CN106867431B - Aqueous, environmental protective plastic cement race track adhesive and preparation method thereof - Google Patents
Aqueous, environmental protective plastic cement race track adhesive and preparation method thereof Download PDFInfo
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- CN106867431B CN106867431B CN201710106018.3A CN201710106018A CN106867431B CN 106867431 B CN106867431 B CN 106867431B CN 201710106018 A CN201710106018 A CN 201710106018A CN 106867431 B CN106867431 B CN 106867431B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of aqueous, environmental protective plastic cement race track adhesive and preparation method thereof, its key points of the technical solution are that including component A and B component；Component A includes the substance of following weight percent meter: 19% ~ 48% deionized water, 0.3% ~ 0.8% dispersing agent, 0.5% ~ 0.7% defoaming agent, 0.2% ~ 0.5% thickener, 1% ~ 2% hydroxyethyl ether cellulose, 0.5% ~ 1% coalescing agent, 40% ~ 60% water-and acrylate lotion, 0.5% ~ 2% fungicide；B component includes the substance of following weight percent meter: 5% ~ 10% amine curing agent, instead of in the prior art using adhesive prepared by aromatic diisocyanate, even if encountering hot weather or when by strong ultraviolet radiation, adhesive through the application will not discharge the toxic gas of aromatics, substantially increase the environmental-protecting performance of adhesive.
Description
Technical field
The present invention relates to adhesive, in particular to a kind of aqueous, environmental protective plastic cement race track adhesive and preparation method thereof.
Background technique
Plastic cement race track is by base polyurethane prepolymer for use as, admixtured polyether, scrap tire rubber, EPDM rubber grain or PU particle, face
The composition such as material, auxiliary agent, filler.Plastic cement race track is with flatness is good, compression strength is high, the elastic appropriate, stable physical property of hardness
Characteristic, be conducive to the performance of sportsman's speed and technology, effectively improve sports achievement, reduce tumble injury rate, be public in the world
The playing field floor material recognized.
But it is no lack of from media the negative report it can be seen that some plastic cement race tracks recently.It is learned according to the report, somewhere
" malicious plastic cement race track ", which occurs, in school causes student the message continuing fermentation of the symptoms such as nose is bleeding, dizziness, skin allergy, dependent part occur
A large amount of quality inspection has also been made to the plastic cement race track for accident school occur in door.The result shows that plastic cement race track is by being exposed to the sun of air, rain
Washing away for water can distribute volatile materials into air, and student sucks a large amount of volatile materials and results in nose is bleeding, dizziness, skin
Phenomena such as allergy, which results in the extensive concerns of society.
Currently, application publication number is that the Chinese patent of CN105038684A discloses a kind of environment-friendly type plastic rubber in existing patent
The preparation of runway polyurethane adhesive, this method are the chlorinated paraffins using polyether polyol, aromatic diisocyanate as raw material
It is auxiliary agent with dibutyl phthalate, white carbon black is filler, and organotin is catalyst, has prepared ring by prepolymer method
It protects, high-performance plastic cement race track polyurethane adhesive, is prepared for that volatility is low, the nontoxic, environment-friendly adhesive that has no irritating odor,
With excellent service performance.
But the raw material in above-mentioned environment-friendly adhesive uses a large amount of solvents and aromatic diisocyanate, encounters sweltering heat
Weather or when ultraviolet light acute irradiation can accelerated release in vitro aromatics poisonous substance, the heavy metals such as residual lead, mercury have human body relatively strong
Chronic toxicity, and lasting contact scar will also result in soil environment and underground water；Moreover, being added in above-mentioned adhesive a large amount of
Silica cause adhesive to be easy to happen cracking with increasing for dioxide-containing silica.
Summary of the invention
The object of the present invention is to provide a kind of aqueous, environmental protective plastic cement race track adhesive, raw material used in the adhesive is very
It is safe and environment-friendly, and there is good resilience performance, it is not easy to crack.
