CN106867703A - A kind of circuit board ultrasonic wave water for cleaning based cleaning agent - Google Patents

A kind of circuit board ultrasonic wave water for cleaning based cleaning agent Download PDF

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Publication number
CN106867703A
CN106867703A CN201611258486.4A CN201611258486A CN106867703A CN 106867703 A CN106867703 A CN 106867703A CN 201611258486 A CN201611258486 A CN 201611258486A CN 106867703 A CN106867703 A CN 106867703A
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CN
China
Prior art keywords
circuit board
ultrasonic wave
cleaning
water
cleaning agent
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611258486.4A
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Chinese (zh)
Inventor
姜莉
刘常兴
陶继宏
王利云
吴德斌
李涛
谢建荣
董颖辉
张小群
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Tongling Safe Circuit Board Co Ltd
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Tongling Safe Circuit Board Co Ltd
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Filing date
Publication date
Application filed by Tongling Safe Circuit Board Co Ltd filed Critical Tongling Safe Circuit Board Co Ltd
Priority to CN201611258486.4A priority Critical patent/CN106867703A/en
Publication of CN106867703A publication Critical patent/CN106867703A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • C11D1/8305Mixtures of non-ionic with anionic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/835Mixtures of non-ionic with cationic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/08Silicates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2079Monocarboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/28Heterocyclic compounds containing nitrogen in the ring
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/32Amides; Substituted amides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/36Organic compounds containing phosphorus
    • C11D3/362Phosphates or phosphites
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/667Neutral esters, e.g. sorbitan esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • C11D1/721End blocked ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/74Carboxylates or sulfonates esters of polyoxyalkylene glycols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • C11D2111/22Electronic devices, e.g. PCBs or semiconductors

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a kind of circuit board ultrasonic wave water for cleaning based cleaning agent, each component and mass percent are as follows:Triethanolamine oleate 5~15%, Sodium Benzoate 3~7%, APES 4~8%, surfactant 1~3%, builder 0~2%, corrosion inhibiter 0~1%, antistatic additive 0~1%, balance of water.Safety and environmental protection of the present invention, nonirritant, non-corrosiveness and No toxicological, it is nontoxic to people, free of a burden to environment, lossless to ozone layer, it is provided simultaneously with excellent cleaning and rinse capacity.

