CN106883690A - A kind of inventive thick film paste solvent-borne type electrophoretic paint - Google Patents
A kind of inventive thick film paste solvent-borne type electrophoretic paint Download PDFInfo
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- CN106883690A CN106883690A CN201710221705.XA CN201710221705A CN106883690A CN 106883690 A CN106883690 A CN 106883690A CN 201710221705 A CN201710221705 A CN 201710221705A CN 106883690 A CN106883690 A CN 106883690A
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- thick film
- electrophoretic paint
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4473—Mixture of polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4407—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained by polymerisation reactions involving only carbon-to-carbon unsaturated bonds
- C09D5/4411—Homopolymers or copolymers of acrylates or methacrylates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/448—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications characterised by the additives used
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to paint field, especially a kind of inventive thick film paste solvent-borne type electrophoretic paint is composed of the following raw materials by weight：20 25 parts of phenylpropyl alcohol water-proof emulsion, 15 20 parts of pure organic siliconresin, 20 45 parts of modified amine curing agent, 10 20 parts of crosslinking agent, 47 parts of deionized water, 15 20 parts of cosolvent, 36 parts of levelling agent, 59 parts of nertralizer, 6 11 parts of metal oxide, 9 13 parts of solid additive, 6 11 parts of the first compound additive, 5 10 parts of the second compound additive；Electrophoretic paint of the invention uses phenylpropyl alcohol water-proof emulsion and pure organic siliconresin, with reference to the solid additive and metal oxide that add so that the electrophoretic paint has strong thick film.
Description
Technical field
The present invention relates to paint field, especially a kind of inventive thick film paste solvent-borne type electrophoretic paint.
Background technology
Electrophoretic paint is divided into ability cathode electrophoresis and anodic electrophoresis, and electrophoretic coating is used as the new low stain of a class, province's energy, province's money
Source, the coating for acting as protection and anticorrosive property, with smooth coating, the features such as water resistance and good chemical resistance, easily realize applying
The mechanization and automation of industry are filled, it is suitable complex-shaped, there are edge corner angle, hole Workpiece coating, it is widely used at present
The application of the handwares such as automobile, automatic vehicle, electromechanics, household electrical appliances.Electrophoretic coating and finishing obtain industry after the sixties in 20th century
Using, closed circulating system operation can be carried out using electrophoretic coating, coating almost 100% is utilized.Electrophoretic coating is with water-soluble
Property or water dispersible Ionomer be film forming matter, can be that anode can also be used as negative electrode by painting workpiece；Existing paint film
Surface irregularity, and surface is more dull and heavy, does not reach requirement attractive in appearance and practical.
The content of the invention
A kind of problem that the purpose of the present invention exists aiming at above-mentioned prior art, there is provided inventive thick film paste solvent-borne type electrophoresis
Paint.
The technical solution adopted in the present invention is：A kind of inventive thick film paste solvent-borne type electrophoretic paint, is composed of the following raw materials by weight：
20-25 parts of phenylpropyl alcohol water-proof emulsion, pure organic siliconresin 15-20 parts, modified amine curing agent 20-45 parts, crosslinking agent 10-20 parts, go
Ionized water 4-7 parts, cosolvent 15-20 parts, levelling agent 3-6 parts, nertralizer 5-9 parts, metal oxide 6-11 parts, solid additive
9-13 parts, first compound additive 6-11 parts, second compound additive 5-10 parts.
The modified amine curing agent is by 1.0-1.5 in mass ratio：1.0-2.0：The polyamine of 0.5-1.0 proportionings, shrink are sweet
Grease and containing double bond compound composition.
The crosslinking agent is by 1-2 in mass ratio：3-5：Compound alcohol ether, isopropanol and silicone fluid composition that 2-4 is matched.
The solid additive is pressed for particle diameter 10-30 nanometers of silica flour of the molybdenum disulfide nano ball with particle diameter 6-9 microns
According to mass ratio 1-3:The mixture of 2-5 compositions.
First compound additive is by 1-2 in mass ratio：3-5：2-4：2 acrylamides for matching, 2- acrylamidos-
2- methyl propane sulfonic acids, dimer (fatty acid) yl and zinc stearate composition.
Second compound additive is by 1.0-1.5 in mass ratio：0.3-0.5：The methyl trimethoxy epoxide of 1.2-1.4 proportionings
Silane, Hydroxypropyl methylcellulose and 2- cyanacrylates composition.
Further, the cosolvent is alcohol ethers organic solvent.