Above-mentioned technical purpose of the invention has the technical scheme that
A kind of aqueous, environmental protective plastic cement race track adhesive, including component A and B component；
The component A includes the substance of following weight percent meter: 19%~48% deionized water, 0.3%~0.8% point
Powder, 0.5%~0.7% defoaming agent, 0.2%~0.5% thickener, 1%~2% hydroxyethyl ether cellulose, 0.5%~1%
Coalescing agent, 40%~60% water-and acrylate lotion, 0.5%~2% fungicide；
The B component includes the substance of following weight percent meter: 5%~10% amine curing agent.
By using above-mentioned technical proposal, raw material used by the adhesive of the application is deionized water, water soluble acrylic acid
Ester lotion, hydroxyethyl ether cellulose and auxiliary agent, the water-and acrylate lotion to play a major role have excellent environmental-protecting performance,
Instead of adhesive prepared by aromatic diisocyanate is used in the prior art, even if encountering hot weather or by strong
When ultraviolet light irradiates, the adhesive through the application will not discharge the toxic gas of aromatics, substantially increase the ring of adhesive
Guaranteed cost；Meanwhile water-and acrylate lotion has excellent flexibility, resilience, facilitates the cracking behavior for reducing adhesive.
The present invention is further arranged to: the water-and acrylate lotion is epoxy-acrylic hybridisation emulsion and elasticity third
Olefin(e) acid latex composite compounding, wherein accounting of the epoxy-acrylic hybridisation emulsion in water-and acrylate lotion is 30%~40%.
By using above-mentioned technical proposal, epoxy-acrylic hybridisation emulsion is to compensate for epoxy resin with acrylic acid respectively
Deficiency, the hybridisation emulsion the advantages of combination epoxy resin and acrylic acid that are prepared by nuclear-shell emulsion polymerization method；Elastomeric propylene
Yogurt liquid, which refers to, is added suitable soft monomer to reduce glass transition temperature, and utilizes the function monomer or oligomer institute band being added
The interaction of some specific functional groups forms ehter bond, ester bond perhaps amide group or by the addition between double bond
The C-C key of macromolecular chain is formed, a kind of acrylic acid ester emulsion with micro- cross-linked structure is formed；By epoxy-acrylic hydridization cream
Liquid is used in compounding with elastomeric propylene yogurt liquid, significantly improves the cementitiousness of adhesive, and has excellent weatherability, resistance to
Alkalinity, uvioresistant photosensitiveness and excellent resilience, tensile strength and non-easy to cracking.
The present invention is further arranged to: the dispersing agent be acrylate copolymer, phenylethylene-maleic anhydride polymer,
One or more of polycarboxylic-acid dispersing agent.
By using above-mentioned technical proposal, dispersing agent select acrylate copolymer, phenylethylene-maleic anhydride polymer,
One or more of polycarboxylic-acid dispersing agent, acrylic acid esters co-polymer are widely used in coating as dispersing agent, it
Good concertedness is generated with many membrane polymers, facilitates the dispersion to system；In phenylethylene-maleic anhydride polymer molecule
Not only contain Hydrophobic Styrene's segment, but also contain hydrophily maleic anhydride segment, there is good dispersion performance, and benzene second
Alkene-maleic anhydride polymer is closely incorporated in solid by the effects of ion pair, hydrogen bond, Van der Waals force by anchoring group
Between filler and liquid filler, very strong space steric effect is formd, to be conducive to steadily disperse；Polycarboxylic-acid dispersion
Agent has Long carbon chain, more active absorption point and the branch that can play space repulsive interaction, has played in emulsion polymerization
The dispersion performance of effect, and polycarboxylic-acid dispersing agent is when in use, and small to pH value and temperature sensitivity, dispersion performance is high,
It is less prone to sedimentation and flocculation.
The present invention is further arranged to: further including 3%~4% functional aid, the functional aid is acrylic acid official
The organosilicon performed polymer of energyization.
By using above-mentioned technical proposal, the organosilicon performed polymer of acrylic acid functionalized facilitates as functional aid
The surface property for improving water-and acrylate lotion, increases the smoothness on surface, while improving the strong of water-and acrylate lotion
Degree, flexibility, agglomeration resistance, scratch resistance and resistance tocrocking.
The present invention is further arranged to: further including 1%~3% antifreezing agent.
