CN106862534A - One kind manufacture metallurgical binding ply-metal Processes and apparatus - Google Patents

One kind manufacture metallurgical binding ply-metal Processes and apparatus Download PDF

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Publication number
CN106862534A
CN106862534A CN201710087503.0A CN201710087503A CN106862534A CN 106862534 A CN106862534 A CN 106862534A CN 201710087503 A CN201710087503 A CN 201710087503A CN 106862534 A CN106862534 A CN 106862534A
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China
Prior art keywords
outer layer
metal
composite
heating
steel
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CN201710087503.0A
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Chinese (zh)
Inventor
丁家伟
丁刚
耿德英
鹿薇薇
鹿策
施孟达
陈志和
朱坚
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Danyang Hengqing Composite Material Science & Technology Co Ltd
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Danyang Hengqing Composite Material Science & Technology Co Ltd
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Priority to CN201710087503.0A priority Critical patent/CN106862534A/en
Publication of CN106862534A publication Critical patent/CN106862534A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D19/00Casting in, on, or around objects which form part of the product
    • B22D19/16Casting in, on, or around objects which form part of the product for making compound objects cast of two or more different metals, e.g. for making rolls for rolling mills
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D19/00Casting in, on, or around objects which form part of the product
    • B22D19/0081Casting in, on, or around objects which form part of the product pretreatment of the insert, e.g. for enhancing the bonding between insert and surrounding cast metal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D27/00Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
    • B22D27/04Influencing the temperature of the metal, e.g. by heating or cooling the mould
    • B22D27/045Directionally solidified castings

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Metal Rolling (AREA)

Abstract

The invention discloses a kind of metallurgical binding ply-metal manufacturing process and equipment, the outer covering layer of core and heterogeneity including heterogeneity, its composite molding technique includes that entirety is carried out to required composition cladding material pipe using sensing heater is heated to 600~1000 DEG C, inner layer metal liquid founding is poured into, cladded type bimetallic composite blank of the interface in metallurgical binding is manufactured into;The good bimetallic blank of founding is carried out being rolled into ply-metal.The outer layer of manufactured ply-metal and the metallurgical bonding interface of core are formed by founding, dense structure high with bond strength, quality is good, and properties of product are excellent, process is simple, controllability is strong, low cost, efficiency high, the advantages of can meet the processability of unlike material.Scarce resource can be saved, reduces cost is adapted to batch production, with wide application market.

Description

One kind manufacture metallurgical binding ply-metal Processes and apparatus
Technical field
The invention belongs to field of compound material, and in particular to one kind manufactures metallurgical binding ply-metal technique and sets It is standby.
Background technology
Composite metal plate can be different with the kind of facestock according to base material, are prepared into the composite plate of various materials.Including:Steel/ Steel composite board, the steel composite board of stainless steel one, the steel composite board of copper one, the steel composite board of aluminium one, the steel composite board of titanium one and aluminium/titanium, fine silver/ Noble metal composite plate such as silver alloy etc., can be widely applied to the fields such as shipbuilding, aerospace building, electronics, chemical industry, machinery.It is wide It is general to be applied to space flight and aviation, military project, atomic energy, national defence and metallurgy, building materials, ship, oil, chemical industry, power system, electronics device In many fields such as part, machinery, automobile, thermal energy conduction, pharmacy, food, information, civilian.
The production method of current composite metal plate can be divided three classes:Gu a solid phase, liquid-liquid phase and the solid phase composite algorithm of liquid one. Industrial production mainly uses compound casting, Explosion composite and composite technique for rolling.Wherein, casting combination process is by a kind of matrix (solid phase) and another matrix (liquid phase) are combined in mold, and composite is formed after solidification.In proper temperature and pressure Combined strength bination high can be obtained down, be suitable to produce the blank of some metallic composites.Current double metallic composite material is cast as Shape technique can be divided into 3 classes:Covering and casting, double fluid casting and centrifugal casting technique.Other combination process also have casting rolling method, inverse To freezing method.At present still in the laboratory research stage, without industrialized production launch.
Disclosed 1. Chinese invention patent application number is 200710011271.7 entitled systems by literature search The production method of copper clad aluminum wire is made, the production method step is cleaning copper pipe inwall, and coats layer protective layer;In inert gas Under protection, copper pipe is heated, casting motlten metal aluminium in it;Copper cover aluminum base is formed copper clad aluminum wire and be combined through rolling, drawing Strip.The method has the disadvantage that:First, pretreatment procedure is complicated, and single production copper cover aluminum blank, low production efficiency, It is difficult to form continuous prodution, production cost is high;Second, casting process is complicated under protective gas, working environment is poor;Its Three, copper cover aluminum base is cooled down again without long-time heat preservation, and phase counterdiffusion is insufficient between bimetallic constituent element, is not formed to a certain extent Good interface cohesion, reduces interface bond strength.2. Chinese invention patent application number is 200810057668.4 invention names Referred to as a kind of high-performance cooper-coated aluminum rectangle section compound conductive bus row and its preparation technology, the technique are direct using horizontal casting Composite forming copper cladding aluminum composite blank;By copper cover aluminum base by rolling, drawing, again rolling mill practice be finally made copper clad aluminum wire.This The shortcoming that technique is present is essentially consisted in:It is high to equipment requirement, copper clad aluminum wire horizontal continuous casting equipment complex structure, manufacturing cost compared with Height, so as to improve the manufacture difficulty and manufacturing cost of copper-clad aluminum composite panel belt.Chinese invention patent application number is 00806525. In x, there is provided a kind of composite sheet material for brazing, it is coated on metal base after solder bonding metal feed powder end is mixed with organic matter, Soldering flitch is made, for the controlled atmosphere soldering of aluminum device.But, the compound needle material at this coating solder bonding metal feed powder end After organic matter volatilization, solder powder has the possibility for coming off to plate, it is impossible to ensure the uniformity and of solder thickness and Mass Distribution Even property, causes welding device locally to have the possibility of solder skip or burn through, it is necessary to locally be mended to the solder skip or burn through of welding assembly Weldering, so as to increased the manufacturing cost of device weight and device.
Just at present from the point of view of domestic and international ply-metal achievement in research, the composite plate prepared by it belongs to greatly non-metallurgical junction Conjunction state, makes the material show some problems, such as lacks metallurgical binding between two kinds of materials, it will cause that coating is too early to be opened Split, greatly reduce the corrosion resistance of material;The quality control of material, such as coating thickness it is uneven, inside is likely to occur corruption Erosion, makes the mechanical behavior of material indefinite.Above mentioned problem it is short-term and it is long-term in be likely to result in serious consequence.
Pursuing resource minimal consumption, benefit maximum today for obtaining, the premium properties having by composite plate and good Good energy-conservation knot material effect is increasingly favored by people, in order to meet the market demand, improve production efficiency, it is ensured that product matter Amount, reduces production cost, improves input and output qualification rate, must just be had breakthrough in technology, and finding one kind can make life The method for producing maximizing the benefits.Therefore research and development novel dual metal composite plate manufacturing process is to realize high-performance metal composite wood Material high-quality, low cost, the key of high efficiency production.For reducing engineering cost, engineering construction quality, extension engineering knot are improved The service life of structure is significant.With wide market development prospect.
The content of the invention
It is double the invention provides one kind manufacture metallurgical binding for the problem that above-mentioned existing ply-metal technology is present Composite metal plate Processes and apparatus, there is provided a kind of flow is short, method is easy, equipment investment is small, production efficiency is high, low cost, property Can process and equipment good and that be especially suitable for industrial mass production ply-metal.
