CN106867234A - Road normal-temperature reaction type high-viscosity chromatic bitumen based on the emulsifiable Isocyanate prepolymers body of water - Google Patents
Road normal-temperature reaction type high-viscosity chromatic bitumen based on the emulsifiable Isocyanate prepolymers body of water Download PDFInfo
- Publication number
- CN106867234A CN106867234A CN201710101061.0A CN201710101061A CN106867234A CN 106867234 A CN106867234 A CN 106867234A CN 201710101061 A CN201710101061 A CN 201710101061A CN 106867234 A CN106867234 A CN 106867234A
- Authority
- CN
- China
- Prior art keywords
- parts
- component
- road
- reaction type
- temperature reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
- C08L75/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/26—Bituminous materials, e.g. tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/482—Mixtures of polyethers containing at least one polyether containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/6692—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/34
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/721—Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
- C08G18/724—Combination of aromatic polyisocyanates with (cyclo)aliphatic polyisocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
- C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/0075—Uses not provided for elsewhere in C04B2111/00 for road construction
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
A kind of road normal-temperature reaction type high-viscosity chromatic bitumen based on the emulsifiable Isocyanate prepolymers body of water, it is related to a kind of road cementitious matter pitch, the road includes base-material component and cross-linking agent component with normal-temperature reaction type high-viscosity chromatic bitumen, and described base-material component and the weight fraction of each component are：0 15 parts of 10 30 parts of rubber oil, 10 40 parts of chloro palm oil methyl ester, 1 15 parts of dimethyl carbonate, 01 parts of dispersant, 01 parts of defoamer, 1 10 parts of SBS resins, 5 25 parts of C5 Petropols, 5 25 parts of C9 Petropols, 5 25 parts of polyamide, 1 15 parts of hydroxy acryl acid resin, 1 25 parts of kaolin, 1 25 parts of calcium carbonate, 01 parts of ultra-violet absorber and toner；The response type chromatic cementing agent high-temperature behavior is strong, heat endurance is good, adhesiveness is strong, pliability good, anti-water damage property is strong, and preparation method is simple, mats formation easily, is particularly suitable for the occasions such as porous pavement and mats formation to use.
Description
Technical field：
The present invention relates to a kind of pitch, and in particular to a kind of road based on the emulsifiable Isocyanate prepolymers body of water is anti-with normal temperature
Answer type high-viscosity chromatic bitumen.
Background technology：
Color asphalt, also known as chromatic cementing agent, are to imitate asphalt component, using various petrochemicals and high score
Sub- material modification agent blending and modifying is formed, the characteristics of with stable performance, lovely luster, good pavement performance.It is primarily adapted for use in green
Mating formation for all kinds of chronic systemics such as road, cycle track, pavement, landscape garden road and landscape road and porous pavement, it is special
Trade mark product can also be applied to runway, bus special lane, crossing.Traditional color asphalt system needs special when mating formation
Equipment of mating formation, limit it in narrow green road, the pavement construction of landscape road；In addition, traditional color asphalt system
Wide bed when filling as plain asphalt, it is necessary to high-temperature digestion, the cost that causes to mat formation can be in any more, and not environmentally, on solving
Technical problem is stated, spy proposes a kind of new technical scheme.
The content of the invention：
The invention aims to the weak point for overcoming above-mentioned prior art to exist, and a kind of water that is based on of offer can breast
Change the road normal-temperature reaction type high-viscosity chromatic bitumen of Isocyanate prepolymers body.