By using above-mentioned technical proposal, antifreezing agent is added, helps to have adhesive described herein at low temperature
Effect prevents in material moisture to freeze, since the adhesive of the application is acted on plastic cement race track, and the coagulation in plastic cement race track
Soil need hardened under subzero temperature, add antifreezing agent, when helping to be laid with plastic cement race track at low temperature, in plastic cement race track each layer it
Between cohesive force it is more preferable, to improve the intensity of plastic cement race track.
The present invention is further arranged to: further including 5%~6% dust-proofing agent, the dust-proofing agent selects fumed silica.
By using above-mentioned technical proposal, fumed silica dust-proofing agent carries out thixotroping by hydrogen bond, can be by pigments and fillers
The moisture Substitutive Coating on surface, allows it to be closely combined together with esters of acrylic acid, plays anti-settling, thickening, anti-stream
It hangs, and helps to play the role of dispersion, improves adhesive force.
Another object of the present invention is to disclose a kind of preparation method of aqueous, environmental protective plastic cement race track adhesive, including such as
Lower step:
(1) it dissolves: by 0.3%~0.8% dispersing agent, 0.5%~0.7% defoaming agent, 1%~3% antifreezing agent, 0.5%
The auxiliary agents such as~2% fungicide are added in 19%~48% deionized water, and 1%~2% hydroxyethyl ether cellulose is then added, and are adjusted
Section revolving speed is 500~1000rpm, disperses 15~25min, cellulose paste is made；
(2) prepared by adhesive: 40%~60% water-and acrylate lotion is added in the cellulose paste that dispersion is completed,
It is stirred under the conditions of 500~1000rpm, and 0.5%~0.7% defoaming agent, 3%~4% functional aid, 5% is added
~6% dust-proofing agent, 0.2%~0.5% thickener and 0.5%~1% coalescing agent are packed after mixing.
By using above-mentioned technical proposal, dispersing agent, defoaming agent, antifreezing agent, fungicide are dissolves uniformly in first
In ionized water, then hydroxyethyl ether cellulose is effectively dissolved, forms cellulose paste；Then to evenly dispersed fiber
Water-and acrylate lotion is added in plain slurry, and is adequately stirred；In addition other function auxiliary agent is added, to make to make
The comprehensive performance of standby adhesive is more excellent.
The present invention is further arranged to: it is 35~40 DEG C that solution temperature is adjusted in step (1).
By using above-mentioned technical proposal, the course of dissolution in rate-determining steps (1) is at 35~40 DEG C, in the temperature for being higher than room temperature
It is dissolved under degree, helps speed up the solution rate of dispersing agent, defoaming agent, antifreezing agent and fungicide in water, mention simultaneously
The solubility of high hydroxyethyl ether cellulose in deionized water helps to prepare uniform and stable cellulose paste.
In conclusion the invention has the following advantages:
1, water-and acrylate lotion uses acrylic acid hybridisation emulsion and elastomeric propylene acid latex composite compounding, has excellent ring
Guaranteed cost；The cementitiousness of adhesive is helped to improve simultaneously, and there is excellent weatherability, alkali resistance, uvioresistant photosensitiveness
And excellent resilience, tensile strength and non-easy to cracking；
2, the organosilicon performed polymer of acrylic acid functionalized and water-and acrylate lotion generate synergistic effect, greatly strengthen
The surface property of emulsion system, increases the smoothness on surface, while improving the intensity of water-and acrylate lotion, flexibility, resisting
Agglomeration, scratch resistance and resistance tocrocking；
3, fumed silica dust-proofing agent, dispersing agent, coalescing agent simultaneously, are added in emulsion system, to improve cream
Dispersibility in liquid system between solid packing and liquid filler.
Specific embodiment
Invention is further described in detail with reference to embodiments.