In order to solve the problems, such as prior art, the technical solution adopted by the present invention is comprised the following steps:
(a)Bimetallic composite blank founding;(b)Compound sheet metal forming;(C)Post processing:
(a)Bimetallic composite blank founding:
Solving the process technology scheme of its technical problem use is:The required material and the outer layer of size that will have been manufactured first are combined Tubes of material(6)After inner wall surface carries out oil removing, processing of rust removing, cleaned using acetone, it is then uniform on cleaned surface One layer of high-temp antioxidizing paint of coating, is fixed in bottom board(13)On the center in molten metal exit above, In outer layer composite material tube(6)One layer of fire resisting material fiber of outside cladding(8), or conduction heating set is installed(19), open Transmission system on dynamic jacking equipment(1)Rotate lifting screw(3)Or hydraulic cylinder(3)Drive and be arranged on lifting column(2)On Lifting arm(4)Will be installed in lifting arm with set speed(4)Electromagnetic induction heater above(5)Drop to outer layer to be combined Tubes of material(6)Bottom, start electromagnetic induction heating power supply, make sensing heater(5)Directly to outer layer composite material tube(6)Enter The overall heating of row, or sensing heater(5)By installed in outer layer of composite material pipe(6)Outside conduction heating set(19)It is right Outer layer of composite material pipe(6)Overall heating is carried out, by installed in outer layer of composite material pipe(6)Temperature thermocouple above(15) Thermometric and control heating-up temperature are carried out, after to be heated to 600 DEG C~1000 DEG C, the internal layer of the required composite parts that will have been smelted is answered Condensation material molten metal(7)Pour into pouring ladle(9)It is interior, by pouring ladle(9)Interior molten metal passes through according to predetermined cast program Depositing funnel(10), feed trumpet(11), casting runner brick(12)Interior a cast runner(14)Pour into outer layer of composite material pipe(6) It is interior, in casting process, electromagnetic induction heater(5)Do not stop heating, molten metal(7)After being poured, sensing heater after It is continuous to carry out heating 10~30 minutes, make poured into a mould molten metal that liquid is kept within the regular hour, to increase the liquid solid time, make Interface forms metallurgical binding, works as molten metal(7)Take a note mode to pour into a mould when being poured at rising head carries out feeding with to rising head, pours After note is finished, heat preserving agent is added in insulated feeder;
When directly being poured into a mould using top, by pouring ladle(9)And gate spool(27)Outer layer of composite material pipe is moved on to together(6)Endoporus Top, by pouring ladle(9)Alignment composite material tube(6)Endoporus center, starts from gate spool(27)Pour into inner layer composite material gold Category liquid(7), molten metal(7)It is poured into composite material tube(6)After interior die cavity, according to poring rate progressively by pouring ladle(9)With Gate spool(27)It is lifted up together, works as molten metal(7)Take a note mode to pour into a mould when being poured at rising head is carried out with to rising head Feeding, after being poured, heat preserving agent is added in insulated feeder;
Start lowering or hoisting gear, by lifting arm(5)Will be installed in lifting arm with set speed(4)Electromagnetic induction above adds Hot device(5)It is lifted up with certain speed, makes electromagnetic induction heater(5)Composite bed is gradually disengaged, while opening bottom water tank (17)Water inlet pipe(16)And outlet pipe(18), make in bottom water tank(17)Under successively cooling from bottom to top, successively order is formed Solidification, and according to quality requirement by controlling electromagnetic induction heater(5)The rate of climb in different regions, realizes region Directional solidification, was raised at insulated feeder by 5~25 minutes and stops, and continued to carrying out heating 10~50 minutes at insulated feeder, To postpone insulated feeder setting time, feeding is carried out to rising head, gas and field trash in composite-layer metal liquid is fully floated, Composite-layer metal casting flaw is eliminated, heating is stopped after reaching the scheduled time, dismounting is coated on outer layer of composite material pipe(6)Outside Fire resisting material fiber(8)Or installed in outer layer of composite material pipe(6)Outside conduction heating set(19), close bottom water tank and enter Water pipe, unclamps outer layer of composite material pipe(6)Fixing device, the interface that will cast is in metallurgical binding by outer layer of composite material (6)And inner layer material(7)It is bimetallic compound interface mixed layer with centre(29)Double metallic composite material from bottom board (13)Hang out above;
When using gas heating, gas supply pipe is opened(24)Valve, light gas nozzle(23), adjust gas quantity big It is small, by high-temperature fuel gas to outer layer composite material tube(6)Heated, after being poured, opened bottom water tank(17)Water inlet Pipe(16)And outlet pipe(18), by bottom water tank(17)Successively cooling from bottom to top is produced, while by gas nozzle(23)By It is lower successively to stop heating upwards, make inner layer material(7)Successively consecutive solidification from bottom to top is formed, and according to quality requirement by control Gas nozzle processed(23)The size of heat time and heating amount in different regions, realizes region directional solidification;
The cladding material of described double metallic composite material(6)Material be stainless steel, mould steel, tool steel, high-speed steel, alloy Steel, mild steel, cast steel, cast iron, alloy cast iron, rich chromium cast iron, titanium, copper, copper alloy, aluminium, aluminium alloy, magnesium, magnesium alloy, Ni-based conjunction Gold, fine silver, silver alloy are one kind of;
Described inner layer composite material(7)Material for stainless steel, mould steel, steel alloy, mild steel, cast steel, cast iron, alloy casting Iron, rich chromium cast iron, titanium, copper, copper alloy, aluminium, aluminium alloy, magnesium, magnesium alloy, nickel-base alloy, fine silver, silver alloy are one kind of;
Described metallurgical binding ply-metal include steel/steel composite board, the steel composite board of stainless steel one, the steel composite board of copper one, The steel composite board of aluminium one, the steel composite board of titanium one, copper/aluminum composite plate, nickel/steel composite board, aluminium/titanium composite panel, fine silver/silver alloy are combined Plate;
The wall thickness of the outer layer blank is the 5%~25% of the bimetallic billet size.
The outer layer of composite material thickness is 0.5mm~1.5mm, and the weight of outer layer of composite material is combined for the bimetallic The 6%~32% of plate gross weight.
Described cladding material pipe(6)It is seamless tubular goods or ERW or spiral welded pipe, geometry includes circle Shape or rectangle;
Described conduction heating set(19)Material be graphite, carborundum.
Described electromagnetic induction power supply is line-frequency induction power supply, medium frequency induction power supply, high frequency induction power supply, and frequency is 500Hz~10000Hz.
(b)Compound sheet metal forming:
The good bimetallic composite blank of founding is put into 320~1280 DEG C are heated in heating furnace, be incubated 30~60 points Clock;The bimetallic composite blank after by heating is placed on milling train, is rolled using existing rolling mill practice, according to required product Size adjusting rolling pass and drafts, by passage tube reducing, and ensure institute's rolling composite plate by existing rolling technological parameter The size and profile of product, the ply-metal product of size needed for obtaining;
The mode of heating of the coating bimetallic composite blank is that gas heating, electrical heating, electromagnetic induction heating, plasma add Heat;
(C)Post processing:
Ply-metal after rolling is annealed, smooth aligning, pickling, trimming scale, ultrasonic examination;Can be according to need The surface of ply-metal is processed, such as surface polishing, embossing, coloring;
Solving the equipment scheme of its technical problem is:The equipment by jacking equipment, induction heating equipment, gas heating equipment, pour Injection system is constituted;Described jacking equipment is single column or planer type structure, in lifting column(2)On power train is installed System(1), by transmission system(1)Rotate lifting screw(3)Or hydraulic cylinder(3)Drive and be arranged on lifting column(2)On lifting Arm(4)Moved up and down with set speed, in lifting arm(4)Above electromagnetic induction heater is installed(5), electromagnetism sense adds Hot device(5)It is connected with electromagnetic induction electrical power control cabinet, bottom board is installed in the bottom of jacking equipment(13), at cast bottom Plate(13)On be provided with a cast runner Cao, in bottom board(13)On a cast runner Cao in be provided with refractory material making cast Runner brick(12), outer layer of composite material pipe(6)It is fixed on bottom board(13)Above, in outer layer composite material tube(6)It is outer Portion coats one layer of fire resisting material fiber(8), or conduction heating set is installed(19), electromagnetic induction heater(5)Install outside Layer composite material tube(6)The fire resisting material fiber of outside(8)Outside, or be directly installed on outer layer of composite material pipe(6)'s Conduction heating set(19)Outside, in outer layer composite material tube(6)Side feed trumpet is installed(11), feed trumpet(11)Under Portion and a cast runner brick(12)It is connected, a cast runner brick(12)Inside there is a cast runner(14), molten metal outlet is installed in outer layer Composite material tube(6)The center of bottom, feed trumpet(11)Top sprue cup is installed(10), in depositing funnel(10) Above have pouring ladle(9), in outer layer composite material tube(6)Above insulated feeder is installed(25)And temperature thermocouple (15), in bottom board(13)Below bottom water tank is installed(17), in bottom water tank(17)The bottom of side is provided with water inlet pipe (16), in bottom water tank(17)The top of side is provided with outlet pipe(18);
In outer layer composite material tube when using gas heating(6)Outside heat insulation mould is installed(20), heat insulation mould(20) It is fixed on bottom board(13)Above, in heat insulation mould(20)Internal layer post heat insulating refractory material(21), in heat insulation mould (20)With outer layer of composite material pipe(6)Intermediate space in gas supply pipe is installed(24), in gas supply pipe(24)It is upper Face is uniformly provided with gas nozzle(23), in heat insulation mould(20)Above heat-preserving cover plate is installed(22);
When directly being poured into a mould using top, in pouring ladle(9)Below hanging draw-in groove is installed(26), gate spool(28)Upper end Sprue cup is installed(27), sprue cup(27)By hanging draw-in groove(26)With pouring ladle(9)It is connected.
Beneficial effect
One kind of the invention manufactures metallurgical binding ply-metal Processes and apparatus, compared with prior art its main feature It is:
1st, double metallic composite material is manufactured using present invention process, the metal for making melting due to special casting method is from bottom to top Solidification, is conducive to the feeding of liquid metals, overcomes the defect that centre spinning is also easy to produce microstructure segregation, manufactured bimetallic Microstructure of composite is uniform, does not have gravity segregation, and crystalline structure is excellent, and the tiny consistency of crystal grain is high, and centrifugation can not be used before making The production of the material of casting production is possibly realized.The range of choice of cladding material and inner layer material is wide, can be according to different Use requirement freely selects the ferrous metal of different performance requirement, nonferrous materials to be combined, so as to meet different works Condition requirement.
6th, the present invention replaces mould straight forming using metal pipe material, and in bimetallic forming process, the technique of casting is received Yield is high, and liquid metals consumption is reduced, and 15~30% are saved than permanent mold casting, and rate of metal is high, has saved material.And And Modeling Material and die cost are saved, and when having saved a large amount of moulders, efficiency is improve, save substantial amounts of manufacture Expense, reduces manufacturing cost, reduces the waste and the pollution of environment of resource and the energy.
7th, the present invention carries out castingin manufacture cladded type bimetallic because outer layer uses shaping pipe, internal layer using liquid metal Composite, with interface firmly, dense internal organization, surface quality is good, and production process is few, low cost, and production efficiency is high etc. Advantage.Both solved the problems, such as that prior art and production efficiency of equipment were low, solve prior art again and equipment be difficult to control to it is double Metal combination interface and the problem being more expensive to manufacture.
Brief description of the drawings
Fig. 1 is a kind of schematic diagram for manufacturing metallurgical binding ply-metal blank Processes and apparatus embodiment 1 of the present invention, Wherein(1)It is transmission system,(2)It is lifting column,(3)It is lifting screw or hydraulic cylinder,(4)It is lifting arm,(5)It is electromagnetism sense Answer heater,(6)It is outer layer of composite material pipe,(7)It is inner layer composite material,(8)It is refractory fibrous material,(9)It is pouring ladle, (10)It is depositing funnel,(11)It is feed trumpet,(12)It is a cast runner brick,(13)It is bottom board,(14)It is a cast runner, (15)It is temperature thermocouple,(16)It is bottom tank inlet pipe,(17)It is bottom water tank,(18)It is bottom radiator drain,(19)It is stone Black heating mantle,(20)It is heat insulation mould,(21)It is insulation fibre,(22)Heat-preserving cover plate,(23)It is gas nozzle,(24)It is combustion gas Pipe,(25)It is insulated feeder,(26)It is hanging draw-in groove,(27)It is sprue cup,(28)It is gate spool,(29)For bimetallic is combined boundary Face mixed layer.
