CN106884336A - A kind of banner fabric of the anti-gas shock of waterproof and preparation method thereof - Google Patents

A kind of banner fabric of the anti-gas shock of waterproof and preparation method thereof Download PDF

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Publication number
CN106884336A
CN106884336A CN201710266164.2A CN201710266164A CN106884336A CN 106884336 A CN106884336 A CN 106884336A CN 201710266164 A CN201710266164 A CN 201710266164A CN 106884336 A CN106884336 A CN 106884336A
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China
Prior art keywords
fabric
nylon
waterproof
flag
calico
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Granted
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CN201710266164.2A
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CN106884336B (en
Inventor
李利娜
王春姣
徐杰
罗岳文
贾书刚
张建涛
曾曼成
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Beijing Bangwei high tech new material technology Co.,Ltd.
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BEIJING BANGWEI HIGH-TECH SPECIAL TEXTILE Co Ltd
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Priority to CN201710266164.2A priority Critical patent/CN106884336B/en
Publication of CN106884336A publication Critical patent/CN106884336A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0034Polyamide fibres
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1656Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662Synthetic film-forming substance
    • C09D5/1675Polyorganosiloxane-containing compositions
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/128Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02Material containing basic nitrogen
    • D06P3/04Material containing basic nitrogen containing amide groups
    • D06P3/24Polyamides; Polyurethanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/003Transfer printing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00Chemical constitution of the fibres, threads or yarns
    • D06N2201/02Synthetic macromolecular fibres
    • D06N2201/0263Polyamide fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00Macromolecular materials of the coating layers
    • D06N2203/06Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/066Silicon polymers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/14Properties of the materials having chemical properties
    • D06N2209/142Hydrophobic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/14Properties of the materials having chemical properties
    • D06N2209/146Soilproof, soil repellent

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Banner fabric the present invention relates to a kind of anti-gas shock of waterproof and preparation method thereof, it is characterised in that the banner fabric is provided with waterproof coating with high-strength nylon66 fiber as base material on high-strength nylon66 fiber, the raw material of water-repellent paint used by waterproof coating constitutes and is:The diluent of solvent type resin class silicone oil 30~35%, toluene 25~30%, curing agent 0.5~1%, silane coupler 3~5%, catalyst 1~3% and surplus;Pattern is printed on high-strength nylon66 fiber after coating.The fabric good water-proof effect, anti-gas shock is good, and printed color is uniform, clear patterns, color fastness are high, one side print can reach double-side pattern effect.

Description

A kind of banner fabric of the anti-gas shock of waterproof and preparation method thereof
Technical field
The present invention relates to banner fabric manufacture technology field, the banner fabric of specially a kind of anti-gas shock of waterproof and its Preparation method.The flag that the method makes can reach waterproof, anti-gas shock and bloth printing has double-sided effect.
Background technology
In September in 2015 commemorates war 70 anniversary military review on 3rd, a pair of colors size point of helicopter suspension Wei not 6m × 9m and 6m × 7.5m, 160~180 kilometers/hour of flying speed.Allow national flag, the army flag can not be random when reviewing troops Swing, stretch straight Founder, and be once a great problem in preparing of reviewing troops at all without breakage after high-speed flight.High-speed flight In, the red flag being suspended on helicopter cable wire can be subject to huge gas shock, can particularly occur in red flag afterbody violent Shake, produces " the hitting ripple " more than velocity of sound, and conventional use of banner fabric far can not meet requirement.30 minutes left sides of general flight The right side, just breakage can't bear in flag face.
Current banner fabric base material has cotton, silk, terylene, nylon, acrylic fibers etc., and conventional mostly plain cloth, wherein with Nylon facing material is preferred, and it has good strength, wearability etc., but different size, different tissues nylon facing material in the ratio of strength to weight Upper difference is larger, therefore selection is that flag makes an important step.The preparation method of double-side pattern flag is printed using discharge mostly Flower process makes, and pulling out print technique needs plate-making, is difficult to control on, brightly painted web process complicated to super large breadth, color. Present printing technique does not all carry out water-proofing treatment, cause rainfall or meet flag in the case of water sprinkles easily soak, it is dirty;In high wind Or special requirement is blown hit in the case of flag at high speed, existing banner fabric shakes violent, badly broken, is difficult to keep original shape State, so needing to improve intensity, tear resistance, the water proof anti-soil performance of banner fabric.Usual flag is a kind of means of publicity, Therefore need color it is good, it is two-sided have a decalcomania effect, prior art has not been able to accomplish only carry out bloth printing and occur double Face prints figuratum effect.