Hydroxyethyl ether cellulose is to contain river (Beijing) Chemical Co., Ltd. by Australia's Chinese to sell；
Coalescing agent selects the 2-amino-2-methyl-1-propanol of Dow Chemical Company production；
Antifreezing agent selects the antifreeze of the water-soluble organic compounds class of Xi'an day base special energy-saving building materials Co., Ltd production
Agent；
The KS-1009 type organic silicon defoamer that defoaming agent selects Kai Na (Tianjin) environmental protection technology Co., Ltd to sell；Thickening
The C-110 type of federal Fine Chemical Co., Ltd's production in Guangdong is selected in agent；
Fungicide selects the production of Xiang Xin Chemical Co., Ltd.；
Acrylate copolymer dispersants select the BYK-154 emulsion system dispersing agent of Bi Ke company of Germany production；
Phenylethylene-maleic anhydride dispersing agent selects the SMA resin of Yuyao City Hui Hong plastic molding and processing plant production；
Polycarboxylic-acid dispersing agent is selected from the SN5040 type High-efficiency polycarboxylic acid sodium-salt type of Taiwan Central Asia production；
The KX-03 type that elastomeric propylene yogurt liquid selects Kuang Xuan Chemical Co., Ltd. in Guangzhou to sell；
Dust-proofing agent selects Degussa AEROSIL200 type fumed silica.
Preparation:
One, the preparation of epoxy-acrylic hybridisation emulsion:
1, prepare raw material: epoxy resin, acrylic monomers and alkyl acrylate monomer, draw vinyl alkyl phosphate
Send out agent, neutralizer, deionized water；
2, preparation process:
(1) 80kg water, 0.4kg dodecyl sodium sulfate and 0.1kg octyl phenol polyoxyethylene ether are stirred evenly, is warming up to
50 DEG C, 10.2kg methyl methacrylate and 5.6kg butyl acrylate and 1.2kg methacrylic acid is added, is continuously heating to 75
℃；0.15kg Ammonium Persulfate 98.5 aqueous solution is added, until lotion is in obvious blue light；Be added dropwise 10.2kg methyl methacrylate and
The mix monomer of 5.6kg butyl acrylate and 1.2kg methacrylic acid drips heat preservation 30 minutes, and seed emulsion is made；
(2) while preparing seed emulsion, with 52kg methyl methacrylate and 26kg butyl acrylate mix monomer
Dissolve 12kg E-51 epoxy resin, then plus 0.6kg benzoyl peroxide initiator, 0.3kg dodecyl sodium sulfate and
1.2kg octyl phenol polyoxyethylene ether, 1.2kg vinyl alkyl phosphate, 0.6kg N, N- dimethylethanolamine and 50kg water are used
High-shear emulsifying dispersion machine is emulsified, and pre-emulsion is obtained；
(3) pre-emulsion is added dropwise into seed emulsion at 80 DEG C, continues emulsion polymerization, after the completion of emulsion polymerization, protect
Temperature 2 hours；
(4) resulting lotion is cooled to 25 DEG C, appropriate N, N- dimethylethanolamine, by lotion pH is added under stirring
Value is adjusted to 8, obtains epoxy/acrylic acid hybridisation emulsion.
Two, the preparation of the organosilicon performed polymer of acrylic acid functionalized:
(1) by vinyltriethoxysilane 20kg, pentaerythritol triacrylate 2kg, pentaerythritol tetraacrylate
2kg, propylene oxide acid glycidyl ester 6kg, methyl acrylate 5kg, hydroxyethyl methacrylate 5kg, acrylic acid 10kg, isopropyl
Alcohol 25kg is added sequentially in reactor tank, and mechanical stirring is evenly dispersed；
(2) reactor tank is warming up to 80 DEG C, 2% azodiisobutyronitrile/aqueous isopropanol 25kg is dripped in half an hour
Cause Raolical polymerizable；
(3) after back flow reaction 2h, tetramethylammonium hydroxide neutralization reaction product is added until pH value is 7；
(4) solid content is adjusted to 50% by filtering removal impurity and precipitating, supplement isopropanol, as acrylic acid functionalized
Organosilicon performed polymer.
Embodiment one:
380kg water is added in stirring container, the dispersion of 5kg acrylate copolymer is added in the case where speed of agitator is 300rpm
Then agent, hydroxyethyl cellulose 15kg, antifreezing agent 20kg, fungicide 5kg, defoaming agent 3kg, fully dispersed 20min turn in stirring
Speed is that epoxy-acrylic hybridisation emulsion 170kg, elastomeric propylene yogurt liquid 300kg, coalescing agent 7kg, sterilization are added under 500rpm
Agent 5kg, defoaming agent 3kg, functional aid 35kg, dust-proofing agent 50kg, thickener 2kg, further increasing speed of agitator is
600rpm stirs 5min, filters and packages after detection is qualified as component A；Component A is uniformly mixed at 100: 6.2 in proportion with B component
Aqueous, environmental protective plastic cement race track adhesive can be obtained.
