CN106862561A - A kind of manufacturing process of aluminium alloy - Google Patents

A kind of manufacturing process of aluminium alloy Download PDF

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Publication number
CN106862561A
CN106862561A CN201510931376.9A CN201510931376A CN106862561A CN 106862561 A CN106862561 A CN 106862561A CN 201510931376 A CN201510931376 A CN 201510931376A CN 106862561 A CN106862561 A CN 106862561A
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China
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cladding
powder
aluminium alloy
subdivision
laser
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CN201510931376.9A
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Inventor
吴复尧
吴海峰
王斌
刘黎明
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Aerospace Research Institute of Materials and Processing Technology
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Aerospace Research Institute of Materials and Processing Technology
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Priority to CN201510931376.9A priority Critical patent/CN106862561A/en
Publication of CN106862561A publication Critical patent/CN106862561A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/10Sintering only
    • B22F3/105Sintering only by using electric current other than for infrared radiant energy, laser radiation or plasma ; by ultrasonic bonding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2203/00Controlling

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  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Powder Metallurgy (AREA)
  • Laser Beam Processing (AREA)

Abstract

The present invention relates to a kind of manufacturing process of aluminium alloy.Methods described includes:The threedimensional model of aluminium alloy is set up, and subdivision is carried out to the threedimensional model, cladding control program worked out according to subdivision result and is loaded into digital control system;The digital control system is set cladding 8-12 layers on substrate, so that basis of formation cladding layer;Reset the digital control system carries out uniform and stable shaping on the basic cladding layer, until forming process terminates.The method of the invention can solve the problems, such as easily to be cracked in aluminium alloy cladding process, it is possible to produce the aluminum alloy materials of high-quality.