Description

A kind of circuit board ultrasonic wave water for cleaning based cleaning agent
Technical field
The present invention relates to circuit board manufacturing area, more particularly to a kind of circuit board ultrasonic wave water for cleaning based cleaning agent.
Background technology
Printed circuit board (PCB) (Printed Circuit Board) joins in welding process in dress, in order to ensure the reliability of welding Property, it is necessary to use activity scaling powder higher.These welding assisted agent residuals on PCB, by open circuit potential plate and component, while drop Low its surface insulation resistance.With the erosion of the humidity in environment, dust oil smoke, electrostatic and various pernicious gases, efflorescence is helped Solder flux can constantly absorb these impurity, even more so that serious corrosion and electric leakage occurs in circuit board, influence the reliability of circuit board.
Conventional traditional circuit-board cleaning generally uses the ODS (ozone layer depletions of Containing Freon (CFC-113) at present Material) cleaning agent, such cleaning agent have good chemical stability, small toxicity, do not burn, surface tension is small, do not damage and be cleaned Material, the advantages of stronger permeability, rapid-drying properties can be kept, also it is widely used so far.
But ODS classes cleaning agent has extremely strong destructive power to ozone layer, and the ecological environment of the serious harm mankind is in the world Time limit stops production and the material for using.In recent years, also develop some short-term substitutes both at home and abroad, such as HCFC (HCFC, Perfluoroparaffin (PFC) and other halogenated solvents etc..HCFC is that the part halogen atom in freon is replaced by hydrogen atom, makes the ODP of CFC (the latent value of ozone-depleting) is reduced, but it remains to damage the ozone layer, and to be also eliminated to the year two thousand twenty, existing the latest no more than the year two thousand forty In many users, oneself uses the cleaning agent containing ODS materials through refusal.Some organic solvents are also used as ODS class cleaning agents Substitute, but cleaning performance not as ODS classes cleaning agent it is good, and flash-point is low, inflammable, explosive, while some also (are waved containing VOCs Hair property organic compound) etc. toxicant.Long Term Contact VOCs can make eye, nose, dry throat, and general weakness, discomfort are easily tired , often there is spirituality headache, failure of memory in labor, dry skin, convulsion are itched, shouting pain, erythema etc., some also result in cancer The malignant disease such as (lung cancer, leukaemia), miscarriage, fetal anomaly and growth retardation.
In addition, existing aqueous cleaning agent also has following defect:
(1) to many sticky wax dirts, such as rosin, glue class, and blind hole, gap on workpiece, hydrophobicity part can not be thorough Bottom removes organic fouling and particulate fouling;
(2) residue after the cleaning of some aqueous cleaning agents is difficult to remove, especially blind hole, the residue in gap, may be right Subsequent handling or application have undesirable effect;
(3) cleaning agent of residual is easy to cause the metal parts such as the pin position of pad and component on PCBA corrosion occur Phenomenon;
(4) waste liquid disposal is complicated, it is difficult to recycle.
With the densification of assembling, the fine-pitch of pin, the cleannes to PCBA propose higher and higher requirement, Requirement to cleaning agent also more and more higher.Residue on PCBA is mainly the electronic welding auxiliary material such as solder(ing) paste, scaling powder Residue, the pollutant, these material compositions such as the hand perspiration stain in operating process, finger mark and aerial fiber, dust for dropping The quality and reliability influence of complexity, cleaning agent and cleaning on circuit board is very big.
The content of the invention
Present invention aim to address the deficiencies in the prior art, there is provided a kind of circuit board ultrasonic wave water for cleaning is washed down Agent.
The technical solution adopted by the present invention is:A kind of circuit board ultrasonic wave water for cleaning based cleaning agent, each component and quality Percentage is as follows:
Triethanolamine oleate 5~15%
Sodium Benzoate 3~7%
APES 4~8%
Surfactant 1~3%
Builder 0~2%
Corrosion inhibiter 0~1%
Antistatic additive 0~1%
Balance of water.
As a further improvement on the present invention, the surfactant includes alkyl trimethyl quaternary ammonium salt, dialkyl group diformazan Based quaternary ammonium salt, monoalkyl quaternary ammonium salts, glycerine mono-acid stearate, aliphatic acid polyethenoxy acid esters, polyglyceryl fatty acid ester and third One or more mixture in diol fatty acid ester.
As a further improvement on the present invention, the corrosion inhibiter includes sodium metasilicate, benzotriazole derivative and alkanolamide In one or more mixture.
As a further improvement on the present invention, the antistatic additive is amine or phosphoric acid derivatives.
Further improved as of the invention, the water is deionized water.
The present invention use beneficial effect be:Safety and environmental protection of the present invention, Wu's excitant, non-corrosiveness and No toxicological, It is nontoxic to people, free of a burden to environment, lossless to ozone layer, it is provided simultaneously with excellent cleaning and rinse capacity.
Specific embodiment
With reference to embodiment, the present invention is described further.
Embodiment 1, a kind of circuit board ultrasonic wave water for cleaning based cleaning agent, each component and mass percent are as follows:
Triethanolamine oleate 5%
Sodium Benzoate 3%
APES 4%
Glycerine mono-acid stearate 1%
Builder 2%
Alkanolamide 1%
Phosphoric acid derivatives 1%
Balance of water.
Embodiment 2, a kind of circuit board ultrasonic wave water for cleaning based cleaning agent, each component and mass percent are as follows:
Triethanolamine oleate 15%
Sodium Benzoate 7%
APES 8%
Polyglyceryl fatty acid ester and methyl glycol fatty acid ester mixture 3%
Builder 2%
Sodium metasilicate 1%
Phosphoric acid derivatives 1%
Balance of deionized water.
Embodiment 3, a kind of circuit board ultrasonic wave water for cleaning based cleaning agent, each component and mass percent are as follows:
Triethanolamine oleate 10%
Sodium Benzoate 4%
APES 6%
Dialkyl dimethyl quaternary ammonium salt 2%
Builder 1%
Alkanolamide 1%
Balance of deionized water.
Embodiment 4, a kind of circuit board ultrasonic wave water for cleaning based cleaning agent, each component and mass percent are as follows:
Triethanolamine oleate 12%
Sodium Benzoate 5%
APES 6%
Aliphatic acid polyethenoxy acid esters and methyl glycol fatty acid ester mixture 3%
Builder 1%
Benzotriazole derivative 1%
Phosphoric acid derivatives 1%
Balance of deionized water.
Embodiment 5, a kind of circuit board ultrasonic wave water for cleaning based cleaning agent, each component and mass percent are as follows:
Triethanolamine oleate 8%
Sodium Benzoate 5%
APES 7%
Alkyl trimethyl quaternary ammonium salt 1%
Builder 1%
Alkanolamide 1%
Balance of deionized water.
Ultrasonic wave cleaning circuit plate is carried out using embodiment 1 to 5, the result of routine inspection and X-ray energy spectrum analysis is carried out Show, the cleansing power and rinsing performance of embodiment 1 to 5 are better than former ODS cleaning agents.
Surfactant is also used for the purposes of antistatic additive sometimes, when surfactant using alkyl trimethyl quaternary ammonium salt, When dialkyl dimethyl quaternary ammonium salt, monoalkyl quaternary ammonium salts, then antistatic additive is not added with.
Safety and environmental protection of the present invention, Wu's excitant, non-corrosiveness and No toxicological, it is nontoxic to people, free of a burden to environment, right Ozone layer is lossless, is provided simultaneously with excellent cleaning and rinse capacity.
Those skilled in the art, can also be it is to be understood that protection scheme of the invention is not limited only to the above embodiments Various permutation and combination and conversion are carried out on the basis of above-described embodiment, on the premise of without prejudice to spirit of the invention, to the present invention The various conversion for carrying out are all fallen within protection scope of the present invention.