The technical solution adopted by the present invention is：A kind of road normal-temperature reaction type based on the emulsifiable Isocyanate prepolymers body of water
High-viscosity chromatic bitumen, the road includes base-material component and cross-linking agent component, described base-material with normal-temperature reaction type high-viscosity chromatic bitumen
The weight fraction of component and each component is：Rubber oil 10-30 parts, 10-40 parts of chloro palm oil methyl ester, dimethyl carbonate 1-15
Part, dispersant 0-1 part, defoamer 0-1 parts, 1-10 parts of SBS resins, 5-25 parts of C5 Petropols, 5-25 parts of C9 Petropols, gather
Amide resin 5-25 parts, hydroxy acryl acid resin 1-15 parts, kaolin 1-25 parts, calcium carbonate 1-25 parts, ultra-violet absorber
0-1 parts and toner 0-15 parts；Described cross-linking agent component and the weight fraction of each component are：The 30-50 of PPG 3000
Part, 10-20 parts of PPG 2000,1-10 parts of polyetheramine ED600,1-15 parts of chloro palm oil methyl ester, TDI 0-10 parts,
MDI 0-10 parts, HDI 0-10 parts, organic bismuth catalyst 0-0.2 parts, DMBA 1-5 parts, 1-5 parts of Slimer NCO Di-100,
DMDEE 0-1 parts and UV resistant agent 0-1 parts；Its technical indicator is：More than 99% solid content, 3.0-8.2%NCO contents, meet
Water energy self-emulsifying.Film forming matter adhesion strength is high, and elasticity is good.
Road normal-temperature reaction type high-viscosity chromatic bitumen includes base-material component and cross-linking agent component, described base-material component and
The weight fraction of each component is：Rubber oil 15-20 parts, 15-30 parts of chloro palm oil methyl ester, dimethyl carbonate 5-10 parts, dispersion
Agent 0.1-0.5 parts, defoamer 0.1-0.5 parts, it is 5-8 parts of SBS resins, 6-20 parts of C5 Petropols, 6-20 parts of C9 Petropols, poly-
Amide resin 6-20 parts, hydroxy acryl acid resin 2-10 parts, kaolin 2-10 parts, calcium carbonate 2-10 parts, ultra-violet absorber
0.1-0.5 parts and toner 1-10 parts；Described cross-linking agent component and the weight fraction of each component are：The 35- of PPG 3000
45 parts, 15-19 parts of PPG 2000,5-8 parts of polyetheramine ED600,5-10 parts of chloro palm oil methyl ester, TDI 1-5 parts,
MDI 1-5 parts, 1 part of HDI, 0.2 part of organic bismuth catalyst, DMBA 2-3 parts, 2-4 parts of Slimer NCO Di-100, DMDEE
0.5 part and 0.5 part of UV resistant agent, its technical indicator is：More than 99% solid content, 3.0-8.2%NCO contents, meet water energy certainly
Emulsification.
The synthesis technique of described base-material component is：Rubber oil 15.87 is added in the reactor equipped with high speed agitator
Part, 19.05 parts of chloro palm oil methyl ester, 9.52 parts of dimethyl carbonate, 0.2 part of dispersant and 0.1 part of defoamer, start stirring
Device, slow 2.44 parts of input SBS resins, 9.52 parts of C5 Petropols, 9.52 parts of C9 Petropols, 9.76 parts of polyamide,
4.76 parts of hydroxy acryl acid resin, 6.35 parts of kaolin, 6.35 parts of calcium carbonate, 6.35 parts of red toner, closed reactor are high
Speed stirring mixing 1-2 hours, obtains the mixture of pulpous state, finally adds 0.2 part of ultra-violet absorber, is uniformly mixed, and goes out
Material is packaged to be the 100 parts of road of liquid pulpous state normal-temperature reaction type high-viscosity chromatic bitumen base-materials.