The content of the invention
In view of the shortcomings of the prior art, the technical problem that the present invention is intended to solve is to provide a kind of anti-gas shock of waterproof Banner fabric and preparation method thereof.The fabric good water-proof effect, anti-gas shock is good, and printed color is uniform, clear patterns, color Fastness is high, one side print can reach double-side pattern effect (i.e. positive and negative pattern aberration is small), is mainly used in advertisement, flag, vertically hung scroll, account Paulin, umbrella cloth etc. require the fabric stamp processing of waterproof, double-side pattern effect.The preparation method is from high-strength nylon66 fiber as base Material, while by substantial amounts of experiment from the water-repellent paint based on solvent type resin class silicone oil, can effectively by nylon66 fiber Creatively combined with thermal transfer printing, realized above-mentioned waterproof, the effect of anti-gas shock, and positive and negative pattern aberration is small, should Method process is simple, without transforming loom and printing equipment, it is easy to industrializing implementation.
The present invention solves the technical scheme that the fabric technical problem uses:A kind of flag of the anti-gas shock of waterproof is provided Flag fabric, it is characterised in that the banner fabric is not more than the nylon fiber long filament of 100D as raw material with fineness, calico is practiced in nylon Waterproof coating is provided with, the raw material composition of water-repellent paint used by waterproof coating is:Solvent type resin class silicone oil 30~35%, toluene 25~30%, the diluent of curing agent 0.5~1%, silane coupler 3~5%, catalyst 1~3% and surplus;After coating Nylon practice calico on be printed on pattern;The spray rating of the fabric is 4 grades, and colorfastness to rubbing is 4-5 grades, and color fastness to light is not low In 4 grades, splice mutual dyefastness 4-5 grades;The tearing brute force of the fabric is that nylon is practiced more than the three times of calico tearing brute force.
The present invention solves the technical scheme that the preparation method technical problem uses:A kind of anti-gas of above-mentioned waterproof is provided The preparation method for flowing the banner fabric of impact, the preparation method is comprised the following steps:
1) the nylon fiber long filament of 100D is not more than as raw material with fineness, makes nylon fabric, then carry out practicing white and drying Sizing, obtains nylon and practices calico;
2) coating treatment:
Water-repellent paint is allocated first, and the raw material composition of the water-repellent paint is:Solvent type resin class silicone oil 30~35%, first The diluent of benzene 25~30%, curing agent 0.5~1%, silane coupler 3~5%, catalyst 1~3% and surplus;Then exist Step 1) nylon that obtains practices deployed water-repellent paint, then drying and shaping coated on calico, i.e., formed on the top layer for practicing calico Waterproof coating;
3) thermal transfer printing:
According to required flag pattern, the decalcomania that will have been designed using disperse dyes is printed onto in transfer paper, and Clot, obtains printing figuratum transfer paper;Again on heat-transfering printing machine by the pattern thermal transfer in transfer paper in coating treatment On experienced calico afterwards, thermal transfer temperature is 200~240 DEG C, and thermal transfer speed is 5.2m/min~6.2m/min;
4) by through step 3) fabric that obtains after thermal transfer printing carries out clot, that is, obtain the described anti-gas shock of waterproof Banner fabric.
The present invention also protects a kind of flag being made using above-mentioned fabric.
Compared with prior art, the beneficial effects of the invention are as follows:
The prominent substantive distinguishing features of the present invention are:The fabric is provided with waterproof coating, and the waterproof coating not only acts as waterproof Effect, moreover it is possible to improve the dyestuff color yield of nylon facing material, improves the tear resistance of nylon facing material, make fabric run into rainfall or In the case of chance water sprinkles, can not exclusively soak, not get wet, keep good extended configuration.The preparation method uses high-strength nylon Fiber is used as base material, and the ratio of strength to weight is high, while from specific silicone oil water-repellent paint, making that hot transfer can be realized on nylon facing material Stamp, while significantly improving the overall tear resistance of fabric, overcoming can not be carried out on RIPSTOP in the prior art The technical barrier of thermal transfer printing, and there is double-side pattern effect by reaching a face stamp after thermal transfer printing.