Fig. 2 is a kind of bowing for schematic diagram 1 for manufacturing metallurgical binding ply-metal Processes and apparatus embodiment 1 of the present invention View;
Fig. 3 is a kind of vertical view of the schematic diagram 3 for manufacturing metallurgical binding ply-metal Processes and apparatus embodiment 2 of the present invention Figure;
Fig. 4 is a kind of vertical view of the schematic diagram 4 for manufacturing metallurgical binding ply-metal Processes and apparatus embodiment 3 of the present invention Figure;
Fig. 5 is a kind of vertical view of the schematic diagram 5 for manufacturing metallurgical binding ply-metal Processes and apparatus embodiment 4 of the present invention Figure;
Fig. 6 is a kind of vertical view of the schematic diagram 6 for manufacturing metallurgical binding ply-metal Processes and apparatus embodiment 5 of the present invention Figure;
Fig. 7 is a kind of schematic diagram of manufacture metallurgical binding ply-metal Processes and apparatus embodiment 6 of the present invention.
Fig. 8 is a kind of schematic diagram of manufacture metallurgical binding ply-metal Processes and apparatus embodiment 7 of the present invention.
Fig. 9 is a kind of schematic diagram of manufacture metallurgical binding ply-metal Processes and apparatus embodiment 8 of the present invention.
Figure 10 is a kind of schematic diagram of manufacture metallurgical binding ply-metal Processes and apparatus embodiment 9 of the present invention.
Figure 11 is a kind of schematic diagram of manufacture metallurgical binding ply-metal Processes and apparatus embodiment 10 of the present invention.
Figure 12 is a kind of schematic diagram of manufacture metallurgical binding ply-metal Processes and apparatus embodiment 11 of the present invention.
Figure 13 is a kind of metallurgical binding bimetallic composite blank cross-sectional view of the invention.
Figure 14 is a kind of metallurgical binding bimetallic circle composite blank horizontal cross-section structure diagram of the invention.
Figure 15 is a kind of metallurgical binding bimetallic rectangle composite blank horizontal cross-section structure diagram of the invention.
Figure 16 is a kind of metallurgical binding ply-metal dimensional structure diagram of the invention.
Figure 17 is a kind of metallurgical binding ply-metal horizontal cross-section structure diagram of the invention.
Specific embodiment
With reference to accompanying drawing, embodiments of the invention are provided as follows:
Embodiment 1:Manufacture metallurgical binding stainless steel/carbon ply-metal.
Figure 16 is a kind of metallurgical binding ply-metal dimensional structure diagram of the invention, and it is by carbon steel core metal 7 Constituted along the stainless steel cladding 6 that the length direction of core metal 7 is coated with it, the stainless steel cladding 6 and carbon steel core metal 7 it Between be by founding formed metallurgical binding fused interface layer.
Figure 17 is a kind of metallurgical binding ply-metal horizontal cross-section structure diagram of the invention.
The process technology scheme of the metallurgical binding ply-metal is prepared, is comprised the following steps:
(a)Bimetallic composite blank founding;(b)Compound sheet metal forming;(C)Post processing:
(a)Bimetallic composite blank founding:
The inner wall surface of the stainless steel seamless pipe 6 of outer layer 304 of the required size that will have been manufactured first carries out oil removing, processing of rust removing Afterwards, cleaned using acetone, then in 304 cleaned stainless steel pipe inner surfaces, uniformly one layer of high-temp antioxidizing of coating is applied Material, is fixed on the center in the molten metal exit above bottom board 13, stainless in outer layer of composite material 304 One layer of fire resisting material fiber 8 of outside cladding of steel pipe 6, starts the transmission system 1 on jacking equipment and rotates the drive peace of lifting screw 3 Lifting arm 4 on lifting column 2 will be under the electromagnetic induction heater 5 above lifting arm 4 with set speed The bottom of the stainless steel tube 6 of outer layer of composite material 304 is dropped to, starts electromagnetic induction heating power supply, make sensing heater 5 multiple to outer layer The stainless steel tube 6 of condensation material 304 carries out surface heating, is entered by the temperature thermocouple 15 above the stainless steel tube 6 of outer layer 304 Row thermometric and control heating-up temperature, to be heated to after 890 DEG C, the internal layer mild steel molten metal 7 that will have been smelted pours into pouring ladle 9 It is interior, by the mild steel molten metal in pouring ladle 9 according to predetermined cast program by depositing funnel 10, feed trumpet 11, casting A cast runner 14 in runner brick 12 is poured into the stainless steel tube 6 of outer layer 304, and in casting process, electromagnetic induction heater 5 does not stop Only heat, after mild steel molten metal 7 is poured, sensing heater proceeds heating 18 minutes, makes poured into a mould molten metal Liquid is kept within the regular hour, to increase the liquid solid time, interface is formed metallurgical binding, when mild steel molten metal 7 is poured into a mould Take a note mode to pour into a mould when to rising head carries out feeding with to rising head, after being poured, heat preserving agent is added into insulated feeder It is interior, start lowering or hoisting gear, the electromagnetic induction heater 5 that will be arranged on above lifting arm 4 with set speed by lifting arm 4 It is lifted up with certain speed, electromagnetic induction heater is gradually disengaged composite bed, forms from bottom to top successively consecutive solidification, And the different rates of climb are controlled in different regions according to quality requirement, it was raised at insulated feeder through 10 minutes and is stopped, after It is continuous, to postpone insulated feeder setting time, feeding to be carried out to rising head to carrying out heating 20 minutes at insulated feeder, make composite bed gold Gas and field trash in category liquid are fully floated, and eliminate composite-layer metal casting flaw, and heating is stopped after reaching the scheduled time, are torn open Except the fire resisting material fiber 8 for being coated on the outside of 304 stainless steel tube of outer layer 6, the fixing device of the stainless steel tube 6 of outer layer 304 is unclamped, will The outer layer for having cast be 304 stainless steels and internal layer for mild steel interface in metallurgical binding cladded type bimetallic composite blank 7 (Figure 13)Hung out from above bottom board 13.
Described electromagnetic induction power supply is medium frequency induction power supply, and frequency is 750Hz.
It is a kind of basic structure of metallurgical binding bimetallic circle composite blank provided in an embodiment of the present invention shown in Figure 13 Schematic diagram, Figure 14 show a kind of metallurgical binding bimetallic circle composite blank provided in an embodiment of the present invention laterally section knot Structure schematic diagram.
The stainless-steel pipe blank 6 of outer layer is circular ERW in the present embodiment, its specific size be Φ 150 × 5 × 2000 (external diameter × wall thickness × length, mm);
(b)Compound sheet metal forming:
The good bimetallic composite blank of founding is put into 1280 DEG C are heated in heating furnace, be incubated 50 minutes;After heating The bimetallic composite blank be placed on milling train, using existing rolling mill practice roll, rolled according to required product size adjusting Passage processed and drafts, by passage tube reducing, and ensure the size of institute's Rolling compund panel products by existing rolling technological parameter And profile, the stainless steel/carbon ply-metal product of size needed for obtaining, product structure figure is as schemed(16), product transverse direction Cross-sectional view is as schemed(17);
In above-mentioned hot rolling technology, the metallurgical binding stainless steel cladding bimetallic circle composite blank of electromagnetism founding is in high temperature, high pressure Under the conditions of better diffusion layer is formed at contact interface, interface bond strength is further increased, so as to improve its extension Rate, tensile strength.
(C)Post processing:
Stainless steel/carbon ply-metal after rolling is annealed, smooth aligning, pickling, trimming scale, ultrasonic wave visit Wound;The surface of ply-metal can be processed as needed, such as surface polishing, embossing, coloring;
The mode of heating of the bimetallic composite blank is gas heating;
Realizing the equipment scheme of metallurgical binding bimetallic composite blank is:
In Fig. 1, the equipment is made up of jacking equipment, induction heating equipment, gas heating equipment, running gate system;Described liter Drop equipment is single column or planer type structure, and transmission system 1 is provided with lifting column 2, is rotated by transmission system 1 Lifting screw 3 or hydraulic cylinder 3 drive the lifting arm 4 on lifting column 2 to be moved up and down with set speed, in lifting Electromagnetic induction heater 5 is installed, electromagnetic induction heater 5 is connected with electromagnetic induction electrical power control cabinet above arm 4, is rising The bottom of drop equipment is provided with bottom board 13, and a cast runner Cao is provided with bottom board 13, pouring on bottom board 13 The a cast runner brick 12 of refractory material making is installed, outer layer of composite material pipe 6 is fixed on bottom board 13 in beam road Cao Above, in one layer of fire resisting material fiber 8 of outside cladding of outer layer composite material tube 6, electromagnetic induction heater 5 is multiple installed in outer layer The outside of the fire resisting material fiber 8 of the outside of condensation material pipe 6, feed trumpet 11, middle note are provided with the side of outer layer composite material tube 6 The bottom of pipe 11 is connected with a cast runner brick 12, there is a cast runner 14 in a cast runner brick 12, and molten metal outlet is installed outside The center of layer composite material tube 6 bottom, the top of feed trumpet 11 is provided with sprue cup 10, above depositing funnel 10 There is pouring ladle 9, insulated feeder 25 and temperature thermocouple 15 are installed above outer layer composite material tube 6.
Embodiment 2:Manufacture metallurgical binding stainless steel-three layers of aluminium-stainless steel ply-metal.
Figure 16 is a kind of metallurgical binding ply-metal dimensional structure diagram of the invention, and it is by the He of aluminium core metal 7 It is constituted along the stainless steel cladding 6 that the length direction of core metal 7 is coated, between the stainless steel cladding 6 and carbon steel core metal 7 It is the fused interface layer of the metallurgical binding formed by founding.
Figure 17 is a kind of metallurgical binding ply-metal horizontal cross-section structure diagram of the invention.
