CN106866169A - A kind of processing system of hazardous waste sludge recycling, method and the haydite produced using the system, method - Google Patents

A kind of processing system of hazardous waste sludge recycling, method and the haydite produced using the system, method Download PDF

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Publication number
CN106866169A
CN106866169A CN201710247866.6A CN201710247866A CN106866169A CN 106866169 A CN106866169 A CN 106866169A CN 201710247866 A CN201710247866 A CN 201710247866A CN 106866169 A CN106866169 A CN 106866169A
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sludge
haydite
belt conveyer
rotary kiln
additive
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CN106866169B (en
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何姗
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Liaoning Hengyu Environmental Protection Machinery Manufacturing Co Ltd
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Liaoning Hengyu Environmental Protection Machinery Manufacturing Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/009—Porous or hollow ceramic granular materials, e.g. microballoons
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/02—Biological treatment
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • C02F11/122—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering using filter presses
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/14—Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/131—Inorganic additives
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C04B33/1321—Waste slurries, e.g. harbour sludge, industrial muds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/16—Nature of the water, waste water, sewage or sludge to be treated from metallurgical processes, i.e. from the production, refining or treatment of metals, e.g. galvanic wastes
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/02—Odour removal or prevention of malodour
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00—Technologies relating to the processing of minerals
    • Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Structural Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Materials Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Dispersion Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The invention discloses a kind of processing system of hazardous waste sludge recycling, method and utilize the system, the haydite of method production, processing system kiln liner of the present invention uses nanometer refractory material, reduce heat-energy losses, improve heat utilization rate and reduce production cost, at the same time a complete set of equipment system of the present invention uses PLC Automatic Controls, with efficiency high, the advantage of energy-conservation, the present invention not only saves and processes hazardous waste sludge with burying method and waste national soil resource in large quantities and with the cement required for solidification method, pitch, the problem of the resources such as additive, and thoroughly solve the problem of hazardous waste sludge zero-emission and secondary pollution, hazardous waste sludge is set to turn waste into wealth, realize the strategic objective of innoxious resource reutilization.

Description

A kind of processing system of hazardous waste sludge recycling, method and using the system, side The haydite of method production
Technical field
The invention belongs to hazardous waste sludge resource and dangerous waste and solid waste recycling economy technical field, and in particular to a kind of dangerous waste Processing system that recycling sludge is utilized, method and the haydite produced using the system, method.
Background technology
At 60,000,000 to 100,000,000 tons, not only landfill yard takes a large amount of soils to the dangerous waste total amount that China produces every year at present, and And the hidden danger of secondary pollution is there is, the safety to land resources and people's life causes serious threat.According to China " 13 Five " planning and country carry out the innoxious utilization of resources by environmental law to the increasingly tighter requirement of efforts at environmental protection to hazardous waste sludge, The problem of hazardous waste sludge secondary pollution and zero-emission is thoroughly solved, it is imperative.
The means of existing treatment hazardous waste sludge are mainly physical method and chemical method, and physical method is filled out including safe soil Bury, burning method, solidification method, safe landfill is a kind of improved sanitary landfills method, also referred to as safe chemistry landfill, It is mainly used to dispose hazardous waste, has the disadvantage that landfill yard will must need not away from residential block, the landfill yard of reply because of sedimentation Disconnected maintenance, landfill may produce inflammable, explosive or poisonous gas in the hazardous waste in underground by decomposing, and need to be controlled System and treatment, and take and waste land resource；Burning method is the combined process of pyrolytic and deep oxidation, and shortcoming one is Burning can produce substantial amounts of sour gas and imperfect combustion quarrel, there is secondary pollution, and two is that investment and operation cost are high；Gu Change method be the coagulating agents such as cement, plastics, waterglass, pitch are subject to hazardous waste sludge it is mixing cured so that institute in hazardous waste sludge The harmful substance for containing is enclosed in firming body and is not invaded out, has the disadvantage there is secondary pollution risk, occupies and waste soil, cost compared with It is high.Chemical method utilizes the chemical property of hazardous waste sludge, by modes such as acid-base neutralization, redox and precipitations, by nuisance Matter is converted into harmless final product, and shortcoming is simply to have carried out harmless treatment, not by hazardous waste sludge recycling, Also there is secondary occupation of land and pollution problem.
The content of the invention
The present invention is a kind of by hazardous waste sludge harmless treatment and recycling, reaches the technology and danger of zero-emission Waste sludge cooperates with harmless treatment and produces the technology of the recycling economy of the resource reutilization of haydite environment-friendly products with solid waste powder Technique and method.
Technical scheme is as follows：
A kind of processing system of hazardous waste sludge recycling, the system includes sludge organism processing pond 1, dehydration filter press 2nd, pulverizer 3, deodorant, sterilized high-frequency microwave frequency conversion, dewatering integrated processing equipment 4, sludge measuring chute 5, solid waste powder metering material Storehouse 6, additive metering feed bin 7, batch mixing measures feed bin 8, rolls mixing plant 9, comminutor 10, screen-dividing machine 11, dry distillation charring time Rotary kiln 12, bag-type dust equipment 121, desulfurization washing tower 122, denitration device 123, active carbon deodorizing equipment 124, plasma are deodorant Equipment 125, light catalase deodorizing device 126, exhaust emissions smokestack 127 up to standard, coloured glaze glazing rotary kiln 13, haydite cooling sorter 14th, metering haydite warehouse 15；Described sludge organism processing pond 1 is connected by waterpipe with dehydration filter press 2；Dehydration filter press 2nd, pulverizer 3, deodorant, sterilized high-frequency microwave frequency conversion, dewatering integrated processing equipment 4, sludge measuring chute 5, batch mixing metering feed bin 8th, mixing plant 9, comminutor 10, screen-dividing machine 11, dry distillation charring rotary kiln 12 is rolled to be sequentially connected by belt conveyer；Coloured glaze The front end sleeve of glazing rotary kiln 13 is in the rear end of dry distillation charring rotary kiln 12；Solid waste powder metering feed bin 6, additive metering feed bin 7 Feed bin 8 is measured by belt conveyer and batch mixing respectively to be connected；Bag-type dust equipment 121 is turned round by wind pipeline with dry distillation charring The kiln hood connection of kiln 12；Bag-type dust equipment 121, desulfurization washing tower 122, denitration device 123, active carbon deodorizing equipment 124 are led to Wind pipeline is crossed to be sequentially connected；Active carbon deodorizing equipment 124, plasma deodorizing device 125, light catalase deodorizing device 126 pass through gas Body communicating pipe is sequentially connected；Light catalase deodorizing device 126 is connected by wind pipeline with exhaust emissions smokestack 127 up to standard；On coloured glaze Glaze rotary kiln 13, haydite cooling sorter 14, metering haydite warehouse 15 are sequentially connected by belt conveyer.
Wherein, the described a diameter of 700-3400mm of dry distillation charring rotary kiln 12, length is 33000-36000mm, in kiln Lining uses nanometer refractory material；The a diameter of 900-3600mm of coloured glaze glazing rotary kiln 13, length is 33000-3600mm, kiln liner Using nanometer refractory material.
The method that hazardous waste sludge recycling is carried out using the processing system of the hazardous waste sludge recycling, including Following steps：
(1) deodorant, antivirus, sterilization treatment, the useless dirt of control are carried out to hazardous waste sludge HW12 or HW17 using microbial technique In the range of 65-95 DEG C, process time is 5-10 seconds to the temperature control of mud；Described HW12 refers to the waste of dyestuff or coating, The sludge produced i.e. after chrome yellow, chrome orange pigment, chrome green pigment, the one of which of iron blue pigment or several wastewater treatments； HW17 refers to carry out sensitized treatment and gold-plated, copper facing, zinc-plated, chromium plating one of which or several etc. using zinc chloride, ammonium chloride etc. The sludge that wastewater treatment is produced；
By the temperature control of hazardous waste sludge at 65-95 DEG C, process time 5-10 seconds, the cell membrane of organic matter can be promoted rapid Rupture, makes under the organic matter catalytic action of enzyme in the cell entered in microbial cell, and microorganism carries out oxidation Decomposition to it, It is eventually converted into H2O、CO2Deng the inorganic matter of stabilization.
(2) hazardous waste sludge after step (1) treatment is added into sludge dehydrating agent, is pumped into being dehydrated press filtration with high pressure sludge Machine 2, makes moisture percentage in sewage sludge be down to 30-60%, and sludge cake is obtained after dehydration；
(3) sludge cake after step (2) gained press filtration is transported into pulverizer 3 with belt conveyer to be crushed；
(4) by step (3) crush after sludge by belt conveyor be sent to high-frequency microwave frequency conversion it is deodorant, sterilized, dehydration Integrated equipment for wastewater treatment 4, is killed virus, is sterilized, and is reached《Pollutant catabolic gene standard in agricultural sludge》Etc. (GB4284) country and The existing relevant agricultural standards in place and regulation；
Sludge after present invention treatment must reach stabilisation and innoxious standard, mistake of the heavy metal in postorder sintering ceramsite To be cured in haydite in journey, safety and stability is never separated out, non-secondary pollution.And reach《Pollutant catabolic gene in agricultural sludge Standard》(GB4284) the existing relevant agricultural standards of country and place and the regulation such as.
(5) step (4) gained sludge belt conveyer is transported to sludge measuring chute 5, then by sludge, solid waste powder, add Plus agent is sent to batch mixing from sludge measuring chute 5, solid waste powder metering feed bin 6, additive metering feed bin 7 by belt conveyer respectively Metering feed bin 8 mixes, and is transported to mixed qualified material by belt conveyer and rolls mixing plant 9 and fully rolled After stir, then granulated in transporting to comminutor 10 by belt conveyer, then screen-dividing machine is sent to by belt conveyer 11 carry out sub-sieve；
(6) the qualified haydite raw material ball of step (5) gained is transported into dry distillation charring rotary kiln 12 by belt conveyer to enter Row dry distillation charring, and will through destructive distillation and charing after raw material ball carry out coloured glaze glazing sintering into coloured glaze glazing rotary kiln 13 after into Be haydite, then by belt conveyer deliver to haydite cool down sorter 14 sorted, underproof haydite belt conveyer Between returning to raw material storage, qualified haydite is transported in metering haydite storage bin 15 by belt conveyer and is stored, do not conformed to The haydite raw material ball of lattice returns to comminutor 10 and granulates again by belt conveyer, wherein, described qualified haydite raw material ball Refer to that, from 2 meters of eminence freely falling bodies to ground, raw material ball is indeformable by it, be qualified without damaging.