Further, the levelling agent is polyether polyester azo polyether polyeste, dimethyl silicone polymer, alkyl-modified has
The mixture of one or more of organic siloxane and terminal groups modification organosilicon.
Further, the nertralizer is one or two the mixture in lactic acid and glacial acetic acid.
Further, the ethylene oxidic ester is in glycidyl acrylate and GMA
Kind or two kinds of mixture.
Preferably, the ethylene oxidic ester is the mixing of glycidyl acrylate and GMA
Thing, and both proportionings in mass ratio are 2-3：3-5.
Preferably, the metal oxide is zinc oxide, sodium oxide molybdena, yittrium oxide, iron oxide, rubidium oxide, manganese oxide, oxidation
One kind in cobalt, zirconium oxide, bismuth oxide, cerium oxide.
The beneficial effect of inventive thick film paste solvent-borne type electrophoretic paint that the present invention is provided is：Electrophoretic paint of the invention uses phenylpropyl alcohol waterproof
Emulsion and pure organic siliconresin, with reference to the solid additive and metal oxide that add so that the electrophoretic paint has strong thick film.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to
Limit the present invention.
Embodiment 1
A kind of inventive thick film paste solvent-borne type electrophoretic paint, is composed of the following raw materials by weight：20 parts of phenylpropyl alcohol water-proof emulsion, pure organosilicon
15 parts of resin, 20 parts of modified amine curing agent, 10 parts of crosslinking agent, 4 parts of deionized water, 15 parts of cosolvent, 3 parts of levelling agent, nertralizer 5
Part, 6 parts of metal oxide, 9 parts of solid additive, 6 parts of the first compound additive, 5 parts of the second compound additive.
Further, the modified amine curing agent is by mass ratio 1.0：1.0：Polyamine, the ethylene oxidic ester of 0.5 proportioning
Constituted with containing double bond compound；The crosslinking agent is by mass ratio 1：3：The 2 compound alcohol ethers for matching, isopropanol and silicone fluid group
Into；The solid additive is particle diameter 10-30 nanometers of silica flour of the molybdenum disulfide nano ball with particle diameter 6-9 microns according to quality
Than 1:The mixture of 2 compositions；First compound additive is by mass ratio 1：3：2：Acrylamide, the 2- acryloyls of 2 proportionings
Amido -2- methyl propane sulfonic acids, dimer (fatty acid) yl and zinc stearate composition；Second compound additive is by mass ratio 1.0：
0.3：1.2 MTMSs for matching, Hydroxypropyl methylcellulose and 2- cyanacrylates composition.
Further, the cosolvent is alcohol ethers organic solvent；The levelling agent is polyether polyester modified organic silicon oxygen
The mixture of alkane and dimethyl silicone polymer；The nertralizer is lactic acid；The ethylene oxidic ester is glycidyl acrylate
With the mixture of GMA, and both proportionings in mass ratio are 2：3；The metal oxide is oxidation
Zinc.
Embodiment 2
A kind of inventive thick film paste solvent-borne type electrophoretic paint, is composed of the following raw materials by weight：25 parts of phenylpropyl alcohol water-proof emulsion, pure organosilicon
20 parts of resin, 45 parts of modified amine curing agent, 20 parts of crosslinking agent, 7 parts of deionized water, 20 parts of cosolvent, 6 parts of levelling agent, nertralizer 9
Part, 11 parts of metal oxide, 13 parts of solid additive, 11 parts of the first compound additive, 10 parts of the second compound additive.
Further, the modified amine curing agent is by mass ratio 1.5：2.0：Polyamine, the ethylene oxidic ester of 1.0 proportionings
Constituted with containing double bond compound；The crosslinking agent is by mass ratio 2：5：The 4 compound alcohol ethers for matching, isopropanol and silicone fluid group
Into；The solid additive is particle diameter 10-30 nanometers of silica flour of the molybdenum disulfide nano ball with particle diameter 6-9 microns according to quality
Than 3:The mixture of 5 compositions；First compound additive is by mass ratio 2：5：4：Acrylamide, the 2- acryloyls of 2 proportionings
Amido -2- methyl propane sulfonic acids, dimer (fatty acid) yl and zinc stearate composition；Second compound additive is by mass ratio 1.5：
0.5：1.4 MTMSs for matching, Hydroxypropyl methylcellulose and 2- cyanacrylates composition.
Further, the cosolvent is alcohol ethers organic solvent；The levelling agent be alkyl-modified organosiloxane and
The mixture of terminal groups modification organosilicon；The nertralizer is glacial acetic acid；The ethylene oxidic ester be glycidyl acrylate and
The mixture of GMA, and both proportionings in mass ratio are 3：5；The metal oxide is oxidation
Yttrium.
