CN106876511A - A kind of solar cell backboard - Google Patents

A kind of solar cell backboard Download PDF

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Publication number
CN106876511A
CN106876511A CN201710096012.2A CN201710096012A CN106876511A CN 106876511 A CN106876511 A CN 106876511A CN 201710096012 A CN201710096012 A CN 201710096012A CN 106876511 A CN106876511 A CN 106876511A
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CN
China
Prior art keywords
solar cell
layer
cell backboard
adhesive
curing agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710096012.2A
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Chinese (zh)
Inventor
刘源
李新军
夏修旸
吴小平
陈洪野
宇野敬
宇野敬一
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cybrid Technologies Inc
Original Assignee
Cybrid Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cybrid Technologies Inc filed Critical Cybrid Technologies Inc
Priority to CN201710096012.2A priority Critical patent/CN106876511A/en
Publication of CN106876511A publication Critical patent/CN106876511A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • H01L31/049Protective back sheets
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/054Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means
    • H01L31/056Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means the light-reflecting means being of the back surface reflector [BSR] type
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/52PV systems with concentrators

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  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of solar cell backboard, including PET matrix layer, weather-proof film layer, adhesive layer, tack coat, the PET matrix layer side is the weather-proof film layer with long-term weatherability, bonded by adhesive layer between the PET matrix layer, weather-proof film layer, the PET matrix layer opposite side is the tack coat for bonding packaging adhesive film.Ultrahigh-reflectivity solar cell backboard provided by the present invention can have good cohesive force with EVA, the advantages of long-term anti-ageing performance is good, while the reflectivity in 400 1100nm wave-length coverages is more than 97%, can significantly improve component power.