Wherein, the sludge dehydrating agent described in step (2) is polyacrylamide sludge dehydrating agent.
Used as further technical scheme of the invention, the running temperature of dry distillation charring rotary kiln 12 is 150- in step (6) 850 DEG C, rotating speed turns for 4-8 per minute；The running temperature of coloured glaze glazing rotary kiln 13 is 900-1250 DEG C, and rotating speed is 4- per minute 8 turns.
A kind of haydite of utilization methods described production, the percentage by weight of the haydite each component is respectively：Sludge 30%- 75%, solid waste powder 15%-60%, additive 10%-20%.
Described additive can be the mixture of bentonite and waterglass, and bentonitic adding proportion is the 15- of total amount 25%, waterglass adding proportion is the 75-85% of total amount；Can be the mixture of crushed crude pearlite and waterglass, crushed crude pearlite Adding proportion is the 15-25% of total amount, and waterglass adding proportion is the 75-85% of total amount；Can be bentonite, crushed crude pearlite with The mixture of waterglass, bentonite is the 15-25% of total amount with total adding proportion of crushed crude pearlite, and waterglass adding proportion is total The 75-85% of amount；Bentonite is more than 200 mesh with the granularity of crushed crude pearlite.
Described additive can be waterglass；Can be the mixture of bentonite and waterglass, bentonitic addition ratio Example is the 15-25% of total amount, and waterglass adding proportion is the 75-85% of total amount；It can be the mixing of crushed crude pearlite and waterglass Thing, the adding proportion of crushed crude pearlite is the 15-25% of total amount, and waterglass adding proportion is the 75-85% of total amount；It can be swelling The mixture of soil, crushed crude pearlite and waterglass three, bentonite is the 15-25% of total amount with total adding proportion of crushed crude pearlite, Waterglass adding proportion is the 75-85% of total amount；Bentonite is more than 200 mesh with the granularity of crushed crude pearlite.
Described solid waste Powder Particle Size is more than 200 mesh, be one or more in mine tailing, metallurgical ground-slag, building waste powder Mixture.
Described sludge, solid waste powder, the part by weight of additive are：Sludge 75%, solid waste powder is 15%, and additive is 10%.
Described sludge, solid waste powder, the part by weight of additive are：Sludge 45%, solid waste powder is 35%, and additive is 20%.
Described sludge, solid waste powder, the part by weight of additive are：Sludge 30%, solid waste powder is 60%, and additive is 10%.
Effective benefit of the invention is：
(1) nanometer refractory material has that purity is high, fusing point is high, thermal structure Strong degree is big, chemical stability and heat endurance The characteristic such as good, kiln liner is reduced heat-energy losses, improves heat utilization rate and is reduced production cost using nanometer refractory material, At the same time a complete set of equipment system of the present invention uses PLC Automatic Controls, with efficiency high, the advantage of energy-conservation.
(2) problem and use that hazardous waste sludge wastes national soil resource in large quantities are processed present invention saves with burying method The problem of the resources such as cement, pitch, additive required for solidification method, thoroughly solves hazardous waste sludge zero-emission and secondary pollution Problem, and hazardous waste sludge is turned waste into wealth, realize the strategic objective of innoxious resource reutilization.
(3) present invention realizes the purpose that hazardous waste sludge cooperates with process resource to utilize with solid waste, will be to improving and protecting The macrohabitat of China makes tremendous contribution with the development of big environmental protection industry.
Brief description of the drawings
Fig. 1 is a kind of processing system schematic diagram of hazardous waste sludge recycling of the invention；
In Fig. 1,1- sludge organism processing ponds；2- dehydration filter press；3- pulverizers；4- high-frequency microwave frequency conversions are deodorant, sterilized, Dewatering integrated processing equipment；5- sludge measuring chutes；6- solid wastes powder measures feed bin；7- additives measure feed bin；8- batch mixings are measured Feed bin；9- rolls mixing plant；10- comminutors；11- screen-dividing machines；12- dry distillation charring rotary kilns；121- bag-type dust equipment； 122- desulfurization washing towers；123- denitration devices；124- active carbon deodorizing equipment；125- plasma deodorizing devices；126- photolyases Deodorizing device；127- exhaust emissions smokestacks up to standard；13- coloured glaze glazing rotary kilns；14- haydites cool down sorter；15- measures haydite Warehouse.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to Limit the present invention.
Specific embodiment
Embodiment 1
A kind of processing system of hazardous waste sludge recycling, the system includes sludge organism processing pond 1, dehydration filter press 2nd, pulverizer 3, deodorant, sterilized high-frequency microwave frequency conversion, dewatering integrated processing equipment 4, sludge measuring chute 5, solid waste powder metering material Storehouse 6, additive metering feed bin 7, batch mixing measures feed bin 8, rolls mixing plant 9, comminutor 10, screen-dividing machine 11, dry distillation charring time Rotary kiln 12, bag-type dust equipment 121, desulfurization washing tower 122, denitration device 123, active carbon deodorizing equipment 124, plasma are deodorant Equipment 125, light catalase deodorizing device 126, exhaust emissions smokestack 127 up to standard, coloured glaze glazing rotary kiln 13, haydite cooling sorter 14th, metering haydite warehouse 15；Described sludge organism processing pond 1 is connected by waterpipe with dehydration filter press 2；Dehydration filter press 2nd, pulverizer 3, deodorant, sterilized high-frequency microwave frequency conversion, dewatering integrated processing equipment 4, sludge measuring chute 5, batch mixing metering feed bin 8th, mixing plant 9, comminutor 10, screen-dividing machine 11, dry distillation charring rotary kiln 12 is rolled to be sequentially connected by belt conveyer；Coloured glaze The front end sleeve of glazing rotary kiln 13 is in the rear end of dry distillation charring rotary kiln 12；Solid waste powder metering feed bin 6, additive metering feed bin 7 Feed bin 8 is measured by belt conveyer and batch mixing respectively to be connected；Bag-type dust equipment 121 is turned round by wind pipeline with dry distillation charring The kiln hood connection of kiln 12；Bag-type dust equipment 121, desulfurization washing tower 122, denitration device 123, active carbon deodorizing equipment 124 are led to Wind pipeline is crossed to be sequentially connected；Active carbon deodorizing equipment 124, plasma deodorizing device 125, light catalase deodorizing device 126 pass through gas Body communicating pipe is sequentially connected；Light catalase deodorizing device 126 is connected by wind pipeline with exhaust emissions smokestack 127 up to standard；On coloured glaze Glaze rotary kiln 13, haydite cooling sorter 14, metering haydite warehouse 15 are sequentially connected by belt conveyer.
Wherein, a diameter of 700mm of dry distillation charring rotary kiln 12, length is 33000mm, and kiln liner uses nanometer fire proofed wood Material；Coloured glaze glazing rotary kiln 13 a diameter of 900, length is 36000mm, and kiln liner uses nanometer refractory material.
A kind of hazardous waste sludge resource utilization method of processing system using the hazardous waste sludge recycling, step Including：
(1) using microbial technique to chrome yellow, chrome orange pigment composite waste produce hazardous waste sludge carry out it is deodorant, kill Poison, sterilization treatment, control the temperature control of waste sludge in the range of 65-95 DEG C, and process time is 5-10 seconds；
(2) hazardous waste sludge after step (1) treatment is added into polyacrylamide sludge dehydrating agent, then it is defeated with high pressure sludge pump Dehydration filter press 2 is sent to, moisture percentage in sewage sludge is down to 30-60%, sludge cake is obtained after dehydration；
(3) sludge cake after step (2) gained press filtration is transported into pulverizer 3 with belt conveyer to be crushed；
(4) by step (3) crush after sludge by belt conveyor be sent to high-frequency microwave frequency conversion it is deodorant, sterilized, dehydration Integrated equipment for wastewater treatment 4, is killed virus, is sterilized, and is reached《Pollutant catabolic gene standard in agricultural sludge》Etc. (GB4284) country and The existing relevant agricultural standards in place and regulation；
(5) step (4) gained sludge belt conveyer is transported to sludge measuring chute 5, then by sludge, solid waste powder, add Plus agent is sent to batch mixing from sludge measuring chute 5, solid waste powder metering feed bin 6, additive metering feed bin 7 by belt conveyer respectively Metering feed bin 8 mixes, and is transported to mixed qualified material by belt conveyer and rolls mixing plant 9 and fully rolled After stir, then granulated in transporting to comminutor 10 by belt conveyer, then screen-dividing machine is sent to by belt conveyer 11 carry out sub-sieve；
(6) the qualified haydite raw material ball of step (5) gained is transported into dry distillation charring rotary kiln 12 by belt conveyer to enter Row dry distillation charring, and will through destructive distillation and charing after raw material ball carry out coloured glaze glazing sintering into coloured glaze glazing rotary kiln 13 after into Be haydite, then by belt conveyer deliver to haydite cool down sorter 14 sorted, underproof haydite belt conveyer Between returning to raw material storage, qualified haydite is transported in metering haydite storage bin 15 by belt conveyer and is stored, do not conformed to The haydite raw material ball of lattice returns to comminutor 10 and granulates again by belt conveyer, wherein, described qualified haydite raw material ball Refer to that, from 2 meters of eminence freely falling bodies to ground, raw material ball is indeformable by it, be qualified without damaging.
The flue dust and tail gas that system is produced are sent to bag-type dust equipment 121 and carry out dust removal process, then will be removed by pipeline Gas after dirt is sent to desulfurization washing tower 122 and carries out desulfurization process, then is sent to denitration device 123 by pipeline and carries out at denitration Manage, then active carbon deodorizing equipment 124, plasma deodorizing device 125, light catalase deodorizing device 126 sequentially passed through by pipeline Discharged by exhaust emissions smokestack 127 up to standard after row treatment.