Marked improvement of the invention is:
1. the performance of banner fabric, the heat transfer print of nylon facing material can be significantly improved using preparation method of the present invention Flower performance, through coating treatment after, reached good printing quality, waterproof effect, improve the tear resistance of fabric, ageing-resistant Performance.
2. preparation method of the present invention uses thermal transfer printing technique, strict to control the thermal transfer temperature in thermal transfer printing to be 200 DEG C~240 DEG C, while strictly control thermal transfer speed, makes that fabric color yield is obviously improved, color fastness is significantly improved, can obtain To the effect of a face printed double-sided pattern, when banner fabric is made, color fastness and color difference index are satisfied by national mark after printing and dyeing Related request in standard, and thermal transfer printing process operation is simple, it is not necessary to complicated plate-making, energy-saving and emission-reduction, meeting environmental protection will Ask.And preparation method of the present invention can be suitably used for, and super large breadth, color be complicated, brightly painted banner fabric making.
3. the flag that after tested, preparation method of the present invention makes is 160~180km/h, wind speed 8m/s in flying speed, is flown Remain to normally use under conditions of about 300 meters of row height, i.e. the tear resistance of banner fabric is stronger;Simultaneously can waterproof, antifouling, Flag remains to keep launching the straight Founder of attitude in the case of rainfall or chance water sprinkle, it is ensured that the effect that flag shows in the air, carries The use value of flag high.
Specific embodiment
The present invention will be further described with reference to embodiments.It should be understood that these embodiments are for explaining the present invention Rather than the protection domain of limitation the claims in the present invention.The implementation condition used in embodiment can be according to specific producer Condition does further adjustment, and unreceipted implementation condition is usually the condition in normal experiment.
The banner fabric (abbreviation fabric) of the anti-gas shock of waterproof of the present invention is not more than 100D with fineness, and single wire fracture is strong Spend for the nylon fiber long filament of 5.0~9.0CN/dtex is raw material, practice in nylon and be provided with waterproof coating, waterproof coating institute on calico Constituted with the raw material of water-repellent paint and be:Solvent type resin class silicone oil 30~35%, toluene 25~30%, curing agent 0.5~1%, The diluent of silane coupler 3~5%, catalyst 1~3% and surplus;Practiced by thermal transfer printing nylon after coating white Pattern is printed on cloth;The spray rating of the fabric is 4 grades, and colorfastness to rubbing is 4-5 grades, and color fastness to light is more than 4 grades, and splicing is mutual Dyefastness 4-5 grades;The tearing brute force of the fabric is that nylon is practiced more than the three times of calico tearing brute force;The fabric bloth printing can Obtain the effect of double-side pattern.
Fabric of the present invention is further characterized by the nylon fiber for high-strength nylon 66 fiber, high-strength nylon 66 fiber With toughness higher, be conducive to further improving the tear resistance of nylon fabric.
The preparation method (abbreviation preparation method or method) of the banner fabric of the above-mentioned anti-gas shock of waterproof includes following step Suddenly:
1) fabric pretreatment:
Fineness is not more than 100D, and single wire fracture intensity is that the nylon fiber long filament of 5.0~9.0CN/dtex is raw material, is adopted With plain weave two-wire lattice weave, nylon fabric is made, then carries out routine and practice white and drying and shaping, obtained nylon and practice calico;
2) coating treatment:
Water-repellent paint is allocated first, and the raw material composition of the water-repellent paint is:Solvent type resin class silicone oil 30~35%, first The diluent of benzene 25~30%, curing agent 0.5~1%, silane coupler 3~5%, catalyst 1~3% and surplus;Then exist Step 1) nylon that obtains practices deployed water-repellent paint, then drying and shaping coated on calico, i.e., formed on the top layer for practicing calico Waterproof coating;The difference of the specific composition and content of the raw material composition of water-repellent paint can have shadow to the color of final stamp Ring, coloured light also has a minor variations, but it is all preferable in the color using this water-repellent paint stamp on the whole;
3) thermal transfer printing:
According to required flag pattern, the stamp that will have been designed in 150~230 DEG C of sublimation characteristics using disperse dyes Pattern printing in transfer paper, if practicing calico breadth is less than flag pattern dimension, then be accomplished by being divided into flag pattern Fritter, by graphic-print after segmentation to fabric, global pattern is spliced into during sewing flag again;Then clot, obtains being printed on figure The transfer paper of case;Again on heat-transfering printing machine by the pattern thermal transfer in transfer paper in step 2) experienced calico after coating treatment On, thermal transfer temperature is 200~240 DEG C, and thermal transfer speed is 5.2m/min~6.2m/min, different thermal transfer temperature and speed Setting, influence can be produced on the shade of stamp;
4) by through step 3) fabric that obtains after thermal transfer printing carries out clot, that is, obtain the described anti-gas shock of waterproof Banner fabric.