Description

A kind of manufacturing process of aluminium alloy
Technical field
The present invention relates to technical field of aluminum alloy technology, the manufacturing process of aluminium alloy is related generally to.
Background technology
Aluminium alloy is most widely used class non-ferrous metal structural material in industry, aviation, Widely applied in space flight, automobile, machine-building, ship and chemical industry.Industrial economy Develop rapidly, the demand to Welded structural member is increasing, the weldability for enabling aluminum alloy to Research is also goed deep into therewith.
Aluminium alloy usually using alloying elements such as copper, zinc, manganese, silicon, magnesium, 20 beginnings of the century by German Alfred Wilm are invented, and help very big to aircraft development, once big Postwar German aluminium Alloying component is listed in state secret.Being compared with common carbon steel has lighter and corrosion resistant property Can, but corrosion resistance is not so good as fine aluminium.The surface of aluminium alloy can shape under environment that is clean, drying Into the oxide layer of protection.
The situation for causing galvanic corrosion (Galvanic corrosion) to accelerate has:Aluminium alloy with The situation of Bu Rust steel contact, other corrosion of metal current potentials are lower than aluminium alloy or in moist ring Under border.If aluminium must have water-containing He Bu Rust steel will be used together Electronics or electrolysis isolation between systems or the metal of outdoor installation two.
The composition of aluminium alloy need to association of Alcoa (Aluminium Association, AA) register.Many tissues announce the standard of more specific manufacture aluminium alloy, including american car work Cheng Xiehui (Society of Automotive Engineers, SAE) is particularly air standard, Also American Society for Testing Materials (American Society for Testing and Materials, ASTM).
Aluminium alloy is most widely used class non-ferrous metal structural material in industry, aviation, Space flight, automobile, machine-building, ship aluminium alloy And widely applied in chemical industry.
As science and technology and industrial economy are developed rapidly in recent years, to aluminum alloy welding binding The demand of component is increasing, and the Research on Weldability for enabling aluminum alloy to also is goed deep into therewith.Aluminium alloy Extensively using the development for promoting aluminum alloy solder technology, while the development of solder technology is expanded again The application field of aluminium alloy, thus aluminium alloy solder technology just turning into research focus it One.
The density of fine aluminium is small (ρ=2.7g/cm3), about the 1/3 of iron, and fusing point is low (660 DEG C), Aluminium is face-centred cubic structure, therefore with plasticity (δ very high:32~40%, ψ:70~90%), It is easy to process, can be made into various section bars, sheet material.Corrosion resistance is good;But the intensity of fine aluminium Very low, annealed condition σ b values are about 8kgf/mm2, therefore should not make structural material.By length The production practices and scientific experiment of phase, people gradually with add alloying element and with heat treatment etc. Method carrys out reinforced aluminum, and this has just obtained a series of aluminium alloy.
Can also have while the alloy of certain element formation is added the advantages of fine aluminium light weight is kept There is intensity higher, σ b values are respectively up to 24~60kgf/mm2.So so that it is " than strong Degree " (the ratio σ b/ ρ of intensity and proportion) surpasses many steel alloys, as preferably knot Structure material, is widely used in the aspects such as machine-building, Transport Machinery, dynamic power machine and aircraft industry, Fuselage, covering, compressor of aircraft etc. are often manufactured with aluminium alloy, to mitigate deadweight.Using aluminium Alloy replaces the welding of steel plate materialses, and construction weight can mitigate more than 50%.
But, aluminium alloy plasticity at room temperature is very poor, shapes extremely difficult, limits The engineering application of the material.Therefore, researcher is just actively developing its near-net-shape technology, Such as powder metallurgy, hot investment casting, directional solidification and Laser Melting Deposition.
Laser melting and coating technique is that 20 century 70s rise with the development of high power laser A kind of new process for modifying surface, refer to laser surface deposition technology be laser beam effect under Alloy powder or ceramic powders are heated and melted rapidly with matrix surface, light beam removes rear self-excitation Be cooled into that dilution rate is extremely low, with matrix material in metallurgical binding face coat so that significantly Improve that matrix surface is wear-resisting, anti-corrosion, heat-resisting, anti-oxidant and a kind of surface of electrical characteristic etc. is strong Change method [after such as carries out carbon tungsten laser melting coating to 60# steel, hardness is up to more than 2200HV, Abrasion resistance properties are 20 times or so of matrix 60# steel.In Q235 steel surface laser melting coatings After CoCrSiB alloys, its wearability is contrasted with the corrosion resistance of flame-spraying, found The former corrosion resistance is apparently higher than the latter
Laser melting and coating technique is a kind of economic benefit new technology very high, and it can be in cheap metal High performance alloy surface is prepared on base material without influenceing the property of matrix, reduces cost, section About valuable Rare Metals Materials, therefore, each industrial advanced country is to laser melting and coating technique in the world Research and application all pay much attention to.
The laser for being applied to laser melting coating mainly has carbon dioxide laser and solid state laser (mainly including disc laser, optical fiber laser and diode laser, old-fashioned lamp pumping swash Light device is low due to electricity conversion, gradually fades out market the problems such as safeguard cumbersome).For Continuous CO 2 laser cladding, domestic and foreign scholars have been done numerous studies high powers solid and have been swashed The research and development of light device is rapid, is mainly used in non-ferrous alloy surface and is modified.According to the literature, adopt Aluminium alloy laser melting coating is carried out with carbon dioxide laser, alloy matrix aluminum is in carbon dioxide laser spoke It is easily deformed according under the conditions of, or even is collapsed.Solid state laser, particularly disc laser are exported Wavelength is 1.06 μm, 1 order of magnitude small compared with carbon dioxide laser wavelength, thus is more suitable for this The laser melting coating of metalloid.