The synthesis technique of described crosslinking agent is：40 parts of PPGs, 3000,15 parts of polyethers are put into four-hole boiling flask
2000,5 parts of polyetheramine ED600 of polyalcohol and 5 parts of chloro palm oil methyl esters, open agitating device and are stirred, and by heating
Device is heated to 105 degree, while being vacuumized 60 minutes by vacuum machine, then reduces the temperature to 85 degree by heat sink, throws
Enter 3 parts of TDI, the temperature of four-hole boiling flask is reacted 2 hours between being maintained at 75-85 degree, then put into 8 parts of MDI, react 1 hour, throw
Enter 12 parts of HDI, 0.03 part of organic bismuth catalyst keeping temperature 75-85 degree to react 2 hours, obtain base polyurethane prepolymer for use as；Continue to throw
Enter 3 parts of DMBA, keeping temperature 75-85 degree reacts 3 hours, be that base polyurethane prepolymer for use as grafting can be led to the hydroxy-acid group of Water-borne modification
It is double isocyanate-terminated to cross heat sink and 8 parts of Slimer NCO Di-100 will be put into below 60 degree of greenhouse cooling, after cooling
Organosilicon performed polymer, can improve intensity and water resistance after solidification, 0.5 part of DMDEE is that the nertralizer of hydroxy-acid group (is again HDI
Curing accelerator) and 0.5 part of uvioresistant additive, after being stirred by agitating device discharging be packaged to be 100 parts it is complete
The emulsifiable component A with elastomeric Isocyanate prepolymers body of complete not solvent-laden, water, isocyanate content is 3.0-
8.2%.
Beneficial effects of the present invention are：The pitch system is divided into base-material component and cross-linking agent component, the double-component asphalt series
Wide bed need to only mix in proportion post blend graded aggregate when filling, and pave, solidify, it is to avoid traditional asphalt paves needs
The technique of special-purpose machinery, high-temperature digestion so that over long distances, that small lot is mated formation is very easy.The response type chromatic cementing agent high temperature
Performance is strong, heat endurance is good, adhesiveness is strong, pliability good, anti-water damage property is strong, and preparation method is simple, mats formation easily, especially
It is adapted to the occasions such as porous pavement to use.
Specific embodiment：
The present invention is further described in conjunction with specific embodiments：
Embodiment one：
A kind of road normal-temperature reaction type high-viscosity chromatic bitumen based on the emulsifiable Isocyanate prepolymers body of water, the road normal temperature
Response type high-viscosity chromatic bitumen includes base-material component and cross-linking agent component, described base-material component and the weight fraction of each component
For：10 parts of rubber oil, 10 parts of chloro palm oil methyl ester, 1 part of dimethyl carbonate, 1 part of dispersant, 1 part of defoamer, SBS resins 1
Part, 5 parts of C5 Petropols, 5 parts of C9 Petropols, 5 parts of polyamide, 1 part of hydroxy acryl acid resin, 1 part of kaolin, carbon
1 part of 1 part of sour calcium, 0.5 part of ultra-violet absorber and toner；Described cross-linking agent component and the weight fraction of each component are：Polyethers
3,000 30 parts of polyalcohol, 2,000 10 parts of PPG, 1 part of polyetheramine ED600,1 part of chloro palm oil methyl ester, TDI 1
Part, 1 part of MDI, 1 part of HDI, 1 part of organic bismuth catalyst, 1 part of DMBA, 1 part of Sl imer NCO Di-100,1 part of DMDEE
And 1 part of UV resistant agent.
Embodiment two：
A kind of road normal-temperature reaction type high-viscosity chromatic bitumen based on the emulsifiable Isocyanate prepolymers body of water, the road normal temperature
Response type high-viscosity chromatic bitumen includes base-material component and cross-linking agent component, described base-material component and the weight fraction of each component
For：20 parts of rubber oil, 30 parts of chloro palm oil methyl ester, 10 parts of dimethyl carbonate, 0.5 part of dispersant, 0.5 part of defoamer, SBS trees
5 parts of fat, 10 parts of C5 Petropols, 15 parts of C9 Petropols, 20 parts of polyamide, 10 parts of hydroxy acryl acid resin, kaolinite
10 parts of 10 parts of soil, 10 parts of calcium carbonate, 0.5 part of ultra-violet absorber and toner；Described cross-linking agent component and the weight of each component
Fraction is：3,000 40 parts of PPG, 2,000 15 parts of PPG, 5 parts of polyetheramine ED600, chloro palm oil methyl ester
8 parts, 5 parts of TDI, 5 parts of MDI, 5 parts of HDI, 0.1 part of organic bismuth catalyst, 3 parts of DMBA, Sl imer NCO Di-100 3
0.5 part of part, 0.5 part of DMDEE and UV resistant agent.
