CN106854402A - A kind of coating composition and preparation method thereof - Google Patents

A kind of coating composition and preparation method thereof Download PDF

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Publication number
CN106854402A
CN106854402A CN201611141592.4A CN201611141592A CN106854402A CN 106854402 A CN106854402 A CN 106854402A CN 201611141592 A CN201611141592 A CN 201611141592A CN 106854402 A CN106854402 A CN 106854402A
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CN
China
Prior art keywords
parts
resin
coating composition
filler
emulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611141592.4A
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Chinese (zh)
Inventor
郝媛媛
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Qinzhou University
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Qinzhou University
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Filing date
Publication date
Application filed by Qinzhou University filed Critical Qinzhou University
Priority to CN201611141592.4A priority Critical patent/CN106854402A/en
Publication of CN106854402A publication Critical patent/CN106854402A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D103/00Coating compositions based on starch, amylose or amylopectin or on their derivatives or degradation products
    • C09D103/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

The invention discloses a kind of coating composition and preparation method thereof, it is made up of following mass fraction formula components:10 20 parts of emulsion, 5 15 parts of polyester based resin, 24 parts of adhesion promoter, 24 parts of pigment, 16 18 parts of filler, 6 10 parts of the solvent of isophorone, 68 parts of fluorine organo-silicon compound, 24 parts of polyalcohol, 46 parts of polymerizable unsaturated compound, 14 16 parts of acrylic resin, 68 parts of unsaturated polyester resin, 13 parts of auxiliary agent, starch with biological degradability of the present invention from natural products, as one-pack-type coating fine properties, and drying property can be formed, ornamenting, pencil hardness, wear resistance, tack, alkali resistance, the characteristics of solvent resistance and excellent weatherability.