Embodiment two:
430kg water is added in stirring container, the dispersion of 7kg acrylate copolymer is added in the case where speed of agitator is 300rpm
Then agent, hydroxyethyl cellulose 16kg, antifreezing agent 20kg, fungicide 6kg, defoaming agent 3kg, fully dispersed 20min turn in stirring
Speed is that epoxy-acrylic hybridisation emulsion 130kg, elastomeric propylene yogurt liquid 280kg, coalescing agent 6kg, sterilization are added under 500rpm
Agent 6kg, defoaming agent 4kg, functional aid 35kg, dust-proofing agent 55kg, thickener 2kg, further increasing speed of agitator is
600rpm stirs 5min, filters and packages after detection is qualified as component A；Component A is mixed at 100: 5.41 in proportion with B component
It is even to obtain aqueous, environmental protective plastic cement race track adhesive.
Embodiment three:
218kg water is added in stirring container, the dispersion of 7kg acrylate copolymer is added in the case where speed of agitator is 300rpm
Then agent, hydroxyethyl cellulose 12kg, antifreezing agent 20kg, fungicide 6kg, defoaming agent 3kg, fully dispersed 20min turn in stirring
Speed is that epoxy-acrylic hybridisation emulsion 260kg, elastomeric propylene yogurt liquid 350kg, coalescing agent 9kg, sterilization are added under 500rpm
Agent 6kg, defoaming agent 4kg, functional aid 40kg, dust-proofing agent 60kg, thickener 5kg, further increasing speed of agitator is
600rpm stirs 5min, filters and packages after detection is qualified as component A；Component A is mixed at 100: 8.05 in proportion with B component
It is even to obtain aqueous, environmental protective plastic cement race track adhesive.
Comparative example one: application publication number is the Chinese patent of CN105038684A.
Comparative example two:
380kg water is added in stirring container, the dispersion of 5kg acrylate copolymer is added in the case where speed of agitator is 300rpm
Then agent, hydroxyethyl cellulose 15kg, antifreezing agent 20kg, fungicide 5kg, defoaming agent 3kg, fully dispersed 20min turn in stirring
Speed is that epoxy-acrylic hybridisation emulsion 470kg, coalescing agent 7kg, fungicide 5kg, defoaming agent 3kg, function are added under 500rpm
Property auxiliary agent 35kg, dust-proofing agent 50kg, thickener 2kg, further increasing speed of agitator is 600rpm, stirs 5min, and detection is qualified
After filter and package as component A；Component A and B component are uniformly mixed can obtain aqueous, environmental protective plastic cement race track glue at 100: 6.2 in proportion
Stick.
Comparative example three:
380kg water is added in stirring container, the dispersion of 5kg acrylate copolymer is added in the case where speed of agitator is 300rpm
Then agent, hydroxyethyl cellulose 15kg, antifreezing agent 20kg, fungicide 5kg, defoaming agent 3kg, fully dispersed 20min turn in stirring
Speed is that elastomeric propylene yogurt liquid 470kg, coalescing agent 7kg, fungicide 5kg, defoaming agent 3kg, functionality are added under 500rpm to help
Agent 35kg, dust-proofing agent 50kg, thickener 2kg, further increasing speed of agitator is 600rpm, stirs 5min, mistake after detection is qualified
Filter is packaged as component A；Component A and B component are uniformly mixed can obtain aqueous, environmental protective plastic cement race track gluing at 100: 6.2 in proportion
Agent.
Plastic cement race track sample preparation: after component A, B component are mixed according to the ratio uniform in embodiment, in addition EPDM rubber
Glue particle is constructed.
Testing index:
(1) T/31010100-C003-2016 " school's athletic ground plastic coat limits of harmful substances " liquid portion.