The running temperature of dry distillation charring rotary kiln 12 is 150-850 DEG C in step (6), and temperature of kiln head is 150 DEG C, with temperature Degree gradually rises in kiln, and kiln end temperature reaches 850 DEG C, and rotating speed is 4 turns per minute；The running temperature of coloured glaze glazing rotary kiln 13 It is 900-1250 DEG C, 900 DEG C of temperature of kiln head, as temperature gradually rises in kiln, kiln end temperature reaches 1250 DEG C, and rotating speed is every 4 turns of minute.
Embodiment 2
A kind of processing system of hazardous waste sludge recycling, the system includes sludge organism processing pond 1, dehydration filter press 2nd, pulverizer 3, deodorant, sterilized high-frequency microwave frequency conversion, dewatering integrated processing equipment 4, sludge measuring chute 5, solid waste powder metering material Storehouse 6, additive metering feed bin 7, batch mixing measures feed bin 8, rolls mixing plant 9, comminutor 10, screen-dividing machine 11, dry distillation charring time Rotary kiln 12, bag-type dust equipment 121, desulfurization washing tower 122, denitration device 123, active carbon deodorizing equipment 124, plasma are deodorant Equipment 125, light catalase deodorizing device 126, exhaust emissions smokestack 127 up to standard, coloured glaze glazing rotary kiln 13, haydite cooling sorter 14th, metering haydite warehouse 15；Described sludge organism processing pond 1 is connected by waterpipe with dehydration filter press 2；Dehydration filter press 2nd, pulverizer 3, deodorant, sterilized high-frequency microwave frequency conversion, dewatering integrated processing equipment 4, sludge measuring chute 5, batch mixing metering feed bin 8th, mixing plant 9, comminutor 10, screen-dividing machine 11, dry distillation charring rotary kiln 12 is rolled to be sequentially connected by belt conveyer；Coloured glaze The front end sleeve of glazing rotary kiln 13 is in the rear end of dry distillation charring rotary kiln 12；Solid waste powder metering feed bin 6, additive metering feed bin 7 Feed bin 8 is measured by belt conveyer and batch mixing respectively to be connected；Bag-type dust equipment 121 is turned round by wind pipeline with dry distillation charring The kiln hood connection of kiln 12；Bag-type dust equipment 121, desulfurization washing tower 122, denitration device 123, active carbon deodorizing equipment 124 are led to Wind pipeline is crossed to be sequentially connected；Active carbon deodorizing equipment 124, plasma deodorizing device 125, light catalase deodorizing device 126 pass through gas Body communicating pipe is sequentially connected；Light catalase deodorizing device 126 is connected by wind pipeline with exhaust emissions smokestack 127 up to standard；On coloured glaze Glaze rotary kiln 13, haydite cooling sorter 14, metering haydite warehouse 15 are sequentially connected by belt conveyer.
Wherein, a diameter of 1000mm of dry distillation charring rotary kiln 12, length is 33000mm, and kiln liner uses nanometer fire proofed wood Material；The a diameter of 1200mm of coloured glaze glazing rotary kiln 13, length is 36000mm, and kiln liner uses nanometer refractory material.
A kind of hazardous waste sludge resource utilization method of processing system using the hazardous waste sludge recycling, step Including：
(1) using microbial technique to chrome orange pigment, chrome green pigment composite waste produce hazardous waste sludge carry out it is deodorant, kill Poison, sterilization treatment, control the temperature control of waste sludge in the range of 65-95 DEG C, and process time is 5-10 seconds；
(2) hazardous waste sludge after step (1) treatment is added into polyacrylamide sludge dehydrating agent, then it is defeated with high pressure sludge pump Dehydration filter press 2 is sent to, moisture percentage in sewage sludge is down to 30-60%, sludge cake is obtained after dehydration；
(3) sludge cake after step (2) gained press filtration is transported into pulverizer 3 with belt conveyer to be crushed；
(4) by step (3) crush after sludge by belt conveyor be sent to high-frequency microwave frequency conversion it is deodorant, sterilized, dehydration Integrated equipment for wastewater treatment 4, is killed virus, is sterilized, and is reached《Pollutant catabolic gene standard in agricultural sludge》Etc. (GB4284) country and The existing relevant agricultural standards in place and regulation；
(5) step (4) gained sludge belt conveyer is transported to sludge measuring chute 5, then by sludge, solid waste powder, add Plus agent is sent to batch mixing from sludge measuring chute 5, solid waste powder metering feed bin 6, additive metering feed bin 7 by belt conveyer respectively Metering feed bin 8 mixes, and is transported to mixed qualified material by belt conveyer and rolls mixing plant 9 and fully rolled After stir, then granulated in transporting to comminutor 10 by belt conveyer, then screen-dividing machine is sent to by belt conveyer 11 carry out sub-sieve；
(6) the qualified haydite raw material ball of step (5) gained is transported into dry distillation charring rotary kiln 12 by belt conveyer to enter Row dry distillation charring, and will through destructive distillation and charing after raw material ball carry out coloured glaze glazing sintering into coloured glaze glazing rotary kiln 13 after into Be haydite, then by belt conveyer deliver to haydite cool down sorter 14 sorted, underproof haydite belt conveyer Between returning to raw material storage, qualified haydite is transported in metering haydite storage bin 15 by belt conveyer and is stored, do not conformed to The haydite raw material ball of lattice returns to comminutor 10 and granulates again by belt conveyer, wherein, described qualified haydite raw material ball Refer to that, from 2 meters of eminence freely falling bodies to ground, raw material ball is indeformable by it, be qualified without damaging.
The flue dust and tail gas that system is produced are sent to bag-type dust equipment 121 and carry out dust removal process, then will be removed by pipeline Gas after dirt is sent to desulfurization washing tower 122 and carries out desulfurization process, then is sent to denitration device 123 by pipeline and carries out at denitration Manage, then active carbon deodorizing equipment 124, plasma deodorizing device 125, light catalase deodorizing device 126 sequentially passed through by pipeline Discharged by exhaust emissions smokestack 127 up to standard after row treatment.
The running temperature of dry distillation charring rotary kiln 12 is 150-850 DEG C in step (6), and temperature of kiln head is 150 DEG C, with temperature Degree gradually rises in kiln, and kiln end temperature reaches 850 DEG C, and rotating speed is 5 turns per minute；The running temperature of coloured glaze glazing rotary kiln 13 It is 900-1250 DEG C, 900 DEG C of temperature of kiln head, as temperature gradually rises in kiln, kiln end temperature reaches 1250 DEG C, and rotating speed is every 5 turns of minute.
Embodiment 3
A kind of processing system of hazardous waste sludge recycling, the system includes sludge organism processing pond 1, dehydration filter press 2nd, pulverizer 3, deodorant, sterilized high-frequency microwave frequency conversion, dewatering integrated processing equipment 4, sludge measuring chute 5, solid waste powder metering material Storehouse 6, additive metering feed bin 7, batch mixing measures feed bin 8, rolls mixing plant 9, comminutor 10, screen-dividing machine 11, dry distillation charring time Rotary kiln 12, bag-type dust equipment 121, desulfurization washing tower 122, denitration device 123, active carbon deodorizing equipment 124, plasma are deodorant Equipment 125, light catalase deodorizing device 126, exhaust emissions smokestack 127 up to standard, coloured glaze glazing rotary kiln 13, haydite cooling sorter 14th, metering haydite warehouse 15；Described sludge organism processing pond 1 is connected by waterpipe with dehydration filter press 2；Dehydration filter press 2nd, pulverizer 3, deodorant, sterilized high-frequency microwave frequency conversion, dewatering integrated processing equipment 4, sludge measuring chute 5, batch mixing metering feed bin 8th, mixing plant 9, comminutor 10, screen-dividing machine 11, dry distillation charring rotary kiln 12 is rolled to be sequentially connected by belt conveyer；Coloured glaze The front end sleeve of glazing rotary kiln 13 is in the rear end of dry distillation charring rotary kiln 12；Solid waste powder metering feed bin 6, additive metering feed bin 7 Feed bin 8 is measured by belt conveyer and batch mixing respectively to be connected；Bag-type dust equipment 121 is turned round by wind pipeline with dry distillation charring The kiln hood connection of kiln 12；Bag-type dust equipment 121, desulfurization washing tower 122, denitration device 123, active carbon deodorizing equipment 124 are led to Wind pipeline is crossed to be sequentially connected；Active carbon deodorizing equipment 124, plasma deodorizing device 125, light catalase deodorizing device 126 pass through gas Body communicating pipe is sequentially connected；Light catalase deodorizing device 126 is connected by wind pipeline with exhaust emissions smokestack 127 up to standard；On coloured glaze Glaze rotary kiln 13, haydite cooling sorter 14, metering haydite warehouse 15 are sequentially connected by belt conveyer.
Wherein, a diameter of 1600mm of dry distillation charring rotary kiln 12, length is 33000mm, and kiln liner uses nanometer fire proofed wood Material；The a diameter of 1800mm of coloured glaze glazing rotary kiln 13, length is 36000mm, and kiln liner uses nanometer refractory material.
