensity is high, and wear-resisting and hard microballon, it can strengthen firmly Degree, wear-resisting and resistance to rinsing property;
Gloss is controlled:Used as a kind of packing material, cenosphere can play a part of reduce gloss, even add In the case that amount requirement is higher, he can also eliminate the disadvantage that normal dull agent causes viscosity to increase considerably.And compare into This is also low;
Inertia:Cenosphere is made up of inert fraction, thus with excellent property durable in use;
It is opaque:The spheroid of cenosphere makes light diffusion and scattering, the result is that it increased the covering of coating;
Dispersiveness:Due to its heavy wall pipe compression strength very high, it can bear the mixer of all kinds to cenosphere Process;
Nodeless mesh pollutes:Different from other fillers, the content of the silicon metal in cenosphere is below harmless level.It is hollow Microballon is not regarded as carcinogen, without especially mark harm Warning Sign.
Hollow glass micropearl material performance index of the invention has:
The hollow glass micropearl inside that hollow glass micropearl material tight arrangement of the invention is overlapped up and down is containing thin 10% gas, its thermal conductivity factor is extremely low, so coating has extraordinary heat insulation and preservation effect.Cenosphere is a kind of intensity Height, wear-resisting and hard microballon, compression strength is high.
Specify organic volatile in " limits of harmful substances in indoor decorating and refurnishing materials interior wall coating " state compulsion standard (voc) highest limitation is 200 g/l, and free formaldehyde is 0.1 g/kg.Organic volatile and free formaldehyde in emulsion paint It is mainly derived from emulsion and various auxiliary agents.The formula design of heat insulating inner wall paint product, first has to consider voc contents and the trip of emulsion From the content of formaldehyde.
Free formaldehyde content is less than 0.1 g/kg in styrene-acrylic emulsion of the invention, meets national standard, is that we prepare The first-selection of heat insulating inner wall paint.The special demands present invention according to individual clients can also select the emulsion without free formaldehyde.
The present invention is had from quality glass microballoon high, advantage:
1), chemical analysis:SiO2>67%, CaO>8.0%MgO>2.5%Na2O<14%, Al2O30.5-2.0, Fe2O3> 0.15 other 2.0%;
2), proportion:2.4-2.6 grams/cc;
Outward appearance:Bright and clean, rounding, glass transparent free from admixture;
Into circle rate:More than >=85%;
3), 0.1% of magnetic particle no more than product weight;
4), air bubble content is less than 10% in bead bead;
5) any silicones class composition, is not contained;
Using glass microballoon of good performance as the main body of inner-outer wall thermal insulating soft material, corresponding other materials system is equipped with Into thermal insulation coatings have very good heat-insulating property.Because the construction of this material is simple, take up room small volume, color with Meaning is adjustable, nontoxic, is highly suitable as heat insulating inner wall material.
Brief description of the drawings
Fig. 1 is the thermal insulation coatings preparation method flow chart of utilization hollow glass micropearl provided in an embodiment of the present invention.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to Limit the present invention.
Application principle of the invention is described in detail below in conjunction with the accompanying drawings.
The thermal insulation coatings of utilization hollow glass micropearl provided in an embodiment of the present invention, the guarantor of the utilization hollow glass micropearl The component of thermo-paint is made up of hollow glass micropearl and compo material;The hollow glass micropearl and compo material Mass ratio is respectively 30%~80%, 20%~70%;The component example in mass ratio of the compo material is by ultra tiny Powder of lacquer putty for use on pulverized limestone and titanium white powder mixture 0~20%, white cement 0~15%, rubber powder 0~10%, floating bead powder 0~5%;Naturally Resin 0~20%, styrene-acrylic emulsion 0~20%, formaldehyde absorbent 2~6%, coalescents 2~5%, defoamer 2~5%, plant Pigment 1%~3%, nano-antibacterial powder 0.5%~1% is constituted.
As shown in figure 1, the preparation method of the thermal insulation coatings of utilization hollow glass micropearl provided in an embodiment of the present invention, including Following steps:
S101:Example weighs each component of compo material in mass ratio, will be low in each component input drum-type blender Speed is mixed;
S103:Coating material each component to be mixed uniformly after mixing, is added by quality after importing another stainless steel The hollow glass micropearl that ratio is weighed, mixed on low speed stirs, and is utilized the thermal insulation coatings of hollow glass micropearl.
