CN106883618B - Marine worker sea water resistance high intensity high resistance heat thermoplastic elastic composite material and preparation method and the application in waterproof flexible cable - Google Patents
Marine worker sea water resistance high intensity high resistance heat thermoplastic elastic composite material and preparation method and the application in waterproof flexible cable Download PDFInfo
- Publication number
- CN106883618B CN106883618B CN201710100857.4A CN201710100857A CN106883618B CN 106883618 B CN106883618 B CN 106883618B CN 201710100857 A CN201710100857 A CN 201710100857A CN 106883618 B CN106883618 B CN 106883618B
- Authority
- CN
- China
- Prior art keywords
- resistance
- sea water
- composite material
- bnns
- sebs
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/20—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances liquids, e.g. oils
- H01B3/22—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances liquids, e.g. oils hydrocarbons
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/448—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from other vinyl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Insulating Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of preparations of sea water resistance high intensity high resistance thermoplastic elastomer composite material of marine worker, and using the material as sheath material, are prepared for a kind of waterproof flexible cable.The invention belongs to technical field of new material preparation, by high-insulativity, corrosion resistance, barrier property and the lubricity of removing hexagonal boron nitride nanosheet, the high insulation of cooperation, inexpensive ultrafine mica powder are modified thermoplastic elastomer (TPE), improve its resistance to corrosion seawater and wearability, improves it in long-time seawater and impregnate the insulation resistance under environment.The waterproof flexible cable of marine worker sea water resistance high intensity high resistance heat thermoplastic elastic composite processing preparation has the performances such as good flexible resistance, water absorption resistance, splendid mechanical performance, sea water resistance aging, seawater corrosion resistance.
Description
Technical field
The present invention relates to the modifies Material Fields of thermoplastic elastomehc solid-state, more particularly to marine worker sea water resistance high intensity
High resistance heat thermoplastic elastic cable jacket material and preparation method thereof.
Background technique
For cable after being invaded by moisture, electrical property and mechanical performance all can rapid drawdown, especially naval vessel or underwater assembly
Use cable.Such as ship cable, it is frequently used for dry and moist alternate environment or long term submersion in water, or even immerse hot water or steaming
In vapour, electrical property, mechanical performance can accelerate to decline, and in use, leakage current is bigger than normal, electric appliance starting difficulty, seriously
When will lead to electric shock and hurt sb.'s feelings.
Currently used water-fast cable has a longitudinal water-blocking and two kinds of radial water-resisting: longitudinal water-blocking usually with water blocking yarn, block water
Powder or waterstop, these materials contain water, prevent moisture along the longitudinal further diffusion of cable；Radial water-resisting is main
It is realized by hot pressing, welding, cold-drawn protective metal shell, as submarine cable generally uses lead set, but such cable poor in flexibility,
Be not suitable for frequently mobile.In addition, there is a large amount of seawater in the use environment of seabed or ship cable, seawater itself is that have very
The electrolyte solution of strong corrosive has very strong wellability to traditional PVC class polar material sheath containing a large amount of salts, long
Time easily penetrates into inside cable after, causes insulation resistance decline, even corrodes interior metal conductor wire core.
Thermoplastic elastomer is a kind of new material, it is just gradually being applied in wire and cable industry.First, thermoplastic
Elastomer is more superior than hard rubber economy in terms of processing.The energy consumption of thermoplastic elastomer is processed than processing hard rubber
Much less.Due to the problems such as facing natural gas shortage, oil embargo, thus energy supply seems nervous, and then many producers are all
Thermoplastic elastomer is regarded as a kind of means for reducing energy consumption.Compared with continuous vulcanization rubber, thermoplastic elastomer is more superior
Be with short production cycle, color distortion multiplicity;Again in terms of waste material can reprocess, thermoplastic elastic physical efficiency plays machine dress
Standby bigger utilization rate.But thermoplastic elastomer (TPE) is also a kind of high molecular material, it is right especially for noncrystalline rubber phase
The obstructing capacity of hydrone is poor, and after being soaked in seawater for a long time, hydrone can gradually be spread inside macromolecule matrix, so as to cause
The problems such as high molecular material decreasing insulating.Chinese invention patent CN 104829919 discloses a kind of submarine cable PE
Protective cover material and preparation method thereof, seawater corrosion resistance and resistance to micro- life using the fillers such as modified hemp and magnesia raising PE
Object corrosion.But PE is soft not as good as thermoplastic elastomer (TPE) as cable jacket material.Chinese invention patent CNI05061881 is disclosed
A kind of wisdom energy seawater corrosion resistant cable sheath rubber and preparation method thereof, it is modified using high quality thin graphene microplate
Second fourth elastomer improves its resistance to corrosion seawater, but graphene microchip is high conductive material, is influenced on the insulation performance of elastomer
It is very big.Chinese invention patent CNI04059321 discloses a kind of weather resistance environmental protection flame retardant flexible cable polymer material and its system
Preparation Method cooperates other halogen-free flame retardants using the fire retardant containing halogen, improves the flame retardant property of flexible cable, but its is resistance to
Seawater and insulation performance are still to be improved.