A kind of hazardous waste sludge resource utilization method of processing system using the hazardous waste sludge recycling, step Including：
(1) deodorant, antivirus, sterilization treatment are carried out to the hazardous waste sludge that chrome yellow waste water is produced using microbial technique, The temperature control of waste sludge is controlled in the range of 65-95 DEG C, process time is 5-10 seconds；
(2) hazardous waste sludge after step (1) treatment is added into polyacrylamide sludge dehydrating agent, then it is defeated with high pressure sludge pump Dehydration filter press 2 is sent to, moisture percentage in sewage sludge is down to 30-60%, sludge cake is obtained after dehydration；
(3) sludge cake after step (2) gained press filtration is transported into pulverizer 3 with belt conveyer to be crushed；
(4) by step (3) crush after sludge by belt conveyor be sent to high-frequency microwave frequency conversion it is deodorant, sterilized, dehydration Integrated equipment for wastewater treatment 4, is killed virus, is sterilized, and is reached《Pollutant catabolic gene standard in agricultural sludge》Etc. (GB4284) country and The existing relevant agricultural standards in place and regulation；
(5) step (4) gained sludge belt conveyer is transported to sludge measuring chute 5, then by sludge, solid waste powder, add Plus agent is sent to batch mixing from sludge measuring chute 5, solid waste powder metering feed bin 6, additive metering feed bin 7 by belt conveyer respectively Metering feed bin 8 mixes, and is transported to mixed qualified material by belt conveyer and rolls mixing plant 9 and fully rolled After stir, then granulated in transporting to comminutor 10 by belt conveyer, then screen-dividing machine is sent to by belt conveyer 11 carry out sub-sieve；
(6) the qualified haydite raw material ball of step (5) gained is transported into dry distillation charring rotary kiln 12 by belt conveyer to enter Row dry distillation charring, and will through destructive distillation and charing after raw material ball carry out coloured glaze glazing sintering into coloured glaze glazing rotary kiln 13 after into Be haydite, then by belt conveyer deliver to haydite cool down sorter 14 sorted, underproof haydite belt conveyer Between returning to raw material storage, qualified haydite is transported in metering haydite storage bin 15 by belt conveyer and is stored, do not conformed to The haydite raw material ball of lattice returns to comminutor 10 and granulates again by belt conveyer, wherein, described qualified haydite raw material ball Refer to that, from 2 meters of eminence freely falling bodies to ground, raw material ball is indeformable by it, be qualified without damaging.
The flue dust and tail gas that system is produced are sent to bag-type dust equipment 121 and carry out dust removal process, then will be removed by pipeline Gas after dirt is sent to desulfurization washing tower 122 and carries out desulfurization process, then is sent to denitration device 123 by pipeline and carries out at denitration Manage, then active carbon deodorizing equipment 124, plasma deodorizing device 125, light catalase deodorizing device 126 sequentially passed through by pipeline Discharged by exhaust emissions smokestack 127 up to standard after row treatment.
The running temperature of dry distillation charring rotary kiln 12 is 150-850 DEG C in step (6), and temperature of kiln head is 150 DEG C, with temperature Degree gradually rises in kiln, and kiln end temperature reaches 850 DEG C, and rotating speed is 6 turns per minute；The running temperature of coloured glaze glazing rotary kiln 13 It is 900-1250 DEG C, 900 DEG C of temperature of kiln head, as temperature gradually rises in kiln, kiln end temperature reaches 1250 DEG C, and rotating speed is every 6 turns of minute.
Embodiment 4
A kind of processing system of hazardous waste sludge recycling, the system includes sludge organism processing pond 1, dehydration filter press 2nd, pulverizer 3, deodorant, sterilized high-frequency microwave frequency conversion, dewatering integrated processing equipment 4, sludge measuring chute 5, solid waste powder metering material Storehouse 6, additive metering feed bin 7, batch mixing measures feed bin 8, rolls mixing plant 9, comminutor 10, screen-dividing machine 11, dry distillation charring time Rotary kiln 12, bag-type dust equipment 121, desulfurization washing tower 122, denitration device 123, active carbon deodorizing equipment 124, plasma are deodorant Equipment 125, light catalase deodorizing device 126, exhaust emissions smokestack 127 up to standard, coloured glaze glazing rotary kiln 13, haydite cooling sorter 14th, metering haydite warehouse 15；Described sludge organism processing pond 1 is connected by waterpipe with dehydration filter press 2；Dehydration filter press 2nd, pulverizer 3, deodorant, sterilized high-frequency microwave frequency conversion, dewatering integrated processing equipment 4, sludge measuring chute 5, batch mixing metering feed bin 8th, mixing plant 9, comminutor 10, screen-dividing machine 11, dry distillation charring rotary kiln 12 is rolled to be sequentially connected by belt conveyer；Coloured glaze The front end sleeve of glazing rotary kiln 13 is in the rear end of dry distillation charring rotary kiln 12；Solid waste powder metering feed bin 6, additive metering feed bin 7 Feed bin 8 is measured by belt conveyer and batch mixing respectively to be connected；Bag-type dust equipment 121 is turned round by wind pipeline with dry distillation charring The kiln hood connection of kiln 12；Bag-type dust equipment 121, desulfurization washing tower 122, denitration device 123, active carbon deodorizing equipment 124 are led to Wind pipeline is crossed to be sequentially connected；Active carbon deodorizing equipment 124, plasma deodorizing device 125, light catalase deodorizing device 126 pass through gas Body communicating pipe is sequentially connected；Light catalase deodorizing device 126 is connected by wind pipeline with exhaust emissions smokestack 127 up to standard；On coloured glaze Glaze rotary kiln 13, haydite cooling sorter 14, metering haydite warehouse 15 are sequentially connected by belt conveyer.
Wherein, a diameter of 2000mm of dry distillation charring rotary kiln 12, length is 33000mm, and kiln liner uses nanometer fire proofed wood Material；The a diameter of 2200mm of coloured glaze glazing rotary kiln 13, length is 33000, and kiln liner uses nanometer refractory material.
A kind of hazardous waste sludge resource utilization method of processing system using the hazardous waste sludge recycling, step Including：
(1) deodorant, antivirus, sterilization treatment are carried out to the hazardous waste sludge that chrome orange pigment wastewater is produced using microbial technique, The temperature control of waste sludge is controlled in the range of 65-95 DEG C, process time is 5-10 seconds；
(2) hazardous waste sludge after step (1) treatment is added into polyacrylamide sludge dehydrating agent, then it is defeated with high pressure sludge pump Dehydration filter press 2 is sent to, moisture percentage in sewage sludge is down to 30-60%, sludge cake is obtained after dehydration；
(3) sludge cake after step (2) gained press filtration is transported into pulverizer 3 with belt conveyer to be crushed；
(4) by step (3) crush after sludge by belt conveyor be sent to high-frequency microwave frequency conversion it is deodorant, sterilized, dehydration Integrated equipment for wastewater treatment 4, is killed virus, is sterilized, and is reached《Pollutant catabolic gene standard in agricultural sludge》Etc. (GB4284) country and The existing relevant agricultural standards in place and regulation；
(5) step (4) gained sludge belt conveyer is transported to sludge measuring chute 5, then by sludge, solid waste powder, add Plus agent is sent to batch mixing from sludge measuring chute 5, solid waste powder metering feed bin 6, additive metering feed bin 7 by belt conveyer respectively Metering feed bin 8 mixes, and is transported to mixed qualified material by belt conveyer and rolls mixing plant 9 and fully rolled After stir, then granulated in transporting to comminutor 10 by belt conveyer, then screen-dividing machine is sent to by belt conveyer 11 carry out sub-sieve；
(6) the qualified haydite raw material ball of step (5) gained is transported into dry distillation charring rotary kiln 12 by belt conveyer to enter Row dry distillation charring, and will through destructive distillation and charing after raw material ball carry out coloured glaze glazing sintering into coloured glaze glazing rotary kiln 13 after into Be haydite, then by belt conveyer deliver to haydite cool down sorter 14 sorted, underproof haydite belt conveyer Between returning to raw material storage, qualified haydite is transported in metering haydite storage bin 15 by belt conveyer and is stored, do not conformed to The haydite raw material ball of lattice returns to comminutor 10 and granulates again by belt conveyer, wherein, described qualified haydite raw material ball Refer to that, from 2 meters of eminence freely falling bodies to ground, raw material ball is indeformable by it, be qualified without damaging.
The running temperature of dry distillation charring rotary kiln 12 is 150-850 DEG C in step (6), and temperature of kiln head is 150 DEG C, with temperature Degree gradually rises in kiln, and kiln end temperature reaches 850 DEG C, and rotating speed is 7 turns per minute；The running temperature of coloured glaze glazing rotary kiln 13 It is 900-1250 DEG C, 900 DEG C of temperature of kiln head, as temperature gradually rises in kiln, kiln end temperature reaches 1250 DEG C, and rotating speed is every 7 turns of minute.
In system operation, the flue dust and tail gas of generation carry out dust removal process by bag-type dust equipment 121, then lead to Piping delivers to desulfurization washing tower 122 and carries out desulfurization process, then delivers to denitration device 123 and carry out denitration process, then sequentially passes through Active carbon deodorizing equipment 124, plasma deodorizing device 125, light catalase deodorizing device 126 are arranged after being processed by tail gas up to standard Smokestack 127 is put to discharge.
Embodiment 5
A kind of processing system of hazardous waste sludge recycling, the system includes sludge organism processing pond 1, dehydration filter press 2nd, pulverizer 3, deodorant, sterilized high-frequency microwave frequency conversion, dewatering integrated processing equipment 4, sludge measuring chute 5, solid waste powder metering material Storehouse 6, additive metering feed bin 7, batch mixing measures feed bin 8, rolls mixing plant 9, comminutor 10, screen-dividing machine 11, dry distillation charring time Rotary kiln 12, bag-type dust equipment 121, desulfurization washing tower 122, denitration device 123, active carbon deodorizing equipment 124, plasma are deodorant Equipment 125, light catalase deodorizing device 126, exhaust emissions smokestack 127 up to standard, coloured glaze glazing rotary kiln 13, haydite cooling sorter 14th, metering haydite warehouse 15；Described sludge organism processing pond 1 is connected by waterpipe with dehydration filter press 2；Dehydration filter press 2nd, pulverizer 3, deodorant, sterilized high-frequency microwave frequency conversion, dewatering integrated processing equipment 4, sludge measuring chute 5, batch mixing metering feed bin 8th, mixing plant 9, comminutor 10, screen-dividing machine 11, dry distillation charring rotary kiln 12 is rolled to be sequentially connected by belt conveyer；Coloured glaze The front end sleeve of glazing rotary kiln 13 is in the rear end of dry distillation charring rotary kiln 12；Solid waste powder metering feed bin 6, additive metering feed bin 7 Feed bin 8 is measured by belt conveyer and batch mixing respectively to be connected；Bag-type dust equipment 121 is turned round by wind pipeline with dry distillation charring The kiln hood connection of kiln 12；Bag-type dust equipment 121, desulfurization washing tower 122, denitration device 123, active carbon deodorizing equipment 124 are led to Wind pipeline is crossed to be sequentially connected；Active carbon deodorizing equipment 124, plasma deodorizing device 125, light catalase deodorizing device 126 pass through gas Body communicating pipe is sequentially connected；Light catalase deodorizing device 126 is connected by wind pipeline with exhaust emissions smokestack 127 up to standard；On coloured glaze Glaze rotary kiln 13, haydite cooling sorter 14, metering haydite warehouse 15 are sequentially connected by belt conveyer.