The fineness that preparation method of the present invention is further characterized by the high-strength nylon fiber long filament is 15D~70D, this The fabric that kind raw material is made is frivolous and the ratio of strength to weight is high.
The fabric construction that preparation method of the present invention is further characterized by nylon66 fiber fabric is plain weave two-wire lattice tissue, double The area of each grid of line lattice is not more than 1 square centimeter, and the size of grid can be 2.5mm × 2.5mm, 3mm × 3mm, 4mm × 4mm, 3mm × 5mm, 5mm × 5mm etc., grid size can influence tear resistance, grid to use rib weave, form grid Effect, can significantly improve the tear resistance of fabric.
Preparation method of the present invention is further characterized by preferably 220~230 DEG C of the thermal transfer temperature.
It is white that preparation method of the present invention is further characterized by the white silk of pattern thermal transfer in transfer paper after coating treatment In the one side of the waterproof coating of cloth.Preparation method of the present invention can be coated in coating treatment with one side, it is also possible to dual coating, The experienced calico of the one side with waterproof coating carries out thermal transfer printing, and the positive and negative aberration of the fabric for obtaining is smaller, color more light It is bright.
Preparation method of the present invention is through step 4) breadth of the banner fabric of the anti-gas shock of waterproof that obtains of clot is not more than 1.9 meters.Specific breadth is relevant with the width of fabric woven design, depending on the width that coating is processed, specific size with to be made Size into flag finished product is relevant.If the flag size for making is especially huge, such as 6 × 9 meters of the national flag of reviewing troops, fabric breadth Bigger, the road number of flag splicing is fewer.At present, the maximum breadth of thermal transfer printing processing is 3.2 meters, and fabric breadth maximum can be arrived 3.2 meters, but the Breadth Maximum of coating processing is 1.9 meters or so, so the Breadth Maximum of the method for the invention finished product fabric is not More than the Breadth Maximum that coating is processed.The method of the invention is different from conventional ROTARY SCREAM PRINTING, PLATE SCREAM PRINTING, discharge printing, It can be more rich more true to nature with more flexible design design, flower pattern chi width, color.
The technological principle of preparation method of the present invention is:Practicing calico to nylon before thermal transfer printing carries out coating treatment, passes through Crossing material behind coating treatment can reach the effect of waterproof, and can change nylon fabric molecule link number, significantly improve fabric Color yield, dyestuff can effectively penetrate into the back side, reach a face stamp and the effect of double-side pattern occur.
Although preparation method of the present invention solidifies various influence factors by repetition test, it is determined that related process parameters, In actual production because ink-jet board difference, transfer interpreter temporary parking, start shooting initial transfer state and continuously transfer printing state etc. Factor influence still has micro variation, so as to cause aberration.Using the flag same continuous air brushing of printing device, a migration volume Paper correspondence flag, entire volume fabric has once printed during thermal transfer printing, suitably adjusts transfer speed, and transfer temperature can mitigate Aberration.The thermal transfer printing is exactly that the pattern on transfer printing paper is transferred on fabric by heat transfer machine, wherein shifting The numerial code spray drawing method that the preparation method of calico paper has numerial code spray drawing method, roller printing method etc., use can produce various patterns Banner fabric, and process is simple is convenient.