The process technology scheme of the metallurgical binding stainless steel-aluminium-rustless steel double-metal composite plate is prepared, including it is following Step:
(a)Bimetallic composite blank founding;(b)Compound sheet metal forming;(C)Post processing:
(a)Coating bimetallic blank founding;
The inner wall surface of the austenitic stainless steel seamless pipe 6 of outer layer 304 of the required size that will have been manufactured first carries out oil removing, rust cleaning After treatment, cleaned using acetone, then uniformly coated a floor height in 304 cleaned Austenitic stainless steel pipe inner surfaces Warm antioxidizing paint, is fixed on the center in the molten metal exit above bottom board 13, difficult to understand in outer layer 304 One layer of fire resisting material fiber 8 of outside cladding of family name's body stainless steel tube 6, starts the transmission system 1 on jacking equipment and rotates lifting spiral shell Bar 3 drives the electromagnetic induction that the lifting arm 4 on lifting column 2 will be arranged on above lifting arm 4 with set speed Heater 5 drops to the bottom of the Austenitic stainless steel pipe 6 of outer layer 304, starts electromagnetic induction heating power supply, makes sensing heater 5 Surface heating is carried out to the austenitic stainless steel steel pipe 6 of outer layer 304, by above the Austenitic stainless steel pipe 6 of outer layer 304 Temperature thermocouple 15 carry out thermometric and control heating-up temperature, it is to be heated to after 890 DEG C, fine aluminium block is heated to 750~800 DEG C It is melted into fine aluminium liquid 7 to be subsequently poured into pouring ladle 9, the fine aluminium liquid in pouring ladle 9 is passed through according to predetermined cast program A cast runner 14 in depositing funnel 10, feed trumpet 11, casting runner brick 12 pours into the austenite stainless of outer layer of composite material 304 In steel pipe 6, in casting process, electromagnetic induction heater 5 do not stop heating, after fine aluminium liquid 7 is poured, sensing heater after It is continuous to carry out heating 18 minutes, make poured into a mould molten metal that liquid is kept within the regular hour, to increase the liquid solid time, make interface Metallurgical binding is formed, take a note mode to pour into a mould when fine aluminium liquid 7 is poured at rising head carries out feeding with to rising head, is poured Afterwards, heat preserving agent is added in insulated feeder, starts lowering or hoisting gear, will be installed in liter with set speed by lifting arm 4 Electromagnetic induction heater 5 above drop arm 4 is lifted up with certain speed, gradually disengages electromagnetic induction heater compound Layer, forms from bottom to top successively consecutive solidification, and the different rates of climb are controlled in different regions according to quality requirement, passes through It is raised within 10 minutes at insulated feeder and stops, continuing to carrying out heating 20 minutes at insulated feeder, when being solidified with postponing insulated feeder Between, feeding is carried out to rising head, gas and field trash in composite-layer metal liquid is fully floated, eliminate composite-layer metal casting and lack Fall into, heating is stopped after reaching the scheduled time, dismounting is coated on the fire resisting material fiber of the outside of 304 Austenitic stainless steel pipe of outer layer 6 8, the fixing device of the Austenitic stainless steel pipe 6 of outer layer 304 is unclamped, the outer layer that will cast is 304 austenitic stainless steels and interior Layer is the interface of fine aluminium in the cladded type bimetallic composite blank 7 of metallurgical binding(Figure 13 and Figure 14)Hung from above bottom board 13 Go out.
The combination interface of stainless steel layer 6 described in the present embodiment and the fine aluminium core 7 is metallurgical bonding interface, this smelting Golden combination interface be the stainless steel layer 6 and the fine aluminium core 7 interface between the counterdiffusion of atom phase and the combination that is formed, its knot It is that mechanical bond to be compared to close intensity and structural stability, there is good processing performance.
Described electromagnetic induction power supply is medium frequency induction power supply, and frequency is 1000Hz.
It is a kind of base of metallurgical binding rustless steel double-metal rectangle composite blank provided in an embodiment of the present invention shown in Figure 13 This structural representation, Figure 15 show a kind of metallurgical binding stainless steel cladding bimetallic rectangle provided in an embodiment of the present invention and is combined Blank laterally cuts open cross-sectional view.
The stainless-steel pipe blank 6 of outer layer is Rectangular Welded Pipe in the present embodiment, and the geometry of cross section is square, side A length of 120mm, stainless steel thickness is 6mm, and length is 3000 mm.
The present embodiment is with the difference of embodiment 1, is below feed trumpet 11 with the difference of Fig. 2 in figure 3 Casting runner brick 12 in a cast runner 14 be the outlet of 2 molten metals, during cast, molten metal is by feed trumpet 11 from pouring beam 2 molten metals outlet in road 14 is flowed out simultaneously, once can directly pour into a mould 2 outer layers for 304 austenitic stainless steels and internal layer are pure The cladded type bimetallic composite blank of aluminium.Other processes and equipment are same as Example 1.Slightly.
(b)Compound sheet metal forming:
The good bimetallic composite blank of founding is put into 450~500 DEG C are heated in heating furnace, be incubated 50 minutes;To add The bimetallic composite blank after heat is placed on milling train, is rolled using existing rolling mill practice, is adjusted according to required product size Whole rolling pass and drafts, by passage tube reducing, and ensure institute's Rolling compund panel products by existing rolling technological parameter Size and profile, the stainless steel-aluminium-rustless steel double-metal composite board product of size needed for obtaining, product structure figure is as schemed (16), product horizontal cross-section structure diagram is as schemed(17);
In above-mentioned hot rolling technology, the metallurgical binding stainless steel-Al bimetal rectangle composite blank of electromagnetism founding is in high temperature, high pressure Under the conditions of better diffusion layer is formed at contact interface, interface bond strength is further increased, so as to improve its extension Rate, tensile strength.
(C)Post processing:
Stainless steel-aluminium-rustless steel double-metal composite plate after rolling is annealed, smooth aligning, pickling, trimming scale, Ultrasonic examination;The surface of ply-metal can be processed as needed, such as surface polishing, embossing, coloring;
The mode of heating of the bimetallic composite blank is gas heating, electrical heating, electromagnetic induction heating, heating plasma;
Embodiment 3:In fig. 4, it is to pour beam in casting runner brick 12 below feed trumpet 11 with the difference of Fig. 2 Road 14 is 3 molten metal outlets, and during cast, molten metal is exported simultaneously by feed trumpet 11 from 3 molten metals of a cast runner 14 Outflow, once can directly pour into a mould 3 outer layers for mould steel and internal layer are the bimetallic composite blank of low-alloy steel.Other processes and Equipment is same as Example 1.Slightly.
Embodiment 4:In Figure 5, with the difference of Fig. 2 it is pouring in casting runner brick 12 below feed trumpet 11 Beam road 14 is four molten metal outlets, and during cast, molten metal is gone out by feed trumpet 11 from four molten metals of a cast runner 14 Mouth flows out simultaneously, once can directly pour into a mould four outer layers for stainless steel and internal layer are the bimetallic composite blank of low-alloy steel.Its Its process and equipment are same as Example 1.Slightly.
Embodiment 5:In figure 6, with the difference of Fig. 2 it is pouring in casting runner brick 12 below feed trumpet 11 Beam road 14 is 6 molten metal outlets, and during cast, molten metal is exported by feed trumpet 11 from 6 molten metals of a cast runner 14 Flow out simultaneously, once can directly pour into a mould 6 outer layers for stainless steel and internal layer are the bimetallic composite blank of low-alloy steel.Other mistakes Journey and equipment are same as Example 1.Slightly.
Embodiment 6:Manufacture metallurgical binding copper-three layers of Solder for Al-Cu Joint Welding ply-metal.
Figure 16 is a kind of metallurgical binding ply-metal dimensional structure diagram of the invention, and it is by fine aluminium core metal 7 Constituted along the red copper coating 6 that the length direction of core metal 7 is coated with it, be between the red copper coating 6 and fine aluminium core metal 7 The fused interface layer of the metallurgical binding formed by founding.
Figure 17 is a kind of metallurgical binding ply-metal horizontal cross-section structure diagram of the invention.
The process technology scheme of the metallurgical binding ply-metal is manufactured, is comprised the following steps:
(a)Bimetallic composite blank founding;(b)Compound sheet metal forming;(C)Post processing:
(a)Bimetallic composite blank founding:
In the figure 7, the difference from Fig. 1 is that 1 rotational hydraulic cylinder of transmission system 3 drives the lifting arm 4 on lifting column 2 Moved up and down with set speed, graphite heating set 19 is installed in the outside of outer layer composite material tube 6.
After the inner wall surface of the outer layer red copper seamless pipe 6 of the required size that will have been manufactured first carries out oil removing, processing of rust removing, Cleaned using acetone, then uniformly coated one layer of high-temp antioxidizing paint in cleaned red copper pipe internal surface, consolidate It is scheduled on the center in the molten metal exit above bottom board 13, being provided with graphite in the outside of outer layer copper tube 6 adds Hot jacket 19, starts the 1 rotational hydraulic cylinder of transmission system 3 on jacking equipment and drives the lifting arm 4 being arranged on lifting column 2 with institute The electromagnetic induction heater 5 being arranged on above lifting arm 4 is dropped to the speed of setting the bottom of outer layer of composite material copper tube 6 Portion, starts electromagnetic induction heating power supply, sensing heater 5 is carried out surface heating to outer layer copper tube 6, by installed in outer layer Temperature thermocouple 15 above copper tube 6 carries out thermometric and control heating-up temperature, to be heated to after 780 DEG C, in having smelted Layer composite pure aluminum metal liquid 7 is poured into pouring ladle 9, and the fine aluminium liquid in pouring ladle 9 is led to according to predetermined cast program The a cast runner 14 crossed in depositing funnel 10, feed trumpet 11, casting runner brick 12 is poured into outer layer copper tube 6, in casting process In, electromagnetic induction heater 5 does not stop heating, and after fine aluminium liquid 7 is poured, sensing heater proceeds heating 18 minutes, Make poured into a mould molten metal that liquid is kept within the regular hour, to increase the liquid solid time, interface is formed metallurgical binding, when pure Aluminium liquid 7 takes a note mode to pour into a mould and carries out feeding with to rising head when being poured at rising head, after being poured, heat preserving agent is added to In insulated feeder, start lowering or hoisting gear, the electromagnetism sense that will be arranged on above lifting arm 4 with set speed by lifting arm 4 Answer heater 5 to be lifted up with certain speed, electromagnetic induction heater is gradually disengaged composite bed, formed from bottom to top successively Consecutive solidification, and the different rates of climb are controlled in different regions according to quality requirement, it was raised to insulated feeder through 10 minutes Place stops, and continues, to carrying out heating 20 minutes at insulated feeder, to postpone insulated feeder setting time, feeding to be carried out to rising head, Gas and field trash in composite-layer metal liquid is fully floated, composite-layer metal casting flaw is eliminated, after reaching the scheduled time Stop heating, dismounting is coated on the fire resisting material fiber 8 of the outside of outer layer copper tube 6, unclamps the fixing device of outer layer copper tube 6, The outer layer that will have been cast be red copper and internal layer for fine aluminium interface in metallurgical binding cladded type bimetallic composite blank 7(Figure 13 And Figure 14)Hung out from above bottom board 13.