Wherein, a diameter of 2500mm of dry distillation charring rotary kiln 12, length is 33000mm, and kiln liner uses nanometer fire proofed wood Material；The a diameter of 2700mm of coloured glaze glazing rotary kiln 13, length is 33000mm, and kiln liner uses nanometer refractory material.
A kind of hazardous waste sludge resource utilization method of processing system using the hazardous waste sludge recycling, step Including：
(1) deodorant, antivirus, sterilization treatment are carried out to the hazardous waste sludge that chrome green pigment wastewater is produced using microbial technique, The temperature control of waste sludge is controlled in the range of 65-95 DEG C, process time is 5-10 seconds；
(2) hazardous waste sludge after step (1) treatment is added into polyacrylamide sludge dehydrating agent, then it is defeated with high pressure sludge pump Dehydration filter press 2 is sent to, moisture percentage in sewage sludge is down to 30-60%, sludge cake is obtained after dehydration；
(3) sludge cake after step (2) gained press filtration is transported into pulverizer 3 with belt conveyer to be crushed；
(4) by step (3) crush after sludge by belt conveyor be sent to high-frequency microwave frequency conversion it is deodorant, sterilized, dehydration Integrated equipment for wastewater treatment 4, is killed virus, is sterilized, and is reached《Pollutant catabolic gene standard in agricultural sludge》Etc. (GB4284) country and The existing relevant agricultural standards in place and regulation；
(5) step (4) gained sludge belt conveyer is transported to sludge measuring chute 5, then by sludge, solid waste powder, add Plus agent is sent to batch mixing from sludge measuring chute 5, solid waste powder metering feed bin 6, additive metering feed bin 7 by belt conveyer respectively Metering feed bin 8 mixes, and is transported to mixed qualified material by belt conveyer and rolls mixing plant 9 and fully rolled After stir, then granulated in transporting to comminutor 10 by belt conveyer, then screen-dividing machine is sent to by belt conveyer 11 carry out sub-sieve；
(6) the qualified haydite raw material ball of step (5) gained is transported into dry distillation charring rotary kiln 12 by belt conveyer to enter Row dry distillation charring, and will through destructive distillation and charing after raw material ball carry out coloured glaze glazing sintering into coloured glaze glazing rotary kiln 13 after into Be haydite, then by belt conveyer deliver to haydite cool down sorter 14 sorted, underproof haydite belt conveyer Between returning to raw material storage, qualified haydite is transported in metering haydite storage bin 15 by belt conveyer and is stored, do not conformed to The haydite raw material ball of lattice returns to comminutor 10 and granulates again by belt conveyer, wherein, described qualified haydite raw material ball Refer to that, from 2 meters of eminence freely falling bodies to ground, raw material ball is indeformable by it, be qualified without damaging.
The flue dust and tail gas that system is produced are sent to bag-type dust equipment 121 and carry out dust removal process, then will be removed by pipeline Gas after dirt is sent to desulfurization washing tower 122 and carries out desulfurization process, then is sent to denitration device 123 by pipeline and carries out at denitration Manage, then active carbon deodorizing equipment 124, plasma deodorizing device 125, light catalase deodorizing device 126 sequentially passed through by pipeline Discharged by exhaust emissions smokestack 127 up to standard after row treatment.
The running temperature of dry distillation charring rotary kiln 12 is 150-850 DEG C in step (6), and temperature of kiln head is 150 DEG C, with temperature Degree gradually rises in kiln, and kiln end temperature reaches 850 DEG C, and rotating speed is 8 turns per minute；The running temperature of coloured glaze glazing rotary kiln 13 It is 900-1250 DEG C, 900 DEG C of temperature of kiln head, as temperature gradually rises in kiln, kiln end temperature reaches 1250 DEG C, and rotating speed is every 8 turns of minute.
Embodiment 6
A kind of processing system of hazardous waste sludge recycling, the system includes sludge organism processing pond 1, dehydration filter press 2nd, pulverizer 3, deodorant, sterilized high-frequency microwave frequency conversion, dewatering integrated processing equipment 4, sludge measuring chute 5, solid waste powder metering material Storehouse 6, additive metering feed bin 7, batch mixing measures feed bin 8, rolls mixing plant 9, comminutor 10, screen-dividing machine 11, dry distillation charring time Rotary kiln 12, bag-type dust equipment 121, desulfurization washing tower 122, denitration device 123, active carbon deodorizing equipment 124, plasma are deodorant Equipment 125, light catalase deodorizing device 126, exhaust emissions smokestack 127 up to standard, coloured glaze glazing rotary kiln 13, haydite cooling sorter 14th, metering haydite warehouse 15；Described sludge organism processing pond 1 is connected by waterpipe with dehydration filter press 2；Dehydration filter press 2nd, pulverizer 3, deodorant, sterilized high-frequency microwave frequency conversion, dewatering integrated processing equipment 4, sludge measuring chute 5, batch mixing metering feed bin 8th, mixing plant 9, comminutor 10, screen-dividing machine 11, dry distillation charring rotary kiln 12 is rolled to be sequentially connected by belt conveyer；Coloured glaze The front end sleeve of glazing rotary kiln 13 is in the rear end of dry distillation charring rotary kiln 12；Solid waste powder metering feed bin 6, additive metering feed bin 7 Feed bin 8 is measured by belt conveyer and batch mixing respectively to be connected；Bag-type dust equipment 121 is turned round by wind pipeline with dry distillation charring The kiln hood connection of kiln 12；Bag-type dust equipment 121, desulfurization washing tower 122, denitration device 123, active carbon deodorizing equipment 124 are led to Wind pipeline is crossed to be sequentially connected；Active carbon deodorizing equipment 124, plasma deodorizing device 125, light catalase deodorizing device 126 pass through gas Body communicating pipe is sequentially connected；Light catalase deodorizing device 126 is connected by wind pipeline with exhaust emissions smokestack 127 up to standard；On coloured glaze Glaze rotary kiln 13, haydite cooling sorter 14, metering haydite warehouse 15 are sequentially connected by belt conveyer.
Wherein, a diameter of 2800mm of dry distillation charring rotary kiln 12, length is 36000mm, and kiln liner uses nanometer fire proofed wood Material；The a diameter of 3000mm of coloured glaze glazing rotary kiln 13, length is 33000mm, and kiln liner uses nanometer refractory material.
A kind of hazardous waste sludge resource utilization method of processing system using the hazardous waste sludge recycling, step Including：
(1) deodorant, antivirus, sterilization treatment are carried out to the hazardous waste sludge that iron blue pigment waste water is produced using microbial technique, The temperature control of waste sludge is controlled in the range of 65-95 DEG C, process time is 5-10 seconds；
(2) hazardous waste sludge after step (1) treatment is added into polyacrylamide sludge dehydrating agent, then it is defeated with high pressure sludge pump Dehydration filter press 2 is sent to, moisture percentage in sewage sludge is down to 30-60%, sludge cake is obtained after dehydration；
(3) sludge cake after step (2) gained press filtration is transported into pulverizer 3 with belt conveyer to be crushed；
(4) by step (3) crush after sludge by belt conveyor be sent to high-frequency microwave frequency conversion it is deodorant, sterilized, dehydration Integrated equipment for wastewater treatment 4, is killed virus, is sterilized, and is reached《Pollutant catabolic gene standard in agricultural sludge》Etc. (GB4284) country and The existing relevant agricultural standards in place and regulation；
(5) step (4) gained sludge belt conveyer is transported to sludge measuring chute 5, then by sludge, solid waste powder, add Plus agent is sent to batch mixing from sludge measuring chute 5, solid waste powder metering feed bin 6, additive metering feed bin 7 by belt conveyer respectively Metering feed bin 8 mixes, and is transported to mixed qualified material by belt conveyer and rolls mixing plant 9 and fully rolled After stir, then granulated in transporting to comminutor 10 by belt conveyer, then screen-dividing machine is sent to by belt conveyer 11 carry out sub-sieve；
(6) the qualified haydite raw material ball of step (5) gained is transported into dry distillation charring rotary kiln 12 by belt conveyer to enter Row dry distillation charring, and will through destructive distillation and charing after raw material ball carry out coloured glaze glazing sintering into coloured glaze glazing rotary kiln 13 after into Be haydite, then by belt conveyer deliver to haydite cool down sorter 14 sorted, underproof haydite belt conveyer Between returning to raw material storage, qualified haydite is transported in metering haydite storage bin 15 by belt conveyer and is stored, do not conformed to The haydite raw material ball of lattice returns to comminutor 10 and granulates again by belt conveyer, wherein, described qualified haydite raw material ball Refer to that, from 2 meters of eminence freely falling bodies to ground, raw material ball is indeformable by it, be qualified without damaging.
The flue dust and tail gas that system is produced are sent to bag-type dust equipment 121 and carry out dust removal process, then will be removed by pipeline Gas after dirt is sent to desulfurization washing tower 122 and carries out desulfurization process, then is sent to denitration device 123 by pipeline and carries out at denitration Manage, then active carbon deodorizing equipment 124, plasma deodorizing device 125, light catalase deodorizing device 126 sequentially passed through by pipeline Discharged by exhaust emissions smokestack 127 up to standard after row treatment.
The running temperature of dry distillation charring rotary kiln 12 is 150-850 DEG C in step (6), and temperature of kiln head is 150 DEG C, with temperature Degree gradually rises in kiln, and kiln end temperature reaches 850 DEG C, and rotating speed is 8 turns per minute；The running temperature of coloured glaze glazing rotary kiln 13 It is 900-1250 DEG C, 900 DEG C of temperature of kiln head, as temperature gradually rises in kiln, kiln end temperature reaches 1250 DEG C, and rotating speed is every 8 turns of minute.