Mixed on low speed mixing speed is 150 revs/min~300 revs/min;Mixing time 60min~90min.
The thermal insulation coatings addition of the utilization hollow glass micropearl that will be obtained utilizes the thermal insulation coatings quality of hollow glass micropearl 30%~50% deionized water, obtain the thermal insulation coatings of the utilization hollow glass micropearl for smearing metope.
During addition deionized water, using heating stirring, whipping temp is 50 DEG C -80 DEG C.
Mixing time is 30min~60min.
Indoor heat insulating coating provided in an embodiment of the present invention, component is made up of hollow glass micropearl and compo material; The mass ratio of the hollow glass micropearl and compo material is respectively 50%~80%, 20%~50%;The mixing The component of coating material example in mass ratio by ultra tiny powder of lacquer putty for use on pulverized limestone and titanium white powder mixture 0~20%, white cement 0~ 15%, rubber powder 0~10%, floating bead powder 0~5%;Natural resin 0~20%, styrene-acrylic emulsion 0~20%, formaldehyde absorbent 2~ 6%, coalescents 2~5%, defoamer 2~5%, phytochrome 1%~3%, nano-antibacterial powder 0.5%~1% is constituted.
Outdoor thermal insulation coatings provided in an embodiment of the present invention, component is made up of hollow glass micropearl and compo material; The mass ratio of the hollow glass micropearl and compo material is respectively 30%~50%, 50%~70%;The mixing The component of coating material example in mass ratio by ultra tiny powder of lacquer putty for use on pulverized limestone and titanium white powder mixture 0~20%, white cement 0~ 15%, rubber powder 0~10%, floating bead powder 0~5%;Natural resin 0~20%, styrene-acrylic emulsion 0~20%, formaldehyde absorbent 2~ 6%, coalescents 2~5%, defoamer 2~5%, phytochrome 1%~3%, nano-antibacterial powder 0.5%~1% is constituted.
Hollow glass micropearl addition of the invention can substantially reduce the thermal conductivity factor of coating in coating, play heat-insulated Effect.
In patent of the present invention using hollow glass micropearl acting as in coating:Cenosphere proterties:Cenosphere is Hollow heavy wall microballon.Microballon 99.5% is aluminum silicate ceramic.It is a kind of high intensity, high rigidity, inert thick-wall hollow microballon.
Hollow glass micropearl energy reduces cost, increases solids content and promotes properties of product, specifically includes:Resin demand The potentiality of few/dosage are big:Because in any shape, spherical with minimum surface area/volume ratio, cenosphere is to resin Demand is also minimum.The accumulation situation of particle is also modified.The particle diameter distribution wide of cenosphere enables that small microballon is filled out It is charged in the space between big microballoon, forms a closely knit entirety.As a result, overall addition is high, it is highly filled, Relatively low organic volatile and the consumption of reduction other compositions;
Low viscosity/improvement mobility:Particle from irregular shape is different, and cenosphere is easy to roll among each other It is dynamic;This causes there is relatively low viscosity, preferable mobility using the system of cenosphere;And, the sprayable property of system Improved;
Hardness/wearability:Common coating or inserts are more or less in surface and leave some soft and hard particles, particle It is damaged or influence attractive in appearance after wearing away.However, cenosphere is that a kind of intensity is high, and wear-resisting and hard microballon, it can strengthen firmly Degree, wear-resisting and resistance to rinsing property;
Gloss is controlled:Used as a kind of packing material, cenosphere can play a part of reduce gloss, even add In the case that amount requirement is higher, he can also eliminate the disadvantage that normal dull agent causes viscosity to increase considerably.And compare into This is also low;
Inertia:Cenosphere is made up of inert fraction, thus with excellent property durable in use;
It is opaque:The spheroid of cenosphere makes light diffusion and scattering, the result is that it increased the covering of coating;
Dispersiveness:Due to its heavy wall pipe compression strength very high, it can bear the mixer of all kinds to cenosphere Process;
Nodeless mesh pollutes:Different from other fillers, the content of the silicon metal in cenosphere is below harmless level.It is hollow Microballon is not regarded as carcinogen, without especially mark harm Warning Sign
The thermal insulation coatings of utilization hollow glass micropearl provided in an embodiment of the present invention, the guarantor of the utilization hollow glass micropearl The component of thermo-paint is made up of hollow glass micropearl and compo material;The hollow glass micropearl and compo material Mass ratio is respectively:
In the thermal insulation coatings of utilization hollow glass micropearl provided in an embodiment of the present invention,
Natural resin:It is mainly used as coating, it can also be used to the production of papermaking, insulating materials, adhesive, medicine, spices etc. Process, can be used as the paint raw materials of ornament materials.