The combination interface of the layer of red copper described in the present embodiment 6 and the fine aluminium core 7 is metallurgical bonding interface, this metallurgy Combination interface be red copper layer 6 and the fine aluminium core 7 interface between the counterdiffusion of atom phase and the combination that is formed, it combines strong Degree and structural stability are that mechanical bond to be compared, and have good processing performance.
Described electromagnetic induction power supply is medium frequency induction power supply, and frequency is 1500Hz.
It is a kind of metallurgical binding red copper coating bimetallic rectangle composite blank provided in an embodiment of the present invention shown in Figure 13 Basic structure schematic diagram, Figure 15 show a kind of metallurgical binding red copper coating bimetallic rectangle provided in an embodiment of the present invention and is combined Blank laterally cuts open cross-sectional view.
The red copper blank 6 of outer layer is Rectangular Welded Pipe in the present embodiment, and the geometry of cross section is square, and the length of side is 150mm, stainless steel thickness is 7mm, and length is 3000 mm.
Other processes and equipment are same as Example 1.Slightly.
(b)Compound sheet metal forming:
The good bimetallic composite blank of founding is put into 450~500 DEG C are heated in heating furnace, be incubated 50 minutes;To add The bimetallic composite blank after heat is placed on milling train, is rolled using existing rolling mill practice, is adjusted according to required product size Whole rolling pass and drafts, by passage tube reducing, and ensure institute's Rolling compund panel products by existing rolling technological parameter Size and profile, three layers of ply-metal product of copper-Solder for Al-Cu Joint Welding of size needed for obtaining, product structure figure is as schemed(16), produce Product horizontal cross-section structure diagram is as schemed(17);
In above-mentioned hot rolling technology, the metallurgical binding copper-aluminum cladding bimetallic rectangle composite blank of electromagnetism founding is in high temperature, high pressure Under the conditions of better diffusion layer is formed at contact interface, interface bond strength is further increased, so as to improve its extension Rate, tensile strength.
(C)Post processing:
Three layers of ply-metal of copper-Solder for Al-Cu Joint Welding after rolling are annealed, smooth aligning, pickling, trimming scale, ultrasound Wave inspection;The surface of ply-metal can be processed as needed, such as surface polishing, embossing, coloring;
The mode of heating of the bimetallic composite blank is electrical heating;
Embodiment 7:Prepare the bimetal copper-steel composite plate of metallurgical binding copper one.
Figure 16 is a kind of metallurgical binding ply-metal dimensional structure diagram of the invention, and it is by carbon steel core metal 7 Constituted along the red copper coating 6 that the length direction of core metal 7 is coated with it, be between the red copper coating 6 and carbon steel core metal 7 The fused interface layer of the metallurgical binding formed by founding.
Figure 17 is a kind of metallurgical binding ply-metal horizontal cross-section structure diagram of the invention.
The process technology scheme of the metallurgical binding ply-metal is manufactured, is comprised the following steps:
(a)Bimetallic composite blank founding;(b)Compound sheet metal forming;(C)Post processing:
(a)Bimetallic composite blank founding:
In fig. 8, it is that bottom water tank 17 is installed below base plate 13 with the difference of Fig. 7, the bottom of the side of water tank 17 bottom of at Water inlet pipe 16 is installed, the top of the side of water tank 17 is provided with outlet pipe 18 bottom of at.
During work, the rotation lifting screw 3 of transmission system 1 started on jacking equipment is driven on lifting column 2 The electromagnetic induction heater 5 being arranged on above lifting arm 4 is dropped to outer layer copper tube 6 by lifting arm 4 with set speed Bottom, opens the water inlet pipe 16 and outlet pipe 18 of bottom water tank 17, starts electromagnetic induction heating power supply, passes through sensing heater 5 Graphite heating outside outer layer of composite material copper tube 6 covers 19 pairs of outer layer copper tubes 6 carries out surface heating, by installing Temperature thermocouple 15 on outer layer copper tube 6 carries out thermometric and control heating-up temperature, to be heated to after 850 DEG C, will smelt The internal layer carbon steel 7 of good required composite parts is poured into be poured into a mould in pouring ladle 9, and heating is stopped after reaching the scheduled time, is passed through The successively cooling from bottom to top of bottom water tank 17, forms successively consecutive solidification, and add by controlling electromagnetic induction according to quality requirement The rate of climb of the hot device 5 in different regions, realizes region directional solidification;Remove the stone outside outer layer copper tube 6 Black heating mantle 19, closes bottom tank inlet pipe, unclamps the fixing device of outer layer copper tube 6, the He of outer layer copper tube 6 that will have been cast Interface between inner layer material carbon steel 7 is in the cladded type bimetallic composite blank of metallurgical binding(Figure 13)From above bottom board 13 Hang out.Other processes and equipment are identical with embodiment 1.Slightly.
Described electromagnetic induction power supply is medium frequency induction power supply, and frequency is 500 Hz.
The red copper blank 6 of outer layer is round seamless steel pipe in the present embodiment, and its specific size is Φ 170 × 8 × 2200 (external diameter × wall thickness × length, mm).
(b)Compound sheet metal forming:
The good bimetallic composite blank of founding is put into 950~980 DEG C are heated in heating furnace, be incubated 50 minutes;To add The bimetallic composite blank after heat is placed on milling train, is rolled using existing rolling mill practice, is adjusted according to required product size Whole rolling pass and drafts, by passage tube reducing, and ensure institute's Rolling compund panel products by existing rolling technological parameter Size and profile, copper-three layers of steel-copper ply-metal product of size needed for obtaining, product structure figure is as schemed(16), produce Product horizontal cross-section structure diagram is as schemed(17);
In above-mentioned hot rolling technology, the metallurgical binding copper-steel coating bimetallic circle composite blank of electromagnetism founding is in high temperature, high-pressure section Better diffusion layer is formed under part at contact interface, interface bond strength is further increased, thus improve its elongation percentage, Tensile strength.
(C)Post processing:
Copper after rolling-three layers of steel-copper ply-metal is annealed, smooth aligning, pickling, trimming scale, ultrasound Wave inspection;The surface of ply-metal can be processed as needed, such as surface polishing, embossing, coloring;
The mode of heating of the bimetallic composite blank is electrical heating.
Embodiment 8:Prepare metallurgical binding titanium-three layers of steel-titanium ply-metal.
Figure 16 is a kind of metallurgical binding ply-metal dimensional structure diagram of the invention, and it is by carbon steel core metal 7 Constituted along the titanium coating 6 that the length direction of core metal 7 is coated with it, be to pass through between the titanium coating 6 and carbon steel core metal 7 The fused interface layer of the metallurgical binding that founding is formed.
Figure 17 is a kind of metallurgical binding ply-metal horizontal cross-section structure diagram of the invention.
The process technology scheme of the metallurgical binding ply-metal is prepared, is comprised the following steps:
(a)Bimetallic composite blank founding;(b)Compound sheet metal forming;(C)Post processing:
(a)Bimetallic composite blank founding:
In fig .9, it is to use gas heating with the difference of Fig. 1, insulation mould is installed in the outside of outer layer of composite material titanium tube 6 Tool 20, heat insulation mould 20 is fixed on above bottom board 13, and heat insulating refractory material 21 is posted in the internal layer of heat insulation mould 20, Gas supply pipe 24 is installed in heat insulation mould 20 and the intermediate space of outer layer of composite material pipe 6, in the upper of gas supply pipe 24 Face is uniformly provided with gas nozzle 23, and heat-preserving cover plate 22 is provided with above heat insulation mould 20.
During work, the valve of gas supply pipe 24 is opened, gas nozzle 23 is lighted, by high-temperature fuel gas to outer layer titanium tube 6 Heated, the internal layer carbon steel liquid 7 of the required composite parts that will have been smelted is poured into be poured into a mould in pouring ladle 9, when being poured Afterwards, successively order is solidifying to take the mode for successively stopping gas nozzle 23 from bottom to top inner layer material carbon steel 7 is formed from bottom to top Gu;The fixing device of outer layer of composite material titanium tube 6 is unclamped, between the cladding material titanium tube 6 that will have been cast and inner layer material carbon steel 7 Interface in metallurgical binding cladded type bimetallic composite blank(Figure 13)Hung out from above bottom board 13.
In the present embodiment the titanium tube blank 6 of outer layer be round seamless steel pipe, its specific size be Φ 150 × 8 × 2000 (outward Footpath × wall thickness × length, mm).
Other processes and equipment are identical with embodiment 1.Slightly.