Description

A kind of solar cell backboard
Technical field
The present invention relates to technical field of solar batteries, more particularly to a kind of solar cell backboard.
Background technology
Solar cell is the device that electric energy is directly converted to using solar energy, the wavelength model of the sunshine that it is mainly utilized Enclose be in 400-1100nm, but general backboard reflectivity is relatively low, 70% or so, this is caused the reflectivity of 400-1100nm The sunshine part for reaching the day sun energy battery component back side is reached outside component through solar energy backboard, causes solar energy to damage Lose, so as to reduce the light energy use efficiency of battery component.Having experimental data proves, for the battery component of 250W, backboard is anti- Penetrating rate often increases by 10%, and electric power generation cell can improve 0.3%.Existing solar energy backboard simultaneously, reflectivity is relatively low, uses Generated heat in journey excessive, cause flavescence to become fragile, influence the service life of solar cell module.
The content of the invention
It is contemplated that at least solving one of technical problem in correlation technique to a certain extent.Therefore, of the invention One purpose is to propose a kind of solar components solar cell backboard with high-weatherability, ultra-high reflectivity.
A kind of solar cell backboard according to embodiments of the present invention, it has four-layer structure, including PET matrix layer, in Described PET matrix layer side is the weather-proof film layer with long-term weatherability, and weather-proof with described positioned at PET matrix layer Property layer adhesive layer bond, in described PET matrix layer opposite side be fluorine-containing coat as solar energy backboard and packaging plastic The tack coat of film.
Preferably, the PET matrix layer is high reflection expansion type PET film, and its thickness is 0.05-1mm.
Preferably, the weather-proof film layer is in weatherability polyethylene terephthalate or polyvinylidene difluoride film One kind, its thickness is 0.02-0.05mm.
Preferably, the adhesive that the adhesive layer is used is adhesive for polyurethane, acrylic resin adhesive, asphalt mixtures modified by epoxy resin One or more mixtures in fat adhesive, polyester adhesive, its thickness is 0.005-0.030mm.
Preferably, the tack coat is fluorine-containing coat, including organic resin, curing agent and inorganic filler, its thickness It is 0.001-0.030mm.
Preferably, the organic resin be tetrafluoroethylene-Ethylene base ester copolymer, tetrafluoroethylene-Ethylene base ether copolymer, One or more in CTFE-vinyl ester copolymer, CTFE-vinyl ether co-polymer.
Preferably, the curing agent is isocyanates system curing agent, imidazole curing agent, hydrazides curing agent, amine curing agent With the one kind in cyanamid dimerization class curing agent.
Preferably, the inorganic filler is titanium dioxide, mica powder, talcum powder, barium sulfate, calcium carbonate, aluminium hydroxide, Buddha's warrior attendant One or more in stone flour.
Beneficial effects of the present invention:Ultrahigh-reflectivity solar cell backboard provided by the present invention can have well with EVA Cohesive force, it is good with thermal diffusivity, the advantages of long-term anti-ageing performance is good, while in the reflection of 400-1100nm wave-length coverages Rate is more than 97%, can significantly improve component power.
Brief description of the drawings
Accompanying drawing is used for providing a further understanding of the present invention, and constitutes a part for specification, with reality of the invention Applying example is used to explain the present invention together, is not construed as limiting the invention.In the accompanying drawings:
Fig. 1 is a kind of structural representation of solar cell backboard proposed by the present invention;
Fig. 2 is the structural representation that a kind of solar cell backboard proposed by the present invention is applied in solar cell module Figure.
In figure:1PET base layers, 2 weather-proof film layers, 3 adhesive layers, 4 tack coats, 5 ultrahigh-reflectivity solar battery backs Plate, 6 the oneth EVA encapsulated layers, 7 cell pieces, 8 the 2nd EVA encapsulated layers, 9 glassy layers.
Specific embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete Site preparation is described, it is clear that described embodiment is only a part of embodiment of the invention, rather than whole embodiments.
The example of the embodiment is shown in the drawings, wherein same or similar label represents identical or class from start to finish As element or the element with same or like function.Embodiment below with reference to Description of Drawings is exemplary, purport For explaining the present invention, and it is not considered as limiting the invention.
In the description of the invention, it is to be understood that term " " center ", " longitudinal direction ", " transverse direction ", " length ", " width ", " thickness ", " on ", D score, "front", "rear", "left", "right", " vertical ", " level ", " top ", " bottom " " interior ", " outward ", " up time The orientation or position relationship of the instruction such as pin ", " counterclockwise ", " axial direction ", " radial direction ", " circumference " be based on orientation shown in the drawings or Position relationship, is for only for ease of the description present invention and simplifies description, must rather than the device or element for indicating or imply meaning With specific orientation, with specific azimuth configuration and operation, therefore must be not considered as limiting the invention.
Additionally, term " first ", " second " are only used for describing purpose, and it is not intended that indicating or implying relative importance Or the implicit quantity for indicating indicated technical characteristic.Thus, define " first ", the feature of " second " can express or Implicitly include one or more this feature.In the description of the invention, " multiple " is meant that two or more, Unless otherwise expressly limited specifically.
In the present invention, unless otherwise clearly defined and limited, term " installation ", " connected ", " connection ", " fixation " etc. Term should be interpreted broadly, for example, it may be fixedly connected, or be detachably connected, or integrally;Can be that machinery connects Connect, or electrically connect;Can be joined directly together, it is also possible to be indirectly connected to by intermediary, can be in two elements The connection in portion or two interaction relationships of element.For the ordinary skill in the art, can be according to specific feelings Condition understands above-mentioned term concrete meaning in the present invention.
