CN106868865A - A kind of method of alcamines solution graft copolymerization modified carbon fiber surface size agent - Google Patents
A kind of method of alcamines solution graft copolymerization modified carbon fiber surface size agent Download PDFInfo
- Publication number
- CN106868865A CN106868865A CN201710056915.8A CN201710056915A CN106868865A CN 106868865 A CN106868865 A CN 106868865A CN 201710056915 A CN201710056915 A CN 201710056915A CN 106868865 A CN106868865 A CN 106868865A
- Authority
- CN
- China
- Prior art keywords
- carbon fiber
- modified
- alcamines
- graft copolymerization
- sizing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 102
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 68
- 238000000034 method Methods 0.000 title claims abstract description 34
- 238000007334 copolymerization reaction Methods 0.000 title claims abstract description 15
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 80
- 239000004917 carbon fiber Substances 0.000 claims abstract description 80
- 239000003607 modifier Substances 0.000 claims abstract description 33
- 238000004513 sizing Methods 0.000 claims abstract description 32
- 239000000835 fiber Substances 0.000 claims abstract description 19
- 230000004048 modification Effects 0.000 claims abstract description 12
- 238000012986 modification Methods 0.000 claims abstract description 12
- 239000004593 Epoxy Substances 0.000 claims description 20
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 5
- 238000004381 surface treatment Methods 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- VEPSIZZAILVTSD-UHFFFAOYSA-N 1-aminobut-3-en-2-ol Chemical compound NCC(O)C=C VEPSIZZAILVTSD-UHFFFAOYSA-N 0.000 claims 1
- WCASXYBKJHWFMY-UHFFFAOYSA-N crotyl alcohol Chemical class CC=CCO WCASXYBKJHWFMY-UHFFFAOYSA-N 0.000 claims 1
- 229920005989 resin Polymers 0.000 abstract description 21
- 239000011347 resin Substances 0.000 abstract description 21
- 239000002131 composite material Substances 0.000 abstract description 16
- 229920001567 vinyl ester resin Polymers 0.000 abstract description 14
- 239000000126 substance Substances 0.000 abstract description 8
- 229920006337 unsaturated polyester resin Polymers 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 4
- 239000011159 matrix material Substances 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 5
- 125000003700 epoxy group Chemical group 0.000 description 4
- 239000003822 epoxy resin Substances 0.000 description 4
- 229920000647 polyepoxide Polymers 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- VVBVTZZZFFHHSP-UHFFFAOYSA-N 4-aminobut-2-en-1-ol Chemical class NCC=CCO VVBVTZZZFFHHSP-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000012783 reinforcing fiber Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000000805 composite resin Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 235000003642 hunger Nutrition 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 230000016507 interphase Effects 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002715 modification method Methods 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 238000009955 starching Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/06—Elements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/40—Fibres of carbon
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710056915.8A CN106868865B (en) | 2017-01-24 | 2017-01-24 | A kind of method of alcamines solution graft copolymerization modified carbon fiber surface size agent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710056915.8A CN106868865B (en) | 2017-01-24 | 2017-01-24 | A kind of method of alcamines solution graft copolymerization modified carbon fiber surface size agent |
Publications (2)
Publication Number | Publication Date |
---|---|
CN106868865A true CN106868865A (en) | 2017-06-20 |
CN106868865B CN106868865B (en) | 2019-03-26 |
Family
ID=59158345
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710056915.8A Active CN106868865B (en) | 2017-01-24 | 2017-01-24 | A kind of method of alcamines solution graft copolymerization modified carbon fiber surface size agent |
Country Status (1)
Country | Link |
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CN (1) | CN106868865B (en) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102926204A (en) * | 2012-11-16 | 2013-02-13 | 金发科技股份有限公司 | Sizing agent for emulsion type carbon fiber, preparation method and application of sizing agent |
JP2014074255A (en) * | 2012-09-14 | 2014-04-24 | Toray Ind Inc | Siding agent application carbon fiber, production method of siding agent application carbon fiber, prepreg, and carbon fiber reinforced composite material |
JP2014108990A (en) * | 2012-12-03 | 2014-06-12 | Mitsubishi Rayon Co Ltd | Carbon fiber-reinforced polypropylene resin composition |
CN104195824A (en) * | 2014-09-15 | 2014-12-10 | 哈尔滨工业大学 | Carbon fiber surface modification method |
-
2017
- 2017-01-24 CN CN201710056915.8A patent/CN106868865B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2014074255A (en) * | 2012-09-14 | 2014-04-24 | Toray Ind Inc | Siding agent application carbon fiber, production method of siding agent application carbon fiber, prepreg, and carbon fiber reinforced composite material |
CN102926204A (en) * | 2012-11-16 | 2013-02-13 | 金发科技股份有限公司 | Sizing agent for emulsion type carbon fiber, preparation method and application of sizing agent |
JP2014108990A (en) * | 2012-12-03 | 2014-06-12 | Mitsubishi Rayon Co Ltd | Carbon fiber-reinforced polypropylene resin composition |
CN104195824A (en) * | 2014-09-15 | 2014-12-10 | 哈尔滨工业大学 | Carbon fiber surface modification method |
Also Published As
Publication number | Publication date |
---|---|
CN106868865B (en) | 2019-03-26 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20210112 Address after: 213002 No.202 Donghai Road, Xinbei District, Changzhou City, Jiangsu Province Patentee after: Changzhou Rongxin composite material Co.,Ltd. Address before: 150001 No. 92 West straight street, Nangang District, Heilongjiang, Harbin Patentee before: HARBIN INSTITUTE OF TECHNOLOGY |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A method for grafting modified carbon fiber surface sizing agent with alcohol amine solution Granted publication date: 20190326 Pledgee: China Construction Bank Corporation Changzhou Xinbei sub branch Pledgor: Changzhou Rongxin composite material Co.,Ltd. Registration number: Y2024980036721 |