(b)Compound sheet metal forming:
The good bimetallic composite blank of founding is put into 1150 DEG C are heated in heating furnace, be incubated 50 minutes;After heating The bimetallic composite blank be placed on milling train, using existing rolling mill practice roll, rolled according to required product size adjusting Passage processed and drafts, by passage tube reducing, and ensure the size of institute's Rolling compund panel products by existing rolling technological parameter And profile, the titanium/carbon steel ply-metal product of size needed for obtaining, product structure figure is as schemed(16), product horizontal section Structural representation is as schemed(17);
In above-mentioned hot rolling technology, the metallurgical binding titanium coating bimetallic circle composite blank of electromagnetism founding is in high temperature, condition of high voltage Better diffusion layer is formed at lower contact interface, interface bond strength is further increased, so as to improve its elongation percentage, resist Tensile strength.
(C)Post processing:
Titanium after rolling/carbon steel ply-metal is annealed, smooth aligning, pickling, trimming scale, ultrasonic examination; The surface of ply-metal can be processed as needed, such as surface polishing, embossing, coloring;
Embodiment 9:Manufacture metallurgical binding nickel-base alloy-three layers of steel-nickel-base alloy ply-metal.
Figure 16 is a kind of metallurgical binding ply-metal dimensional structure diagram of the invention, and it is by carbon steel core metal 7 Constituted along the nickel coating 6 that the length direction of core metal 7 is coated with it, between the nickel-base alloy coating 6 and carbon steel core metal 7 It is the fused interface layer of the metallurgical binding formed by founding.
Figure 17 is a kind of metallurgical binding ply-metal horizontal cross-section structure diagram of the invention.
The process technology scheme of the metallurgical binding ply-metal is manufactured, is comprised the following steps:
(a)Bimetallic composite blank founding;(b)Compound sheet metal forming;(C)Post processing:
(a)Bimetallic composite blank founding:
In Fig. 10, it is that bottom water tank 17 is installed below base plate 13 with the difference of Fig. 9, the bottom of the side of water tank 17 bottom of at Water inlet pipe 16 is installed, the top of the side of water tank 17 is provided with outlet pipe 18 bottom of at.
During work, the valve of gas supply pipe 24 is opened, gas nozzle 23 is lighted, by high-temperature fuel gas to cladding material nickel Base alloy pipe 6 is heated, and the internal layer carbon steel liquid 7 of the required composite parts that will have been smelted is poured into be poured into a mould in pouring ladle 9, when After being poured, open the water inlet pipe 16 and outlet pipe 18 of bottom water tank 17, by bottom water tank 17 produce from bottom to top it is successively cold But, while taking the mode for successively stopping gas nozzle 23 from bottom to top to make inner layer material 7, successively consecutive solidification, and root are formed According to quality requirement by controlling the size of heat time and heating amount of the gas nozzle 23 in different regions, realize that region is determined To solidification;Unclamp the fixing device of cladding material nickel-based alloy pipe 6, the cladding material nickel-base alloy 6 and internal layer material that will have been cast Interface between material carbon steel 7 is in the cladded type bimetallic composite blank of metallurgical binding(Figure 13)Hung out from above bottom board 13.
In the present embodiment the nickel tube blank 6 of outer layer be round seamless steel pipe, its specific size be Φ 160 × 8 × 2000 (outward Footpath × wall thickness × length, mm).
Other processes and equipment are identical with embodiment 1 and 8.Slightly.
(b)Compound sheet metal forming:
The good bimetallic composite blank of founding is put into 1100 DEG C are heated in heating furnace, be incubated 50 minutes;After heating The bimetallic composite blank be placed on milling train, using existing rolling mill practice roll, rolled according to required product size adjusting Passage processed and drafts, by passage tube reducing, and ensure the size of institute's Rolling compund panel products by existing rolling technological parameter And profile, the nickel carbon bimetal copper-steel composite board product of size needed for obtaining, product structure figure is as schemed(16), product horizontal section Structural representation is as schemed(17);
In above-mentioned hot rolling technology, the metallurgical binding nickel coating bimetallic circle composite blank of electromagnetism founding is in high temperature, condition of high voltage Better diffusion layer is formed at lower contact interface, interface bond strength is further increased, so as to improve its elongation percentage, resist Tensile strength.
(C)Post processing:
Nickel-base alloy after rolling/carbon steel ply-metal is annealed, smooth aligning, pickling, trimming scale, ultrasonic wave Flaw detection;The surface of ply-metal can be processed as needed, such as surface polishing, embossing, coloring;
Embodiment 10:Manufacture metallurgical binding stainless steel-three layers of aluminium-stainless steel ply-metal.
Figure 16 is a kind of metallurgical binding ply-metal dimensional structure diagram of the invention, and it is by carbon steel core metal 7 Constituted along the stainless steel cladding 6 that the length direction of core metal 7 is coated with it, the stainless steel cladding 6 and carbon steel core metal 7 it Between be by founding formed metallurgical binding fused interface layer.
Figure 17 is a kind of metallurgical binding ply-metal horizontal cross-section structure diagram of the invention.
The process technology scheme of the metallurgical binding ply-metal is manufactured, is comprised the following steps:
(a)Bimetallic composite blank founding;(b)Compound sheet metal forming;(C)Post processing:
(a)Bimetallic composite blank founding:
In fig. 11, it is directly to be poured into a mould using top with the difference of Fig. 1, hanging draw-in groove 26 is installed below pouring ladle 9, The upper end of gate spool 28 is provided with sprue cup 27, and sprue cup 27 is connected by hanging draw-in groove 26 with pouring ladle 9;Under base plate 13 Face is provided with bottom water tank 17, and the bottom of at, the bottom of the side of water tank 17 is provided with water inlet pipe 16, and the bottom of at, the top of the side of water tank 17 is installed There is outlet pipe 18.
During work, pouring ladle 9 and gate spool 27 are moved on into the endoporus of outer layer 306L stainless steel tubes 6 top together, by pouring ladle 9 The endoporus center of alignment 306L stainless steel tubes 6, beginning pours into internal layer aluminum alloy melt 7 from gate spool 27, and aluminum alloy melt 7 is poured into 306L After die cavity in stainless steel tube 6, progressively pouring ladle 9 and gate spool 27 are lifted up together according to poring rate, work as aluminium alloy Liquid 7 takes a note mode to pour into a mould and carries out feeding with to rising head when being poured at rising head, after being poured, heat preserving agent is added into guarantor Temperature emits intraoral, opens the water inlet pipe 16 and outlet pipe 18 of bottom water tank 17, bottom water tank 17 is produced successively cooling from bottom to top, will Sensing heater 5 is lifted up, and forms from bottom to top successively consecutive solidification.
The 306L stainless steel tubes steel tube blank 6 of outer layer is round seamless steel pipe in the present embodiment, and its specific size is Φ 150 × 7.5 × 2500 (external diameter × wall thickness × length, mm).
Other processes and equipment are same as Example 1.Slightly.
(b)Compound sheet metal forming:
The good bimetallic composite blank of founding is put into 450~500 DEG C are heated in heating furnace, be incubated 60 minutes;To add The bimetallic composite blank after heat is placed on milling train, is rolled using existing rolling mill practice, is adjusted according to required product size Whole rolling pass and drafts, by passage tube reducing, and ensure institute's Rolling compund panel products by existing rolling technological parameter Size and profile, the stainless steel-aluminium-rustless steel double-metal composite board product of size needed for obtaining, product structure figure is as schemed (16), product horizontal cross-section structure diagram is as schemed(17);
In above-mentioned hot rolling technology, the metallurgical binding stainless steel cladding bimetallic circle composite blank of electromagnetism founding is in high temperature, high pressure Under the conditions of better diffusion layer is formed at contact interface, interface bond strength is further increased, so as to improve its extension Rate, tensile strength.
(C)Post processing:
Stainless steel-aluminium-rustless steel double-metal composite plate after rolling is annealed, smooth aligning, pickling, trimming scale, Ultrasonic examination;The surface of ply-metal can be processed as needed, such as surface polishing, embossing, coloring;
Embodiment 11:Prepare metallurgical binding stainless steel and carbon steel-three layers of stainless steel ply-metal.
Figure 16 is a kind of metallurgical binding ply-metal dimensional structure diagram of the invention, and it is by carbon steel core metal 7 Constituted along the stainless steel cladding 6 that the length direction of core metal 7 is coated with it, the stainless steel cladding 6 and carbon steel core metal 7 it Between be by founding formed metallurgical binding fused interface layer.
Figure 17 is a kind of metallurgical binding ply-metal horizontal cross-section structure diagram of the invention.
The process technology scheme of the metallurgical binding ply-metal is manufactured, is comprised the following steps:
(a)Bimetallic composite blank founding;(b)Compound sheet metal forming;(C)Post processing:
(a)Bimetallic composite blank founding:
In fig. 12, it is to use gas heating with the difference of Fig. 1 and Figure 11, in outer layer of composite material 10Cr17 ferrites The outside of stainless steel tube 6 is provided with heat insulation mould 20, and heat insulation mould 20 is fixed on above bottom board 13, in heat insulation mould 20 Internal layer post heat insulating refractory material 21, in the centre of heat insulation mould 20 and outer layer composite wood 10Cr17 ferrite stainless steel pipes 6 Gas supply pipe 24 is installed in gap, gas nozzle 23 uniformly is installed above gas supply pipe 24, in insulation mould Heat-preserving cover plate 22 is installed above tool 20.
When work starts, the valve of gas supply pipe 24 is opened, gas nozzle 23 is lighted, by high-temperature fuel gas to outer layer 10Cr17 ferrite stainless steel pipes 6 are heated, and the internal layer low-alloy molten steel 7 of the required composite parts that will have been smelted is poured into and poured In note bag 9, pouring ladle 9 and gate spool 27 are moved on into the endoporus of outer layer 10Cr17 ferrite stainless steel pipes 6 top together, will poured into a mould Bag 9 is directed at the endoporus center of 10Cr17 ferrite stainless steel pipes 6, and beginning pours into internal layer low-alloy steel molten metal 7 from gate spool 27, After molten metal 7 is poured into the die cavity in 10Cr17 ferrite stainless steel pipes 6, according to poring rate progressively by pouring ladle 9 and cast Pipe 27 is lifted up together, and take a note mode to pour into a mould when molten metal 7 is poured at rising head carries out feeding with to rising head, cast After finishing, heat preserving agent is added in insulated feeder, opens the water inlet pipe 16 and outlet pipe 18 of bottom water tank 17, produce bottom water tank 17 Raw successively cooling from bottom to top, sensing heater 5 is lifted up, and forms from bottom to top successively consecutive solidification, and according to matter Amount requires the size by controlling heat time and heating amount of the gas nozzle 23 in different regions, realizes that region orientation is solidifying Gu.