Summary of the invention
The present invention is directed to problem mentioned above, provides a kind of marine worker sea water resistance high intensity high resistance heat thermoplastic elastic
Composite material, the material can be used for the sheath of cable.
To solve the above-mentioned problems, the technical scheme is that
A kind of marine worker sea water resistance high intensity high resistance thermoplastic elastomer composite material, parts by weight composition are as follows: polyphenyl
70 ~ 110 parts of 100 parts of ethylene analog thermoplastic elastomer SEBS, polypropylene PP, 100 ~ 120 parts of operation oil, ultrafine mica powder 5 ~
15 parts, 1 ~ 5 part of hexagonal boron nitride nanosheet (BNNS), 0.5 ~ 0.7 part of antioxidant, 0.05 ~ 0.15 part of titante coupling agent,
0.05 ~ 0.25 part of silane coupling agent.
The ultrafine mica powder is one or more of phlogopite, muscovite and sericite, and particle size range is 300 ~ 800
Nanometer.
The removing hexagonal boron nitride nanosheet, particle size range are 100 ~ 300 nanometers, 8 ~ 15 nanometers of thickness.
The marine worker sea water resistance high intensity high resistance thermoplastic elastomer composite material, it is multiple using BNNS and ultrafine mica powder
With filled modified thermoplastic elastomer, using corrosion-resistant, high insulation, barrier property and the lubricity of BNNS, cooperate high insulation, it is low at
This ultrafine mica powder, under lower hexagonal boron nitride loading (1 ~ 5 part), improve thermoplastic elastomer (TPE) seawater corrosion resistance,
Wearability and long-time seawater impregnate the insulation resistance under environment.
Its preparation process is as follows:
(1) BNNS is added in operation oil, silane coupling agent then is added as dispersion by the 4% ~ 7% of BNNS weight
Agent is used ultrasonic disperser ultrasonic disperse 8 ~ 12 minutes after mixing.
(2) operation oil, the half of antioxidant ratio and the SEBS by scattered containing BNNS are proportionally added into high speed
Mixed in mixing machine it is oil-filled, mixing 8 ~ after ten minutes, place 24 ~ 36 hours, while SEBS is sufficiently swollen, keep BNNS uniform
It is dispersed in SEBS powder surface, is then used mixer mixing 10 ~ 15 minutes, last extruding pelletization is spare.
(3) half of PP, ultrafine mica powder, titanate coupling agent, antioxidant ratio is proportionally added into mixed at high speed
It in machine, mixes 8 ~ 12 minutes, is used mixer mixing 10 ~ 15 minutes after taking-up, last extruding pelletization is spare.
(4) above-mentioned (2) and (3) standby material are added in double screw extruder and carry out melt blending, be then granulated and obtain
Marine worker sea water resistance high intensity high resistance thermoplastic elastomer composite material pellet.
The present invention utilizes the nano-material modified SEBS/PP co-blending elastic body of two-dimensional layer, improves SEBS/PP co-blending elastic body
Resistance to corrosion seawater, wearability and electrical insulation capability, to widen TPE material answering in terms of marine field cable cover(ing)
With solving current Plastic protective cover material is really up to the mark, multiple folding and unfolding cracking, and rubber sheath power consumption of polymer processing is big, low efficiency, type are few etc.
Industry bottleneck problem is specifically as follows:
1) high molecular material (the especially amorphous area of amorphism macromolecule and crystalline polymer) free volume is deposited
Water suction is easy afterwards in water causing to impregnate for a long time, is declined so as to cause jacket insulation and is even corroded inner conductor.This item
Mesh can use the excellent barrier property of BNNS, corrosion resistance and mechanics enhancing characteristic using BNNS filling SEBS, improve SEBS phase
Sea water resistance energy and mechanical strength.