Embodiment three：
A kind of road normal-temperature reaction type high-viscosity chromatic bitumen based on the emulsifiable Isocyanate prepolymers body of water, the road normal temperature
Response type high-viscosity chromatic bitumen includes base-material component and cross-linking agent component, described base-material component and the weight fraction of each component
For：30 parts of rubber oil, 40 parts of chloro palm oil methyl ester, 15 parts of dimethyl carbonate, 1 part of dispersant, 1 part of defoamer, SBS resins 10
Part, 25 parts of C5 Petropols, 25 parts of C9 Petropols, 25 parts of polyamide, 15 parts of hydroxy acryl acid resin, kaolin 25
Part, 25 parts of calcium carbonate, 1 part of ultra-violet absorber and 15 parts of toner；Described cross-linking agent component and the weight fraction of each component are：
3,000 50 parts of PPG, 2,000 20 parts of PPG, 10 parts of polyetheramine ED600,15 parts of chloro palm oil methyl ester,
10 parts of TDI, 10 parts of MDI, 10 parts of HDI, 0.2 part of organic bismuth catalyst, 5 parts of DMBA, 5 parts of Slimer NCO Di-100,
1 part of 1 part of DMDEE and UV resistant agent.
The flooring mode on colorful water-permeable road surface is：100 parts of road made above normal-temperature reaction type high-viscosity asphalt base-material is taken,
33 parts of crosslinking agent, is uniformly mixed, and mixes 4000 parts of basalt aggregates of 2-5mm diameters, after mixing and stirring, paves
On the soil layer of compacting, curing period 5-24 hour, is hardened in thickness requirement 30mm, superficial compaction, obtains the colour of high intensity flexible
High-viscosity asphalt porous pavement.
Using effect is tested：
This research is tested by 3000 squares of road surfaces place, is investigated this and is based on the emulsifiable Isocyanate prepolymers body of water
The road effect of normal-temperature reaction type high-viscosity chromatic bitumen each side.Test event standards of grading are：Very satisfied 5 points, it is satisfied with 4
Point, general 3 points, it is unsatisfied with 2 points, very dissatisfied 1 point.Wherein common group is common color bituminous paving；
| Test event | Embodiment one | Embodiment two | Embodiment three | Common group |
| High-temperature behavior | 4.8 | 4.9 | 4.7 | 3.0 |
| Heat endurance | 4.8 | 4.9 | 5.0 | 1.0 |
| Adhesiveness | 4.7 | 4.9 | 4.8 | 3.0 |
| Pliability | 4.7 | 4.9 | 4.9 | 3.0 |
| Anti-water damage | 4.7 | 4.9 | 4.8 | 2.0 |
| Mat formation speed | 5.0 | 4.9 | 4.9 | 4.0 |
In sum, the present invention its not only can effectively solve draw high-temperature behavior, heat endurance, adhesiveness, pliability,
Anti-water damage property and curing rate problem, and use safety and health.
For a person skilled in the art, other can be made various corresponding according to above technical scheme and design
Change and deformation, and all these change and deformation should all belong within the protection domain of the claims in the present invention.