(2) impact absorbing: the ability absorbed using impact absorption tester detecting field Ground shock waves.It is 20 kilograms by quality
Weight is freely fallen on an anvil, and power is transmitted to ergograph bottom by spring by anvil, and ergograph is pacified by spherical pan
Mounted in ground.Ergograph is made of strength sensor, and the maximum value of impact return force can be recorded in impact process.It should
Maximum value on firm ground (such as concrete) measured by data be compared, while calculate synthetic surface impact return
The percentage of active force.
(3) VERTICAL DEFORMATION: using the vertical deformation in vertical deformation tester detection place.The weight for being 20 kilograms by quality
Under fall on spring, load is transmitted to the ergograph for being placed on detected material surface by spring, includes a power in ergograph
Quantity sensor, sensor can record the increment of strength in impact process, pass through the deformation intake device of ergograph two sides
Average measures the deflection on detected material surface.
(4) tensile strength and elongation at break: the measurement of the method as defined in GB/T1.654, according to the rules in middle Appendix D
D3.1 prepares sample, and control tensile speed is 100 ± 10mm/min.
(5) fire-retardant: to be carried out according to annex E method in " national plastic cement race track testing requirements and technical standard ".
By upper table it is found that using adhesive prepared by the present embodiment be laid with plastic cement race track, have optimal safety,
The feature of environmental protection；Meanwhile for comparative example two, comparative example three, the tensile strength and fracture for substantially increasing plastic cement race track are stretched
Long rate, enhance its service performance,
This specific embodiment is only explanation of the invention, is not limitation of the present invention, those skilled in the art
Member can according to need the modification that not creative contribution is made to the present embodiment after reading this specification, but as long as at this
All by the protection of Patent Law in the scope of the claims of invention.
Claims (7)
1. a kind of aqueous, environmental protective plastic cement race track adhesive, including component A and B component；
The component A includes the substance of following weight percent meter: 19% ~ 48% deionized water, 0.3% ~ 0.8% dispersing agent, 0.5% ~
0.7% defoaming agent, 0.2% ~ 0.5% thickener, 1% ~ 2% hydroxyethyl ether cellulose, 0.5% ~ 1% coalescing agent, 40% ~ 60% aqueous third
Olefin(e) acid ester lotion, 0.5% ~ 2% fungicide；
The B component relative to component A include following weight percent based on substance: 5% ~ 10% amine curing agent；
The water-and acrylate lotion is epoxy-acrylic hybridisation emulsion and elastomeric propylene acid latex composite compounding, wherein epoxy-the third
Accounting of the olefin(e) acid hybridisation emulsion in water-and acrylate lotion is 30% ~ 40%.
2. aqueous, environmental protective plastic cement race track adhesive according to claim 1, it is characterised in that: the dispersing agent is acrylic acid
One or more of ester copolymer, phenylethylene-maleic anhydride polymer, polycarboxylic-acid dispersing agent.
3. aqueous, environmental protective plastic cement race track adhesive according to claim 1, it is characterised in that: further include 3% ~ 4% functionality
Auxiliary agent, the functional aid are the organosilicon performed polymer of acrylic acid functionalized.
4. aqueous, environmental protective plastic cement race track adhesive according to claim 3, it is characterised in that: further include 1% ~ 3% antifreezing agent.
5. aqueous, environmental protective plastic cement race track adhesive according to claim 4, it is characterised in that: further include 5% ~ 6% dust-proof
Agent, the dust-proofing agent select fumed silica.
6. a kind of preparation method of aqueous, environmental protective plastic cement race track adhesive as claimed in claim 5, it is characterised in that including such as
Lower step:
(1) it dissolves: 0.3% ~ 0.8% dispersing agent, 0.5% ~ 0.7% defoaming agent, 1% ~ 3% antifreezing agent, 0.5% ~ 2% sterilization agent aid is added
Enter into 19% ~ 48% deionized water, 1% ~ 2% hydroxyethyl ether cellulose is then added, adjusting revolving speed is 500 ~ 1000rpm, dispersion
Cellulose paste is made in 15 ~ 25min；
(2) preparation of component A: being added 40% ~ 60% water-and acrylate lotion in the cellulose paste that dispersion is completed, 500 ~
Be stirred under the conditions of 1000rpm, and be added 0.5% ~ 0.7% defoaming agent, 3% ~ 4% functional aid, 5% ~ 6% dust-proofing agent, 0.2% ~
0.5% thickener and 0.5% ~ 1% coalescing agent, package spare after mixing；
(3) preparation of adhesive: component A and B component mix in proportion.