Styrene-acrylic emulsion:It is mainly used in buildings waterproof, casein glue, water-based ink, splicing adhesive etc. to be used, with nontoxic, stingless Swash, it is harmless, meet environmental requirement.
Coalescents can promote macromolecular compound Plastic Flow and elastic deformation also known as coalescing aid, improve cohesiveness Can, can in the range of wide construction temperature film forming material, be a kind of evanescent plasticizer, contribute to the wetting of color stuffing Dispersion, letdown phase add half contribute to suppress bubble generation.
Defoamer, is also called defrother or foamicide, and the bubble of many influence productions can be produced during industrial production Foam is, it is necessary to add defoamer.It is widely used in removing latex, textile sizing, food fermentation, biological medicine, coating, oil The unwanted bubbles produced during the industry productions such as work, papermaking, industry cleaning link, sewage disposal.In general, foam is that gas exists Coarse dispersion in liquid, belongs to solution-air heterogeneous system, and bulk density keeps off the gas-liquid dispersion of liquid close to gas Body, gas-liquid dispersion body is divided into the few " foam of few " bubble dispersion " the gentle many liquid of many gas of liquid.And defoamer can effectively go Foam-expelling, bubble.Defoamer of the invention is combined into containing amine, imines and amide-type using organosiloxane, polyethers, silicon and oil Organic reagent, the suds time is longer with antifoaming speed faster, and Applicable media scope is wider, or even harsh media environment such as height The characteristics of temperature, strong acid and highly basic.
Phytochrome includes fat-soluble chloroplast pigment and water miscible cell liquid pigment, and the former is present in chloroplaset, It is relevant with photosynthesis, such as chlorophyll;The latter is present in vacuole, and especially the color with flower is relevant, and such as anthocyanidin belongs to flavones Class material.Chlorophyll has bacteriostasis in itself, can be prepared into the medicine of anti-inflammatory.Water colo(u)r is mainly pattern glucoside, also known as Phytochrome includes fat-soluble chloroplast pigment and water miscible cell liquid pigment, and the former is present in chloroplaset, with light cooperation With relevant, such as chlorophyll;The latter is present in vacuole, and especially the color with flower is relevant, and such as anthocyanidin belongs to Flavonoid substances.Leaf Green element has bacteriostasis in itself, can be prepared into the medicine of anti-inflammatory.Water colo(u)r is mainly pattern glucoside, general also known as anthocyanidin Store-through is in spending.Water and ethanol are dissolved in, insoluble in organic solvents such as ether, chloroforms, meeting acetic acid dithizone can precipitate;Carry out miscellaneous Matter is removed and purify air.
In sum, thermal insulation coatings of the invention are nontoxic, harmless, "dead", and light resistance is strong, high adsorption capacity, can be with It is coated on ornament materials, the toxic gases such as formaldehyde, purify air, and durable in use, nondiscoloration can be absorbed.
Application principle of the invention is further described with reference to specific embodiment.
Embodiment 1:
Indoor heat insulating coating provided in an embodiment of the present invention, component is made up of hollow glass micropearl and compo material; The mass ratio of the hollow glass micropearl and compo material is respectively 50%, 50%;The group of the compo material Divide example in mass ratio by ultra tiny powder of lacquer putty for use on pulverized limestone and titanium white powder mixture 20%, white cement 15%, rubber powder 10%, floating bead powder 5%;Natural resin 20%, styrene-acrylic emulsion 20%, formaldehyde absorbent 2%, coalescents 3%, defoamer 3.5%, phytochrome 1%%, nano-antibacterial powder 0.5% is constituted.