In the present embodiment the stainless-steel pipe blank 6 of outer layer be round seamless steel pipe, its specific size be Φ 150 × 6 × 2300 (external diameter × wall thickness × length, mm).
(b)Compound sheet metal forming:
The good bimetallic composite blank of founding is put into 1280 DEG C are heated in heating furnace, be incubated 50 minutes;After heating The bimetallic composite blank be placed on milling train, using existing rolling mill practice roll, rolled according to required product size adjusting Passage processed and drafts, by passage tube reducing, and ensure the size of institute's Rolling compund panel products by existing rolling technological parameter And profile, the stainless steel/carbon ply-metal product of size needed for obtaining, product structure figure is as schemed(16), product transverse direction Cross-sectional view is as schemed(17);
In above-mentioned hot rolling technology, the metallurgical binding stainless steel cladding bimetallic circle composite blank of electromagnetism founding is in high temperature, high pressure Under the conditions of better diffusion layer is formed at contact interface, interface bond strength is further increased, so as to improve its extension Rate, tensile strength.
(C)Post processing:
Stainless steel/carbon ply-metal after rolling is annealed, smooth aligning, pickling, trimming scale, ultrasonic wave visit Wound;The surface of ply-metal can be processed as needed, such as surface polishing, embossing, coloring;
Other processes and equipment are identical with embodiment 1 and 9.Slightly.

Claims (8)

  1. It is 1. a kind of to manufacture metallurgical binding ply-metal technique, it is characterised in that:Process technology scheme is comprised the following steps:
    (a)Bimetallic composite blank founding;(b)Compound sheet metal forming;(C)Post processing:
    (a)Bimetallic composite blank founding:
    Solving the process technology scheme of its technical problem use is:The required material and the outer layer of size that will have been manufactured first are combined Tubes of material(6)After inner wall surface carries out oil removing, processing of rust removing, cleaned using acetone, it is then uniform on cleaned surface One layer of high-temp antioxidizing paint of coating, is fixed in bottom board(13)On the center in molten metal exit above, In outer layer composite material tube(6)One layer of fire resisting material fiber of outside cladding(8), or conduction heating set is installed(19), open Transmission system on dynamic jacking equipment(1)Rotate lifting screw(3)Or hydraulic cylinder(3)Drive and be arranged on lifting column(2)On Lifting arm(4)Will be installed in lifting arm with set speed(4)Electromagnetic induction heater above(5)Drop to outer layer to be combined Tubes of material(6)Bottom, start electromagnetic induction heating power supply, make sensing heater(6)Directly to outer layer composite material tube(6)Enter The overall heating of row, or sensing heater(5)By installed in outer layer of composite material pipe(6)Outside conduction heating set(19)It is right Outer layer of composite material pipe(6)Overall heating is carried out, by installed in outer layer of composite material pipe(6)Temperature thermocouple above(15) Thermometric and control heating-up temperature are carried out, after to be heated to 600 DEG C~1000 DEG C, the internal layer of the required composite parts that will have been smelted is answered Condensation material molten metal(7)Pour into pouring ladle(9)It is interior, by pouring ladle(9)Interior molten metal passes through according to predetermined cast program Depositing funnel(10), feed trumpet(11), casting runner brick(12)Interior a cast runner(14)Pour into outer layer of composite material pipe(6) It is interior, in casting process, electromagnetic induction heater(5)Do not stop heating, molten metal(7)After being poured, sensing heater after It is continuous to carry out heating 10~30 minutes, make poured into a mould molten metal that liquid is kept within the regular hour, to increase the liquid solid time, make Interface forms metallurgical binding, works as molten metal(7)Take a note mode to pour into a mould when being poured at rising head carries out feeding with to rising head, pours After note is finished, heat preserving agent is added in insulated feeder;
    When directly being poured into a mould using top, by pouring ladle(9)And gate spool(27)Outer layer of composite material pipe is moved on to together(6)Endoporus Top, by pouring ladle(9)Alignment composite material tube(6)Endoporus center, starts from gate spool(27)Pour into inner layer composite material gold Category liquid(7), molten metal(7)It is poured into composite material tube(6)After interior die cavity, according to poring rate progressively by pouring ladle(9)With Gate spool(27)It is lifted up together, works as molten metal(7)Take a note mode to pour into a mould when being poured at rising head is carried out with to rising head Feeding, after being poured, heat preserving agent is added in insulated feeder;
    Start lowering or hoisting gear, by lifting arm(5)Will be installed in lifting arm with set speed(4)Electromagnetic induction above adds Hot device(5)It is lifted up with certain speed, makes electromagnetic induction heater(5)Composite bed is gradually disengaged, while opening bottom water tank (17)Water inlet pipe(16)And outlet pipe(18), make in bottom water tank(17)Under successively cooling from bottom to top, successively order is formed Solidification, and according to quality requirement by controlling electromagnetic induction heater(5)The rate of climb in different regions, realizes region Directional solidification, was raised at insulated feeder by 5~25 minutes and stops, and continued to carrying out heating 10~50 minutes at insulated feeder, To postpone insulated feeder setting time, feeding is carried out to rising head, gas and field trash in composite-layer metal liquid is fully floated, Composite-layer metal casting flaw is eliminated, heating is stopped after reaching the scheduled time, dismounting is coated on outer layer of composite material pipe(6)Outside Fire resisting material fiber(8)Or installed in outer layer of composite material pipe(6)Outside conduction heating set(19), close bottom water tank and enter Water pipe, unclamps outer layer of composite material pipe(6)Fixing device, the interface that will cast is in metallurgical binding by outer layer of composite material (6)And inner layer material(7)It is bimetallic compound interface mixed layer with centre(29)Double metallic composite material from bottom board (13)Hang out above;
    When using gas heating, gas supply pipe is opened(24)Valve, light gas nozzle(23), adjust gas quantity big It is small, by high-temperature fuel gas to outer layer composite material tube(6)Heated, after being poured, opened bottom water tank(17)Water inlet Pipe(16)And outlet pipe(18), by bottom water tank(17)Successively cooling from bottom to top is produced, while by gas nozzle(23)By It is lower successively to stop heating upwards, make inner layer material(7)Successively consecutive solidification from bottom to top is formed, and according to quality requirement by control Gas nozzle processed(23)The size of heat time and heating amount in different regions, realizes region directional solidification;
    The cladding material of described double metallic composite material(6)Material be stainless steel, mould steel, tool steel, high-speed steel, alloy Steel, mild steel, cast steel, cast iron, alloy cast iron, rich chromium cast iron, titanium, copper, copper alloy, aluminium, aluminium alloy, magnesium, magnesium alloy, Ni-based conjunction Gold, fine silver, silver alloy are one kind of;
    Described inner layer composite material(7)Material for stainless steel, mould steel, steel alloy, mild steel, cast steel, cast iron, alloy casting Iron, rich chromium cast iron, titanium, copper, copper alloy, aluminium, aluminium alloy, magnesium, magnesium alloy, nickel-base alloy, fine silver, silver alloy are one kind of;
    (b)Compound sheet metal forming:
    The good bimetallic composite blank of founding is put into 320~1280 DEG C are heated in heating furnace, be incubated 30~60 points Clock;The bimetallic composite blank after by heating is placed on milling train, is rolled using existing rolling mill practice, according to required product Size adjusting rolling pass and drafts, by passage tube reducing, and ensure institute's rolling composite plate by existing rolling technological parameter The size and profile of product, the ply-metal product of size needed for obtaining;
    The mode of heating of the bimetallic blank is one of gas heating, electrical heating, electromagnetic induction heating, heating plasma Kind;
    (C)Post processing:
    Ply-metal after rolling is annealed, smooth aligning, pickling, trimming scale, ultrasonic examination;Can be according to need The surface of ply-metal is processed, such as surface polishing, embossing, coloring.
  2. 2. it is a kind of realize manufacture metallurgical binding ply-metal technique equipment, it is characterized in that:The equipment is by jacking equipment, sense Firing equipment, gas heating equipment, running gate system is answered to constitute;Described jacking equipment is single column or planer type structure, In lifting column(2)On transmission system 1 is installed, by transmission system(1)Rotate lifting screw(3)Or hydraulic cylinder(3)Drive Installed in lifting column(2)On lifting arm(4)Moved up and down with set speed, in lifting arm(4)Above be provided with Electromagnetic induction heater(5), electromagnetic induction heater(5)It is connected with electromagnetic induction electrical power control cabinet, under jacking equipment Portion is provided with bottom board(13), in bottom board(13)On be provided with a cast runner Cao, in bottom board(13)On pour beam The a cast runner brick of refractory material making is installed in road Cao(12), outer layer of composite material pipe(6)It is fixed on bottom board(13) Above, in outer layer composite material tube(6)One layer of fire resisting material fiber of outside cladding(8), or conduction heating set is installed (19), electromagnetic induction heater(5)Installed in outer layer of composite material pipe(6)The fire resisting material fiber of outside(8)Outside, or It is directly installed on outer layer of composite material pipe(6)Conduction heating set(19)Outside, in outer layer composite material tube(6)Side peace Equipped with feed trumpet(11), feed trumpet(11)Bottom and a cast runner brick(12)It is connected, a cast runner brick(12)Inside there is cast Runner(14), molten metal outlet is installed in outer layer of composite material pipe(6)The center of bottom, feed trumpet(11)Top install There is sprue cup(10), in depositing funnel(10)Above have pouring ladle(9), in outer layer composite material tube(6)Above install There is insulated feeder(25)And temperature thermocouple(15), in bottom board(13)Below bottom water tank is installed(17), in bottom water tank (17)The bottom of side is provided with water inlet pipe(16), in bottom water tank(17)The top of side is provided with outlet pipe(18);
    When using gas heating, in outer layer composite material tube(6)Outside heat insulation mould is installed(20), heat insulation mould(20) It is fixed on bottom board(13)Above, in heat insulation mould(20)Internal layer post heat insulating refractory material(21), in heat insulation mould (20)With outer layer of composite material pipe(6)Intermediate space in gas supply pipe is installed(24), in gas supply pipe(24)It is upper Face is uniformly provided with gas nozzle(23), in heat insulation mould(20)Above heat-preserving cover plate is installed(22);
    When directly being poured into a mould using top, in pouring ladle(9)Below hanging draw-in groove is installed(26), gate spool(28)Upper end Sprue cup is installed(27), sprue cup(27)By hanging draw-in groove(26)With pouring ladle(9)It is connected.