2) TPE in general wearability be not so good as vulcanized rubber, for roving cable, sheath it is resistance to
Mill property is also most important.This project uses the mica filled TPE with high insulating property, and TPE sheath not only can be improved and inhaling
Insulation performance after water can also improve the wearability of sheath, so as to further increase the life and reliability of cable.
3) BNNS/SEBS nanocomposite and its dispersing method: SEBS and PP usually requires to fill industrial white before being blended
The operation oil such as oil improves the processability of SEBS, and first BNNS is dispersed in operation oil using the Oil feeding process of SEBS, is then carried out
Oil-extended process can not only be such that BNNS disperses in SEBS more uniform, but also BNNS can be made to be filled in the greatest extent
SEBS phase improves the problem that SEBS phase is poor relative to PP phase sea water resistance, intensity is low, so as to be added using less BNNS
Amount improves the sea water resistance and mechanical strength of SEBS/PP co-blending elastic body.
4) different nanofillers are first carried out mixing respectively with SEBS and PP respectively and are blended in advance by this patent, then again by this
Two kinds of well pre-mixed materials are granulated, the secondary blending of twin-screw extrusion.The technique not only may be implemented different nanometers and fill out
Material difference in different phases is dispersed, and requires reduction, powder to disperse in the base more evenly twin screw device.In addition,
The differences in viscosity that two-phase can be adjusted by the additional amount of nano-powder in mixing technology for premixing, makes two-phase in secondary spiral shell
Melt viscosity is closer in bar blending, it is easier to form inierpeneirating network structure, improve the mechanical performance of nanocomposite.
Specific embodiment
Below in conjunction with specific embodiment, the present invention will be described in detail, herein illustrative examples and explanation of the invention
For explaining the present invention, but it is not as a limitation of the invention.
Example 1 is embodied:
100 parts of polystyrene-type thermoplastic elastomers SEBS, 70 parts of polypropylene PP, 46#120 parts of technical white oil, 300
5 parts of nanogold mica powder, 5 parts of hexagonal boron nitride nanosheet (BNNS), 0.5 part of antioxidant 1010, titante coupling agent three
TTS0.05 parts of isostearic acid isopropyl titanate, 0.25 part of Silane coupling agent KH550.Specific preparation process is as follows:
(1) BNNS is added in operation oil, Silane coupling agent KH550 is then added as dispersing agent, with super after mixing
Sound wave disperser ultrasonic disperse 12 minutes.
(2) operation oil, 0.25 part of antioxidant 1010 and the SEBS by scattered containing BNNS are added to high-speed mixer
Middle mixing is oil-filled, mixes 10 minutes, takes out after placing 36 hours, mixer mixing 15 minutes, then extruding pelletization was spare.
(3) PP, 300 nanogold mica powders, TTS, 0.25 part of antioxidant 1010 are proportionally added into high-speed mixer,
Mixing 10 minutes is used mixer mixing 15 minutes after taking-up, and last extruding pelletization is spare.
(4) above-mentioned (2), (3) standby material are added in double screw extruder and carry out melt blending, be then granulated and obtain sea
Work sea water resistance high intensity high resistance thermoplastic elastomer composite material pellet.
(5) using the marine worker sea water resistance high intensity high resistance thermoplastic elastomer composite material pellet of above-mentioned (4) as cable
Insulation and restrictive coating, manufacture waterproof flexible cable.
Example 2 is embodied:
100 parts of polystyrene-type thermoplastic elastomers SEBS, 90 parts of polypropylene PP, 32#120 parts of technical white oil, 500
10 parts of sericite in powder of nanometer, 3 parts of hexagonal boron nitride nanosheet (BNNS), 0.6 part of irgasfos 168, titante coupling agent KR-
0.1 part of 138s, 0.15 part of Silane coupling agent KH550.Specific preparation process is as follows:
(1) BNNS is added in operation oil, Silane coupling agent KH550 is then added as dispersing agent, with super after mixing
Sound wave disperser ultrasonic disperse 10 minutes.
(2) it is mixed to be added to high speed by the operation oil by scattered containing BNNS, 0.3 part of irgasfos 168, antioxidant and SEBS
Mixed in conjunction machine it is oil-filled, mix 9 minutes, place 30 hours, mixer mixing 12 minutes after taking-up, then extruding pelletization is spare.