Banner fabric obtained in preparation method of the present invention just can form duplex pringing effect by a thermal transfer printing Really, color yield reaches more than 90%;With good water proof anti-soil function, flag is set to tackle the bad weathers such as rainwater, significantly The blowing-resistant that improve flag hits ability.The present invention can use fineness to be not more than the nylon66 fiber of 100D for raw material can also be used Nylon 6 is raw material, and during from high-strength nylon66 fiber as raw material, fabric has intensity and tear resistance higher.Present invention system Can be used to make the fabric of various advertisement flags, various countries' national flag, coloured flag, sandy beach flag, Gua Qi, tent cloth, umbrella cloth as method, be applicable Scope is wide.
Embodiment 1
The present embodiment makes jumbo red flag fabric, and specific preparation method is:
1) fabric pretreatment:
With high-strength nylon 66 fiber long filament as raw material, weaved using two-wire lattice plain weave, make nylon66 fiber fabric, then enter Row is conventional to practice white and drying and shaping, obtains nylon and practices calico;
2) coating treatment:
Formula components are mixed in proportion first and obtains water-repellent paint, the raw material composition of the water-repellent paint is:It is molten Formulation resinae silicone oil 34%, toluene 26%, curing agent 0.8%, silane coupler 3.5%, catalyst 1.5% and surplus it is dilute Release agent;Then in step 1) coat deployed water-repellent paint on the fabric that obtains, and be one side coating, then drying and shaping, i.e., Waterproof coating is formed on the top layer for practicing calico;Water-repellent paint is after deployed, it is necessary to be used in 24 hours;
3) thermal transfer printing:
According to the pattern of required jumbo red flag, the decalcomania that will have been designed using disperse dyes is printed onto transfer paper On, and clot, obtain printing figuratum transfer paper;Pattern in transfer paper is alignd with the coat side of fabric, then in heat By the pattern thermal transfer in transfer paper in step 2 on transfer printing machine) on experienced calico after coating treatment, thermal transfer temperature is 230 DEG C, thermal transfer speed is 6m/min;
4) by through step 3) fabric that obtains after thermal transfer printing carries out clot, that is, obtain the described anti-gas shock of waterproof Banner fabric, jumbo red flag fabric of the present embodiment for needed for.
The high-strength nylon 66 fiber long filament is that square meter grammes per square metre is 32g/m in the present embodiment2Nylon66 fiber practice white silk tartan, carefully It is 29D to spend, and single wire fracture intensity is 7.5CN/dtex;Grid size is 2.5mm × 2.5mm.During thermal transfer, the figure in transfer paper Case is imprinted in the one side of the waterproof coating of the experienced calico after coating treatment.
Jumbo red flag fabric obtained in above-mentioned preparation method is carried out into performance test, is detected by third party testing agency, The tearing resistance of jumbo red flag fabric is significantly increased obtained in the present embodiment, greatly improves fabric and resists air-flow and blows the energy for hitting Power.Meanwhile, the color fastness of fabric stamp can be significantly improved using the method, realize a face stamp and the effect of double-side pattern occur Really, had a great deal of practical meanings for banner fabric.The spray rating of jumbo red flag fabric obtained in the present embodiment is 4 Level, the colorfastness to rubbing of fabric is 4-5 grades, and color fastness to light is more than 4 grades, splices mutual 4-5 grades of dyefastness (staining), positive and negative Aberration 4-5 grades.Result of practical application proves, the 6m × 9m flags made using the material, hangs under helicopter, with 160~ 180 kilometers/hour speed flight, when be about 2 hours, flight terminate after, only the flag lower right corner produce about 3 × 5cm or so Flash.And the flag of in the market conventional material, comparable applications condition, flight about half an hour, flag just breakage fall four/ Three or so.Under drizzle or moderate rain meteorological condition, straight Founder is launched in helicopter suspension flight, flag face, and flag face do not soak in itself, no Shirring, a small amount of globule of residual can also fall after shake from flag emaciated face.And the flag of other fabrics, comparable applications condition, flag face Soak, shirring.
Embodiment 2
The present embodiment makes a kind of banner fabric of the anti-gas shock of waterproof, specific preparation method with embodiment 1, difference Place is that the high-strength nylon 66 fiber long filament is that square meter grammes per square metre is 39g/m in the present embodiment2Nylon66 fiber practice white silk tartan, fineness It is 30D;Grid size is 3 × 5mm;The raw material of the water-repellent paint is constituted:Solvent type resin class silicone oil 32%, toluene 27%th, the diluent of curing agent 0.8%, silane coupler 4%, catalyst 1.2% and surplus;Thermal transfer temperature is 223 DEG C, heat Transfer speed is 5.6m/min.