Laser melting coating can be divided into two classes by the difference of powder feeding technique:The preset method of powder and synchronous powder feeding system Method.Two methods effect is similar, and synchronous powder feeding system method has easily realizes Automated condtrol, laser energy Amount absorptivity is high, and without internal porosity, especially deposited metals are ceramic, can significantly improve cladding layer Anti-cracking performance, make hard ceramic mutually the advantages of can be uniformly distributed in cladding layer.
Laser cladding forming technology is in the case of without special tooling mould, by high power The various metal dusts of laser fusion synchronous transport, pointwise is successively piled up and carrys out Prototyping Metal Parts Process.Technology formation of parts by the way of increment growth, is remarkably improved stock utilization, And formed parts only need final finishing, part manufacture and lead time can be greatly shortened, carried Development efficiency high, reduces cost.In addition, multiple material and difference can be carried out in an equipment The manufacture of shape part, and Element Design can easily be changed by reprogram, with very high Processing flexibility, should with wide exploitation on by the quick preparation of alloy manufacture severe service components Use prospect.
Aluminium alloy, due to the presence of higher thermal stress, easily occurs during Laser Melting Deposition Cracking.According to both at home and abroad, the Al-alloy products size of laser forming manufacture is limited, general There is 60mm or so, the problem easily split in addition is difficult to be solved by changing technological parameter.Aluminium is closed Auri body is susceptible to cracking in preheating, for the technique for avoiding the problem from being used becomes multiple It is miscellaneous.Forming technology and the pre-heating technique to substrate by adjusting initial cladding layer of the invention, system The aluminum alloy materials of flawless have been made, and on the basis of grasp shapes the alloying technology, manufacture Go out larger-size aluminum alloy sample.
The content of the invention
The problem that the present invention easily ftractures for aluminium alloy in the prior art, employs following technology Scheme:
The present invention by adjust initial cladding layer forming technology and to the pre-heating technique of substrate come Flawless aluminium alloy laser solid forming is carried out, the concrete technical scheme of use is as follows:
1. a kind of manufacturing process of aluminium alloy, methods described includes:
(1) threedimensional model of aluminium alloy is set up, and subdivision is carried out to the threedimensional model, according to Subdivision result is worked out cladding control program and is loaded into digital control system;
(2) it is 150-180 to be arranged to control the sweep speed of powder-feeding nozzle by the digital control system M/h, the powder feed rate of powder feed system is set as 9 to 12 gram/minutes, and will be molten The subdivision for covering every layer in control program is highly set as 0.15-0.25mm, the cladding on substrate 8-12 layers, so that basis of formation cladding layer;
(3) sweep speed of powder-feeding nozzle is adjusted to 250-350 ms/h again, while will The powder feed rate of powder feed system is adjusted to 8-12 gram/minutes, and every layer is cutd open in cladding control program Divide Height Adjustment to be 0.5-1.0mm, uniform and stable shaping carried out on the basic cladding layer, Until forming process terminates.
2. the method as described in technical scheme 1, it is characterised in that:The material of the substrate is The aluminium alloy of titaniferous.
3. the method as described in technical scheme 1 or 2, it is characterised in that:The material of the substrate Material thickness is 8-12mm.
4. the method as any one of technical scheme 1 to 3, it is characterised in that:It is described Oxygen content in the working chamber of cladding is less than 80ppm.
5. the method as any one of technical scheme 1 to 4, it is characterised in that:First Argon gas is filled with working chamber to exclude air, 12-16 liters/min of argon flow amount works as shaping About in 1000ppm, open cleaning system makes oxygen content be less than 100ppm to indoor oxygen content.
6. the method as any one of technical scheme 1 to 5, it is characterised in that:It is described The granularity about 50-300 mesh of the Al alloy powder that powder feed system is used.
7. the method as described in technical scheme 1, it is characterised in that:Form the basic cladding During layer, laser power parameters as 500-1000W are set.
8. the method according to any one of technical scheme 1 to 7, it is characterised in that:Enter During the row uniform and stable shaping, laser power parameters as 1500-2500W are set.
9. the method according to any one of technical scheme 1 to 7, it is characterised in that:Institute State the granularity about 100-200 mesh of the Al alloy powder of powder feed system use.
10. the method according to any one of technical scheme 1 to 7, it is characterised in that:: When forming the basic cladding layer, laser power parameters as 600-800W are set.
The present invention is manufactured using laser three-dimensional RP technique, and the technology is according to quick Forming Theory is directly melted the Al alloy powder of synchronous transport using high-power laser beam, then Rapid solidification, with being synchronized with the movement for laser beam and powder-feeding nozzle, continuously successively cladding goes out densification High-performance metal structural member manufacture method.The present invention by setting different subdivisions highly, The different speeds of service (sweep speed of nozzle) of lathe are controlled, setting powder feed system is different Powder feed rate, you can manufacture flawless aluminum alloy materials or aluminium aluminium base other easily split alloy material Material.Compared with traditional handicraft, aluminum alloy materials are manufactured using the process, can avoid melting Occur the phenomenon that aluminium alloy is easily cracked during covering, produce the aluminium alloy material of flawless Material, is that aluminium alloy realizes that engineering is laid a good foundation in quick manufacture field.
Specific embodiment
Below by specific embodiment, the present invention is described in detail.
The present invention is using laser solid forming technology manufacture flawless aluminum alloy materials, the method institute It is laser solid forming equipment with equipment, it can be by commercially available.
Preferably, laser 1 uses 4KW carbon dioxide fast axle stream lasers;Substrate 6 is used Aluminum alloy materials, on the substrate face carry out cladding;Al alloy powder uses plasma electric rotating Pole method production, the mesh of about 100 mesh of granularity -200.
The step of preparing flawless aluminum alloy materials using the said equipment is as follows:
First, water-cooled lathe will be fixed on by aluminum alloy plate materials tooling fixture used by moulding material On table top, forming room is then closed.It is now air in working chamber, due to the cladding of aluminium alloy Needs can just carry out cladding in oxygen content less than 80ppm, so needing first to be filled with argon gas to exclude Air, 12-16 liters/min of flow.When the indoor oxygen content of shaping is about in 1000ppm, Opening cleaning system further reduces oxygen content (because cleaning system works when oxygen content is higher It is easily damaged cleaning system), just can open cladding program when oxygen content is less than 80ppm.
Then laser is opened, the pressure of high-purity carbon dioxide, high-purity He, high-purity N 2 is adjusted Section to 0.5MPa or so, make the laser beam that laser 1 is produced by after speculum 4 in substrate A branch of hot spot is formed on 6 and molten bath is formed;Then powder feeder 2 is opened, powder sprays by powder feeding Converged at after mouth 5 in laser facula focus;Set powder feed rate as 5 gram/minutes, powder feeding gas Body flow 5-6L/min.
Then, the basic cladding layer (or being initiation layer) of cladding aluminium alloy is prepared, wherein profit The threedimensional model for cladding forming sample is set up with 3 d modeling software, will using subdivision software Threedimensional model subdivision works out cladding control program and is loaded into digital control system according to subdivision result.
Sample threedimensional model can such as be set up.With size as 60mm × 150mm × 3.5mm As a example by sample, the file of entitled shiyang1.prt is initially set up, then set up right angle seat Mark system, input length, width and height are respectively the parameter of 60mm, 150mm and 3.5mm, just establish sample The threedimensional model of product, UG is exited in deposit after model then is saved as into shiyang1.stl forms System.The subdivision software for being carried using laser forming equipment afterwards carries out the subdivision of threedimensional model, Subdivision software (special-purpose software) is opened, shiyang1.stl files are imported, subdivision ginseng is set Number, CNC program input machine tool control computer 3 is automatically generated by subdivision software.Every layer is cutd open Height is divided to be set as 0.15-0.25mm;The substrate of selection is the aluminium alloy of thickness about 8-12mm Sheet material.After unlatching equipment operation key, laser and powder feed system and lathe start simultaneously, swash Light beam and powder-feeding nozzle are scanned along the motion path of subdivision Software Create and move, and powder is defeated It is sent in laser spot and forms cladding layer afterwards after fusing and solidification, so with the motion of lathe Just continuous cladding process has been started.Sweeping for powder-feeding nozzle is adjusted when proceeding by ground floor cladding It is 150-180 ms/h to retouch speed, and powder feed rate is 9 to 12 gram/minutes, continuous cladding 8-12 layers of formation aluminium alloy initiation layer.
Then, after the completion of aluminium alloy initiation layer cladding, using cuing open that laser forming equipment is carried Component software carries out subdivision to threedimensional model unshaped part again.It is first turned on subdivision software (specially With software), shiyang1.stl files are imported, subdivision parameter is set, by subdivision software certainly Dynamic generation CNC program input machine tool control system computer.Every layer of subdivision is highly set as 0.4mm-0.6mm;The sweep speed for adjusting powder-feeding nozzle is 250-350 ms/h, powder feeding speed Degree 8-12 gram/minutes, stabilize it cladding forming, cladding control program end of run postforming Sample physical member is completed, and whole laser cladding forming process terminates.
The air intake valve and laser of working chamber are closed afterwards, and adjustment digital control system is manual mould Formula, home position is adjusted to by water-cooled machine-tool platform face, opens working chamber's door and ventilation is aerated to it, Operating personnel enter working chamber after 20min, and unnecessary Al alloy powder is removed after sample cooling to be formed End, opens tooling fixture and substrate is removed from water-cooled machine-tool platform face, and the aluminium shaped on substrate is closed Golden sample is aluminum alloy materials formed thereby.
Embodiment 1:The present embodiment manufacture width 60mm, 150mm high, the aluminium of wall thickness 3.5mm are closed Golden sample.Specific manufacturing step is as follows:
The aluminum alloy plate materials of thickness about 12mm are chosen, is fixed on lathe with tooling fixture.Open Laser is opened, laser power parameters as 800W, high-purity carbon dioxide, high-purity He, height are set The pressure of pure N2 is adjusted to 0.5MPa or so, cooling water flow about 20L/min.By aluminium alloy Powder loads powder feeder.The subdivision software set up model and carried using former carries out three-dimensional The subdivision of model, every layer of subdivision is highly set as 0.15mm, the sweep speed of powder-feeding nozzle It is set as 150 ms/h, the gram/minute of powder feed rate 10.During 10 layers of cladding, using shaping The subdivision software that equipment is carried carries out subdivision to threedimensional model unshaped part again, and every layer is cutd open Height is divided to be set as 0.5mm, the sweep speed of powder-feeding nozzle is set as 250 ms/h, send The gram/minute of powder speed 8;Power is 2000W, powder feeding gas flow 12L/min.In 250-350 Between m/h the sweep speed of micro-adjustment powder-feeding nozzle make the speed of growth stabilization, when cladding into When shape is completed, arrestment.Working chamber's air intake valve and laser are closed, by water-cooled machine-tool platform Face is adjusted to home position, remove substrate from water-cooled machine-tool platform face after sample cooling, on substrate The aluminum alloy sample of shaping is that size is 60mm × 150mm × 3.5mm aluminum alloy materials.
Embodiment 2:The present embodiment manufacture height width 40mm, 50mm high, the aluminium of wall thickness 10mm Alloy sample.Specific manufacturing step is substantially the same manner as Example 1, simply in 12 layers of cladding, The subdivision software carried using former carries out subdivision to threedimensional model unshaped part again, Every layer of subdivision is highly set as 0.6mm, the sweep speed of powder-feeding nozzle be set as 300 meters/ Hour, the gram/minute of powder feed rate 10;Power is 2500W, powder feeding gas flow 8L/min.
The above embodiments are merely illustrative of the technical solutions of the present invention rather than is limited, this The those of ordinary skill in field can modify to technical scheme or equally replace Change, without departing from the spirit and scope of the present invention, protection scope of the present invention should be with claim It is described to be defined.