Claims (4)
1. a kind of road normal-temperature reaction type high-viscosity chromatic bitumen based on the emulsifiable Isocyanate prepolymers body of water, it is characterised in that：
Road normal-temperature reaction type high-viscosity chromatic bitumen includes base-material component and cross-linking agent component, described base-material component and each component
Weight fraction is：Rubber oil 10-30 parts, 10-40 parts of chloro palm oil methyl ester, dimethyl carbonate 1-15 parts, dispersant 0-1 parts,
Defoamer 0-1 parts, 1-10 parts of SBS resins, 5-25 parts of C5 Petropols, 5-25 parts of C9 Petropols, polyamide 5-25 parts,
Hydroxy acryl acid resin 1-15 parts, kaolin 1-25 parts, calcium carbonate 1-25 parts, ultra-violet absorber 0-1 parts and toner 0-15
Part；Described cross-linking agent component and the weight fraction of each component are：30-50 parts of PPG 3000, PPG 2000
10-20 parts, 1-10 parts of polyetheramine ED600,1-15 parts of chloro palm oil methyl ester, TDI 0-10 parts, MDI 0-10 parts, HDI 0-
10 parts, organic bismuth catalyst 0-0.2 parts, DMBA 1-5 parts, 1-5 parts, DMDEE 0-1 parts of Slimer NCO Di-100 and anti-purple
0-1 parts of outside line agent；Its technical indicator is：More than 99% solid content, 3.0-8.2%NCO contents, meet water energy self-emulsifying.
2. the road based on the emulsifiable Isocyanate prepolymers body of water according to claim 1 is dripped with normal-temperature reaction type high-viscosity chromatic
It is blue or green, it is characterised in that：The road includes base-material component and cross-linking agent component, described base-material with normal-temperature reaction type high-viscosity chromatic bitumen
The weight fraction of component and each component is：Rubber oil 15-20 parts, 15-30 parts of chloro palm oil methyl ester, dimethyl carbonate 5-10
Part, dispersant 0.1-0.5 parts, defoamer 0.1-0.5 parts, 5-8 parts of SBS resins, 6-20 parts of C5 Petropols, C9 Petropols 6-
20 parts, polyamide 6-20 parts, hydroxy acryl acid resin 2-10 parts, kaolin 2-10 parts, calcium carbonate 2-10 parts, ultraviolet
Absorbent 0.1-0.5 parts and toner 1-10 parts；Described cross-linking agent component and the weight fraction of each component are：PPG
3000 35-45 parts, 15-19 parts of PPG 2000,5-8 parts of polyetheramine ED600,5-10 parts of chloro palm oil methyl ester,
TDI 1-5 parts, MDI 1-5 parts, 1 part of HDI, 0.2 part of organic bismuth catalyst, DMBA 2-3 parts, Slimer NCO Di-100 2-
0.5 part of 4 parts, 0.5 part of DMDEE and UV resistant agent, its technical indicator is：More than 99% solid content, 3.0-8.2%NCO contain
Amount, meets water energy self-emulsifying.
3. the normal-temperature reaction type viscous coloured silk high of the road based on the emulsifiable Isocyanate prepolymers body of water according to claim 1 and 2
Color pitch, it is characterised in that：The synthesis technique of described base-material component is：Rubber is added in the reactor equipped with high speed agitator
0.1 part of 15.87 parts of glue oil, 19.05 parts of chloro palm oil methyl ester, 9.52 parts of dimethyl carbonate, 0.2 part of dispersant and defoamer,
Agitator is started, slow 2.44 parts of input SBS resins, 9.52 parts of C5 Petropols, 9.52 parts of C9 Petropols, polyamide
9.76 parts, 4.76 parts of hydroxy acryl acid resin, 6.35 parts of kaolin, 6.35 parts of calcium carbonate, 6.35 parts of red toner is closed anti-
Kettle is answered, high-speed stirred mixes 1-2 hours, obtains the mixture of pulpous state, finally add 0.2 part of ultra-violet absorber, stirring mixing
Uniformly, discharging is packaged to be the 100 parts of road of liquid pulpous state normal-temperature reaction type high-viscosity chromatic bitumen base-materials.