Embodiment 3
A kind of inventive thick film paste solvent-borne type electrophoretic paint, is composed of the following raw materials by weight：23 parts of phenylpropyl alcohol water-proof emulsion, pure organosilicon
17 parts of resin, 35 parts of modified amine curing agent, 15 parts of crosslinking agent, 5 parts of deionized water, 17 parts of cosolvent, 5 parts of levelling agent, nertralizer 7
Part, metal oxide 6-11 parts, solid additive 9-13 parts, 9 parts of the first compound additive, 8 parts of the second compound additive.
Further, the modified amine curing agent is by mass ratio 1.2：1.5：Polyamine, the ethylene oxidic ester of 0.7 proportioning
Constituted with containing double bond compound；The crosslinking agent is by mass ratio 1.5：4.0：The 3.0 compound alcohol ethers for matching, isopropanol and silicon
Glue is constituted；The solid additive is pressed for particle diameter 10-30 nanometers of silica flour of the molybdenum disulfide nano ball with particle diameter 6-9 microns
According to mass ratio 2:The mixture of 3 compositions；First compound additive is by mass ratio 1.5：4.0：3.0：The propylene of 2.0 proportionings
Acid amides, 2- acrylamide-2-methylpro panesulfonic acids, dimer (fatty acid) yl and zinc stearate composition；Second compound additive by
In mass ratio 1.3：0.4：1.3 MTMSs for matching, Hydroxypropyl methylcellulose and 2- cyanacrylates composition.
Further, the cosolvent is alcohol ethers organic solvent；The levelling agent is polyether polyester modified organic silicon oxygen
The mixture of alkane, dimethyl silicone polymer, alkyl-modified organosiloxane and terminal groups modification organosilicon；The nertralizer is lactic acid
With the mixture of glacial acetic acid；The ethylene oxidic ester is the mixing of glycidyl acrylate and GMA
Thing, and both proportionings in mass ratio are 2.5：4.0；The metal oxide be iron oxide,.
Presently preferred embodiments of the present invention is the foregoing is only, is not intended to limit the invention, it is all in essence of the invention
Any modification, equivalent and improvement made within god and principle etc., should be included within the scope of the present invention.
Claims (7)
1. a kind of inventive thick film paste solvent-borne type electrophoretic paint, it is characterised in that be composed of the following raw materials by weight：Phenylpropyl alcohol water-proof emulsion 20-
25 parts, pure organic siliconresin 15-20 parts, modified amine curing agent 20-45 parts, crosslinking agent 10-20 parts, deionized water 4-7 parts, hydrotropy
Agent 15-20 parts, levelling agent 3-6 parts, nertralizer 5-9 parts, metal oxide 6-11 parts, solid additive 9-13 parts, first be combined
Additive 6-11 parts, second compound additive 5-10 parts；
The modified amine curing agent is by 1.0-1.5 in mass ratio：1.0-2.0：Polyamine, the ethylene oxidic ester of 0.5-1.0 proportionings
Constituted with containing double bond compound；
The crosslinking agent is by 1-2 in mass ratio：3-5：Compound alcohol ether, isopropanol and silicone fluid composition that 2-4 is matched；
The solid additive is particle diameter 10-30 nanometers of silica flour of the molybdenum disulfide nano ball with particle diameter 6-9 microns according to matter
Amount compares 1-3:The mixture of 2-5 compositions；
First compound additive is by 1-2 in mass ratio：3-5：2-4：Acrylamide, the 2- acrylamido -2- first of 2 proportionings
Base propane sulfonic acid, dimer (fatty acid) yl and zinc stearate composition；
Second compound additive is by 1.0-1.5 in mass ratio：0.3-0.5：The methyl trimethoxy epoxide silicon of 1.2-1.4 proportionings
Alkane, Hydroxypropyl methylcellulose and 2- cyanacrylates composition.
2. inventive thick film paste solvent-borne type electrophoretic paint according to claim 1, it is characterised in that the cosolvent is that alcohol ethers are organic
Solvent.
3. inventive thick film paste solvent-borne type electrophoretic paint according to claim 1, it is characterised in that the levelling agent changes for polyether polyester
One or more of property organosiloxane, dimethyl silicone polymer, alkyl-modified organosiloxane and terminal groups modification organosilicon
Mixture.
4. inventive thick film paste solvent-borne type electrophoretic paint according to claim 1, it is characterised in that the nertralizer is lactic acid and ice vinegar
One or two mixture in acid.