Embodiment 7
A kind of processing system of hazardous waste sludge recycling, the system includes sludge organism processing pond 1, dehydration filter press 2nd, pulverizer 3, deodorant, sterilized high-frequency microwave frequency conversion, dewatering integrated processing equipment 4, sludge measuring chute 5, solid waste powder metering material Storehouse 6, additive metering feed bin 7, batch mixing measures feed bin 8, rolls mixing plant 9, comminutor 10, screen-dividing machine 11, dry distillation charring time Rotary kiln 12, bag-type dust equipment 121, desulfurization washing tower 122, denitration device 123, active carbon deodorizing equipment 124, plasma are deodorant Equipment 125, light catalase deodorizing device 126, exhaust emissions smokestack 127 up to standard, coloured glaze glazing rotary kiln 13, haydite cooling sorter 14th, metering haydite warehouse 15；Described sludge organism processing pond 1 is connected by waterpipe with dehydration filter press 2；Dehydration filter press 2nd, pulverizer 3, deodorant, sterilized high-frequency microwave frequency conversion, dewatering integrated processing equipment 4, sludge measuring chute 5, batch mixing metering feed bin 8th, mixing plant 9, comminutor 10, screen-dividing machine 11, dry distillation charring rotary kiln 12 is rolled to be sequentially connected by belt conveyer；Coloured glaze The front end sleeve of glazing rotary kiln 13 is in the rear end of dry distillation charring rotary kiln 12；Solid waste powder metering feed bin 6, additive metering feed bin 7 Feed bin 8 is measured by belt conveyer and batch mixing respectively to be connected；Bag-type dust equipment 121 is turned round by wind pipeline with dry distillation charring The kiln hood connection of kiln 12；Bag-type dust equipment 121, desulfurization washing tower 122, denitration device 123, active carbon deodorizing equipment 124 are led to Wind pipeline is crossed to be sequentially connected；Active carbon deodorizing equipment 124, plasma deodorizing device 125, light catalase deodorizing device 126 pass through gas Body communicating pipe is sequentially connected；Light catalase deodorizing device 126 is connected by wind pipeline with exhaust emissions smokestack 127 up to standard；On coloured glaze Glaze rotary kiln 13, haydite cooling sorter 14, metering haydite warehouse 15 are sequentially connected by belt conveyer.
Wherein, a diameter of 3400mm of dry distillation charring rotary kiln 12, length is 36000mm, and kiln liner uses nanometer fire proofed wood Material；The a diameter of 3600mm of coloured glaze glazing rotary kiln 13, length is 33000mm, and kiln liner uses nanometer refractory material.
A kind of hazardous waste sludge resource utilization method of processing system using the hazardous waste sludge recycling, step Including：
(1) deodorant, antivirus is carried out to the hazardous waste sludge that zinc chloride treatment waste water is produced using microbial technique, at sterilizing Reason, controls the temperature control of waste sludge in the range of 65-95 DEG C, and process time is 5-10 seconds；
(2) hazardous waste sludge after step (1) treatment is added into polyacrylamide sludge dehydrating agent, then it is defeated with high pressure sludge pump Dehydration filter press 2 is sent to, moisture percentage in sewage sludge is down to 30-60%, sludge cake is obtained after dehydration；
(3) sludge cake after step (2) gained press filtration is transported into pulverizer 3 with belt conveyer to be crushed；
(4) by step (3) crush after sludge by belt conveyor be sent to high-frequency microwave frequency conversion it is deodorant, sterilized, dehydration Integrated equipment for wastewater treatment 4, is killed virus, is sterilized, and is reached《Pollutant catabolic gene standard in agricultural sludge》Etc. (GB4284) country and The existing relevant agricultural standards in place and regulation；
(5) step (4) gained sludge belt conveyer is transported to sludge measuring chute 5, then by sludge, solid waste powder, add Plus agent is sent to batch mixing from sludge measuring chute 5, solid waste powder metering feed bin 6, additive metering feed bin 7 by belt conveyer respectively Metering feed bin 8 mixes, and is transported to mixed qualified material by belt conveyer and rolls mixing plant 9 and fully rolled After stir, then granulated in transporting to comminutor 10 by belt conveyer, then screen-dividing machine is sent to by belt conveyer 11 carry out sub-sieve；
(6) the qualified haydite raw material ball of step (5) gained is transported into dry distillation charring rotary kiln 12 by belt conveyer to enter Row dry distillation charring, and will through destructive distillation and charing after raw material ball carry out coloured glaze glazing sintering into coloured glaze glazing rotary kiln 13 after into Be haydite, then by belt conveyer deliver to haydite cool down sorter 14 sorted, underproof haydite belt conveyer Between returning to raw material storage, qualified haydite is transported in metering haydite storage bin 15 by belt conveyer and is stored, do not conformed to The haydite raw material ball of lattice returns to comminutor 10 and granulates again by belt conveyer, wherein, described qualified haydite raw material ball Refer to that, from 2 meters of eminence freely falling bodies to ground, raw material ball is indeformable by it, be qualified without damaging.
The flue dust and tail gas that system is produced are sent to bag-type dust equipment 121 and carry out dust removal process, then will be removed by pipeline Gas after dirt is sent to desulfurization washing tower 122 and carries out desulfurization process, then is sent to denitration device 123 by pipeline and carries out at denitration Manage, then active carbon deodorizing equipment 124, plasma deodorizing device 125, light catalase deodorizing device 126 sequentially passed through by pipeline Discharged by exhaust emissions smokestack 127 up to standard after row treatment.
The running temperature of dry distillation charring rotary kiln 12 is 150-850 DEG C in step (6), and temperature of kiln head is 150 DEG C, with temperature Degree gradually rises in kiln, and kiln end temperature reaches 850 DEG C, and rotating speed is 5 turns per minute；The running temperature of coloured glaze glazing rotary kiln 13 It is 900-1250 DEG C, 900 DEG C of temperature of kiln head, as temperature gradually rises in kiln, kiln end temperature reaches 1250 DEG C, and rotating speed is every 5 turns of minute.
Embodiment 8
A kind of processing system of hazardous waste sludge recycling, the system includes sludge organism processing pond 1, dehydration filter press 2nd, pulverizer 3, deodorant, sterilized high-frequency microwave frequency conversion, dewatering integrated processing equipment 4, sludge measuring chute 5, solid waste powder metering material Storehouse 6, additive metering feed bin 7, batch mixing measures feed bin 8, rolls mixing plant 9, comminutor 10, screen-dividing machine 11, dry distillation charring time Rotary kiln 12, bag-type dust equipment 121, desulfurization washing tower 122, denitration device 123, active carbon deodorizing equipment 124, plasma are deodorant Equipment 125, light catalase deodorizing device 126, exhaust emissions smokestack 127 up to standard, coloured glaze glazing rotary kiln 13, haydite cooling sorter 14th, metering haydite warehouse 15；Described sludge organism processing pond 1 is connected by waterpipe with dehydration filter press 2；Dehydration filter press 2nd, pulverizer 3, deodorant, sterilized high-frequency microwave frequency conversion, dewatering integrated processing equipment 4, sludge measuring chute 5, batch mixing metering feed bin 8th, mixing plant 9, comminutor 10, screen-dividing machine 11, dry distillation charring rotary kiln 12 is rolled to be sequentially connected by belt conveyer；Coloured glaze The front end sleeve of glazing rotary kiln 13 is in the rear end of dry distillation charring rotary kiln 12；Solid waste powder metering feed bin 6, additive metering feed bin 7 Feed bin 8 is measured by belt conveyer and batch mixing respectively to be connected；Bag-type dust equipment 121 is turned round by wind pipeline with dry distillation charring The kiln hood connection of kiln 12；Bag-type dust equipment 121, desulfurization washing tower 122, denitration device 123, active carbon deodorizing equipment 124 are led to Wind pipeline is crossed to be sequentially connected；Active carbon deodorizing equipment 124, plasma deodorizing device 125, light catalase deodorizing device 126 pass through gas Body communicating pipe is sequentially connected；Light catalase deodorizing device 126 is connected by wind pipeline with exhaust emissions smokestack 127 up to standard；On coloured glaze Glaze rotary kiln 13, haydite cooling sorter 14, metering haydite warehouse 15 are sequentially connected by belt conveyer.
Wherein, a diameter of 700mm of dry distillation charring rotary kiln 12, length is 36000mm, and kiln liner uses nanometer fire proofed wood Material；The a diameter of 900mm of coloured glaze glazing rotary kiln 13, length is 33000mm, and kiln liner uses nanometer refractory material.
A kind of hazardous waste sludge resource utilization method of processing system using the hazardous waste sludge recycling, step Including：
(1) deodorant, antivirus, sterilization treatment are carried out to the hazardous waste sludge that copper plating treatment waste water is produced using microbial technique, The temperature control of waste sludge is controlled in the range of 65-95 DEG C, process time is 5-10 seconds；
(2) hazardous waste sludge after step (1) treatment is added into polyacrylamide sludge dehydrating agent, then it is defeated with high pressure sludge pump Dehydration filter press 2 is sent to, moisture percentage in sewage sludge is down to 30-60%, sludge cake is obtained after dehydration；
(3) sludge cake after step (2) gained press filtration is transported into pulverizer 3 with belt conveyer to be crushed；
(4) by step (3) crush after sludge by belt conveyor be sent to high-frequency microwave frequency conversion it is deodorant, sterilized, dehydration Integrated equipment for wastewater treatment 4, is killed virus, is sterilized, and is reached《Pollutant catabolic gene standard in agricultural sludge》Etc. (GB4284) country and The existing relevant agricultural standards in place and regulation；
(5) step (4) gained sludge belt conveyer is transported to sludge measuring chute 5, then by sludge, solid waste powder, add Plus agent is sent to batch mixing from sludge measuring chute 5, solid waste powder metering feed bin 6, additive metering feed bin 7 by belt conveyer respectively Metering feed bin 8 mixes, and is transported to mixed qualified material by belt conveyer and rolls mixing plant 9 and fully rolled After stir, then granulated in transporting to comminutor 10 by belt conveyer, then screen-dividing machine is sent to by belt conveyer 11 carry out sub-sieve；
(6) the qualified haydite raw material ball of step (5) gained is transported into dry distillation charring rotary kiln 12 by belt conveyer to enter Row dry distillation charring, and will through destructive distillation and charing after raw material ball carry out coloured glaze glazing sintering into coloured glaze glazing rotary kiln 13 after into Be haydite, then by belt conveyer deliver to haydite cool down sorter 14 sorted, underproof haydite belt conveyer Between returning to raw material storage, qualified haydite is transported in metering haydite storage bin 15 by belt conveyer and is stored, do not conformed to The haydite raw material ball of lattice returns to comminutor 10 and granulates again by belt conveyer, wherein, described qualified haydite raw material ball Refer to that, from 2 meters of eminence freely falling bodies to ground, raw material ball is indeformable by it, be qualified without damaging.