Embodiment 2:
Indoor heat insulating coating provided in an embodiment of the present invention, component is made up of hollow glass micropearl and compo material; The mass ratio of the hollow glass micropearl and compo material is respectively 80%, 20%;The group of the compo material Divide example in mass ratio by ultra tiny powder of lacquer putty for use on pulverized limestone and titanium white powder mixture 20%, white cement 15%, rubber powder 10%, floating bead powder 5%;The styrene-acrylic emulsion 20% of natural resin 20%, formaldehyde absorbent 6%, defoamer 3.5%, nano-antibacterial powder 0.5% is constituted.
Embodiment 3:
Indoor heat insulating coating provided in an embodiment of the present invention, component is made up of hollow glass micropearl and compo material; The mass ratio of the hollow glass micropearl and compo material is respectively 60%, 40%;The group of the compo material Divide example in mass ratio by ultra tiny powder of lacquer putty for use on pulverized limestone and titanium white powder mixture 20%, white cement 10%, rubber powder 13%, floating bead powder 5%;Natural resin 20%, styrene-acrylic emulsion 12%, formaldehyde absorbent 6%, coalescents 5%, defoamer 5%, phytochrome 3%, nano-antibacterial powder 1% is constituted.
Embodiment 4
Outdoor thermal insulation coatings provided in an embodiment of the present invention, component is made up of hollow glass micropearl and compo material; The mass ratio of the hollow glass micropearl and compo material is respectively 30%, 70%;The group of the compo material Point in mass ratio example by ultra tiny powder of lacquer putty for use on pulverized limestone and titanium white powder mixture 0~20%, white cement 0~15%, rubber powder 0~ 10%, floating bead powder 0~5%;Natural resin 0~20%, styrene-acrylic emulsion 0~20%, formaldehyde absorbent 2~6%, coalescents 2 ~5%, defoamer 2~5%, phytochrome 1%~3%, nano-antibacterial powder 0.5%~1% is constituted.
Embodiment 5
Outdoor thermal insulation coatings provided in an embodiment of the present invention, component is made up of hollow glass micropearl and compo material; The mass ratio of the hollow glass micropearl and compo material is respectively 50%, 50%;The group of the compo material Point in mass ratio example by ultra tiny powder of lacquer putty for use on pulverized limestone and titanium white powder mixture 0~20%, white cement 0~15%, rubber powder 0~ 10%, floating bead powder 0~5%;Natural resin 0~20%, styrene-acrylic emulsion 0~20%, formaldehyde absorbent 2~6%, coalescents 2 ~5%, defoamer 2~5%, phytochrome 1%~3%, nano-antibacterial powder 0.5%~1% is constituted.
Embodiment 6
Outdoor thermal insulation coatings provided in an embodiment of the present invention, component is made up of hollow glass micropearl and compo material; The mass ratio of the hollow glass micropearl and compo material is respectively 40%, 60%;The group of the compo material Point in mass ratio example by ultra tiny powder of lacquer putty for use on pulverized limestone and titanium white powder mixture 0~20%, white cement 0~15%, rubber powder 0~ 10%, floating bead powder 0~5%;Natural resin 0~20%, styrene-acrylic emulsion 0~20%, formaldehyde absorbent 2~6%, coalescents 2 ~5%, defoamer 2~5%, phytochrome 1%~3%, nano-antibacterial powder 0.5%~1% is constituted.
Presently preferred embodiments of the present invention is the foregoing is only, is not intended to limit the invention, it is all in essence of the invention Any modification, equivalent and improvement made within god and principle etc., should be included within the scope of the present invention.

Claims (8)

1. a kind of thermal insulation coatings of utilization hollow glass micropearl, it is characterised in that the insulation of the utilization hollow glass micropearl is applied The component of material is made up of hollow glass micropearl and compo material;The quality of the hollow glass micropearl and compo material Ratio is respectively 30%~80%, 20%~70%;The component example in mass ratio of the compo material is by ultra tiny putty Powder lime powder and titanium white powder mixture 0~20%, white cement 0~15%, rubber powder 0~10%, floating bead powder 0~5%;Natural resin 0~20%, styrene-acrylic emulsion 0~20%, formaldehyde absorbent 2%~6%, coalescents 2%~5%, defoamer 2%~5% is planted Element 1%~3%, nano-antibacterial powder 0.5%~1% is looked for constitute.