Claims (10)

1. a kind of manufacturing process of aluminium alloy, methods described includes:
(1) threedimensional model of aluminium alloy is set up, and subdivision is carried out to the threedimensional model, according to Subdivision result is worked out cladding control program and is loaded into digital control system;
(2) it is 150-180 to be arranged to control the sweep speed of powder-feeding nozzle by the digital control system M/h, the powder feed rate of powder feed system is set as 9 to 12 gram/minutes, and will be molten The subdivision for covering every layer in control program is highly set as 0.15-0.25mm, the cladding on substrate 8-12 layers, so that basis of formation cladding layer;
(3) sweep speed of powder-feeding nozzle is adjusted to 250-350 ms/h again, while will The powder feed rate of powder feed system is adjusted to 8-12 gram/minutes, and every layer is cutd open in cladding control program Divide Height Adjustment to be 0.5-1.0mm, uniform and stable shaping carried out on the basic cladding layer, Until forming process terminates.
2. the method for claim 1, it is characterised in that:The material of the substrate is The aluminium alloy of titaniferous.
3. method as claimed in claim 1 or 2, it is characterised in that:The material of the substrate Material thickness is 8-12mm.
4. method as claimed any one in claims 1 to 3, it is characterised in that:It is described Oxygen content in the working chamber of cladding is less than 80ppm.
5. the method as any one of Claims 1-4, it is characterised in that:First Argon gas is filled with working chamber to exclude air, 12-16 liters/min of argon flow amount works as shaping About in 1000ppm, open cleaning system makes oxygen content be less than 100ppm to indoor oxygen content.
6. the method as any one of claim 1 to 5, it is characterised in that:It is described The granularity about 50-300 mesh of the Al alloy powder that powder feed system is used.
7. the method for claim 1, it is characterised in that:Form the basic cladding During layer, laser power parameters as 500-1000W are set.
8. method according to any one of claim 1 to 7, it is characterised in that:Enter During the row uniform and stable shaping, laser power parameters as 1500-2500W are set.
9. method according to any one of claim 1 to 7, it is characterised in that:Institute State the granularity about 100-200 mesh of the Al alloy powder of powder feed system use.
10. method according to any one of claim 1 to 7, it is characterised in that:: When forming the basic cladding layer, laser power parameters as 600-800W are set.
CN201510931376.9A 2015-12-14 2015-12-14 A kind of manufacturing process of aluminium alloy Pending CN106862561A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019029031A1 (en) * 2017-08-07 2019-02-14 华南理工大学 Additive manufacturing method for lead-free environmentally-friendly high-strength brass alloy

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019029031A1 (en) * 2017-08-07 2019-02-14 华南理工大学 Additive manufacturing method for lead-free environmentally-friendly high-strength brass alloy
US11401588B2 (en) 2017-08-07 2022-08-02 South China University Of Technology Additive manufacturing method of lead-free environmentally-friendly high-strength brass alloy

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