4. the normal-temperature reaction type viscous coloured silk high of the road based on the emulsifiable Isocyanate prepolymers body of water according to claim 1 and 2
Color pitch, it is characterised in that：The synthesis technique of described crosslinking agent is：40 parts of PPGs are put into four-hole boiling flask
3000th, 15 parts of PPGs, 2000,5 parts of polyetheramine ED600 and 5 parts of chloro palm oil methyl esters, open agitating device and are stirred
Mix, and by heating devices heat to 105 degree, while vacuumize 60 minutes by vacuum machine, then by heat sink by temperature
Degree drops to 85 degree, puts into 3 parts of TDI, the temperature of four-hole boiling flask is reacted 2 hours between being maintained at 75-85 degree, then put into 8 parts
MDI, reacts 1 hour, and 12 parts of HDI of input, 0.03 part of organic bismuth catalyst keeping temperature 75-85 degree react 2 hours, obtain poly- ammonia
Ester performed polymer；Continue to put into 3 parts of DMBA, keeping temperature 75-85 degree reacts 3 hours, be that base polyurethane prepolymer for use as grafting can be with aqueous
The hydroxy-acid group of change, will put into 8 parts of Slimer NCO Di-100 below 60 degree of greenhouse cooling, after cooling by heat sink is
Double isocyanate-terminated organosilicon performed polymers, can improve intensity and water resistance after solidification, 0.5 part of DMDEE is hydroxy-acid group
Nertralizer (being again the curing accelerator of HDI) and 0.5 part of uvioresistant additive, after being stirred by agitating device discharge
It is packaged to be the component A with elastomeric Isocyanate prepolymers body that 100 parts are entirely free of solvent, that water is emulsifiable, isocyanide
Acid and esters content is 3.0-8.2%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710101061.0A CN106867234A (en) | 2017-02-23 | 2017-02-23 | Road normal-temperature reaction type high-viscosity chromatic bitumen based on the emulsifiable Isocyanate prepolymers body of water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710101061.0A CN106867234A (en) | 2017-02-23 | 2017-02-23 | Road normal-temperature reaction type high-viscosity chromatic bitumen based on the emulsifiable Isocyanate prepolymers body of water |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106867234A true CN106867234A (en) | 2017-06-20 |
Family
ID=59168029
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710101061.0A Pending CN106867234A (en) | 2017-02-23 | 2017-02-23 | Road normal-temperature reaction type high-viscosity chromatic bitumen based on the emulsifiable Isocyanate prepolymers body of water |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106867234A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107523066A (en) * | 2017-08-08 | 2017-12-29 | 浙江理工大学 | Permeable laying of roadway environment-protecting color cementitious matter and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2289681A (en) * | 1994-05-19 | 1995-11-29 | Nissin Kasei Co Limited | A binder composition for a colored pavement |
| CN103497481A (en) * | 2013-08-06 | 2014-01-08 | 苏州拓博琳新材料科技有限公司 | Colored asphalt cementing material and preparation method thereof |
| CN104628305A (en) * | 2015-01-22 | 2015-05-20 | 南京同安道路工程有限公司 | High-modulus colored asphalt mixture and preparation method thereof |
| CN106281194A (en) * | 2016-08-27 | 2017-01-04 | 惠州市腾威新材料有限公司 | A kind of Solvent-free high-elasticity isocyanates aqueous runway glue and preparation method thereof |
| CN106366288A (en) * | 2016-08-27 | 2017-02-01 | 惠州市腾威新材料有限公司 | Novel environmental-friendly runway material and preparation method thereof |
-
2017
- 2017-02-23 CN CN201710101061.0A patent/CN106867234A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2289681A (en) * | 1994-05-19 | 1995-11-29 | Nissin Kasei Co Limited | A binder composition for a colored pavement |
| CN103497481A (en) * | 2013-08-06 | 2014-01-08 | 苏州拓博琳新材料科技有限公司 | Colored asphalt cementing material and preparation method thereof |