5. inventive thick film paste solvent-borne type electrophoretic paint according to claim 1, it is characterised in that the ethylene oxidic ester is acrylic acid
One or two mixture in ethylene oxidic ester and GMA.
6. inventive thick film paste solvent-borne type electrophoretic paint according to claim 5, it is characterised in that the ethylene oxidic ester is acrylic acid
The mixture of ethylene oxidic ester and GMA, and both proportionings in mass ratio are 2-3：3-5.
7. inventive thick film paste solvent-borne type electrophoretic paint according to claim 1, it is characterised in that the metal oxide is oxidation
One kind in zinc, sodium oxide molybdena, yittrium oxide, iron oxide, rubidium oxide, manganese oxide, cobalt oxide, zirconium oxide, bismuth oxide, cerium oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710221705.XA CN106883690A (en) | 2017-04-06 | 2017-04-06 | A kind of inventive thick film paste solvent-borne type electrophoretic paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710221705.XA CN106883690A (en) | 2017-04-06 | 2017-04-06 | A kind of inventive thick film paste solvent-borne type electrophoretic paint |
Publications (1)
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| CN106883690A true CN106883690A (en) | 2017-06-23 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710221705.XA Pending CN106883690A (en) | 2017-04-06 | 2017-04-06 | A kind of inventive thick film paste solvent-borne type electrophoretic paint |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021006220A1 (en) * | 2019-07-11 | 2021-01-14 | 日本ペイント・オートモーティブコーティングス株式会社 | Cationic electrodeposition coating composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1422910A (en) * | 2001-11-28 | 2003-06-11 | 日本涂料株式会社 | Electrophoretic coating composition |
| CN1651530A (en) * | 2004-12-28 | 2005-08-10 | 华南理工大学 | Fluorinated low surface energy cathode electrophoresis paint and its preparation method |
| CN103333595A (en) * | 2013-06-09 | 2013-10-02 | 广东科德化工实业有限公司 | Cathode electrophoresis paint with combined bottom surfaces and preparation method and application method thereof |
| CN104312246A (en) * | 2014-09-30 | 2015-01-28 | 苏州长盛机电有限公司 | Metallic cathode electrophoretic paint and preparation method thereof |
| CN105885661A (en) * | 2016-06-22 | 2016-08-24 | 广德瑞邦涂料有限公司 | Cathode electrophoretic paint |
| CN106318087A (en) * | 2016-08-19 | 2017-01-11 | 浩力森涂料（上海）有限公司 | Fluorine-silicon-modified anodic acrylic-acid electrophoretic coating and preparation method thereof |
-
2017
- 2017-04-06 CN CN201710221705.XA patent/CN106883690A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1422910A (en) * | 2001-11-28 | 2003-06-11 | 日本涂料株式会社 | Electrophoretic coating composition |
| CN1651530A (en) * | 2004-12-28 | 2005-08-10 | 华南理工大学 | Fluorinated low surface energy cathode electrophoresis paint and its preparation method |
| CN103333595A (en) * | 2013-06-09 | 2013-10-02 | 广东科德化工实业有限公司 | Cathode electrophoresis paint with combined bottom surfaces and preparation method and application method thereof |
| CN104312246A (en) * | 2014-09-30 | 2015-01-28 | 苏州长盛机电有限公司 | Metallic cathode electrophoretic paint and preparation method thereof |
| CN105885661A (en) * | 2016-06-22 | 2016-08-24 | 广德瑞邦涂料有限公司 | Cathode electrophoretic paint |
| CN106318087A (en) * | 2016-08-19 | 2017-01-11 | 浩力森涂料（上海）有限公司 | Fluorine-silicon-modified anodic acrylic-acid electrophoretic coating and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021006220A1 (en) * | 2019-07-11 | 2021-01-14 | 日本ペイント・オートモーティブコーティングス株式会社 | Cationic electrodeposition coating composition |
| JP2021014515A (en) * | 2019-07-11 | 2021-02-12 | 日本ペイント・オートモーティブコーティングス株式会社 | Cationic electrodeposition coating composition |
| EP3998316A4 (en) * | 2019-07-11 | 2023-07-12 | Nippon Paint Automotive Coatings Co., Ltd. | Cationic electrodeposition coating composition |
| JP7401214B2 (en) | 2019-07-11 | 2023-12-19 | 日本ペイント・オートモーティブコーティングス株式会社 | Cationic electrodeposition paint composition |
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Application publication date: 20170623 |