Embodiment one:
Reference picture 1, a kind of solar cell backboard, including PET matrix layer 1, weather-proof film layer 2, transparent adhesive layer 3 And the tack coat 4 with packaging adhesive film cementation;
The above-mentioned PET matrix layer 1 that the present invention is given is high reflection expansion type pet film, thickness 50~500 microns, specific thickness is 250 microns;Weather-proof film layer 2 is weatherability polyethylene terephthalate or gathers inclined fluorine One kind in vinyl film, thickness is 20~50 microns, and specific thickness is 22.5 microns;Transparent adhesive 3 is transparent polyester type Adhesive, its thickness are 5-30 microns, and specific thickness is 10 microns;Included with the tack coat 4 of packaging adhesive film cementation organic Resin, curing agent, inorganic condiment, its thickness are 1-30 microns, and preferred thickness is 5 microns.Wherein organic resin is trifluoro chloroethene Alkene-vinyl ester copolymer, curing agent is isocyanate curing agent, and inorganic filler is titanium dioxide.
Application of the above-mentioned ultrahigh-reflectivity solar cell backboard 5 in solar cell module is as shown in Figure 2.Ultrahigh-reflectivity Tack coat 4 in solar cell backboard 5 is bonded with an EVA encapsulated layers 6, and cell piece 7 is encapsulated installed in first, second EVA Between layer 6 and 8, the second encapsulated layer 8 bonds the whole battery installation of completion with outermost glassy layer 9.
In the present embodiment, ultrahigh-reflectivity solar cell backboard has the reflectivity of superelevation, in the reflection of 400-1100nm Rate, for 250W battery components, lifts more than 1.2W, while this reality 99.5% than common 80% reflectivity backboard generated output Applying a dorsulum has good weatherability (UV300KWh, △ b=1.9).
Embodiment two:
Reference picture 1, a kind of solar cell backboard, including PET matrix layer 1, weather-proof film layer 2, transparent adhesive layer 3 and With the tack coat 4 of packaging adhesive film cementation;
The above-mentioned PET matrix layer 1 that the present invention is given is high reflection expansion type pet film, thickness 50~1000 microns, specific thickness is 150 microns;Weather-proof film layer 2 is weatherability polyethylene terephthalate or poly- inclined One kind in fluoroethylene film, thickness is 20~50 microns, and specific thickness is 22.5 microns;Transparent adhesive 3 is transparent poly- Ester type adhesive, its thickness are 5-30 microns, and specific thickness is 10 microns;Tack coat 4 with packaging adhesive film cementation is included Organic resin, curing agent, inorganic condiment, its thickness are 1-30 microns, and preferred thickness is 5 microns.Wherein organic resin is trifluoro Vinyl chloride-vinyl ester copolymer, curing agent is isocyanate curing agent, and inorganic filler is barium sulfate.
In the present embodiment, ultrahigh-reflectivity solar cell backboard has the reflectivity of superelevation, in the reflection of 400-1100nm Rate, for 250W battery components, lifts more than 1.1W, while this reality 97.5% than common 80% reflectivity backboard generated output Applying a dorsulum has good weatherability (UV300KWh, △ b=2.3).
Embodiment three:
Reference picture 1, a kind of solar cell backboard, including PET matrix layer 1, weather-proof film layer 2, transparent adhesive layer 3 and With the tack coat 4 of packaging adhesive film cementation;
The above-mentioned PET matrix layer 1 that the present invention is given is high reflection expansion type pet film, thickness 50~1000 microns, specific thickness is 125 microns;Weather-proof film layer 2 is weatherability polyethylene terephthalate or poly- inclined One kind in fluoroethylene film, thickness is 20~50 microns, and specific thickness is 38 microns;Transparent adhesive 3 is transparent polyester Type adhesive, its thickness are 5-30 microns, and specific thickness is 10 microns;Tack coat 4 with packaging adhesive film cementation includes Machine resin, curing agent, inorganic condiment, its thickness are 1-30 microns, and preferred thickness is 5 microns.Wherein organic resin is trifluoro chlorine Ethylene-vinyl ester copolymer and tetrafluoroethylene-Ethylene base ester copolymer mixture, curing agent is isocyanate curing agent, nothing Machine filler is titanium dioxide and barium sulfate.
In the present embodiment, solar cell backboard has the reflectivity of superelevation, exists in the reflectivity of 400-1100nm 97.1%, for 250W battery components, more than 1.1W is lifted than common 80% reflectivity backboard generated output, while the present embodiment Dorsulum has good weatherability (UV300KWh, △ b=2.1).
The sample according to obtained in embodiment experiment has following other typical performances:
Product of the present invention has the reflectivity and good ageing-resistant performance of superelevation, both ensure that the service life of component, Significant role is made in lifting more to component power.
In the present invention, unless otherwise clearly defined and limited, fisrt feature second feature " on " or D score can be with It is the first and second feature directly contacts, or the first and second features are by intermediary mediate contact.And, fisrt feature exists Second feature " on ", " top " and " above " but fisrt feature are directly over second feature or oblique upper, or be merely representative of Fisrt feature level height is higher than second feature.Fisrt feature second feature " under ", " lower section " and " below " can be One feature is immediately below second feature or obliquely downward, or is merely representative of fisrt feature level height less than second feature.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show The description of example " or " some examples " etc. means to combine specific features, structure, material or spy that the embodiment or example are described Point is contained at least one embodiment of the invention or example.In this manual, to the schematic representation of above-mentioned term not Necessarily refer to identical embodiment or example.And, the specific features of description, structure, material or feature can be any One or more embodiments or example in combine in an appropriate manner.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, Any one skilled in the art the invention discloses technical scope in, technology according to the present invention scheme and its Inventive concept is subject to equivalent or change, should all be included within the scope of the present invention.