2. a kind of preparation method of the thermal insulation coatings of utilization hollow glass micropearl as claimed in claim 1, it is characterised in that described Comprised the following steps using the preparation method of the thermal insulation coatings of hollow glass micropearl:
Example weighs each component of compo material in mass ratio, and mixed on low speed is stirred during each component is put into drum-type blender Mix;
Coating material each component to be mixed uniformly after mixing, adds what example in mass ratio was weighed after importing another stainless steel Hollow glass micropearl, mixed on low speed stirs, and is utilized the thermal insulation coatings of hollow glass micropearl.
3. the preparation method of the thermal insulation coatings of hollow glass micropearl is utilized as claimed in claim 2, it is characterised in that low speed is mixed It is 150 revs/min~300 revs/min to close mixing speed;Mixing time 60min~90min.
4. the preparation method of the thermal insulation coatings of hollow glass micropearl is utilized as claimed in claim 2, it is characterised in that will be obtained Utilization hollow glass micropearl thermal insulation coatings addition using the 30%~50% of the thermal insulation coatings quality of hollow glass micropearl Deionized water, obtains the thermal insulation coatings of the utilization hollow glass micropearl for smearing metope.
5. the preparation method of the thermal insulation coatings of hollow glass micropearl is utilized as claimed in claim 4, it is characterised in that addition is gone During ionized water, using heating stirring, whipping temp is 50 DEG C -80 DEG C.
6. the preparation method of the thermal insulation coatings of hollow glass micropearl is utilized as claimed in claim 5, it is characterised in that during stirring Between be 30min~60min.
7. the indoor heat insulating coating that prepared by a kind of thermal insulation coatings of utilization hollow glass micropearl as claimed in claim 1, its feature It is that the component of the indoor heat insulating coating is made up of hollow glass micropearl and compo material;The hollow glass micropearl 50%~80%, 20%~50% is respectively with the mass ratio of compo material;The component of the compo material is pressed Mass ratio by ultra tiny powder of lacquer putty for use on pulverized limestone and titanium white powder mixture 0~20%, white cement 0~15%, rubber powder 0~10%, Floating bead powder 0~5%;Natural resin 0~20%, styrene-acrylic emulsion 0~20%, formaldehyde absorbent 2%~6%, coalescents 2%~ 5%, defoamer 2%~5%, phytochrome 1%~3%, nano-antibacterial powder 0.5%~1% is constituted.
8. the outdoor thermal insulation coatings that prepared by a kind of thermal insulation coatings of utilization hollow glass micropearl as claimed in claim 1, its feature It is that the component of the outdoor thermal insulation coatings is made up of hollow glass micropearl and compo material;The hollow glass micropearl 30%~50%, 50%~70% is respectively with the mass ratio of compo material;The component of the compo material is pressed Mass ratio by ultra tiny powder of lacquer putty for use on pulverized limestone and titanium white powder mixture 0~20%, white cement 0~15%, rubber powder 0~10%, Floating bead powder 0~5%;Natural resin 0~20%, styrene-acrylic emulsion 0~20%, formaldehyde absorbent 2%~6%, coalescents 2%~ 5%, defoamer 2%~5%, phytochrome 1%~3%, nano-antibacterial powder 0.5%~1% is constituted.
CN201710261969.8A 2017-04-20 2017-04-20 A kind of thermal insulation coatings of utilization hollow glass micropearl and preparation method thereof Pending CN106892626A (en)

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CN101696334A (en) * 2009-10-27 2010-04-21 华南理工大学 Dry powder paint for construction as well as preparation method and use method thereof
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CN104230230A (en) * 2014-08-28 2014-12-24 黄艳 Antimicrobial architectural paint
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1384154A (en) * 2001-05-09 2002-12-11 张为民 Building powder paint and its production process
CN101671523A (en) * 2009-10-01 2010-03-17 厦门大学 Aqueous flame-retardant and thermal-insulated coating and preparation method thereof
CN101696334A (en) * 2009-10-27 2010-04-21 华南理工大学 Dry powder paint for construction as well as preparation method and use method thereof
CN102702822A (en) * 2012-06-12 2012-10-03 中国科学院广州能源研究所 SiO2 freeze-drying glue composite thermal insulation exterior wall coating and preparation method thereof
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