(3) PP, 500 nanometers of sericites in powder, KR-138s, 0.3 part of irgasfos 168 are proportionally added into high-speed mixer
In, it mixes 8 minutes, is used mixer mixing 12 minutes after taking-up, last extruding pelletization is spare.
(4) above-mentioned (2) and (3) standby material are added in double screw extruder and carry out melt blending, be then granulated and obtain
Marine worker sea water resistance high intensity high resistance thermoplastic elastomer composite material pellet.
(5) using the marine worker sea water resistance high intensity high resistance thermoplastic elastomer composite material pellet of above-mentioned (4) as cable
Insulation and restrictive coating, manufacture waterproof flexible cable.
Example 3 is embodied:
100 parts of polystyrene-type thermoplastic elastomers SEBS, 110 parts of polypropylene PP, 46#120 parts of technical white oil, 800
15 parts of white mica powder of nanometer, 1 part of hexagonal boron nitride nanosheet (BNNS), 0.7 part of antioxidant 1010, titante coupling agent
TTS0.15 parts, 0.05 part of Silane coupling agent KH550.Specific preparation process is as follows:
(1) BNNS is added in operation oil, Silane coupling agent KH550 is then added as dispersing agent, with super after mixing
Sound wave disperser ultrasonic disperse 8 minutes.
(2) operation oil, 0.35 part of antioxidant 1010 and the SEBS by scattered containing BNNS are added to high-speed mixer
Middle mixing is oil-filled, after mixing 8 minutes, places 24 hours, mixer mixing 10 minutes after taking-up, then extruding pelletization is spare.
(3) PP, 800 nanometers of white mica powders, TTS, 0.35 part of antioxidant 1010 are proportionally added into high-speed mixer,
Mixing 8 minutes is used mixer mixing 10 minutes after taking-up, and last extruding pelletization is spare.
(4) above-mentioned (2) and (3) standby material are added in double screw extruder and carry out melt blending, be then granulated and obtain
Marine worker sea water resistance high intensity high resistance thermoplastic elastomer composite material pellet.
(5) using the marine worker sea water resistance high intensity high resistance thermoplastic elastomer composite material pellet of above-mentioned (4) as cable
Insulation and restrictive coating, manufacture waterproof flexible cable.
Compare embodiment:
100 parts of polystyrene-type thermoplastic elastomers SEBS, 70 parts of polypropylene PP, 120 parts of technical white oil 46#, resist
1,010 0.5 parts of oxygen agent.
(1) SEBS and technical white oil 46# are put into high-speed mixer and mix oil-filled, mixing 10 minutes, placement 36 is small
When it is spare.
(2) SEBS, PP and antioxidant after will be oil-filled be put into high-speed mixer, are mixed 10 minutes, are added after taking-up
Melt blending is carried out into double screw extruder progress, is then granulated and obtains common SEBS/PP thermoplastic elastomer (TPE).
Using the marine worker sea water resistance high intensity high resistance thermoplastic elastomer composite material pellet of above-mentioned (2) as the exhausted of cable
Edge and restrictive coating, manufacture waterproof flexible cable.
After tested, embodiment 1-3 and comparison embodiment made from protective cover material performance it is as shown in the table:
。
Claims (3)
1. a kind of marine worker preparation method of sea water resistance high intensity high resistance thermoplastic elastomer composite material, which is characterized in that
It include following material, parts by weight are as follows:
100 parts of polystyrene-type thermoplastic elastomers SEBS；
70 ~ 110 parts of polypropylene PP；
100 ~ 120 parts of operation oil；
5 ~ 15 parts of mica powder；
1 ~ 5 part of hexagonal boron nitride nanosheet (BNNS)；
0.5 ~ 0.7 part of antioxidant；
Compatilizer is 0.05 ~ 0.15 part of titante coupling agent；
Dispersing agent is 0.05 ~ 0.25 part of silane coupling agent；
It follows the steps below:
1) BNNS is added in operation oil, silane coupling agent then is added as dispersing agent, mixing by the 4% ~ 7% of BNNS weight
It uses ultrasonic disperser ultrasonic disperse 8 ~ 12 minutes afterwards；
2) operation oil, the half of antioxidant and the SEBS by scattered containing BNNS, which are proportionally added into high-speed mixer, mixes
Close it is oil-filled, mixing 8 ~ after ten minutes, place 24 ~ 36 hours, while SEBS is sufficiently swollen, BNNS is made to be dispersed in SEBS
Then powder surface is used mixer mixing 10 ~ 15 minutes, last extruding pelletization is spare；
3) by PP, ultrafine mica powder, titanate coupling agent, antioxidant the other half be proportionally added into high-speed mixer, mix
It closes 8 ~ 12 minutes, is used mixer mixing 10 ~ 15 minutes after taking-up, last extruding pelletization is spare；
4) above-mentioned 2) be added in double screw extruder with 3) standby material is subjected to melt blending, is then granulated and obtains composite material
Pellet.