Claims (8)

1. a kind of solar cell backboard, it is characterised in that:Including PET matrix layer, weather-proof film layer, adhesive layer, tack coat, The PET matrix layer side is the weather-proof film layer with long-term weatherability, is led between the PET matrix layer, weather-proof film layer Adhesive layer bonding is crossed, the PET matrix layer opposite side is the tack coat for bonding packaging adhesive film.
2. a kind of solar cell backboard according to claim 1, it is characterised in that:The PET matrix layer is high reflection Expansion type PET film, its thickness is 0.05-1mm.
3. a kind of solar cell backboard according to claim 1, it is characterised in that:The weather-proof film layer is weatherability One kind in polyethylene terephthalate or polyvinylidene difluoride film, its thickness is 0.02-0.05mm.
4. a kind of solar cell backboard according to claim 1, it is characterised in that:The gluing that the adhesive layer is used Agent is one or more mixing in adhesive for polyurethane, acrylic resin adhesive, epoxy resin adhesive, polyester adhesive Thing, its thickness is 0.005-0.030mm.
5. a kind of solar cell backboard according to claim 1, it is characterised in that:The tack coat is fluorine-containing coating Layer, including organic resin, curing agent and inorganic filler, its thickness are 0.001-0.030mm.
6. a kind of solar cell backboard according to claim 5, it is characterised in that:The organic resin is tetrafluoro second Alkene-vinyl ester copolymer, tetrafluoroethylene-Ethylene base ether copolymer, CTFE-vinyl ester copolymer, trifluoro chloroethene One or more in alkene-vinyl ether co-polymer.
7. a kind of solar cell backboard according to claim 5, it is characterised in that:The curing agent is isocyanates system One kind in curing agent, imidazole curing agent, hydrazides curing agent, amine curing agent and cyanamid dimerization class curing agent.
8. a kind of solar cell backboard according to claim 5, it is characterised in that:The inorganic filler be titanium dioxide, One or more in mica powder, talcum powder, barium sulfate, calcium carbonate, aluminium hydroxide, bortz powder.
CN201710096012.2A 2017-02-22 2017-02-22 A kind of solar cell backboard Pending CN106876511A (en)

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Application Number Priority Date Filing Date Title
CN201710096012.2A CN106876511A (en) 2017-02-22 2017-02-22 A kind of solar cell backboard

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Application Number Priority Date Filing Date Title
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Publications (1)

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CN106876511A true CN106876511A (en) 2017-06-20