7. the preparation method of aqueous, environmental protective plastic cement race track adhesive according to claim 6, it is characterised in that: step (1)
Middle adjusting solution temperature is 35 ~ 40 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710106018.3A CN106867431B (en) | 2017-02-25 | 2017-02-25 | Aqueous, environmental protective plastic cement race track adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710106018.3A CN106867431B (en) | 2017-02-25 | 2017-02-25 | Aqueous, environmental protective plastic cement race track adhesive and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106867431A CN106867431A (en) | 2017-06-20 |
| CN106867431B true CN106867431B (en) | 2019-01-01 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710106018.3A Active CN106867431B (en) | 2017-02-25 | 2017-02-25 | Aqueous, environmental protective plastic cement race track adhesive and preparation method thereof |
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| Country | Link |
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| CN107118728A (en) * | 2017-06-22 | 2017-09-01 | 合肥月煌新型装饰材料有限公司 | It is a kind of for adhesive of runway and preparation method thereof |
| CN110777603B (en) * | 2019-10-26 | 2022-02-22 | 苏州大乘环保新材有限公司 | Construction method of environment-friendly water-based all-plastic runway and environment-friendly water-based all-plastic runway |
| CN111138842A (en) * | 2019-12-30 | 2020-05-12 | 杭州和诚塑胶工程有限公司 | Environment-friendly plastic track and preparation method thereof |
| CN111925752B (en) * | 2020-07-07 | 2021-11-05 | 林俊贤 | Adhesive for high-temperature photoelectric semiconductor material and preparation method thereof |
| CN111732403B (en) * | 2020-07-30 | 2020-11-20 | 苏州大乘环保新材有限公司 | Moulding color pavement coating |
| CN114149771B (en) * | 2021-11-26 | 2023-02-10 | 苏州大乘环保新材有限公司 | Aqueous EAU high-environment-friendly synthetic athletic ground material adhesive and preparation method thereof |
| CN114292608A (en) * | 2022-02-18 | 2022-04-08 | 大茂环保新材料股份有限公司 | Water-based environment-friendly runway surface layer adhesive and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103205224A (en) * | 2012-08-30 | 2013-07-17 | 湖北航天化学技术研究所 | Acrylate emulsion laminating adhesive, and preparation method and application thereof |
| JP5695966B2 (en) * | 2011-05-10 | 2015-04-08 | 日本電信電話株式会社 | Interest estimation apparatus, method and program |
| CN105367695A (en) * | 2014-08-18 | 2016-03-02 | 齐鲁工业大学 | High-temperature-curable one-component epoxy-modified acrylate emulsion |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5695966A (en) * | 1979-12-28 | 1981-08-03 | Matsumoto Seiyaku Kogyo Kk | Two-pack composition and adhesive bonding therewith |
-
2017
- 2017-02-25 CN CN201710106018.3A patent/CN106867431B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5695966B2 (en) * | 2011-05-10 | 2015-04-08 | 日本電信電話株式会社 | Interest estimation apparatus, method and program |
| CN103205224A (en) * | 2012-08-30 | 2013-07-17 | 湖北航天化学技术研究所 | Acrylate emulsion laminating adhesive, and preparation method and application thereof |
| CN105367695A (en) * | 2014-08-18 | 2016-03-02 | 齐鲁工业大学 | High-temperature-curable one-component epoxy-modified acrylate emulsion |
Non-Patent Citations (3)
| Title |
|---|
| 丙烯酸酯液体橡胶改性环氧树脂胶粘剂的研究;孔杰 等;《环氧树脂胶粘剂》;20021231;第23卷(第6期);第29-32页 |
| 新型双组分丙烯酸环氧酯胶粘剂的制备与性能研究;黄斌全 等;《粘接》;20121231(第12期);第65-67页 |
| 环氧_丙烯酸酯类复合水性涂料的研究进展;孙绍晖 等;《化工进展》;20041231;第23卷(第9期);第984-989页 |
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