Description

A kind of coating composition and preparation method thereof
Technical field
The present invention relates to paint field, in particular to a kind of coating composition and preparation method thereof.
Background technology
In recent years, reduced on earth environment influence from the treatability for improving discarded object, the discharge capacity reduction for reducing CO2 etc. Angle considers, it is desirable to actively using small to environmental pressure from natural products, the raw material with biological degradability.
As this representative materials from natural products, the modified shallow lake such as the starch or acetylated starch of polysaccharide Powder, is previously used for food industry, paper industry, and in recent years, using these starch as biodegradable plastic raw material, By commercialization in the wide spectrums such as food containers, package, buffer substrate tablet, agricultural film, disposable diaper.
The content of the invention
The invention provides a kind of coating composition and preparation method thereof, the present invention is from natural products with biology The starch of degradability, as one-pack-type coating fine properties and can be formed drying property, ornamenting, pencil hardness, The characteristics of wear resistance, tack, alkali resistance, solvent resistance and excellent weatherability.
To achieve the above object, the present invention provides following technical scheme:
A kind of coating composition and preparation method thereof, is made up of following mass fraction formula components:Emulsion 10-20 parts, it is poly- 5-15 parts of ester system resin, adhesion promoter 2-4 parts, pigment 2-4 parts, filler 16-18 parts, solvent 6-10 parts of isophorone, 6-8 parts of fluorine organo-silicon compound, polyalcohol 2-4 parts, polymerizable unsaturated compound 4-6 parts, acrylic resin 14-16 parts, no Saturated polyester resin 6-8 parts, auxiliary agent 1-3 parts.
Further:It is made up of following mass fraction formula components:10 parts of emulsion, 5 parts of polyester based resin, adhesion promoter 2 parts, 2 parts of pigment, 16 parts of filler, 6 parts of the solvent of isophorone, 6 parts of fluorine organo-silicon compound, 2 parts of polyalcohol, polymerism insatiable hunger With 4 parts of compound, 14 parts of acrylic resin, 6 parts of unsaturated polyester resin, 1 part of auxiliary agent.
Further:It is made up of following mass fraction formula components:15 parts of emulsion, 10 parts of polyester based resin, adhesive force promote 3 parts of agent, 3 parts of pigment, 17 parts of filler, 8 parts of the solvent of isophorone, 7 parts of fluorine organo-silicon compound, 3 parts of polyalcohol, polymerism are not 5 parts of saturated compounds, 15 parts of acrylic resin, 7 parts of unsaturated polyester resin, 2 parts of auxiliary agent.
Further:It is made up of following mass fraction formula components:20 parts of emulsion, 15 parts of polyester based resin, adhesive force promote 4 parts of agent, 4 parts of pigment, 18 parts of filler, 10 parts of the solvent of isophorone, 8 parts of fluorine organo-silicon compound, 4 parts of polyalcohol, polymerism 6 parts of unsaturated compound, 16 parts of acrylic resin, 8 parts of unsaturated polyester resin, 3 parts of auxiliary agent.
Further:Preparation method of the present invention has following steps:
Step one, selection emulsion, polyester based resin, filler, acrylic resin and unsaturated polyester resin, according to quality point Number carries out dispensing, and after being well mixed, decoction is secondary, 1.0~1.5 hours every time, obtains mixture;
Step 2, step one gains are carried out filtering go the removal of impurity;
Step 3, step 2 gained will be warming up to 200-400 DEG C of addition surplus stock, be sufficiently stirred for, stood 12 small Shi Hou,
Step 4, will step 3 gained stir evenly, filter, get product.
The beneficial effects of the invention are as follows:The present invention is from the starch with biological degradability of natural products, as single It is liquid type coating fine properties and the drying property that can be formed, ornamenting, pencil hardness, wear resistance, tack, resistance to The characteristics of alkalescence, solvent resistance and excellent weatherability.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all Belong to the scope of protection of the invention.
Embodiment one:
A kind of coating composition is made up of following mass fraction formula components:Emulsion 10-20 parts, polyester based resin 5-15 Part, adhesion promoter 2-4 parts, pigment 2-4 parts, filler 16-18 parts, solvent 6-10 parts of isophorone, fluorine organosilicon compound Thing 6-8 parts, polyalcohol 2-4 parts, polymerizable unsaturated compound 4-6 parts, acrylic resin 14-16 parts, unsaturated polyester resin 6-8 parts, auxiliary agent 1-3 parts.
Embodiment two:
A kind of coating composition is made up of following mass fraction formula components:10 parts of emulsion, 5 parts of polyester based resin, attachment It is 2 parts of power accelerator, 2 parts of pigment, 16 parts of filler, 6 parts of the solvent of isophorone, 6 parts of fluorine organo-silicon compound, 2 parts of polyalcohol, poly- 4 parts of unsaturated compound of conjunction property, 14 parts of acrylic resin, 6 parts of unsaturated polyester resin, 1 part of auxiliary agent.
Embodiment three:
A kind of coating composition is made up of following mass fraction formula components:15 parts of emulsion, 10 parts of polyester based resin, attachment It is 3 parts of power accelerator, 3 parts of pigment, 17 parts of filler, 8 parts of the solvent of isophorone, 7 parts of fluorine organo-silicon compound, 3 parts of polyalcohol, poly- 5 parts of unsaturated compound of conjunction property, 15 parts of acrylic resin, 7 parts of unsaturated polyester resin, 2 parts of auxiliary agent.
Example IV:
A kind of coating composition is made up of following mass fraction formula components:20 parts of emulsion, 15 parts of polyester based resin, attachment 4 parts of power accelerator, 4 parts of pigment, 18 parts of filler, 10 parts of the solvent of isophorone, 8 parts of fluorine organo-silicon compound, 4 parts of polyalcohol, 6 parts of polymerizable unsaturated compound, 16 parts of acrylic resin, 8 parts of unsaturated polyester resin, 3 parts of auxiliary agent.
Embodiment five:
A kind of preparation method preparation method of coating composition comprises the following steps:
Step one, selection emulsion, polyester based resin, filler, acrylic resin and unsaturated polyester resin, according to quality point Number carries out dispensing, and after being well mixed, decoction is secondary, 1.0~1.5 hours every time, obtains mixture;
Step 2, step one gains are carried out filtering go the removal of impurity;
Step 3, step 2 gained will be warming up to 200-400 DEG C of addition surplus stock, be sufficiently stirred for, stood 12 small Shi Hou,
Step 4, will step 3 gained stir evenly, filter, get product.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each implementation method is only wrapped Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should Specification an as entirety, the technical scheme in each embodiment can also be formed into those skilled in the art through appropriately combined May be appreciated other embodiment.