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107611203A (en) * 2017-10-16 2018-01-19 苏州中来光伏新材股份有限公司 A kind of high performance solar cells backboard and preparation method and component
CN107749430A (en) * 2017-10-20 2018-03-02 张东 A kind of solar cell backboard, solar cell and preparation method thereof
CN109968768A (en) * 2017-12-28 2019-07-05 宁波长阳科技股份有限公司 A kind of insulating heat-conductive solar cell backboard
CN110938387A (en) * 2018-09-25 2020-03-31 苏州维兰德新材料有限公司 High-weather-resistance polyolefin composite film for solar cell back plate and preparation method thereof
WO2021128585A1 (en) * 2019-12-27 2021-07-01 苏州赛伍应用技术股份有限公司 Solar cell backplane
CN114420781A (en) * 2022-01-11 2022-04-29 苏州赛伍应用技术股份有限公司 Blue high-reflection solar cell backboard
CN115911164A (en) * 2022-10-21 2023-04-04 隆基绿能科技股份有限公司 Solar module and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130209795A1 (en) * 2010-10-20 2013-08-15 Suzhou Sunshine New Materials Technology Co., Ltd. Polymer backsheet of solar cell assembly and manufacturing process thereof
CN203826402U (en) * 2013-12-30 2014-09-10 苏州赛伍应用技术有限公司 Transparent solar cell backboard and solar cell assembly
CN104512081A (en) * 2014-11-27 2015-04-15 苏州赛伍应用技术有限公司 Two-layer structural PET (polyethylene terephthalate) film and solar battery back plate prepared from two-layer structural PET film
CN104518040A (en) * 2014-11-27 2015-04-15 苏州赛伍应用技术有限公司 Tri-layer PET (polyethylene glycol terephthalate) film and solar battery backboard constituted by same
CN104512082A (en) * 2014-11-27 2015-04-15 苏州赛伍应用技术有限公司 Three-layer structural PET (polyethylene terephthalate) film and solar battery back plate prepared from three-layer structural PET film

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130209795A1 (en) * 2010-10-20 2013-08-15 Suzhou Sunshine New Materials Technology Co., Ltd. Polymer backsheet of solar cell assembly and manufacturing process thereof
CN203826402U (en) * 2013-12-30 2014-09-10 苏州赛伍应用技术有限公司 Transparent solar cell backboard and solar cell assembly
CN104512081A (en) * 2014-11-27 2015-04-15 苏州赛伍应用技术有限公司 Two-layer structural PET (polyethylene terephthalate) film and solar battery back plate prepared from two-layer structural PET film
CN104518040A (en) * 2014-11-27 2015-04-15 苏州赛伍应用技术有限公司 Tri-layer PET (polyethylene glycol terephthalate) film and solar battery backboard constituted by same
CN104512082A (en) * 2014-11-27 2015-04-15 苏州赛伍应用技术有限公司 Three-layer structural PET (polyethylene terephthalate) film and solar battery back plate prepared from three-layer structural PET film

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107611203A (en) * 2017-10-16 2018-01-19 苏州中来光伏新材股份有限公司 A kind of high performance solar cells backboard and preparation method and component
CN107611203B (en) * 2017-10-16 2024-04-30 苏州中来光伏新材股份有限公司 High-performance solar cell backboard, preparation method and assembly
CN107749430A (en) * 2017-10-20 2018-03-02 张东 A kind of solar cell backboard, solar cell and preparation method thereof
CN107749430B (en) * 2017-10-20 2019-11-08 周新芳 A kind of solar cell backboard, solar battery and preparation method thereof
CN109968768A (en) * 2017-12-28 2019-07-05 宁波长阳科技股份有限公司 A kind of insulating heat-conductive solar cell backboard
CN109968768B (en) * 2017-12-28 2021-04-13 宁波长阳科技股份有限公司 Insulating heat conduction solar cell backplate
CN110938387A (en) * 2018-09-25 2020-03-31 苏州维兰德新材料有限公司 High-weather-resistance polyolefin composite film for solar cell back plate and preparation method thereof
WO2021128585A1 (en) * 2019-12-27 2021-07-01 苏州赛伍应用技术股份有限公司 Solar cell backplane
CN114420781A (en) * 2022-01-11 2022-04-29 苏州赛伍应用技术股份有限公司 Blue high-reflection solar cell backboard
CN115911164A (en) * 2022-10-21 2023-04-04 隆基绿能科技股份有限公司 Solar module and preparation method thereof

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Application publication date: 20170620