The banner fabric of the anti-gas shock of waterproof obtained in the present embodiment is designated as fabric A.Mechanics, waterproof to fabric A, color The performance indications such as fastness are tested, as a result for:(1) tearing brute force:Warp-wise 142N, broadwise 139N;(2) colorfastness to rubbing is 4- 5 grades;(3) positive and negative aberration is 4-5 grades;(4) spray rating is 4 grades.
Comparative example
, with embodiment 2, difference is that painting is eliminated in manufacturing process for selected raw material and preparation method in comparative example Layer processing procedure, step 1) treatment after directly carry out thermal transfer printing technique, finished product fabric, the finished product fabric is designated as fabric B。
Fabric A obtained in embodiment 2 and comparative example and fabric B are carried out into correlated performance test and comparison, by detection, fabric A and fabric B difference are:(1) tearing brute force:The tearing brute force of fabric A is warp-wise 142N, broadwise 139N;Tearing for fabric B is strong Power is warp-wise 20N, broadwise 19N;(2) colorfastness to rubbing:Fabric A is 4-5 grades, and fabric B is 1-2 grades;(3) positive and negative aberration:Face Material A is 4-5 grades, and fabric B is 3 grades.(4) fabric A spray ratings are 4 grades, and fabric B spray ratings are 1 grade.
In addition, (under the meteorological condition of drizzle or moderate rain, helicopter is flown with the speed of 160~180km/h under the same conditions Row 2h) make a flight test, shake violent in the flag flight course of comparative example, sound is huge, and flag face is integrally soaked, and surface has Large area shirring, though there is improvement after the exhibition of stretching, shirring still substantially, has had a strong impact on the attractive in appearance of flag.And the flag of embodiment 2 Founder that flag In-Flight Deployment attitude is straight, deployed condition is hardly influenceed by rainy weather, and after flight terminates, on inspection, flag face is not Soak, not shirring, a small amount of globule of residual can also fall after shake from flag emaciated face, and the pattern printed and dyed on red flag is in rainwash Under, do not have any dizzy dye, decolouring, colour fading, splicing mutually dye the problems such as.
Embodiment 3
The present embodiment makes a kind of banner fabric of the anti-gas shock of waterproof, specific preparation method with embodiment 1, difference It in the present embodiment from nylon 6 fiber long filament is raw material that place is, square meter grammes per square metre is 73g/m2, fineness is 70D, and grid size is 2×2mm。
The performance indications such as mechanics, waterproof, the color fastness of banner fabric to the anti-gas shock of waterproof obtained in the present embodiment Tested, as a result for:(1) tearing brute force:Warp-wise 213N, broadwise 204N;(2) colorfastness to rubbing is 4-5 grades;(3) positive and negative Aberration is 4 grades;(4) spray rating is 4 grades;(5) 4 grades of color fastness to light.The tearing brute force of the fabric is practiced compared with the present embodiment nylon Tearing brute force (the tearing brute force of calico:Warp-wise 114N, broadwise 48.1N) have and significantly lifted.
Embodiment 4
The present embodiment makes banner fabric, in coating treatment, carries out dual coating.
Embodiment 5
The present embodiment is a kind of advertisement flag of the anti-gas shock of waterproof, and size is 1.35m × 6m, and the fabric of the advertisement flag is The preparation method of embodiment 2 is obtained.
The processes such as white silk involved in the present invention is white, drying and shaping, clot are prior art.
The present invention does not address part and is applied to prior art.

Claims (8)

1. the banner fabric of the anti-gas shock of a kind of waterproof, it is characterised in that the banner fabric is not more than the nylon of 100D with fineness Fiber filament is raw material, practices in nylon and be provided with waterproof coating on calico, and the raw material composition of water-repellent paint used by waterproof coating is:It is molten Formulation resinae silicone oil 30~35%, toluene 25~30%, curing agent 0.5~1%, silane coupler 3~5%, catalyst 1~ 3% and the diluent of surplus;Nylon after coating to be practiced and be printed on pattern on calico;The spray rating of the fabric is 4 grades, and rub color Fastness is 4-5 grades, and color fastness to light is not less than 4 grades, is spliced mutual dyefastness 4-5 grades;The tearing brute force of the fabric is practiced for nylon It is more than the twice of calico tearing brute force.