2. a kind of marine worker according to claim 1 system of sea water resistance high intensity high resistance thermoplastic elastomer composite material
Preparation Method, which is characterized in that the mica powder is one or more of phlogopite, muscovite and sericite, and particle size range is
300 ~ 800 nanometers.
3. a kind of marine worker according to claim 1 system of sea water resistance high intensity high resistance thermoplastic elastomer composite material
Preparation Method, which is characterized in that the removing hexagonal boron nitride nanosheet, particle size range are 100 ~ 300 nanometers, and thickness 8 ~ 15 is received
Rice.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710100857.4A CN106883618B (en) | 2017-02-23 | 2017-02-23 | Marine worker sea water resistance high intensity high resistance heat thermoplastic elastic composite material and preparation method and the application in waterproof flexible cable |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710100857.4A CN106883618B (en) | 2017-02-23 | 2017-02-23 | Marine worker sea water resistance high intensity high resistance heat thermoplastic elastic composite material and preparation method and the application in waterproof flexible cable |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106883618A CN106883618A (en) | 2017-06-23 |
| CN106883618B true CN106883618B (en) | 2019-03-12 |
Family
ID=59179037
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710100857.4A Active CN106883618B (en) | 2017-02-23 | 2017-02-23 | Marine worker sea water resistance high intensity high resistance heat thermoplastic elastic composite material and preparation method and the application in waterproof flexible cable |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106883618B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108102221A (en) * | 2017-12-14 | 2018-06-01 | 义乌倍肯新材料科技有限公司 | A kind of inorganic nano antiseptic thermoplastic elastomer (TPE) and preparation method thereof |
| CN108666014A (en) * | 2018-06-20 | 2018-10-16 | 沈阳天荣电缆材料有限公司 | A kind of sea water resistance semiconductive sealing binding strap and preparation method thereof |
| CN110885653B (en) * | 2019-11-18 | 2022-07-05 | 北京航天控制仪器研究所 | Low-temperature fast-curing epoxy insulating adhesive and preparation method and application thereof |
| CN111995876A (en) * | 2020-07-09 | 2020-11-27 | 上海泛优包装科技有限公司 | Plastic spring material for all-plastic recyclable environment-friendly spray head |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201508716U (en) * | 2009-08-26 | 2010-06-16 | 安徽慧艺线缆集团有限公司 | Light marine power cable |
| CN101838436A (en) * | 2010-06-17 | 2010-09-22 | 深圳职业技术学院 | SEBS thermoplastic elastomer cable insulation material and preparation method thereof |
| CN201838349U (en) * | 2010-09-09 | 2011-05-18 | 江苏晨光电缆有限公司 | Deepwater detection cable for offshore oil exploration |
| CN103435955A (en) * | 2013-08-13 | 2013-12-11 | 东莞市安拓普塑胶聚合物科技有限公司 | Halogen-free flame retardant thermoplastic elastomer composite material and preparation method thereof |
| CN105579511A (en) * | 2013-06-19 | 2016-05-11 | 3M创新有限公司 | Component part produced from a polymer/boron nitride compound, polymer/boron nitride compound for producing such a component part and use thereof |
| CN105859986A (en) * | 2016-05-31 | 2016-08-17 | 刘雷 | Insulating water-resistant cable material for computer and preparation method of material |
| CN106432923A (en) * | 2016-09-22 | 2017-02-22 | 佛山市飞时达新材料科技有限公司 | Seawater-resistant EPDM cable material and manufacturing method thereof |
-
2017
- 2017-02-23 CN CN201710100857.4A patent/CN106883618B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201508716U (en) * | 2009-08-26 | 2010-06-16 | 安徽慧艺线缆集团有限公司 | Light marine power cable |
| CN101838436A (en) * | 2010-06-17 | 2010-09-22 | 深圳职业技术学院 | SEBS thermoplastic elastomer cable insulation material and preparation method thereof |
| CN201838349U (en) * | 2010-09-09 | 2011-05-18 | 江苏晨光电缆有限公司 | Deepwater detection cable for offshore oil exploration |
| CN105579511A (en) * | 2013-06-19 | 2016-05-11 | 3M创新有限公司 | Component part produced from a polymer/boron nitride compound, polymer/boron nitride compound for producing such a component part and use thereof |