The flue dust and tail gas that system is produced are sent to bag-type dust equipment 121 and carry out dust removal process, then will be removed by pipeline Gas after dirt is sent to desulfurization washing tower 122 and carries out desulfurization process, then is sent to denitration device 123 by pipeline and carries out at denitration Manage, then active carbon deodorizing equipment 124, plasma deodorizing device 125, light catalase deodorizing device 126 sequentially passed through by pipeline Discharged by exhaust emissions smokestack 127 up to standard after row treatment.
The running temperature of dry distillation charring rotary kiln 12 is 150-850 DEG C in step (6), and temperature of kiln head is 150 DEG C, with temperature Degree gradually rises in kiln, and kiln end temperature reaches 850 DEG C, and rotating speed is 6 turns per minute；The running temperature of coloured glaze glazing rotary kiln 13 It is 900-1250 DEG C, 900 DEG C of temperature of kiln head, as temperature gradually rises in kiln, kiln end temperature reaches 1250 DEG C, and rotating speed is every 6 turns of minute.
Embodiment 9
A kind of processing system of hazardous waste sludge recycling, the system includes sludge organism processing pond 1, dehydration filter press 2nd, pulverizer 3, deodorant, sterilized high-frequency microwave frequency conversion, dewatering integrated processing equipment 4, sludge measuring chute 5, solid waste powder metering material Storehouse 6, additive metering feed bin 7, batch mixing measures feed bin 8, rolls mixing plant 9, comminutor 10, screen-dividing machine 11, dry distillation charring time Rotary kiln 12, bag-type dust equipment 121, desulfurization washing tower 122, denitration device 123, active carbon deodorizing equipment 124, plasma are deodorant Equipment 125, light catalase deodorizing device 126, exhaust emissions smokestack 127 up to standard, coloured glaze glazing rotary kiln 13, haydite cooling sorter 14th, metering haydite warehouse 15；Described sludge organism processing pond 1 is connected by waterpipe with dehydration filter press 2；Dehydration filter press 2nd, pulverizer 3, deodorant, sterilized high-frequency microwave frequency conversion, dewatering integrated processing equipment 4, sludge measuring chute 5, batch mixing metering feed bin 8th, mixing plant 9, comminutor 10, screen-dividing machine 11, dry distillation charring rotary kiln 12 is rolled to be sequentially connected by belt conveyer；Coloured glaze The front end sleeve of glazing rotary kiln 13 is in the rear end of dry distillation charring rotary kiln 12；Solid waste powder metering feed bin 6, additive metering feed bin 7 Feed bin 8 is measured by belt conveyer and batch mixing respectively to be connected；Bag-type dust equipment 121 is turned round by wind pipeline with dry distillation charring The kiln hood connection of kiln 12；Bag-type dust equipment 121, desulfurization washing tower 122, denitration device 123, active carbon deodorizing equipment 124 are led to Wind pipeline is crossed to be sequentially connected；Active carbon deodorizing equipment 124, plasma deodorizing device 125, light catalase deodorizing device 126 pass through gas Body communicating pipe is sequentially connected；Light catalase deodorizing device 126 is connected by wind pipeline with exhaust emissions smokestack 127 up to standard；On coloured glaze Glaze rotary kiln 13, haydite cooling sorter 14, metering haydite warehouse 15 are sequentially connected by belt conveyer.
Wherein, a diameter of 1000mm of dry distillation charring rotary kiln 12, length is 36000mm, and kiln liner uses nanometer fire proofed wood Material；The a diameter of 1200mm of coloured glaze glazing rotary kiln 13, length is 33000mm, and kiln liner uses nanometer refractory material.
A kind of hazardous waste sludge resource utilization method of processing system using the hazardous waste sludge recycling, step Including：
(1) deodorant, antivirus, sterilization treatment are carried out to the hazardous waste sludge that zinc-plated treatment waste water is produced using microbial technique, The temperature control of waste sludge is controlled in the range of 65-95 DEG C, process time is 5-10 seconds；
(2) hazardous waste sludge after step (1) treatment is added into polyacrylamide sludge dehydrating agent, then it is defeated with high pressure sludge pump Dehydration filter press 2 is sent to, moisture percentage in sewage sludge is down to 30-60%, sludge cake is obtained after dehydration；
(3) sludge cake after step (2) gained press filtration is transported into pulverizer 3 with belt conveyer to be crushed；
(4) by step (3) crush after sludge by belt conveyor be sent to high-frequency microwave frequency conversion it is deodorant, sterilized, dehydration Integrated equipment for wastewater treatment 4, is killed virus, is sterilized, and is reached《Pollutant catabolic gene standard in agricultural sludge》Etc. (GB4284) country and The existing relevant agricultural standards in place and regulation；
(5) step (4) gained sludge belt conveyer is transported to sludge measuring chute 5, then by sludge, solid waste powder, add Plus agent is sent to batch mixing from sludge measuring chute 5, solid waste powder metering feed bin 6, additive metering feed bin 7 by belt conveyer respectively Metering feed bin 8 mixes, and is transported to mixed qualified material by belt conveyer and rolls mixing plant 9 and fully rolled After stir, then granulated in transporting to comminutor 10 by belt conveyer, then screen-dividing machine is sent to by belt conveyer 11 carry out sub-sieve；
(6) the qualified haydite raw material ball of step (5) gained is transported into dry distillation charring rotary kiln 12 by belt conveyer to enter Row dry distillation charring, and will through destructive distillation and charing after raw material ball carry out coloured glaze glazing sintering into coloured glaze glazing rotary kiln 13 after into Be haydite, then by belt conveyer deliver to haydite cool down sorter 14 sorted, underproof haydite belt conveyer Between returning to raw material storage, qualified haydite is transported in metering haydite storage bin 15 by belt conveyer and is stored, do not conformed to The haydite raw material ball of lattice returns to comminutor 10 and granulates again by belt conveyer, wherein, described qualified haydite raw material ball Refer to that, from 2 meters of eminence freely falling bodies to ground, raw material ball is indeformable by it, be qualified without damaging.
The flue dust and tail gas that system is produced are sent to bag-type dust equipment 121 and carry out dust removal process, then will be removed by pipeline Gas after dirt is sent to desulfurization washing tower 122 and carries out desulfurization process, then is sent to denitration device 123 by pipeline and carries out at denitration Manage, then active carbon deodorizing equipment 124, plasma deodorizing device 125, light catalase deodorizing device 126 sequentially passed through by pipeline Discharged by exhaust emissions smokestack 127 up to standard after row treatment.
The running temperature of dry distillation charring rotary kiln 12 is 150-850 DEG C in step (6), and temperature of kiln head is 150 DEG C, with temperature Degree gradually rises in kiln, and kiln end temperature reaches 850 DEG C, and rotating speed is 7 turns per minute；The running temperature of coloured glaze glazing rotary kiln 13 It is 900-1250 DEG C, 900 DEG C of temperature of kiln head, as temperature gradually rises in kiln, kiln end temperature reaches 1250 DEG C, and rotating speed is every 7 turns of minute.
Embodiment 10
The haydite produced using the system and method, its composition part by weight is respectively：Sludge 75%, mine tailing 15%th, additive is 10%, wherein bentonitic adding proportion is the 15% of additive total amount, waterglass adding proportion is addition The 85% of agent total amount.
Embodiment 11
The haydite produced using the system and method, its composition part by weight is respectively：Sludge 45%, metallurgical quarrel powder The adding proportion of the 35%th, additive 20%, wherein crushed crude pearlite is the 15% of additive total amount, and waterglass adding proportion is addition The 85% of agent total amount.
Embodiment 12
The haydite produced using the system and method, its composition part by weight is respectively：Sludge 30%, building waste powder 60%th, additive 10%, wherein bentonite are the 15% of additive total amount with total adding proportion of crushed crude pearlite, waterglass addition Ratio is the 85% of additive total amount.
Embodiment 13
The haydite produced using the system and method, its composition part by weight is respectively：Sludge 75%, solid waste powder The adding proportion of the 15%th, additive 10%, wherein mine tailing is the 80% of solid waste powder total amount, and the adding proportion of building waste powder is The 20% of solid waste powder total amount；Bentonitic adding proportion is the 25% of additive total amount, and waterglass adding proportion is that additive is total The 75% of amount.
Embodiment 14
The haydite produced using the system and method, its composition part by weight is respectively：Sludge 45%, solid waste powder are 35%th, additive is 20%, and wherein the adding proportion of mine tailing is the 70% of solid waste powder total amount, the adding proportion of building waste powder It is the 30% of solid waste powder total amount；The adding proportion of crushed crude pearlite is the 25% of additive total amount, and the adding proportion of waterglass is to add Plus the 75% of agent total amount.
Embodiment 15
The haydite produced using the system and method, its composition part by weight is respectively：Sludge 30%, solid waste powder are 60%th, additive is 10%, and wherein the adding proportion of mine tailing is the 60% of solid waste powder total amount, the adding proportion of building waste powder It is the 40% of solid waste powder total amount；Bentonite is the 25% of additive total amount with total adding proportion of crushed crude pearlite, waterglass addition Ratio is the 75% of additive total amount.
Embodiment 16
The haydite produced using the system and method, its composition part by weight is respectively：Sludge 75%, solid waste powder are 15%th, additive is 10%, and wherein the adding proportion of mine tailing is the 80% of solid waste powder total amount, and the adding proportion of metallurgy quarrel powder is The 20% of solid waste powder total amount；Bentonitic adding proportion is the 10% of additive total amount, and the adding proportion of waterglass is additive The 70% of total amount, the adding proportion of crushed crude pearlite is the 20% of additive total amount.