  3. 3. it is a kind of according to claim 1 to manufacture metallurgical binding ply-metal technique, it is characterized in that:The outer layer pipe The wall thickness of material is the 5%~25% of the bimetallic billet size.
  4. 4. it is a kind of according to claim 1 to manufacture metallurgical binding ply-metal technique, it is characterized in that:The outer layer is combined The weight of material is the 6%~32% of the ply-metal gross weight.
  5. 5. a kind of compound metallurgical combination bimetallic plates manufacturing process according to claim 1, it is characterized in that:Described metallurgical junction Closing ply-metal includes steel/steel composite board, the steel composite board of stainless steel one, the steel composite board of copper one, the steel composite board of aluminium one, titanium one Steel composite board, copper/aluminum composite plate, nickel/steel composite board, aluminium/titanium composite panel, fine silver/silver alloy composite plate.
  6. 6. a kind of manufacture metallurgical binding ply-metal technique is standby according to claim 1, it is characterized in that:Described outer layer Tubes of material is seamless steel pipe or ERW or spiral welded pipe, and geometry includes circular or rectangle.
  7. 7. it is a kind of according to claim 1 to manufacture metallurgical binding ply-metal technique, it is characterized in that:Described conduction adds The material of hot jacket is graphite or carborundum.
  8. 8. it is a kind of according to claim 1 to manufacture metallurgical binding ply-metal Processes and apparatus, it is characterized in that:Described Electromagnetic induction power supply is line-frequency induction power supply, medium frequency induction power supply, high frequency induction power supply, and frequency is 500Hz~10000Hz.
CN201710087503.0A 2017-02-17 2017-02-17 One kind manufacture metallurgical binding ply-metal Processes and apparatus Pending CN106862534A (en)

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CN107552768A (en) * 2017-09-18 2018-01-09 江苏凯讯新材料有限公司 The technique that aluminum silicon carbide composite material heat-radiating substrate surface covers metal level
CN107866443A (en) * 2017-08-07 2018-04-03 上海利正卫星应用技术有限公司 Strip on-line heating device during a kind of magnesium alloy rolling
CN108389660A (en) * 2018-03-06 2018-08-10 王书杰 The preparation method of copper clad aluminum composite bar
CN108878063A (en) * 2018-07-02 2018-11-23 孟静 The preparation method of copper clad aluminum cable
CN109047727A (en) * 2018-10-09 2018-12-21 鞍钢股份有限公司 A kind of device and method manufacturing metallurgical composition metal blank
CN109108256A (en) * 2018-08-13 2019-01-01 莱芜市天铭冶金设备有限公司 It is a kind of continuously to cover the compound slab of material and its casting device, method
CN109926567A (en) * 2019-04-01 2019-06-25 洛阳鹏起实业有限公司 A kind of titanium alloy/bimetal copper-steel composite members and preparation method thereof
CN109940155A (en) * 2019-03-27 2019-06-28 中国兵器工业第五九研究所 A kind of preparation method of magnesium/aluminum alloy dual-metal extruded rod
CN111230073A (en) * 2020-01-16 2020-06-05 青岛力晨新材料科技有限公司 Stainless steel/carbon steel composite board and manufacturing process thereof
CN111391432A (en) * 2020-04-22 2020-07-10 西安向阳航天材料股份有限公司 Bimetal composite steel plate with adhesive interface and manufacturing method thereof
CN111889990A (en) * 2020-06-24 2020-11-06 如皋市宏茂铸钢有限公司 Thermal fatigue resistant high-performance hot work die steel and manufacturing process thereof
CN111957892A (en) * 2020-08-31 2020-11-20 华中科技大学 Heat treatment method of aluminum/magnesium bimetal for lost foam casting and product
CN112170793A (en) * 2019-07-03 2021-01-05 宝山钢铁股份有限公司 Manufacturing method of metal composite long material and metal composite long material
CN112191827A (en) * 2020-09-28 2021-01-08 安徽七里松铝业科技有限公司 Die for manufacturing aluminum alloy plate and manufacturing method thereof
CN113523240A (en) * 2021-07-19 2021-10-22 青岛力晨新材料科技有限公司 Bimetal composite board and preparation method thereof
CN114210953A (en) * 2021-12-17 2022-03-22 歌尔光学科技有限公司 Magnesium-lithium-aluminum composite material part and preparation method and application thereof
CN114589465A (en) * 2022-03-16 2022-06-07 四川鑫鼎新材料有限公司 Preparation method of composite strip steel for die casting composite slab rolling cutter
CN117483719A (en) * 2023-11-09 2024-02-02 苏州朗威电子机械股份有限公司 Preparation device and process of composite steel plate with carbide ceramic interlayer

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CN107866443A (en) * 2017-08-07 2018-04-03 上海利正卫星应用技术有限公司 Strip on-line heating device during a kind of magnesium alloy rolling
CN107866443B (en) * 2017-08-07 2023-11-28 上海利正卫星应用技术有限公司 On-line heating device for plate and strip during magnesium alloy rolling
CN107552768A (en) * 2017-09-18 2018-01-09 江苏凯讯新材料有限公司 The technique that aluminum silicon carbide composite material heat-radiating substrate surface covers metal level
CN107552768B (en) * 2017-09-18 2019-06-14 江苏凯讯新材料有限公司 A kind of process in aluminium gold hard rock composite material surface covering molybdenum foil
CN108389660A (en) * 2018-03-06 2018-08-10 王书杰 The preparation method of copper clad aluminum composite bar
CN108389660B (en) * 2018-03-06 2019-06-25 扬州飞翎合金科技有限公司 The preparation method of cable copper clad aluminum composite bar
CN108878063A (en) * 2018-07-02 2018-11-23 孟静 The preparation method of copper clad aluminum cable
CN109108256A (en) * 2018-08-13 2019-01-01 莱芜市天铭冶金设备有限公司 It is a kind of continuously to cover the compound slab of material and its casting device, method
CN109047727B (en) * 2018-10-09 2020-07-17 鞍钢股份有限公司 Method for manufacturing metallurgical composite metal blank
CN109047727A (en) * 2018-10-09 2018-12-21 鞍钢股份有限公司 A kind of device and method manufacturing metallurgical composition metal blank
CN109940155A (en) * 2019-03-27 2019-06-28 中国兵器工业第五九研究所 A kind of preparation method of magnesium/aluminum alloy dual-metal extruded rod
CN109926567A (en) * 2019-04-01 2019-06-25 洛阳鹏起实业有限公司 A kind of titanium alloy/bimetal copper-steel composite members and preparation method thereof
CN112170793A (en) * 2019-07-03 2021-01-05 宝山钢铁股份有限公司 Manufacturing method of metal composite long material and metal composite long material
CN111230073A (en) * 2020-01-16 2020-06-05 青岛力晨新材料科技有限公司 Stainless steel/carbon steel composite board and manufacturing process thereof
CN111230073B (en) * 2020-01-16 2021-09-28 青岛力晨新材料科技有限公司 Method for manufacturing stainless steel/carbon steel composite board
CN111391432A (en) * 2020-04-22 2020-07-10 西安向阳航天材料股份有限公司 Bimetal composite steel plate with adhesive interface and manufacturing method thereof
CN111391432B (en) * 2020-04-22 2024-06-11 西安向阳航天材料股份有限公司 Bimetal composite steel plate with adhesive interface and manufacturing method thereof
CN111889990B (en) * 2020-06-24 2021-05-04 如皋市宏茂铸钢有限公司 Thermal fatigue resistant high-performance hot work die steel and manufacturing process thereof
CN111889990A (en) * 2020-06-24 2020-11-06 如皋市宏茂铸钢有限公司 Thermal fatigue resistant high-performance hot work die steel and manufacturing process thereof
CN111957892A (en) * 2020-08-31 2020-11-20 华中科技大学 Heat treatment method of aluminum/magnesium bimetal for lost foam casting and product
CN112191827B (en) * 2020-09-28 2021-09-21 安徽七里松铝业科技有限公司 Die for manufacturing aluminum alloy plate and application method thereof
CN112191827A (en) * 2020-09-28 2021-01-08 安徽七里松铝业科技有限公司 Die for manufacturing aluminum alloy plate and manufacturing method thereof
CN113523240A (en) * 2021-07-19 2021-10-22 青岛力晨新材料科技有限公司 Bimetal composite board and preparation method thereof
CN114210953A (en) * 2021-12-17 2022-03-22 歌尔光学科技有限公司 Magnesium-lithium-aluminum composite material part and preparation method and application thereof
CN114589465A (en) * 2022-03-16 2022-06-07 四川鑫鼎新材料有限公司 Preparation method of composite strip steel for die casting composite slab rolling cutter
CN117483719A (en) * 2023-11-09 2024-02-02 苏州朗威电子机械股份有限公司 Preparation device and process of composite steel plate with carbide ceramic interlayer
CN117483719B (en) * 2023-11-09 2024-04-16 苏州朗威电子机械股份有限公司 Preparation device and process of composite steel plate with carbide ceramic interlayer

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