| CN103435955A (en) * | 2013-08-13 | 2013-12-11 | 东莞市安拓普塑胶聚合物科技有限公司 | Halogen-free flame retardant thermoplastic elastomer composite material and preparation method thereof |
| CN105859986A (en) * | 2016-05-31 | 2016-08-17 | 刘雷 | Insulating water-resistant cable material for computer and preparation method of material |
| CN106432923A (en) * | 2016-09-22 | 2017-02-22 | 佛山市飞时达新材料科技有限公司 | Seawater-resistant EPDM cable material and manufacturing method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 氮化硼纳米片制备方法研究进展;赵迪 等;《功能材料》;20161231;第47卷(第12期);第12071页第2-3段 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106883618A (en) | 2017-06-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106883618B (en) | Marine worker sea water resistance high intensity high resistance heat thermoplastic elastic composite material and preparation method and the application in waterproof flexible cable | |
| JP6379776B2 (en) | Non-halogen flame retardant thermoplastic elastomer composition, method for producing the same, electric wire and cable | |
| EP2630187B1 (en) | A semiconductive polyolefin composition which contains epoxy-groups | |
| CN105801964B (en) | Security protection cable elastomer sheathing material and preparation method thereof | |
| WO2012052077A1 (en) | A cable comprising a layer which is formed of a composition containing epoxy-groups | |
| KR101696122B1 (en) | A conductive jacket | |
| CN105504463A (en) | Process for preparing modified chlorinated polyethylene cable material | |
| CN108690272A (en) | A kind of water-fast corrosion proof cable material of marine settings pressure resistance | |
| JP5056601B2 (en) | Non-halogen flame retardant thermoplastic elastomer resin composition, method for producing the same, and electric wire / cable using the same | |
| CN103224669A (en) | Salt corrosion resistance twisted cable insulation rubber used for ocean wind power and preparation method thereof | |
| CN106463206B (en) | Vehicle-mounted electric wire and cable | |
| JP6418138B2 (en) | Flame retardant resin composition and flame retardant cable | |
| CN108026339A (en) | Fire retardant resin composition, metal cable, Connectorized fiber optic cabling and products formed using the fire retardant resin composition | |
| CN104945727A (en) | Outdoor overhead ageing-resistant insulating polyolefin cable material and preparation method thereof | |
| CN108384117A (en) | A kind of antistatic polypropylene composition | |
| JP2005133036A (en) | Non-halogen flame retardant thermoplastic resin composition and electric wire and cable using the same | |
| CN112574496A (en) | Low-smoke halogen-free flame-retardant cable material and preparation method and application thereof | |
| CN101831019A (en) | Preparation method of rubber type chlorinated polyethylene with high electrical property | |
| CN112080090A (en) | Preparation method of cable sleeve | |
| CN105778206B (en) | A kind of softness PE cable protective cover material and preparation method thereof | |
| CN108154959A (en) | A kind of novel high-pressure transmission of electricity power cable | |
| CN103540043A (en) | Low temperature resistant high elasticity chlorinated polyethylene power line jacket material as well as preparation method thereof | |
| WO2019102920A1 (en) | Flame retardant resin composition, insulated wire using this, cable, optical fiber cable, and molded article | |
| JP2004010864A (en) | Tracking-resistant resin composition crosslinkable with water and power cable having insulating coated layer formed out of the composition | |
| CN108997664A (en) | sheath material and cable |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20200108 Address after: 225652, Beijiao, Jiangsu, Gaoyou province Yangzhou Ling Tong Industrial Park Co-patentee after: Beijing mechanical and electrical engineering general design department Patentee after: Yaguang Cable Co., Ltd., Yangzhou Address before: 225652, Beijiao, Jiangsu, Gaoyou province Yangzhou Ling Tong Industrial Park Patentee before: Yaguang Cable Co., Ltd., Yangzhou |
|
| TR01 | Transfer of patent right |