Embodiment 17
The haydite produced using the system and method, its composition part by weight is respectively：Sludge 45%, solid waste powder are 35%th, additive is 20%, and wherein the adding proportion of mine tailing is the 70% of solid waste powder total amount, and the adding proportion of metallurgy quarrel powder is The 30% of solid waste powder total amount；Bentonitic adding proportion is the 5% of additive total amount, and the adding proportion of waterglass is that additive is total The 75% of amount, the adding proportion of crushed crude pearlite is the 20% of additive total amount.
Embodiment 18
The haydite produced using the system and method, its composition part by weight is respectively：Sludge 30%, solid waste powder are 60%th, additive is 10%, and wherein the adding proportion of mine tailing is the 60% of solid waste powder total amount, and the adding proportion of metallurgy quarrel powder is The 40% of solid waste powder total amount；Bentonitic adding proportion is the 25% of additive total amount, and the adding proportion of waterglass is additive The 50% of total amount, the adding proportion of crushed crude pearlite is the 25% of additive total amount.
Embodiment 19
The haydite produced using the system and method, its composition part by weight is respectively：Sludge 45%, solid waste powder are 35%th, additive is 20%, and wherein the adding proportion of mine tailing is the 70% of solid waste powder total amount, and the adding proportion of metallurgy quarrel powder is The 10% of solid waste powder total amount, the adding proportion of building waste powder is the 20% of solid waste powder total amount；Bentonitic adding proportion is to add Plus the 20% of agent total amount, the adding proportion of waterglass is the 80% of additive total amount.
Embodiment 20
The haydite produced using the system and method, its composition part by weight is respectively：Sludge 30%, solid waste powder are 60%th, additive is 10%, and wherein the adding proportion of mine tailing is the 50% of solid waste powder total amount, and the adding proportion of metallurgy quarrel powder is The 20% of solid waste powder total amount, the adding proportion of building waste powder is the 30% of solid waste powder total amount；Bentonite is total with crushed crude pearlite Adding proportion is the 20% of additive total amount, and the adding proportion of waterglass is the 80% of additive total amount.
Presently preferred embodiments of the present invention is the foregoing is only, is not intended to limit the invention, it is all in essence of the invention Any modification, equivalent and improvement made within god and principle etc., should be included within the scope of the present invention.

Claims (11)

1. a kind of processing system of hazardous waste sludge recycling, it is characterised in that the system includes sludge organism processing pond (1), dehydration filter press (2), pulverizer (3), deodorant, sterilized high-frequency microwave frequency conversion, dewatering integrated processing equipment (4), sludge Measuring chute (5), solid waste powder measure feed bin (6), additive and measure feed bin (7), batch mixing metering feed bin (8), roll mixing plant (9), comminutor (10), screen-dividing machine (11), dry distillation charring rotary kiln (12), bag-type dust equipment (121), desulfurization washing tower (122), denitration device (123), active carbon deodorizing equipment (124), plasma deodorizing device (125), light catalase deodorizing device (126), exhaust emissions smokestack (127) up to standard, coloured glaze glazing rotary kiln (13), haydite cool down sorter (14), metering haydite storage Storehouse (15)；Described sludge organism processing pond (1) is connected by waterpipe with dehydration filter press (2)；Dehydration filter press (2), powder Broken machine (3), deodorant, sterilized high-frequency microwave frequency conversion, dewatering integrated processing equipment (4), sludge measuring chute (5), batch mixing metering material Storehouse (8), mixing plant (9), comminutor (10), screen-dividing machine (11), dry distillation charring rotary kiln (12) are rolled by belt conveyer It is sequentially connected；Rear end of the front end sleeve of coloured glaze glazing rotary kiln (13) in dry distillation charring rotary kiln (12)；Solid waste powder measures feed bin (6), additive is measured feed bin (7) and is connected by belt conveyer and batch mixing metering feed bin (8) respectively；Bag-type dust equipment (121) it is connected with the kiln hood of dry distillation charring rotary kiln (12) by wind pipeline；Bag-type dust equipment (121), desulfurization washing tower (122), denitration device (123), active carbon deodorizing equipment (124) are sequentially connected by wind pipeline；Active carbon deodorizing equipment (124), plasma deodorizing device (125), light catalase deodorizing device (126) are sequentially connected by air communicating pipe；Light catalase is removed Smelly equipment (126) is connected by wind pipeline with exhaust emissions smokestack (127) up to standard；Coloured glaze glazing rotary kiln (13), haydite cooling Sorter (14), metering haydite warehouse (15) are sequentially connected by belt conveyer.
2. the processing system of a kind of hazardous waste sludge recycling according to claim 1, it is characterised in that described is dry Charing rotary kiln (12) a diameter of 700-3400mm is evaporated, length is 33000-36000mm, and kiln liner uses nanometer refractory material； Coloured glaze glazing rotary kiln (13) a diameter of 900-3600mm, length is 33000-3600mm, and kiln liner uses nanometer refractory material.
3. the side of hazardous waste sludge recycling is carried out using the processing system of hazardous waste sludge recycling described in claim 1 Method, it is characterised in that comprise the following steps：
(1) deodorant, antivirus, sterilization treatment are carried out to hazardous waste sludge HW12 or HW17 using microbial technique, control waste sludge In the range of 65-95 DEG C, process time is 5-10 seconds to temperature control；Described HW12 refers to the waste of dyestuff or coating, i.e. chromium The sludge produced after yellow pigment, chrome orange pigment, chrome green pigment, the one of which of iron blue pigment or several wastewater treatments；HW17 is Refer to carry out sensitized treatment and gold-plated, copper facing using zinc chloride, ammonium chloride etc., at zinc-plated, chromium plating one of which or the waste water such as several Manage the sludge for producing；
(2) hazardous waste sludge after step (1) treatment is added into sludge dehydrating agent, dehydration filter press is pumped into high pressure sludge (2) moisture percentage in sewage sludge is down to 30-60%, sludge cake is obtained after dehydration；
(3) sludge cake after step (2) gained press filtration is transported into pulverizer (3) with belt conveyer to be crushed；
(4) by step (3) crush after sludge by belt conveyor be sent to high-frequency microwave frequency conversion it is deodorant, sterilized, dehydration one Change processing equipment (4), killed virus, sterilized, reach《Pollutant catabolic gene standard in agricultural sludge》(GB4284) country and the ground such as The relevant agricultural standards and regulation of Fang Xianhang；
(5) step (4) gained sludge belt conveyer is transported to sludge measuring chute (5), then by sludge, solid waste powder, addition Agent is measured during feed bin (6), additive measure feed bin (7) from sludge measuring chute (5), solid waste powder be sent to by belt conveyer respectively Batch mixing measures feed bin (8) mixing, is transported to mixed qualified material by belt conveyer and rolls mixing plant (9) and carry out Stirred after fully rolling, then granulated in transporting to comminutor (10) by belt conveyer, then by belt conveyer Being sent to screen-dividing machine (11) carries out sub-sieve；
(6) the qualified haydite raw material ball of step (5) gained is transported into dry distillation charring rotary kiln (12) by belt conveyer is carried out Dry distillation charring, and will through destructive distillation and charing after raw material ball carry out coloured glaze glazing sintering into coloured glaze glazing rotary kiln (13) after into Be haydite, then by belt conveyer deliver to haydite cool down sorter (14) sorted, underproof haydite belt-conveying Between machine returns to raw material storage, qualified haydite is transported in metering haydite storage bin (15) by belt conveyer and is stored, Underproof haydite raw material ball returns to comminutor (10) and granulates again by belt conveyer, wherein, described qualified haydite Raw material ball refers to that, from 2 meters of eminence freely falling bodies to ground, raw material ball is indeformable by it, is qualified without damaging.
4. method according to claim 3, it is characterised in that sludge dehydrating agent described in step (2) is dirty for polyacrylamide Mud dehydrating agent.
5. method according to claim 3, it is characterised in that the operation temperature of dry distillation charring rotary kiln (12) in step (6) It is 150-850 DEG C to spend, and rotating speed turns for 4-8 per minute；The running temperature of coloured glaze glazing rotary kiln (13) is 900-1250 DEG C, rotating speed For 4-8 per minute turns.
6. a kind of haydite that utilization claim 3 methods described is produced, it is characterised in that the percentage by weight of the haydite each component Respectively：Sludge 30%-75%, solid waste powder is 15%-60%, and additive is 10%-20%.
7. haydite according to claim 6, it is characterised in that described additive can be waterglass；It can be bentonite With the mixture of waterglass, bentonitic adding proportion is the 15-25% of total amount, and waterglass adding proportion is the 75- of total amount 85%；Can be the mixture of crushed crude pearlite and waterglass, the adding proportion of crushed crude pearlite is the 15-25% of total amount, waterglass Adding proportion is the 75-85% of total amount；Can be the mixture of bentonite, crushed crude pearlite and waterglass three, bentonite and treasure Total adding proportion of pearl rock dust is the 15-25% of total amount, and waterglass adding proportion is the 75-85% of total amount；Bentonite and pearl The granularity of rock dust is more than 200 mesh.
8. haydite according to claim 6, it is characterised in that described solid waste Powder Particle Size is more than 200 mesh, is mine tailing, smelting The mixture of one or more in golden ground-slag, building waste powder.
9. haydite according to claim 6, it is characterised in that described sludge, solid waste powder, the part by weight of additive are： Sludge 75%, solid waste powder is 15%, and additive is 10%.
10. haydite according to claim 6, it is characterised in that described sludge, solid waste powder, the part by weight of additive For：Sludge 45%, solid waste powder is 35%, and additive is 20%.
11. haydites according to claim 6, it is characterised in that described sludge, solid waste powder, the part by weight of additive For：Sludge 30%, solid waste powder is 60%, and additive is 10%.
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CN114213144A (en) * 2022-02-23 2022-03-22 山东恒远利废技术股份有限公司 Method for treating cyanidation tailing sludge and preparing ceramsite simultaneously

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