| CN104628305A (en) * | 2015-01-22 | 2015-05-20 | 南京同安道路工程有限公司 | High-modulus colored asphalt mixture and preparation method thereof |
| CN106281194A (en) * | 2016-08-27 | 2017-01-04 | 惠州市腾威新材料有限公司 | A kind of Solvent-free high-elasticity isocyanates aqueous runway glue and preparation method thereof |
| CN106366288A (en) * | 2016-08-27 | 2017-02-01 | 惠州市腾威新材料有限公司 | Novel environmental-friendly runway material and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107523066A (en) * | 2017-08-08 | 2017-12-29 | 浙江理工大学 | Permeable laying of roadway environment-protecting color cementitious matter and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102408860B (en) | Flexible epoxy adhesive and application | |
| CN104610769B (en) | A kind of preparation method of high-strength cold laid asphaltic compound | |
| US20200040186A1 (en) | Asphalt concrete composition having improved waterproof performance by comprising sis, recycled asphalt aggregate, and fine powder aggregate with improved particle size, and construction method using the same | |
| MX2012007213A (en) | Composite pavement structures. | |
| CN107268434A (en) | One kind is applied to the flexible paving structure of the regional Steel Bridge Deck of damp and hot high temperature and construction method | |
| CN102796243B (en) | Polyurethane modified epoxy resin adhesive, and preparation method and application thereof | |
| SG184757A1 (en) | Method for producing mineral-bearing cover layers for floor coverings | |
| CN111500246A (en) | Solvent-free polyurethane adhesive for colored pavement and preparation method thereof | |
| CN107532059A (en) | Modified asphalt binder emulsion | |
| CN106007557A (en) | Environment-friendly water-based plastic track | |
| CN111393071A (en) | Antiskid layer material composition for permeable pavement and preparation method thereof | |
| CN109280320B (en) | Reaction type normal temperature color asphalt and preparation method and application thereof | |
| CN106867234A (en) | Road normal-temperature reaction type high-viscosity chromatic bitumen based on the emulsifiable Isocyanate prepolymers body of water | |
| CN103958441B (en) | The method repairing pavement system, the method particularly repairing open-pore asphalt | |
| CN108047949A (en) | Polyurethane-modified asphalt waterproofing paint for building and its production method | |
| CN106398186A (en) | Environment-friendly plastic slurry for sports ground and preparation method of environment-friendly plastic slurry | |
| KR102119742B1 (en) | Double Layer Asphalt Concrete Compositions Having Low Noise and Permeable Using Styrene Isoprene Styrene, Styrene Ethylene Butylene Styrene and Aggregate-powder of Improved Grain Size and Constructing Methods Using Thereof | |
| CN106867358B (en) | A kind of wear-resisting low noise type road surface repair layer and preparation method thereof | |
| KR102007726B1 (en) | Water-Impermeable Waterproof Asphalt Concrete Composition Comprising SIS And SBS And Constructing Methods Using Mixing System Device | |
| CN108341930A (en) | A kind of modified epoxy and its preparation method and application | |
| US20060047059A1 (en) | Coloring binder for pavement of a road and method for producing the same | |
| KR102119732B1 (en) | Modified-Asphalt Concrete Compositions for Pavement of Roads Using Styrene Isoprene Styrene, Styrene Ethylene Butylene Styrene and Aggregate-powder of Improved Grain Size and Constructing Methods Using Thereof | |
| CN107022198B (en) | A kind of bionical self-healing property pitch and preparation method thereof | |
| KR102132607B1 (en) | Modified-Resin Stone Mastic Asphalt Concrete Compositions Using Stylene Isoprene Stylene and Constructing Methods Using Thereof | |
| KR102119771B1 (en) | Middle Temperature Asphalt Compositions Having Low Noise and Permeable Using Styrene Isoprene Styrene, Styrene Ethylene Butylene Styrene and Aggregate-powder of Improved Grain Size and Constructing Methods Using Thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170620 |