Claims (5)

1. a kind of circuit board ultrasonic wave water for cleaning based cleaning agent, it is characterized in that each component and mass percent are as follows:
Triethanolamine oleate 5~15%
Sodium Benzoate 3~7%
APES 4~8%
Surfactant 1~3%
Builder 0~2%
Corrosion inhibiter 0~1%
Antistatic additive 0~1%
Balance of water.
2. a kind of circuit board ultrasonic wave water for cleaning based cleaning agent according to claim 1, it is characterized in that the surface is lived Property agent include alkyl trimethyl quaternary ammonium salt, dialkyl dimethyl quaternary ammonium salt, monoalkyl quaternary ammonium salts, glycerine mono-acid stearate, fat One or more mixture in fat acid polyoxyethylene acid esters, polyglyceryl fatty acid ester and methyl glycol fatty acid ester.
3. a kind of circuit board ultrasonic wave water for cleaning based cleaning agent according to claim 1, it is characterized in that the corrosion inhibiter Including one or more the mixture in sodium metasilicate, benzotriazole derivative and alkanolamide.
4. a kind of circuit board ultrasonic wave water for cleaning based cleaning agent according to claim 1, it is characterized in that described antistatic Agent is amine or phosphoric acid derivatives.
5. a kind of circuit board ultrasonic wave water for cleaning based cleaning agent according to any one in claim 1 to 4, its feature It is that the water is deionized water.
CN201611258486.4A 2016-12-30 2016-12-30 A kind of circuit board ultrasonic wave water for cleaning based cleaning agent Pending CN106867703A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611258486.4A CN106867703A (en) 2016-12-30 2016-12-30 A kind of circuit board ultrasonic wave water for cleaning based cleaning agent

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Application Number Priority Date Filing Date Title
CN201611258486.4A CN106867703A (en) 2016-12-30 2016-12-30 A kind of circuit board ultrasonic wave water for cleaning based cleaning agent

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112455112A (en) * 2020-11-13 2021-03-09 上海富驰高科技股份有限公司 Printing method of MIM (metal-insulator-metal) craft product

Citations (4)

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Publication number Priority date Publication date Assignee Title
US5688753A (en) * 1995-04-06 1997-11-18 Church & Dwight Co.,Inc. Flux removing composition
CN1316495A (en) * 2001-04-30 2001-10-10 山东大学 Water-base composite detergent for printed circuit board
CN101368138A (en) * 2007-08-15 2009-02-18 江苏海迅实业集团股份有限公司 Electronic instrument detergent
CN104893834A (en) * 2015-06-01 2015-09-09 东莞市伟思化学科技有限公司 Water-based cleaning solution for cleaning printed circuit board and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5688753A (en) * 1995-04-06 1997-11-18 Church & Dwight Co.,Inc. Flux removing composition
CN1316495A (en) * 2001-04-30 2001-10-10 山东大学 Water-base composite detergent for printed circuit board
CN101368138A (en) * 2007-08-15 2009-02-18 江苏海迅实业集团股份有限公司 Electronic instrument detergent
CN104893834A (en) * 2015-06-01 2015-09-09 东莞市伟思化学科技有限公司 Water-based cleaning solution for cleaning printed circuit board and preparation method thereof

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Title
刘程: "《表面活性剂应用手册 第3版》", 30 September 2004, 化学工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112455112A (en) * 2020-11-13 2021-03-09 上海富驰高科技股份有限公司 Printing method of MIM (metal-insulator-metal) craft product

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