Claims (5)

1. a kind of coating composition, it is characterised in that:It is made up of following mass fraction formula components:
Emulsion 10-20 parts, polyester based resin 5-15 parts, adhesion promoter 2-4 parts, pigment 2-4 parts, filler 16-18 parts, different Buddhist Solvent 6-10 parts of your ketone, 6-8 parts of fluorine organo-silicon compound, polyalcohol 2-4 parts, polymerizable unsaturated compound 4-6 parts, propylene Acid resin 14-16 parts, unsaturated polyester resin 6-8 parts, auxiliary agent 1-3 parts.
2. a kind of coating composition according to claim 1, it is characterised in that:By following mass fraction formula components group Into:
10 parts of emulsion, 5 parts of polyester based resin, 2 parts of adhesion promoter, 2 parts of pigment, 16 parts of filler, the solvent 6 of isophorone Part, 6 parts of fluorine organo-silicon compound, 2 parts of polyalcohol, 4 parts of polymerizable unsaturated compound, 14 parts of acrylic resin, unsaturation are poly- 6 parts of ester resin, 1 part of auxiliary agent.
3. a kind of coating composition according to claim 1, it is characterised in that:By following mass fraction formula components group Into:
15 parts of emulsion, 10 parts of polyester based resin, 3 parts of adhesion promoter, 3 parts of pigment, 17 parts of filler, the solvent 8 of isophorone Part, 7 parts of fluorine organo-silicon compound, 3 parts of polyalcohol, 5 parts of polymerizable unsaturated compound, 15 parts of acrylic resin, unsaturation are poly- 7 parts of ester resin, 2 parts of auxiliary agent.
4. a kind of coating composition according to claim 1, it is characterised in that:By following mass fraction formula components group Into:
20 parts of emulsion, 15 parts of polyester based resin, 4 parts of adhesion promoter, 4 parts of pigment, 18 parts of filler, the solvent 10 of isophorone Part, 8 parts of fluorine organo-silicon compound, 4 parts of polyalcohol, 6 parts of polymerizable unsaturated compound, 16 parts of acrylic resin, unsaturation are poly- 8 parts of ester resin, 3 parts of auxiliary agent.
5. a kind of a kind of preparation method of coating composition according to claim 1, it is characterised in that:Including following step Suddenly:
Step one, selection emulsion, polyester based resin, filler, acrylic resin and unsaturated polyester resin, enter according to mass fraction Row dispensing, after being well mixed, decoction is secondary, 1.0~1.5 hours every time, obtains mixture;
Step 2, step one gains are carried out filtering go the removal of impurity;
Step 3, will step 2 gained be warming up to 200-400 DEG C addition surplus stock, be sufficiently stirred for, stand 12 hours after,
Step 4, will step 3 gained stir evenly, filter, get product.
CN201611141592.4A 2016-12-12 2016-12-12 A kind of coating composition and preparation method thereof Pending CN106854402A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611141592.4A CN106854402A (en) 2016-12-12 2016-12-12 A kind of coating composition and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201611141592.4A CN106854402A (en) 2016-12-12 2016-12-12 A kind of coating composition and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106854402A true CN106854402A (en) 2017-06-16

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101583679A (en) * 2007-01-23 2009-11-18 大金工业株式会社 Coating composition
CN103952043A (en) * 2014-04-28 2014-07-30 沈建国 General coating, preparation method thereof and general paint
CN104140755A (en) * 2014-07-27 2014-11-12 北京东方雨虹防水技术股份有限公司 Environment-friendly elastic weather-resistant acrylic polyurethane coating, preparation and application
CN104672972A (en) * 2013-11-27 2015-06-03 常州校果信息服务有限公司 Coating material composition

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101583679A (en) * 2007-01-23 2009-11-18 大金工业株式会社 Coating composition
CN104672972A (en) * 2013-11-27 2015-06-03 常州校果信息服务有限公司 Coating material composition
CN103952043A (en) * 2014-04-28 2014-07-30 沈建国 General coating, preparation method thereof and general paint
CN104140755A (en) * 2014-07-27 2014-11-12 北京东方雨虹防水技术股份有限公司 Environment-friendly elastic weather-resistant acrylic polyurethane coating, preparation and application

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Application publication date: 20170616

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