2. the banner fabric of the anti-gas shock of waterproof according to claim 1, it is characterised in that the nylon fiber is height Strong nylon 66 fiber.
3. a kind of preparation method of the banner fabric of the anti-gas shock of waterproof described in claim 1 or 2, the preparation method includes Following steps:
1) fabric pretreatment:
The nylon fiber long filament of 100D is not more than as raw material with fineness, nylon fabric is made, then carries out practicing white and drying and shaping, obtained Practice calico to nylon;
2) coating treatment:
Water-repellent paint is allocated first, and the raw material composition of the water-repellent paint is:Solvent type resin class silicone oil 30~35%, toluene 25 ~30%, the diluent of curing agent 0.5~1%, silane coupler 3~5%, catalyst 1~3% and surplus;Then in step 1) deployed water-repellent paint, then drying and shaping are coated on the nylon white silk calico for obtaining, i.e., forms waterproof on the top layer for practicing calico Coating;
3) thermal transfer printing:
According to required flag pattern, the decalcomania that will have been designed using disperse dyes is printed onto in transfer paper, and clot, Obtain printing figuratum transfer paper;White silk on heat-transfering printing machine by the pattern thermal transfer in transfer paper after coating treatment again On calico, thermal transfer temperature is 200~240 DEG C, and thermal transfer speed is 5.2m/min~6.2m/min;
4) by through step 3) fabric that obtains after thermal transfer printing carries out clot, that is, obtain the flag of the described anti-gas shock of waterproof Flag fabric.
4. preparation method according to claim 3, it is characterised in that the fineness of the nylon fiber long filament is 15D~70D.
5. preparation method according to claim 3, it is characterised in that the thermal transfer temperature is 220~230 DEG C.
6. preparation method according to claim 3, it is characterised in that the pattern thermal transfer in transfer paper is after coating treatment Experienced calico waterproof coating one side on.
7. according to any described preparation methods of claim 3-6, it is characterised in that the fabric construction of the nylon fabric is flat Line two-wire lattice tissue.
8. a kind of flag, it is characterised in that fabric of the flag as described in claim 1 or 2 is made.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109371709A (en) * 2018-09-28 2019-02-22 深圳特朗商实业有限公司 Anti-dropout thickening agent and its preparation process on a kind of waterproof coating fabric
CN111851086A (en) * 2020-07-06 2020-10-30 安徽拓扑数码新材料有限公司 Production method of high-weather-resistance flag fabric
CN112339466A (en) * 2020-11-07 2021-02-09 泗阳捷锋帽业有限公司 Reflective film thermal transfer printing method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3922399A (en) * 1974-06-21 1975-11-25 Arnold G Ochsner Dual surface textiles
CN101372813A (en) * 2008-10-17 2009-02-25 仪征新天地织物面料实业有限公司 Waterproof breathable environment-protective facing material and production method thereof
CN104453350A (en) * 2014-11-30 2015-03-25 盐城市华普轻纺机械有限公司 Non-woven fabric for tent
CN104499288A (en) * 2014-11-30 2015-04-08 盐城市华普轻纺机械有限公司 High-waterproof non-woven fabric for tent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3922399A (en) * 1974-06-21 1975-11-25 Arnold G Ochsner Dual surface textiles
CN101372813A (en) * 2008-10-17 2009-02-25 仪征新天地织物面料实业有限公司 Waterproof breathable environment-protective facing material and production method thereof
CN104453350A (en) * 2014-11-30 2015-03-25 盐城市华普轻纺机械有限公司 Non-woven fabric for tent
CN104499288A (en) * 2014-11-30 2015-04-08 盐城市华普轻纺机械有限公司 High-waterproof non-woven fabric for tent

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109371709A (en) * 2018-09-28 2019-02-22 深圳特朗商实业有限公司 Anti-dropout thickening agent and its preparation process on a kind of waterproof coating fabric
CN111851086A (en) * 2020-07-06 2020-10-30 安徽拓扑数码新材料有限公司 Production method of high-weather-resistance flag fabric
CN112339466A (en) * 2020-11-07 2021-02-09 泗阳捷锋帽业有限公司 Reflective film thermal transfer printing method

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